Polysulfonylamines. XCV. (1,2-Benzenedisulfonylimido-N,O)(1,4,7,10,13-pentaoxacyclopentadecane-κ⁵O)sodium

In the title complex, [Na(C₆H₄NO₄S₂)(C₁₀H₂₀O₅)], an irregular coordination sphere around Na⁺ is formed by the five O atoms of 15-crown-5 and the N and one O atom of the disulfonylimide 1,3,2-benzodithiazole 1,1,3,3-tetraoxide(1−). In one C—C—O segment of the polyether ring, two successive gauche torsion angles of the same sign constitute a conformational corner.

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