μ-Di­phenyl­phosphido-μ-hydrido-bis­[carbonyl(η⁵-cyclo­penta­dienyl)­iron(II)]

The title compound, [Fe₂(C₅H₅)₂(C₁₂H₁₀P)H(CO)₂], features near symmetric hydride and phosphide bridges. The two carbonyl/cyclo­penta­dienyl groups are in trans positions. One of the cyclo­penta­dienyl rings is disordered over two positions, with occupancies of 0.65 and 0.35.

Key indicators

• Single-crystal X-ray study
• T = 198 K
• Mean [sigma](C-C) = 0.002 Å
• R factor = 0.017
• wR factor = 0.045
• Data-to-parameter ratio = 14.8

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT213_ALERT_2_C Atom C14A    has ADP max/min Ratio .............       3.70 prolat
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for        Fe1
PLAT301_ALERT_3_C Main Residue  Disorder .........................      15.00 Perc.

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           27.50
           From the CIF: _reflns_number_total               4609
           Count of symmetry unique reflns         2674
           Completeness (_total/calc)            172.36%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      1935
           Fraction of Friedel pairs measured     0.724
           Are heavy atom types Z>Si present          yes

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: SMART (Bruker, 1997-1999); cell refinement: SMART; data reduction: SAINT (Bruker, 1997-1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1977b); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997b); molecular graphics: SHELXTL (Shelxdrick, 1997a); software used to prepare material for publication: SHELXTL.

µ-Diphenylphosphido-µ-hydrido-bis[carbonyl(η⁵– cyclopentadienyl)iron(II)]

Crystal data

[Fe2(C5H5)2(C12H10P)H(CO)2]	F(000) = 992
Mr = 484.08	Dx = 1.570 Mg m^−3
Orthorhombic, P212121	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2ab	Cell parameters from 6155 reflections
a = 10.2945 (5) Å	θ = 2.4–28.6°
b = 12.5071 (6) Å	µ = 1.51 mm^−1
c = 15.9110 (8) Å	T = 198 K
V = 2048.61 (17) Å^3	Prism, dark red
Z = 4	0.48 × 0.35 × 0.30 mm

Data collection

Bruker AXS SMART1000/P4 diffractometer	4609 independent reflections
Radiation source: fine-focus sealed tube, Bruker AXS SMART1000/P4	4506 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.023
ω and φ scans	θmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −12→13
Tmin = 0.561, Tmax = 0.635	k = −16→16
14556 measured reflections	l = −20→20

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.017	H atoms treated by a mixture of independent and constrained refinement
wR(F^2) = 0.045	w = 1/[σ^2(Fo^2) + (0.0186P)^2 + 0.1562P] where P = (Fo^2 + 2Fc^2)/3
S = 1.05	(Δ/σ)max = 0.002
4609 reflections	Δρmax = 0.25 e Å^−3
311 parameters	Δρmin = −0.27 e Å^−3
20 restraints	Absolute structure: Flack (1983), 1955 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.002 (8)

Special details

Experimental. Crystal decay was monitored by repeating the initial 50 frames at the end of the data collection and analyzing duplicate reflections.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. One of the cyclopentadienyl rings was disorderd over two positions. The occupancy was refined using an isotropic model and fixed at 0.65 (C13 - C17) and 0.35 (C13a) - C17a) in subsequent cycles.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Fe1	0.295161 (18)	0.503897 (15)	1.055861 (12)	0.02157 (5)
Fe2	0.321022 (18)	0.363100 (14)	0.927500 (13)	0.02101 (5)
P1	0.38123 (3)	0.53126 (2)	0.93229 (2)	0.01929 (7)
C1	0.31211 (13)	0.64067 (10)	0.86986 (9)	0.0213 (3)
C2	0.19245 (15)	0.63233 (11)	0.83002 (10)	0.0286 (3)
H2	0.1477	0.5659	0.8307	0.034*
C3	0.13683 (16)	0.71926 (12)	0.78912 (11)	0.0336 (3)
H3	0.0544	0.7120	0.7629	0.040*
C4	0.20107 (18)	0.81588 (12)	0.78649 (11)	0.0350 (4)
H4	0.1633	0.8753	0.7585	0.042*
C5	0.32035 (17)	0.82542 (12)	0.82478 (11)	0.0349 (4)
H5	0.3653	0.8917	0.8227	0.042*
C6	0.37562 (16)	0.73915 (11)	0.86643 (11)	0.0284 (3)
H6	0.4577	0.7472	0.8929	0.034*
C7	0.55469 (13)	0.55414 (10)	0.91426 (10)	0.0224 (3)
C8	0.60081 (15)	0.55678 (11)	0.83159 (10)	0.0273 (3)
H8	0.5410	0.5529	0.7862	0.033*
C9	0.73178 (15)	0.56501 (11)	0.81495 (11)	0.0309 (3)
H9	0.7617	0.5671	0.7585	0.037*
C10	0.81945 (16)	0.57019 (12)	0.88034 (12)	0.0350 (4)
H10	0.9099	0.5749	0.8690	0.042*
C11	0.77592 (16)	0.56861 (14)	0.96210 (12)	0.0372 (4)
H11	0.8365	0.5719	1.0071	0.045*
C12	0.64328 (15)	0.56214 (12)	0.97931 (11)	0.0292 (3)
H12	0.6137	0.5632	1.0359	0.035*
C13	0.1072 (11)	0.4981 (9)	1.1006 (7)	0.046 (2)	0.65
H13A	0.0563	0.4348	1.0996	0.056*	0.65
C14	0.1138 (12)	0.5733 (9)	1.0374 (7)	0.051 (3)	0.65
H14A	0.0665	0.5713	0.9862	0.062*	0.65
C15	0.1997 (10)	0.6509 (7)	1.0607 (5)	0.051 (2)	0.65
H15A	0.2233	0.7115	1.0280	0.061*	0.65
C16	0.2470 (6)	0.6264 (6)	1.1406 (5)	0.0450 (18)	0.65
H16A	0.3080	0.6667	1.1722	0.054*	0.65
C17	0.1866 (6)	0.5303 (6)	1.1653 (3)	0.0384 (14)	0.65
H17A	0.1986	0.4943	1.2172	0.046*	0.65
C18	0.43321 (16)	0.46037 (13)	1.10810 (10)	0.0303 (3)
C19	0.49289 (18)	0.30189 (13)	0.87515 (14)	0.0422 (5)
H19	0.5556	0.3421	0.8448	0.051*
C20	0.49273 (17)	0.28441 (14)	0.96164 (14)	0.0442 (5)
H20	0.5547	0.3115	1.0004	0.053*
C21	0.3851 (2)	0.21969 (13)	0.98201 (12)	0.0414 (4)
H21	0.3619	0.1953	1.0365	0.050*
C22	0.31879 (18)	0.19801 (11)	0.90761 (13)	0.0384 (4)
H22	0.2426	0.1557	0.9024	0.046*
C23	0.38501 (19)	0.25021 (12)	0.84071 (12)	0.0394 (4)
H23	0.3604	0.2500	0.7832	0.047*
C24	0.16781 (15)	0.37888 (10)	0.88459 (10)	0.0271 (3)
O18	0.52127 (12)	0.43238 (11)	1.14741 (9)	0.0446 (3)
O24	0.06506 (11)	0.37955 (9)	0.85442 (9)	0.0413 (3)
H1	0.267 (2)	0.3829 (18)	1.0244 (14)	0.059 (7)*
C13A	0.1543 (13)	0.4836 (9)	1.1486 (9)	0.048 (3)	0.35
H13B	0.1500	0.4222	1.1836	0.058*	0.35
C14A	0.087 (2)	0.5004 (17)	1.0752 (13)	0.044 (4)	0.35
H14B	0.0211	0.4552	1.0530	0.053*	0.35
C15A	0.132 (2)	0.5963 (15)	1.0384 (10)	0.034 (4)	0.35
H15B	0.1076	0.6227	0.9846	0.041*	0.35
C16A	0.2175 (10)	0.6459 (8)	1.0947 (10)	0.036 (3)	0.35
H16B	0.2580	0.7136	1.0883	0.043*	0.35
C17A	0.2312 (12)	0.5756 (13)	1.1618 (6)	0.047 (3)	0.35
H17B	0.2845	0.5878	1.2096	0.057*	0.35

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Fe1	0.01860 (10)	0.02563 (9)	0.02049 (10)	0.00119 (7)	0.00124 (7)	−0.00020 (8)
Fe2	0.01828 (9)	0.01931 (8)	0.02544 (10)	0.00096 (7)	0.00054 (8)	−0.00037 (8)
P1	0.01591 (15)	0.02075 (14)	0.02123 (17)	−0.00022 (11)	0.00018 (15)	0.00017 (13)
C1	0.0212 (7)	0.0225 (6)	0.0202 (6)	0.0014 (5)	0.0006 (5)	0.0007 (5)
C2	0.0258 (7)	0.0244 (6)	0.0355 (8)	−0.0017 (6)	−0.0042 (7)	0.0009 (6)
C3	0.0292 (8)	0.0323 (7)	0.0394 (9)	0.0024 (6)	−0.0102 (7)	0.0032 (7)
C4	0.0382 (9)	0.0286 (7)	0.0383 (9)	0.0042 (6)	−0.0043 (8)	0.0078 (6)
C5	0.0378 (9)	0.0262 (6)	0.0408 (9)	−0.0042 (6)	−0.0029 (8)	0.0070 (6)
C6	0.0246 (7)	0.0263 (6)	0.0342 (8)	−0.0036 (5)	−0.0028 (7)	0.0030 (6)
C7	0.0187 (6)	0.0194 (5)	0.0291 (8)	−0.0009 (4)	0.0009 (6)	−0.0006 (5)
C8	0.0232 (8)	0.0311 (7)	0.0278 (8)	−0.0008 (5)	0.0016 (6)	−0.0005 (6)
C9	0.0286 (8)	0.0284 (7)	0.0355 (9)	0.0019 (6)	0.0093 (7)	0.0007 (6)
C10	0.0181 (7)	0.0333 (7)	0.0537 (11)	0.0022 (6)	0.0045 (8)	0.0050 (7)
C11	0.0204 (8)	0.0474 (9)	0.0438 (10)	−0.0031 (6)	−0.0057 (7)	0.0065 (8)
C12	0.0235 (8)	0.0353 (7)	0.0289 (8)	−0.0047 (5)	−0.0019 (6)	0.0027 (6)
C13	0.022 (5)	0.042 (3)	0.076 (6)	−0.003 (3)	0.014 (4)	−0.016 (4)
C14	0.023 (3)	0.092 (8)	0.040 (4)	0.025 (4)	−0.002 (3)	−0.020 (4)
C15	0.061 (5)	0.038 (2)	0.053 (4)	0.019 (3)	0.031 (4)	0.006 (3)
C16	0.034 (2)	0.045 (3)	0.056 (5)	−0.003 (3)	0.009 (2)	−0.026 (4)
C17	0.045 (4)	0.045 (3)	0.026 (2)	0.016 (2)	0.013 (3)	0.004 (3)
C18	0.0269 (8)	0.0378 (8)	0.0261 (8)	−0.0013 (6)	0.0029 (7)	0.0041 (6)
C19	0.0329 (9)	0.0258 (7)	0.0679 (13)	0.0043 (6)	0.0204 (9)	−0.0050 (8)
C20	0.0304 (9)	0.0367 (8)	0.0655 (14)	0.0151 (7)	−0.0153 (9)	−0.0153 (9)
C21	0.0522 (11)	0.0299 (7)	0.0420 (10)	0.0186 (8)	0.0051 (9)	0.0081 (7)
C22	0.0318 (9)	0.0210 (6)	0.0625 (11)	0.0015 (6)	0.0037 (8)	−0.0054 (7)
C23	0.0513 (11)	0.0307 (8)	0.0362 (9)	0.0147 (7)	0.0024 (9)	−0.0062 (7)
C24	0.0274 (8)	0.0218 (6)	0.0322 (8)	−0.0024 (5)	0.0000 (6)	0.0020 (6)
O18	0.0271 (6)	0.0666 (8)	0.0402 (7)	0.0020 (6)	−0.0074 (6)	0.0170 (6)
O24	0.0274 (6)	0.0383 (6)	0.0583 (8)	−0.0045 (5)	−0.0137 (6)	0.0068 (6)
C13A	0.047 (6)	0.041 (5)	0.057 (7)	0.023 (4)	0.033 (5)	0.021 (5)
C14A	0.010 (4)	0.037 (6)	0.084 (11)	−0.009 (3)	0.006 (6)	−0.028 (7)
C15A	0.032 (7)	0.044 (5)	0.026 (6)	0.015 (4)	0.008 (5)	0.018 (5)
C16A	0.022 (3)	0.024 (5)	0.063 (9)	−0.002 (3)	0.003 (6)	−0.022 (7)
C17A	0.050 (9)	0.067 (9)	0.025 (6)	0.026 (7)	−0.009 (5)	−0.026 (8)

Geometric parameters (Å, º)

Fe1—C18	1.7341 (17)	C9—C10	1.379 (2)
Fe1—C17A	2.021 (7)	C9—H9	0.9500
Fe1—C16A	2.044 (10)	C10—C11	1.376 (3)
Fe1—C15A	2.06 (2)	C10—H10	0.9500
Fe1—C13	2.063 (12)	C11—C12	1.395 (2)
Fe1—C14	2.080 (12)	C11—H11	0.9500
Fe1—C13A	2.085 (9)	C12—H12	0.9500
Fe1—C15	2.086 (8)	C13—C17	1.374 (7)
Fe1—C17	2.095 (5)	C13—C14	1.378 (9)
Fe1—C16	2.100 (6)	C13—H13A	0.9500
Fe1—C14A	2.17 (2)	C14—C15	1.365 (9)
Fe1—P1	2.1836 (4)	C14—H14A	0.9500
Fe1—Fe2	2.7098 (3)	C15—C16	1.395 (7)
Fe1—H1	1.62 (2)	C15—H15A	0.9500
Fe2—C24	1.7299 (16)	C16—C17	1.409 (6)
Fe2—C23	2.0819 (16)	C16—H16A	0.9500
Fe2—C22	2.0891 (14)	C17—H17A	0.9500
Fe2—C20	2.0948 (16)	C18—O18	1.156 (2)
Fe2—C21	2.0985 (15)	C19—C20	1.393 (3)
Fe2—C19	2.1001 (17)	C19—C23	1.397 (3)
Fe2—P1	2.1940 (4)	C19—H19	0.9500
Fe2—H1	1.66 (2)	C20—C21	1.410 (3)
P1—C7	1.8311 (14)	C20—H20	0.9500
P1—C1	1.8345 (14)	C21—C22	1.393 (3)
C1—C2	1.389 (2)	C21—H21	0.9500
C1—C6	1.3955 (19)	C22—C23	1.423 (3)
C2—C3	1.390 (2)	C22—H22	0.9500
C2—H2	0.9500	C23—H23	0.9500
C3—C4	1.378 (2)	C24—O24	1.1616 (19)
C3—H3	0.9500	C13A—C14A	1.376 (12)
C4—C5	1.376 (2)	C13A—C17A	1.413 (10)
C4—H4	0.9500	C13A—H13B	0.9500
C5—C6	1.388 (2)	C14A—C15A	1.411 (13)
C5—H5	0.9500	C14A—H14B	0.9500
C6—H6	0.9500	C15A—C16A	1.404 (13)
C7—C12	1.383 (2)	C15A—H15B	0.9500
C7—C8	1.399 (2)	C16A—C17A	1.390 (10)
C8—C9	1.378 (2)	C16A—H16B	0.9500
C8—H8	0.9500	C17A—H17B	0.9500
C18—Fe1—C17A	90.4 (3)	C1—C2—H2	119.3
C18—Fe1—C16A	116.7 (4)	C3—C2—H2	119.3
C17A—Fe1—C16A	40.0 (3)	C4—C3—C2	120.15 (15)
C18—Fe1—C15A	155.5 (5)	C4—C3—H3	119.9
C17A—Fe1—C15A	66.2 (6)	C2—C3—H3	119.9
C16A—Fe1—C15A	40.0 (4)	C5—C4—C3	119.39 (14)
C18—Fe1—C13	126.3 (3)	C5—C4—H4	120.3
C17A—Fe1—C13	54.7 (4)	C3—C4—H4	120.3
C16A—Fe1—C13	63.8 (4)	C4—C5—C6	120.65 (14)
C15A—Fe1—C13	45.5 (6)	C4—C5—H5	119.7
C18—Fe1—C14	159.1 (3)	C6—C5—H5	119.7
C17A—Fe1—C14	68.9 (4)	C5—C6—C1	120.84 (15)
C16A—Fe1—C14	47.8 (5)	C5—C6—H6	119.6
C15A—Fe1—C14	9.4 (6)	C1—C6—H6	119.6
C13—Fe1—C14	38.9 (3)	C12—C7—C8	118.57 (14)
C18—Fe1—C13A	101.1 (4)	C12—C7—P1	122.49 (12)
C17A—Fe1—C13A	40.2 (3)	C8—C7—P1	118.81 (11)
C16A—Fe1—C13A	67.6 (4)	C9—C8—C7	120.97 (15)
C15A—Fe1—C13A	66.1 (5)	C9—C8—H8	119.5
C13—Fe1—C13A	25.7 (4)	C7—C8—H8	119.5
C14—Fe1—C13A	61.7 (4)	C8—C9—C10	119.93 (17)
C18—Fe1—C15	130.2 (3)	C8—C9—H9	120.0
C17A—Fe1—C15	54.9 (3)	C10—C9—H9	120.0
C16A—Fe1—C15	16.0 (3)	C11—C10—C9	119.97 (14)
C15A—Fe1—C15	29.1 (5)	C11—C10—H10	120.0
C13—Fe1—C15	64.9 (4)	C9—C10—H10	120.0
C14—Fe1—C15	38.2 (3)	C10—C11—C12	120.34 (16)
C13A—Fe1—C15	75.7 (3)	C10—C11—H11	119.8
C18—Fe1—C17	95.08 (15)	C12—C11—H11	119.8
C17A—Fe1—C17	20.4 (4)	C7—C12—C11	120.18 (16)
C16A—Fe1—C17	53.3 (3)	C7—C12—H12	119.9
C15A—Fe1—C17	65.6 (5)	C11—C12—H12	119.9
C13—Fe1—C17	38.6 (2)	C17—C13—C14	108.5 (7)
C14—Fe1—C17	64.7 (3)	C17—C13—Fe1	72.0 (5)
C13A—Fe1—C17	19.9 (3)	C14—C13—Fe1	71.2 (7)
C15—Fe1—C17	65.1 (2)	C17—C13—H13A	125.7
C18—Fe1—C16	96.6 (2)	C14—C13—H13A	125.7
C17A—Fe1—C16	20.5 (4)	Fe1—C13—H13A	122.7
C16A—Fe1—C16	23.0 (3)	C15—C14—C13	108.6 (8)
C15A—Fe1—C16	59.0 (5)	C15—C14—Fe1	71.1 (6)
C13—Fe1—C16	65.3 (4)	C13—C14—Fe1	69.9 (7)
C14—Fe1—C16	64.8 (4)	C15—C14—H14A	125.7
C13A—Fe1—C16	58.0 (3)	C13—C14—H14A	125.7
C15—Fe1—C16	38.93 (19)	Fe1—C14—H14A	124.8
C17—Fe1—C16	39.25 (17)	C14—C15—C16	108.5 (9)
C18—Fe1—C14A	137.5 (6)	C14—C15—Fe1	70.6 (6)
C17A—Fe1—C14A	64.4 (6)	C16—C15—Fe1	71.1 (5)
C16A—Fe1—C14A	65.6 (6)	C14—C15—H15A	125.8
C15A—Fe1—C14A	38.9 (4)	C16—C15—H15A	125.8
C13—Fe1—C14A	12.1 (6)	Fe1—C15—H15A	124.2
C14—Fe1—C14A	30.7 (6)	C15—C16—C17	106.7 (8)
C13A—Fe1—C14A	37.7 (4)	C15—C16—Fe1	70.0 (5)
C15—Fe1—C14A	63.0 (6)	C17—C16—Fe1	70.2 (4)
C17—Fe1—C14A	50.0 (5)	C15—C16—H16A	126.6
C16—Fe1—C14A	71.9 (6)	C17—C16—H16A	126.6
C18—Fe1—P1	98.53 (5)	Fe1—C16—H16A	124.8
C17A—Fe1—P1	144.5 (5)	C13—C17—C16	107.7 (7)
C16A—Fe1—P1	107.2 (4)	C13—C17—Fe1	69.5 (6)
C15A—Fe1—P1	97.0 (5)	C16—C17—Fe1	70.6 (4)
C13—Fe1—P1	134.2 (3)	C13—C17—H17A	126.2
C14—Fe1—P1	99.9 (3)	C16—C17—H17A	126.2
C13A—Fe1—P1	159.9 (5)	Fe1—C17—H17A	125.4
C15—Fe1—P1	94.93 (18)	O18—C18—Fe1	175.88 (15)
C17—Fe1—P1	160.05 (17)	C20—C19—C23	108.29 (17)
C16—Fe1—P1	124.0 (2)	C20—C19—Fe2	70.39 (10)
C14A—Fe1—P1	122.2 (5)	C23—C19—Fe2	69.78 (10)
C18—Fe1—H1	90.2 (8)	C20—C19—H19	125.9
C17A—Fe1—H1	127.8 (10)	C23—C19—H19	125.9
C16A—Fe1—H1	146.5 (9)	Fe2—C19—H19	125.5
C15A—Fe1—H1	109.5 (10)	C19—C20—C21	108.54 (17)
C13—Fe1—H1	84.5 (9)	C19—C20—Fe2	70.80 (11)
C14—Fe1—H1	100.5 (9)	C21—C20—Fe2	70.49 (9)
C13A—Fe1—H1	88.8 (9)	C19—C20—H20	125.7
C15—Fe1—H1	138.5 (9)	C21—C20—H20	125.7
C17—Fe1—H1	107.9 (8)	Fe2—C20—H20	124.6
C16—Fe1—H1	146.8 (8)	C22—C21—C20	107.54 (17)
C14A—Fe1—H1	81.1 (10)	C22—C21—Fe2	70.21 (9)
P1—Fe1—H1	86.7 (8)	C20—C21—Fe2	70.21 (9)
C24—Fe2—C23	95.97 (8)	C22—C21—H21	126.2
C24—Fe2—C22	92.46 (7)	C20—C21—H21	126.2
C23—Fe2—C22	39.88 (7)	Fe2—C21—H21	125.0
C24—Fe2—C20	157.71 (7)	C21—C22—C23	108.17 (15)
C23—Fe2—C20	65.57 (8)	C21—C22—Fe2	70.94 (9)
C22—Fe2—C20	65.43 (7)	C23—C22—Fe2	69.79 (9)
C24—Fe2—C21	123.16 (7)	C21—C22—H22	125.9
C23—Fe2—C21	66.11 (7)	C23—C22—H22	125.9
C22—Fe2—C21	38.86 (7)	Fe2—C22—H22	125.0
C20—Fe2—C21	39.30 (8)	C19—C23—C22	107.45 (17)
C24—Fe2—C19	130.78 (8)	C19—C23—Fe2	71.19 (10)
C23—Fe2—C19	39.03 (8)	C22—C23—Fe2	70.33 (9)
C22—Fe2—C19	65.72 (7)	C19—C23—H23	126.3
C20—Fe2—C19	38.80 (9)	C22—C23—H23	126.3
C21—Fe2—C19	65.65 (8)	Fe2—C23—H23	123.8
C24—Fe2—P1	99.32 (4)	O24—C24—Fe2	173.78 (13)
C23—Fe2—P1	125.72 (5)	C14A—C13A—C17A	106.6 (11)
C22—Fe2—P1	162.92 (5)	C14A—C13A—Fe1	74.4 (11)
C20—Fe2—P1	101.71 (5)	C17A—C13A—Fe1	67.5 (5)
C21—Fe2—P1	135.75 (6)	C14A—C13A—H13B	126.7
C19—Fe2—P1	97.19 (5)	C17A—C13A—H13B	126.7
C24—Fe2—Fe1	97.68 (5)	Fe1—C13A—H13B	123.0
C23—Fe2—Fe1	166.34 (6)	C13A—C14A—C15A	108.5 (12)
C22—Fe2—Fe1	139.06 (6)	C13A—C14A—Fe1	67.9 (10)
C20—Fe2—Fe1	101.11 (5)	C15A—C14A—Fe1	66.5 (12)
C21—Fe2—Fe1	105.95 (5)	C13A—C14A—H14B	125.8
C19—Fe2—Fe1	128.21 (6)	C15A—C14A—H14B	125.8
P1—Fe2—Fe1	51.583 (11)	Fe1—C14A—H14B	131.6
C24—Fe2—H1	92.4 (8)	C16A—C15A—C14A	108.5 (11)
C23—Fe2—H1	145.6 (8)	C16A—C15A—Fe1	69.3 (9)
C22—Fe2—H1	106.6 (8)	C14A—C15A—Fe1	74.6 (12)
C20—Fe2—H1	96.6 (8)	C16A—C15A—H15B	125.8
C21—Fe2—H1	81.4 (8)	C14A—C15A—H15B	125.8
C19—Fe2—H1	135.1 (8)	Fe1—C15A—H15B	121.9
P1—Fe2—H1	85.4 (8)	C17A—C16A—C15A	106.0 (9)
Fe1—Fe2—H1	33.8 (8)	C17A—C16A—Fe1	69.1 (5)
C7—P1—C1	100.19 (6)	C15A—C16A—Fe1	70.7 (10)
C7—P1—Fe1	124.14 (5)	C17A—C16A—H16B	127.0
C1—P1—Fe1	116.56 (5)	C15A—C16A—H16B	127.0
C7—P1—Fe2	114.83 (4)	Fe1—C16A—H16B	124.8
C1—P1—Fe2	125.92 (5)	C16A—C17A—C13A	110.1 (9)
Fe1—P1—Fe2	76.489 (13)	C16A—C17A—Fe1	70.9 (5)
C2—C1—C6	117.63 (13)	C13A—C17A—Fe1	72.3 (5)
C2—C1—P1	122.34 (10)	C16A—C17A—H17B	125.0
C6—C1—P1	119.85 (11)	C13A—C17A—H17B	124.9
C1—C2—C3	121.33 (14)	Fe1—C17A—H17B	123.4