Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807004989/lh2304sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807004989/lh2304Isup2.hkl |
CCDC reference: 640413
Data collection: COLLECT (Nonius, 1998); cell refinement: EVALCCD (Duisenberg et al., 2003); data reduction: EVALCCD; program(s) used to solve structure: using known coordinates (Reference?); program(s) used to refine structure: SHELXTL (Sheldrick, 2001); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXTL and local programs.
[Re6Se8(C2H3N)2(C6H15P)4](SbF6)2 | F(000) = 2480 |
Mr = 2775.09 | Dx = 3.185 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 17172 reflections |
a = 13.010 (3) Å | θ = 2.5–27.5° |
b = 17.155 (3) Å | µ = 18.62 mm−1 |
c = 13.438 (3) Å | T = 150 K |
β = 105.24 (3)° | Prism, orange |
V = 2893.8 (10) Å3 | 0.62 × 0.42 × 0.40 mm |
Z = 2 |
Nonius KappaCCD area-detector diffractometer | 6605 independent reflections |
Radiation source: sealed tube | 5470 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.039 |
φ and ω scans | θmax = 27.5°, θmin = 4.6° |
Absorption correction: gaussian (SADABS; Sheldrick, 2006) | h = −16→16 |
Tmin = 0.031, Tmax = 0.050 | k = −21→22 |
30352 measured reflections | l = −14→17 |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.024 | H-atom parameters constrained |
wR(F2) = 0.045 | w = 1/[σ2(Fo2) + 7.3346P] where P = (Fo2 + 2Fc2)/3 |
S = 1.14 | (Δ/σ)max = 0.002 |
6605 reflections | Δρmax = 0.80 e Å−3 |
288 parameters | Δρmin = −1.01 e Å−3 |
0 restraints | Extinction correction: SHELXTL (Sheldrick, 2001), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: using known coordinates | Extinction coefficient: 0.000341 (16) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Re1 | 0.639696 (13) | 0.533058 (11) | 0.560393 (14) | 0.01103 (5) | |
Re2 | 0.449147 (14) | 0.598005 (11) | 0.524497 (14) | 0.01107 (5) | |
Re3 | 0.511667 (14) | 0.533872 (11) | 0.372036 (14) | 0.01126 (5) | |
Se1 | 0.66998 (3) | 0.40526 (3) | 0.65705 (4) | 0.01443 (10) | |
Se2 | 0.57342 (4) | 0.59239 (3) | 0.70395 (4) | 0.01448 (10) | |
Se3 | 0.69244 (4) | 0.47042 (3) | 0.41186 (4) | 0.01476 (10) | |
Se4 | 0.59530 (4) | 0.65752 (3) | 0.45748 (4) | 0.01462 (10) | |
P1 | 0.82377 (9) | 0.57933 (7) | 0.64057 (10) | 0.0149 (3) | |
P2 | 0.37905 (9) | 0.72502 (7) | 0.56445 (10) | 0.0146 (3) | |
N1 | 0.5254 (3) | 0.5711 (2) | 0.2262 (3) | 0.0151 (9) | |
C1 | 0.8958 (4) | 0.5289 (3) | 0.7580 (4) | 0.0225 (12) | |
H1A | 0.8993 | 0.4728 | 0.7419 | 0.027* | |
H1B | 0.9698 | 0.5489 | 0.7781 | 0.027* | |
C2 | 0.8495 (5) | 0.5366 (4) | 0.8501 (4) | 0.0326 (14) | |
H2A | 0.8418 | 0.5919 | 0.8649 | 0.049* | |
H2B | 0.8972 | 0.5115 | 0.9103 | 0.049* | |
H2C | 0.7795 | 0.5113 | 0.8345 | 0.049* | |
C3 | 0.9178 (4) | 0.5694 (3) | 0.5620 (4) | 0.0228 (12) | |
H3A | 0.9898 | 0.5830 | 0.6049 | 0.027* | |
H3B | 0.9196 | 0.5140 | 0.5416 | 0.027* | |
C4 | 0.8933 (4) | 0.6196 (4) | 0.4644 (4) | 0.0318 (14) | |
H4A | 0.8205 | 0.6091 | 0.4231 | 0.048* | |
H4B | 0.9437 | 0.6071 | 0.4239 | 0.048* | |
H4C | 0.8999 | 0.6748 | 0.4836 | 0.048* | |
C5 | 0.8285 (4) | 0.6833 (3) | 0.6753 (4) | 0.0232 (12) | |
H5A | 0.7970 | 0.7137 | 0.6120 | 0.028* | |
H5B | 0.7828 | 0.6914 | 0.7229 | 0.028* | |
C6 | 0.9390 (4) | 0.7167 (3) | 0.7261 (5) | 0.0323 (14) | |
H6A | 0.9711 | 0.6878 | 0.7896 | 0.048* | |
H6B | 0.9323 | 0.7718 | 0.7426 | 0.048* | |
H6C | 0.9843 | 0.7119 | 0.6786 | 0.048* | |
C7 | 0.2559 (4) | 0.7573 (3) | 0.4713 (4) | 0.0211 (11) | |
H7A | 0.2402 | 0.8113 | 0.4887 | 0.025* | |
H7B | 0.2684 | 0.7583 | 0.4018 | 0.025* | |
C8 | 0.1574 (4) | 0.7066 (3) | 0.4672 (4) | 0.0285 (13) | |
H8A | 0.1692 | 0.6540 | 0.4438 | 0.043* | |
H8B | 0.0949 | 0.7297 | 0.4190 | 0.043* | |
H8C | 0.1453 | 0.7037 | 0.5361 | 0.043* | |
C9 | 0.3480 (4) | 0.7250 (3) | 0.6890 (4) | 0.0212 (11) | |
H9A | 0.2999 | 0.6804 | 0.6901 | 0.025* | |
H9B | 0.4149 | 0.7152 | 0.7429 | 0.025* | |
C10 | 0.2969 (5) | 0.7976 (4) | 0.7188 (5) | 0.0402 (16) | |
H10A | 0.3437 | 0.8425 | 0.7194 | 0.060* | |
H10B | 0.2858 | 0.7907 | 0.7876 | 0.060* | |
H10C | 0.2282 | 0.8067 | 0.6687 | 0.060* | |
C11 | 0.4646 (4) | 0.8098 (3) | 0.5668 (4) | 0.0204 (11) | |
H11A | 0.4814 | 0.8136 | 0.4992 | 0.024* | |
H11B | 0.4243 | 0.8572 | 0.5751 | 0.024* | |
C12 | 0.5696 (4) | 0.8091 (3) | 0.6519 (5) | 0.0297 (14) | |
H12A | 0.5546 | 0.8154 | 0.7192 | 0.045* | |
H12B | 0.6150 | 0.8520 | 0.6407 | 0.045* | |
H12C | 0.6063 | 0.7594 | 0.6503 | 0.045* | |
C13 | 0.5351 (4) | 0.5874 (3) | 0.1478 (4) | 0.0206 (11) | |
C14 | 0.5478 (4) | 0.6082 (4) | 0.0466 (4) | 0.0337 (15) | |
H14A | 0.6217 | 0.5992 | 0.0450 | 0.051* | |
H14B | 0.5299 | 0.6633 | 0.0328 | 0.051* | |
H14C | 0.5001 | 0.5760 | −0.0062 | 0.051* | |
Sb1 | 0.73332 (3) | 0.91633 (2) | 0.39924 (3) | 0.02375 (9) | |
F1 | 0.7830 (4) | 0.8151 (2) | 0.4290 (4) | 0.0704 (14) | |
F2 | 0.8103 (3) | 0.9449 (3) | 0.5322 (3) | 0.0697 (14) | |
F3 | 0.8542 (3) | 0.9374 (2) | 0.3531 (3) | 0.0460 (10) | |
F4 | 0.6602 (3) | 0.8872 (3) | 0.2656 (3) | 0.0634 (13) | |
F5 | 0.6120 (3) | 0.8954 (2) | 0.4439 (3) | 0.0502 (10) | |
F6 | 0.6871 (4) | 1.0185 (2) | 0.3723 (4) | 0.0855 (17) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Re1 | 0.01019 (9) | 0.01073 (10) | 0.01163 (10) | −0.00072 (7) | 0.00191 (7) | −0.00061 (8) |
Re2 | 0.01140 (9) | 0.00994 (10) | 0.01146 (10) | 0.00004 (7) | 0.00230 (7) | −0.00060 (8) |
Re3 | 0.01176 (9) | 0.01113 (10) | 0.01079 (10) | −0.00032 (7) | 0.00276 (7) | −0.00004 (8) |
Se1 | 0.0140 (2) | 0.0139 (2) | 0.0142 (2) | 0.00134 (18) | 0.00157 (17) | 0.0007 (2) |
Se2 | 0.0156 (2) | 0.0142 (2) | 0.0129 (2) | −0.00072 (18) | 0.00240 (18) | −0.0024 (2) |
Se3 | 0.0137 (2) | 0.0156 (2) | 0.0158 (2) | 0.00021 (18) | 0.00523 (17) | −0.0011 (2) |
Se4 | 0.0150 (2) | 0.0120 (2) | 0.0165 (2) | −0.00182 (18) | 0.00345 (18) | 0.0006 (2) |
P1 | 0.0123 (6) | 0.0155 (6) | 0.0154 (6) | −0.0016 (5) | 0.0011 (5) | 0.0000 (5) |
P2 | 0.0169 (6) | 0.0134 (6) | 0.0135 (6) | 0.0012 (5) | 0.0040 (5) | −0.0007 (5) |
N1 | 0.017 (2) | 0.011 (2) | 0.018 (2) | 0.0004 (16) | 0.0061 (16) | 0.0020 (18) |
C1 | 0.014 (2) | 0.027 (3) | 0.023 (3) | 0.000 (2) | −0.003 (2) | 0.003 (2) |
C2 | 0.032 (3) | 0.042 (4) | 0.020 (3) | −0.006 (3) | 0.001 (2) | 0.005 (3) |
C3 | 0.015 (2) | 0.029 (3) | 0.027 (3) | 0.002 (2) | 0.009 (2) | −0.001 (3) |
C4 | 0.028 (3) | 0.041 (4) | 0.027 (3) | −0.005 (3) | 0.009 (2) | 0.005 (3) |
C5 | 0.019 (3) | 0.020 (3) | 0.028 (3) | 0.000 (2) | 0.001 (2) | −0.001 (2) |
C6 | 0.024 (3) | 0.023 (3) | 0.044 (4) | −0.005 (2) | −0.001 (3) | −0.007 (3) |
C7 | 0.022 (3) | 0.019 (3) | 0.022 (3) | 0.007 (2) | 0.005 (2) | 0.001 (2) |
C8 | 0.020 (3) | 0.031 (3) | 0.032 (3) | 0.005 (2) | 0.003 (2) | −0.008 (3) |
C9 | 0.030 (3) | 0.018 (3) | 0.017 (3) | 0.000 (2) | 0.008 (2) | −0.003 (2) |
C10 | 0.068 (5) | 0.033 (4) | 0.022 (3) | 0.017 (3) | 0.015 (3) | −0.002 (3) |
C11 | 0.027 (3) | 0.014 (3) | 0.021 (3) | 0.002 (2) | 0.006 (2) | 0.002 (2) |
C12 | 0.029 (3) | 0.021 (3) | 0.035 (4) | −0.012 (2) | 0.003 (2) | −0.009 (3) |
C13 | 0.019 (3) | 0.019 (3) | 0.022 (3) | −0.002 (2) | 0.002 (2) | 0.000 (2) |
C14 | 0.030 (3) | 0.050 (4) | 0.020 (3) | −0.016 (3) | 0.005 (2) | 0.009 (3) |
Sb1 | 0.01872 (17) | 0.0293 (2) | 0.0237 (2) | −0.00210 (14) | 0.00649 (14) | 0.00040 (17) |
F1 | 0.083 (3) | 0.045 (3) | 0.091 (4) | 0.020 (2) | 0.036 (3) | 0.022 (3) |
F2 | 0.035 (2) | 0.135 (4) | 0.038 (2) | −0.001 (2) | 0.0072 (17) | −0.038 (3) |
F3 | 0.0253 (18) | 0.080 (3) | 0.036 (2) | −0.0141 (18) | 0.0136 (15) | 0.002 (2) |
F4 | 0.032 (2) | 0.122 (4) | 0.035 (2) | −0.016 (2) | 0.0068 (17) | −0.023 (2) |
F5 | 0.0293 (19) | 0.084 (3) | 0.044 (2) | −0.0110 (19) | 0.0200 (16) | −0.005 (2) |
F6 | 0.080 (3) | 0.038 (3) | 0.144 (5) | 0.022 (2) | 0.037 (3) | 0.025 (3) |
Re1—Re2 | 2.6440 (6) | C3—H3A | 0.9900 |
Re1—Re2i | 2.6457 (5) | C3—H3B | 0.9900 |
Re1—Re3 | 2.6392 (9) | C3—C4 | 1.532 (7) |
Re1—Re3i | 2.6383 (6) | C4—H4A | 0.9800 |
Re1—Se1 | 2.5259 (6) | C4—H4B | 0.9800 |
Re1—Se2 | 2.5250 (7) | C4—H4C | 0.9800 |
Re1—Se3 | 2.5159 (7) | C5—H5A | 0.9900 |
Re1—Se4 | 2.5269 (7) | C5—H5B | 0.9900 |
Re1—P1 | 2.4839 (13) | C5—C6 | 1.531 (7) |
Re2—Re1i | 2.6457 (5) | C6—H6A | 0.9800 |
Re2—Re3 | 2.6355 (6) | C6—H6B | 0.9800 |
Re2—Re3i | 2.6341 (5) | C6—H6C | 0.9800 |
Re2—Se1i | 2.5239 (10) | C7—H7A | 0.9900 |
Re2—Se2 | 2.5278 (10) | C7—H7B | 0.9900 |
Re2—Se3i | 2.5161 (7) | C7—C8 | 1.537 (7) |
Re2—Se4 | 2.5237 (7) | C8—H8A | 0.9800 |
Re2—P2 | 2.4749 (13) | C8—H8B | 0.9800 |
Re3—Re1i | 2.6383 (6) | C8—H8C | 0.9800 |
Re3—Re2i | 2.6342 (5) | C9—H9A | 0.9900 |
Re3—Se1i | 2.5184 (7) | C9—H9B | 0.9900 |
Re3—Se2i | 2.5231 (7) | C9—C10 | 1.515 (7) |
Re3—Se3 | 2.5181 (7) | C10—H10A | 0.9800 |
Re3—Se4 | 2.5188 (7) | C10—H10B | 0.9800 |
Re3—N1 | 2.113 (4) | C10—H10C | 0.9800 |
Se1—Re2i | 2.5239 (10) | C11—H11A | 0.9900 |
Se1—Re3i | 2.5184 (7) | C11—H11B | 0.9900 |
Se2—Re3i | 2.5232 (7) | C11—C12 | 1.534 (7) |
Se3—Re2i | 2.5161 (7) | C12—H12A | 0.9800 |
P1—C1 | 1.828 (5) | C12—H12B | 0.9800 |
P1—C3 | 1.822 (5) | C12—H12C | 0.9800 |
P1—C5 | 1.841 (5) | C13—C14 | 1.457 (7) |
P2—C7 | 1.840 (5) | C14—H14A | 0.9800 |
P2—C9 | 1.822 (5) | C14—H14B | 0.9800 |
P2—C11 | 1.827 (5) | C14—H14C | 0.9800 |
N1—C13 | 1.129 (6) | Sb1—F1 | 1.860 (4) |
C1—H1A | 0.9900 | Sb1—F2 | 1.870 (4) |
C1—H1B | 0.9900 | Sb1—F3 | 1.872 (3) |
C1—C2 | 1.518 (8) | Sb1—F4 | 1.865 (4) |
C2—H2A | 0.9800 | Sb1—F5 | 1.866 (3) |
C2—H2B | 0.9800 | Sb1—F6 | 1.857 (4) |
C2—H2C | 0.9800 | ||
Re2—Re1—Re2i | 89.829 (19) | Re1—Se3—Re2i | 63.44 (2) |
Re2—Re1—Re3 | 59.85 (2) | Re1—Se3—Re3 | 63.24 (3) |
Re2—Re1—Re3i | 59.824 (15) | Re2i—Se3—Re3 | 63.102 (18) |
Re2i—Re1—Re3i | 59.835 (13) | Re1—Se4—Re2 | 63.137 (18) |
Re2i—Re1—Re3 | 59.792 (14) | Re1—Se4—Re3 | 63.07 (2) |
Re2—Re1—Se1 | 118.139 (19) | Re2—Se4—Re3 | 63.021 (16) |
Re2i—Re1—Se1 | 58.37 (2) | Re1—P1—C1 | 116.14 (17) |
Re2—Re1—Se2 | 58.50 (2) | Re1—P1—C3 | 115.88 (18) |
Re2i—Re1—Se2 | 118.283 (17) | Re1—P1—C5 | 112.56 (16) |
Re2—Re1—Se3 | 118.25 (3) | C1—P1—C3 | 100.7 (2) |
Re2i—Re1—Se3 | 58.283 (16) | C1—P1—C5 | 105.3 (2) |
Re2—Re1—Se4 | 58.372 (19) | C3—P1—C5 | 104.8 (3) |
Re2i—Re1—Se4 | 118.10 (2) | Re2—P2—C7 | 114.97 (17) |
Re2—Re1—P1 | 134.05 (3) | Re2—P2—C9 | 112.47 (17) |
Re2i—Re1—P1 | 136.12 (3) | Re2—P2—C11 | 116.55 (18) |
Re3—Re1—Re3i | 89.56 (2) | C7—P2—C9 | 105.1 (2) |
Re3—Re1—Se1 | 118.139 (15) | C7—P2—C11 | 100.9 (2) |
Re3i—Re1—Se1 | 58.326 (16) | C9—P2—C11 | 105.4 (2) |
Re3—Re1—Se2 | 118.326 (18) | Re3—N1—C13 | 176.5 (4) |
Re3i—Re1—Se2 | 58.46 (2) | P1—C1—H1A | 108.3 |
Re3—Re1—Se3 | 58.422 (17) | P1—C1—H1B | 108.3 |
Re3i—Re1—Se3 | 118.10 (2) | P1—C1—C2 | 116.1 (4) |
Re3—Re1—Se4 | 58.314 (15) | H1A—C1—H1B | 107.4 |
Re3i—Re1—Se4 | 118.175 (18) | H1A—C1—C2 | 108.3 |
Re3—Re1—P1 | 135.06 (4) | H1B—C1—C2 | 108.3 |
Re3i—Re1—P1 | 135.36 (3) | C1—C2—H2A | 109.5 |
Se1—Re1—Se2 | 89.74 (2) | C1—C2—H2B | 109.5 |
Se1—Re1—Se3 | 89.95 (2) | C1—C2—H2C | 109.5 |
Se1—Re1—Se4 | 175.697 (16) | H2A—C2—H2B | 109.5 |
Se1—Re1—P1 | 92.98 (4) | H2A—C2—H2C | 109.5 |
Se2—Re1—Se3 | 175.91 (4) | H2B—C2—H2C | 109.5 |
Se2—Re1—Se4 | 90.16 (2) | P1—C3—H3A | 108.5 |
Se2—Re1—P1 | 91.35 (4) | P1—C3—H3B | 108.5 |
Se3—Re1—Se4 | 89.85 (2) | P1—C3—C4 | 115.0 (4) |
Se3—Re1—P1 | 92.74 (4) | H3A—C3—H3B | 107.5 |
Se4—Re1—P1 | 91.32 (4) | H3A—C3—C4 | 108.5 |
Re1—Re2—Re1i | 90.17 (2) | H3B—C3—C4 | 108.5 |
Re1—Re2—Re3 | 59.99 (2) | C3—C4—H4A | 109.5 |
Re1—Re2—Re3i | 59.979 (15) | C3—C4—H4B | 109.5 |
Re1i—Re2—Re3i | 59.98 (2) | C3—C4—H4C | 109.5 |
Re1i—Re2—Re3 | 59.942 (13) | H4A—C4—H4B | 109.5 |
Re1—Re2—Se1i | 118.37 (3) | H4A—C4—H4C | 109.5 |
Re1i—Re2—Se1i | 58.441 (16) | H4B—C4—H4C | 109.5 |
Re1—Re2—Se2 | 58.40 (2) | P1—C5—H5A | 108.3 |
Re1i—Re2—Se2 | 118.453 (18) | P1—C5—H5B | 108.3 |
Re1—Re2—Se3i | 118.457 (19) | P1—C5—C6 | 116.1 (4) |
Re1i—Re2—Se3i | 58.276 (17) | H5A—C5—H5B | 107.4 |
Re1—Re2—Se4 | 58.491 (18) | H5A—C5—C6 | 108.3 |
Re1i—Re2—Se4 | 118.336 (17) | H5B—C5—C6 | 108.3 |
Re1—Re2—P2 | 135.45 (3) | C5—C6—H6A | 109.5 |
Re1i—Re2—P2 | 134.24 (3) | C5—C6—H6B | 109.5 |
Re3—Re2—Re3i | 89.732 (14) | C5—C6—H6C | 109.5 |
Re3i—Re2—Se1i | 118.402 (16) | H6A—C6—H6B | 109.5 |
Re3—Re2—Se1i | 58.386 (17) | H6A—C6—H6C | 109.5 |
Re3—Re2—Se2 | 118.364 (19) | H6B—C6—H6C | 109.5 |
Re3i—Re2—Se2 | 58.481 (14) | P2—C7—H7A | 108.5 |
Re3i—Re2—Se3i | 58.488 (17) | P2—C7—H7B | 108.5 |
Re3—Re2—Se3i | 118.20 (2) | P2—C7—C8 | 115.0 (4) |
Re3—Re2—Se4 | 58.40 (2) | H7A—C7—H7B | 107.5 |
Re3i—Re2—Se4 | 118.449 (17) | H7A—C7—C8 | 108.5 |
Re3—Re2—P2 | 137.97 (3) | H7B—C7—C8 | 108.5 |
Re3i—Re2—P2 | 132.29 (3) | C7—C8—H8A | 109.5 |
Se1i—Re2—Se2 | 176.107 (18) | C7—C8—H8B | 109.5 |
Se1i—Re2—Se3i | 89.99 (3) | C7—C8—H8C | 109.5 |
Se1i—Re2—Se4 | 89.59 (3) | H8A—C8—H8B | 109.5 |
Se1i—Re2—P2 | 93.53 (3) | H8A—C8—H8C | 109.5 |
Se2—Re2—Se3i | 89.99 (3) | H8B—C8—H8C | 109.5 |
Se2—Re2—Se4 | 90.17 (3) | P2—C9—H9A | 107.9 |
Se2—Re2—P2 | 90.36 (3) | P2—C9—H9B | 107.9 |
Se3i—Re2—Se4 | 176.040 (18) | P2—C9—C10 | 117.5 (4) |
Se3i—Re2—P2 | 89.57 (4) | H9A—C9—H9B | 107.2 |
Se4—Re2—P2 | 94.38 (4) | H9A—C9—C10 | 107.9 |
Re1—Re3—Re1i | 90.44 (2) | H9B—C9—C10 | 107.9 |
Re1—Re3—Re2 | 60.168 (15) | C9—C10—H10A | 109.5 |
Re1i—Re3—Re2i | 60.195 (13) | C9—C10—H10B | 109.5 |
Re1i—Re3—Re2 | 60.221 (18) | C9—C10—H10C | 109.5 |
Re1—Re3—Re2i | 60.227 (11) | H10A—C10—H10B | 109.5 |
Re1i—Re3—Se1i | 58.603 (18) | H10A—C10—H10C | 109.5 |
Re1—Re3—Se1i | 118.75 (3) | H10B—C10—H10C | 109.5 |
Re1i—Re3—Se2i | 58.527 (17) | P2—C11—H11A | 108.5 |
Re1—Re3—Se2i | 118.871 (18) | P2—C11—H11B | 108.5 |
Re1—Re3—Se3 | 58.34 (2) | P2—C11—C12 | 115.2 (4) |
Re1i—Re3—Se3 | 118.596 (19) | H11A—C11—H11B | 107.5 |
Re1—Re3—Se4 | 58.611 (17) | H11A—C11—C12 | 108.5 |
Re1i—Re3—Se4 | 118.794 (18) | H11B—C11—C12 | 108.5 |
Re1—Re3—N1 | 134.86 (10) | C11—C12—H12A | 109.5 |
Re1i—Re3—N1 | 134.70 (10) | C11—C12—H12B | 109.5 |
Re2—Re3—Re2i | 90.266 (15) | C11—C12—H12C | 109.5 |
Re2i—Re3—Se1i | 118.79 (2) | H12A—C12—H12B | 109.5 |
Re2—Re3—Se1i | 58.59 (3) | H12A—C12—H12C | 109.5 |
Re2i—Re3—Se2i | 58.65 (2) | H12B—C12—H12C | 109.5 |
Re2—Re3—Se2i | 118.738 (18) | N1—C13—C14 | 179.8 (6) |
Re2—Re3—Se3 | 118.49 (3) | C13—C14—H14A | 109.5 |
Re2i—Re3—Se3 | 58.412 (18) | C13—C14—H14B | 109.5 |
Re2—Re3—Se4 | 58.579 (17) | C13—C14—H14C | 109.5 |
Re2i—Re3—Se4 | 118.83 (2) | H14A—C14—H14B | 109.5 |
Re2—Re3—N1 | 135.53 (11) | H14A—C14—H14C | 109.5 |
Re2i—Re3—N1 | 134.20 (11) | H14B—C14—H14C | 109.5 |
Se1i—Re3—Se2i | 89.95 (2) | F1—Sb1—F2 | 88.3 (2) |
Se1i—Re3—Se3 | 176.492 (18) | F1—Sb1—F3 | 88.65 (19) |
Se1i—Re3—Se4 | 89.82 (2) | F1—Sb1—F4 | 91.0 (2) |
Se1i—Re3—N1 | 92.03 (11) | F1—Sb1—F5 | 91.6 (2) |
Se2i—Re3—Se3 | 90.05 (2) | F1—Sb1—F6 | 178.4 (2) |
Se2i—Re3—Se4 | 176.806 (18) | F2—Sb1—F3 | 88.87 (17) |
Se2i—Re3—N1 | 91.08 (11) | F2—Sb1—F4 | 178.32 (17) |
Se3—Re3—Se4 | 89.99 (2) | F2—Sb1—F5 | 91.66 (17) |
Se3—Re3—N1 | 91.48 (11) | F2—Sb1—F6 | 90.2 (2) |
Se4—Re3—N1 | 92.11 (11) | F3—Sb1—F4 | 89.60 (17) |
Re1—Se1—Re2i | 63.192 (15) | F3—Sb1—F5 | 179.44 (16) |
Re1—Se1—Re3i | 63.071 (19) | F3—Sb1—F6 | 90.6 (2) |
Re2i—Se1—Re3i | 63.02 (3) | F4—Sb1—F5 | 89.88 (17) |
Re1—Se2—Re2 | 63.105 (18) | F4—Sb1—F6 | 90.4 (2) |
Re1—Se2—Re3i | 63.016 (17) | F5—Sb1—F6 | 89.2 (2) |
Re2—Se2—Re3i | 62.868 (17) |
Symmetry code: (i) −x+1, −y+1, −z+1. |