Download citation
Download citation
link to html
A two-dimensional silver(I) coordination polymer, {[Ag(L)2]BF4}n, has been formed from AgBF4 and 1,5-bis­(phenyl­sulfanyl)­pentane (L, C17H20S2), in which each silver(I) center is coordinated by four S atoms from distinct ligands and displays a distorted tetrahedral geometry. Each ligand links two AgI atoms to form an infinite two-dimensional (4,4)-grid-like network. The BF4 ions are incorporated into the cavities of the coordination framework to complete and stabilize the structure.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803028605/lh6148sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803028605/lh6148Isup2.hkl
Contains datablock I

CCDC reference: 222962

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.007 Å
  • Disorder in solvent or counterion
  • R factor = 0.030
  • wR factor = 0.064
  • Data-to-parameter ratio = 11.9

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT128_ALERT_4_C Non-standard setting of Space group Pc .... Pn PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors .... F1 PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors .... F2' PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors .... F3 PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors .... F3' PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... F1' PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... B1 PLAT250_ALERT_2_C Large U3/U1 ratio for average U(i,j) tensor .... 2.26 PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 38.00 Perc. PLAT850_ALERT_2_C Check Flack Parameter Value of 0.0 with su gt 0 !
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 25.03 From the CIF: _reflns_number_total 5074 Count of symmetry unique reflns 3085 Completeness (_total/calc) 164.47% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 1989 Fraction of Friedel pairs measured 0.645 Are heavy atom types Z>Si present yes
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 10 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 9 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP in SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXL97.

Poly[[silver(I)-di-µ-1,5-bis(phenylsulfanyl)pentane] tetrafluoroborate] top
Crystal data top
[Ag(C17H20S2)2]BF4F(000) = 792
Mr = 771.62Dx = 1.467 Mg m3
Monoclinic, PnMo Kα radiation, λ = 0.71073 Å
Hall symbol: P_-2yacCell parameters from 981 reflections
a = 9.209 (3) Åθ = 3.1–19.7°
b = 10.182 (3) ŵ = 0.86 mm1
c = 19.158 (5) ÅT = 293 K
β = 103.507 (5)°Prism, colorless
V = 1746.7 (9) Å30.30 × 0.20 × 0.20 mm
Z = 2
Data collection top
Bruker SMART 1000
diffractometer
4519 reflections with I > 2σ(I)
ω scansRint = 0.025
Absorption correction: multi-scan
SADABS (Sheldrick, 1997)
θmax = 25.0°, θmin = 2.0°
Tmin = 0.782, Tmax = 0.847h = 1010
7056 measured reflectionsk = 812
5074 independent reflectionsl = 2222
Refinement top
Refinement on F2 w = 1/[σ2(Fo2) + (0.030P)2]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.030(Δ/σ)max < 0.001
wR(F2) = 0.064Δρmax = 0.43 e Å3
S = 1.07Δρmin = 0.30 e Å3
5074 reflectionsAbsolute structure: Flack (1983); 1989 Friedel pairs
425 parametersAbsolute structure parameter: 0.00 (2)
H-atom parameters constrained
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Full-MATRIX

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.793322 (19)0.19422 (3)0.752687 (14)0.05103 (10)
S10.72698 (13)0.55992 (11)0.76004 (6)0.0536 (3)
S21.06107 (12)0.16724 (10)0.83734 (6)0.0480 (3)
S30.16656 (11)0.19570 (10)0.61871 (5)0.0417 (2)
S40.59617 (11)0.00789 (10)0.74055 (6)0.0469 (2)
C10.6350 (6)0.5590 (4)0.8882 (3)0.0614 (12)
H1A0.73150.58370.91120.074*
C20.5241 (8)0.5448 (5)0.9271 (3)0.0832 (17)
H2A0.54670.55820.97650.100*
C30.3822 (8)0.5109 (6)0.8912 (5)0.100 (2)
H3A0.30750.50480.91650.120*
C40.3479 (7)0.4858 (6)0.8188 (4)0.093 (2)
H4A0.25190.45990.79550.112*
C50.4550 (5)0.4990 (5)0.7819 (3)0.0677 (14)
H5A0.43140.48300.73280.081*
C60.5983 (4)0.5355 (4)0.8151 (2)0.0467 (10)
C70.8922 (5)0.4695 (4)0.8055 (2)0.0519 (11)
H7A0.97390.49010.78330.062*
H7B0.92100.49760.85530.062*
C80.8673 (5)0.3233 (4)0.8030 (2)0.0531 (11)
H8A0.82340.29800.75380.064*
H8B0.79600.30200.83140.064*
C91.0075 (5)0.2429 (4)0.8303 (2)0.0491 (10)
H9A1.05000.26390.88020.059*
H9B1.08080.26440.80300.059*
C100.9712 (4)0.0954 (4)0.8229 (2)0.0494 (10)
H10A0.90940.07280.85570.059*
H10B0.91330.07850.77450.059*
C111.1056 (5)0.0082 (4)0.8376 (2)0.0530 (11)
H11A1.16860.03110.88410.064*
H11B1.16220.02460.80170.064*
C121.0529 (4)0.1937 (4)0.9287 (2)0.0437 (9)
C131.1833 (6)0.2255 (5)0.9790 (3)0.0628 (14)
H13A1.27340.23280.96520.075*
C141.1775 (7)0.2462 (6)1.0496 (3)0.0779 (16)
H14A1.26450.26821.08330.094*
C151.0473 (7)0.2349 (5)1.0708 (3)0.0723 (15)
H15A1.04550.24851.11860.087*
C160.9193 (6)0.2036 (5)1.0218 (3)0.0661 (13)
H16A0.82990.19601.03610.079*
C170.9219 (6)0.1833 (4)0.9507 (3)0.0539 (12)
H17A0.83390.16240.91750.065*
C180.5528 (4)0.0916 (4)0.8711 (2)0.0500 (10)
H18A0.57600.17510.85730.060*
C190.5212 (5)0.0738 (6)0.9375 (2)0.0621 (13)
H19A0.52440.14480.96840.074*
C200.4850 (5)0.0494 (7)0.9578 (3)0.0726 (15)
H20A0.46440.06201.00260.087*
C210.4792 (6)0.1545 (6)0.9112 (3)0.0699 (16)
H21A0.45210.23730.92430.084*
C220.5138 (5)0.1369 (5)0.8452 (3)0.0561 (12)
H22A0.51250.20790.81450.067*
C230.5503 (4)0.0126 (4)0.8253 (2)0.0409 (9)
C240.4116 (5)0.0405 (4)0.6833 (2)0.0502 (11)
H24A0.34420.02800.69140.060*
H24B0.41820.03430.63360.060*
C250.3436 (4)0.1716 (4)0.6940 (2)0.0504 (11)
H25A0.34150.18180.74400.061*
H25B0.40470.24150.68160.061*
C260.1852 (5)0.1826 (4)0.6474 (2)0.0492 (11)
H26A0.12580.11050.65870.059*
H26B0.18850.17440.59730.059*
C270.1106 (5)0.3111 (4)0.6579 (2)0.0538 (11)
H27A0.10130.31570.70730.065*
H27B0.17500.38270.65060.065*
C280.0437 (5)0.3321 (4)0.6085 (2)0.0523 (11)
H28A0.08560.41420.62050.063*
H28B0.03520.33730.55910.063*
C290.3461 (4)0.2469 (4)0.5687 (2)0.0412 (9)
C300.4429 (5)0.1488 (4)0.5352 (2)0.0490 (10)
H30A0.40980.06240.53560.059*
C310.5878 (5)0.1798 (5)0.5014 (3)0.0565 (13)
H31A0.65250.11360.47980.068*
C320.6374 (5)0.3053 (5)0.4992 (3)0.0628 (13)
H32A0.73540.32530.47620.075*
C330.5420 (6)0.4020 (5)0.5311 (3)0.0717 (15)
H33A0.57580.48830.52910.086*
C340.3973 (5)0.3747 (5)0.5659 (2)0.0590 (12)
H34A0.33410.44180.58760.071*
B10.1221 (7)0.2876 (6)0.6411 (3)0.0793 (19)
F10.114 (4)0.1772 (14)0.6782 (13)0.257 (14)0.50
F20.0534 (17)0.269 (2)0.5743 (5)0.169 (8)0.50
F30.253 (2)0.340 (3)0.6409 (14)0.230 (14)0.50
F40.0318 (5)0.3659 (4)0.6683 (2)0.1125 (12)
F1'0.2416 (14)0.2607 (12)0.6910 (7)0.122 (4)0.50
F2'0.0765 (17)0.1738 (14)0.6127 (16)0.191 (8)0.50
F3'0.166 (4)0.355 (2)0.5902 (15)0.262 (14)0.50
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0556 (2)0.04937 (17)0.04836 (16)0.0004 (2)0.01272 (13)0.00044 (19)
S10.0547 (7)0.0449 (6)0.0604 (7)0.0041 (5)0.0116 (5)0.0113 (5)
S20.0436 (6)0.0453 (6)0.0546 (6)0.0040 (5)0.0102 (5)0.0025 (5)
S30.0407 (6)0.0429 (6)0.0412 (5)0.0024 (5)0.0091 (4)0.0001 (5)
S40.0365 (6)0.0509 (6)0.0541 (6)0.0019 (5)0.0124 (5)0.0046 (5)
C10.068 (3)0.041 (3)0.074 (3)0.000 (2)0.015 (3)0.007 (2)
C20.126 (6)0.056 (3)0.081 (4)0.006 (3)0.051 (4)0.006 (3)
C30.083 (5)0.067 (4)0.172 (8)0.018 (4)0.074 (5)0.026 (5)
C40.051 (4)0.082 (4)0.148 (6)0.002 (3)0.028 (4)0.025 (4)
C50.046 (3)0.060 (3)0.089 (4)0.007 (2)0.001 (3)0.020 (3)
C60.044 (2)0.033 (2)0.061 (3)0.0012 (18)0.008 (2)0.0098 (19)
C70.048 (3)0.038 (2)0.070 (3)0.0043 (18)0.016 (2)0.003 (2)
C80.050 (3)0.046 (3)0.063 (3)0.006 (2)0.013 (2)0.004 (2)
C90.047 (2)0.042 (2)0.060 (3)0.008 (2)0.016 (2)0.007 (2)
C100.045 (2)0.043 (2)0.061 (3)0.0049 (19)0.014 (2)0.000 (2)
C110.045 (3)0.050 (3)0.065 (3)0.008 (2)0.014 (2)0.006 (2)
C120.039 (2)0.038 (2)0.052 (2)0.0009 (17)0.0042 (19)0.0017 (19)
C130.048 (3)0.064 (3)0.072 (4)0.006 (2)0.003 (3)0.006 (3)
C140.078 (4)0.082 (4)0.062 (3)0.005 (3)0.007 (3)0.017 (3)
C150.100 (4)0.058 (3)0.051 (3)0.010 (3)0.003 (3)0.003 (2)
C160.074 (3)0.062 (3)0.068 (3)0.009 (3)0.028 (3)0.005 (3)
C170.045 (3)0.054 (3)0.061 (3)0.009 (2)0.008 (2)0.002 (2)
C180.042 (2)0.050 (3)0.055 (3)0.003 (2)0.006 (2)0.001 (2)
C190.047 (3)0.090 (4)0.047 (2)0.002 (3)0.007 (2)0.009 (3)
C200.047 (3)0.114 (5)0.056 (3)0.009 (3)0.011 (2)0.030 (3)
C210.059 (3)0.072 (4)0.079 (4)0.010 (3)0.017 (3)0.039 (3)
C220.047 (3)0.042 (2)0.079 (3)0.000 (2)0.015 (2)0.004 (2)
C230.029 (2)0.043 (2)0.048 (2)0.0003 (17)0.0047 (17)0.0004 (19)
C240.043 (3)0.059 (3)0.047 (2)0.005 (2)0.007 (2)0.001 (2)
C250.042 (3)0.055 (3)0.052 (2)0.0075 (19)0.006 (2)0.004 (2)
C260.038 (2)0.057 (3)0.053 (2)0.0044 (19)0.011 (2)0.000 (2)
C270.044 (2)0.058 (3)0.057 (2)0.007 (2)0.006 (2)0.006 (2)
C280.046 (3)0.053 (3)0.058 (3)0.003 (2)0.011 (2)0.014 (2)
C290.043 (2)0.049 (2)0.030 (2)0.003 (2)0.0061 (18)0.0008 (19)
C300.055 (3)0.046 (2)0.046 (2)0.004 (2)0.011 (2)0.000 (2)
C310.051 (3)0.060 (3)0.055 (3)0.010 (2)0.005 (2)0.005 (2)
C320.048 (3)0.076 (4)0.057 (3)0.006 (3)0.005 (2)0.008 (3)
C330.070 (3)0.052 (3)0.081 (3)0.016 (3)0.007 (3)0.005 (3)
C340.055 (3)0.050 (3)0.063 (3)0.005 (2)0.006 (2)0.005 (2)
B10.097 (5)0.082 (5)0.058 (4)0.019 (4)0.017 (4)0.007 (4)
F10.51 (4)0.118 (11)0.215 (15)0.165 (18)0.24 (2)0.071 (11)
F20.172 (13)0.28 (2)0.056 (5)0.081 (15)0.030 (6)0.058 (8)
F30.118 (11)0.34 (3)0.27 (2)0.130 (16)0.116 (13)0.21 (2)
F40.147 (3)0.091 (3)0.117 (3)0.043 (2)0.067 (2)0.009 (2)
F1'0.092 (7)0.099 (8)0.146 (9)0.029 (6)0.028 (7)0.014 (6)
F2'0.149 (10)0.142 (12)0.27 (2)0.004 (10)0.015 (15)0.137 (14)
F3'0.40 (4)0.24 (2)0.23 (2)0.17 (2)0.24 (2)0.118 (18)
Geometric parameters (Å, º) top
Ag1—S1i2.5884 (13)C18—C231.373 (6)
Ag1—S42.5985 (12)C18—C191.382 (6)
Ag1—S22.6300 (13)C18—H18A0.9300
Ag1—S3ii2.6772 (12)C19—C201.377 (7)
S1—C61.778 (4)C19—H19A0.9300
S1—C71.818 (4)C20—C211.388 (8)
S1—Ag1iii2.5884 (13)C20—H20A0.9300
S2—C121.790 (5)C21—C221.386 (7)
S2—C111.832 (4)C21—H21A0.9300
S3—C291.784 (4)C22—C231.386 (6)
S3—C281.831 (4)C22—H22A0.9300
S3—Ag1iv2.6772 (12)C24—C251.509 (6)
S4—C231.783 (4)C24—H24A0.9700
S4—C241.825 (4)C24—H24B0.9700
C1—C61.383 (6)C25—C261.526 (6)
C1—C21.405 (7)C25—H25A0.9700
C1—H1A0.9300C25—H25B0.9700
C2—C31.372 (9)C26—C271.514 (6)
C2—H2A0.9300C26—H26A0.9700
C3—C41.373 (9)C26—H26B0.9700
C3—H3A0.9300C27—C281.527 (6)
C4—C51.348 (8)C27—H27A0.9700
C4—H4A0.9300C27—H27B0.9700
C5—C61.375 (6)C28—H28A0.9700
C5—H5A0.9300C28—H28B0.9700
C7—C81.506 (5)C29—C341.380 (6)
C7—H7A0.9700C29—C301.392 (6)
C7—H7B0.9700C30—C311.377 (6)
C8—C91.515 (6)C30—H30A0.9300
C8—H8A0.9700C31—C321.355 (6)
C8—H8B0.9700C31—H31A0.9300
C9—C101.537 (6)C32—C331.365 (7)
C9—H9A0.9700C32—H32A0.9300
C9—H9B0.9700C33—C341.373 (6)
C10—C111.496 (6)C33—H33A0.9300
C10—H10A0.9700C34—H34A0.9300
C10—H10B0.9700B1—F21.302 (8)
C11—H11A0.9700B1—F2'1.307 (8)
C11—H11B0.9700B1—F1'1.307 (8)
C12—C171.372 (7)B1—F31.320 (8)
C12—C131.391 (6)B1—F3'1.332 (9)
C13—C141.383 (7)B1—F11.341 (9)
C13—H13A0.9300B1—F41.342 (6)
C14—C151.357 (8)F1—F2'1.22 (2)
C14—H14A0.9300F1—F1'1.42 (3)
C15—C161.363 (7)F2—F2'1.20 (2)
C15—H15A0.9300F2—F3'1.34 (3)
C16—C171.383 (7)F3—F3'1.12 (2)
C16—H16A0.9300F3—F1'1.28 (2)
C17—H17A0.9300
S1i—Ag1—S4122.83 (4)C20—C21—H21A119.8
S1i—Ag1—S2105.46 (3)C21—C22—C23119.4 (5)
S4—Ag1—S2120.91 (4)C21—C22—H22A120.3
S1i—Ag1—S3ii97.69 (4)C23—C22—H22A120.3
S4—Ag1—S3ii99.69 (3)C18—C23—C22119.9 (4)
S2—Ag1—S3ii105.81 (4)C18—C23—S4121.3 (3)
C6—S1—C7104.14 (19)C22—C23—S4118.8 (3)
C6—S1—Ag1iii111.46 (14)C25—C24—S4115.9 (3)
C7—S1—Ag1iii109.52 (13)C25—C24—H24A108.3
C12—S2—C11101.8 (2)S4—C24—H24A108.3
C12—S2—Ag1109.88 (14)C25—C24—H24B108.3
C11—S2—Ag1106.29 (14)S4—C24—H24B108.3
C29—S3—C28103.9 (2)H24A—C24—H24B107.4
C29—S3—Ag1iv101.43 (13)C24—C25—C26110.8 (3)
C28—S3—Ag1iv109.50 (15)C24—C25—H25A109.5
C23—S4—C24100.56 (19)C26—C25—H25A109.5
C23—S4—Ag1108.24 (13)C24—C25—H25B109.5
C24—S4—Ag1117.01 (15)C26—C25—H25B109.5
C6—C1—C2119.0 (5)H25A—C25—H25B108.1
C6—C1—H1A120.5C27—C26—C25112.8 (3)
C2—C1—H1A120.5C27—C26—H26A109.0
C3—C2—C1119.0 (6)C25—C26—H26A109.0
C3—C2—H2A120.5C27—C26—H26B109.0
C1—C2—H2A120.5C25—C26—H26B109.0
C2—C3—C4121.4 (6)H26A—C26—H26B107.8
C2—C3—H3A119.3C26—C27—C28115.1 (4)
C4—C3—H3A119.3C26—C27—H27A108.5
C5—C4—C3119.2 (6)C28—C27—H27A108.5
C5—C4—H4A120.4C26—C27—H27B108.5
C3—C4—H4A120.4C28—C27—H27B108.5
C4—C5—C6121.7 (5)H27A—C27—H27B107.5
C4—C5—H5A119.1C27—C28—S3109.6 (3)
C6—C5—H5A119.1C27—C28—H28A109.7
C5—C6—C1119.7 (4)S3—C28—H28A109.7
C5—C6—S1117.7 (4)C27—C28—H28B109.7
C1—C6—S1122.5 (3)S3—C28—H28B109.7
C8—C7—S1112.4 (3)H28A—C28—H28B108.2
C8—C7—H7A109.1C34—C29—C30118.9 (4)
S1—C7—H7A109.1C34—C29—S3124.1 (3)
C8—C7—H7B109.1C30—C29—S3116.8 (4)
S1—C7—H7B109.1C31—C30—C29119.9 (4)
H7A—C7—H7B107.9C31—C30—H30A120.1
C7—C8—C9114.3 (4)C29—C30—H30A120.1
C7—C8—H8A108.7C32—C31—C30120.9 (4)
C9—C8—H8A108.7C32—C31—H31A119.5
C7—C8—H8B108.7C30—C31—H31A119.5
C9—C8—H8B108.7C31—C32—C33119.3 (5)
H8A—C8—H8B107.6C31—C32—H32A120.4
C8—C9—C10110.3 (3)C33—C32—H32A120.4
C8—C9—H9A109.6C32—C33—C34121.4 (5)
C10—C9—H9A109.6C32—C33—H33A119.3
C8—C9—H9B109.6C34—C33—H33A119.3
C10—C9—H9B109.6C33—C34—C29119.6 (4)
H9A—C9—H9B108.1C33—C34—H34A120.2
C11—C10—C9114.2 (3)C29—C34—H34A120.2
C11—C10—H10A108.7F2—B1—F2'55.0 (10)
C9—C10—H10A108.7F2—B1—F1'145.2 (13)
C11—C10—H10B108.7F2'—B1—F1'104.7 (11)
C9—C10—H10B108.7F2—B1—F3106.9 (13)
H10A—C10—H10B107.6F2'—B1—F3124.0 (15)
C10—C11—S2113.8 (3)F1'—B1—F358.1 (12)
C10—C11—H11A108.8F2—B1—F3'61.0 (14)
S2—C11—H11A108.8F2'—B1—F3'106.0 (14)
C10—C11—H11B108.8F1'—B1—F3'107.3 (14)
S2—C11—H11B108.8F3—B1—F3'50.0 (12)
H11A—C11—H11B107.7F2—B1—F1109.0 (13)
C17—C12—C13119.0 (4)F2'—B1—F155.0 (11)
C17—C12—S2122.0 (3)F1'—B1—F165.1 (13)
C13—C12—S2119.0 (4)F3—B1—F1120.2 (17)
C14—C13—C12119.2 (5)F3'—B1—F1152.4 (10)
C14—C13—H13A120.4F2—B1—F4105.4 (10)
C12—C13—H13A120.4F2'—B1—F4121.4 (10)
C15—C14—C13121.2 (5)F1'—B1—F4109.4 (7)
C15—C14—H14A119.4F3—B1—F4114.3 (10)
C13—C14—H14A119.4F3'—B1—F4107.3 (8)
C14—C15—C16119.7 (5)F1—B1—F4100.2 (7)
C14—C15—H15A120.1F2'—F1—B161.1 (7)
C16—C15—H15A120.1F2'—F1—F1'102.6 (14)
C15—C16—C17120.2 (5)B1—F1—F1'56.3 (8)
C15—C16—H16A119.9F2'—F2—B162.7 (7)
C17—C16—H16A119.9F2'—F2—F3'111.9 (18)
C12—C17—C16120.6 (5)B1—F2—F3'60.6 (8)
C12—C17—H17A119.7F3'—F3—F1'124.9 (15)
C16—C17—H17A119.7F3'—F3—B165.5 (9)
C23—C18—C19120.8 (4)F1'—F3—B160.4 (8)
C23—C18—H18A119.6F3—F1'—B161.5 (7)
C19—C18—H18A119.6F3—F1'—F1117.2 (11)
C20—C19—C18119.7 (5)B1—F1'—F158.6 (8)
C20—C19—H19A120.1F2—F2'—F1124.8 (10)
C18—C19—H19A120.1F2—F2'—B162.3 (7)
C19—C20—C21119.8 (5)F1—F2'—B163.9 (7)
C19—C20—H20A120.1F3—F3'—B164.5 (8)
C21—C20—H20A120.1F3—F3'—F2117.7 (16)
C22—C21—C20120.3 (5)B1—F3'—F258.4 (9)
C22—C21—H21A119.8
S1i—Ag1—S2—C1267.04 (15)F1'—B1—F1—F2'131.8 (14)
S4—Ag1—S2—C1278.17 (15)F3—B1—F1—F2'112.6 (18)
S3ii—Ag1—S2—C12169.90 (14)F3'—B1—F1—F2'52 (4)
S1i—Ag1—S2—C11176.41 (16)F4—B1—F1—F2'121.4 (13)
S4—Ag1—S2—C1131.21 (16)F2—B1—F1—F1'142.9 (14)
S3ii—Ag1—S2—C1180.72 (16)F2'—B1—F1—F1'131.8 (14)
S1i—Ag1—S4—C2374.36 (14)F3—B1—F1—F1'19.2 (13)
S2—Ag1—S4—C2364.76 (14)F3'—B1—F1—F1'80 (4)
S3ii—Ag1—S4—C23179.87 (13)F4—B1—F1—F1'106.8 (8)
S1i—Ag1—S4—C2438.26 (16)F1'—B1—F2—F2'62 (2)
S2—Ag1—S4—C24177.38 (16)F3—B1—F2—F2'120 (2)
S3ii—Ag1—S4—C2467.52 (16)F3'—B1—F2—F2'141 (2)
C6—C1—C2—C31.4 (7)F1—B1—F2—F2'11 (2)
C1—C2—C3—C42.5 (9)F4—B1—F2—F2'117.8 (15)
C2—C3—C4—C52.2 (9)F2'—B1—F2—F3'141 (2)
C3—C4—C5—C60.8 (8)F1'—B1—F2—F3'78 (2)
C4—C5—C6—C10.3 (7)F3—B1—F2—F3'20.5 (16)
C4—C5—C6—S1176.1 (4)F1—B1—F2—F3'151.8 (13)
C2—C1—C6—C50.0 (6)F4—B1—F2—F3'101.5 (10)
C2—C1—C6—S1176.2 (3)F2—B1—F3—F3'23.6 (19)
C7—S1—C6—C5132.2 (3)F2'—B1—F3—F3'82 (2)
Ag1iii—S1—C6—C5109.8 (3)F1'—B1—F3—F3'169 (2)
C7—S1—C6—C151.5 (4)F1—B1—F3—F3'148.3 (17)
Ag1iii—S1—C6—C166.5 (4)F4—B1—F3—F3'92.6 (14)
C6—S1—C7—C868.4 (4)F2—B1—F3—F1'145.3 (14)
Ag1iii—S1—C7—C8172.3 (3)F2'—B1—F3—F1'86.5 (17)
S1—C7—C8—C9171.3 (3)F3'—B1—F3—F1'169 (2)
C7—C8—C9—C10178.0 (4)F1—B1—F3—F1'20.6 (16)
C8—C9—C10—C11171.0 (4)F4—B1—F3—F1'98.5 (14)
C9—C10—C11—S2174.3 (3)F3'—F3—F1'—B112 (3)
C12—S2—C11—C1088.1 (3)F3'—F3—F1'—F16 (4)
Ag1—S2—C11—C1026.9 (3)B1—F3—F1'—F118.8 (14)
C11—S2—C12—C1792.0 (4)F2—B1—F1'—F373 (2)
Ag1—S2—C12—C1720.4 (4)F2'—B1—F1'—F3121.2 (18)
C11—S2—C12—C1388.0 (4)F3'—B1—F1'—F38.9 (19)
Ag1—S2—C12—C13159.7 (3)F1—B1—F1'—F3160.4 (15)
C17—C12—C13—C140.1 (7)F4—B1—F1'—F3107.2 (12)
S2—C12—C13—C14179.9 (4)F2—B1—F1'—F188 (2)
C12—C13—C14—C150.5 (9)F2'—B1—F1'—F139.1 (12)
C13—C14—C15—C160.5 (9)F3—B1—F1'—F1160.4 (15)
C14—C15—C16—C170.1 (8)F3'—B1—F1'—F1151.5 (12)
C13—C12—C17—C160.3 (7)F4—B1—F1'—F192.4 (8)
S2—C12—C17—C16179.7 (3)F2'—F1—F1'—F322.6 (19)
C15—C16—C17—C120.3 (7)B1—F1—F1'—F319.4 (15)
C23—C18—C19—C200.8 (6)F2'—F1—F1'—B142.0 (10)
C18—C19—C20—C210.5 (7)B1—F2—F2'—F114 (3)
C19—C20—C21—C221.8 (7)F3'—F2—F2'—F151 (4)
C20—C21—C22—C231.7 (7)F3'—F2—F2'—B136.5 (14)
C19—C18—C23—C220.9 (6)B1—F1—F2'—F214 (3)
C19—C18—C23—S4178.1 (3)F1'—F1—F2'—F253 (3)
C21—C22—C23—C180.3 (6)F1'—F1—F2'—B139.5 (8)
C21—C22—C23—S4179.4 (4)F1'—B1—F2'—F2148.5 (15)
C24—S4—C23—C1891.5 (3)F3—B1—F2'—F287 (2)
Ag1—S4—C23—C1831.7 (3)F3'—B1—F2'—F235 (2)
C24—S4—C23—C2289.4 (4)F1—B1—F2'—F2167 (2)
Ag1—S4—C23—C22147.4 (3)F4—B1—F2'—F287.3 (18)
C23—S4—C24—C2570.6 (4)F2—B1—F2'—F1167 (2)
Ag1—S4—C24—C2546.3 (4)F1'—B1—F2'—F144.3 (16)
S4—C24—C25—C26175.6 (3)F3—B1—F2'—F1105 (2)
C24—C25—C26—C27178.2 (4)F3'—B1—F2'—F1157.6 (17)
C25—C26—C27—C28175.5 (4)F4—B1—F2'—F179.9 (14)
C26—C27—C28—S356.3 (4)F1'—F3—F3'—B112 (2)
C29—S3—C28—C27171.6 (3)F1'—F3—F3'—F213 (4)
Ag1iv—S3—C28—C2763.9 (3)B1—F3—F3'—F225.0 (15)
C28—S3—C29—C3437.3 (4)F2—B1—F3'—F3154.0 (19)
Ag1iv—S3—C29—C3476.4 (4)F2'—B1—F3'—F3121 (2)
C28—S3—C29—C30147.7 (3)F1'—B1—F3'—F310 (2)
Ag1iv—S3—C29—C3098.7 (3)F1—B1—F3'—F379 (4)
C34—C29—C30—C311.4 (6)F4—B1—F3'—F3107.6 (15)
S3—C29—C30—C31173.9 (4)F2'—B1—F3'—F232.7 (17)
C29—C30—C31—C321.1 (7)F1'—B1—F3'—F2144.1 (16)
C30—C31—C32—C330.1 (8)F3—B1—F3'—F2154.0 (19)
C31—C32—C33—C340.6 (8)F1—B1—F3'—F275 (4)
C32—C33—C34—C290.3 (8)F4—B1—F3'—F298.4 (12)
C30—C29—C34—C330.7 (7)F2'—F2—F3'—F311 (3)
S3—C29—C34—C33174.3 (4)B1—F2—F3'—F326.6 (17)
F2—B1—F1—F2'11 (2)F2'—F2—F3'—B137.4 (15)
Symmetry codes: (i) x, y1, z; (ii) x+1, y, z; (iii) x, y+1, z; (iv) x1, y, z.
 

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds