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The crystal structure of the tricyclic keto lactone, C18H18O4, has been determined by X-ray diffraction. The eight-membered heterocyclic ring in the molecule displays a distorted boat conformation in contrast to the more favoured boat-chair conformation in various oxygen-containing eight-membered ring systems.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks lact, lactone

CCDC reference: 128040

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