Download citation
Download citation
link to html
The title compound, [Sn2(C6H5)5(C11H11NO3)Cl], is a dinuclear organotin adduct in which the two Sn atoms are bridged via the carboxyl­ate O—C—O group of a 2-[(E)-1-(2-hydroxy­aryl)­alkyl­idene­amino]­acetate ligand. Each Sn atom has a distorted trigonal bipyramidal geometry, with the Ph3SnCl moiety being less distorted.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805004666/lh6366sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805004666/lh6366Isup2.hkl
Contains datablock I

CCDC reference: 269817

Key indicators

  • Single-crystal X-ray study
  • T = 160 K
  • Mean [sigma](C-C) = 0.009 Å
  • R factor = 0.045
  • wR factor = 0.113
  • Data-to-parameter ratio = 23.6

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.84 Ratio PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 9
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 2 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: COLLECT (Nonius, 2000); cell refinement: DENZO–SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97 and PLATON (Spek, 2004).

Chloro{µ-2-[(E)-1-(2-oxido-3- methylphenyl)ethylideneamino]acetato}pentaphenylditin(IV) top
Crystal data top
[Sn2(C6H5)5(C5H11NO3)Cl]Z = 2
Mr = 863.39F(000) = 860
Triclinic, P1Dx = 1.636 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 11.6984 (2) ÅCell parameters from 47226 reflections
b = 13.0662 (2) Åθ = 2.0–30.0°
c = 13.9410 (3) ŵ = 1.54 mm1
α = 111.5066 (9)°T = 160 K
β = 90.6470 (9)°Prism, yellow
γ = 115.4904 (9)°0.15 × 0.15 × 0.08 mm
V = 1752.94 (6) Å3
Data collection top
Nonius KappaCCD area-detector
diffractometer
10272 independent reflections
Radiation source: Nonius FR590 sealed tube generator8257 reflections with I > 2σ(I)
Horizontally mounted graphite crystal monochromatorRint = 0.060
Detector resolution: 9 pixels mm-1θmax = 30.1°, θmin = 2.3°
φ and ω scans with κ offsetsh = 1616
Absorption correction: multi-scan
(Blessing, 1995)
k = 1818
Tmin = 0.759, Tmax = 0.881l = 1919
57965 measured reflections
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.045H-atom parameters constrained
wR(F2) = 0.113 w = 1/[σ2(Fo2) + 10.8098P]
where P = (Fo2 + 2Fc2)/3
S = 1.20(Δ/σ)max = 0.001
10271 reflectionsΔρmax = 1.29 e Å3
436 parametersΔρmin = 1.06 e Å3
0 restraintsExtinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.0045 (3)
Special details top

Experimental. Solvent used: acetone Cooling Device: Oxford Cryosystems Cryostream 700 Crystal mount: glued on a glass fibre Mosaicity (°.): 0.625 (1) Frames collected: 440 Seconds exposure per frame: 30 Degrees rotation per frame: 2.0 Crystal-Detector distance (mm): 30.0

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.98658 (3)0.22463 (3)0.23097 (2)0.02001 (9)
Sn20.65404 (3)0.24086 (3)0.27368 (3)0.02289 (9)
Cl0.49581 (13)0.45904 (12)0.16666 (13)0.0411 (3)
O10.8607 (3)0.0588 (3)0.2532 (3)0.0243 (7)
O20.8169 (3)0.0273 (3)0.3693 (3)0.0268 (7)
O31.1266 (3)0.4025 (3)0.2628 (3)0.0244 (7)
N11.0366 (3)0.2809 (3)0.3983 (3)0.0208 (7)
C10.8780 (4)0.0603 (4)0.3443 (4)0.0204 (8)
C20.9817 (4)0.1767 (4)0.4305 (4)0.0242 (9)
H2010.94460.20040.49350.029*
H2021.05150.15990.44980.029*
C31.1106 (4)0.3927 (4)0.4715 (4)0.0232 (9)
C41.1590 (4)0.5056 (4)0.4522 (4)0.0237 (9)
C51.1630 (4)0.5057 (4)0.3512 (4)0.0227 (9)
C61.2147 (4)0.6195 (4)0.3400 (4)0.0253 (9)
C71.2577 (5)0.7293 (4)0.4284 (4)0.0316 (11)
H71.29220.80570.42080.038*
C81.2518 (5)0.7307 (4)0.5287 (4)0.0334 (11)
H81.28100.80730.58860.040*
C91.2036 (5)0.6206 (4)0.5402 (4)0.0303 (10)
H91.20030.62190.60870.036*
C100.8317 (4)0.2532 (4)0.1885 (4)0.0238 (9)
C111.0987 (4)0.1467 (4)0.1454 (3)0.0213 (8)
C120.8599 (5)0.3576 (4)0.1685 (4)0.0277 (10)
H120.94590.40790.16510.033*
C130.7636 (5)0.3897 (5)0.1534 (4)0.0325 (11)
H130.78430.46150.14030.039*
C140.6381 (5)0.3167 (5)0.1577 (4)0.0338 (11)
H140.57280.33920.14920.041*
C150.6079 (5)0.2113 (5)0.1744 (4)0.0314 (11)
H150.52130.16130.17700.038*
C160.7030 (5)0.1768 (4)0.1876 (4)0.0249 (9)
H160.68010.10180.19580.030*
C171.0717 (5)0.0238 (4)0.1177 (4)0.0247 (9)
H170.99960.02930.13690.030*
C181.1492 (5)0.0216 (5)0.0622 (4)0.0289 (10)
H181.13080.10540.04450.035*
C191.2537 (5)0.0544 (5)0.0322 (4)0.0309 (11)
H191.30670.02300.00600.037*
C201.2799 (5)0.1763 (5)0.0585 (4)0.0323 (11)
H201.35020.22820.03680.039*
C211.2044 (5)0.2234 (4)0.1161 (4)0.0264 (9)
H211.22470.30790.13560.032*
C221.1466 (6)0.4062 (5)0.5809 (4)0.0353 (12)
H2211.07490.40270.61740.053*
H2221.22370.48620.61960.053*
H2231.16490.33840.57700.053*
C231.2235 (5)0.6180 (5)0.2320 (4)0.0300 (10)
H2311.26750.70370.23790.045*
H2321.13630.57510.18920.045*
H2331.27240.57440.19870.045*
C240.6440 (5)0.2429 (5)0.4271 (4)0.0285 (10)
C250.7358 (5)0.1476 (5)0.5169 (4)0.0326 (11)
H250.80430.07800.51120.039*
C260.7287 (7)0.1529 (7)0.6154 (5)0.0445 (15)
H260.79290.08830.67560.053*
C270.6279 (8)0.2525 (8)0.6241 (6)0.0554 (19)
H270.62310.25710.69050.066*
C280.5342 (7)0.3451 (8)0.5373 (7)0.057 (2)
H280.46340.41200.54430.069*
C290.5426 (6)0.3416 (6)0.4384 (5)0.0422 (14)
H290.47850.40720.37850.051*
C300.5426 (4)0.1609 (4)0.2392 (4)0.0232 (9)
C310.5290 (5)0.0718 (4)0.3247 (4)0.0260 (9)
H310.57390.04570.39330.031*
C320.4513 (5)0.0206 (5)0.3115 (4)0.0300 (10)
H320.44180.03880.37070.036*
C330.3873 (5)0.0570 (5)0.2109 (4)0.0306 (11)
H330.33450.02170.20110.037*
C340.4004 (5)0.1443 (5)0.1251 (4)0.0311 (11)
H340.35680.16900.05640.037*
C350.4774 (5)0.1961 (5)0.1397 (4)0.0266 (9)
H350.48550.25660.08050.032*
C360.8083 (5)0.2597 (5)0.2050 (4)0.0269 (10)
C370.7911 (5)0.3318 (5)0.0980 (4)0.0338 (11)
H370.70870.37100.05380.041*
C380.8924 (6)0.3475 (6)0.0548 (5)0.0416 (13)
H380.87890.39550.01840.050*
C391.0121 (6)0.2934 (6)0.1180 (6)0.0439 (15)
H391.08090.30470.08870.053*
C401.0312 (5)0.2240 (6)0.2227 (5)0.0395 (13)
H401.11340.18790.26630.047*
C410.9327 (5)0.2050 (5)0.2669 (5)0.0322 (11)
H410.94900.15430.33980.039*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.01964 (15)0.01710 (15)0.02248 (16)0.00810 (11)0.00489 (11)0.00787 (11)
Sn20.02073 (15)0.02117 (16)0.02842 (18)0.00992 (12)0.00394 (12)0.01176 (13)
Cl0.0284 (6)0.0219 (6)0.0594 (9)0.0085 (5)0.0006 (6)0.0068 (6)
O10.0220 (15)0.0180 (15)0.0268 (17)0.0048 (12)0.0023 (13)0.0085 (13)
O20.0259 (16)0.0205 (15)0.0314 (18)0.0061 (13)0.0032 (14)0.0139 (14)
O30.0248 (16)0.0156 (14)0.0273 (17)0.0058 (12)0.0079 (13)0.0074 (12)
N10.0189 (17)0.0184 (17)0.0259 (19)0.0087 (14)0.0056 (14)0.0099 (15)
C10.0175 (19)0.0190 (19)0.025 (2)0.0093 (16)0.0045 (16)0.0084 (16)
C20.023 (2)0.022 (2)0.029 (2)0.0097 (17)0.0060 (18)0.0127 (18)
C30.019 (2)0.022 (2)0.024 (2)0.0080 (17)0.0034 (16)0.0066 (17)
C40.020 (2)0.017 (2)0.031 (2)0.0077 (16)0.0049 (17)0.0066 (17)
C50.0166 (19)0.021 (2)0.030 (2)0.0089 (16)0.0071 (17)0.0091 (17)
C60.019 (2)0.019 (2)0.037 (3)0.0088 (17)0.0091 (18)0.0118 (19)
C70.027 (2)0.020 (2)0.043 (3)0.0078 (19)0.008 (2)0.013 (2)
C80.033 (3)0.019 (2)0.039 (3)0.011 (2)0.008 (2)0.003 (2)
C90.030 (2)0.022 (2)0.032 (3)0.0106 (19)0.007 (2)0.0060 (19)
C100.022 (2)0.021 (2)0.026 (2)0.0095 (17)0.0005 (17)0.0079 (17)
C110.022 (2)0.023 (2)0.020 (2)0.0128 (17)0.0031 (16)0.0077 (17)
C120.028 (2)0.023 (2)0.028 (2)0.0094 (19)0.0030 (19)0.0103 (19)
C130.036 (3)0.028 (2)0.037 (3)0.017 (2)0.001 (2)0.015 (2)
C140.034 (3)0.034 (3)0.036 (3)0.021 (2)0.000 (2)0.010 (2)
C150.020 (2)0.038 (3)0.036 (3)0.013 (2)0.0061 (19)0.017 (2)
C160.026 (2)0.022 (2)0.029 (2)0.0130 (18)0.0089 (18)0.0114 (18)
C170.029 (2)0.025 (2)0.022 (2)0.0134 (19)0.0048 (18)0.0106 (18)
C180.035 (3)0.028 (2)0.025 (2)0.019 (2)0.001 (2)0.0078 (19)
C190.029 (2)0.042 (3)0.025 (2)0.024 (2)0.0049 (19)0.008 (2)
C200.026 (2)0.036 (3)0.035 (3)0.016 (2)0.012 (2)0.014 (2)
C210.024 (2)0.026 (2)0.028 (2)0.0123 (18)0.0056 (18)0.0089 (19)
C220.040 (3)0.028 (3)0.027 (3)0.009 (2)0.003 (2)0.010 (2)
C230.026 (2)0.025 (2)0.041 (3)0.0101 (19)0.011 (2)0.018 (2)
C240.029 (2)0.035 (3)0.039 (3)0.021 (2)0.016 (2)0.026 (2)
C250.036 (3)0.046 (3)0.031 (3)0.026 (2)0.013 (2)0.023 (2)
C260.060 (4)0.068 (4)0.036 (3)0.048 (4)0.019 (3)0.030 (3)
C270.073 (5)0.093 (6)0.055 (4)0.065 (5)0.044 (4)0.055 (4)
C280.054 (4)0.077 (5)0.085 (6)0.039 (4)0.042 (4)0.066 (5)
C290.034 (3)0.047 (3)0.060 (4)0.020 (3)0.018 (3)0.036 (3)
C300.018 (2)0.022 (2)0.032 (2)0.0087 (17)0.0054 (17)0.0150 (18)
C310.026 (2)0.022 (2)0.030 (2)0.0117 (18)0.0034 (18)0.0107 (18)
C320.027 (2)0.025 (2)0.040 (3)0.0137 (19)0.006 (2)0.013 (2)
C330.024 (2)0.034 (3)0.045 (3)0.016 (2)0.008 (2)0.025 (2)
C340.026 (2)0.041 (3)0.032 (3)0.015 (2)0.005 (2)0.022 (2)
C350.024 (2)0.030 (2)0.026 (2)0.0121 (19)0.0063 (18)0.0121 (19)
C360.027 (2)0.029 (2)0.035 (3)0.018 (2)0.009 (2)0.018 (2)
C370.038 (3)0.035 (3)0.032 (3)0.020 (2)0.005 (2)0.014 (2)
C380.056 (4)0.047 (3)0.038 (3)0.034 (3)0.022 (3)0.021 (3)
C390.044 (3)0.052 (4)0.066 (4)0.035 (3)0.032 (3)0.039 (3)
C400.029 (3)0.050 (3)0.053 (4)0.020 (2)0.011 (2)0.032 (3)
C410.022 (2)0.038 (3)0.042 (3)0.016 (2)0.006 (2)0.020 (2)
Geometric parameters (Å, º) top
Sn1—O32.057 (3)C18—H180.9500
Sn1—C112.116 (4)C19—C201.384 (7)
Sn1—C102.119 (4)C19—H190.9500
Sn1—N12.160 (4)C20—C211.388 (7)
Sn1—O12.172 (3)C20—H200.9500
Sn2—C362.117 (5)C21—H210.9500
Sn2—C302.132 (4)C22—H2210.9800
Sn2—C242.153 (5)C22—H2220.9800
Sn2—O22.415 (3)C22—H2230.9800
Sn2—Cl2.4610 (13)C23—H2310.9800
O1—C11.276 (5)C23—H2320.9800
O2—C11.239 (5)C23—H2330.9800
O3—C51.340 (5)C24—C291.390 (7)
N1—C31.313 (6)C24—C251.395 (8)
N1—C21.472 (6)C25—C261.401 (7)
C1—C21.506 (6)C25—H250.9500
C2—H2010.9900C26—C271.377 (10)
C2—H2020.9900C26—H260.9500
C3—C41.465 (6)C27—C281.374 (11)
C3—C221.502 (7)C27—H270.9500
C4—C51.410 (7)C28—C291.398 (9)
C4—C91.412 (6)C28—H280.9500
C5—C61.414 (6)C29—H290.9500
C6—C71.378 (7)C30—C351.387 (7)
C6—C231.504 (7)C30—C311.396 (7)
C7—C81.394 (8)C31—C321.384 (6)
C7—H70.9500C31—H310.9500
C8—C91.374 (7)C32—C331.391 (7)
C8—H80.9500C32—H320.9500
C9—H90.9500C33—C341.382 (8)
C10—C121.394 (6)C33—H330.9500
C10—C161.400 (6)C34—C351.390 (7)
C11—C171.391 (6)C34—H340.9500
C11—C211.394 (6)C35—H350.9500
C12—C131.398 (7)C36—C371.398 (7)
C12—H120.9500C36—C411.413 (7)
C13—C141.381 (8)C37—C381.394 (8)
C13—H130.9500C37—H370.9500
C14—C151.375 (7)C38—C391.379 (9)
C14—H140.9500C38—H380.9500
C15—C161.400 (7)C39—C401.361 (9)
C15—H150.9500C39—H390.9500
C16—H160.9500C40—C411.385 (8)
C17—C181.384 (7)C40—H400.9500
C17—H170.9500C41—H410.9500
C18—C191.387 (7)
O3—Sn1—C1191.89 (15)C11—C17—H17119.8
O3—Sn1—C1094.61 (15)C17—C18—C19120.4 (5)
C11—Sn1—C10134.26 (17)C17—C18—H18119.8
O3—Sn1—N184.27 (13)C19—C18—H18119.8
C11—Sn1—N1112.60 (15)C20—C19—C18119.4 (5)
C10—Sn1—N1113.09 (16)C20—C19—H19120.3
O3—Sn1—O1160.87 (13)C18—C19—H19120.3
C11—Sn1—O194.66 (15)C19—C20—C21120.5 (5)
C10—Sn1—O193.64 (15)C19—C20—H20119.7
N1—Sn1—O176.61 (13)C21—C20—H20119.7
C36—Sn2—C30128.01 (18)C20—C21—C11120.0 (4)
C36—Sn2—C24117.50 (18)C20—C21—H21120.0
C30—Sn2—C24111.18 (18)C11—C21—H21120.0
C36—Sn2—O283.24 (16)C3—C22—H221109.5
C30—Sn2—O284.30 (14)C3—C22—H222109.5
C24—Sn2—O284.51 (16)H221—C22—H222109.5
C36—Sn2—Cl93.48 (14)C3—C22—H223109.5
C30—Sn2—Cl96.33 (13)H221—C22—H223109.5
C24—Sn2—Cl98.69 (15)H222—C22—H223109.5
O2—Sn2—Cl176.24 (9)C6—C23—H231109.5
C1—O1—Sn1117.5 (3)C6—C23—H232109.5
C1—O2—Sn2134.2 (3)H231—C23—H232109.5
C5—O3—Sn1128.3 (3)C6—C23—H233109.5
C3—N1—C2117.8 (4)H231—C23—H233109.5
C3—N1—Sn1128.5 (3)H232—C23—H233109.5
C2—N1—Sn1113.6 (3)C29—C24—C25118.2 (5)
O2—C1—O1125.6 (4)C29—C24—Sn2119.5 (4)
O2—C1—C2115.7 (4)C25—C24—Sn2122.3 (4)
O1—C1—C2118.7 (4)C24—C25—C26121.1 (5)
N1—C2—C1111.9 (4)C24—C25—H25119.5
N1—C2—H201109.2C26—C25—H25119.5
C1—C2—H201109.2C27—C26—C25119.5 (7)
N1—C2—H202109.2C27—C26—H26120.2
C1—C2—H202109.2C25—C26—H26120.2
H201—C2—H202107.9C28—C27—C26120.2 (6)
N1—C3—C4123.2 (4)C28—C27—H27119.9
N1—C3—C22118.7 (4)C26—C27—H27119.9
C4—C3—C22118.1 (4)C27—C28—C29120.4 (6)
C5—C4—C9118.5 (4)C27—C28—H28119.8
C5—C4—C3123.8 (4)C29—C28—H28119.8
C9—C4—C3117.7 (4)C24—C29—C28120.5 (6)
O3—C5—C4123.5 (4)C24—C29—H29119.7
O3—C5—C6116.4 (4)C28—C29—H29119.7
C4—C5—C6120.0 (4)C35—C30—C31118.2 (4)
C7—C6—C5119.3 (5)C35—C30—Sn2124.9 (4)
C7—C6—C23121.5 (4)C31—C30—Sn2116.8 (3)
C5—C6—C23119.2 (4)C32—C31—C30121.3 (5)
C6—C7—C8121.5 (5)C32—C31—H31119.3
C6—C7—H7119.3C30—C31—H31119.3
C8—C7—H7119.3C31—C32—C33119.4 (5)
C9—C8—C7119.5 (5)C31—C32—H32120.3
C9—C8—H8120.2C33—C32—H32120.3
C7—C8—H8120.2C34—C33—C32120.2 (5)
C8—C9—C4121.2 (5)C34—C33—H33119.9
C8—C9—H9119.4C32—C33—H33119.9
C4—C9—H9119.4C33—C34—C35119.8 (5)
C12—C10—C16118.4 (4)C33—C34—H34120.1
C12—C10—Sn1118.7 (3)C35—C34—H34120.1
C16—C10—Sn1122.7 (3)C30—C35—C34121.1 (5)
C17—C11—C21119.2 (4)C30—C35—H35119.4
C17—C11—Sn1123.0 (3)C34—C35—H35119.4
C21—C11—Sn1117.7 (3)C37—C36—C41116.6 (5)
C10—C12—C13121.1 (5)C37—C36—Sn2122.1 (4)
C10—C12—H12119.4C41—C36—Sn2121.2 (4)
C13—C12—H12119.4C38—C37—C36121.4 (5)
C14—C13—C12119.7 (5)C38—C37—H37119.3
C14—C13—H13120.2C36—C37—H37119.3
C12—C13—H13120.1C39—C38—C37120.2 (6)
C15—C14—C13120.0 (5)C39—C38—H38119.9
C15—C14—H14120.0C37—C38—H38119.9
C13—C14—H14120.0C40—C39—C38119.7 (5)
C14—C15—C16120.9 (5)C40—C39—H39120.2
C14—C15—H15119.6C38—C39—H39120.2
C16—C15—H15119.6C39—C40—C41121.0 (5)
C10—C16—C15119.8 (4)C39—C40—H40119.5
C10—C16—H16120.1C41—C40—H40119.5
C15—C16—H16120.1C40—C41—C36121.0 (5)
C18—C17—C11120.4 (4)C40—C41—H41119.5
C18—C17—H17119.8C36—C41—H41119.5
O3—Sn1—O1—C14.4 (6)O1—Sn1—C11—C21176.2 (3)
C11—Sn1—O1—C1105.2 (3)C16—C10—C12—C133.4 (7)
C10—Sn1—O1—C1119.8 (3)Sn1—C10—C12—C13171.8 (4)
N1—Sn1—O1—C17.0 (3)C10—C12—C13—C140.4 (8)
C36—Sn2—O2—C168.0 (4)C12—C13—C14—C151.5 (8)
C30—Sn2—O2—C161.4 (4)C13—C14—C15—C160.2 (8)
C24—Sn2—O2—C1173.4 (4)C12—C10—C16—C154.6 (7)
C11—Sn1—O3—C5142.5 (4)Sn1—C10—C16—C15170.4 (4)
C10—Sn1—O3—C582.9 (4)C14—C15—C16—C102.9 (8)
N1—Sn1—O3—C529.9 (4)C21—C11—C17—C180.4 (7)
O1—Sn1—O3—C532.4 (6)Sn1—C11—C17—C18179.6 (3)
O3—Sn1—N1—C39.9 (4)C11—C17—C18—C191.0 (7)
C11—Sn1—N1—C399.6 (4)C17—C18—C19—C200.1 (7)
C10—Sn1—N1—C382.6 (4)C18—C19—C20—C211.3 (8)
O1—Sn1—N1—C3170.9 (4)C19—C20—C21—C111.9 (8)
O3—Sn1—N1—C2168.1 (3)C17—C11—C21—C201.1 (7)
C11—Sn1—N1—C278.4 (3)Sn1—C11—C21—C20179.0 (4)
C10—Sn1—N1—C299.4 (3)C36—Sn2—C24—C29112.9 (4)
O1—Sn1—N1—C211.1 (3)C30—Sn2—C24—C2986.0 (4)
Sn2—O2—C1—O15.0 (7)O2—Sn2—C24—C29167.7 (4)
Sn2—O2—C1—C2174.4 (3)Cl—Sn2—C24—C2914.3 (4)
Sn1—O1—C1—O2178.1 (3)C36—Sn2—C24—C2567.6 (4)
Sn1—O1—C1—C21.3 (5)C30—Sn2—C24—C2593.6 (4)
C3—N1—C2—C1168.0 (4)O2—Sn2—C24—C2511.9 (4)
Sn1—N1—C2—C113.8 (4)Cl—Sn2—C24—C25166.1 (4)
O2—C1—C2—N1172.1 (4)C29—C24—C25—C262.1 (8)
O1—C1—C2—N18.5 (6)Sn2—C24—C25—C26178.4 (4)
C2—N1—C3—C4172.8 (4)C24—C25—C26—C271.4 (8)
Sn1—N1—C3—C49.3 (6)C25—C26—C27—C280.8 (9)
C2—N1—C3—C226.6 (6)C26—C27—C28—C292.2 (10)
Sn1—N1—C3—C22171.3 (3)C25—C24—C29—C280.6 (8)
N1—C3—C4—C518.4 (7)Sn2—C24—C29—C28179.8 (5)
C22—C3—C4—C5162.2 (5)C27—C28—C29—C241.5 (10)
N1—C3—C4—C9161.5 (4)C36—Sn2—C30—C3554.3 (5)
C22—C3—C4—C917.9 (7)C24—Sn2—C30—C35147.1 (4)
Sn1—O3—C5—C431.3 (6)O2—Sn2—C30—C35131.1 (4)
Sn1—O3—C5—C6152.4 (3)Cl—Sn2—C30—C3545.2 (4)
C9—C4—C5—O3178.1 (4)C36—Sn2—C30—C31129.7 (4)
C3—C4—C5—O32.1 (7)C24—Sn2—C30—C3129.0 (4)
C9—C4—C5—C61.9 (7)O2—Sn2—C30—C3152.8 (3)
C3—C4—C5—C6178.2 (4)Cl—Sn2—C30—C31130.9 (3)
O3—C5—C6—C7178.0 (4)C35—C30—C31—C320.9 (7)
C4—C5—C6—C71.6 (7)Sn2—C30—C31—C32175.5 (4)
O3—C5—C6—C231.0 (6)C30—C31—C32—C331.2 (7)
C4—C5—C6—C23177.4 (4)C31—C32—C33—C340.6 (7)
C5—C6—C7—C80.2 (7)C32—C33—C34—C350.2 (7)
C23—C6—C7—C8178.7 (5)C31—C30—C35—C340.1 (7)
C6—C7—C8—C90.8 (8)Sn2—C30—C35—C34176.0 (4)
C7—C8—C9—C40.5 (8)C33—C34—C35—C300.5 (7)
C5—C4—C9—C80.9 (7)C30—Sn2—C36—C3762.7 (5)
C3—C4—C9—C8179.2 (5)C24—Sn2—C36—C37139.8 (4)
O3—Sn1—C10—C1214.6 (4)O2—Sn2—C36—C37140.0 (4)
C11—Sn1—C10—C1282.6 (4)Cl—Sn2—C36—C3738.1 (4)
N1—Sn1—C10—C12100.3 (4)C30—Sn2—C36—C41120.8 (4)
O1—Sn1—C10—C12177.3 (4)C24—Sn2—C36—C4136.8 (5)
O3—Sn1—C10—C16160.4 (4)O2—Sn2—C36—C4143.4 (4)
C11—Sn1—C10—C16102.5 (4)Cl—Sn2—C36—C41138.4 (4)
N1—Sn1—C10—C1674.6 (4)C41—C36—C37—C380.6 (8)
O1—Sn1—C10—C162.3 (4)Sn2—C36—C37—C38177.3 (4)
O3—Sn1—C11—C17165.8 (4)C36—C37—C38—C391.3 (9)
C10—Sn1—C11—C1795.9 (4)C37—C38—C39—C400.5 (9)
N1—Sn1—C11—C1781.2 (4)C38—C39—C40—C410.9 (9)
O1—Sn1—C11—C173.8 (4)C39—C40—C41—C361.6 (8)
O3—Sn1—C11—C2114.2 (4)C37—C36—C41—C400.8 (7)
C10—Sn1—C11—C2184.1 (4)Sn2—C36—C41—C40175.9 (4)
N1—Sn1—C11—C2198.7 (4)
 

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds