(4,4'-Di­methyl-2,2'-bi­pyridine)(ethynyl­benzene)(tri­phenyl­phosphine)­platinum(II) hexa­fluoro­antimonate

The reaction between the metal diphosphine [Ag(PPh₃)₂(MeCN)](SbF₆) and the metal acetyl­ide compound Pt(dmbpy)(C₂Ph)₂ (dmbpy is 4,4'-di­methyl-2,2'-bi­pyridine) gave the title compound, Pt(dmbpy)(C₂Ph)·SbF₆ or [Pt(C₈H₅)(C₁₈H₁₅P)(C₁₂H₁₂N₂)](SbF₆). The Pt center is four-coordinated and exhibits a distorted square-planar coordin­ation geometry.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.013 Å
• R factor = 0.041
• wR factor = 0.110
• Data-to-parameter ratio = 14.2

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



PLAT_371  Alert C Long   C(sp2)-C(sp1) Bond  C(2)   -   C(3)   =       1.43 Ang.

PLAT_601  Alert C Structure Contains Solvent Accessible VOIDS of      36.00 A   3


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 2 Alert Level C = Please check

---

S1. Comment

Transition metal acetylide complexes are of considerable interest because of their potential applications in many fields of materials chemistry, including luminiscent materials and conducting polymers (Chan et al., 2001). We are interested in the design of photoluminescent heterometallic cluster complexes by self-assembly between two metal components, one with alkynyl ligands and the other with vacant coordination sites. Thus, the reaction between Pt(dmbpy)(C₂Ph)₂, with two alkynyl ligands, and [Ag(PPh₃)₂(MeCN)]⁺, with a vacant coordination site, was expected to afford a Pt–Ag heteronuclear species. However, the product isolated from the reaction was the title compound, (I). A perspective drawing of the complex with atomic numbering scheme is depicted in Fig. 1 and selected geometric parameters are presented in Table 1.

The Pt atom is located in a distorted square-planar coordination geometry. The Pt—P distance is 2.246 (2) Å, which is slighlty shorter than that observed in the complex of PtCuCl(C₂Bu)₂(PMe₂Ph)₂ [2.300 (3) Å; Yamazaki & Deeming, 1993]. The Pt—N distances are 2.068 (6) and 2.094 (6) Å, which are similar to those observed in the complex of Pt(1,10-phenanthroline)(C₉H₇)₂ (Hissler et al., 2000).

S2. Experimental

The starting compounds Pt(dmbpy)(C₂Ph)₂ (Chan et al., 2001) and [Ag(PPh₃)₂(MeCN)](SbF₆) were prepared according to literature procedures (Bachman et al., 1998). Pt(dmbpy)(C₂Ph)₂ and [Ag(PPh₃)₂(MeCN)](SbF₆) were reacted, in an equimolar ratio, in dichloromethane under anaerobic conditions for 24 h. The solvent was then reduced in vacuo. Well shaped yellow crystals suitable for X-ray diffraction analysis were grown by slow diffusion of diethyl ether into the dichloromethane solution.

S3. Refinement

All H atoms were included in calculated positions with C—H distances of 0.93 and 0.96 Å (methyl). They were included in the refinement in riding-motion approximation, with U_iso = 1.2U_eq (1.5U_eq for methyl) of the carrier atom.

Computing details

Data collection: SMART (Siemens, 1996); cell refinement: SMART and SAINT (Siemens, 1994); data reduction: XPREP (Siemens, 1994); program(s) used to solve structure: SHELXTL (Siemens, 1994); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures

Fig. 1. A view of the compound with the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.

(4,4'-dimethyl-2,2'-bipyridine)(ethynylbenzene)(triphenylphosphine)platinum(II) hexafluoroantimonate

Crystal data

[Pt(C8H5)(C18H15P)(C12H12N2)](SbF6)	F(000) = 1888
Mr = 978.47	Dx = 1.814 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 4988 reflections
a = 14.4131 (4) Å	θ = 1.5–25.1°
b = 10.1848 (2) Å	µ = 4.76 mm^−1
c = 24.7099 (7) Å	T = 293 K
β = 98.915 (1)°	Block, yellow
V = 3583.46 (16) Å^3	0.50 × 0.30 × 0.25 mm
Z = 4

Data collection

Siemens SMART CCD diffractometer	6291 independent reflections
Radiation source: fine-focus sealed tube	4473 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.024
ω scans	θmax = 25.1°, θmin = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −7→17
Tmin = 0.194, Tmax = 0.304	k = −9→12
10524 measured reflections	l = −29→29

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.041	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.110	H-atom parameters constrained
S = 1.19	w = 1/[σ^2(Fo^2) + (0.0387P)^2 + 9.8193P] where P = (Fo^2 + 2Fc^2)/3
6291 reflections	(Δ/σ)max = 0.002
442 parameters	Δρmax = 1.04 e Å^−3
0 restraints	Δρmin = −0.61 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt	0.11648 (2)	0.00002 (3)	0.094070 (11)	0.04068 (11)
Sb	0.49147 (5)	0.18053 (7)	0.10878 (3)	0.06338 (19)
P	0.06876 (14)	−0.0455 (2)	0.17434 (8)	0.0424 (5)
F1	0.4859 (4)	0.0352 (6)	0.0637 (3)	0.101 (2)
F2	0.6135 (6)	0.1462 (11)	0.1340 (6)	0.227 (7)
F3	0.5005 (5)	0.3269 (7)	0.1539 (2)	0.104 (2)
F4	0.3707 (6)	0.2193 (13)	0.0842 (5)	0.219 (6)
F5	0.4544 (11)	0.0870 (10)	0.1626 (4)	0.229 (7)
F6	0.5241 (11)	0.2795 (10)	0.0542 (4)	0.219 (6)
N1	0.1700 (4)	0.0471 (6)	0.0236 (3)	0.0418 (15)
N2	0.2270 (4)	−0.1346 (6)	0.0971 (2)	0.0416 (15)
C1	0.0150 (6)	0.1284 (8)	0.0793 (3)	0.0470 (19)
C2	−0.0466 (6)	0.2070 (8)	0.0645 (3)	0.050 (2)
C3	−0.1147 (5)	0.3057 (8)	0.0450 (3)	0.047 (2)
C4	−0.1952 (6)	0.3232 (9)	0.0678 (4)	0.063 (2)
H4A	−0.2067	0.2677	0.0959	0.075*
C5	−0.2598 (7)	0.4219 (12)	0.0500 (5)	0.081 (3)
H5A	−0.3133	0.4342	0.0661	0.098*
C6	−0.2414 (9)	0.5006 (11)	0.0074 (6)	0.094 (4)
H6A	−0.2845	0.5656	−0.0056	0.113*
C7	−0.1622 (10)	0.4866 (11)	−0.0166 (5)	0.084 (3)
H7A	−0.1513	0.5414	−0.0450	0.101*
C8	−0.0995 (7)	0.3899 (9)	0.0026 (4)	0.063 (2)
H8A	−0.0453	0.3801	−0.0131	0.076*
C11	0.1695 (5)	−0.0594 (8)	0.2290 (3)	0.0410 (18)
C12	0.1662 (6)	−0.1371 (8)	0.2743 (3)	0.051 (2)
H12A	0.1114	−0.1825	0.2776	0.061*
C13	0.2437 (6)	−0.1483 (9)	0.3150 (3)	0.057 (2)
H13A	0.2403	−0.1996	0.3457	0.069*
C14	0.3252 (6)	−0.0837 (9)	0.3098 (4)	0.057 (2)
H14A	0.3775	−0.0924	0.3368	0.069*
C15	0.3297 (6)	−0.0068 (9)	0.2654 (4)	0.063 (2)
H15A	0.3849	0.0381	0.2624	0.075*
C16	0.2525 (6)	0.0054 (8)	0.2242 (3)	0.054 (2)
H16A	0.2565	0.0569	0.1936	0.065*
C21	−0.0079 (6)	0.0718 (8)	0.2017 (3)	0.049 (2)
C22	0.0280 (7)	0.1662 (9)	0.2385 (4)	0.063 (2)
H22A	0.0926	0.1718	0.2494	0.076*
C23	−0.0314 (9)	0.2547 (11)	0.2598 (4)	0.084 (3)
H23A	−0.0064	0.3178	0.2851	0.101*
C24	−0.1256 (9)	0.2478 (12)	0.2434 (5)	0.081 (3)
H24A	−0.1649	0.3068	0.2574	0.097*
C25	−0.1635 (7)	0.1547 (12)	0.2062 (5)	0.080 (3)
H25A	−0.2282	0.1497	0.1956	0.095*
C26	−0.1043 (6)	0.0682 (10)	0.1846 (4)	0.066 (3)
H26A	−0.1295	0.0071	0.1584	0.079*
C31	0.0069 (5)	−0.2006 (8)	0.1732 (3)	0.0453 (19)
C32	−0.0498 (6)	−0.2332 (10)	0.2123 (4)	0.061 (2)
H32A	−0.0575	−0.1739	0.2399	0.073*
C33	−0.0944 (6)	−0.3540 (10)	0.2100 (4)	0.067 (3)
H33A	−0.1318	−0.3754	0.2361	0.081*
C34	−0.0838 (7)	−0.4421 (11)	0.1695 (4)	0.070 (3)
H34A	−0.1132	−0.5235	0.1687	0.084*
C35	−0.0305 (6)	−0.4107 (9)	0.1308 (4)	0.061 (2)
H35A	−0.0246	−0.4700	0.1029	0.073*
C36	0.0155 (6)	−0.2903 (8)	0.1325 (3)	0.050 (2)
H36A	0.0524	−0.2702	0.1059	0.060*
C42	0.2498 (5)	−0.0163 (7)	0.0162 (3)	0.0397 (18)
C43	0.2982 (6)	0.0174 (8)	−0.0258 (3)	0.052 (2)
H43A	0.3529	−0.0274	−0.0299	0.063*
C44	0.2660 (6)	0.1170 (9)	−0.0618 (3)	0.050 (2)
C45	0.1851 (6)	0.1797 (9)	−0.0541 (3)	0.053 (2)
H45A	0.1614	0.2475	−0.0774	0.064*
C46	0.1388 (6)	0.1427 (8)	−0.0120 (3)	0.052 (2)
H46A	0.0834	0.1858	−0.0080	0.063*
C47	0.3179 (7)	0.1593 (11)	−0.1071 (4)	0.078 (3)
H47A	0.3721	0.1045	−0.1072	0.118*
H47B	0.3374	0.2490	−0.1015	0.118*
H47C	0.2774	0.1513	−0.1417	0.118*
C52	0.2799 (5)	−0.1199 (7)	0.0564 (3)	0.0433 (18)
C53	0.3537 (5)	−0.2008 (8)	0.0522 (4)	0.051 (2)
H53A	0.3887	−0.1869	0.0241	0.062*
C54	0.3782 (6)	−0.3034 (8)	0.0887 (4)	0.056 (2)
C55	0.3234 (6)	−0.3164 (9)	0.1299 (4)	0.055 (2)
H55A	0.3367	−0.3830	0.1557	0.066*
C56	0.2498 (6)	−0.2325 (8)	0.1332 (3)	0.051 (2)
H56A	0.2146	−0.2438	0.1614	0.061*
C57	0.4592 (7)	−0.3934 (10)	0.0842 (5)	0.076 (3)
H57A	0.4650	−0.4569	0.1132	0.114*
H57B	0.5161	−0.3431	0.0869	0.114*
H57C	0.4484	−0.4379	0.0495	0.114*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt	0.04262 (17)	0.04339 (18)	0.03631 (16)	−0.00069 (16)	0.00701 (11)	0.00109 (15)
Sb	0.0604 (4)	0.0776 (4)	0.0557 (4)	−0.0025 (3)	0.0203 (3)	−0.0065 (4)
P	0.0424 (11)	0.0477 (12)	0.0370 (11)	−0.0083 (9)	0.0059 (9)	−0.0027 (9)
F1	0.080 (4)	0.101 (5)	0.119 (5)	−0.007 (3)	0.011 (4)	−0.046 (4)
F2	0.090 (6)	0.221 (11)	0.335 (15)	0.051 (6)	−0.076 (7)	−0.166 (11)
F3	0.142 (6)	0.099 (5)	0.076 (4)	−0.014 (4)	0.036 (4)	−0.026 (4)
F4	0.097 (6)	0.292 (14)	0.250 (12)	0.068 (7)	−0.030 (7)	−0.151 (11)
F5	0.43 (2)	0.149 (9)	0.139 (8)	−0.116 (11)	0.137 (11)	0.009 (7)
F6	0.412 (18)	0.148 (8)	0.132 (8)	−0.053 (10)	0.159 (10)	−0.022 (6)
N1	0.042 (4)	0.046 (4)	0.039 (4)	0.002 (3)	0.009 (3)	0.006 (3)
N2	0.045 (4)	0.043 (4)	0.036 (3)	−0.001 (3)	0.006 (3)	−0.002 (3)
C1	0.053 (5)	0.051 (5)	0.038 (4)	−0.003 (4)	0.011 (4)	−0.004 (4)
C2	0.054 (5)	0.045 (5)	0.051 (5)	0.001 (4)	0.012 (4)	−0.005 (4)
C3	0.042 (4)	0.050 (5)	0.046 (5)	0.003 (4)	−0.004 (4)	−0.008 (4)
C4	0.049 (5)	0.054 (6)	0.084 (7)	0.002 (5)	0.005 (5)	−0.006 (5)
C5	0.056 (6)	0.078 (8)	0.106 (9)	0.008 (6)	0.001 (6)	−0.016 (7)
C6	0.091 (9)	0.055 (6)	0.119 (10)	0.014 (7)	−0.044 (8)	−0.017 (8)
C7	0.104 (9)	0.068 (7)	0.072 (7)	0.000 (7)	−0.011 (7)	0.005 (6)
C8	0.070 (6)	0.063 (6)	0.055 (6)	0.003 (5)	0.003 (5)	−0.003 (5)
C11	0.044 (4)	0.040 (4)	0.040 (4)	−0.008 (4)	0.008 (3)	−0.002 (4)
C12	0.053 (5)	0.059 (5)	0.042 (5)	−0.017 (4)	0.010 (4)	−0.002 (4)
C13	0.063 (6)	0.071 (6)	0.038 (5)	−0.005 (5)	0.006 (4)	0.004 (4)
C14	0.049 (5)	0.067 (6)	0.052 (5)	−0.008 (5)	−0.006 (4)	0.004 (5)
C15	0.049 (5)	0.060 (6)	0.079 (6)	−0.019 (5)	0.009 (5)	−0.002 (6)
C16	0.059 (5)	0.053 (5)	0.048 (5)	−0.014 (5)	0.004 (4)	0.002 (5)
C21	0.053 (5)	0.052 (5)	0.046 (5)	0.003 (4)	0.022 (4)	0.005 (4)
C22	0.072 (6)	0.056 (6)	0.059 (6)	−0.001 (5)	0.004 (5)	−0.010 (5)
C23	0.121 (10)	0.064 (7)	0.068 (7)	0.008 (7)	0.017 (7)	−0.012 (6)
C24	0.083 (8)	0.091 (8)	0.075 (8)	0.020 (7)	0.036 (6)	0.004 (7)
C25	0.050 (6)	0.111 (9)	0.083 (7)	0.013 (6)	0.029 (5)	0.005 (7)
C26	0.049 (5)	0.077 (7)	0.072 (6)	−0.005 (5)	0.016 (5)	−0.008 (6)
C31	0.044 (4)	0.049 (5)	0.040 (4)	−0.006 (4)	−0.001 (4)	0.002 (4)
C32	0.057 (6)	0.072 (6)	0.051 (5)	−0.020 (5)	0.002 (4)	−0.006 (5)
C33	0.057 (6)	0.083 (7)	0.060 (6)	−0.028 (5)	0.004 (5)	0.022 (6)
C34	0.075 (7)	0.060 (6)	0.065 (7)	−0.022 (5)	−0.017 (5)	0.009 (6)
C35	0.069 (6)	0.052 (6)	0.053 (5)	−0.005 (5)	−0.017 (5)	0.000 (4)
C36	0.049 (5)	0.049 (5)	0.047 (5)	−0.006 (4)	−0.005 (4)	−0.001 (4)
C42	0.038 (4)	0.048 (5)	0.033 (4)	0.001 (4)	0.005 (3)	−0.003 (4)
C43	0.049 (5)	0.059 (6)	0.051 (5)	0.008 (4)	0.016 (4)	0.003 (4)
C44	0.052 (5)	0.058 (5)	0.040 (5)	0.004 (4)	0.004 (4)	0.006 (4)
C45	0.055 (5)	0.059 (5)	0.046 (5)	0.007 (4)	0.008 (4)	0.022 (4)
C46	0.050 (5)	0.056 (5)	0.052 (5)	0.010 (4)	0.011 (4)	0.009 (4)
C47	0.068 (6)	0.096 (8)	0.078 (7)	0.010 (6)	0.036 (5)	0.040 (6)
C52	0.045 (4)	0.039 (4)	0.044 (4)	−0.005 (4)	0.001 (4)	0.008 (4)
C53	0.041 (4)	0.056 (5)	0.059 (5)	0.010 (4)	0.014 (4)	0.003 (4)
C54	0.058 (5)	0.044 (5)	0.063 (6)	0.007 (4)	−0.003 (4)	0.001 (5)
C55	0.060 (5)	0.045 (5)	0.056 (5)	0.001 (4)	−0.003 (4)	0.004 (4)
C56	0.049 (5)	0.053 (5)	0.050 (5)	0.001 (4)	0.004 (4)	0.008 (4)
C57	0.072 (7)	0.057 (6)	0.097 (8)	0.026 (5)	0.004 (6)	0.009 (6)

Geometric parameters (Å, º)

Pt—C1	1.954 (9)	C22—C23	1.401 (13)
Pt—N1	2.068 (6)	C22—H22A	0.9300
Pt—N2	2.094 (6)	C23—C24	1.357 (15)
Pt—P	2.246 (2)	C23—H23A	0.9300
Sb—F5	1.783 (8)	C24—C25	1.372 (15)
Sb—F4	1.797 (8)	C24—H24A	0.9300
Sb—F6	1.803 (9)	C25—C26	1.389 (13)
Sb—F2	1.807 (7)	C25—H25A	0.9300
Sb—F1	1.847 (6)	C26—H26A	0.9300
Sb—F3	1.854 (6)	C31—C36	1.378 (11)
P—C31	1.812 (8)	C31—C32	1.400 (11)
P—C21	1.827 (8)	C32—C33	1.385 (12)
P—C11	1.828 (8)	C32—H32A	0.9300
N1—C46	1.341 (10)	C33—C34	1.369 (14)
N1—C42	1.356 (9)	C33—H33A	0.9300
N2—C56	1.343 (9)	C34—C35	1.356 (13)
N2—C52	1.362 (9)	C34—H34A	0.9300
C1—C2	1.209 (11)	C35—C36	1.391 (11)
C2—C3	1.435 (11)	C35—H35A	0.9300
C3—C4	1.378 (11)	C36—H36A	0.9300
C3—C8	1.397 (12)	C42—C43	1.380 (11)
C4—C5	1.395 (13)	C42—C52	1.468 (10)
C4—H4A	0.9300	C43—C44	1.381 (11)
C5—C6	1.381 (17)	C43—H43A	0.9300
C5—H5A	0.9300	C44—C45	1.368 (11)
C6—C7	1.373 (18)	C44—C47	1.505 (11)
C6—H6A	0.9300	C45—C46	1.372 (11)
C7—C8	1.370 (14)	C45—H45A	0.9300
C7—H7A	0.9300	C46—H46A	0.9300
C8—H8A	0.9300	C47—H47A	0.9600
C11—C12	1.378 (10)	C47—H47B	0.9600
C11—C16	1.387 (11)	C47—H47C	0.9600
C12—C13	1.387 (11)	C52—C53	1.363 (10)
C12—H12A	0.9300	C53—C54	1.390 (11)
C13—C14	1.370 (11)	C53—H53A	0.9300
C13—H13A	0.9300	C54—C55	1.387 (12)
C14—C15	1.359 (12)	C54—C57	1.503 (12)
C14—H14A	0.9300	C55—C56	1.375 (11)
C15—C16	1.392 (12)	C55—H55A	0.9300
C15—H15A	0.9300	C56—H56A	0.9300
C16—H16A	0.9300	C57—H57A	0.9600
C21—C22	1.367 (12)	C57—H57B	0.9600
C21—C26	1.389 (12)	C57—H57C	0.9600
C1—Pt—N1	93.0 (3)	C21—C22—H22A	119.6
C1—Pt—N2	171.2 (3)	C23—C22—H22A	119.6
N1—Pt—N2	78.6 (2)	C24—C23—C22	119.7 (10)
C1—Pt—P	88.9 (2)	C24—C23—H23A	120.1
N1—Pt—P	175.58 (18)	C22—C23—H23A	120.1
N2—Pt—P	99.68 (18)	C23—C24—C25	120.8 (10)
F5—Sb—F4	89.0 (7)	C23—C24—H24A	119.6
F5—Sb—F6	177.4 (7)	C25—C24—H24A	119.6
F4—Sb—F6	88.6 (7)	C24—C25—C26	119.4 (10)
F5—Sb—F2	91.6 (7)	C24—C25—H25A	120.3
F4—Sb—F2	178.4 (5)	C26—C25—H25A	120.3
F6—Sb—F2	90.7 (7)	C21—C26—C25	120.7 (10)
F5—Sb—F1	91.8 (4)	C21—C26—H26A	119.6
F4—Sb—F1	91.3 (4)	C25—C26—H26A	119.6
F6—Sb—F1	89.3 (4)	C36—C31—C32	118.4 (8)
F2—Sb—F1	90.1 (4)	C36—C31—P	119.3 (6)
F5—Sb—F3	89.0 (4)	C32—C31—P	122.3 (6)
F4—Sb—F3	90.0 (4)	C33—C32—C31	119.9 (9)
F6—Sb—F3	89.9 (4)	C33—C32—H32A	120.0
F2—Sb—F3	88.5 (4)	C31—C32—H32A	120.0
F1—Sb—F3	178.4 (3)	C34—C33—C32	120.6 (9)
C31—P—C21	104.6 (4)	C34—C33—H33A	119.7
C31—P—C11	106.1 (4)	C32—C33—H33A	119.7
C21—P—C11	103.5 (4)	C35—C34—C33	120.0 (9)
C31—P—Pt	112.5 (3)	C35—C34—H34A	120.0
C21—P—Pt	118.6 (3)	C33—C34—H34A	120.0
C11—P—Pt	110.6 (3)	C34—C35—C36	120.4 (9)
C46—N1—C42	117.6 (7)	C34—C35—H35A	119.8
C46—N1—Pt	126.1 (5)	C36—C35—H35A	119.8
C42—N1—Pt	116.0 (5)	C31—C36—C35	120.7 (8)
C56—N2—C52	117.7 (7)	C31—C36—H36A	119.7
C56—N2—Pt	128.0 (5)	C35—C36—H36A	119.7
C52—N2—Pt	114.2 (5)	N1—C42—C43	121.4 (7)
C2—C1—Pt	173.2 (7)	N1—C42—C52	114.8 (7)
C1—C2—C3	175.7 (9)	C43—C42—C52	123.8 (7)
C4—C3—C8	117.9 (8)	C42—C43—C44	120.5 (8)
C4—C3—C2	121.9 (8)	C42—C43—H43A	119.7
C8—C3—C2	120.2 (8)	C44—C43—H43A	119.7
C3—C4—C5	121.8 (10)	C45—C44—C43	117.5 (8)
C3—C4—H4A	119.1	C45—C44—C47	120.2 (8)
C5—C4—H4A	119.1	C43—C44—C47	122.2 (8)
C6—C5—C4	117.5 (11)	C44—C45—C46	120.1 (8)
C6—C5—H5A	121.3	C44—C45—H45A	119.9
C4—C5—H5A	121.3	C46—C45—H45A	119.9
C7—C6—C5	122.6 (11)	N1—C46—C45	122.9 (8)
C7—C6—H6A	118.7	N1—C46—H46A	118.6
C5—C6—H6A	118.7	C45—C46—H46A	118.6
C8—C7—C6	118.3 (11)	C44—C47—H47A	109.5
C8—C7—H7A	120.8	C44—C47—H47B	109.5
C6—C7—H7A	120.8	H47A—C47—H47B	109.5
C7—C8—C3	121.9 (10)	C44—C47—H47C	109.5
C7—C8—H8A	119.1	H47A—C47—H47C	109.5
C3—C8—H8A	119.1	H47B—C47—H47C	109.5
C12—C11—C16	118.7 (7)	N2—C52—C53	121.5 (7)
C12—C11—P	121.4 (6)	N2—C52—C42	116.0 (7)
C16—C11—P	119.8 (6)	C53—C52—C42	122.4 (7)
C11—C12—C13	120.7 (8)	C52—C53—C54	121.9 (8)
C11—C12—H12A	119.6	C52—C53—H53A	119.1
C13—C12—H12A	119.6	C54—C53—H53A	119.1
C14—C13—C12	119.9 (8)	C55—C54—C53	115.6 (8)
C14—C13—H13A	120.0	C55—C54—C57	122.3 (8)
C12—C13—H13A	120.0	C53—C54—C57	122.2 (9)
C15—C14—C13	120.1 (8)	C56—C55—C54	121.1 (8)
C15—C14—H14A	120.0	C56—C55—H55A	119.4
C13—C14—H14A	120.0	C54—C55—H55A	119.4
C14—C15—C16	120.5 (8)	N2—C56—C55	122.2 (8)
C14—C15—H15A	119.7	N2—C56—H56A	118.9
C16—C15—H15A	119.7	C55—C56—H56A	118.9
C11—C16—C15	119.9 (8)	C54—C57—H57A	109.5
C11—C16—H16A	120.0	C54—C57—H57B	109.5
C15—C16—H16A	120.0	H57A—C57—H57B	109.5
C22—C21—C26	118.6 (8)	C54—C57—H57C	109.5
C22—C21—P	121.2 (7)	H57A—C57—H57C	109.5
C26—C21—P	120.2 (7)	H57B—C57—H57C	109.5
C21—C22—C23	120.8 (10)