metal-organic compounds
In the centrosymmetric title compound, [Ag2(C21H19N5)2](ClO4)2·CH3CN, the N-heterocycle chelates to two Ag cations through its four Lewis basic atoms to confer a distorted square-planar environment for each metal atom. The perchlorate anion interacts weakly with the Ag atom at a distance exceeding 3.0 Å.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805000243/lh6344sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805000243/lh6344Isup2.hkl |
CCDC reference: 263541
Computing details top
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
Bis[µ-3,5-bis(2-pyridyl)-4-(4-isopropylphenyl)-4H-1,2,4-triazole[disilver(I) diperchlorate acetonitrile solvate top
Crystal data top
[Ag2(C21H19N5)2](ClO4)2·C2H3N | F(000) = 2296 |
Mr = 1138.52 | Dx = 1.637 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 2357 reflections |
a = 15.830 (1) Å | θ = 2.5–21.6° |
b = 9.7850 (8) Å | µ = 1.03 mm−1 |
c = 30.020 (2) Å | T = 295 K |
β = 96.533 (2)° | Block, colorless |
V = 4619.7 (7) Å3 | 0.22 × 0.10 × 0.09 mm |
Z = 4 |
Data collection top
Bruker SMART APEX area-detector diffractometer | 5154 independent reflections |
Radiation source: fine-focus sealed tube | 3183 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.048 |
φ and ω scans | θmax = 27.5°, θmin = 2.5° |
Absorption correction: multi-scan (SADABS; Bruker, 2002) | h = −16→20 |
Tmin = 0.313, Tmax = 0.913 | k = −12→12 |
13366 measured reflections | l = −39→34 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.053 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.150 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.072P)2] where P = (Fo2 + 2Fc2)/3 |
5154 reflections | (Δ/σ)max = 0.001 |
344 parameters | Δρmax = 0.79 e Å−3 |
68 restraints | Δρmin = −0.58 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Ag1 | 0.66586 (3) | 0.61394 (4) | 0.53211 (1) | 0.0616 (2) | |
Cl1 | 0.9115 (4) | 0.7259 (5) | 0.61145 (18) | 0.0560 (9) | 0.696 (5) |
Cl1' | 0.9121 (9) | 0.739 (1) | 0.6045 (5) | 0.0560 (9) | 0.304 |
O1 | 0.8283 (4) | 0.7668 (8) | 0.5958 (3) | 0.098 (3) | 0.696 (5) |
O2 | 0.9556 (5) | 0.8368 (7) | 0.6348 (3) | 0.104 (3) | 0.696 (5) |
O3 | 0.9571 (7) | 0.681 (1) | 0.5759 (3) | 0.086 (3) | 0.696 (5) |
O4 | 0.9088 (6) | 0.6158 (6) | 0.6428 (2) | 0.120 (3) | 0.696 (5) |
O1' | 0.828 (1) | 0.686 (2) | 0.6036 (7) | 0.119 (8) | 0.304 (5) |
O2' | 0.910 (1) | 0.873 (1) | 0.5857 (6) | 0.118 (7) | 0.304 (5) |
O3' | 0.963 (1) | 0.650 (2) | 0.5805 (6) | 0.063 (6) | 0.304 (5) |
O4' | 0.950 (1) | 0.746 (2) | 0.6503 (4) | 0.112 (6) | 0.304 (5) |
N1 | 0.6268 (2) | 0.4078 (4) | 0.4936 (1) | 0.0449 (9) | |
N2 | 0.7680 (2) | 0.5590 (4) | 0.4864 (1) | 0.0380 (8) | |
N3 | 0.7897 (2) | 0.4799 (3) | 0.4203 (1) | 0.0344 (8) | |
N4 | 0.8268 (2) | 0.6415 (4) | 0.4694 (1) | 0.0383 (9) | |
N5 | 0.8925 (2) | 0.8040 (4) | 0.4071 (1) | 0.0436 (9) | |
N6 | 1.0000 | 0.0092 (12) | 0.2500 | 0.114 (3) | |
C1 | 0.5666 (3) | 0.3208 (5) | 0.5040 (2) | 0.054 (1) | |
C2 | 0.5562 (3) | 0.1918 (5) | 0.4862 (2) | 0.055 (1) | |
C3 | 0.6091 (4) | 0.1498 (5) | 0.4563 (2) | 0.053 (1) | |
C4 | 0.6711 (3) | 0.2357 (4) | 0.4444 (2) | 0.046 (1) | |
C5 | 0.6789 (3) | 0.3639 (4) | 0.4638 (1) | 0.038 (1) | |
C6 | 0.7450 (3) | 0.4644 (4) | 0.4565 (1) | 0.034 (1) | |
C7 | 0.8380 (3) | 0.5939 (4) | 0.4295 (1) | 0.035 (1) | |
C8 | 0.8919 (3) | 0.6686 (5) | 0.4008 (1) | 0.038 (1) | |
C9 | 0.9399 (3) | 0.6053 (5) | 0.3712 (2) | 0.048 (1) | |
C10 | 0.9900 (3) | 0.6861 (6) | 0.3472 (2) | 0.058 (1) | |
C11 | 0.9905 (3) | 0.8248 (7) | 0.3531 (2) | 0.062 (1) | |
C12 | 0.9419 (3) | 0.8784 (5) | 0.3835 (2) | 0.056 (1) | |
C13 | 0.7773 (3) | 0.4032 (4) | 0.3783 (1) | 0.035 (1) | |
C14 | 0.7114 (3) | 0.4371 (4) | 0.3475 (1) | 0.036 (1) | |
C15 | 0.6977 (3) | 0.3617 (4) | 0.3082 (1) | 0.041 (1) | |
C16 | 0.7508 (3) | 0.2535 (4) | 0.3003 (1) | 0.040 (1) | |
C17 | 0.8181 (3) | 0.2243 (5) | 0.3320 (2) | 0.050 (1) | |
C18 | 0.8317 (3) | 0.2982 (5) | 0.3715 (2) | 0.046 (1) | |
C19 | 0.7337 (3) | 0.1691 (5) | 0.2571 (2) | 0.052 (1) | |
C20 | 0.6496 (4) | 0.0938 (6) | 0.2559 (2) | 0.069 (2) | |
C21 | 0.7374 (4) | 0.2553 (6) | 0.2147 (2) | 0.070 (2) | |
C22 | 1.0000 | 0.122 (1) | 0.2500 | 0.070 (2) | |
C23 | 1.0000 | 0.268 (1) | 0.2500 | 0.101 (3) | |
H1 | 0.5300 | 0.3493 | 0.5243 | 0.065* | |
H2 | 0.5138 | 0.1344 | 0.4945 | 0.066* | |
H3 | 0.6032 | 0.0628 | 0.4438 | 0.063* | |
H4 | 0.7073 | 0.2083 | 0.4238 | 0.055* | |
H9 | 0.9385 | 0.5109 | 0.3676 | 0.058* | |
H10 | 1.0234 | 0.6465 | 0.3272 | 0.070* | |
H11 | 1.0231 | 0.8810 | 0.3368 | 0.074* | |
H12 | 0.9433 | 0.9725 | 0.3880 | 0.067* | |
H14 | 0.6759 | 0.5098 | 0.3526 | 0.043* | |
H15 | 0.6524 | 0.3838 | 0.2869 | 0.049* | |
H17 | 0.8551 | 0.1538 | 0.3268 | 0.060* | |
H18 | 0.8769 | 0.2769 | 0.3930 | 0.055* | |
H19 | 0.7786 | 0.1000 | 0.2576 | 0.062* | |
H20a | 0.6496 | 0.0395 | 0.2825 | 0.103* | |
H20b | 0.6421 | 0.0355 | 0.2300 | 0.103* | |
H20c | 0.6039 | 0.1588 | 0.2544 | 0.103* | |
H21a | 0.7913 | 0.3008 | 0.2163 | 0.105* | |
H21b | 0.6926 | 0.3220 | 0.2125 | 0.105* | |
H21c | 0.7304 | 0.1970 | 0.1888 | 0.105* | |
H23a | 1.0551 | 0.3019 | 0.2443 | 0.151* | 0.50 |
H23b | 0.9874 | 0.3022 | 0.2786 | 0.151* | 0.50 |
H23c | 0.9579 | 0.3021 | 0.2269 | 0.151* | 0.50 |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Ag1 | 0.0794 (3) | 0.0444 (2) | 0.0680 (3) | −0.0108 (2) | 0.0385 (2) | −0.0159 (2) |
Cl1 | 0.050 (1) | 0.056 (1) | 0.061 (2) | 0.008 (1) | 0.005 (1) | −0.011 (1) |
Cl1' | 0.050 (1) | 0.056 (1) | 0.061 (2) | 0.008 (1) | 0.005 (1) | −0.011 (1) |
O1 | 0.060 (4) | 0.104 (5) | 0.125 (6) | 0.028 (4) | −0.016 (4) | −0.011 (5) |
O2 | 0.106 (5) | 0.076 (4) | 0.127 (6) | −0.012 (4) | 0.000 (4) | −0.035 (4) |
O3 | 0.098 (6) | 0.085 (6) | 0.079 (6) | 0.007 (5) | 0.036 (5) | 0.002 (5) |
O4 | 0.158 (6) | 0.098 (5) | 0.111 (5) | 0.028 (4) | 0.055 (5) | 0.048 (4) |
O1' | 0.09 (1) | 0.14 (1) | 0.13 (1) | −0.022 (9) | 0.032 (8) | 0.004 (9) |
O2' | 0.14 (1) | 0.093 (9) | 0.13 (1) | 0.029 (8) | 0.035 (8) | 0.013 (7) |
O3' | 0.07 (1) | 0.047 (7) | 0.07 (1) | 0.005 (6) | 0.009 (7) | −0.013 (6) |
O4' | 0.11 (1) | 0.14 (1) | 0.079 (9) | −0.003 (9) | −0.009 (7) | 0.005 (8) |
N1 | 0.044 (2) | 0.039 (2) | 0.054 (2) | −0.007 (2) | 0.014 (2) | −0.004 (2) |
N2 | 0.041 (2) | 0.040 (2) | 0.034 (2) | −0.006 (2) | 0.009 (2) | −0.007 (2) |
N3 | 0.035 (2) | 0.036 (2) | 0.032 (2) | −0.002 (2) | 0.004 (2) | −0.006 (2) |
N4 | 0.038 (2) | 0.042 (2) | 0.036 (2) | −0.004 (2) | 0.005 (2) | −0.004 (2) |
N5 | 0.046 (2) | 0.046 (2) | 0.041 (2) | −0.007 (2) | 0.011 (2) | −0.001 (2) |
N6 | 0.135 (9) | 0.119 (8) | 0.082 (6) | 0.000 | −0.014 (6) | 0.000 |
C1 | 0.049 (3) | 0.053 (3) | 0.063 (3) | −0.008 (3) | 0.015 (3) | 0.001 (3) |
C2 | 0.051 (3) | 0.049 (3) | 0.062 (3) | −0.019 (2) | −0.006 (3) | 0.011 (3) |
C3 | 0.061 (3) | 0.036 (2) | 0.057 (3) | −0.003 (2) | −0.010 (3) | −0.005 (2) |
C4 | 0.062 (3) | 0.034 (2) | 0.041 (3) | −0.003 (2) | 0.003 (2) | −0.007 (2) |
C5 | 0.040 (3) | 0.038 (2) | 0.035 (2) | 0.002 (2) | 0.001 (2) | 0.001 (2) |
C6 | 0.036 (2) | 0.029 (2) | 0.037 (2) | 0.001 (2) | 0.001 (2) | 0.000 (2) |
C7 | 0.034 (2) | 0.042 (2) | 0.029 (2) | 0.002 (2) | 0.005 (2) | −0.006 (2) |
C8 | 0.032 (2) | 0.049 (2) | 0.031 (2) | −0.002 (2) | 0.001 (2) | 0.001 (2) |
C9 | 0.045 (3) | 0.056 (3) | 0.046 (3) | 0.003 (2) | 0.013 (2) | −0.004 (2) |
C10 | 0.049 (3) | 0.086 (4) | 0.043 (3) | 0.002 (3) | 0.017 (2) | −0.006 (3) |
C11 | 0.047 (3) | 0.086 (4) | 0.055 (3) | −0.010 (3) | 0.016 (3) | 0.011 (3) |
C12 | 0.057 (3) | 0.058 (3) | 0.055 (3) | −0.011 (3) | 0.019 (3) | 0.003 (2) |
C13 | 0.038 (2) | 0.037 (2) | 0.030 (2) | −0.003 (2) | 0.001 (2) | −0.008 (2) |
C14 | 0.038 (2) | 0.036 (2) | 0.033 (2) | 0.006 (2) | 0.003 (2) | −0.005 (2) |
C15 | 0.041 (3) | 0.047 (3) | 0.034 (2) | 0.006 (2) | 0.000 (2) | −0.003 (2) |
C16 | 0.046 (3) | 0.044 (2) | 0.032 (2) | 0.001 (2) | 0.009 (2) | −0.009 (2) |
C17 | 0.051 (3) | 0.050 (3) | 0.048 (3) | 0.017 (2) | 0.003 (2) | −0.015 (2) |
C18 | 0.047 (3) | 0.049 (3) | 0.040 (3) | 0.015 (2) | −0.006 (2) | −0.008 (2) |
C19 | 0.057 (3) | 0.050 (3) | 0.048 (3) | 0.003 (2) | 0.008 (2) | −0.019 (2) |
C20 | 0.086 (4) | 0.062 (3) | 0.059 (4) | −0.019 (3) | 0.010 (3) | −0.021 (3) |
C21 | 0.093 (5) | 0.078 (4) | 0.041 (3) | −0.020 (3) | 0.015 (3) | −0.014 (3) |
C22 | 0.066 (6) | 0.079 (6) | 0.062 (5) | 0.000 | −0.003 (4) | 0.000 |
C23 | 0.100 (8) | 0.105 (8) | 0.094 (8) | 0.000 | 0.001 (6) | 0.000 |
Geometric parameters (Å, º) top
Ag1—N1 | 2.371 (4) | C13—C14 | 1.354 (6) |
Ag1—N2 | 2.300 (4) | C13—C18 | 1.371 (6) |
Ag1—N4i | 2.396 (4) | C14—C15 | 1.387 (6) |
Ag1—N5i | 2.284 (4) | C15—C16 | 1.389 (6) |
Cl1—O1 | 1.406 (6) | C16—C17 | 1.375 (6) |
Cl1—O2 | 1.430 (6) | C16—C19 | 1.536 (6) |
Cl1—O3 | 1.423 (6) | C17—C18 | 1.385 (6) |
Cl1—O4 | 1.434 (6) | C19—C20 | 1.519 (8) |
Cl1'—O1' | 1.427 (9) | C19—C21 | 1.531 (7) |
Cl1'—O2' | 1.421 (9) | C22—C23 | 1.43 (1) |
Cl1'—O3' | 1.435 (9) | C1—H1 | 0.93 |
Cl1'—O4' | 1.433 (9) | C2—H2 | 0.93 |
N1—C1 | 1.341 (6) | C3—H3 | 0.93 |
N1—C5 | 1.354 (6) | C4—H4 | 0.93 |
N2—C6 | 1.312 (5) | C9—H9 | 0.93 |
N2—N4 | 1.374 (5) | C10—H10 | 0.93 |
N3—C7 | 1.363 (5) | C11—H11 | 0.93 |
N3—C6 | 1.369 (5) | C12—H12 | 0.93 |
N3—C13 | 1.463 (5) | C14—H14 | 0.93 |
N4—C7 | 1.316 (5) | C15—H15 | 0.93 |
N5—C12 | 1.330 (6) | C17—H17 | 0.93 |
N5—C8 | 1.338 (6) | C18—H18 | 0.93 |
N6—C22 | 1.10 (1) | C19—H19 | 0.98 |
C1—C2 | 1.373 (7) | C20—H20a | 0.96 |
C2—C3 | 1.361 (8) | C20—H20b | 0.96 |
C3—C4 | 1.369 (7) | C20—H20c | 0.96 |
C4—C5 | 1.383 (6) | C21—H21a | 0.96 |
C5—C6 | 1.470 (6) | C21—H21b | 0.96 |
C7—C8 | 1.475 (6) | C21—H21c | 0.96 |
C8—C9 | 1.379 (6) | C23—H23a | 0.97 |
C9—C10 | 1.380 (7) | C23—H23b | 0.97 |
C10—C11 | 1.369 (8) | C23—H23c | 0.97 |
C11—C12 | 1.363 (8) | ||
N1—Ag1—N2 | 70.9 (1) | C13—C14—C15 | 119.0 (4) |
N1—Ag1—N4i | 148.3 (1) | C16—C15—C14 | 120.7 (4) |
N1—Ag1—N5i | 125.6 (1) | C17—C16—C15 | 118.5 (4) |
N2—Ag1—N4i | 100.6 (1) | C17—C16—C19 | 121.4 (4) |
N2—Ag1—N5i | 159.2 (1) | C15—C16—C19 | 120.1 (4) |
N4i—Ag1—N5i | 71.9 (1) | C16—C17—C18 | 121.2 (4) |
O1—Cl1—O4 | 109.6 (5) | C13—C18—C17 | 118.6 (4) |
O1—Cl1—O3 | 111.9 (5) | C20—C19—C21 | 111.4 (4) |
O4—Cl1—O3 | 108.4 (5) | C20—C19—C16 | 110.5 (4) |
O1—Cl1—O2 | 109.5 (5) | C21—C19—C16 | 112.7 (4) |
O4—Cl1—O2 | 107.3 (5) | N6—C22—C23 | 180 |
O3—Cl1—O2 | 109.9 (5) | N1—C1—H1 | 118.3 |
O1'—Cl1'—O2' | 110.7 (8) | C2—C1—H1 | 118.3 |
O1'—Cl1'—O4' | 108.5 (8) | C3—C2—H2 | 120.7 |
O2'—Cl1'—O4' | 109.3 (8) | C1—C2—H2 | 120.7 |
O1'—Cl1'—O3' | 109.7 (8) | C2—C3—H3 | 120.0 |
O2'—Cl1'—O3' | 110.3 (8) | C4—C3—H3 | 120.0 |
O4'—Cl1'—O3' | 108.4 (8) | C3—C4—H4 | 120.7 |
C1—N1—C5 | 117.1 (4) | C5—C4—H4 | 120.7 |
C1—N1—Ag1 | 125.4 (3) | C8—C9—H9 | 121.0 |
C5—N1—Ag1 | 116.5 (3) | C10—C9—H9 | 121.0 |
C6—N2—N4 | 107.9 (3) | C11—C10—H10 | 120.1 |
C6—N2—Ag1 | 114.5 (3) | C9—C10—H10 | 120.1 |
N4—N2—Ag1 | 129.5 (3) | C12—C11—H11 | 120.9 |
C7—N3—C6 | 105.0 (3) | C10—C11—H11 | 120.9 |
C7—N3—C13 | 127.6 (4) | N5—C12—H12 | 118.1 |
C6—N3—C13 | 126.7 (3) | C11—C12—H12 | 118.1 |
C7—N4—N2 | 107.2 (3) | C13—C14—H14 | 120.5 |
C7—N4—Ag1i | 109.0 (3) | C15—C14—H14 | 120.5 |
N2—N4—Ag1i | 129.1 (3) | C16—C15—H15 | 119.6 |
C12—N5—C8 | 117.5 (4) | C14—C15—H15 | 119.6 |
C12—N5—Ag1i | 123.3 (3) | C16—C17—H17 | 119.4 |
C8—N5—Ag1i | 117.6 (3) | C18—C17—H17 | 119.4 |
N1—C1—C2 | 123.4 (5) | C13—C18—H18 | 120.7 |
C3—C2—C1 | 118.7 (5) | C17—C18—H18 | 120.7 |
C2—C3—C4 | 120.0 (5) | C20—C19—H19 | 107.3 |
C3—C4—C5 | 118.7 (5) | C21—C19—H19 | 107.3 |
N1—C5—C4 | 122.3 (4) | C16—C19—H19 | 107.3 |
N1—C5—C6 | 112.6 (4) | C19—C20—H20a | 109.5 |
C4—C5—C6 | 125.0 (4) | C19—C20—H20b | 109.5 |
N2—C6—N3 | 109.7 (4) | H20a—C20—H20b | 109.5 |
N2—C6—C5 | 121.0 (4) | C19—C20—H20c | 109.5 |
N3—C6—C5 | 129.3 (4) | H20a—C20—H20c | 109.5 |
N4—C7—N3 | 110.1 (4) | H20b—C20—H20c | 109.5 |
N4—C7—C8 | 120.2 (4) | C19—C21—H21a | 109.5 |
N3—C7—C8 | 129.6 (4) | C19—C21—H21b | 109.5 |
N5—C8—C9 | 122.7 (4) | H21a—C21—H21b | 109.5 |
N5—C8—C7 | 113.8 (4) | C19—C21—H21c | 109.5 |
C9—C8—C7 | 123.4 (4) | H21a—C21—H21c | 109.5 |
C8—C9—C10 | 118.0 (5) | H21b—C21—H21c | 109.5 |
C11—C10—C9 | 119.8 (5) | C22—C23—H23a | 110.2 |
C12—C11—C10 | 118.2 (5) | C22—C23—H23b | 110.4 |
N5—C12—C11 | 123.8 (5) | H23a—C23—H23b | 108.7 |
C14—C13—C18 | 122.0 (4) | C22—C23—H23c | 110.3 |
C14—C13—N3 | 118.7 (4) | H23a—C23—H23c | 108.3 |
C18—C13—N3 | 119.2 (4) | H23b—C23—H23c | 108.8 |
N5i—Ag1—N1—C1 | 0.2 (5) | Ag1i—N4—C7—N3 | −145.2 (3) |
N2—Ag1—N1—C1 | 165.8 (4) | N2—N4—C7—C8 | 174.3 (4) |
N4i—Ag1—N1—C1 | −115.2 (4) | Ag1i—N4—C7—C8 | 30.7 (5) |
N5i—Ag1—N1—C5 | −168.1 (3) | C6—N3—C7—N4 | 2.8 (5) |
N2—Ag1—N1—C5 | −2.5 (3) | C13—N3—C7—N4 | 173.8 (4) |
N4i—Ag1—N1—C5 | 76.4 (4) | C6—N3—C7—C8 | −172.7 (4) |
N5i—Ag1—N2—C6 | 159.2 (3) | C13—N3—C7—C8 | −1.7 (7) |
N1—Ag1—N2—C6 | 14.0 (3) | C12—N5—C8—C9 | 0.1 (7) |
N4i—Ag1—N2—C6 | −134.4 (3) | Ag1i—N5—C8—C9 | −166.3 (3) |
N5i—Ag1—N2—N4 | −56.4 (5) | C12—N5—C8—C7 | 177.8 (4) |
N1—Ag1—N2—N4 | 158.4 (3) | Ag1i—N5—C8—C7 | 11.4 (5) |
N4i—Ag1—N2—N4 | 10.0 (4) | N4—C7—C8—N5 | −30.2 (6) |
C6—N2—N4—C7 | −0.2 (4) | N3—C7—C8—N5 | 144.9 (4) |
Ag1—N2—N4—C7 | −146.4 (3) | N4—C7—C8—C9 | 147.5 (4) |
C6—N2—N4—Ag1i | 133.4 (3) | N3—C7—C8—C9 | −37.4 (7) |
Ag1—N2—N4—Ag1i | −12.7 (5) | N5—C8—C9—C10 | −0.3 (7) |
C5—N1—C1—C2 | 0.3 (7) | C7—C8—C9—C10 | −177.8 (4) |
Ag1—N1—C1—C2 | −168.0 (4) | C8—C9—C10—C11 | −0.4 (7) |
N1—C1—C2—C3 | −0.4 (8) | C9—C10—C11—C12 | 1.2 (8) |
C1—C2—C3—C4 | −0.1 (7) | C8—N5—C12—C11 | 0.8 (8) |
C2—C3—C4—C5 | 0.6 (7) | Ag1i—N5—C12—C11 | 166.4 (4) |
C1—N1—C5—C4 | 0.4 (6) | C10—C11—C12—N5 | −1.5 (8) |
Ag1—N1—C5—C4 | 169.7 (3) | C7—N3—C13—C14 | −91.2 (5) |
C1—N1—C5—C6 | −177.3 (4) | C6—N3—C13—C14 | 78.0 (6) |
Ag1—N1—C5—C6 | −7.9 (4) | C7—N3—C13—C18 | 89.9 (5) |
C3—C4—C5—N1 | −0.8 (7) | C6—N3—C13—C18 | −101.0 (5) |
C3—C4—C5—C6 | 176.5 (4) | C18—C13—C14—C15 | 1.1 (7) |
N4—N2—C6—N3 | 2.0 (5) | N3—C13—C14—C15 | −177.8 (4) |
Ag1—N2—C6—N3 | 153.8 (3) | C13—C14—C15—C16 | −0.4 (7) |
N4—N2—C6—C5 | −176.8 (4) | C14—C15—C16—C17 | −1.0 (7) |
Ag1—N2—C6—C5 | −25.0 (5) | C14—C15—C16—C19 | 178.7 (4) |
C7—N3—C6—N2 | −2.9 (4) | C15—C16—C17—C18 | 1.7 (7) |
C13—N3—C6—N2 | −174.1 (4) | C19—C16—C17—C18 | −178.0 (5) |
C7—N3—C6—C5 | 175.8 (4) | C14—C13—C18—C17 | −0.4 (7) |
C13—N3—C6—C5 | 4.6 (7) | N3—C13—C18—C17 | 178.5 (4) |
N1—C5—C6—N2 | 22.4 (6) | C16—C17—C18—C13 | −1.0 (8) |
C4—C5—C6—N2 | −155.2 (4) | C17—C16—C19—C20 | 115.2 (6) |
N1—C5—C6—N3 | −156.2 (4) | C15—C16—C19—C20 | −64.6 (6) |
C4—C5—C6—N3 | 26.3 (7) | C17—C16—C19—C21 | −119.5 (5) |
N2—N4—C7—N3 | −1.6 (5) | C15—C16—C19—C21 | 60.7 (6) |
Symmetry code: (i) −x+3/2, −y+3/2, −z+1. |