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In the structure of the title compound, (2,3,5,6,8,9,11,12,14,15-deca­hydro-1,4,7,10,13,16-benzohexa­oxacyclo­octa­decine)potassium chloro­chromate(VI), [K(C16H24O6)][CrClO3], the K+ cation is located approximately in the center of the crown ether cavity and is coordinated by two anions, one on each side of the macrocylic ring, one anion being related to the other by the symmetry operator (x, y - 1, z). One anion is bonded through O and Cl atoms and the other only by an O atom. As a result, in the crystal structure, polymeric chains, consisting of alternating anions and cations, are formed along the [010] direction.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806025360/lh2117sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806025360/lh2117Isup2.hkl
Contains datablock I

CCDC reference: 618269

Key indicators

  • Single-crystal X-ray study
  • T = 100 K
  • Mean [sigma](C-C) = 0.002 Å
  • R factor = 0.027
  • wR factor = 0.050
  • Data-to-parameter ratio = 28.6

checkCIF/PLATON results

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Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 34.72 From the CIF: _reflns_number_total 7230 Count of symmetry unique reflns 4596 Completeness (_total/calc) 157.31% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 2634 Fraction of Friedel pairs measured 0.573 Are heavy atom types Z>Si present yes
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 0 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion
checkCIF publication errors
Alert level A PUBL024_ALERT_1_A The number of authors is greater than 5. Please specify the role of each of the co-authors for your paper.
Author Response: All autors made significant contribution in this work. The idea of synthesis belongs to Kamalov and Kotlyar. The synthesis was performed by Kiriyak and Pluzhnik-Gladyr. X-ray diffraction experiment, structure solution and refinement was performed by Zubatyuk. The analysis of diffraction data was performed by Shishkin and Zubatyuk.

1 ALERT level A = Data missing that is essential or data in wrong format 0 ALERT level G = General alerts. Data that may be required is missing

Computing details top

Data collection: CrysAlis CCD (Oxford Diffraction, 2006); cell refinement: CrysAlis RED (Oxford Diffraction, 2006); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: please specify; software used to prepare material for publication: SHELXL97.

(2,3,5,6,8,9,11,12,14,15-decahydro-1,4,7,10,13,16- benzohexaoxacyclooctadecine)potassium chlorochromate top
Crystal data top
[K(C16H24O6)][CrClO3]F(000) = 1008
Mr = 486.9Dx = 1.564 Mg m3
Orthorhombic, Pna21Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2c -2nCell parameters from 8193 reflections
a = 15.8744 (12) Åθ = 2.6–34.8°
b = 7.8637 (10) ŵ = 0.93 mm1
c = 16.562 (2) ÅT = 100 K
V = 2067.4 (4) Å3Prism, pale orange
Z = 40.4 × 0.3 × 0.25 mm
Data collection top
Xcalibur 3
diffractometer
7230 independent reflections
Radiation source: Enhance (Mo) X-ray Source5979 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.024
Detector resolution: 16.1827 pixels mm-1θmax = 34.7°, θmin = 2.9°
ω scansh = 2025
Absorption correction: multi-scan
(CrysAlis RED; Oxford Diffraction, 2006)
k = 1212
Tmin = 0.708, Tmax = 0.793l = 2621
15472 measured reflections
Refinement top
Refinement on F2H-atom parameters constrained
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.02P)2]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.027(Δ/σ)max = 0.001
wR(F2) = 0.050Δρmax = 0.41 e Å3
S = 1.02Δρmin = 0.37 e Å3
7230 reflectionsAbsolute structure: Flack (1983), 2634 Friedel pairs
253 parametersAbsolute structure parameter: 0.009 (11)
1 restraint
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cr10.320664 (13)0.99136 (3)0.406533 (13)0.01455 (4)
K10.332281 (18)0.51318 (4)0.370222 (15)0.01553 (6)
Cl10.27020 (2)0.87280 (5)0.29566 (2)0.02445 (8)
O10.24374 (6)0.42156 (14)0.22905 (6)0.0173 (2)
O20.42520 (6)0.41285 (13)0.23302 (6)0.0179 (2)
O30.51081 (6)0.52176 (13)0.37710 (6)0.0202 (2)
O40.40578 (6)0.45712 (14)0.51630 (6)0.0191 (2)
O50.23117 (6)0.53318 (13)0.50929 (6)0.0173 (2)
O60.15244 (6)0.49638 (13)0.35528 (5)0.01624 (19)
O70.38595 (7)0.85769 (15)0.44456 (7)0.0256 (2)
O80.24429 (7)1.02899 (18)0.46756 (7)0.0326 (3)
O90.36707 (8)1.16465 (15)0.38117 (7)0.0318 (3)
C10.11703 (9)0.53426 (17)0.28163 (8)0.0144 (3)
C20.03812 (9)0.60547 (18)0.27131 (9)0.0181 (3)
H2A0.00520.63550.3170.022*
C30.00687 (10)0.6332 (2)0.19360 (9)0.0227 (3)
H3A0.04750.68150.18660.027*
C40.05440 (10)0.5911 (2)0.12719 (10)0.0235 (3)
H4A0.03260.60970.07450.028*
C50.13414 (10)0.52155 (19)0.13688 (8)0.0200 (3)
H5A0.1670.49410.09070.024*
C60.16612 (9)0.49187 (18)0.21352 (8)0.0157 (2)
C70.29581 (9)0.3869 (2)0.15989 (8)0.0193 (3)
H7A0.31120.49460.13260.023*
H7B0.26490.31460.12090.023*
C80.37373 (9)0.2972 (2)0.18846 (9)0.0199 (3)
H8A0.35790.19980.22320.024*
H8B0.40550.25290.14150.024*
C90.50002 (9)0.3318 (2)0.26089 (9)0.0206 (3)
H9A0.53230.2860.21460.025*
H9B0.48550.23610.29720.025*
C100.55208 (9)0.46070 (19)0.30552 (10)0.0223 (3)
H10A0.60660.40880.32070.027*
H10B0.56390.5580.26930.027*
C110.53649 (10)0.4332 (2)0.44816 (10)0.0246 (3)
H11A0.59820.44430.45540.03*
H11B0.52280.31090.44290.03*
C120.49173 (9)0.5065 (2)0.52007 (9)0.0241 (3)
H12A0.51760.46370.57050.029*
H12B0.49630.63210.51960.029*
C130.35902 (10)0.5134 (2)0.58458 (8)0.0232 (3)
H13A0.35930.63920.58730.028*
H13B0.38450.46860.63480.028*
C140.27074 (10)0.4497 (2)0.57608 (8)0.0216 (3)
H14A0.27120.32530.5670.026*
H14B0.23880.4730.62620.026*
C150.14798 (9)0.4713 (2)0.49822 (9)0.0198 (3)
H15A0.11390.4960.54690.024*
H15B0.14940.34640.49050.024*
C160.10823 (9)0.5539 (2)0.42582 (8)0.0188 (3)
H16A0.0480.52210.42230.023*
H16B0.11210.67920.43030.023*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cr10.01470 (9)0.01534 (10)0.01362 (8)0.00058 (9)0.00104 (9)0.00147 (10)
K10.01361 (12)0.01862 (14)0.01435 (12)0.00156 (12)0.00061 (10)0.00062 (12)
Cl10.03110 (18)0.02263 (17)0.01962 (14)0.00111 (16)0.00677 (15)0.00083 (15)
O10.0154 (5)0.0239 (5)0.0126 (4)0.0037 (4)0.0014 (4)0.0004 (4)
O20.0156 (5)0.0141 (5)0.0240 (5)0.0021 (4)0.0017 (4)0.0012 (4)
O30.0162 (5)0.0180 (5)0.0263 (5)0.0028 (4)0.0007 (4)0.0032 (4)
O40.0169 (5)0.0228 (6)0.0177 (4)0.0008 (4)0.0047 (4)0.0007 (4)
O50.0178 (4)0.0202 (5)0.0138 (4)0.0024 (4)0.0005 (4)0.0020 (4)
O60.0151 (4)0.0216 (5)0.0121 (4)0.0025 (4)0.0004 (3)0.0008 (4)
O70.0261 (6)0.0259 (6)0.0247 (5)0.0077 (5)0.0060 (4)0.0004 (5)
O80.0204 (5)0.0568 (9)0.0207 (5)0.0091 (6)0.0033 (4)0.0021 (5)
O90.0496 (8)0.0203 (5)0.0257 (5)0.0105 (5)0.0007 (5)0.0004 (5)
C10.0152 (6)0.0132 (6)0.0148 (6)0.0037 (5)0.0020 (5)0.0007 (5)
C20.0168 (7)0.0142 (6)0.0233 (7)0.0013 (6)0.0008 (5)0.0002 (5)
C30.0175 (7)0.0195 (7)0.0311 (8)0.0011 (6)0.0070 (6)0.0055 (6)
C40.0247 (8)0.0238 (8)0.0221 (7)0.0065 (7)0.0095 (6)0.0070 (6)
C50.0223 (7)0.0226 (8)0.0151 (6)0.0050 (6)0.0014 (5)0.0021 (6)
C60.0144 (6)0.0162 (6)0.0165 (6)0.0040 (6)0.0010 (4)0.0007 (5)
C70.0209 (7)0.0235 (7)0.0136 (6)0.0017 (6)0.0041 (5)0.0029 (6)
C80.0218 (7)0.0175 (7)0.0203 (6)0.0003 (6)0.0051 (5)0.0038 (6)
C90.0153 (7)0.0163 (7)0.0303 (7)0.0042 (5)0.0049 (6)0.0022 (6)
C100.0143 (6)0.0206 (7)0.0321 (8)0.0022 (6)0.0047 (6)0.0020 (6)
C110.0153 (7)0.0257 (8)0.0329 (8)0.0007 (6)0.0046 (6)0.0082 (7)
C120.0211 (7)0.0256 (8)0.0257 (7)0.0032 (7)0.0096 (6)0.0053 (7)
C130.0267 (7)0.0267 (8)0.0161 (6)0.0031 (7)0.0054 (5)0.0032 (6)
C140.0281 (8)0.0242 (8)0.0127 (6)0.0028 (6)0.0000 (6)0.0031 (5)
C150.0171 (6)0.0270 (8)0.0153 (6)0.0042 (6)0.0025 (5)0.0003 (6)
C160.0150 (6)0.0254 (7)0.0161 (6)0.0005 (6)0.0027 (5)0.0022 (5)
Geometric parameters (Å, º) top
Cr1—O71.6048 (11)C3—H3A0.95
Cr1—O91.6051 (12)C4—C51.388 (2)
Cr1—O81.6059 (11)C4—H4A0.95
Cr1—Cl12.2096 (5)C5—C61.3869 (19)
K1—O42.7218 (10)C5—H5A0.95
K1—O9i2.8017 (13)C7—C81.500 (2)
K1—O52.8118 (10)C7—H7A0.99
K1—O12.8215 (10)C7—H7B0.99
K1—O22.8217 (11)C8—H8A0.99
K1—O32.8371 (11)C8—H8B0.99
K1—O62.8686 (10)C9—C101.502 (2)
K1—O73.0953 (12)C9—H9A0.99
K1—Cl13.2394 (6)C9—H9B0.99
O1—C61.3748 (16)C10—H10A0.99
O1—C71.4386 (16)C10—H10B0.99
O2—C91.4249 (17)C11—C121.502 (2)
O2—C81.4279 (18)C11—H11A0.99
O3—C111.4270 (19)C11—H11B0.99
O3—C101.4370 (19)C12—H12A0.99
O4—C121.4200 (18)C12—H12B0.99
O4—C131.4233 (18)C13—C141.495 (2)
O5—C151.4193 (17)C13—H13A0.99
O5—C141.4315 (17)C13—H13B0.99
O6—C11.3757 (16)C14—H14A0.99
O6—C161.4359 (16)C14—H14B0.99
O9—K1ii2.8017 (13)C15—C161.503 (2)
C1—C21.383 (2)C15—H15A0.99
C1—C61.4109 (19)C15—H15B0.99
C2—C31.396 (2)C16—H16A0.99
C2—H2A0.95C16—H16B0.99
C3—C41.374 (2)
O7—Cr1—O9111.25 (6)C2—C3—H3A119.8
O7—Cr1—O8111.18 (6)C3—C4—C5120.20 (14)
O9—Cr1—O8110.78 (7)C3—C4—H4A119.9
O7—Cr1—Cl1106.49 (4)C5—C4—H4A119.9
O9—Cr1—Cl1107.88 (5)C6—C5—C4120.38 (14)
O8—Cr1—Cl1109.09 (5)C6—C5—H5A119.8
O4—K1—O9i72.52 (3)C4—C5—H5A119.8
O4—K1—O561.69 (3)O1—C6—C5124.53 (13)
O9i—K1—O596.56 (3)O1—C6—C1116.14 (11)
O4—K1—O1155.33 (3)C5—C6—C1119.33 (13)
O9i—K1—O184.38 (3)O1—C7—C8108.15 (11)
O5—K1—O1114.12 (3)O1—C7—H7A110.1
O4—K1—O2116.51 (3)C8—C7—H7A110.1
O9i—K1—O271.07 (3)O1—C7—H7B110.1
O5—K1—O2166.84 (3)C8—C7—H7B110.1
O1—K1—O261.43 (3)H7A—C7—H7B108.4
O4—K1—O362.61 (3)O2—C8—C7109.59 (12)
O9i—K1—O379.85 (4)O2—C8—H8A109.8
O5—K1—O3122.41 (3)C7—C8—H8A109.8
O1—K1—O3122.48 (3)O2—C8—H8B109.8
O2—K1—O361.10 (3)C7—C8—H8B109.8
O4—K1—O6119.72 (3)H8A—C8—H8B108.2
O9i—K1—O699.02 (3)O2—C9—C10108.41 (12)
O5—K1—O660.34 (3)O2—C9—H9A110
O1—K1—O654.62 (3)C10—C9—H9A110
O2—K1—O6115.97 (3)O2—C9—H9B110
O3—K1—O6177.06 (3)C10—C9—H9B110
O4—K1—O770.75 (3)H9A—C9—H9B108.4
O9i—K1—O7140.91 (3)O3—C10—C9112.37 (12)
O5—K1—O777.43 (3)O3—C10—H10A109.1
O1—K1—O7133.64 (3)C9—C10—H10A109.1
O2—K1—O7114.91 (3)O3—C10—H10B109.1
O3—K1—O771.84 (3)C9—C10—H10B109.1
O6—K1—O7110.40 (3)H10A—C10—H10B107.9
O4—K1—Cl1127.64 (3)O3—C11—C12109.37 (12)
O9i—K1—Cl1159.82 (3)O3—C11—H11A109.8
O5—K1—Cl195.15 (2)C12—C11—H11A109.8
O1—K1—Cl175.85 (2)O3—C11—H11B109.8
O2—K1—Cl195.52 (2)C12—C11—H11B109.8
O3—K1—Cl1107.36 (2)H11A—C11—H11B108.2
O6—K1—Cl172.82 (2)O4—C12—C11108.35 (12)
O7—K1—Cl158.08 (2)O4—C12—H12A110
Cr1—Cl1—K186.633 (16)C11—C12—H12A110
C6—O1—C7116.24 (11)O4—C12—H12B110
C6—O1—K1119.92 (8)C11—C12—H12B110
C7—O1—K1114.95 (8)H12A—C12—H12B108.4
C9—O2—C8111.07 (11)O4—C13—C14108.05 (12)
C9—O2—K1107.45 (8)O4—C13—H13A110.1
C8—O2—K1107.16 (8)C14—C13—H13A110.1
C11—O3—C10112.78 (11)O4—C13—H13B110.1
C11—O3—K1107.87 (8)C14—C13—H13B110.1
C10—O3—K1114.48 (8)H13A—C13—H13B108.4
C12—O4—C13112.40 (11)O5—C14—C13109.31 (12)
C12—O4—K1114.00 (8)O5—C14—H14A109.8
C13—O4—K1115.62 (8)C13—C14—H14A109.8
C15—O5—C14110.54 (11)O5—C14—H14B109.8
C15—O5—K1113.96 (8)C13—C14—H14B109.8
C14—O5—K1110.90 (8)H14A—C14—H14B108.3
C1—O6—C16116.97 (10)O5—C15—C16110.21 (12)
C1—O6—K1118.25 (7)O5—C15—H15A109.6
C16—O6—K1113.68 (7)C16—C15—H15A109.6
Cr1—O7—K1103.85 (5)O5—C15—H15B109.6
Cr1—O9—K1ii139.20 (7)C16—C15—H15B109.6
O6—C1—C2124.58 (12)H15A—C15—H15B108.1
O6—C1—C6115.59 (11)O6—C16—C15107.94 (12)
C2—C1—C6119.82 (12)O6—C16—H16A110.1
C1—C2—C3119.94 (13)C15—C16—H16A110.1
C1—C2—H2A120O6—C16—H16B110.1
C3—C2—H2A120C15—C16—H16B110.1
C4—C3—C2120.32 (14)H16A—C16—H16B108.4
C4—C3—H3A119.8
O7—Cr1—Cl1—K119.71 (5)O4—K1—O5—C1418.48 (9)
O9—Cr1—Cl1—K1139.22 (5)O9i—K1—O5—C1447.60 (9)
O8—Cr1—Cl1—K1100.37 (5)O1—K1—O5—C14134.36 (9)
O4—K1—Cl1—Cr12.47 (3)O2—K1—O5—C1467.10 (17)
O9i—K1—Cl1—Cr1174.36 (8)O3—K1—O5—C1434.52 (10)
O5—K1—Cl1—Cr160.33 (3)O6—K1—O5—C14144.26 (10)
O1—K1—Cl1—Cr1173.94 (2)O7—K1—O5—C1493.19 (9)
O2—K1—Cl1—Cr1127.39 (3)Cl1—K1—O5—C14148.86 (9)
O3—K1—Cl1—Cr165.97 (3)O4—K1—O6—C1176.59 (8)
O6—K1—Cl1—Cr1117.11 (2)O9i—K1—O6—C1108.47 (9)
O7—K1—Cl1—Cr111.39 (3)O5—K1—O6—C1159.08 (10)
O4—K1—O1—C6116.66 (11)O1—K1—O6—C132.02 (8)
O9i—K1—O1—C6137.02 (10)O2—K1—O6—C135.21 (10)
O5—K1—O1—C642.33 (10)O7—K1—O6—C197.70 (9)
O2—K1—O1—C6151.50 (10)Cl1—K1—O6—C152.57 (8)
O3—K1—O1—C6148.80 (9)O4—K1—O6—C1633.67 (10)
O6—K1—O1—C631.77 (9)O9i—K1—O6—C16108.62 (9)
O7—K1—O1—C653.27 (11)O5—K1—O6—C1616.17 (8)
Cl1—K1—O1—C647.01 (9)O1—K1—O6—C16174.94 (10)
O4—K1—O1—C797.19 (11)O2—K1—O6—C16178.13 (9)
O9i—K1—O1—C776.83 (10)O7—K1—O6—C1645.22 (9)
O5—K1—O1—C7171.52 (9)Cl1—K1—O6—C1690.35 (9)
O2—K1—O1—C75.35 (9)O9—Cr1—O7—K1138.58 (5)
O3—K1—O1—C72.65 (10)O8—Cr1—O7—K197.44 (6)
O6—K1—O1—C7177.92 (11)Cl1—Cr1—O7—K121.27 (5)
O7—K1—O1—C792.88 (10)O4—K1—O7—Cr1152.17 (6)
Cl1—K1—O1—C799.14 (9)O9i—K1—O7—Cr1172.98 (5)
O4—K1—O2—C93.89 (9)O5—K1—O7—Cr188.08 (5)
O9i—K1—O2—C954.36 (9)O1—K1—O7—Cr123.39 (7)
O5—K1—O2—C974.89 (16)O2—K1—O7—Cr196.78 (5)
O1—K1—O2—C9148.31 (9)O3—K1—O7—Cr1141.29 (6)
O3—K1—O2—C934.29 (8)O6—K1—O7—Cr136.68 (6)
O6—K1—O2—C9145.35 (8)Cl1—K1—O7—Cr116.24 (4)
O7—K1—O2—C983.84 (9)O7—Cr1—O9—K1ii148.47 (8)
Cl1—K1—O2—C9141.10 (8)O8—Cr1—O9—K1ii24.26 (11)
O4—K1—O2—C8123.33 (8)Cl1—Cr1—O9—K1ii95.08 (9)
O9i—K1—O2—C865.07 (9)C16—O6—C1—C27.79 (19)
O5—K1—O2—C844.54 (17)K1—O6—C1—C2149.51 (11)
O1—K1—O2—C828.88 (8)C16—O6—C1—C6173.66 (12)
O3—K1—O2—C8153.73 (9)K1—O6—C1—C631.94 (14)
O6—K1—O2—C825.91 (9)O6—C1—C2—C3177.71 (13)
O7—K1—O2—C8156.73 (8)C6—C1—C2—C30.8 (2)
Cl1—K1—O2—C899.47 (8)C1—C2—C3—C40.4 (2)
O4—K1—O3—C1120.13 (9)C2—C3—C4—C50.4 (2)
O9i—K1—O3—C1155.33 (9)C3—C4—C5—C60.8 (2)
O5—K1—O3—C1136.03 (10)C7—O1—C6—C53.7 (2)
O1—K1—O3—C11131.92 (9)K1—O1—C6—C5149.47 (11)
O2—K1—O3—C11129.21 (10)C7—O1—C6—C1176.67 (12)
O7—K1—O3—C1197.37 (9)K1—O1—C6—C130.94 (15)
Cl1—K1—O3—C11144.09 (9)C4—C5—C6—O1179.11 (14)
O4—K1—O3—C10146.55 (9)C4—C5—C6—C10.5 (2)
O9i—K1—O3—C1071.09 (9)O6—C1—C6—O11.34 (17)
O5—K1—O3—C10162.45 (8)C2—C1—C6—O1179.96 (12)
O1—K1—O3—C105.50 (10)O6—C1—C6—C5178.27 (13)
O2—K1—O3—C102.79 (8)C2—C1—C6—C50.4 (2)
O7—K1—O3—C10136.21 (9)C6—O1—C7—C8175.05 (12)
Cl1—K1—O3—C1089.49 (9)K1—O1—C7—C837.52 (14)
O9i—K1—O4—C12103.10 (10)C9—O2—C8—C7179.82 (11)
O5—K1—O4—C12149.09 (11)K1—O2—C8—C763.10 (12)
O1—K1—O4—C12124.39 (11)O1—C7—C8—O269.91 (15)
O2—K1—O4—C1245.60 (11)C8—O2—C9—C10178.76 (12)
O3—K1—O4—C1215.67 (10)K1—O2—C9—C1064.33 (12)
O6—K1—O4—C12166.36 (10)C11—O3—C10—C995.81 (15)
O7—K1—O4—C1263.32 (10)K1—O3—C10—C928.03 (14)
Cl1—K1—O4—C1275.75 (10)O2—C9—C10—O364.16 (15)
O9i—K1—O4—C13124.36 (10)C10—O3—C11—C12179.04 (12)
O5—K1—O4—C1316.55 (9)K1—O3—C11—C1253.55 (13)
O1—K1—O4—C13103.07 (11)C13—O4—C12—C11176.86 (13)
O2—K1—O4—C13178.14 (9)K1—O4—C12—C1149.09 (14)
O3—K1—O4—C13148.21 (11)O3—C11—C12—O471.66 (16)
O6—K1—O4—C1333.83 (11)C12—O4—C13—C14177.99 (13)
O7—K1—O4—C1369.22 (10)K1—O4—C13—C1448.74 (14)
Cl1—K1—O4—C1356.79 (11)C15—O5—C14—C13178.20 (12)
O4—K1—O5—C15143.98 (10)K1—O5—C14—C1350.80 (13)
O9i—K1—O5—C1577.91 (9)O4—C13—C14—O567.39 (16)
O1—K1—O5—C158.85 (10)C14—O5—C15—C16177.51 (12)
O2—K1—O5—C1558.40 (17)K1—O5—C15—C1651.82 (14)
O3—K1—O5—C15160.03 (9)C1—O6—C16—C15169.25 (12)
O6—K1—O5—C1518.76 (9)K1—O6—C16—C1547.33 (13)
O7—K1—O5—C15141.30 (9)O5—C15—C16—O667.06 (15)
Cl1—K1—O5—C1585.63 (9)
Symmetry codes: (i) x, y1, z; (ii) x, y+1, z.
 

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