(2,4,6-Trimethyl­dithio­benzoato-κ²S,S′)bis­(triphenyl­phosphine-κP)gold(I)

The asymmetric unit of the title compound, [Au(C₁₀H₈S₂)(C₁₈H₁₅P)₂], consists of two independent mol­ecules. The Au coordination environment can be described as a highly distorted tetra­hedral arrangement (S₂AuP₂), but is more accurately described as a flattened trigonal pyramid defined by three normal covalent bonds (SAuP₂), with a second S atom more distantly bonded to the Au atom.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.013 Å
• R factor = 0.066
• wR factor = 0.099
• Data-to-parameter ratio = 21.9

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.79 Ratio

Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR) is > 1.10
            Tmin and Tmax reported:      0.551     0.601
            Tmin and Tmax expected:      0.483     0.599
            RR =      1.136
            Please check that your absorption correction is appropriate.
CRYSC01_ALERT_1_C The word below has not been recognised as a standard
            identifier.
            reddish
CRYSC01_ALERT_1_C No recognised colour has been given for crystal colour.
PLAT060_ALERT_3_C Ratio Tmax/Tmin (Exp-to-Rep) (too) Large .......       1.15
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.14
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.56 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.18 Ratio
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Au1    -   S2      ..       5.85 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Au2    -   S4      ..       7.35 su
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C29
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C25
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         13

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           29.12
           From the CIF: _reflns_number_total              20259
           Count of symmetry unique reflns        10915
           Completeness (_total/calc)            185.61%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      9344
           Fraction of Friedel pairs measured     0.856
           Are heavy atom types Z>Si present        yes

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  12 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   7 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: COLLECT (Nonius, 2000); cell refinement: DENZO and SCALEPACK (Otwinowski & Minor, 1997); data reduction: DENZO and SCALEPACK; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

(2,4,6-Trimethyldithiobenzoato-κ²S,S')bis(triphenylphosphine-κP)gold(I)

Crystal data

[Au(C10H8S2)(C18H15P)2]	F(000) = 1832
Mr = 916.81	Dx = 1.543 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 10009 reflections
a = 12.277 (3) Å	θ = 2.6–29.1°
b = 18.803 (4) Å	µ = 3.95 mm^−1
c = 17.132 (4) Å	T = 100 K
β = 93.922 (9)°	Fragment, reddish
V = 3945.6 (16) Å^3	0.19 × 0.17 × 0.13 mm
Z = 4

Data collection

Bruker Nonius KappaCCD area-detector diffractometer	15115 reflections with I > 2σ(I)
ω scans with κ offsets	Rint = 0
Absorption correction: multi-scan HKL SCALEPACK (Otwinowski & Minor 1997)	θmax = 29.1°, θmin = 2.8°
Tmin = 0.551, Tmax = 0.601	h = −16→16
20259 measured reflections	k = −25→24
20259 independent reflections	l = −23→23

Refinement

Refinement on F^2	H-atom parameters constrained
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + 14.6708P] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.066	(Δ/σ)max = 0.007
wR(F^2) = 0.099	Δρmax = 3.28 e Å^−3
S = 1.05	Δρmin = −1.54 e Å^−3
20259 reflections	Absolute structure: Flack (1983), with 9362 Friedel pairs
927 parameters	Absolute structure parameter: 0.146 (5)
1 restraint

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.6717 (7)	0.4713 (4)	0.1429 (5)	0.0233 (19)
C2	0.7753 (6)	0.4992 (6)	0.1313 (4)	0.0277 (17)
H2	0.7814	0.5445	0.1074	0.033*
C3	0.8698 (7)	0.4610 (5)	0.1547 (5)	0.032 (2)
H3	0.9399	0.4805	0.1479	0.039*
C4	0.8598 (8)	0.3946 (5)	0.1878 (6)	0.039 (2)
H4	0.9232	0.3682	0.2044	0.047*
C5	0.7586 (9)	0.3670 (5)	0.1965 (7)	0.045 (3)
H5	0.7522	0.3207	0.218	0.054*
C6	0.6652 (8)	0.4050 (5)	0.1746 (6)	0.044 (3)
H6	0.5957	0.3847	0.1816	0.052*
C7	0.5072 (6)	0.4787 (4)	0.0141 (5)	0.0190 (18)
C8	0.5684 (7)	0.4278 (4)	−0.0203 (5)	0.029 (2)
H8	0.6333	0.4107	0.0068	0.034*
C9	0.5370 (7)	0.4007 (5)	−0.0941 (6)	0.034 (2)
H9	0.5792	0.3647	−0.1167	0.04*
C10	0.4441 (8)	0.4265 (5)	−0.1340 (5)	0.033 (2)
H10	0.4235	0.4097	−0.1852	0.04*
C11	0.3803 (7)	0.4772 (4)	−0.0993 (5)	0.033 (2)
H11	0.3151	0.4937	−0.1263	0.04*
C12	0.4111 (6)	0.5037 (5)	−0.0258 (4)	0.0245 (16)
H12	0.3675	0.5384	−0.0024	0.029*
C13	0.5915 (6)	0.6069 (4)	0.0867 (5)	0.0194 (19)
C14	0.6133 (7)	0.6526 (4)	0.1490 (5)	0.029 (2)
H14	0.6004	0.6377	0.2005	0.035*
C15	0.6538 (8)	0.7200 (5)	0.1366 (6)	0.037 (3)
H15	0.668	0.7511	0.1797	0.045*
C16	0.6738 (7)	0.7423 (5)	0.0623 (6)	0.038 (3)
H16	0.7025	0.7885	0.0542	0.046*
C17	0.6518 (7)	0.6970 (4)	−0.0006 (6)	0.031 (2)
H17	0.663	0.7126	−0.0522	0.037*
C18	0.6132 (7)	0.6287 (4)	0.0118 (5)	0.0247 (19)
H18	0.6017	0.5969	−0.031	0.03*
C19	0.2392 (7)	0.3582 (4)	0.1912 (5)	0.022 (2)
C20	0.2327 (8)	0.3746 (4)	0.1116 (5)	0.032 (2)
H20	0.2786	0.4103	0.0924	0.039*
C21	0.1594 (8)	0.3390 (5)	0.0607 (6)	0.040 (3)
H21	0.1546	0.3515	0.0069	0.049*
C22	0.0933 (8)	0.2860 (5)	0.0859 (7)	0.040 (3)
H22	0.0436	0.2621	0.0499	0.048*
C23	0.1000 (8)	0.2679 (5)	0.1646 (7)	0.042 (3)
H23	0.0565	0.2304	0.1827	0.051*
C24	0.1704 (8)	0.3048 (4)	0.2168 (6)	0.034 (2)
H24	0.172	0.2937	0.271	0.04*
C25	0.4165 (7)	0.3615 (4)	0.3203 (5)	0.024 (2)
C26	0.3939 (8)	0.2948 (4)	0.3486 (6)	0.039 (2)
H26	0.3273	0.272	0.3318	0.047*
C27	0.4674 (9)	0.2605 (5)	0.4016 (6)	0.041 (3)
H27	0.4495	0.2153	0.422	0.049*
C28	0.5646 (9)	0.2914 (5)	0.4242 (7)	0.047 (3)
H28	0.6151	0.2677	0.4597	0.03 (2)*
C29	0.5888 (10)	0.3562 (6)	0.3955 (8)	0.072 (4)
H29	0.6562	0.3783	0.4119	0.086*
C30	0.5169 (10)	0.3908 (6)	0.3427 (8)	0.063 (4)
H30	0.5368	0.4352	0.3216	0.075*
C31	0.2195 (7)	0.4395 (4)	0.3270 (5)	0.0201 (18)
C32	0.2433 (7)	0.4420 (4)	0.4068 (5)	0.0227 (19)
H32	0.3152	0.4312	0.4274	0.027*
C33	0.1644 (7)	0.4599 (4)	0.4577 (5)	0.027 (2)
H33	0.1823	0.4621	0.5125	0.033*
C34	0.0596 (8)	0.4745 (4)	0.4279 (6)	0.034 (2)
H34	0.0042	0.4843	0.4625	0.04*
C35	0.0344 (7)	0.4749 (4)	0.3474 (5)	0.032 (2)
H35	−0.0372	0.4865	0.3268	0.038*
C36	0.1146 (7)	0.4583 (4)	0.2979 (5)	0.027 (2)
H36	0.0981	0.4598	0.2429	0.033*
C37	0.3573 (7)	0.6428 (4)	0.2919 (5)	0.0239 (19)
C38	0.3235 (6)	0.7094 (4)	0.3317 (5)	0.0192 (17)
C39	0.2333 (7)	0.7089 (4)	0.3752 (5)	0.027 (2)
C40	0.2025 (7)	0.7728 (4)	0.4103 (5)	0.031 (2)
H40	0.142	0.7725	0.4421	0.037*
C41	0.2566 (8)	0.8355 (4)	0.4004 (5)	0.032 (2)
C42	0.3452 (7)	0.8341 (4)	0.3554 (6)	0.033 (2)
H42	0.3831	0.8773	0.3477	0.039*
C43	0.3821 (7)	0.7726 (4)	0.3206 (5)	0.026 (2)
C44	0.1675 (7)	0.6423 (4)	0.3855 (5)	0.028 (2)
H44A	0.1216	0.6329	0.3375	0.042*
H44B	0.1211	0.6487	0.4293	0.042*
H44C	0.217	0.6021	0.3964	0.042*
C45	0.2205 (8)	0.9052 (5)	0.4346 (7)	0.052 (3)
H45A	0.1775	0.9322	0.3943	0.078*
H45B	0.2848	0.9329	0.4529	0.078*
H45C	0.1757	0.8956	0.4786	0.078*
C46	0.4780 (8)	0.7750 (5)	0.2706 (6)	0.036 (2)
H46A	0.506	0.8238	0.2692	0.054*
H46B	0.455	0.7595	0.2174	0.054*
H46C	0.5356	0.7434	0.2928	0.054*
C47	0.2882 (7)	0.5689 (4)	0.6337 (5)	0.0205 (19)
C48	0.3469 (6)	0.5071 (4)	0.6446 (4)	0.0226 (16)
H48	0.3306	0.4749	0.6849	0.027*
C49	0.4303 (6)	0.4922 (5)	0.5961 (5)	0.033 (2)
H49	0.4724	0.4501	0.6038	0.04*
C50	0.4518 (7)	0.5385 (4)	0.5372 (5)	0.027 (2)
H50	0.5081	0.5277	0.5037	0.032*
C51	0.3940 (7)	0.5990 (4)	0.5262 (5)	0.0261 (19)
H51	0.4095	0.6303	0.4849	0.031*
C52	0.3123 (7)	0.6156 (4)	0.5749 (5)	0.0205 (18)
H52	0.2729	0.6589	0.568	0.025*
C53	0.0949 (7)	0.6534 (4)	0.6466 (5)	0.0205 (19)
C54	0.0268 (8)	0.6269 (5)	0.5854 (6)	0.035 (2)
H54	0.0264	0.5774	0.574	0.042*
C55	−0.0398 (8)	0.6721 (5)	0.5416 (6)	0.039 (2)
H55	−0.0845	0.654	0.4986	0.047*
C56	−0.0428 (8)	0.7441 (5)	0.5591 (6)	0.041 (3)
H56	−0.0901	0.7753	0.5293	0.049*
C57	0.0230 (9)	0.7689 (5)	0.6196 (6)	0.044 (3)
H57	0.0221	0.8182	0.6316	0.052*
C58	0.0920 (9)	0.7240 (4)	0.6644 (6)	0.037 (2)
H58	0.1368	0.7424	0.7072	0.044*
C59	0.2580 (7)	0.6421 (4)	0.7776 (5)	0.023 (2)
C60	0.3575 (7)	0.6742 (5)	0.7681 (5)	0.031 (2)
H60	0.3881	0.672	0.7187	0.038*
C61	0.4130 (8)	0.7095 (5)	0.8297 (7)	0.042 (3)
H61	0.4817	0.7309	0.8223	0.051*
C62	0.3696 (9)	0.7140 (5)	0.9013 (6)	0.039 (3)
H62	0.4073	0.7385	0.9434	0.047*
C63	0.2720 (9)	0.6826 (5)	0.9108 (5)	0.039 (2)
H63	0.2418	0.6853	0.9603	0.047*
C64	0.2153 (8)	0.6470 (4)	0.8504 (5)	0.033 (2)
H64	0.1468	0.6257	0.8587	0.04*
C65	−0.1776 (6)	0.5413 (4)	0.7927 (5)	0.0186 (18)
C66	−0.1689 (7)	0.5843 (4)	0.7267 (5)	0.028 (2)
H66	−0.0994	0.5921	0.7069	0.033*
C67	−0.2600 (8)	0.6154 (5)	0.6903 (5)	0.037 (2)
H67	−0.2536	0.6453	0.6461	0.044*
C68	−0.3618 (8)	0.6029 (5)	0.7186 (6)	0.036 (2)
H68	−0.4252	0.6227	0.6922	0.044*
C69	−0.3716 (8)	0.5623 (5)	0.7840 (7)	0.046 (3)
H69	−0.4411	0.5556	0.8041	0.055*
C70	−0.2796 (7)	0.5310 (4)	0.8209 (5)	0.033 (2)
H70	−0.2865	0.5023	0.8659	0.039*
C71	−0.1103 (6)	0.4132 (4)	0.8693 (5)	0.0172 (17)
C72	−0.1423 (7)	0.3633 (4)	0.8124 (5)	0.0245 (19)
H72	−0.1327	0.3731	0.7589	0.029*
C73	−0.1874 (7)	0.3002 (4)	0.8330 (5)	0.027 (2)
H73	−0.2086	0.2664	0.7936	0.033*
C74	−0.2028 (7)	0.2847 (4)	0.9099 (5)	0.0226 (19)
H74	−0.2353	0.2409	0.9233	0.027*
C75	−0.1701 (7)	0.3339 (4)	0.9681 (5)	0.025 (2)
H75	−0.1791	0.3235	1.0216	0.03*
C76	−0.1243 (7)	0.3980 (4)	0.9470 (6)	0.022 (2)
H76	−0.1025	0.4318	0.9862	0.027*
C77	−0.0179 (7)	0.5433 (4)	0.9288 (4)	0.0181 (17)
C78	0.0806 (7)	0.5235 (4)	0.9694 (5)	0.028 (2)
H78	0.1248	0.4877	0.9485	0.034*
C79	0.1132 (7)	0.5551 (4)	1.0388 (5)	0.026 (2)
H79	0.1799	0.541	1.0658	0.032*
C80	0.0505 (8)	0.6071 (4)	1.0701 (5)	0.031 (2)
H80	0.0741	0.6293	1.1181	0.037*
C81	−0.0467 (8)	0.6268 (4)	1.0311 (5)	0.031 (2)
H81	−0.0913	0.6617	1.0532	0.037*
C82	−0.0800 (7)	0.5959 (4)	0.9595 (5)	0.023 (2)
H82	−0.1457	0.6111	0.9319	0.028*
C83	0.1407 (7)	0.3413 (4)	0.6917 (5)	0.026 (2)
C84	0.1726 (6)	0.2670 (4)	0.6706 (5)	0.0210 (18)
C85	0.2533 (7)	0.2548 (4)	0.6198 (5)	0.026 (2)
C86	0.2813 (7)	0.1847 (4)	0.6036 (5)	0.029 (2)
H86	0.3362	0.1763	0.5682	0.034*
C87	0.2323 (7)	0.1265 (4)	0.6371 (5)	0.028 (2)
C88	0.1518 (7)	0.1405 (4)	0.6877 (5)	0.030 (2)
H88	0.1168	0.1017	0.7112	0.036*
C89	0.1201 (7)	0.2095 (4)	0.7054 (5)	0.027 (2)
C90	0.3104 (8)	0.3148 (5)	0.5811 (6)	0.035 (2)
H90A	0.2656	0.3309	0.5349	0.052*
H90B	0.3813	0.2983	0.5652	0.052*
H90C	0.3215	0.3544	0.618	0.052*
C91	0.2626 (7)	0.0513 (4)	0.6189 (6)	0.039 (2)
H91A	0.1982	0.0262	0.5958	0.058*
H91B	0.2895	0.0273	0.6671	0.058*
H91C	0.3198	0.0514	0.5817	0.058*
C92	0.0331 (8)	0.2227 (5)	0.7608 (6)	0.036 (2)
H92A	−0.0015	0.1775	0.7732	0.054*
H92B	−0.0219	0.255	0.7365	0.054*
H92C	0.0658	0.2441	0.809	0.054*
Au1	0.40956 (2)	0.506823 (14)	0.195725 (18)	0.02387 (8)
Au2	0.09083 (2)	0.494836 (13)	0.754908 (17)	0.02288 (8)
P1	0.54579 (17)	0.51733 (10)	0.10953 (12)	0.0207 (5)
P2	0.32074 (19)	0.41526 (11)	0.25841 (14)	0.0216 (5)
P3	0.18320 (17)	0.58916 (10)	0.70196 (13)	0.0184 (5)
P4	−0.05466 (14)	0.49726 (12)	0.83623 (10)	0.0181 (4)
S1	0.46054 (19)	0.59383 (11)	0.33036 (13)	0.0245 (5)
S2	0.29084 (19)	0.62080 (10)	0.20475 (14)	0.0255 (5)
S3	0.1950 (2)	0.37588 (11)	0.77695 (14)	0.0265 (5)
S4	0.05408 (19)	0.38847 (11)	0.63257 (14)	0.0270 (5)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.022 (5)	0.028 (4)	0.020 (5)	0.009 (3)	0.003 (4)	−0.002 (3)
C2	0.019 (4)	0.044 (5)	0.020 (4)	0.010 (5)	0.000 (3)	−0.001 (5)
C3	0.018 (5)	0.050 (5)	0.028 (5)	−0.003 (4)	−0.004 (4)	−0.002 (4)
C4	0.035 (6)	0.047 (6)	0.035 (6)	0.012 (5)	−0.013 (5)	−0.017 (5)
C5	0.041 (7)	0.027 (5)	0.066 (8)	−0.004 (4)	−0.002 (6)	0.003 (5)
C6	0.025 (6)	0.039 (5)	0.065 (8)	−0.006 (4)	−0.005 (5)	0.016 (5)
C7	0.018 (4)	0.021 (4)	0.018 (4)	−0.004 (3)	0.005 (3)	−0.008 (3)
C8	0.022 (5)	0.029 (4)	0.034 (6)	0.000 (4)	−0.006 (4)	−0.010 (4)
C9	0.022 (5)	0.035 (5)	0.045 (6)	0.005 (4)	0.002 (5)	−0.013 (4)
C10	0.034 (6)	0.040 (5)	0.025 (5)	−0.007 (4)	0.006 (4)	−0.015 (4)
C11	0.027 (5)	0.039 (5)	0.033 (5)	−0.001 (4)	−0.005 (4)	−0.009 (4)
C12	0.015 (4)	0.029 (4)	0.029 (4)	−0.002 (4)	−0.003 (3)	−0.011 (4)
C13	0.009 (4)	0.018 (4)	0.032 (5)	−0.003 (3)	0.003 (4)	0.002 (3)
C14	0.031 (5)	0.032 (5)	0.025 (5)	−0.009 (4)	0.004 (4)	−0.012 (4)
C15	0.036 (6)	0.042 (5)	0.035 (6)	−0.022 (4)	0.011 (5)	−0.014 (4)
C16	0.025 (6)	0.032 (5)	0.059 (8)	−0.009 (4)	0.012 (5)	−0.004 (5)
C17	0.026 (5)	0.033 (5)	0.035 (6)	−0.005 (4)	0.005 (4)	0.004 (4)
C18	0.022 (5)	0.026 (4)	0.026 (5)	−0.002 (4)	0.000 (4)	0.000 (4)
C19	0.025 (5)	0.016 (4)	0.022 (5)	0.002 (3)	−0.007 (4)	−0.004 (3)
C20	0.036 (6)	0.025 (4)	0.035 (6)	0.006 (4)	−0.002 (5)	−0.005 (4)
C21	0.053 (7)	0.037 (5)	0.031 (6)	0.016 (5)	0.000 (5)	−0.009 (4)
C22	0.034 (6)	0.027 (5)	0.057 (8)	0.007 (4)	−0.018 (5)	−0.014 (5)
C23	0.027 (6)	0.023 (5)	0.076 (9)	0.000 (4)	−0.008 (6)	−0.009 (5)
C24	0.035 (6)	0.029 (4)	0.035 (6)	−0.005 (4)	−0.013 (5)	0.001 (4)
C25	0.014 (5)	0.021 (4)	0.037 (6)	0.007 (3)	−0.007 (4)	0.000 (4)
C26	0.035 (6)	0.030 (5)	0.051 (7)	−0.003 (4)	−0.002 (5)	0.007 (4)
C27	0.048 (7)	0.030 (5)	0.042 (7)	0.010 (5)	−0.012 (5)	0.007 (4)
C28	0.049 (7)	0.036 (5)	0.052 (7)	0.017 (5)	−0.016 (6)	−0.003 (5)
C29	0.055 (8)	0.063 (7)	0.091 (11)	−0.018 (6)	−0.049 (8)	0.018 (7)
C30	0.053 (8)	0.040 (6)	0.091 (10)	−0.012 (5)	−0.024 (7)	0.016 (6)
C31	0.025 (5)	0.015 (4)	0.021 (5)	0.001 (3)	0.007 (4)	0.000 (3)
C32	0.023 (5)	0.024 (4)	0.021 (5)	0.002 (3)	−0.003 (4)	0.005 (3)
C33	0.038 (6)	0.026 (4)	0.017 (5)	0.002 (4)	0.001 (4)	−0.001 (3)
C34	0.036 (6)	0.031 (5)	0.036 (6)	−0.008 (4)	0.017 (5)	−0.010 (4)
C35	0.025 (5)	0.031 (5)	0.039 (6)	−0.004 (4)	−0.002 (4)	−0.002 (4)
C36	0.033 (6)	0.025 (4)	0.025 (5)	0.001 (4)	0.004 (4)	0.000 (4)
C37	0.020 (5)	0.023 (4)	0.028 (5)	−0.006 (3)	−0.001 (4)	0.000 (4)
C38	0.015 (4)	0.018 (4)	0.023 (5)	0.005 (3)	−0.009 (4)	−0.001 (3)
C39	0.025 (5)	0.029 (4)	0.025 (5)	0.006 (4)	−0.010 (4)	−0.002 (4)
C40	0.027 (5)	0.034 (5)	0.032 (6)	0.005 (4)	0.000 (4)	−0.008 (4)
C41	0.031 (6)	0.033 (5)	0.031 (6)	0.010 (4)	−0.012 (4)	−0.016 (4)
C42	0.024 (5)	0.020 (4)	0.051 (7)	0.001 (4)	−0.017 (5)	−0.003 (4)
C43	0.023 (5)	0.029 (4)	0.022 (5)	0.000 (4)	−0.015 (4)	0.000 (4)
C44	0.021 (5)	0.030 (4)	0.033 (6)	0.000 (4)	−0.003 (4)	0.001 (4)
C45	0.037 (6)	0.031 (5)	0.084 (9)	0.013 (4)	−0.026 (6)	−0.028 (5)
C46	0.037 (6)	0.037 (5)	0.033 (6)	−0.012 (4)	−0.003 (5)	0.004 (4)
C47	0.016 (5)	0.024 (4)	0.021 (5)	−0.007 (3)	0.003 (4)	−0.005 (3)
C48	0.025 (4)	0.020 (4)	0.023 (4)	0.000 (4)	0.005 (3)	0.005 (4)
C49	0.021 (4)	0.041 (5)	0.038 (5)	0.007 (4)	0.006 (4)	0.009 (5)
C50	0.019 (5)	0.029 (4)	0.032 (6)	0.000 (4)	0.003 (4)	0.004 (4)
C51	0.022 (5)	0.033 (4)	0.024 (5)	−0.009 (4)	0.002 (4)	0.002 (4)
C52	0.024 (5)	0.019 (4)	0.018 (5)	−0.003 (3)	−0.003 (4)	−0.003 (3)
C53	0.017 (5)	0.022 (4)	0.024 (5)	−0.001 (3)	0.006 (4)	0.002 (3)
C54	0.028 (6)	0.035 (5)	0.042 (6)	−0.003 (4)	0.003 (5)	0.001 (4)
C55	0.029 (6)	0.058 (6)	0.031 (6)	0.002 (5)	0.007 (5)	0.006 (5)
C56	0.035 (6)	0.053 (6)	0.035 (6)	0.015 (5)	0.003 (5)	0.023 (5)
C57	0.055 (7)	0.036 (5)	0.037 (6)	0.011 (5)	−0.014 (5)	−0.006 (4)
C58	0.053 (7)	0.027 (5)	0.030 (6)	0.002 (4)	−0.005 (5)	0.003 (4)
C59	0.033 (6)	0.010 (3)	0.026 (5)	0.004 (3)	0.009 (4)	0.002 (3)
C60	0.025 (5)	0.041 (5)	0.028 (5)	0.004 (4)	0.000 (4)	−0.007 (4)
C61	0.013 (5)	0.048 (6)	0.065 (8)	0.000 (4)	−0.007 (5)	−0.015 (5)
C62	0.051 (7)	0.030 (5)	0.033 (6)	0.008 (5)	−0.012 (5)	−0.007 (4)
C63	0.067 (8)	0.035 (5)	0.014 (5)	−0.013 (5)	−0.004 (5)	−0.005 (4)
C64	0.052 (7)	0.023 (4)	0.024 (5)	−0.008 (4)	0.000 (5)	−0.006 (4)
C65	0.009 (4)	0.020 (4)	0.026 (5)	−0.008 (3)	0.000 (3)	−0.005 (3)
C66	0.018 (5)	0.033 (4)	0.032 (5)	0.000 (4)	0.008 (4)	0.004 (4)
C67	0.044 (6)	0.037 (5)	0.030 (6)	0.010 (4)	0.004 (5)	0.012 (4)
C68	0.022 (5)	0.048 (6)	0.037 (6)	0.002 (4)	−0.010 (5)	0.012 (5)
C69	0.025 (6)	0.051 (6)	0.061 (8)	0.010 (5)	0.002 (5)	0.010 (5)
C70	0.035 (6)	0.037 (5)	0.027 (5)	−0.001 (4)	0.004 (4)	0.001 (4)
C71	0.019 (4)	0.019 (4)	0.014 (4)	0.005 (3)	−0.002 (3)	0.002 (3)
C72	0.026 (5)	0.028 (4)	0.020 (5)	−0.003 (4)	0.002 (4)	0.001 (3)
C73	0.028 (5)	0.023 (4)	0.031 (6)	0.001 (4)	0.002 (4)	−0.006 (4)
C74	0.022 (5)	0.020 (4)	0.026 (5)	−0.003 (3)	0.002 (4)	0.004 (3)
C75	0.031 (5)	0.029 (4)	0.016 (5)	−0.002 (4)	0.000 (4)	0.002 (4)
C76	0.022 (5)	0.019 (4)	0.026 (5)	0.005 (3)	0.005 (4)	−0.002 (4)
C77	0.024 (5)	0.020 (4)	0.010 (4)	−0.002 (3)	0.002 (4)	0.004 (3)
C78	0.019 (5)	0.025 (4)	0.041 (6)	0.003 (3)	0.004 (4)	−0.005 (4)
C79	0.020 (5)	0.036 (5)	0.023 (5)	0.001 (4)	−0.003 (4)	−0.007 (4)
C80	0.038 (6)	0.034 (5)	0.021 (5)	−0.010 (4)	0.005 (4)	−0.006 (4)
C81	0.033 (6)	0.029 (4)	0.032 (6)	0.005 (4)	0.008 (4)	−0.003 (4)
C82	0.024 (5)	0.027 (4)	0.020 (5)	0.000 (4)	0.004 (4)	0.000 (4)
C83	0.018 (5)	0.029 (4)	0.031 (6)	−0.004 (3)	0.007 (4)	0.001 (4)
C84	0.012 (4)	0.023 (4)	0.028 (5)	0.002 (3)	−0.003 (4)	−0.003 (3)
C85	0.023 (5)	0.020 (4)	0.035 (5)	−0.001 (3)	−0.005 (4)	−0.002 (4)
C86	0.017 (5)	0.034 (5)	0.034 (6)	0.003 (4)	−0.005 (4)	−0.009 (4)
C87	0.016 (5)	0.024 (4)	0.042 (6)	0.001 (3)	−0.010 (4)	−0.005 (4)
C88	0.032 (6)	0.022 (4)	0.034 (6)	0.003 (4)	−0.008 (4)	0.006 (4)
C89	0.027 (5)	0.029 (4)	0.025 (5)	−0.008 (4)	−0.007 (4)	0.000 (4)
C90	0.032 (6)	0.035 (5)	0.038 (6)	0.004 (4)	0.005 (5)	0.006 (4)
C91	0.024 (5)	0.021 (4)	0.070 (8)	0.000 (4)	−0.005 (5)	−0.011 (4)
C92	0.039 (6)	0.028 (5)	0.041 (6)	−0.008 (4)	0.011 (5)	0.001 (4)
Au1	0.02401 (17)	0.02290 (16)	0.02517 (17)	−0.00147 (14)	0.00511 (13)	−0.00087 (15)
Au2	0.02475 (17)	0.02023 (15)	0.02442 (17)	−0.00101 (14)	0.00715 (13)	−0.00076 (14)
P1	0.0180 (11)	0.0210 (11)	0.0233 (11)	−0.0001 (8)	0.0029 (9)	−0.0029 (8)
P2	0.0211 (13)	0.0207 (10)	0.0229 (13)	0.0002 (9)	0.0003 (10)	−0.0016 (9)
P3	0.0185 (12)	0.0184 (10)	0.0186 (12)	0.0003 (8)	0.0037 (9)	−0.0012 (8)
P4	0.0178 (9)	0.0183 (9)	0.0180 (9)	0.0000 (10)	−0.0011 (7)	−0.0007 (10)
S1	0.0253 (13)	0.0277 (11)	0.0201 (12)	0.0043 (9)	−0.0005 (10)	0.0005 (9)
S2	0.0273 (13)	0.0212 (10)	0.0265 (13)	0.0074 (9)	−0.0084 (10)	−0.0019 (9)
S3	0.0305 (14)	0.0192 (10)	0.0286 (14)	0.0043 (9)	−0.0068 (11)	0.0004 (9)
S4	0.0245 (13)	0.0278 (11)	0.0285 (13)	0.0005 (9)	0.0011 (10)	0.0032 (9)

Geometric parameters (Å, º)

C1—C6	1.365 (11)	C48—H48	0.95
C1—C2	1.403 (11)	C49—C50	1.371 (12)
C1—P1	1.828 (8)	C49—H49	0.95
C2—C3	1.400 (11)	C50—C51	1.346 (11)
C2—H2	0.95	C50—H50	0.95
C3—C4	1.380 (13)	C51—C52	1.384 (11)
C3—H3	0.95	C51—H51	0.95
C4—C5	1.365 (13)	C52—H52	0.95
C4—H4	0.95	C53—C58	1.363 (11)
C5—C6	1.380 (13)	C53—C54	1.388 (13)
C5—H5	0.95	C53—P3	1.843 (9)
C6—H6	0.95	C54—C55	1.368 (13)
C7—C8	1.374 (10)	C54—H54	0.95
C7—C12	1.403 (10)	C55—C56	1.388 (13)
C7—P1	1.822 (8)	C55—H55	0.95
C8—C9	1.393 (12)	C56—C57	1.352 (14)
C8—H8	0.95	C56—H56	0.95
C9—C10	1.376 (13)	C57—C58	1.390 (13)
C9—H9	0.95	C57—H57	0.95
C10—C11	1.393 (12)	C58—H58	0.95
C10—H10	0.95	C59—C60	1.382 (12)
C11—C12	1.383 (11)	C59—C64	1.388 (12)
C11—H11	0.95	C59—P3	1.831 (9)
C12—H12	0.95	C60—C61	1.387 (13)
C13—C14	1.381 (11)	C60—H60	0.95
C13—C18	1.391 (11)	C61—C62	1.373 (14)
C13—P1	1.826 (8)	C61—H61	0.95
C14—C15	1.383 (12)	C62—C63	1.355 (14)
C14—H14	0.95	C62—H62	0.95
C15—C16	1.379 (13)	C63—C64	1.381 (12)
C15—H15	0.95	C63—H63	0.95
C16—C17	1.386 (13)	C64—H64	0.95
C16—H16	0.95	C65—C70	1.386 (11)
C17—C18	1.390 (11)	C65—C66	1.401 (11)
C17—H17	0.95	C65—P4	1.834 (8)
C18—H18	0.95	C66—C67	1.373 (12)
C19—C20	1.394 (12)	C66—H66	0.95
C19—C24	1.401 (12)	C67—C68	1.391 (13)
C19—P2	1.823 (9)	C67—H67	0.95
C20—C21	1.383 (13)	C68—C69	1.368 (13)
C20—H20	0.95	C68—H68	0.95
C21—C22	1.372 (14)	C69—C70	1.387 (13)
C21—H21	0.95	C69—H69	0.95
C22—C23	1.388 (14)	C70—H70	0.95
C22—H22	0.95	C71—C76	1.384 (12)
C23—C24	1.387 (13)	C71—C72	1.390 (11)
C23—H23	0.95	C71—P4	1.828 (8)
C24—H24	0.95	C72—C73	1.367 (11)
C25—C26	1.379 (12)	C72—H72	0.95
C25—C30	1.380 (14)	C73—C74	1.374 (12)
C25—P2	1.832 (8)	C73—H73	0.95
C26—C27	1.394 (13)	C74—C75	1.399 (11)
C26—H26	0.95	C74—H74	0.95
C27—C28	1.359 (14)	C75—C76	1.389 (11)
C27—H27	0.95	C75—H75	0.95
C28—C29	1.355 (15)	C76—H76	0.95
C28—H28	0.95	C77—C82	1.375 (11)
C29—C30	1.382 (15)	C77—C78	1.403 (11)
C29—H29	0.95	C77—P4	1.836 (8)
C30—H30	0.95	C78—C79	1.364 (11)
C31—C32	1.379 (11)	C78—H78	0.95
C31—C36	1.394 (12)	C79—C80	1.376 (11)
C31—P2	1.826 (8)	C79—H79	0.95
C32—C33	1.389 (11)	C80—C81	1.378 (13)
C32—H32	0.95	C80—H80	0.95
C33—C34	1.379 (12)	C81—C82	1.393 (12)
C33—H33	0.95	C81—H81	0.95
C34—C35	1.392 (12)	C82—H82	0.95
C34—H34	0.95	C83—C84	1.501 (11)
C35—C36	1.378 (11)	C83—S4	1.673 (9)
C35—H35	0.95	C83—S3	1.693 (10)
C36—H36	0.95	C84—C85	1.383 (11)
C37—C38	1.497 (11)	C84—C89	1.410 (11)
C37—S1	1.666 (9)	C85—C86	1.395 (11)
C37—S2	1.703 (9)	C85—C90	1.507 (12)
C38—C39	1.376 (12)	C86—C87	1.391 (12)
C38—C43	1.409 (11)	C86—H86	0.95
C39—C40	1.409 (11)	C87—C88	1.384 (12)
C39—C44	1.506 (11)	C87—C91	1.500 (11)
C40—C41	1.369 (12)	C88—C89	1.394 (11)
C40—H40	0.95	C88—H88	0.95
C41—C42	1.375 (13)	C89—C92	1.498 (12)
C41—C45	1.514 (11)	C90—H90A	0.98
C42—C43	1.392 (12)	C90—H90B	0.98
C42—H42	0.95	C90—H90C	0.98
C43—C46	1.502 (12)	C91—H91A	0.98
C44—H44A	0.98	C91—H91B	0.98
C44—H44B	0.98	C91—H91C	0.98
C44—H44C	0.98	C92—H92A	0.98
C45—H45A	0.98	C92—H92B	0.98
C45—H45B	0.98	C92—H92C	0.98
C45—H45C	0.98	Au1—P1	2.314 (2)
C46—H46A	0.98	Au1—P2	2.338 (2)
C46—H46B	0.98	Au1—S2	2.602 (2)
C46—H46C	0.98	Au1—S1	2.862 (2)
C47—C48	1.372 (11)	Au2—P3	2.323 (2)
C47—C52	1.384 (11)	Au2—P4	2.340 (2)
C47—P3	1.839 (8)	Au2—S3	2.592 (2)
C48—C49	1.391 (10)	Au2—S4	2.910 (2)
C6—C1—C2	118.4 (8)	C54—C53—P3	117.1 (6)
C6—C1—P1	119.1 (7)	C55—C54—C53	119.9 (9)
C2—C1—P1	122.3 (6)	C55—C54—H54	120.1
C3—C2—C1	120.6 (9)	C53—C54—H54	120.1
C3—C2—H2	119.7	C54—C55—C56	120.7 (10)
C1—C2—H2	119.7	C54—C55—H55	119.7
C4—C3—C2	119.1 (9)	C56—C55—H55	119.7
C4—C3—H3	120.4	C57—C56—C55	118.7 (9)
C2—C3—H3	120.4	C57—C56—H56	120.7
C5—C4—C3	119.8 (9)	C55—C56—H56	120.7
C5—C4—H4	120.1	C56—C57—C58	121.5 (9)
C3—C4—H4	120.1	C56—C57—H57	119.2
C4—C5—C6	121.2 (9)	C58—C57—H57	119.2
C4—C5—H5	119.4	C53—C58—C57	119.5 (9)
C6—C5—H5	119.4	C53—C58—H58	120.3
C1—C6—C5	120.7 (9)	C57—C58—H58	120.3
C1—C6—H6	119.6	C60—C59—C64	118.0 (9)
C5—C6—H6	119.6	C60—C59—P3	123.9 (7)
C8—C7—C12	119.4 (7)	C64—C59—P3	118.0 (7)
C8—C7—P1	123.1 (7)	C59—C60—C61	120.8 (9)
C12—C7—P1	117.5 (5)	C59—C60—H60	119.6
C7—C8—C9	121.3 (8)	C61—C60—H60	119.6
C7—C8—H8	119.4	C62—C61—C60	120.6 (9)
C9—C8—H8	119.4	C62—C61—H61	119.7
C10—C9—C8	119.3 (8)	C60—C61—H61	119.7
C10—C9—H9	120.4	C63—C62—C61	118.7 (9)
C8—C9—H9	120.4	C63—C62—H62	120.6
C9—C10—C11	120.0 (9)	C61—C62—H62	120.6
C9—C10—H10	120	C62—C63—C64	121.8 (9)
C11—C10—H10	120	C62—C63—H63	119.1
C12—C11—C10	120.6 (9)	C64—C63—H63	119.1
C12—C11—H11	119.7	C63—C64—C59	120.1 (9)
C10—C11—H11	119.7	C63—C64—H64	119.9
C11—C12—C7	119.4 (8)	C59—C64—H64	119.9
C11—C12—H12	120.3	C70—C65—C66	118.9 (8)
C7—C12—H12	120.3	C70—C65—P4	122.2 (7)
C14—C13—C18	119.3 (7)	C66—C65—P4	118.9 (6)
C14—C13—P1	117.1 (7)	C67—C66—C65	120.4 (8)
C18—C13—P1	123.4 (6)	C67—C66—H66	119.8
C13—C14—C15	120.3 (8)	C65—C66—H66	119.8
C13—C14—H14	119.8	C66—C67—C68	119.6 (8)
C15—C14—H14	119.8	C66—C67—H67	120.2
C16—C15—C14	120.7 (9)	C68—C67—H67	120.2
C16—C15—H15	119.7	C69—C68—C67	120.7 (9)
C14—C15—H15	119.7	C69—C68—H68	119.6
C15—C16—C17	119.5 (8)	C67—C68—H68	119.6
C15—C16—H16	120.3	C68—C69—C70	119.7 (9)
C17—C16—H16	120.3	C68—C69—H69	120.1
C16—C17—C18	120.0 (9)	C70—C69—H69	120.1
C16—C17—H17	120	C65—C70—C69	120.6 (9)
C18—C17—H17	120	C65—C70—H70	119.7
C17—C18—C13	120.2 (8)	C69—C70—H70	119.7
C17—C18—H18	119.9	C76—C71—C72	119.2 (7)
C13—C18—H18	119.9	C76—C71—P4	123.4 (6)
C20—C19—C24	118.0 (8)	C72—C71—P4	117.4 (6)
C20—C19—P2	118.7 (6)	C73—C72—C71	120.3 (8)
C24—C19—P2	122.7 (7)	C73—C72—H72	119.9
C21—C20—C19	120.1 (9)	C71—C72—H72	119.9
C21—C20—H20	120	C72—C73—C74	121.1 (8)
C19—C20—H20	120	C72—C73—H73	119.4
C22—C21—C20	121.8 (10)	C74—C73—H73	119.4
C22—C21—H21	119.1	C73—C74—C75	119.5 (7)
C20—C21—H21	119.1	C73—C74—H74	120.2
C21—C22—C23	119.0 (9)	C75—C74—H74	120.2
C21—C22—H22	120.5	C76—C75—C74	119.3 (8)
C23—C22—H22	120.5	C76—C75—H75	120.4
C24—C23—C22	119.8 (9)	C74—C75—H75	120.4
C24—C23—H23	120.1	C71—C76—C75	120.6 (8)
C22—C23—H23	120.1	C71—C76—H76	119.7
C23—C24—C19	121.2 (9)	C75—C76—H76	119.7
C23—C24—H24	119.4	C82—C77—C78	118.9 (8)
C19—C24—H24	119.4	C82—C77—P4	124.0 (7)
C26—C25—C30	117.5 (9)	C78—C77—P4	117.1 (6)
C26—C25—P2	124.7 (7)	C79—C78—C77	120.5 (7)
C30—C25—P2	117.8 (7)	C79—C78—H78	119.8
C25—C26—C27	120.9 (9)	C77—C78—H78	119.8
C25—C26—H26	119.6	C78—C79—C80	120.7 (8)
C27—C26—H26	119.6	C78—C79—H79	119.6
C28—C27—C26	120.3 (9)	C80—C79—H79	119.6
C28—C27—H27	119.9	C79—C80—C81	119.4 (8)
C26—C27—H27	119.9	C79—C80—H80	120.3
C29—C28—C27	119.4 (10)	C81—C80—H80	120.3
C29—C28—H28	120.3	C80—C81—C82	120.4 (8)
C27—C28—H28	120.3	C80—C81—H81	119.8
C28—C29—C30	120.9 (11)	C82—C81—H81	119.8
C28—C29—H29	119.6	C77—C82—C81	120.0 (8)
C30—C29—H29	119.6	C77—C82—H82	120
C25—C30—C29	120.9 (10)	C81—C82—H82	120
C25—C30—H30	119.5	C84—C83—S4	120.9 (7)
C29—C30—H30	119.5	C84—C83—S3	118.1 (6)
C32—C31—C36	118.3 (8)	S4—C83—S3	121.0 (5)
C32—C31—P2	122.6 (7)	C85—C84—C89	120.4 (7)
C36—C31—P2	119.1 (6)	C85—C84—C83	121.1 (7)
C31—C32—C33	121.4 (8)	C89—C84—C83	118.5 (7)
C31—C32—H32	119.3	C84—C85—C86	118.6 (8)
C33—C32—H32	119.3	C84—C85—C90	121.8 (7)
C34—C33—C32	119.2 (8)	C86—C85—C90	119.5 (8)
C34—C33—H33	120.4	C87—C86—C85	122.8 (8)
C32—C33—H33	120.4	C87—C86—H86	118.6
C33—C34—C35	120.5 (8)	C85—C86—H86	118.6
C33—C34—H34	119.8	C88—C87—C86	117.2 (7)
C35—C34—H34	119.8	C88—C87—C91	120.5 (8)
C36—C35—C34	119.2 (9)	C86—C87—C91	122.3 (8)
C36—C35—H35	120.4	C87—C88—C89	122.3 (8)
C34—C35—H35	120.4	C87—C88—H88	118.8
C35—C36—C31	121.3 (8)	C89—C88—H88	118.8
C35—C36—H36	119.4	C88—C89—C84	118.7 (8)
C31—C36—H36	119.4	C88—C89—C92	120.8 (8)
C38—C37—S1	120.6 (7)	C84—C89—C92	120.5 (7)
C38—C37—S2	118.1 (6)	C85—C90—H90A	109.5
S1—C37—S2	121.2 (5)	C85—C90—H90B	109.5
C39—C38—C43	121.1 (7)	H90A—C90—H90B	109.5
C39—C38—C37	120.0 (7)	C85—C90—H90C	109.5
C43—C38—C37	118.8 (7)	H90A—C90—H90C	109.5
C38—C39—C40	118.4 (8)	H90B—C90—H90C	109.5
C38—C39—C44	121.8 (7)	C87—C91—H91A	109.5
C40—C39—C44	119.8 (8)	C87—C91—H91B	109.5
C41—C40—C39	122.4 (9)	H91A—C91—H91B	109.5
C41—C40—H40	118.8	C87—C91—H91C	109.5
C39—C40—H40	118.8	H91A—C91—H91C	109.5
C40—C41—C42	117.5 (8)	H91B—C91—H91C	109.5
C40—C41—C45	122.7 (9)	C89—C92—H92A	109.5
C42—C41—C45	119.8 (9)	C89—C92—H92B	109.5
C41—C42—C43	123.4 (8)	H92A—C92—H92B	109.5
C41—C42—H42	118.3	C89—C92—H92C	109.5
C43—C42—H42	118.3	H92A—C92—H92C	109.5
C42—C43—C38	117.3 (8)	H92B—C92—H92C	109.5
C42—C43—C46	120.6 (8)	P1—Au1—P2	137.40 (7)
C38—C43—C46	122.1 (7)	P1—Au1—S2	113.57 (7)
C39—C44—H44A	109.5	P2—Au1—S2	107.36 (8)
C39—C44—H44B	109.5	P1—Au1—S1	109.74 (7)
H44A—C44—H44B	109.5	P2—Au1—S1	97.69 (7)
C39—C44—H44C	109.5	S2—Au1—S1	64.78 (7)
H44A—C44—H44C	109.5	P3—Au2—P4	129.10 (8)
H44B—C44—H44C	109.5	P3—Au2—S3	117.81 (8)
C41—C45—H45A	109.5	P4—Au2—S3	108.63 (8)
C41—C45—H45B	109.5	P3—Au2—S4	107.42 (7)
H45A—C45—H45B	109.5	P4—Au2—S4	110.81 (7)
C41—C45—H45C	109.5	S3—Au2—S4	64.05 (7)
H45A—C45—H45C	109.5	C7—P1—C13	103.9 (4)
H45B—C45—H45C	109.5	C7—P1—C1	104.7 (4)
C43—C46—H46A	109.5	C13—P1—C1	103.8 (4)
C43—C46—H46B	109.5	C7—P1—Au1	112.6 (2)
H46A—C46—H46B	109.5	C13—P1—Au1	117.5 (3)
C43—C46—H46C	109.5	C1—P1—Au1	113.1 (3)
H46A—C46—H46C	109.5	C19—P2—C31	100.7 (4)
H46B—C46—H46C	109.5	C19—P2—C25	110.1 (4)
C48—C47—C52	120.0 (7)	C31—P2—C25	101.7 (4)
C48—C47—P3	118.2 (6)	C19—P2—Au1	113.4 (3)
C52—C47—P3	121.7 (6)	C31—P2—Au1	118.1 (2)
C47—C48—C49	119.4 (8)	C25—P2—Au1	111.8 (3)
C47—C48—H48	120.3	C59—P3—C47	102.9 (4)
C49—C48—H48	120.3	C59—P3—C53	104.9 (4)
C50—C49—C48	119.9 (8)	C47—P3—C53	102.8 (4)
C50—C49—H49	120.1	C59—P3—Au2	111.9 (3)
C48—C49—H49	120.1	C47—P3—Au2	118.2 (3)
C51—C50—C49	120.9 (8)	C53—P3—Au2	114.6 (3)
C51—C50—H50	119.6	C71—P4—C65	101.6 (3)
C49—C50—H50	119.6	C71—P4—C77	102.5 (3)
C50—C51—C52	120.2 (8)	C65—P4—C77	106.6 (4)
C50—C51—H51	119.9	C71—P4—Au2	119.0 (3)
C52—C51—H51	119.9	C65—P4—Au2	114.0 (3)
C47—C52—C51	119.7 (8)	C77—P4—Au2	111.8 (3)
C47—C52—H52	120.2	C37—S1—Au1	83.0 (3)
C51—C52—H52	120.2	C37—S2—Au1	90.9 (3)
C58—C53—C54	119.7 (8)	C83—S3—Au2	92.6 (3)
C58—C53—P3	123.1 (7)	C83—S4—Au2	82.4 (3)
C6—C1—C2—C3	−2.6 (12)	C85—C84—C89—C88	0.3 (13)
P1—C1—C2—C3	−177.2 (6)	C83—C84—C89—C88	−178.1 (8)
C1—C2—C3—C4	1.5 (13)	C85—C84—C89—C92	179.7 (8)
C2—C3—C4—C5	0.6 (14)	C83—C84—C89—C92	1.2 (13)
C3—C4—C5—C6	−1.7 (16)	C8—C7—P1—C13	106.8 (7)
C2—C1—C6—C5	1.6 (15)	C12—C7—P1—C13	−72.2 (6)
P1—C1—C6—C5	176.4 (8)	C8—C7—P1—C1	−1.7 (8)
C4—C5—C6—C1	0.5 (17)	C12—C7—P1—C1	179.2 (6)
C12—C7—C8—C9	0.3 (12)	C8—C7—P1—Au1	−125.0 (6)
P1—C7—C8—C9	−178.7 (7)	C12—C7—P1—Au1	55.9 (6)
C7—C8—C9—C10	1.3 (14)	C14—C13—P1—C7	172.1 (7)
C8—C9—C10—C11	−2.4 (14)	C18—C13—P1—C7	−13.2 (8)
C9—C10—C11—C12	2.0 (13)	C14—C13—P1—C1	−78.6 (7)
C10—C11—C12—C7	−0.3 (13)	C18—C13—P1—C1	96.0 (7)
C8—C7—C12—C11	−0.8 (12)	C14—C13—P1—Au1	47.0 (7)
P1—C7—C12—C11	178.3 (6)	C18—C13—P1—Au1	−138.3 (6)
C18—C13—C14—C15	1.6 (13)	C6—C1—P1—C7	−79.8 (8)
P1—C13—C14—C15	176.5 (7)	C2—C1—P1—C7	94.8 (7)
C13—C14—C15—C16	−0.5 (15)	C6—C1—P1—C13	171.5 (8)
C14—C15—C16—C17	0.8 (15)	C2—C1—P1—C13	−13.9 (8)
C15—C16—C17—C18	−2.1 (14)	C6—C1—P1—Au1	43.1 (8)
C16—C17—C18—C13	3.2 (13)	C2—C1—P1—Au1	−142.2 (6)
C14—C13—C18—C17	−3.0 (12)	P2—Au1—P1—C7	65.0 (3)
P1—C13—C18—C17	−177.5 (7)	S2—Au1—P1—C7	−97.8 (3)
C24—C19—C20—C21	0.4 (12)	S1—Au1—P1—C7	−168.1 (3)
P2—C19—C20—C21	−170.5 (7)	P2—Au1—P1—C13	−174.4 (3)
C19—C20—C21—C22	−1.4 (13)	S2—Au1—P1—C13	22.8 (3)
C20—C21—C22—C23	0.2 (14)	S1—Au1—P1—C13	−47.5 (3)
C21—C22—C23—C24	2.0 (14)	P2—Au1—P1—C1	−53.5 (3)
C22—C23—C24—C19	−3.0 (14)	S2—Au1—P1—C1	143.7 (3)
C20—C19—C24—C23	1.8 (13)	S1—Au1—P1—C1	73.4 (3)
P2—C19—C24—C23	172.3 (7)	C20—C19—P2—C31	124.5 (7)
C30—C25—C26—C27	3.8 (15)	C24—C19—P2—C31	−46.0 (8)
P2—C25—C26—C27	−173.7 (8)	C20—C19—P2—C25	−128.7 (7)
C25—C26—C27—C28	−2.2 (16)	C24—C19—P2—C25	60.8 (8)
C26—C27—C28—C29	0.8 (17)	C20—C19—P2—Au1	−2.6 (8)
C27—C28—C29—C30	−1 (2)	C24—C19—P2—Au1	−173.1 (6)
C26—C25—C30—C29	−4.0 (18)	C32—C31—P2—C19	138.1 (6)
P2—C25—C30—C29	173.6 (11)	C36—C31—P2—C19	−43.8 (7)
C28—C29—C30—C25	3 (2)	C32—C31—P2—C25	24.8 (7)
C36—C31—C32—C33	2.6 (11)	C36—C31—P2—C25	−157.1 (6)
P2—C31—C32—C33	−179.3 (6)	C32—C31—P2—Au1	−97.9 (6)
C31—C32—C33—C34	1.0 (12)	C36—C31—P2—Au1	80.2 (7)
C32—C33—C34—C35	−3.3 (12)	C26—C25—P2—C19	−36.2 (10)
C33—C34—C35—C36	2.1 (12)	C30—C25—P2—C19	146.3 (9)
C34—C35—C36—C31	1.6 (12)	C26—C25—P2—C31	69.9 (9)
C32—C31—C36—C35	−3.9 (11)	C30—C25—P2—C31	−107.5 (9)
P2—C31—C36—C35	178.0 (6)	C26—C25—P2—Au1	−163.2 (7)
S1—C37—C38—C39	−101.3 (9)	C30—C25—P2—Au1	19.4 (9)
S2—C37—C38—C39	81.1 (9)	P1—Au1—P2—C19	−65.7 (3)
S1—C37—C38—C43	81.8 (9)	S2—Au1—P2—C19	97.8 (3)
S2—C37—C38—C43	−95.8 (8)	S1—Au1—P2—C19	163.7 (3)
C43—C38—C39—C40	−1.8 (13)	P1—Au1—P2—C31	176.9 (3)
C37—C38—C39—C40	−178.6 (8)	S2—Au1—P2—C31	−19.6 (3)
C43—C38—C39—C44	178.0 (8)	S1—Au1—P2—C31	46.3 (3)
C37—C38—C39—C44	1.2 (12)	P1—Au1—P2—C25	59.4 (3)
C38—C39—C40—C41	2.4 (13)	S2—Au1—P2—C25	−137.1 (3)
C44—C39—C40—C41	−177.3 (8)	S1—Au1—P2—C25	−71.2 (3)
C39—C40—C41—C42	−1.3 (14)	C60—C59—P3—C47	17.1 (8)
C39—C40—C41—C45	176.8 (9)	C64—C59—P3—C47	−159.2 (7)
C40—C41—C42—C43	−0.5 (14)	C60—C59—P3—C53	−90.2 (8)
C45—C41—C42—C43	−178.6 (8)	C64—C59—P3—C53	93.6 (7)
C41—C42—C43—C38	1.0 (13)	C60—C59—P3—Au2	145.0 (6)
C41—C42—C43—C46	178.6 (9)	C64—C59—P3—Au2	−31.2 (7)
C39—C38—C43—C42	0.1 (12)	C48—C47—P3—C59	91.6 (7)
C37—C38—C43—C42	177.0 (8)	C52—C47—P3—C59	−85.2 (7)
C39—C38—C43—C46	−177.4 (8)	C48—C47—P3—C53	−159.6 (7)
C37—C38—C43—C46	−0.6 (12)	C52—C47—P3—C53	23.6 (8)
C52—C47—C48—C49	0.0 (12)	C48—C47—P3—Au2	−32.3 (8)
P3—C47—C48—C49	−176.9 (6)	C52—C47—P3—Au2	150.9 (6)
C47—C48—C49—C50	−1.2 (13)	C58—C53—P3—C59	−0.7 (9)
C48—C49—C50—C51	1.0 (14)	C54—C53—P3—C59	−179.0 (7)
C49—C50—C51—C52	0.5 (13)	C58—C53—P3—C47	−108.1 (8)
C48—C47—C52—C51	1.5 (12)	C54—C53—P3—C47	73.7 (7)
P3—C47—C52—C51	178.2 (6)	C58—C53—P3—Au2	122.4 (7)
C50—C51—C52—C47	−1.7 (12)	C54—C53—P3—Au2	−55.8 (7)
C58—C53—C54—C55	2.5 (14)	P4—Au2—P3—C59	65.3 (3)
P3—C53—C54—C55	−179.3 (7)	S3—Au2—P3—C59	−88.1 (3)
C53—C54—C55—C56	−2.1 (14)	S4—Au2—P3—C59	−157.5 (3)
C54—C55—C56—C57	1.2 (15)	P4—Au2—P3—C47	−175.4 (3)
C55—C56—C57—C58	−0.7 (16)	S3—Au2—P3—C47	31.2 (3)
C54—C53—C58—C57	−1.9 (14)	S4—Au2—P3—C47	−38.2 (3)
P3—C53—C58—C57	180.0 (8)	P4—Au2—P3—C53	−54.0 (3)
C56—C57—C58—C53	1.0 (16)	S3—Au2—P3—C53	152.6 (3)
C64—C59—C60—C61	0.6 (13)	S4—Au2—P3—C53	83.3 (3)
P3—C59—C60—C61	−175.6 (7)	C76—C71—P4—C65	−105.6 (7)
C59—C60—C61—C62	−0.7 (14)	C72—C71—P4—C65	72.7 (7)
C60—C61—C62—C63	0.6 (14)	C76—C71—P4—C77	4.5 (8)
C61—C62—C63—C64	−0.4 (15)	C72—C71—P4—C77	−177.2 (6)
C62—C63—C64—C59	0.3 (15)	C76—C71—P4—Au2	128.3 (6)
C60—C59—C64—C63	−0.4 (13)	C72—C71—P4—Au2	−53.4 (7)
P3—C59—C64—C63	176.1 (7)	C70—C65—P4—C71	32.2 (7)
C70—C65—C66—C67	−0.5 (12)	C66—C65—P4—C71	−145.1 (6)
P4—C65—C66—C67	176.9 (7)	C70—C65—P4—C77	−74.7 (7)
C65—C66—C67—C68	−1.1 (14)	C66—C65—P4—C77	107.9 (7)
C66—C67—C68—C69	2.6 (15)	C70—C65—P4—Au2	161.4 (6)
C67—C68—C69—C70	−2.5 (16)	C66—C65—P4—Au2	−15.9 (7)
C66—C65—C70—C69	0.6 (13)	C82—C77—P4—C71	−101.0 (7)
P4—C65—C70—C69	−176.7 (7)	C78—C77—P4—C71	79.7 (6)
C68—C69—C70—C65	0.9 (15)	C82—C77—P4—C65	5.4 (8)
C76—C71—C72—C73	0.2 (12)	C78—C77—P4—C65	−173.9 (6)
P4—C71—C72—C73	−178.1 (6)	C82—C77—P4—Au2	130.6 (6)
C71—C72—C73—C74	0.4 (13)	C78—C77—P4—Au2	−48.7 (6)
C72—C73—C74—C75	−1.0 (13)	P3—Au2—P4—C71	−179.6 (3)
C73—C74—C75—C76	1.0 (12)	S3—Au2—P4—C71	−24.4 (3)
C72—C71—C76—C75	−0.2 (12)	S4—Au2—P4—C71	44.2 (3)
P4—C71—C76—C75	178.1 (7)	P3—Au2—P4—C65	60.4 (3)
C74—C75—C76—C71	−0.5 (13)	S3—Au2—P4—C65	−144.3 (3)
C82—C77—C78—C79	0.9 (12)	S4—Au2—P4—C65	−75.7 (3)
P4—C77—C78—C79	−179.7 (6)	P3—Au2—P4—C77	−60.5 (3)
C77—C78—C79—C80	−0.2 (13)	S3—Au2—P4—C77	94.8 (3)
C78—C79—C80—C81	0.7 (13)	S4—Au2—P4—C77	163.3 (3)
C79—C80—C81—C82	−1.9 (13)	C38—C37—S1—Au1	180.0 (7)
C78—C77—C82—C81	−2.1 (12)	S2—C37—S1—Au1	−2.5 (5)
P4—C77—C82—C81	178.6 (6)	P1—Au1—S1—C37	109.0 (3)
C80—C81—C82—C77	2.6 (13)	P2—Au1—S1—C37	−104.1 (3)
S4—C83—C84—C85	81.8 (10)	S2—Au1—S1—C37	1.5 (3)
S3—C83—C84—C85	−98.1 (9)	C38—C37—S2—Au1	−179.7 (6)
S4—C83—C84—C89	−99.8 (9)	S1—C37—S2—Au1	2.7 (5)
S3—C83—C84—C89	80.3 (9)	P1—Au1—S2—C37	−103.1 (3)
C89—C84—C85—C86	0.2 (13)	P2—Au1—S2—C37	89.0 (3)
C83—C84—C85—C86	178.6 (8)	S1—Au1—S2—C37	−1.5 (3)
C89—C84—C85—C90	179.5 (8)	C84—C83—S3—Au2	−179.6 (6)
C83—C84—C85—C90	−2.1 (13)	S4—C83—S3—Au2	0.5 (5)
C84—C85—C86—C87	−0.7 (13)	P3—Au2—S3—C83	−97.2 (3)
C90—C85—C86—C87	179.9 (8)	P4—Au2—S3—C83	104.4 (3)
C85—C86—C87—C88	0.7 (13)	S4—Au2—S3—C83	−0.3 (3)
C85—C86—C87—C91	179.6 (9)	C84—C83—S4—Au2	179.7 (7)
C86—C87—C88—C89	−0.2 (13)	S3—C83—S4—Au2	−0.5 (5)
C91—C87—C88—C89	−179.1 (8)	P3—Au2—S4—C83	113.3 (3)
C87—C88—C89—C84	−0.3 (13)	P4—Au2—S4—C83	−101.0 (3)
C87—C88—C89—C92	−179.6 (9)	S3—Au2—S4—C83	0.3 (3)