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The title compound, [Pt(CO3)(C18H15P)2]·C6H6, has pre­viously been reported by Cariati, Mason, Robertson & Ugo [Chem. Commun. (1967), p. 408]. However, no coordin­ates were published. We present here a redetermination of this structure using new intensity data. The Pt atom shows a distorted square-planar coordination. It carries two PPh3 residues and is chelated by a carbonate ion.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806001322/lh6579sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806001322/lh6579Isup2.hkl
Contains datablock I

CCDC reference: 298496

Key indicators

  • Single-crystal X-ray study
  • T = 100 K
  • Mean [sigma](C-C) = 0.020 Å
  • R factor = 0.057
  • wR factor = 0.126
  • Data-to-parameter ratio = 14.5

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT213_ALERT_2_C Atom C26 has ADP max/min Ratio ............. 3.50 prolat PLAT213_ALERT_2_C Atom C51 has ADP max/min Ratio ............. 3.30 prolat PLAT243_ALERT_4_C High 'Solvent' Ueq as Compared to Neighbors for C73 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for C74 PLAT332_ALERT_2_C Large Phenyl C-C Range C21 -C26 0.19 Ang. PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 20
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: X-AREA (Stoe & Cie, 2001); cell refinement: X-AREA; data reduction: X-AREA; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP in SHELXTL-Plus (Sheldrick, 1991); software used to prepare material for publication: SHELXL97 and PLATON.

Carbonatobis(triphenylphosphine)platinum(II) benzene solvate top
Crystal data top
[Pt(CO3)(C18H15P)2]·C6H6Z = 2
Mr = 857.75F(000) = 852
Triclinic, P1Dx = 1.580 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.594 (2) ÅCell parameters from 12395 reflections
b = 12.512 (2) Åθ = 2.1–25.2°
c = 15.195 (2) ŵ = 4.02 mm1
α = 85.15 (1)°T = 100 K
β = 71.34 (1)°Needle, colourless
γ = 70.91 (1)°0.11 × 0.08 × 0.04 mm
V = 1802.9 (5) Å3
Data collection top
Stoe IPDS-II two-circle
diffractometer
6408 independent reflections
Radiation source: fine-focus sealed tube4337 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.081
ω scansθmax = 25.2°, θmin = 1.4°
Absorption correction: multi-scan
(MULABS; Spek, 2003; Blessing, 1995)
h = 1112
Tmin = 0.666, Tmax = 0.856k = 1414
21885 measured reflectionsl = 018
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.057Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.126H-atom parameters constrained
S = 0.95 w = 1/[σ2(Fo2) + (0.0154P)2]
where P = (Fo2 + 2Fc2)/3
6408 reflections(Δ/σ)max < 0.001
442 parametersΔρmax = 2.04 e Å3
0 restraintsΔρmin = 1.27 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pt10.67942 (6)0.62015 (5)0.22046 (4)0.01740 (13)
P10.6181 (3)0.7725 (3)0.1357 (2)0.0197 (6)
P20.7993 (3)0.6854 (3)0.2924 (2)0.0197 (7)
C10.6510 (13)0.4274 (10)0.2256 (8)0.026 (3)
O10.5932 (8)0.5168 (7)0.1775 (7)0.030 (2)
O20.7176 (8)0.4598 (8)0.2748 (6)0.027 (2)
O30.6456 (8)0.3311 (7)0.2235 (7)0.034 (2)
C110.4796 (11)0.7684 (10)0.0902 (8)0.020 (2)
C120.5077 (12)0.6725 (11)0.0297 (9)0.028 (3)
H120.59320.61140.01630.034*
C130.4052 (10)0.6767 (10)0.0053 (7)0.018 (2)
H130.42140.61240.04160.022*
C140.2816 (12)0.7598 (10)0.0039 (9)0.028 (3)
H140.21880.75670.02800.033*
C150.2518 (13)0.8510 (12)0.0635 (10)0.036 (3)
H150.16370.90930.07710.043*
C160.3539 (13)0.8549 (11)0.1028 (9)0.032 (3)
H160.33570.91940.13930.038*
C210.5406 (11)0.9098 (10)0.1945 (9)0.024 (3)
C220.5615 (12)1.0086 (10)0.1582 (9)0.025 (3)
H220.62921.00770.09920.031*
C230.4817 (14)1.1139 (12)0.2085 (10)0.037 (3)
H230.49311.18300.18190.045*
C240.3889 (15)1.1136 (13)0.2955 (11)0.045 (4)
H240.34131.18180.33140.054*
C250.3646 (16)1.0136 (12)0.3311 (12)0.042 (4)
H250.29581.01690.38990.051*
C260.4316 (14)0.9145 (10)0.2879 (8)0.028 (3)
H260.41180.84810.31470.034*
C310.7631 (12)0.7749 (9)0.0330 (8)0.023 (3)
C320.7408 (13)0.8456 (11)0.0407 (9)0.030 (3)
H320.64910.89500.03620.036*
C330.8551 (13)0.8439 (10)0.1228 (10)0.032 (3)
H330.84100.89660.17030.038*
C340.9912 (15)0.7625 (15)0.1331 (10)0.043 (4)
H341.06750.75700.18840.052*
C351.0069 (11)0.6912 (11)0.0580 (9)0.027 (3)
H351.09700.63900.06230.032*
C360.8988 (11)0.6937 (10)0.0205 (9)0.028 (3)
H360.91380.64080.06780.034*
C410.7464 (11)0.6509 (10)0.4147 (8)0.022 (2)
C420.6046 (12)0.6632 (10)0.4583 (8)0.024 (3)
H420.54140.68390.42270.028*
C430.5539 (12)0.6455 (11)0.5541 (8)0.028 (3)
H430.45790.65180.58370.033*
C440.6511 (14)0.6179 (11)0.6046 (10)0.036 (3)
H440.61940.60660.66950.044*
C450.7929 (13)0.6070 (11)0.5612 (9)0.031 (3)
H450.85610.58730.59680.037*
C460.8424 (13)0.6247 (11)0.4661 (9)0.031 (3)
H460.93810.61930.43670.037*
C510.9879 (11)0.6013 (11)0.2483 (7)0.021 (3)
C521.0922 (13)0.6506 (12)0.2487 (10)0.032 (3)
H521.06510.72590.27130.038*
C531.2366 (13)0.5856 (12)0.2150 (10)0.032 (3)
H531.30660.61890.21190.039*
C541.2749 (12)0.4761 (12)0.1872 (9)0.033 (3)
H541.37080.43060.16930.040*
C551.1723 (12)0.4323 (12)0.1856 (10)0.033 (3)
H551.19940.35710.16280.039*
C561.0266 (12)0.4961 (12)0.2169 (10)0.036 (3)
H560.95800.46350.21530.043*
C610.7932 (13)0.8332 (11)0.2913 (10)0.030 (3)
C620.8616 (13)0.8810 (12)0.2114 (10)0.032 (3)
H620.91280.83550.15650.038*
C630.8566 (13)0.9932 (12)0.2103 (11)0.036 (3)
H630.90671.02290.15580.044*
C640.7796 (15)1.0611 (12)0.2878 (11)0.043 (4)
H640.77381.13860.28660.051*
C650.7092 (16)1.0158 (13)0.3691 (11)0.044 (4)
H650.65831.06170.42380.053*
C660.7147 (13)0.9028 (12)0.3689 (11)0.040 (4)
H660.66370.87310.42310.048*
C710.9662 (19)0.1470 (16)0.5225 (13)0.058 (5)
H711.03600.08220.53410.069*
C720.9830 (17)0.1900 (17)0.4327 (14)0.064 (5)
H721.06650.15260.38500.077*
C730.891 (2)0.2789 (18)0.4092 (14)0.071 (5)
H730.90240.30000.34630.086*
C740.7707 (15)0.3434 (13)0.4862 (11)0.042 (4)
H740.70590.41210.47520.051*
C750.7548 (19)0.3007 (15)0.5749 (12)0.055 (4)
H750.67760.34230.62460.066*
C760.8453 (17)0.2007 (15)0.5949 (13)0.052 (4)
H760.82620.16970.65520.062*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt10.01574 (19)0.0176 (2)0.0179 (2)0.00476 (15)0.00497 (15)0.00240 (16)
P10.0192 (14)0.0203 (16)0.0173 (16)0.0055 (12)0.0039 (12)0.0012 (13)
P20.0227 (15)0.0148 (15)0.0253 (18)0.0062 (13)0.0124 (13)0.0018 (13)
C10.041 (7)0.023 (7)0.018 (6)0.021 (6)0.003 (6)0.005 (5)
O10.016 (4)0.023 (5)0.049 (6)0.005 (4)0.008 (4)0.002 (4)
O20.027 (4)0.040 (5)0.020 (5)0.013 (4)0.015 (4)0.007 (4)
O30.024 (4)0.028 (5)0.045 (6)0.003 (4)0.008 (4)0.004 (4)
C110.016 (5)0.023 (6)0.018 (6)0.006 (5)0.000 (5)0.000 (5)
C120.024 (6)0.031 (7)0.024 (7)0.008 (5)0.001 (5)0.002 (6)
C130.017 (5)0.026 (6)0.011 (6)0.004 (5)0.008 (4)0.007 (5)
C140.023 (6)0.029 (7)0.032 (7)0.008 (5)0.010 (5)0.002 (6)
C150.025 (6)0.039 (8)0.035 (8)0.002 (6)0.010 (6)0.003 (7)
C160.031 (7)0.033 (7)0.034 (8)0.013 (6)0.010 (6)0.002 (6)
C210.017 (5)0.024 (6)0.034 (7)0.009 (5)0.013 (5)0.006 (6)
C220.020 (6)0.018 (6)0.031 (7)0.002 (5)0.003 (5)0.000 (5)
C230.035 (7)0.029 (7)0.042 (9)0.000 (6)0.011 (6)0.011 (7)
C240.039 (8)0.043 (9)0.041 (9)0.004 (7)0.008 (7)0.021 (7)
C250.044 (8)0.023 (7)0.046 (10)0.000 (6)0.004 (7)0.002 (7)
C260.060 (8)0.017 (6)0.016 (6)0.015 (6)0.021 (6)0.011 (5)
C310.030 (6)0.013 (6)0.026 (7)0.013 (5)0.001 (5)0.005 (5)
C320.029 (6)0.029 (7)0.032 (8)0.005 (5)0.013 (6)0.001 (6)
C330.039 (7)0.013 (6)0.039 (8)0.009 (5)0.005 (6)0.008 (6)
C340.028 (7)0.074 (12)0.026 (8)0.024 (8)0.003 (6)0.008 (8)
C350.015 (5)0.038 (7)0.034 (7)0.015 (5)0.010 (5)0.001 (6)
C360.021 (6)0.025 (6)0.035 (8)0.003 (5)0.011 (5)0.009 (6)
C410.022 (6)0.023 (6)0.018 (6)0.005 (5)0.005 (5)0.001 (5)
C420.029 (6)0.029 (7)0.017 (6)0.013 (5)0.011 (5)0.009 (5)
C430.024 (6)0.048 (8)0.015 (6)0.013 (6)0.008 (5)0.007 (6)
C440.044 (8)0.032 (7)0.031 (8)0.007 (6)0.015 (6)0.001 (6)
C450.039 (7)0.031 (7)0.021 (7)0.005 (6)0.014 (6)0.007 (6)
C460.024 (6)0.035 (7)0.032 (8)0.007 (6)0.009 (6)0.005 (6)
C510.013 (5)0.042 (8)0.009 (5)0.009 (5)0.008 (4)0.006 (5)
C520.023 (6)0.033 (8)0.043 (9)0.012 (6)0.013 (6)0.006 (7)
C530.024 (6)0.042 (9)0.037 (8)0.018 (6)0.012 (6)0.007 (7)
C540.018 (6)0.041 (8)0.038 (8)0.009 (6)0.003 (5)0.007 (7)
C550.015 (6)0.038 (8)0.037 (8)0.002 (5)0.001 (5)0.006 (6)
C560.019 (6)0.041 (8)0.056 (9)0.018 (6)0.014 (6)0.004 (7)
C610.029 (6)0.025 (7)0.040 (8)0.009 (5)0.017 (6)0.009 (6)
C620.027 (7)0.037 (8)0.033 (8)0.013 (6)0.008 (6)0.002 (7)
C630.028 (6)0.036 (8)0.055 (10)0.018 (6)0.020 (7)0.009 (7)
C640.046 (8)0.023 (7)0.058 (10)0.018 (7)0.007 (8)0.001 (7)
C650.058 (9)0.035 (8)0.037 (9)0.018 (7)0.007 (7)0.007 (7)
C660.023 (7)0.035 (8)0.038 (9)0.005 (6)0.009 (6)0.001 (7)
C710.069 (11)0.059 (11)0.054 (11)0.018 (9)0.036 (10)0.014 (9)
C720.043 (9)0.074 (13)0.063 (13)0.002 (9)0.014 (9)0.014 (11)
C730.067 (12)0.079 (14)0.057 (12)0.006 (10)0.025 (10)0.014 (11)
C740.045 (8)0.040 (8)0.050 (10)0.015 (7)0.022 (7)0.011 (7)
C750.073 (11)0.053 (10)0.048 (10)0.030 (9)0.022 (9)0.004 (9)
C760.056 (10)0.054 (10)0.056 (11)0.029 (9)0.024 (9)0.015 (9)
Geometric parameters (Å, º) top
Pt1—O12.057 (8)C41—C421.396 (15)
Pt1—O22.067 (9)C41—C461.414 (16)
Pt1—P12.242 (3)C42—C431.408 (16)
Pt1—P22.279 (3)C42—H420.9500
P1—C311.812 (12)C43—C441.413 (17)
P1—C211.816 (13)C43—H430.9500
P1—C111.826 (11)C44—C451.399 (18)
P2—C411.818 (12)C44—H440.9500
P2—C611.828 (13)C45—C461.396 (18)
P2—C511.854 (11)C45—H450.9500
C1—O31.228 (14)C46—H460.9500
C1—O21.340 (14)C51—C561.325 (18)
C1—O11.364 (15)C51—C521.432 (16)
C11—C161.383 (17)C52—C531.421 (17)
C11—C121.465 (17)C52—H520.9500
C12—C131.341 (16)C53—C541.36 (2)
C12—H120.9500C53—H530.9500
C13—C141.354 (16)C54—C551.376 (17)
C13—H130.9500C54—H540.9500
C14—C151.407 (19)C55—C561.426 (17)
C14—H140.9500C55—H550.9500
C15—C161.407 (18)C56—H560.9500
C15—H150.9500C61—C661.38 (2)
C16—H160.9500C61—C621.398 (18)
C21—C221.366 (16)C62—C631.386 (19)
C21—C261.507 (17)C62—H620.9500
C22—C231.436 (18)C63—C641.37 (2)
C22—H220.9500C63—H630.9500
C23—C241.37 (2)C64—C651.40 (2)
C23—H230.9500C64—H640.9500
C24—C251.39 (2)C65—C661.40 (2)
C24—H240.9500C65—H650.9500
C25—C261.318 (19)C66—H660.9500
C25—H250.9500C71—C761.40 (2)
C26—H260.9500C71—C721.40 (2)
C31—C321.399 (17)C71—H710.9500
C31—C361.428 (16)C72—C731.33 (3)
C32—C331.429 (18)C72—H720.9500
C32—H320.9500C73—C741.48 (2)
C33—C341.44 (2)C73—H730.9500
C33—H330.9500C74—C751.39 (2)
C34—C351.41 (2)C74—H740.9500
C34—H340.9500C75—C761.38 (2)
C35—C361.357 (17)C75—H750.9500
C35—H350.9500C76—H760.9500
C36—H360.9500
O1—Pt1—O264.8 (3)C35—C36—H36119.6
O1—Pt1—P199.7 (3)C31—C36—H36119.6
O2—Pt1—P1164.2 (2)C42—C41—C46121.0 (11)
O1—Pt1—P2162.1 (2)C42—C41—P2117.6 (8)
O2—Pt1—P297.3 (2)C46—C41—P2121.0 (9)
P1—Pt1—P298.16 (11)C41—C42—C43121.0 (10)
C31—P1—C21110.0 (5)C41—C42—H42119.5
C31—P1—C11104.4 (5)C43—C42—H42119.5
C21—P1—C11101.4 (5)C44—C43—C42117.4 (11)
C31—P1—Pt1111.0 (4)C44—C43—H43121.3
C21—P1—Pt1117.6 (4)C42—C43—H43121.3
C11—P1—Pt1111.3 (4)C45—C44—C43121.6 (12)
C41—P2—C61105.1 (6)C45—C44—H44119.2
C41—P2—C51104.3 (5)C43—C44—H44119.2
C61—P2—C51106.0 (5)C44—C45—C46120.6 (11)
C41—P2—Pt1108.1 (4)C44—C45—H45119.7
C61—P2—Pt1123.5 (4)C46—C45—H45119.7
C51—P2—Pt1108.3 (4)C41—C46—C45118.3 (11)
O3—C1—O2124.7 (12)C41—C46—H46120.9
O3—C1—O1125.7 (11)C45—C46—H46120.9
O2—C1—O1109.6 (9)C56—C51—C52119.9 (11)
C1—O1—Pt192.6 (6)C56—C51—P2120.5 (8)
C1—O2—Pt192.8 (7)C52—C51—P2119.5 (10)
C16—C11—C12117.6 (10)C53—C52—C51119.3 (12)
C16—C11—P1123.9 (9)C53—C52—H52120.4
C12—C11—P1118.3 (8)C51—C52—H52120.4
C13—C12—C11115.8 (11)C54—C53—C52120.3 (11)
C13—C12—H12122.1C54—C53—H53119.9
C11—C12—H12122.1C52—C53—H53119.9
C12—C13—C14128.9 (12)C55—C54—C53118.8 (12)
C12—C13—H13115.6C55—C54—H54120.6
C14—C13—H13115.6C53—C54—H54120.6
C13—C14—C15115.8 (11)C54—C55—C56122.1 (13)
C13—C14—H14122.1C54—C55—H55118.9
C15—C14—H14122.1C56—C55—H55118.9
C16—C15—C14119.3 (12)C51—C56—C55119.4 (11)
C16—C15—H15120.4C51—C56—H56120.3
C14—C15—H15120.4C55—C56—H56120.3
C11—C16—C15122.5 (12)C66—C61—C62117.9 (13)
C11—C16—H16118.8C66—C61—P2120.5 (10)
C15—C16—H16118.8C62—C61—P2121.5 (12)
C22—C21—C26118.4 (11)C63—C62—C61121.6 (15)
C22—C21—P1126.1 (10)C63—C62—H62119.2
C26—C21—P1115.1 (8)C61—C62—H62119.2
C21—C22—C23120.4 (12)C64—C63—C62120.1 (13)
C21—C22—H22119.8C64—C63—H63120.0
C23—C22—H22119.8C62—C63—H63120.0
C24—C23—C22119.3 (13)C63—C64—C65119.7 (13)
C24—C23—H23120.4C63—C64—H64120.1
C22—C23—H23120.4C65—C64—H64120.1
C23—C24—C25120.1 (14)C66—C65—C64119.5 (14)
C23—C24—H24120.0C66—C65—H65120.3
C25—C24—H24120.0C64—C65—H65120.3
C26—C25—C24123.8 (15)C65—C66—C61121.2 (13)
C26—C25—H25118.1C65—C66—H66119.4
C24—C25—H25118.1C61—C66—H66119.4
C25—C26—C21117.8 (11)C76—C71—C72119.2 (16)
C25—C26—H26121.1C76—C71—H71120.4
C21—C26—H26121.1C72—C71—H71120.4
C32—C31—C36118.4 (11)C73—C72—C71125.0 (18)
C32—C31—P1120.9 (9)C73—C72—H72117.5
C36—C31—P1120.2 (9)C71—C72—H72117.5
C31—C32—C33120.5 (11)C72—C73—C74116.3 (18)
C31—C32—H32119.8C72—C73—H73121.8
C33—C32—H32119.8C74—C73—H73121.8
C34—C33—C32119.8 (13)C75—C74—C73118.1 (16)
C34—C33—H33120.1C75—C74—H74120.9
C32—C33—H33120.1C73—C74—H74120.9
C35—C34—C33117.2 (12)C76—C75—C74123.5 (18)
C35—C34—H34121.4C76—C75—H75118.3
C33—C34—H34121.4C74—C75—H75118.3
C36—C35—C34122.9 (12)C75—C76—C71117.2 (16)
C36—C35—H35118.5C75—C76—H76121.4
C34—C35—H35118.5C71—C76—H76121.4
C35—C36—C31120.9 (11)
O1—Pt1—P1—C3199.3 (5)C21—P1—C31—C36125.1 (10)
O2—Pt1—P1—C3188.1 (10)C11—P1—C31—C36126.8 (10)
P2—Pt1—P1—C3179.4 (4)Pt1—P1—C31—C366.8 (10)
O1—Pt1—P1—C21132.8 (4)C36—C31—C32—C336.1 (17)
O2—Pt1—P1—C21144.0 (10)P1—C31—C32—C33177.8 (9)
P2—Pt1—P1—C2148.5 (4)C31—C32—C33—C345.4 (18)
O1—Pt1—P1—C1116.4 (5)C32—C33—C34—C353.5 (19)
O2—Pt1—P1—C1127.7 (11)C33—C34—C35—C363 (2)
P2—Pt1—P1—C11164.8 (4)C34—C35—C36—C313.6 (19)
O1—Pt1—P2—C4148.5 (10)C32—C31—C36—C355.2 (18)
O2—Pt1—P2—C4147.8 (5)P1—C31—C36—C35176.9 (9)
P1—Pt1—P2—C41135.6 (4)C61—P2—C41—C4293.5 (10)
O1—Pt1—P2—C61171.6 (10)C51—P2—C41—C42155.2 (9)
O2—Pt1—P2—C61170.9 (6)Pt1—P2—C41—C4240.1 (10)
P1—Pt1—P2—C6112.5 (5)C61—P2—C41—C4679.6 (11)
O1—Pt1—P2—C5163.9 (10)C51—P2—C41—C4631.7 (11)
O2—Pt1—P2—C5164.6 (5)Pt1—P2—C41—C46146.7 (9)
P1—Pt1—P2—C51112.0 (4)C46—C41—C42—C432.6 (19)
O3—C1—O1—Pt1174.7 (12)P2—C41—C42—C43175.7 (10)
O2—C1—O1—Pt14.1 (9)C41—C42—C43—C441.7 (19)
O2—Pt1—O1—C12.7 (6)C42—C43—C44—C451 (2)
P1—Pt1—O1—C1173.9 (6)C43—C44—C45—C461 (2)
P2—Pt1—O1—C12.0 (13)C42—C41—C46—C452.5 (18)
O3—C1—O2—Pt1174.8 (12)P2—C41—C46—C45175.4 (10)
O1—C1—O2—Pt14.1 (9)C44—C45—C46—C411.7 (19)
O1—Pt1—O2—C12.8 (6)C41—P2—C51—C5687.8 (11)
P1—Pt1—O2—C19.5 (14)C61—P2—C51—C56161.5 (11)
P2—Pt1—O2—C1177.0 (6)Pt1—P2—C51—C5627.1 (11)
C31—P1—C11—C16114.0 (10)C41—P2—C51—C5291.9 (10)
C21—P1—C11—C160.3 (11)C61—P2—C51—C5218.8 (11)
Pt1—P1—C11—C16126.2 (10)Pt1—P2—C51—C52153.2 (9)
C31—P1—C11—C1260.3 (10)C56—C51—C52—C530.2 (18)
C21—P1—C11—C12174.6 (9)P2—C51—C52—C53179.9 (9)
Pt1—P1—C11—C1259.5 (9)C51—C52—C53—C543.4 (19)
C16—C11—C12—C132.2 (16)C52—C53—C54—C555 (2)
P1—C11—C12—C13176.8 (8)C53—C54—C55—C564 (2)
C11—C12—C13—C143.4 (18)C52—C51—C56—C551.2 (19)
C12—C13—C14—C154.9 (19)P2—C51—C56—C55178.4 (10)
C13—C14—C15—C165.1 (18)C54—C55—C56—C510 (2)
C12—C11—C16—C153.0 (18)C41—P2—C61—C6620.3 (12)
P1—C11—C16—C15177.3 (10)C51—P2—C61—C66130.4 (11)
C14—C15—C16—C115 (2)Pt1—P2—C61—C66104.1 (11)
C31—P1—C21—C2215.1 (12)C41—P2—C61—C62162.7 (10)
C11—P1—C21—C2294.9 (10)C51—P2—C61—C6252.6 (11)
Pt1—P1—C21—C22143.5 (9)Pt1—P2—C61—C6272.9 (11)
C31—P1—C21—C26172.1 (8)C66—C61—C62—C632.7 (18)
C11—P1—C21—C2677.9 (9)P2—C61—C62—C63179.7 (9)
Pt1—P1—C21—C2643.7 (9)C61—C62—C63—C642.2 (19)
C26—C21—C22—C230.5 (17)C62—C63—C64—C652 (2)
P1—C21—C22—C23173.1 (9)C63—C64—C65—C662 (2)
C21—C22—C23—C243.0 (19)C64—C65—C66—C613 (2)
C22—C23—C24—C255 (2)C62—C61—C66—C653 (2)
C23—C24—C25—C264 (2)P2—C61—C66—C65179.9 (11)
C24—C25—C26—C210 (2)C76—C71—C72—C731 (3)
C22—C21—C26—C252.0 (17)C71—C72—C73—C747 (3)
P1—C21—C26—C25175.4 (11)C72—C73—C74—C756 (2)
C21—P1—C31—C3263.4 (10)C73—C74—C75—C760 (2)
C11—P1—C31—C3244.7 (10)C74—C75—C76—C717 (2)
Pt1—P1—C31—C32164.7 (8)C72—C71—C76—C756 (2)
 

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