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The crystal structure of the mineral pearceite, (Ag,Cu)16(As,Sb)2S11, has been solved and refined at 300, 120 and 15 K. At room temperature pearceite crystallizes with trigonal symmetry, space group P\bar 3m1; the refinement of the structure leads to a residual factor of R = 0.0464 for 1109 independent observed reflections and 92 variables. The crystal structure consists of sheets stacked along the c axis. The As atoms form isolated (As,Sb)S3 pyramids, which typically occur in sulfosalts, copper cations link two S atoms in a linear coordination, and the silver cations are found in a fully occupied position and in various sites corresponding to the most pronounced probability density function locations (modes) of diffusion-like paths. These positions correspond to low-coordination (2, 3 and 4) sites, in agreement with the preference of silver for such environments. d10 silver-ion distribution has been determined by means of a combination of a Gram–Charlier description of the atomic displacement factors and a split-atom model. To analyse the crystal chemical behaviour of the silver cations as a function of temperature, a structural study was carried out at 120 K (R = 0.0450). The refinement indicates that the mineral exhibits the same structural arrangement as the room-temperature structure (space group P\overline 3m1) and shows that the silver cations are still highly disordered. In order to investigate a possible ordering scheme for the silver cations, a data collection at ultra-low temperature (15 K) was performed. The structural skeleton was found to be similar to that of the room-temperature and 120 K atomic structures, but the best solution was achieved with a fully split-atom model of five silver positions, giving an R value of 0.0449 for 651 observed reflections and 78 parameters. Although the silver cation densities condense into better defined modes, the joint probability density function still exhibits a strong overlapping of neighbouring sites.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S010876810600108X/lc5042sup1.cif
Contains datablocks global, 300K, 120K, 15K

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010876810600108X/lc5042300Ksup2.hkl
Contains datablocks global, (I)

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010876810600108X/lc5042120Ksup3.hkl
Contains datablocks global, (I)

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010876810600108X/lc504215Ksup4.hkl
Contains datablock 15K

Computing details top

For all compounds, program(s) used to refine structure: (Jana2000; Petricek and Dusek, 2000); software used to prepare material for publication: (Jana2000; Petricek and Dusek, 2000).

Figures top
[Figure 1]
[Figure 2]
[Figure 3]
[Figure 4]
(300K) top
Crystal data top
Ag13.034As1.179Cu2.966S11Sb0.821F(000) = 955
Mr = 2135.4Dx = 6.309 Mg m3
Trigonal, P3m1Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 3;-2"µ = 17.51 mm1
a = 7.3876 (4) ÅT = 300 K
c = 11.8882 (7) ÅPrism, black
V = 561.89 (5) Å30.15 × 0.15 × 0.04 mm
Z = 1
Data collection top
Nonius KappaCCD
diffractometer
1109 reflections with I > 2σ(I)
ω scansRint = 0.048
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
θmax = 40.0°, θmin = 6.5°
Tmin = 0.197, Tmax = 0.727h = 1313
20965 measured reflectionsk = 1212
1352 independent reflectionsl = 2121
Refinement top
Refinement on F2Weighting scheme based on measured s.u.'s w = 1/[σ2(I) + 0.001936I2]
R[F2 > 2σ(F2)] = 0.046(Δ/σ)max = 0.0003
wR(F2) = 0.127Δρmax = 1.41 e Å3
S = 1.89Δρmin = 1.00 e Å3
1352 reflectionsExtinction correction: B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)
92 parametersExtinction coefficient: 0.294979
Crystal data top
Ag13.034As1.179Cu2.966S11Sb0.821Z = 1
Mr = 2135.4Mo Kα radiation
Trigonal, P3m1µ = 17.51 mm1
a = 7.3876 (4) ÅT = 300 K
c = 11.8882 (7) Å0.15 × 0.15 × 0.04 mm
V = 561.89 (5) Å3
Data collection top
Nonius KappaCCD
diffractometer
1352 independent reflections
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
1109 reflections with I > 2σ(I)
Tmin = 0.197, Tmax = 0.727Rint = 0.048
20965 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.04692 parameters
wR(F2) = 0.127Δρmax = 1.41 e Å3
S = 1.89Δρmin = 1.00 e Å3
1352 reflections
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
As0.3333330.6666670.40748 (5)0.02317 (18)0.590 (13)
Sb0.3333330.6666670.4074760.02317 (18)0.410 (13)
Ag10.3009 (2)0.15043 (12)0.38526 (11)0.0528 (7)0.672 (18)
Cu10.3008670.1504340.3852640.0528 (7)0.328 (18)
Ag20.3566 (4)0.240 (3)0.1233 (2)0.345 (10)0.366 (4)
Ag30.2921 (9)0.3808 (8)0.1174 (3)0.119 (2)0.384 (4)
Cu20000.0282 (3)
S1000.18164 (12)0.0267 (4)
S20.01656 (16)0.50828 (8)0.31324 (9)0.0269 (3)
S30.6666670.3333330.0174 (2)0.0428 (6)
S4000.50.114 (3)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
As0.0242 (2)0.0242 (2)0.0211 (3)0.01210 (12)00
Sb0.0242 (2)0.0242 (2)0.0211 (3)0.01210 (12)00
Ag10.0676 (10)0.0404 (7)0.0596 (9)0.0338 (5)0.0021 (5)0.0011 (2)
Cu10.0676 (10)0.0404 (7)0.0596 (9)0.0338 (5)0.0021 (5)0.0011 (2)
Ag20.0388 (9)0.62 (2)0.0447 (7)0.082 (5)0.0064 (7)0.018 (5)
Ag30.194 (4)0.110 (2)0.0490 (13)0.072 (2)0.0287 (14)0.0002 (12)
Cu20.0350 (4)0.0350 (4)0.0148 (4)0.0175 (2)00
S10.0324 (5)0.0324 (5)0.0154 (5)0.0162 (3)00
S20.0219 (4)0.0251 (3)0.0325 (5)0.0109 (2)0.0009 (3)0.00045 (16)
S30.0437 (7)0.0437 (7)0.0411 (10)0.0219 (4)00
S40.157 (4)0.157 (4)0.028 (3)0.0787 (18)00
Geometric parameters (Å, º) top
As—Sb0Ag2—Ag31.35 (2)
As—S22.3157 (10)Ag2—Ag3v2.881 (5)
As—S2i2.3157 (12)Ag2—Ag3iv2.23 (2)
As—S2ii2.3157 (10)Ag2—Ag3vi2.658 (18)
Sb—S22.3157 (10)Ag2—Cu22.750 (4)
Sb—S2i2.3157 (12)Ag2—S12.428 (4)
Sb—S2ii2.3157 (10)Ag2—S2i2.836 (11)
Ag1—Cu10Ag2—S32.393 (5)
Ag1—S2i2.4459 (14)Ag3—Ag3ii2.417 (6)
Ag1—S2iii2.446 (2)Ag3—Ag3vi1.502 (12)
Ag1—S42.3592 (15)Ag3—Cu22.906 (4)
Cu1—S2i2.4459 (11)Ag3—S12.661 (4)
Cu1—S2iii2.4459 (11)Ag3—S2i2.664 (4)
Cu1—S42.3592Ag3—S3vii2.545 (6)
Ag2—Ag2ii2.980 (14)Cu2—S12.1594 (15)
Ag2—Ag2iv0.91 (3)Cu2—S1viii2.1594 (15)
Sb—As—S20Ag3ix—Cu2—Ag3xv106.7 (2)
Sb—As—S2i0Ag3ix—Cu2—S161.31 (8)
Sb—As—S2ii0Ag3ix—Cu2—S1viii118.69 (8)
S2—As—S2i98.57 (4)Ag3x—Cu2—Ag381.12 (17)
S2—As—S2ii98.57 (3)Ag3x—Cu2—Ag3viii98.88 (17)
S2i—As—S298.57 (4)Ag3x—Cu2—Ag3ix180
S2i—As—S2ii98.57 (4)Ag3x—Cu2—Ag3xi150.0 (2)
S2ii—As—S298.57 (3)Ag3x—Cu2—Ag3v30.0 (2)
S2ii—As—S2i98.57 (4)Ag3x—Cu2—Ag3xii81.1 (2)
As—Sb—S20Ag3x—Cu2—Ag3xiii98.9 (2)
As—Sb—S2i0Ag3x—Cu2—Ag3iv62.43 (15)
As—Sb—S2ii0Ag3x—Cu2—Ag3xiv117.57 (15)
S2—Sb—S2i98.57 (3)Ag3x—Cu2—Ag3vi106.7 (2)
S2—Sb—S2ii98.57 (3)Ag3x—Cu2—Ag3xv73.3 (2)
S2i—Sb—S298.57 (3)Ag3x—Cu2—S1118.69 (8)
S2i—Sb—S2ii98.57 (4)Ag3x—Cu2—S1viii61.31 (8)
S2ii—Sb—S298.57 (3)Ag3xi—Cu2—Ag3117.57 (12)
S2ii—Sb—S2i98.57 (4)Ag3xi—Cu2—Ag3viii62.43 (12)
Cu1—Ag1—S2i0Ag3xi—Cu2—Ag3ix30.0 (2)
Cu1—Ag1—S2iii0Ag3xi—Cu2—Ag3x150.0 (2)
Cu1—Ag1—S40Ag3xi—Cu2—Ag3v180
S2i—Ag1—S2iii104.86 (6)Ag3xi—Cu2—Ag3xii73.3 (2)
S2i—Ag1—S4127.57 (7)Ag3xi—Cu2—Ag3xiii106.7 (2)
S2iii—Ag1—S2i104.86 (6)Ag3xi—Cu2—Ag3iv98.88 (16)
S2iii—Ag1—S4127.57 (4)Ag3xi—Cu2—Ag3xiv81.12 (16)
Ag1—Cu1—S2i0Ag3xi—Cu2—Ag3vi98.88 (17)
Ag1—Cu1—S2iii0Ag3xi—Cu2—Ag3xv81.12 (17)
Ag1—Cu1—S40Ag3xi—Cu2—S161.31 (7)
S2i—Cu1—S2iii104.86 (3)Ag3xi—Cu2—S1viii118.69 (7)
S2i—Cu1—S4127.57 (2)Ag3v—Cu2—Ag362.43 (12)
S2iii—Cu1—S2i104.86 (3)Ag3v—Cu2—Ag3viii117.57 (12)
S2iii—Cu1—S4127.57 (2)Ag3v—Cu2—Ag3ix150.0 (2)
Ag2ii—Ag2—Ag2iv120.0 (5)Ag3v—Cu2—Ag3x30.0 (2)
Ag2ii—Ag2—Ag377.9 (7)Ag3v—Cu2—Ag3xi180
Ag2ii—Ag2—Ag3v84.4 (2)Ag3v—Cu2—Ag3xii106.7 (2)
Ag2ii—Ag2—Ag3iv130.7 (6)Ag3v—Cu2—Ag3xiii73.3 (2)
Ag2ii—Ag2—Ag3vi100.2 (7)Ag3v—Cu2—Ag3iv81.12 (16)
Ag2ii—Ag2—Cu2143.3 (4)Ag3v—Cu2—Ag3xiv98.88 (16)
Ag2ii—Ag2—S1155.2 (7)Ag3v—Cu2—Ag3vi81.12 (17)
Ag2ii—Ag2—S2i58.3 (3)Ag3v—Cu2—Ag3xv98.88 (17)
Ag2ii—Ag2—S351.5 (3)Ag3v—Cu2—S1118.69 (7)
Ag2iv—Ag2—Ag2ii120.0 (5)Ag3v—Cu2—S1viii61.31 (7)
Ag2iv—Ag2—Ag3161.8 (4)Ag3xii—Cu2—Ag398.88 (16)
Ag2iv—Ag2—Ag3v95.9 (5)Ag3xii—Cu2—Ag3viii81.12 (16)
Ag2iv—Ag2—Ag3iv10.8 (3)Ag3xii—Cu2—Ag3ix98.9 (2)
Ag2iv—Ag2—Ag3vi139.8 (4)Ag3xii—Cu2—Ag3x81.1 (2)
Ag2iv—Ag2—Cu280.5 (4)Ag3xii—Cu2—Ag3xi73.3 (2)
Ag2iv—Ag2—S179.2 (5)Ag3xii—Cu2—Ag3v106.7 (2)
Ag2iv—Ag2—S2i121.5 (4)Ag3xii—Cu2—Ag3xiii180
Ag2iv—Ag2—S379.0 (5)Ag3xii—Cu2—Ag3iv29.96 (17)
Ag3—Ag2—Ag3v82.3 (4)Ag3xii—Cu2—Ag3xiv150.04 (17)
Ag3—Ag2—Ag3iv151.0 (3)Ag3xii—Cu2—Ag3vi117.57 (15)
Ag3—Ag2—Ag3vi22.3 (2)Ag3xii—Cu2—Ag3xv62.43 (15)
Ag3—Ag2—Cu282.8 (3)Ag3xii—Cu2—S161.31 (10)
Ag3—Ag2—S184.5 (3)Ag3xii—Cu2—S1viii118.69 (10)
Ag3—Ag2—S2i68.8 (5)Ag3xiii—Cu2—Ag381.12 (16)
Ag3—Ag2—S3114.1 (7)Ag3xiii—Cu2—Ag3viii98.88 (16)
Ag3v—Ag2—Ag382.3 (4)Ag3xiii—Cu2—Ag3ix81.1 (2)
Ag3v—Ag2—Ag3iv94.5 (4)Ag3xiii—Cu2—Ag3x98.9 (2)
Ag3v—Ag2—Ag3vi86.0 (4)Ag3xiii—Cu2—Ag3xi106.7 (2)
Ag3v—Ag2—Cu262.09 (10)Ag3xiii—Cu2—Ag3v73.3 (2)
Ag3v—Ag2—S1110.69 (14)Ag3xiii—Cu2—Ag3xii180
Ag3v—Ag2—S2i136.1 (6)Ag3xiii—Cu2—Ag3iv150.04 (17)
Ag3v—Ag2—S356.80 (14)Ag3xiii—Cu2—Ag3xiv29.96 (17)
Ag3iv—Ag2—Ag3151.0 (3)Ag3xiii—Cu2—Ag3vi62.43 (15)
Ag3iv—Ag2—Ag3v94.5 (4)Ag3xiii—Cu2—Ag3xv117.57 (15)
Ag3iv—Ag2—Ag3vi129.0 (3)Ag3xiii—Cu2—S1118.69 (10)
Ag3iv—Ag2—Cu270.5 (3)Ag3xiii—Cu2—S1viii61.31 (10)
Ag3iv—Ag2—S169.5 (4)Ag3iv—Cu2—Ag373.3 (2)
Ag3iv—Ag2—S2i126.5 (4)Ag3iv—Cu2—Ag3viii106.7 (2)
Ag3iv—Ag2—S387.1 (6)Ag3iv—Cu2—Ag3ix117.57 (15)
Ag3vi—Ag2—Ag322.3 (2)Ag3iv—Cu2—Ag3x62.43 (15)
Ag3vi—Ag2—Ag3v86.0 (4)Ag3iv—Cu2—Ag3xi98.88 (16)
Ag3vi—Ag2—Ag3iv129.0 (3)Ag3iv—Cu2—Ag3v81.12 (16)
Ag3vi—Ag2—Cu264.98 (19)Ag3iv—Cu2—Ag3xii29.96 (17)
Ag3vi—Ag2—S162.9 (2)Ag3iv—Cu2—Ag3xiii150.04 (17)
Ag3vi—Ag2—S2i79.5 (4)Ag3iv—Cu2—Ag3xiv180
Ag3vi—Ag2—S3131.8 (6)Ag3iv—Cu2—Ag3vi98.9 (2)
Cu2—Ag2—S148.81 (9)Ag3iv—Cu2—Ag3xv81.1 (2)
Cu2—Ag2—S2i139.8 (4)Ag3iv—Cu2—S161.31 (10)
Cu2—Ag2—S3112.1 (3)Ag3iv—Cu2—S1viii118.69 (10)
S1—Ag2—S2i99.0 (2)Ag3xiv—Cu2—Ag3106.7 (2)
S1—Ag2—S3153.3 (7)Ag3xiv—Cu2—Ag3viii73.3 (2)
S2i—Ag2—S3105.4 (2)Ag3xiv—Cu2—Ag3ix62.43 (15)
Ag2—Ag3—Ag2v95.3 (4)Ag3xiv—Cu2—Ag3x117.57 (15)
Ag2—Ag3—Ag2iv7.3 (3)Ag3xiv—Cu2—Ag3xi81.12 (16)
Ag2—Ag3—Ag2vi118.0 (6)Ag3xiv—Cu2—Ag3v98.88 (16)
Ag2—Ag3—Ag3ii102.1 (5)Ag3xiv—Cu2—Ag3xii150.04 (17)
Ag2—Ag3—Ag3vi137.8 (5)Ag3xiv—Cu2—Ag3xiii29.96 (17)
Ag2—Ag3—Cu269.9 (3)Ag3xiv—Cu2—Ag3iv180
Ag2—Ag3—S165.2 (3)Ag3xiv—Cu2—Ag3vi81.1 (2)
Ag2—Ag3—S2i83.1 (3)Ag3xiv—Cu2—Ag3xv98.9 (2)
Ag2—Ag3—S3vii137.1 (3)Ag3xiv—Cu2—S1118.69 (10)
Ag2v—Ag3—Ag295.3 (4)Ag3xiv—Cu2—S1viii61.31 (10)
Ag2v—Ag3—Ag2iv93.3 (3)Ag3vi—Cu2—Ag330.0 (2)
Ag2v—Ag3—Ag2vi84.9 (4)Ag3vi—Cu2—Ag3viii150.0 (2)
Ag2v—Ag3—Ag3ii95.6 (2)Ag3vi—Cu2—Ag3ix73.3 (2)
Ag2v—Ag3—Ag3vi84.1 (4)Ag3vi—Cu2—Ag3x106.7 (2)
Ag2v—Ag3—Cu256.75 (12)Ag3vi—Cu2—Ag3xi98.88 (17)
Ag2v—Ag3—S1101.96 (18)Ag3vi—Cu2—Ag3v81.12 (17)
Ag2v—Ag3—S2i157.4 (3)Ag3vi—Cu2—Ag3xii117.57 (15)
Ag2v—Ag3—S3vii51.90 (15)Ag3vi—Cu2—Ag3xiii62.43 (15)
Ag2iv—Ag3—Ag27.3 (3)Ag3vi—Cu2—Ag3iv98.9 (2)
Ag2iv—Ag3—Ag2v93.3 (3)Ag3vi—Cu2—Ag3xiv81.1 (2)
Ag2iv—Ag3—Ag2vi110.8 (5)Ag3vi—Cu2—Ag3xv180
Ag2iv—Ag3—Ag3ii109.3 (3)Ag3vi—Cu2—S161.31 (8)
Ag2iv—Ag3—Ag3vi130.7 (3)Ag3vi—Cu2—S1viii118.69 (8)
Ag2iv—Ag3—Cu263.15 (16)Ag3xv—Cu2—Ag3150.0 (2)
Ag2iv—Ag3—S158.73 (16)Ag3xv—Cu2—Ag3viii30.0 (2)
Ag2iv—Ag3—S2i87.6 (2)Ag3xv—Cu2—Ag3ix106.7 (2)
Ag2iv—Ag3—S3vii139.2 (2)Ag3xv—Cu2—Ag3x73.3 (2)
Ag2vi—Ag3—Ag2118.0 (6)Ag3xv—Cu2—Ag3xi81.12 (17)
Ag2vi—Ag3—Ag2v84.9 (4)Ag3xv—Cu2—Ag3v98.88 (17)
Ag2vi—Ag3—Ag2iv110.8 (5)Ag3xv—Cu2—Ag3xii62.43 (15)
Ag2vi—Ag3—Ag3ii139.8 (6)Ag3xv—Cu2—Ag3xiii117.57 (15)
Ag2vi—Ag3—Ag3vi19.9 (5)Ag3xv—Cu2—Ag3iv81.1 (2)
Ag2vi—Ag3—Cu259.0 (4)Ag3xv—Cu2—Ag3xiv98.9 (2)
Ag2vi—Ag3—S154.3 (4)Ag3xv—Cu2—Ag3vi180
Ag2vi—Ag3—S2i115.78 (19)Ag3xv—Cu2—S1118.69 (8)
Ag2vi—Ag3—S3vii89.0 (4)Ag3xv—Cu2—S1viii61.31 (8)
Ag3ii—Ag3—Ag3vi120.0 (4)S1—Cu2—S1viii180
Ag3ii—Ag3—Cu2148.8 (2)S1viii—Cu2—S1180
Ag3ii—Ag3—S1159.0 (3)Ag2—S1—Ag2ix112.2 (5)
Ag3ii—Ag3—S2i63.02 (13)Ag2—S1—Ag2xi130.4 (5)
Ag3ii—Ag3—S3vii61.65 (18)Ag2—S1—Ag2xii112.2 (6)
Ag3vi—Ag3—Ag3ii120.0 (4)Ag2—S1—Ag2iv21.6 (6)
Ag3vi—Ag3—Cu275.0 (2)Ag2—S1—Ag2vi92.1 (5)
Ag3vi—Ag3—S173.6 (3)Ag2—S1—Ag330.2 (5)
Ag3vi—Ag3—S2i112.1 (3)Ag2—S1—Ag3ix136.5 (3)
Ag3vi—Ag3—S3vii72.8 (3)Ag2—S1—Ag3xi146.22 (16)
Cu2—Ag3—S145.38 (8)Ag2—S1—Ag3xii83.8 (5)
Cu2—Ag3—S2i140.7 (2)Ag2—S1—Ag3iv51.7 (5)
Cu2—Ag3—S3vii102.95 (14)Ag2—S1—Ag3vi62.8 (5)
S1—Ag3—S2i97.80 (13)Ag2—S1—Cu273.41 (7)
S1—Ag3—S3vii139.1 (2)Ag2ix—S1—Ag2112.2 (5)
S2i—Ag3—S3vii116.19 (19)Ag2ix—S1—Ag2xi92.1 (5)
Ag2—Cu2—Ag2viii180Ag2ix—S1—Ag2xii112.2 (5)
Ag2—Cu2—Ag2ix94.2 (4)Ag2ix—S1—Ag2iv130.4 (5)
Ag2—Cu2—Ag2x85.8 (4)Ag2ix—S1—Ag2vi21.6 (5)
Ag2—Cu2—Ag2xi106.5 (4)Ag2ix—S1—Ag383.8 (4)
Ag2—Cu2—Ag2v73.5 (4)Ag2ix—S1—Ag3ix30.2 (4)
Ag2—Cu2—Ag2xii94.2 (4)Ag2ix—S1—Ag3xi62.8 (4)
Ag2—Cu2—Ag2xiii85.8 (4)Ag2ix—S1—Ag3xii136.5 (3)
Ag2—Cu2—Ag2iv19.1 (6)Ag2ix—S1—Ag3iv146.2 (2)
Ag2—Cu2—Ag2xiv160.9 (6)Ag2ix—S1—Ag3vi51.7 (4)
Ag2—Cu2—Ag2vi78.9 (5)Ag2ix—S1—Cu273.41 (17)
Ag2—Cu2—Ag2xv101.1 (5)Ag2xi—S1—Ag2130.4 (5)
Ag2—Cu2—Ag327.3 (4)Ag2xi—S1—Ag2ix92.1 (5)
Ag2—Cu2—Ag3viii152.7 (4)Ag2xi—S1—Ag2xii21.6 (6)
Ag2—Cu2—Ag3ix113.38 (17)Ag2xi—S1—Ag2iv112.2 (6)
Ag2—Cu2—Ag3x66.62 (17)Ag2xi—S1—Ag2vi112.2 (5)
Ag2—Cu2—Ag3xi118.84 (12)Ag2xi—S1—Ag3146.22 (16)
Ag2—Cu2—Ag3v61.16 (12)Ag2xi—S1—Ag3ix62.8 (5)
Ag2—Cu2—Ag3xii74.0 (4)Ag2xi—S1—Ag3xi30.2 (5)
Ag2—Cu2—Ag3xiii106.0 (4)Ag2xi—S1—Ag3xii51.7 (5)
Ag2—Cu2—Ag3iv46.3 (4)Ag2xi—S1—Ag3iv83.8 (5)
Ag2—Cu2—Ag3xiv133.7 (4)Ag2xi—S1—Ag3vi136.5 (3)
Ag2—Cu2—Ag3vi56.0 (4)Ag2xi—S1—Cu273.41 (7)
Ag2—Cu2—Ag3xv124.0 (4)Ag2xii—S1—Ag2112.2 (6)
Ag2—Cu2—S157.79 (7)Ag2xii—S1—Ag2ix112.2 (5)
Ag2—Cu2—S1viii122.21 (7)Ag2xii—S1—Ag2xi21.6 (6)
Ag2viii—Cu2—Ag2180Ag2xii—S1—Ag2iv92.1 (6)
Ag2viii—Cu2—Ag2ix85.8 (4)Ag2xii—S1—Ag2vi130.4 (5)
Ag2viii—Cu2—Ag2x94.2 (4)Ag2xii—S1—Ag3136.5 (3)
Ag2viii—Cu2—Ag2xi73.5 (4)Ag2xii—S1—Ag3ix83.8 (5)
Ag2viii—Cu2—Ag2v106.5 (4)Ag2xii—S1—Ag3xi51.7 (5)
Ag2viii—Cu2—Ag2xii85.8 (4)Ag2xii—S1—Ag3xii30.2 (5)
Ag2viii—Cu2—Ag2xiii94.2 (4)Ag2xii—S1—Ag3iv62.8 (5)
Ag2viii—Cu2—Ag2iv160.9 (6)Ag2xii—S1—Ag3vi146.22 (16)
Ag2viii—Cu2—Ag2xiv19.1 (6)Ag2xii—S1—Cu273.41 (7)
Ag2viii—Cu2—Ag2vi101.1 (5)Ag2iv—S1—Ag221.6 (6)
Ag2viii—Cu2—Ag2xv78.9 (5)Ag2iv—S1—Ag2ix130.4 (5)
Ag2viii—Cu2—Ag3152.7 (4)Ag2iv—S1—Ag2xi112.2 (6)
Ag2viii—Cu2—Ag3viii27.3 (4)Ag2iv—S1—Ag2xii92.1 (6)
Ag2viii—Cu2—Ag3ix66.62 (17)Ag2iv—S1—Ag2vi112.2 (5)
Ag2viii—Cu2—Ag3x113.38 (17)Ag2iv—S1—Ag351.7 (5)
Ag2viii—Cu2—Ag3xi61.16 (12)Ag2iv—S1—Ag3ix146.22 (16)
Ag2viii—Cu2—Ag3v118.84 (12)Ag2iv—S1—Ag3xi136.5 (3)
Ag2viii—Cu2—Ag3xii106.0 (4)Ag2iv—S1—Ag3xii62.8 (5)
Ag2viii—Cu2—Ag3xiii74.0 (4)Ag2iv—S1—Ag3iv30.2 (5)
Ag2viii—Cu2—Ag3iv133.7 (4)Ag2iv—S1—Ag3vi83.8 (5)
Ag2viii—Cu2—Ag3xiv46.3 (4)Ag2iv—S1—Cu273.41 (7)
Ag2viii—Cu2—Ag3vi124.0 (4)Ag2vi—S1—Ag292.1 (5)
Ag2viii—Cu2—Ag3xv56.0 (4)Ag2vi—S1—Ag2ix21.6 (5)
Ag2viii—Cu2—S1122.21 (7)Ag2vi—S1—Ag2xi112.2 (5)
Ag2viii—Cu2—S1viii57.79 (7)Ag2vi—S1—Ag2xii130.4 (5)
Ag2ix—Cu2—Ag294.2 (4)Ag2vi—S1—Ag2iv112.2 (5)
Ag2ix—Cu2—Ag2viii85.8 (4)Ag2vi—S1—Ag362.8 (4)
Ag2ix—Cu2—Ag2x180Ag2vi—S1—Ag3ix51.7 (4)
Ag2ix—Cu2—Ag2xi78.9 (5)Ag2vi—S1—Ag3xi83.8 (4)
Ag2ix—Cu2—Ag2v101.1 (5)Ag2vi—S1—Ag3xii146.2 (2)
Ag2ix—Cu2—Ag2xii94.2 (5)Ag2vi—S1—Ag3iv136.5 (3)
Ag2ix—Cu2—Ag2xiii85.8 (5)Ag2vi—S1—Ag3vi30.2 (4)
Ag2ix—Cu2—Ag2iv106.5 (4)Ag2vi—S1—Cu273.41 (17)
Ag2ix—Cu2—Ag2xiv73.5 (4)Ag3—S1—Ag3ix112.1 (2)
Ag2ix—Cu2—Ag2vi19.1 (4)Ag3—S1—Ag3xi138.08 (17)
Ag2ix—Cu2—Ag2xv160.9 (4)Ag3—S1—Ag3xii112.1 (2)
Ag2ix—Cu2—Ag374.0 (3)Ag3—S1—Ag3iv81.3 (2)
Ag2ix—Cu2—Ag3viii106.0 (3)Ag3—S1—Ag3vi32.8 (2)
Ag2ix—Cu2—Ag3ix27.3 (3)Ag3—S1—Cu273.31 (8)
Ag2ix—Cu2—Ag3x152.7 (3)Ag3ix—S1—Ag3112.1 (2)
Ag2ix—Cu2—Ag3xi56.0 (3)Ag3ix—S1—Ag3xi32.8 (2)
Ag2ix—Cu2—Ag3v124.0 (3)Ag3ix—S1—Ag3xii112.1 (2)
Ag2ix—Cu2—Ag3xii113.4 (3)Ag3ix—S1—Ag3iv138.08 (18)
Ag2ix—Cu2—Ag3xiii66.6 (3)Ag3ix—S1—Ag3vi81.3 (2)
Ag2ix—Cu2—Ag3iv118.8 (3)Ag3ix—S1—Cu273.31 (8)
Ag2ix—Cu2—Ag3xiv61.2 (3)Ag3xi—S1—Ag3138.08 (17)
Ag2ix—Cu2—Ag3vi46.3 (3)Ag3xi—S1—Ag3ix32.8 (2)
Ag2ix—Cu2—Ag3xv133.7 (3)Ag3xi—S1—Ag3xii81.3 (2)
Ag2ix—Cu2—S157.8 (3)Ag3xi—S1—Ag3iv112.1 (2)
Ag2ix—Cu2—S1viii122.2 (3)Ag3xi—S1—Ag3vi112.1 (2)
Ag2x—Cu2—Ag285.8 (4)Ag3xi—S1—Cu273.31 (8)
Ag2x—Cu2—Ag2viii94.2 (4)Ag3xii—S1—Ag3112.1 (2)
Ag2x—Cu2—Ag2ix180Ag3xii—S1—Ag3ix112.1 (2)
Ag2x—Cu2—Ag2xi101.1 (5)Ag3xii—S1—Ag3xi81.3 (2)
Ag2x—Cu2—Ag2v78.9 (5)Ag3xii—S1—Ag3iv32.8 (2)
Ag2x—Cu2—Ag2xii85.8 (5)Ag3xii—S1—Ag3vi138.08 (18)
Ag2x—Cu2—Ag2xiii94.2 (5)Ag3xii—S1—Cu273.31 (9)
Ag2x—Cu2—Ag2iv73.5 (4)Ag3iv—S1—Ag381.3 (2)
Ag2x—Cu2—Ag2xiv106.5 (4)Ag3iv—S1—Ag3ix138.08 (18)
Ag2x—Cu2—Ag2vi160.9 (4)Ag3iv—S1—Ag3xi112.1 (2)
Ag2x—Cu2—Ag2xv19.1 (4)Ag3iv—S1—Ag3xii32.8 (2)
Ag2x—Cu2—Ag3106.0 (3)Ag3iv—S1—Ag3vi112.1 (2)
Ag2x—Cu2—Ag3viii74.0 (3)Ag3iv—S1—Cu273.31 (9)
Ag2x—Cu2—Ag3ix152.7 (3)Ag3vi—S1—Ag332.8 (2)
Ag2x—Cu2—Ag3x27.3 (3)Ag3vi—S1—Ag3ix81.3 (2)
Ag2x—Cu2—Ag3xi124.0 (3)Ag3vi—S1—Ag3xi112.1 (2)
Ag2x—Cu2—Ag3v56.0 (3)Ag3vi—S1—Ag3xii138.08 (18)
Ag2x—Cu2—Ag3xii66.6 (3)Ag3vi—S1—Ag3iv112.1 (2)
Ag2x—Cu2—Ag3xiii113.4 (3)Ag3vi—S1—Cu273.31 (8)
Ag2x—Cu2—Ag3iv61.2 (3)As—S2—Sb0
Ag2x—Cu2—Ag3xiv118.8 (3)As—S2—Ag1ix102.29 (5)
Ag2x—Cu2—Ag3vi133.7 (3)As—S2—Ag1xvi102.29 (4)
Ag2x—Cu2—Ag3xv46.3 (3)As—S2—Cu1ix102.29 (4)
Ag2x—Cu2—S1122.2 (3)As—S2—Cu1xvi102.29 (3)
Ag2x—Cu2—S1viii57.8 (3)As—S2—Ag2xvii130.4 (2)
Ag2xi—Cu2—Ag2106.5 (4)As—S2—Ag2vi130.4 (4)
Ag2xi—Cu2—Ag2viii73.5 (4)As—S2—Ag3xvii105.74 (15)
Ag2xi—Cu2—Ag2ix78.9 (5)As—S2—Ag3vi105.74 (18)
Ag2xi—Cu2—Ag2x101.1 (5)Sb—S2—Ag1ix102.29 (5)
Ag2xi—Cu2—Ag2v180Sb—S2—Ag1xvi102.29 (4)
Ag2xi—Cu2—Ag2xii19.1 (6)Sb—S2—Cu1ix102.29 (4)
Ag2xi—Cu2—Ag2xiii160.9 (6)Sb—S2—Cu1xvi102.29 (3)
Ag2xi—Cu2—Ag2iv94.2 (4)Sb—S2—Ag2xvii130.4 (2)
Ag2xi—Cu2—Ag2xiv85.8 (4)Sb—S2—Ag2vi130.4 (4)
Ag2xi—Cu2—Ag2vi94.2 (4)Sb—S2—Ag3xvii105.74 (15)
Ag2xi—Cu2—Ag2xv85.8 (4)Sb—S2—Ag3vi105.74 (18)
Ag2xi—Cu2—Ag3118.84 (12)Ag1ix—S2—Ag1xvi111.92 (6)
Ag2xi—Cu2—Ag3viii61.16 (12)Ag1ix—S2—Cu1ix0
Ag2xi—Cu2—Ag3ix56.0 (4)Ag1ix—S2—Cu1xvi111.92 (5)
Ag2xi—Cu2—Ag3x124.0 (4)Ag1ix—S2—Ag2xvii125.64 (14)
Ag2xi—Cu2—Ag3xi27.3 (4)Ag1ix—S2—Ag2vi73.3 (3)
Ag2xi—Cu2—Ag3v152.7 (4)Ag1ix—S2—Ag3xvii139.26 (12)
Ag2xi—Cu2—Ag3xii46.3 (4)Ag1ix—S2—Ag3vi90.33 (12)
Ag2xi—Cu2—Ag3xiii133.7 (4)Ag1xvi—S2—Ag1ix111.92 (6)
Ag2xi—Cu2—Ag3iv74.0 (4)Ag1xvi—S2—Cu1ix111.92 (5)
Ag2xi—Cu2—Ag3xiv106.0 (4)Ag1xvi—S2—Cu1xvi0
Ag2xi—Cu2—Ag3vi113.38 (17)Ag1xvi—S2—Ag2xvii73.3 (3)
Ag2xi—Cu2—Ag3xv66.62 (17)Ag1xvi—S2—Ag2vi125.6 (5)
Ag2xi—Cu2—S157.79 (7)Ag1xvi—S2—Ag3xvii90.3 (2)
Ag2xi—Cu2—S1viii122.21 (7)Ag1xvi—S2—Ag3vi139.26 (19)
Ag2v—Cu2—Ag273.5 (4)Cu1ix—S2—Cu1xvi111.92 (4)
Ag2v—Cu2—Ag2viii106.5 (4)Cu1ix—S2—Ag2xvii125.64 (14)
Ag2v—Cu2—Ag2ix101.1 (5)Cu1ix—S2—Ag2vi73.3 (3)
Ag2v—Cu2—Ag2x78.9 (5)Cu1ix—S2—Ag3xvii139.26 (12)
Ag2v—Cu2—Ag2xi180Cu1ix—S2—Ag3vi90.33 (11)
Ag2v—Cu2—Ag2xii160.9 (6)Cu1xvi—S2—Cu1ix111.92 (4)
Ag2v—Cu2—Ag2xiii19.1 (6)Cu1xvi—S2—Ag2xvii73.3 (3)
Ag2v—Cu2—Ag2iv85.8 (4)Cu1xvi—S2—Ag2vi125.6 (5)
Ag2v—Cu2—Ag2xiv94.2 (4)Cu1xvi—S2—Ag3xvii90.33 (19)
Ag2v—Cu2—Ag2vi85.8 (4)Cu1xvi—S2—Ag3vi139.26 (18)
Ag2v—Cu2—Ag2xv94.2 (4)Ag2xvii—S2—Ag2vi63.4 (4)
Ag2v—Cu2—Ag361.16 (12)Ag2xvii—S2—Ag3xvii28.1 (4)
Ag2v—Cu2—Ag3viii118.84 (12)Ag2xvii—S2—Ag3vi66.1 (3)
Ag2v—Cu2—Ag3ix124.0 (4)Ag2vi—S2—Ag2xvii63.4 (4)
Ag2v—Cu2—Ag3x56.0 (4)Ag2vi—S2—Ag3xvii66.1 (3)
Ag2v—Cu2—Ag3xi152.7 (4)Ag2vi—S2—Ag3vi28.1 (3)
Ag2v—Cu2—Ag3v27.3 (4)Ag3xvii—S2—Ag3vi54.0 (2)
Ag2v—Cu2—Ag3xii133.7 (4)Ag3vi—S2—Ag3xvii54.0 (2)
Ag2v—Cu2—Ag3xiii46.3 (4)Ag2—S3—Ag2xviii94.9 (5)
Ag2v—Cu2—Ag3iv106.0 (4)Ag2—S3—Ag2ii77.0 (5)
Ag2v—Cu2—Ag3xiv74.0 (4)Ag2—S3—Ag2xix94.9 (5)
Ag2v—Cu2—Ag3vi66.62 (17)Ag2—S3—Ag2iv22.0 (7)
Ag2v—Cu2—Ag3xv113.38 (17)Ag2—S3—Ag2xx108.8 (4)
Ag2v—Cu2—S1122.21 (7)Ag2—S3—Ag3vii105.7 (4)
Ag2v—Cu2—S1viii57.79 (7)Ag2—S3—Ag3x78.0 (2)
Ag2xii—Cu2—Ag294.2 (4)Ag2—S3—Ag3v71.30 (16)
Ag2xii—Cu2—Ag2viii85.8 (4)Ag2—S3—Ag3xxi158.6 (4)
Ag2xii—Cu2—Ag2ix94.2 (5)Ag2—S3—Ag3xxii124.3 (4)
Ag2xii—Cu2—Ag2x85.8 (5)Ag2—S3—Ag3xxiii138.6 (5)
Ag2xii—Cu2—Ag2xi19.1 (6)Ag2xviii—S3—Ag294.9 (5)
Ag2xii—Cu2—Ag2v160.9 (6)Ag2xviii—S3—Ag2ii108.8 (4)
Ag2xii—Cu2—Ag2xiii180Ag2xviii—S3—Ag2xix94.9 (4)
Ag2xii—Cu2—Ag2iv78.9 (5)Ag2xviii—S3—Ag2iv77.0 (5)
Ag2xii—Cu2—Ag2xiv101.1 (5)Ag2xviii—S3—Ag2xx22.0 (5)
Ag2xii—Cu2—Ag2vi106.5 (4)Ag2xviii—S3—Ag3vii158.6 (4)
Ag2xii—Cu2—Ag2xv73.5 (4)Ag2xviii—S3—Ag3x105.7 (4)
Ag2xii—Cu2—Ag3113.38 (18)Ag2xviii—S3—Ag3v138.6 (3)
Ag2xii—Cu2—Ag3viii66.62 (18)Ag2xviii—S3—Ag3xxi78.0 (4)
Ag2xii—Cu2—Ag3ix74.0 (4)Ag2xviii—S3—Ag3xxii71.3 (3)
Ag2xii—Cu2—Ag3x106.0 (4)Ag2xviii—S3—Ag3xxiii124.3 (4)
Ag2xii—Cu2—Ag3xi46.3 (4)Ag2ii—S3—Ag277.0 (5)
Ag2xii—Cu2—Ag3v133.7 (4)Ag2ii—S3—Ag2xviii108.8 (4)
Ag2xii—Cu2—Ag3xii27.3 (4)Ag2ii—S3—Ag2xix22.0 (7)
Ag2xii—Cu2—Ag3xiii152.7 (4)Ag2ii—S3—Ag2iv94.9 (5)
Ag2xii—Cu2—Ag3iv56.0 (4)Ag2ii—S3—Ag2xx94.9 (5)
Ag2xii—Cu2—Ag3xiv124.0 (4)Ag2ii—S3—Ag3vii71.30 (16)
Ag2xii—Cu2—Ag3vi118.84 (13)Ag2ii—S3—Ag3x138.6 (5)
Ag2xii—Cu2—Ag3xv61.16 (13)Ag2ii—S3—Ag3v105.7 (4)
Ag2xii—Cu2—S157.79 (7)Ag2ii—S3—Ag3xxi124.3 (4)
Ag2xii—Cu2—S1viii122.21 (7)Ag2ii—S3—Ag3xxii158.6 (4)
Ag2xiii—Cu2—Ag285.8 (4)Ag2ii—S3—Ag3xxiii78.0 (2)
Ag2xiii—Cu2—Ag2viii94.2 (4)Ag2xix—S3—Ag294.9 (5)
Ag2xiii—Cu2—Ag2ix85.8 (5)Ag2xix—S3—Ag2xviii94.9 (4)
Ag2xiii—Cu2—Ag2x94.2 (5)Ag2xix—S3—Ag2ii22.0 (7)
Ag2xiii—Cu2—Ag2xi160.9 (6)Ag2xix—S3—Ag2iv108.8 (4)
Ag2xiii—Cu2—Ag2v19.1 (6)Ag2xix—S3—Ag2xx77.0 (5)
Ag2xiii—Cu2—Ag2xii180Ag2xix—S3—Ag3vii78.0 (2)
Ag2xiii—Cu2—Ag2iv101.1 (5)Ag2xix—S3—Ag3x158.6 (4)
Ag2xiii—Cu2—Ag2xiv78.9 (5)Ag2xix—S3—Ag3v124.3 (4)
Ag2xiii—Cu2—Ag2vi73.5 (4)Ag2xix—S3—Ag3xxi105.7 (4)
Ag2xiii—Cu2—Ag2xv106.5 (4)Ag2xix—S3—Ag3xxii138.6 (5)
Ag2xiii—Cu2—Ag366.62 (18)Ag2xix—S3—Ag3xxiii71.30 (16)
Ag2xiii—Cu2—Ag3viii113.38 (18)Ag2iv—S3—Ag222.0 (7)
Ag2xiii—Cu2—Ag3ix106.0 (4)Ag2iv—S3—Ag2xviii77.0 (5)
Ag2xiii—Cu2—Ag3x74.0 (4)Ag2iv—S3—Ag2ii94.9 (5)
Ag2xiii—Cu2—Ag3xi133.7 (4)Ag2iv—S3—Ag2xix108.8 (4)
Ag2xiii—Cu2—Ag3v46.3 (4)Ag2iv—S3—Ag2xx94.9 (4)
Ag2xiii—Cu2—Ag3xii152.7 (4)Ag2iv—S3—Ag3vii124.3 (4)
Ag2xiii—Cu2—Ag3xiii27.3 (4)Ag2iv—S3—Ag3x71.30 (16)
Ag2xiii—Cu2—Ag3iv124.0 (4)Ag2iv—S3—Ag3v78.0 (2)
Ag2xiii—Cu2—Ag3xiv56.0 (4)Ag2iv—S3—Ag3xxi138.6 (5)
Ag2xiii—Cu2—Ag3vi61.16 (13)Ag2iv—S3—Ag3xxii105.7 (4)
Ag2xiii—Cu2—Ag3xv118.84 (13)Ag2iv—S3—Ag3xxiii158.6 (4)
Ag2xiii—Cu2—S1122.21 (7)Ag2xx—S3—Ag2108.8 (4)
Ag2xiii—Cu2—S1viii57.79 (7)Ag2xx—S3—Ag2xviii22.0 (5)
Ag2iv—Cu2—Ag219.1 (6)Ag2xx—S3—Ag2ii94.9 (5)
Ag2iv—Cu2—Ag2viii160.9 (6)Ag2xx—S3—Ag2xix77.0 (5)
Ag2iv—Cu2—Ag2ix106.5 (4)Ag2xx—S3—Ag2iv94.9 (4)
Ag2iv—Cu2—Ag2x73.5 (4)Ag2xx—S3—Ag3vii138.6 (3)
Ag2iv—Cu2—Ag2xi94.2 (4)Ag2xx—S3—Ag3x124.3 (4)
Ag2iv—Cu2—Ag2v85.8 (4)Ag2xx—S3—Ag3v158.6 (4)
Ag2iv—Cu2—Ag2xii78.9 (5)Ag2xx—S3—Ag3xxi71.3 (3)
Ag2iv—Cu2—Ag2xiii101.1 (5)Ag2xx—S3—Ag3xxii78.0 (4)
Ag2iv—Cu2—Ag2xiv180Ag2xx—S3—Ag3xxiii105.7 (4)
Ag2iv—Cu2—Ag2vi94.2 (5)Ag3vii—S3—Ag3x84.6 (2)
Ag2iv—Cu2—Ag2xv85.8 (5)Ag3vii—S3—Ag3v56.71 (16)
Ag2iv—Cu2—Ag346.3 (4)Ag3vii—S3—Ag3xxi84.6 (2)
Ag2iv—Cu2—Ag3viii133.7 (4)Ag3vii—S3—Ag3xxii100.7 (2)
Ag2iv—Cu2—Ag3ix118.84 (13)Ag3vii—S3—Ag3xxiii34.3 (3)
Ag2iv—Cu2—Ag3x61.16 (13)Ag3x—S3—Ag3vii84.6 (2)
Ag2iv—Cu2—Ag3xi113.38 (18)Ag3x—S3—Ag3v34.3 (3)
Ag2iv—Cu2—Ag3v66.62 (18)Ag3x—S3—Ag3xxi84.6 (2)
Ag2iv—Cu2—Ag3xii56.0 (4)Ag3x—S3—Ag3xxii56.7 (2)
Ag2iv—Cu2—Ag3xiii124.0 (4)Ag3x—S3—Ag3xxiii100.72 (17)
Ag2iv—Cu2—Ag3iv27.3 (4)Ag3v—S3—Ag3vii56.71 (16)
Ag2iv—Cu2—Ag3xiv152.7 (4)Ag3v—S3—Ag3x34.3 (3)
Ag2iv—Cu2—Ag3vi74.0 (4)Ag3v—S3—Ag3xxi100.7 (2)
Ag2iv—Cu2—Ag3xv106.0 (4)Ag3v—S3—Ag3xxii84.6 (2)
Ag2iv—Cu2—S157.79 (7)Ag3v—S3—Ag3xxiii84.6 (2)
Ag2iv—Cu2—S1viii122.21 (7)Ag3xxi—S3—Ag3vii84.6 (2)
Ag2xiv—Cu2—Ag2160.9 (6)Ag3xxi—S3—Ag3x84.6 (2)
Ag2xiv—Cu2—Ag2viii19.1 (6)Ag3xxi—S3—Ag3v100.7 (2)
Ag2xiv—Cu2—Ag2ix73.5 (4)Ag3xxi—S3—Ag3xxii34.34 (16)
Ag2xiv—Cu2—Ag2x106.5 (4)Ag3xxi—S3—Ag3xxiii56.7 (2)
Ag2xiv—Cu2—Ag2xi85.8 (4)Ag3xxii—S3—Ag3vii100.7 (2)
Ag2xiv—Cu2—Ag2v94.2 (4)Ag3xxii—S3—Ag3x56.7 (2)
Ag2xiv—Cu2—Ag2xii101.1 (5)Ag3xxii—S3—Ag3v84.6 (2)
Ag2xiv—Cu2—Ag2xiii78.9 (5)Ag3xxii—S3—Ag3xxi34.34 (16)
Ag2xiv—Cu2—Ag2iv180Ag3xxii—S3—Ag3xxiii84.6 (2)
Ag2xiv—Cu2—Ag2vi85.8 (5)Ag3xxiii—S3—Ag3vii34.3 (3)
Ag2xiv—Cu2—Ag2xv94.2 (5)Ag3xxiii—S3—Ag3x100.72 (17)
Ag2xiv—Cu2—Ag3133.7 (4)Ag3xxiii—S3—Ag3v84.6 (2)
Ag2xiv—Cu2—Ag3viii46.3 (4)Ag3xxiii—S3—Ag3xxi56.7 (2)
Ag2xiv—Cu2—Ag3ix61.16 (13)Ag3xxiii—S3—Ag3xxii84.6 (2)
Ag2xiv—Cu2—Ag3x118.84 (13)Ag1—S4—Ag1xxiv180
Ag2xiv—Cu2—Ag3xi66.62 (18)Ag1—S4—Ag1ix89.92 (5)
Ag2xiv—Cu2—Ag3v113.38 (18)Ag1—S4—Ag1xxv90.08 (5)
Ag2xiv—Cu2—Ag3xii124.0 (4)Ag1—S4—Ag1xi89.92 (3)
Ag2xiv—Cu2—Ag3xiii56.0 (4)Ag1—S4—Ag1xxvi90.08 (3)
Ag2xiv—Cu2—Ag3iv152.7 (4)Ag1—S4—Cu10
Ag2xiv—Cu2—Ag3xiv27.3 (4)Ag1—S4—Cu1xxiv180
Ag2xiv—Cu2—Ag3vi106.0 (4)Ag1—S4—Cu1ix89.92 (4)
Ag2xiv—Cu2—Ag3xv74.0 (4)Ag1—S4—Cu1xxv90.08 (4)
Ag2xiv—Cu2—S1122.21 (7)Ag1—S4—Cu1xi89.92 (2)
Ag2xiv—Cu2—S1viii57.79 (7)Ag1—S4—Cu1xxvi90.08 (2)
Ag2vi—Cu2—Ag278.9 (5)Ag1xxiv—S4—Ag1180
Ag2vi—Cu2—Ag2viii101.1 (5)Ag1xxiv—S4—Ag1ix90.08 (5)
Ag2vi—Cu2—Ag2ix19.1 (4)Ag1xxiv—S4—Ag1xxv89.92 (5)
Ag2vi—Cu2—Ag2x160.9 (4)Ag1xxiv—S4—Ag1xi90.08 (3)
Ag2vi—Cu2—Ag2xi94.2 (4)Ag1xxiv—S4—Ag1xxvi89.92 (3)
Ag2vi—Cu2—Ag2v85.8 (4)Ag1xxiv—S4—Cu1180
Ag2vi—Cu2—Ag2xii106.5 (4)Ag1xxiv—S4—Cu1xxiv0
Ag2vi—Cu2—Ag2xiii73.5 (4)Ag1xxiv—S4—Cu1ix90.08 (4)
Ag2vi—Cu2—Ag2iv94.2 (5)Ag1xxiv—S4—Cu1xxv89.92 (4)
Ag2vi—Cu2—Ag2xiv85.8 (5)Ag1xxiv—S4—Cu1xi90.08 (2)
Ag2vi—Cu2—Ag2xv180Ag1xxiv—S4—Cu1xxvi89.92 (2)
Ag2vi—Cu2—Ag356.0 (3)Ag1ix—S4—Ag189.92 (5)
Ag2vi—Cu2—Ag3viii124.0 (3)Ag1ix—S4—Ag1xxiv90.08 (5)
Ag2vi—Cu2—Ag3ix46.3 (3)Ag1ix—S4—Ag1xxv180
Ag2vi—Cu2—Ag3x133.7 (3)Ag1ix—S4—Ag1xi89.92 (6)
Ag2vi—Cu2—Ag3xi74.0 (3)Ag1ix—S4—Ag1xxvi90.08 (6)
Ag2vi—Cu2—Ag3v106.0 (3)Ag1ix—S4—Cu189.92 (2)
Ag2vi—Cu2—Ag3xii118.8 (3)Ag1ix—S4—Cu1xxiv90.08 (2)
Ag2vi—Cu2—Ag3xiii61.2 (3)Ag1ix—S4—Cu1ix0
Ag2vi—Cu2—Ag3iv113.4 (3)Ag1ix—S4—Cu1xxv180
Ag2vi—Cu2—Ag3xiv66.6 (3)Ag1ix—S4—Cu1xi89.92 (4)
Ag2vi—Cu2—Ag3vi27.3 (3)Ag1ix—S4—Cu1xxvi90.08 (4)
Ag2vi—Cu2—Ag3xv152.7 (3)Ag1xxv—S4—Ag190.08 (5)
Ag2vi—Cu2—S157.8 (3)Ag1xxv—S4—Ag1xxiv89.92 (5)
Ag2vi—Cu2—S1viii122.2 (3)Ag1xxv—S4—Ag1ix180
Ag2xv—Cu2—Ag2101.1 (5)Ag1xxv—S4—Ag1xi90.08 (6)
Ag2xv—Cu2—Ag2viii78.9 (5)Ag1xxv—S4—Ag1xxvi89.92 (6)
Ag2xv—Cu2—Ag2ix160.9 (4)Ag1xxv—S4—Cu190.08 (2)
Ag2xv—Cu2—Ag2x19.1 (4)Ag1xxv—S4—Cu1xxiv89.92 (2)
Ag2xv—Cu2—Ag2xi85.8 (4)Ag1xxv—S4—Cu1ix180
Ag2xv—Cu2—Ag2v94.2 (4)Ag1xxv—S4—Cu1xxv0
Ag2xv—Cu2—Ag2xii73.5 (4)Ag1xxv—S4—Cu1xi90.08 (4)
Ag2xv—Cu2—Ag2xiii106.5 (4)Ag1xxv—S4—Cu1xxvi89.92 (4)
Ag2xv—Cu2—Ag2iv85.8 (5)Ag1xi—S4—Ag189.92 (3)
Ag2xv—Cu2—Ag2xiv94.2 (5)Ag1xi—S4—Ag1xxiv90.08 (3)
Ag2xv—Cu2—Ag2vi180Ag1xi—S4—Ag1ix89.92 (6)
Ag2xv—Cu2—Ag3124.0 (3)Ag1xi—S4—Ag1xxv90.08 (6)
Ag2xv—Cu2—Ag3viii56.0 (3)Ag1xi—S4—Ag1xxvi180
Ag2xv—Cu2—Ag3ix133.7 (3)Ag1xi—S4—Cu189.92 (2)
Ag2xv—Cu2—Ag3x46.3 (3)Ag1xi—S4—Cu1xxiv90.08 (2)
Ag2xv—Cu2—Ag3xi106.0 (3)Ag1xi—S4—Cu1ix89.92 (4)
Ag2xv—Cu2—Ag3v74.0 (3)Ag1xi—S4—Cu1xxv90.08 (4)
Ag2xv—Cu2—Ag3xii61.2 (3)Ag1xi—S4—Cu1xi0
Ag2xv—Cu2—Ag3xiii118.8 (3)Ag1xi—S4—Cu1xxvi180
Ag2xv—Cu2—Ag3iv66.6 (3)Ag1xxvi—S4—Ag190.08 (3)
Ag2xv—Cu2—Ag3xiv113.4 (3)Ag1xxvi—S4—Ag1xxiv89.92 (3)
Ag2xv—Cu2—Ag3vi152.7 (3)Ag1xxvi—S4—Ag1ix90.08 (6)
Ag2xv—Cu2—Ag3xv27.3 (3)Ag1xxvi—S4—Ag1xxv89.92 (6)
Ag2xv—Cu2—S1122.2 (3)Ag1xxvi—S4—Ag1xi180
Ag2xv—Cu2—S1viii57.8 (3)Ag1xxvi—S4—Cu190.08 (2)
Ag3—Cu2—Ag3viii180Ag1xxvi—S4—Cu1xxiv89.92 (2)
Ag3—Cu2—Ag3ix98.88 (17)Ag1xxvi—S4—Cu1ix90.08 (4)
Ag3—Cu2—Ag3x81.12 (17)Ag1xxvi—S4—Cu1xxv89.92 (4)
Ag3—Cu2—Ag3xi117.57 (12)Ag1xxvi—S4—Cu1xi180
Ag3—Cu2—Ag3v62.43 (12)Ag1xxvi—S4—Cu1xxvi0
Ag3—Cu2—Ag3xii98.88 (16)Cu1—S4—Cu1xxiv180
Ag3—Cu2—Ag3xiii81.12 (16)Cu1—S4—Cu1ix89.919
Ag3—Cu2—Ag3iv73.3 (2)Cu1—S4—Cu1xxv90.081
Ag3—Cu2—Ag3xiv106.7 (2)Cu1—S4—Cu1xi89.919
Ag3—Cu2—Ag3vi30.0 (2)Cu1—S4—Cu1xxvi90.081
Ag3—Cu2—Ag3xv150.0 (2)Cu1xxiv—S4—Cu1180
Ag3—Cu2—S161.31 (7)Cu1xxiv—S4—Cu1ix90.081
Ag3—Cu2—S1viii118.69 (7)Cu1xxiv—S4—Cu1xxv89.919
Ag3viii—Cu2—Ag3180Cu1xxiv—S4—Cu1xi90.081
Ag3viii—Cu2—Ag3ix81.12 (17)Cu1xxiv—S4—Cu1xxvi89.919
Ag3viii—Cu2—Ag3x98.88 (17)Cu1ix—S4—Cu189.919
Ag3viii—Cu2—Ag3xi62.43 (12)Cu1ix—S4—Cu1xxiv90.081
Ag3viii—Cu2—Ag3v117.57 (12)Cu1ix—S4—Cu1xxv180
Ag3viii—Cu2—Ag3xii81.12 (16)Cu1ix—S4—Cu1xi89.919
Ag3viii—Cu2—Ag3xiii98.88 (16)Cu1ix—S4—Cu1xxvi90.081
Ag3viii—Cu2—Ag3iv106.7 (2)Cu1xxv—S4—Cu190.081
Ag3viii—Cu2—Ag3xiv73.3 (2)Cu1xxv—S4—Cu1xxiv89.919
Ag3viii—Cu2—Ag3vi150.0 (2)Cu1xxv—S4—Cu1ix180
Ag3viii—Cu2—Ag3xv30.0 (2)Cu1xxv—S4—Cu1xi90.081
Ag3viii—Cu2—S1118.69 (7)Cu1xxv—S4—Cu1xxvi89.919
Ag3viii—Cu2—S1viii61.31 (7)Cu1xi—S4—Cu189.919
Ag3ix—Cu2—Ag398.88 (17)Cu1xi—S4—Cu1xxiv90.081
Ag3ix—Cu2—Ag3viii81.12 (17)Cu1xi—S4—Cu1ix89.919
Ag3ix—Cu2—Ag3x180Cu1xi—S4—Cu1xxv90.081
Ag3ix—Cu2—Ag3xi30.0 (2)Cu1xi—S4—Cu1xxvi180
Ag3ix—Cu2—Ag3v150.0 (2)Cu1xxvi—S4—Cu190.081
Ag3ix—Cu2—Ag3xii98.9 (2)Cu1xxvi—S4—Cu1xxiv89.919
Ag3ix—Cu2—Ag3xiii81.1 (2)Cu1xxvi—S4—Cu1ix90.081
Ag3ix—Cu2—Ag3iv117.57 (15)Cu1xxvi—S4—Cu1xxv89.919
Ag3ix—Cu2—Ag3xiv62.43 (15)Cu1xxvi—S4—Cu1xi180
Ag3ix—Cu2—Ag3vi73.3 (2)
Symmetry codes: (i) y+1, xy+1, z; (ii) y+1, x+1, z; (iii) y+1, x, z; (iv) x, xy, z; (v) y, x, z; (vi) x+y, y, z; (vii) x+1, y+1, z; (viii) x, y, z; (ix) y, xy, z; (x) y, x+y, z; (xi) y, x, z; (xii) x+y, x, z; (xiii) xy, x, z; (xiv) x, x+y, z; (xv) xy, y, z; (xvi) y, x+1, z; (xvii) x+y, x+1, z; (xviii) y+1, xy, z; (xix) x+y+1, x+1, z; (xx) x+y+1, y, z; (xxi) xy+1, x, z; (xxii) x+1, x+y, z; (xxiii) xy+1, y+1, z; (xxiv) x, y, z+1; (xxv) y, x+y, z+1; (xxvi) y, x, z+1.
(120K) top
Crystal data top
Ag13.034As1.179Cu2.966S11Sb0.821F(000) = 955
Mr = 2135.4Dx = 6.377 Mg m3
Trigonal, P3m1Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 3;-2"µ = 17.70 mm1
a = 7.3721 (6) ÅT = 120 K
c = 11.8104 (12) ÅPrism, black
V = 555.88 (9) Å30.15 × 0.15 × 0.04 mm
Z = 1
Data collection top
Nonius KappaCCD
diffractometer
1167 reflections with I > 2σ(I)
ϕ/ω scansRint = 0.048
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
θmax = 40.0°, θmin = 6.5°
Tmin = 0.165, Tmax = 0.659h = 1213
17722 measured reflectionsk = 1313
1341 independent reflectionsl = 2021
Refinement top
Refinement on F2Weighting scheme based on measured s.u.'s w = 1/[σ2(I) + 0.001936I2]
R[F2 > 2σ(F2)] = 0.045(Δ/σ)max = 0.001
wR(F2) = 0.133Δρmax = 1.57 e Å3
S = 2.19Δρmin = 1.86 e Å3
1341 reflectionsExtinction correction: B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)
96 parametersExtinction coefficient: 0.39 (8)
Crystal data top
Ag13.034As1.179Cu2.966S11Sb0.821Z = 1
Mr = 2135.4Mo Kα radiation
Trigonal, P3m1µ = 17.70 mm1
a = 7.3721 (6) ÅT = 120 K
c = 11.8104 (12) Å0.15 × 0.15 × 0.04 mm
V = 555.88 (9) Å3
Data collection top
Nonius KappaCCD
diffractometer
1341 independent reflections
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
1167 reflections with I > 2σ(I)
Tmin = 0.165, Tmax = 0.659Rint = 0.048
17722 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.04596 parameters
wR(F2) = 0.133Δρmax = 1.57 e Å3
S = 2.19Δρmin = 1.86 e Å3
1341 reflections
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
As0.3333330.6666670.40833 (5)0.01518 (14)0.5896
Sb0.3333330.6666670.4083290.01518 (14)0.4104
Ag10.29992 (17)0.14996 (9)0.38548 (11)0.0361 (4)0.6724
Cu10.2999180.1499590.3854820.0361 (4)0.3276
Ag20.3567 (4)0.226 (3)0.12401 (17)0.263 (9)0.324 (5)
Ag30.2857 (5)0.3745 (4)0.1160 (2)0.0674 (13)0.376 (4)
Ag40.4538 (11)0.092 (2)0.1137 (5)0.083 (6)0.101 (13)
Cu20000.0191 (3)
S1000.18297 (13)0.0192 (4)
S20.01678 (16)0.50839 (8)0.31254 (10)0.0191 (3)
S30.6666670.3333330.0206 (2)0.0346 (6)
S40.0853 (6)00.50.0179 (15)0.1667
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
As0.01564 (18)0.01564 (18)0.0142 (2)0.00782 (9)00
Sb0.01564 (18)0.01564 (18)0.0142 (2)0.00782 (9)00
Ag10.0493 (6)0.0274 (4)0.0387 (6)0.0247 (3)0.0156 (4)0.0078 (2)
Cu10.0493 (6)0.0274 (4)0.0387 (6)0.0247 (3)0.0156 (4)0.0078 (2)
Ag20.0224 (7)0.50 (2)0.0230 (5)0.055 (4)0.0021 (5)0.003 (4)
Ag30.106 (2)0.0315 (14)0.0310 (11)0.0092 (12)0.0249 (10)0.0007 (8)
Ag40.105 (8)0.130 (10)0.021 (2)0.065 (5)0.0100 (18)0.020 (4)
Cu20.0243 (4)0.0243 (4)0.0086 (4)0.01216 (18)00
S10.0241 (5)0.0241 (5)0.0095 (5)0.0120 (2)00
S20.0159 (4)0.0186 (3)0.0219 (4)0.00796 (19)0.0032 (3)0.00161 (16)
S30.0378 (7)0.0378 (7)0.0282 (10)0.0189 (4)00
S40.0138 (14)0.029 (3)0.0162 (17)0.0144 (13)0.0018 (7)0.0035 (14)
Bond lengths (Å) top
As—Sb0Ag2—Ag42.78 (3)
As—S22.3161 (11)Ag2—Ag4xii2.10 (2)
As—S2i2.3161 (12)Ag2—Cu22.731 (4)
As—S2ii2.3161 (11)Ag2—S12.408 (4)
Sb—S22.3161 (11)Ag2—S2i2.865 (13)
Sb—S2i2.3161 (12)Ag2—S32.352 (5)
Sb—S2ii2.3161 (11)Ag3—Ag3ii2.504 (3)
Ag1—Cu10Ag3—Ag3x2.965 (4)
Ag1—S2i2.4469 (13)Ag3—Ag3xi1.452 (6)
Ag1—S2iii2.4469 (17)Ag3—Ag4v2.33 (2)
Ag1—S41.951 (3)Ag3—Ag4xii1.253 (10)
Ag1—S4iv2.825 (4)Ag3—Cu22.850 (2)
Ag1—S4v2.4272 (18)Ag3—S12.621 (2)
Ag1—S4vi2.4272 (16)Ag3—S2i2.677 (3)
Ag1—S4vii2.825 (4)Ag3—S3xiii2.570 (3)
Ag1—S4viii1.951 (4)Ag4—Ag4xiv2.933 (11)
Cu1—S2i2.4469 (11)Ag4—Ag4xv2.664 (15)
Cu1—S2iii2.4469 (11)Ag4—Ag4xvi2.66 (2)
Cu1—S41.951 (3)Ag4—S2iii2.398 (7)
Cu1—S4iv2.825 (4)Ag4—S32.932 (13)
Cu1—S4v2.4272 (12)Ag4—S3xiv2.209 (11)
Cu1—S4vi2.4272 (12)Cu2—S12.1610 (16)
Cu1—S4vii2.825 (3)Cu2—S1xvii2.1610 (16)
Cu1—S4viii1.951 (3)S4—S4iv1.258 (7)
Ag2—Ag2ix0.70 (3)S4—S4v1.089 (6)
Ag2—Ag31.43 (2)S4—S4vi0.629 (3)
Ag2—Ag3x2.861 (4)S4—S4vii1.089 (6)
Ag2—Ag3ix2.11 (2)S4—S4viii0.629 (6)
Ag2—Ag3xi2.696 (19)
Symmetry codes: (i) y+1, xy+1, z; (ii) y+1, x+1, z; (iii) y+1, x, z; (iv) x, y, z+1; (v) y, xy, z; (vi) y, x+y, z+1; (vii) x+y, x, z; (viii) xy, x, z+1; (ix) x, xy, z; (x) y, x, z; (xi) x+y, y, z; (xii) x+y+1, x+1, z; (xiii) x+1, y+1, z; (xiv) x+1, y, z; (xv) y, xy1, z; (xvi) x+y+1, x, z; (xvii) x, y, z.
(15K) top
Crystal data top
Ag12.21As1.194Cu3.79S11Sb0.806F(000) = 941
Mr = 2098.2Dx = 6.234 Mg m3
Trigonal, P3m1Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 3;-2"µ = 17.68 mm1
a = 7.389 (1) ÅT = 15 K
c = 11.816 (2) ÅPrism, black
V = 558.69 (14) Å30.18 × 0.16 × 0.15 mm
Z = 1
Data collection top
Oxford Diffraction Xcalibur 2
diffractometer
650 reflections with I > 2σ(I)
ω scansRint = 0.051
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
θmax = 33.2°, θmin = 4.7°
Tmin = 0.069, Tmax = 0.158h = 1110
2442 measured reflectionsk = 910
818 independent reflectionsl = 418
Refinement top
Refinement on F2Weighting scheme based on measured s.u.'s w = 1/[σ2(I) + 0.001936I2]
R[F2 > 2σ(F2)] = 0.044(Δ/σ)max = 0.001
wR(F2) = 0.126Δρmax = 1.54 e Å3
S = 1.84Δρmin = 1.48 e Å3
818 reflectionsExtinction correction: B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)
77 parametersExtinction coefficient: 0.01 (2)
Crystal data top
Ag12.21As1.194Cu3.79S11Sb0.806Z = 1
Mr = 2098.2Mo Kα radiation
Trigonal, P3m1µ = 17.68 mm1
a = 7.389 (1) ÅT = 15 K
c = 11.816 (2) Å0.18 × 0.16 × 0.15 mm
V = 558.69 (14) Å3
Data collection top
Oxford Diffraction Xcalibur 2
diffractometer
818 independent reflections
Absorption correction: gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
650 reflections with I > 2σ(I)
Tmin = 0.069, Tmax = 0.158Rint = 0.051
2442 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.04477 parameters
wR(F2) = 0.126Δρmax = 1.54 e Å3
S = 1.84Δρmin = 1.48 e Å3
818 reflections
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
As0.3333330.6666670.40976 (8)0.0144 (3)0.596 (17)
Sb0.3333330.6666670.4097640.0144 (3)0.404 (17)
Ag10.2989 (3)0.14946 (15)0.38540 (14)0.0301 (9)0.538 (17)
Cu10.2989210.1494610.3854010.0301 (9)0.462 (17)
Ag20.3606 (4)0.2215 (6)0.1239 (2)0.0175 (9)*0.152 (3)
Ag30.3341 (6)0.3675 (12)0.1109 (3)0.0346 (11)*0.225 (7)
Ag40.4475 (11)0.5525 (11)0.1133 (6)0.069 (5)0.1057
Ag50.3568 (7)0.2954 (13)0.1228 (3)0.0162 (16)*0.102 (4)
Ag60.251 (2)0.3821 (5)0.1211 (4)0.050 (5)0.218 (9)
Cu20000.0195 (6)
S1000.1829 (2)0.0208 (8)
S20.0152 (3)0.50762 (16)0.31195 (17)0.0204 (6)
S30.6666670.3333330.0210 (3)0.0358 (11)
S40.0861 (13)00.50.018 (5)0.1667
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
As0.0148 (5)0.0148 (5)0.0138 (5)0.0074 (2)00
Sb0.0148 (5)0.0148 (5)0.0138 (5)0.0074 (2)00
Ag10.0418 (13)0.0237 (11)0.0310 (12)0.0209 (6)0.0223 (7)0.0112 (4)
Cu10.0418 (13)0.0237 (11)0.0310 (12)0.0209 (6)0.0223 (7)0.0112 (4)
Ag40.084 (6)0.084 (6)0.020 (3)0.027 (7)0.012 (2)0.012 (2)
Ag60.095 (11)0.0240 (12)0.0192 (11)0.0223 (18)0.020 (3)0.0039 (7)
Cu20.0252 (8)0.0252 (8)0.0082 (8)0.0126 (4)00
S10.0251 (11)0.0251 (11)0.0123 (11)0.0125 (5)00
S20.0175 (9)0.0199 (7)0.0230 (9)0.0087 (5)0.0022 (7)0.0011 (3)
S30.0409 (15)0.0409 (15)0.0254 (16)0.0205 (8)00
S40.015 (4)0.029 (8)0.014 (3)0.014 (4)0.0000 (14)0.000 (3)
Bond lengths (Å) top
As—Sb0Ag2—Ag6xviii2.507 (16)
As—Ag1i3.3758 (19)Ag2—Cu22.750 (2)
As—Ag1ii3.376 (2)Ag2—S12.429 (3)
As—Ag1iii3.3757 (19)Ag2—S2iv2.880 (4)
As—Cu1i3.3758 (7)Ag2—S2x3.263 (5)
As—Cu1ii3.3757 (7)Ag2—S32.326 (3)
As—Cu1iii3.3757 (7)Ag3—Ag3xix3.451 (5)
As—S22.341 (2)Ag3—Ag3v2.205 (7)
As—S2iv2.341 (2)Ag3—Ag3xv2.655 (5)
As—S2v2.341 (2)Ag3—Ag3ix2.962 (14)
Sb—Ag1i3.3758 (18)Ag3—Ag3xviii2.222 (13)
Sb—Ag1ii3.376 (2)Ag3—Ag41.194 (10)
Sb—Ag1iii3.3757 (18)Ag3—Ag4xix3.003 (8)
Sb—Cu1i3.3758Ag3—Ag4xx2.655 (16)
Sb—Cu1ii3.3757Ag3—Ag50.649 (14)
Sb—Cu1iii3.3757Ag3—Ag5v2.467 (8)
Sb—S22.341 (2)Ag3—Ag5xv2.773 (5)
Sb—S2iv2.341 (2)Ag3—Ag5xxi3.396 (9)
Sb—S2v2.341 (2)Ag3—Ag5ix2.354 (15)
Ag1—Ag1vi3.313 (3)Ag3—Ag5xviii2.699 (13)
Ag1—Ag1vii3.316 (2)Ag3—Ag60.688 (17)
Ag1—Ag1viii3.3131 (17)Ag3—Ag6iv3.218 (15)
Ag1—Ag1iii3.316 (3)Ag3—Ag6xvii3.361 (12)
Ag1—Cu10Ag3—Ag6v2.541 (13)
Ag1—Cu1vi3.313 (2)Ag3—Ag6xv2.948 (9)
Ag1—Cu1vii3.3156 (15)Ag3—Ag6ix3.422 (19)
Ag1—Cu1viii3.3131 (12)Ag3—Ag6xviii1.559 (18)
Ag1—Cu1iii3.3156 (18)Ag3—Cu22.912 (5)
Ag1—Ag23.129 (3)Ag3—S12.736 (6)
Ag1—Ag2ix3.129 (3)Ag3—S2iv2.622 (4)
Ag1—Ag53.243 (5)Ag3—S32.802 (7)
Ag1—Ag5ix3.243 (5)Ag3—S3xix2.707 (8)
Ag1—S13.064 (3)Ag4—Ag4xix2.995 (11)
Ag1—S2iv2.453 (2)Ag4—Ag4iv2.531 (16)
Ag1—S2x2.453 (3)Ag4—Ag4xx2.531 (16)
Ag1—S41.946 (5)Ag4—Ag51.672 (12)
Ag1—S4xi2.829 (8)Ag4—Ag5xix3.083 (8)
Ag1—S4vi2.428 (3)Ag4—Ag5iv3.259 (12)
Ag1—S4vii2.428 (3)Ag4—Ag5v1.672 (12)
Ag1—S4xii2.829 (7)Ag4—Ag5xv3.083 (8)
Ag1—S4xiii1.946 (7)Ag4—Ag5xvi3.346 (14)
Cu1—Cu1vi3.3131Ag4—Ag5ix3.346 (14)
Cu1—Cu1vii3.3156Ag4—Ag5xviii3.259 (12)
Cu1—Cu1viii3.3131Ag4—Ag61.370 (11)
Cu1—Cu1iii3.3156Ag4—Ag6xix3.435 (13)
Cu1—Ag23.129 (2)Ag4—Ag6iv2.027 (15)
Cu1—Ag2ix3.129 (3)Ag4—Ag6v1.370 (11)
Cu1—Ag53.243 (5)Ag4—Ag6xv3.435 (13)
Cu1—Ag5ix3.243 (5)Ag4—Ag6xx3.31 (2)
Cu1—S13.064 (2)Ag4—Ag6xxii3.31 (2)
Cu1—S2iv2.453 (2)Ag4—Ag6xviii2.027 (15)
Cu1—S2x2.453 (2)Ag4—S2iv2.417 (8)
Cu1—S41.946 (5)Ag4—S33.009 (10)
Cu1—S4xi2.829 (8)Ag4—S3xix2.158 (9)
Cu1—S4vi2.428 (3)Ag5—Ag5v2.569 (8)
Cu1—S4vii2.428 (3)Ag5—Ag5xv3.006 (7)
Cu1—S4xii2.829 (7)Ag5—Ag5ix1.729 (16)
Cu1—S4xiii1.946 (7)Ag5—Ag5xviii3.090 (14)
Ag2—Ag2xiv3.433 (7)Ag5—Ag61.237 (17)
Ag2—Ag2v3.088 (4)Ag5—Ag6xvii3.167 (10)
Ag2—Ag2xv3.427 (5)Ag5—Ag6v2.916 (15)
Ag2—Ag2xvi3.433 (4)Ag5—Ag6xv2.917 (7)
Ag2—Ag2ix0.609 (8)Ag5—Ag6ix2.845 (19)
Ag2—Ag31.199 (11)Ag5—Ag6xviii2.062 (18)
Ag2—Ag3xiv3.375 (13)Ag5—Cu22.840 (5)
Ag2—Ag3xvii3.115 (7)Ag5—S12.543 (5)
Ag2—Ag3v2.872 (5)Ag5—S2iv2.624 (6)
Ag2—Ag3xv2.890 (5)Ag5—S32.474 (6)
Ag2—Ag3ix1.800 (12)Ag5—S3xix3.304 (9)
Ag2—Ag3xviii3.105 (13)Ag6—Ag6iv3.245 (12)
Ag2—Ag42.200 (10)Ag6—Ag6v2.714 (11)
Ag2—Ag4xix3.208 (8)Ag6—Ag6xv3.319 (11)
Ag2—Ag4xiv2.792 (14)Ag6—Ag6xx3.24 (2)
Ag2—Ag4xvii3.440 (10)Ag6—Ag6xviii0.88 (2)
Ag2—Ag50.561 (12)Ag6—Cu22.867 (4)
Ag2—Ag5xiv3.297 (13)Ag6—S12.589 (4)
Ag2—Ag5xvii3.478 (8)Ag6—S23.254 (11)
Ag2—Ag5v2.872 (6)Ag6—S2iv2.735 (9)
Ag2—Ag5xv3.196 (6)Ag6—S33.476 (15)
Ag2—Ag5ix1.169 (13)Ag6—S3xix2.516 (6)
Ag2—Ag5xviii3.424 (13)Cu2—S12.161 (3)
Ag2—Ag61.742 (14)Cu2—S1xxiii2.161 (3)
Ag2—Ag6xvii2.993 (7)S4—S4xi1.273 (14)
Ag2—Ag6v3.378 (14)S4—S4vi1.102 (12)
Ag2—Ag6xv2.901 (5)S4—S4vii0.636 (7)
Ag2—Ag6xii3.022 (14)S4—S4xii1.102 (12)
Ag2—Ag6ix2.312 (16)S4—S4xiii0.636 (12)
Symmetry codes: (i) x+1, y+1, z+1; (ii) y, x+y+1, z+1; (iii) y, x, z+1; (iv) y+1, xy+1, z; (v) y+1, x+1, z; (vi) y, xy, z; (vii) y, x+y, z+1; (viii) y, x, z; (ix) x, xy, z; (x) y+1, x, z; (xi) x, y, z+1; (xii) x+y, x, z; (xiii) xy, x, z+1; (xiv) y+1, xy, z; (xv) y, x, z; (xvi) x+y+1, x+1, z; (xvii) y, x+y, z; (xviii) x+y, y, z; (xix) x+1, y+1, z; (xx) x+y, x+1, z; (xxi) xy, x, z; (xxii) x, xy+1, z; (xxiii) x, y, z.

Experimental details

(300K)(120K)(15K)
Crystal data
Chemical formulaAg13.034As1.179Cu2.966S11Sb0.821Ag13.034As1.179Cu2.966S11Sb0.821Ag12.21As1.194Cu3.79S11Sb0.806
Mr2135.42135.42098.2
Crystal system, space groupTrigonal, P3m1Trigonal, P3m1Trigonal, P3m1
Temperature (K)30012015
a, c (Å)7.3876 (4), 11.8882 (7)7.3721 (6), 11.8104 (12)7.389 (1), 11.816 (2)
V3)561.89 (5)555.88 (9)558.69 (14)
Z111
Radiation typeMo KαMo KαMo Kα
µ (mm1)17.5117.7017.68
Crystal size (mm)0.15 × 0.15 × 0.040.15 × 0.15 × 0.040.18 × 0.16 × 0.15
Data collection
DiffractometerNonius KappaCCD
diffractometer
Nonius KappaCCD
diffractometer
Oxford Diffraction Xcalibur 2
diffractometer
Absorption correctionGaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
Gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
Gaussian
(Jana2000; Petricek, Dusek & Palatinus, 2000)
Tmin, Tmax0.197, 0.7270.165, 0.6590.069, 0.158
No. of measured, independent and
observed [I > 2σ(I)] reflections
20965, 1352, 1109 17722, 1341, 1167 2442, 818, 650
Rint0.0480.0480.051
(sin θ/λ)max1)0.9040.9040.769
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.046, 0.127, 1.89 0.045, 0.133, 2.19 0.044, 0.126, 1.84
No. of reflections13521341818
No. of parameters929677
No. of restraints???
Δρmax, Δρmin (e Å3)1.41, 1.001.57, 1.861.54, 1.48

Computer programs: (Jana2000; Petricek and Dusek, 2000).

Selected geometric parameters (Å, º) for (300K) top
As—Sb0Ag2—Ag31.35 (2)
As—S22.3157 (10)Ag2—Ag3v2.881 (5)
As—S2i2.3157 (12)Ag2—Ag3iv2.23 (2)
As—S2ii2.3157 (10)Ag2—Ag3vi2.658 (18)
Sb—S22.3157 (10)Ag2—Cu22.750 (4)
Sb—S2i2.3157 (12)Ag2—S12.428 (4)
Sb—S2ii2.3157 (10)Ag2—S2i2.836 (11)
Ag1—Cu10Ag2—S32.393 (5)
Ag1—S2i2.4459 (14)Ag3—Ag3ii2.417 (6)
Ag1—S2iii2.446 (2)Ag3—Ag3vi1.502 (12)
Ag1—S42.3592 (15)Ag3—Cu22.906 (4)
Cu1—S2i2.4459 (11)Ag3—S12.661 (4)
Cu1—S2iii2.4459 (11)Ag3—S2i2.664 (4)
Cu1—S42.3592Ag3—S3vii2.545 (6)
Ag2—Ag2ii2.980 (14)Cu2—S12.1594 (15)
Ag2—Ag2iv0.91 (3)Cu2—S1viii2.1594 (15)
Sb—As—S20Ag3ix—Cu2—Ag3xv106.7 (2)
Sb—As—S2i0Ag3ix—Cu2—S161.31 (8)
Sb—As—S2ii0Ag3ix—Cu2—S1viii118.69 (8)
S2—As—S2i98.57 (4)Ag3x—Cu2—Ag381.12 (17)
S2—As—S2ii98.57 (3)Ag3x—Cu2—Ag3viii98.88 (17)
S2i—As—S298.57 (4)Ag3x—Cu2—Ag3ix180
S2i—As—S2ii98.57 (4)Ag3x—Cu2—Ag3xi150.0 (2)
S2ii—As—S298.57 (3)Ag3x—Cu2—Ag3v30.0 (2)
S2ii—As—S2i98.57 (4)Ag3x—Cu2—Ag3xii81.1 (2)
As—Sb—S20Ag3x—Cu2—Ag3xiii98.9 (2)
As—Sb—S2i0Ag3x—Cu2—Ag3iv62.43 (15)
As—Sb—S2ii0Ag3x—Cu2—Ag3xiv117.57 (15)
S2—Sb—S2i98.57 (3)Ag3x—Cu2—Ag3vi106.7 (2)
S2—Sb—S2ii98.57 (3)Ag3x—Cu2—Ag3xv73.3 (2)
S2i—Sb—S298.57 (3)Ag3x—Cu2—S1118.69 (8)
S2i—Sb—S2ii98.57 (4)Ag3x—Cu2—S1viii61.31 (8)
S2ii—Sb—S298.57 (3)Ag3xi—Cu2—Ag3117.57 (12)
S2ii—Sb—S2i98.57 (4)Ag3xi—Cu2—Ag3viii62.43 (12)
Cu1—Ag1—S2i0Ag3xi—Cu2—Ag3ix30.0 (2)
Cu1—Ag1—S2iii0Ag3xi—Cu2—Ag3x150.0 (2)
Cu1—Ag1—S40Ag3xi—Cu2—Ag3v180
S2i—Ag1—S2iii104.86 (6)Ag3xi—Cu2—Ag3xii73.3 (2)
S2i—Ag1—S4127.57 (7)Ag3xi—Cu2—Ag3xiii106.7 (2)
S2iii—Ag1—S2i104.86 (6)Ag3xi—Cu2—Ag3iv98.88 (16)
S2iii—Ag1—S4127.57 (4)Ag3xi—Cu2—Ag3xiv81.12 (16)
Ag1—Cu1—S2i0Ag3xi—Cu2—Ag3vi98.88 (17)
Ag1—Cu1—S2iii0Ag3xi—Cu2—Ag3xv81.12 (17)
Ag1—Cu1—S40Ag3xi—Cu2—S161.31 (7)
S2i—Cu1—S2iii104.86 (3)Ag3xi—Cu2—S1viii118.69 (7)
S2i—Cu1—S4127.57 (2)Ag3v—Cu2—Ag362.43 (12)
S2iii—Cu1—S2i104.86 (3)Ag3v—Cu2—Ag3viii117.57 (12)
S2iii—Cu1—S4127.57 (2)Ag3v—Cu2—Ag3ix150.0 (2)
Ag2ii—Ag2—Ag2iv120.0 (5)Ag3v—Cu2—Ag3x30.0 (2)
Ag2ii—Ag2—Ag377.9 (7)Ag3v—Cu2—Ag3xi180
Ag2ii—Ag2—Ag3v84.4 (2)Ag3v—Cu2—Ag3xii106.7 (2)
Ag2ii—Ag2—Ag3iv130.7 (6)Ag3v—Cu2—Ag3xiii73.3 (2)
Ag2ii—Ag2—Ag3vi100.2 (7)Ag3v—Cu2—Ag3iv81.12 (16)
Ag2ii—Ag2—Cu2143.3 (4)Ag3v—Cu2—Ag3xiv98.88 (16)
Ag2ii—Ag2—S1155.2 (7)Ag3v—Cu2—Ag3vi81.12 (17)
Ag2ii—Ag2—S2i58.3 (3)Ag3v—Cu2—Ag3xv98.88 (17)
Ag2ii—Ag2—S351.5 (3)Ag3v—Cu2—S1118.69 (7)
Ag2iv—Ag2—Ag2ii120.0 (5)Ag3v—Cu2—S1viii61.31 (7)
Ag2iv—Ag2—Ag3161.8 (4)Ag3xii—Cu2—Ag398.88 (16)
Ag2iv—Ag2—Ag3v95.9 (5)Ag3xii—Cu2—Ag3viii81.12 (16)
Ag2iv—Ag2—Ag3iv10.8 (3)Ag3xii—Cu2—Ag3ix98.9 (2)
Ag2iv—Ag2—Ag3vi139.8 (4)Ag3xii—Cu2—Ag3x81.1 (2)
Ag2iv—Ag2—Cu280.5 (4)Ag3xii—Cu2—Ag3xi73.3 (2)
Ag2iv—Ag2—S179.2 (5)Ag3xii—Cu2—Ag3v106.7 (2)
Ag2iv—Ag2—S2i121.5 (4)Ag3xii—Cu2—Ag3xiii180
Ag2iv—Ag2—S379.0 (5)Ag3xii—Cu2—Ag3iv29.96 (17)
Ag3—Ag2—Ag3v82.3 (4)Ag3xii—Cu2—Ag3xiv150.04 (17)
Ag3—Ag2—Ag3iv151.0 (3)Ag3xii—Cu2—Ag3vi117.57 (15)
Ag3—Ag2—Ag3vi22.3 (2)Ag3xii—Cu2—Ag3xv62.43 (15)
Ag3—Ag2—Cu282.8 (3)Ag3xii—Cu2—S161.31 (10)
Ag3—Ag2—S184.5 (3)Ag3xii—Cu2—S1viii118.69 (10)
Ag3—Ag2—S2i68.8 (5)Ag3xiii—Cu2—Ag381.12 (16)
Ag3—Ag2—S3114.1 (7)Ag3xiii—Cu2—Ag3viii98.88 (16)
Ag3v—Ag2—Ag382.3 (4)Ag3xiii—Cu2—Ag3ix81.1 (2)
Ag3v—Ag2—Ag3iv94.5 (4)Ag3xiii—Cu2—Ag3x98.9 (2)
Ag3v—Ag2—Ag3vi86.0 (4)Ag3xiii—Cu2—Ag3xi106.7 (2)
Ag3v—Ag2—Cu262.09 (10)Ag3xiii—Cu2—Ag3v73.3 (2)
Ag3v—Ag2—S1110.69 (14)Ag3xiii—Cu2—Ag3xii180
Ag3v—Ag2—S2i136.1 (6)Ag3xiii—Cu2—Ag3iv150.04 (17)
Ag3v—Ag2—S356.80 (14)Ag3xiii—Cu2—Ag3xiv29.96 (17)
Ag3iv—Ag2—Ag3151.0 (3)Ag3xiii—Cu2—Ag3vi62.43 (15)
Ag3iv—Ag2—Ag3v94.5 (4)Ag3xiii—Cu2—Ag3xv117.57 (15)
Ag3iv—Ag2—Ag3vi129.0 (3)Ag3xiii—Cu2—S1118.69 (10)
Ag3iv—Ag2—Cu270.5 (3)Ag3xiii—Cu2—S1viii61.31 (10)
Ag3iv—Ag2—S169.5 (4)Ag3iv—Cu2—Ag373.3 (2)
Ag3iv—Ag2—S2i126.5 (4)Ag3iv—Cu2—Ag3viii106.7 (2)
Ag3iv—Ag2—S387.1 (6)Ag3iv—Cu2—Ag3ix117.57 (15)
Ag3vi—Ag2—Ag322.3 (2)Ag3iv—Cu2—Ag3x62.43 (15)
Ag3vi—Ag2—Ag3v86.0 (4)Ag3iv—Cu2—Ag3xi98.88 (16)
Ag3vi—Ag2—Ag3iv129.0 (3)Ag3iv—Cu2—Ag3v81.12 (16)
Ag3vi—Ag2—Cu264.98 (19)Ag3iv—Cu2—Ag3xii29.96 (17)
Ag3vi—Ag2—S162.9 (2)Ag3iv—Cu2—Ag3xiii150.04 (17)
Ag3vi—Ag2—S2i79.5 (4)Ag3iv—Cu2—Ag3xiv180
Ag3vi—Ag2—S3131.8 (6)Ag3iv—Cu2—Ag3vi98.9 (2)
Cu2—Ag2—S148.81 (9)Ag3iv—Cu2—Ag3xv81.1 (2)
Cu2—Ag2—S2i139.8 (4)Ag3iv—Cu2—S161.31 (10)
Cu2—Ag2—S3112.1 (3)Ag3iv—Cu2—S1viii118.69 (10)
S1—Ag2—S2i99.0 (2)Ag3xiv—Cu2—Ag3106.7 (2)
S1—Ag2—S3153.3 (7)Ag3xiv—Cu2—Ag3viii73.3 (2)
S2i—Ag2—S3105.4 (2)Ag3xiv—Cu2—Ag3ix62.43 (15)
Ag2—Ag3—Ag2v95.3 (4)Ag3xiv—Cu2—Ag3x117.57 (15)
Ag2—Ag3—Ag2iv7.3 (3)Ag3xiv—Cu2—Ag3xi81.12 (16)
Ag2—Ag3—Ag2vi118.0 (6)Ag3xiv—Cu2—Ag3v98.88 (16)
Ag2—Ag3—Ag3ii102.1 (5)Ag3xiv—Cu2—Ag3xii150.04 (17)
Ag2—Ag3—Ag3vi137.8 (5)Ag3xiv—Cu2—Ag3xiii29.96 (17)
Ag2—Ag3—Cu269.9 (3)Ag3xiv—Cu2—Ag3iv180
Ag2—Ag3—S165.2 (3)Ag3xiv—Cu2—Ag3vi81.1 (2)
Ag2—Ag3—S2i83.1 (3)Ag3xiv—Cu2—Ag3xv98.9 (2)
Ag2—Ag3—S3vii137.1 (3)Ag3xiv—Cu2—S1118.69 (10)
Ag2v—Ag3—Ag295.3 (4)Ag3xiv—Cu2—S1viii61.31 (10)
Ag2v—Ag3—Ag2iv93.3 (3)Ag3vi—Cu2—Ag330.0 (2)
Ag2v—Ag3—Ag2vi84.9 (4)Ag3vi—Cu2—Ag3viii150.0 (2)
Ag2v—Ag3—Ag3ii95.6 (2)Ag3vi—Cu2—Ag3ix73.3 (2)
Ag2v—Ag3—Ag3vi84.1 (4)Ag3vi—Cu2—Ag3x106.7 (2)
Ag2v—Ag3—Cu256.75 (12)Ag3vi—Cu2—Ag3xi98.88 (17)
Ag2v—Ag3—S1101.96 (18)Ag3vi—Cu2—Ag3v81.12 (17)
Ag2v—Ag3—S2i157.4 (3)Ag3vi—Cu2—Ag3xii117.57 (15)
Ag2v—Ag3—S3vii51.90 (15)Ag3vi—Cu2—Ag3xiii62.43 (15)
Ag2iv—Ag3—Ag27.3 (3)Ag3vi—Cu2—Ag3iv98.9 (2)
Ag2iv—Ag3—Ag2v93.3 (3)Ag3vi—Cu2—Ag3xiv81.1 (2)
Ag2iv—Ag3—Ag2vi110.8 (5)Ag3vi—Cu2—Ag3xv180
Ag2iv—Ag3—Ag3ii109.3 (3)Ag3vi—Cu2—S161.31 (8)
Ag2iv—Ag3—Ag3vi130.7 (3)Ag3vi—Cu2—S1viii118.69 (8)
Ag2iv—Ag3—Cu263.15 (16)Ag3xv—Cu2—Ag3150.0 (2)
Ag2iv—Ag3—S158.73 (16)Ag3xv—Cu2—Ag3viii30.0 (2)
Ag2iv—Ag3—S2i87.6 (2)Ag3xv—Cu2—Ag3ix106.7 (2)
Ag2iv—Ag3—S3vii139.2 (2)Ag3xv—Cu2—Ag3x73.3 (2)
Ag2vi—Ag3—Ag2118.0 (6)Ag3xv—Cu2—Ag3xi81.12 (17)
Ag2vi—Ag3—Ag2v84.9 (4)Ag3xv—Cu2—Ag3v98.88 (17)
Ag2vi—Ag3—Ag2iv110.8 (5)Ag3xv—Cu2—Ag3xii62.43 (15)
Ag2vi—Ag3—Ag3ii139.8 (6)Ag3xv—Cu2—Ag3xiii117.57 (15)
Ag2vi—Ag3—Ag3vi19.9 (5)Ag3xv—Cu2—Ag3iv81.1 (2)
Ag2vi—Ag3—Cu259.0 (4)Ag3xv—Cu2—Ag3xiv98.9 (2)
Ag2vi—Ag3—S154.3 (4)Ag3xv—Cu2—Ag3vi180
Ag2vi—Ag3—S2i115.78 (19)Ag3xv—Cu2—S1118.69 (8)
Ag2vi—Ag3—S3vii89.0 (4)Ag3xv—Cu2—S1viii61.31 (8)
Ag3ii—Ag3—Ag3vi120.0 (4)S1—Cu2—S1viii180
Ag3ii—Ag3—Cu2148.8 (2)S1viii—Cu2—S1180
Ag3ii—Ag3—S1159.0 (3)Ag2—S1—Ag2ix112.2 (5)
Ag3ii—Ag3—S2i63.02 (13)Ag2—S1—Ag2xi130.4 (5)
Ag3ii—Ag3—S3vii61.65 (18)Ag2—S1—Ag2xii112.2 (6)
Ag3vi—Ag3—Ag3ii120.0 (4)Ag2—S1—Ag2iv21.6 (6)
Ag3vi—Ag3—Cu275.0 (2)Ag2—S1—Ag2vi92.1 (5)
Ag3vi—Ag3—S173.6 (3)Ag2—S1—Ag330.2 (5)
Ag3vi—Ag3—S2i112.1 (3)Ag2—S1—Ag3ix136.5 (3)
Ag3vi—Ag3—S3vii72.8 (3)Ag2—S1—Ag3xi146.22 (16)
Cu2—Ag3—S145.38 (8)Ag2—S1—Ag3xii83.8 (5)
Cu2—Ag3—S2i140.7 (2)Ag2—S1—Ag3iv51.7 (5)
Cu2—Ag3—S3vii102.95 (14)Ag2—S1—Ag3vi62.8 (5)
S1—Ag3—S2i97.80 (13)Ag2—S1—Cu273.41 (7)
S1—Ag3—S3vii139.1 (2)Ag2ix—S1—Ag2112.2 (5)
S2i—Ag3—S3vii116.19 (19)Ag2ix—S1—Ag2xi92.1 (5)
Ag2—Cu2—Ag2viii180Ag2ix—S1—Ag2xii112.2 (5)
Ag2—Cu2—Ag2ix94.2 (4)Ag2ix—S1—Ag2iv130.4 (5)
Ag2—Cu2—Ag2x85.8 (4)Ag2ix—S1—Ag2vi21.6 (5)
Ag2—Cu2—Ag2xi106.5 (4)Ag2ix—S1—Ag383.8 (4)
Ag2—Cu2—Ag2v73.5 (4)Ag2ix—S1—Ag3ix30.2 (4)
Ag2—Cu2—Ag2xii94.2 (4)Ag2ix—S1—Ag3xi62.8 (4)
Ag2—Cu2—Ag2xiii85.8 (4)Ag2ix—S1—Ag3xii136.5 (3)
Ag2—Cu2—Ag2iv19.1 (6)Ag2ix—S1—Ag3iv146.2 (2)
Ag2—Cu2—Ag2xiv160.9 (6)Ag2ix—S1—Ag3vi51.7 (4)
Ag2—Cu2—Ag2vi78.9 (5)Ag2ix—S1—Cu273.41 (17)
Ag2—Cu2—Ag2xv101.1 (5)Ag2xi—S1—Ag2130.4 (5)
Ag2—Cu2—Ag327.3 (4)Ag2xi—S1—Ag2ix92.1 (5)
Ag2—Cu2—Ag3viii152.7 (4)Ag2xi—S1—Ag2xii21.6 (6)
Ag2—Cu2—Ag3ix113.38 (17)Ag2xi—S1—Ag2iv112.2 (6)
Ag2—Cu2—Ag3x66.62 (17)Ag2xi—S1—Ag2vi112.2 (5)
Ag2—Cu2—Ag3xi118.84 (12)Ag2xi—S1—Ag3146.22 (16)
Ag2—Cu2—Ag3v61.16 (12)Ag2xi—S1—Ag3ix62.8 (5)
Ag2—Cu2—Ag3xii74.0 (4)Ag2xi—S1—Ag3xi30.2 (5)
Ag2—Cu2—Ag3xiii106.0 (4)Ag2xi—S1—Ag3xii51.7 (5)
Ag2—Cu2—Ag3iv46.3 (4)Ag2xi—S1—Ag3iv83.8 (5)
Ag2—Cu2—Ag3xiv133.7 (4)Ag2xi—S1—Ag3vi136.5 (3)
Ag2—Cu2—Ag3vi56.0 (4)Ag2xi—S1—Cu273.41 (7)
Ag2—Cu2—Ag3xv124.0 (4)Ag2xii—S1—Ag2112.2 (6)
Ag2—Cu2—S157.79 (7)Ag2xii—S1—Ag2ix112.2 (5)
Ag2—Cu2—S1viii122.21 (7)Ag2xii—S1—Ag2xi21.6 (6)
Ag2viii—Cu2—Ag2180Ag2xii—S1—Ag2iv92.1 (6)
Ag2viii—Cu2—Ag2ix85.8 (4)Ag2xii—S1—Ag2vi130.4 (5)
Ag2viii—Cu2—Ag2x94.2 (4)Ag2xii—S1—Ag3136.5 (3)
Ag2viii—Cu2—Ag2xi73.5 (4)Ag2xii—S1—Ag3ix83.8 (5)
Ag2viii—Cu2—Ag2v106.5 (4)Ag2xii—S1—Ag3xi51.7 (5)
Ag2viii—Cu2—Ag2xii85.8 (4)Ag2xii—S1—Ag3xii30.2 (5)
Ag2viii—Cu2—Ag2xiii94.2 (4)Ag2xii—S1—Ag3iv62.8 (5)
Ag2viii—Cu2—Ag2iv160.9 (6)Ag2xii—S1—Ag3vi146.22 (16)
Ag2viii—Cu2—Ag2xiv19.1 (6)Ag2xii—S1—Cu273.41 (7)
Ag2viii—Cu2—Ag2vi101.1 (5)Ag2iv—S1—Ag221.6 (6)
Ag2viii—Cu2—Ag2xv78.9 (5)Ag2iv—S1—Ag2ix130.4 (5)
Ag2viii—Cu2—Ag3152.7 (4)Ag2iv—S1—Ag2xi112.2 (6)
Ag2viii—Cu2—Ag3viii27.3 (4)Ag2iv—S1—Ag2xii92.1 (6)
Ag2viii—Cu2—Ag3ix66.62 (17)Ag2iv—S1—Ag2vi112.2 (5)
Ag2viii—Cu2—Ag3x113.38 (17)Ag2iv—S1—Ag351.7 (5)
Ag2viii—Cu2—Ag3xi61.16 (12)Ag2iv—S1—Ag3ix146.22 (16)
Ag2viii—Cu2—Ag3v118.84 (12)Ag2iv—S1—Ag3xi136.5 (3)
Ag2viii—Cu2—Ag3xii106.0 (4)Ag2iv—S1—Ag3xii62.8 (5)
Ag2viii—Cu2—Ag3xiii74.0 (4)Ag2iv—S1—Ag3iv30.2 (5)
Ag2viii—Cu2—Ag3iv133.7 (4)Ag2iv—S1—Ag3vi83.8 (5)
Ag2viii—Cu2—Ag3xiv46.3 (4)Ag2iv—S1—Cu273.41 (7)
Ag2viii—Cu2—Ag3vi124.0 (4)Ag2vi—S1—Ag292.1 (5)
Ag2viii—Cu2—Ag3xv56.0 (4)Ag2vi—S1—Ag2ix21.6 (5)
Ag2viii—Cu2—S1122.21 (7)Ag2vi—S1—Ag2xi112.2 (5)
Ag2viii—Cu2—S1viii57.79 (7)Ag2vi—S1—Ag2xii130.4 (5)
Ag2ix—Cu2—Ag294.2 (4)Ag2vi—S1—Ag2iv112.2 (5)
Ag2ix—Cu2—Ag2viii85.8 (4)Ag2vi—S1—Ag362.8 (4)
Ag2ix—Cu2—Ag2x180Ag2vi—S1—Ag3ix51.7 (4)
Ag2ix—Cu2—Ag2xi78.9 (5)Ag2vi—S1—Ag3xi83.8 (4)
Ag2ix—Cu2—Ag2v101.1 (5)Ag2vi—S1—Ag3xii146.2 (2)
Ag2ix—Cu2—Ag2xii94.2 (5)Ag2vi—S1—Ag3iv136.5 (3)
Ag2ix—Cu2—Ag2xiii85.8 (5)Ag2vi—S1—Ag3vi30.2 (4)
Ag2ix—Cu2—Ag2iv106.5 (4)Ag2vi—S1—Cu273.41 (17)
Ag2ix—Cu2—Ag2xiv73.5 (4)Ag3—S1—Ag3ix112.1 (2)
Ag2ix—Cu2—Ag2vi19.1 (4)Ag3—S1—Ag3xi138.08 (17)
Ag2ix—Cu2—Ag2xv160.9 (4)Ag3—S1—Ag3xii112.1 (2)
Ag2ix—Cu2—Ag374.0 (3)Ag3—S1—Ag3iv81.3 (2)
Ag2ix—Cu2—Ag3viii106.0 (3)Ag3—S1—Ag3vi32.8 (2)
Ag2ix—Cu2—Ag3ix27.3 (3)Ag3—S1—Cu273.31 (8)
Ag2ix—Cu2—Ag3x152.7 (3)Ag3ix—S1—Ag3112.1 (2)
Ag2ix—Cu2—Ag3xi56.0 (3)Ag3ix—S1—Ag3xi32.8 (2)
Ag2ix—Cu2—Ag3v124.0 (3)Ag3ix—S1—Ag3xii112.1 (2)
Ag2ix—Cu2—Ag3xii113.4 (3)Ag3ix—S1—Ag3iv138.08 (18)
Ag2ix—Cu2—Ag3xiii66.6 (3)Ag3ix—S1—Ag3vi81.3 (2)
Ag2ix—Cu2—Ag3iv118.8 (3)Ag3ix—S1—Cu273.31 (8)
Ag2ix—Cu2—Ag3xiv61.2 (3)Ag3xi—S1—Ag3138.08 (17)
Ag2ix—Cu2—Ag3vi46.3 (3)Ag3xi—S1—Ag3ix32.8 (2)
Ag2ix—Cu2—Ag3xv133.7 (3)Ag3xi—S1—Ag3xii81.3 (2)
Ag2ix—Cu2—S157.8 (3)Ag3xi—S1—Ag3iv112.1 (2)
Ag2ix—Cu2—S1viii122.2 (3)Ag3xi—S1—Ag3vi112.1 (2)
Ag2x—Cu2—Ag285.8 (4)Ag3xi—S1—Cu273.31 (8)
Ag2x—Cu2—Ag2viii94.2 (4)Ag3xii—S1—Ag3112.1 (2)
Ag2x—Cu2—Ag2ix180Ag3xii—S1—Ag3ix112.1 (2)
Ag2x—Cu2—Ag2xi101.1 (5)Ag3xii—S1—Ag3xi81.3 (2)
Ag2x—Cu2—Ag2v78.9 (5)Ag3xii—S1—Ag3iv32.8 (2)
Ag2x—Cu2—Ag2xii85.8 (5)Ag3xii—S1—Ag3vi138.08 (18)
Ag2x—Cu2—Ag2xiii94.2 (5)Ag3xii—S1—Cu273.31 (9)
Ag2x—Cu2—Ag2iv73.5 (4)Ag3iv—S1—Ag381.3 (2)
Ag2x—Cu2—Ag2xiv106.5 (4)Ag3iv—S1—Ag3ix138.08 (18)
Ag2x—Cu2—Ag2vi160.9 (4)Ag3iv—S1—Ag3xi112.1 (2)
Ag2x—Cu2—Ag2xv19.1 (4)Ag3iv—S1—Ag3xii32.8 (2)
Ag2x—Cu2—Ag3106.0 (3)Ag3iv—S1—Ag3vi112.1 (2)
Ag2x—Cu2—Ag3viii74.0 (3)Ag3iv—S1—Cu273.31 (9)
Ag2x—Cu2—Ag3ix152.7 (3)Ag3vi—S1—Ag332.8 (2)
Ag2x—Cu2—Ag3x27.3 (3)Ag3vi—S1—Ag3ix81.3 (2)
Ag2x—Cu2—Ag3xi124.0 (3)Ag3vi—S1—Ag3xi112.1 (2)
Ag2x—Cu2—Ag3v56.0 (3)Ag3vi—S1—Ag3xii138.08 (18)
Ag2x—Cu2—Ag3xii66.6 (3)Ag3vi—S1—Ag3iv112.1 (2)
Ag2x—Cu2—Ag3xiii113.4 (3)Ag3vi—S1—Cu273.31 (8)
Ag2x—Cu2—Ag3iv61.2 (3)As—S2—Sb0
Ag2x—Cu2—Ag3xiv118.8 (3)As—S2—Ag1ix102.29 (5)
Ag2x—Cu2—Ag3vi133.7 (3)As—S2—Ag1xvi102.29 (4)
Ag2x—Cu2—Ag3xv46.3 (3)As—S2—Cu1ix102.29 (4)
Ag2x—Cu2—S1122.2 (3)As—S2—Cu1xvi102.29 (3)
Ag2x—Cu2—S1viii57.8 (3)As—S2—Ag2xvii130.4 (2)
Ag2xi—Cu2—Ag2106.5 (4)As—S2—Ag2vi130.4 (4)
Ag2xi—Cu2—Ag2viii73.5 (4)As—S2—Ag3xvii105.74 (15)
Ag2xi—Cu2—Ag2ix78.9 (5)As—S2—Ag3vi105.74 (18)
Ag2xi—Cu2—Ag2x101.1 (5)Sb—S2—Ag1ix102.29 (5)
Ag2xi—Cu2—Ag2v180Sb—S2—Ag1xvi102.29 (4)
Ag2xi—Cu2—Ag2xii19.1 (6)Sb—S2—Cu1ix102.29 (4)
Ag2xi—Cu2—Ag2xiii160.9 (6)Sb—S2—Cu1xvi102.29 (3)
Ag2xi—Cu2—Ag2iv94.2 (4)Sb—S2—Ag2xvii130.4 (2)
Ag2xi—Cu2—Ag2xiv85.8 (4)Sb—S2—Ag2vi130.4 (4)
Ag2xi—Cu2—Ag2vi94.2 (4)Sb—S2—Ag3xvii105.74 (15)
Ag2xi—Cu2—Ag2xv85.8 (4)Sb—S2—Ag3vi105.74 (18)
Ag2xi—Cu2—Ag3118.84 (12)Ag1ix—S2—Ag1xvi111.92 (6)
Ag2xi—Cu2—Ag3viii61.16 (12)Ag1ix—S2—Cu1ix0
Ag2xi—Cu2—Ag3ix56.0 (4)Ag1ix—S2—Cu1xvi111.92 (5)
Ag2xi—Cu2—Ag3x124.0 (4)Ag1ix—S2—Ag2xvii125.64 (14)
Ag2xi—Cu2—Ag3xi27.3 (4)Ag1ix—S2—Ag2vi73.3 (3)
Ag2xi—Cu2—Ag3v152.7 (4)Ag1ix—S2—Ag3xvii139.26 (12)
Ag2xi—Cu2—Ag3xii46.3 (4)Ag1ix—S2—Ag3vi90.33 (12)
Ag2xi—Cu2—Ag3xiii133.7 (4)Ag1xvi—S2—Ag1ix111.92 (6)
Ag2xi—Cu2—Ag3iv74.0 (4)Ag1xvi—S2—Cu1ix111.92 (5)
Ag2xi—Cu2—Ag3xiv106.0 (4)Ag1xvi—S2—Cu1xvi0
Ag2xi—Cu2—Ag3vi113.38 (17)Ag1xvi—S2—Ag2xvii73.3 (3)
Ag2xi—Cu2—Ag3xv66.62 (17)Ag1xvi—S2—Ag2vi125.6 (5)
Ag2xi—Cu2—S157.79 (7)Ag1xvi—S2—Ag3xvii90.3 (2)
Ag2xi—Cu2—S1viii122.21 (7)Ag1xvi—S2—Ag3vi139.26 (19)
Ag2v—Cu2—Ag273.5 (4)Cu1ix—S2—Cu1xvi111.92 (4)
Ag2v—Cu2—Ag2viii106.5 (4)Cu1ix—S2—Ag2xvii125.64 (14)
Ag2v—Cu2—Ag2ix101.1 (5)Cu1ix—S2—Ag2vi73.3 (3)
Ag2v—Cu2—Ag2x78.9 (5)Cu1ix—S2—Ag3xvii139.26 (12)
Ag2v—Cu2—Ag2xi180Cu1ix—S2—Ag3vi90.33 (11)
Ag2v—Cu2—Ag2xii160.9 (6)Cu1xvi—S2—Cu1ix111.92 (4)
Ag2v—Cu2—Ag2xiii19.1 (6)Cu1xvi—S2—Ag2xvii73.3 (3)
Ag2v—Cu2—Ag2iv85.8 (4)Cu1xvi—S2—Ag2vi125.6 (5)
Ag2v—Cu2—Ag2xiv94.2 (4)Cu1xvi—S2—Ag3xvii90.33 (19)
Ag2v—Cu2—Ag2vi85.8 (4)Cu1xvi—S2—Ag3vi139.26 (18)
Ag2v—Cu2—Ag2xv94.2 (4)Ag2xvii—S2—Ag2vi63.4 (4)
Ag2v—Cu2—Ag361.16 (12)Ag2xvii—S2—Ag3xvii28.1 (4)
Ag2v—Cu2—Ag3viii118.84 (12)Ag2xvii—S2—Ag3vi66.1 (3)
Ag2v—Cu2—Ag3ix124.0 (4)Ag2vi—S2—Ag2xvii63.4 (4)
Ag2v—Cu2—Ag3x56.0 (4)Ag2vi—S2—Ag3xvii66.1 (3)
Ag2v—Cu2—Ag3xi152.7 (4)Ag2vi—S2—Ag3vi28.1 (3)
Ag2v—Cu2—Ag3v27.3 (4)Ag3xvii—S2—Ag3vi54.0 (2)
Ag2v—Cu2—Ag3xii133.7 (4)Ag3vi—S2—Ag3xvii54.0 (2)
Ag2v—Cu2—Ag3xiii46.3 (4)Ag2—S3—Ag2xviii94.9 (5)
Ag2v—Cu2—Ag3iv106.0 (4)Ag2—S3—Ag2ii77.0 (5)
Ag2v—Cu2—Ag3xiv74.0 (4)Ag2—S3—Ag2xix94.9 (5)
Ag2v—Cu2—Ag3vi66.62 (17)Ag2—S3—Ag2iv22.0 (7)
Ag2v—Cu2—Ag3xv113.38 (17)Ag2—S3—Ag2xx108.8 (4)
Ag2v—Cu2—S1122.21 (7)Ag2—S3—Ag3vii105.7 (4)
Ag2v—Cu2—S1viii57.79 (7)Ag2—S3—Ag3x78.0 (2)
Ag2xii—Cu2—Ag294.2 (4)Ag2—S3—Ag3v71.30 (16)
Ag2xii—Cu2—Ag2viii85.8 (4)Ag2—S3—Ag3xxi158.6 (4)
Ag2xii—Cu2—Ag2ix94.2 (5)Ag2—S3—Ag3xxii124.3 (4)
Ag2xii—Cu2—Ag2x85.8 (5)Ag2—S3—Ag3xxiii138.6 (5)
Ag2xii—Cu2—Ag2xi19.1 (6)Ag2xviii—S3—Ag294.9 (5)
Ag2xii—Cu2—Ag2v160.9 (6)Ag2xviii—S3—Ag2ii108.8 (4)
Ag2xii—Cu2—Ag2xiii180Ag2xviii—S3—Ag2xix94.9 (4)
Ag2xii—Cu2—Ag2iv78.9 (5)Ag2xviii—S3—Ag2iv77.0 (5)
Ag2xii—Cu2—Ag2xiv101.1 (5)Ag2xviii—S3—Ag2xx22.0 (5)
Ag2xii—Cu2—Ag2vi106.5 (4)Ag2xviii—S3—Ag3vii158.6 (4)
Ag2xii—Cu2—Ag2xv73.5 (4)Ag2xviii—S3—Ag3x105.7 (4)
Ag2xii—Cu2—Ag3113.38 (18)Ag2xviii—S3—Ag3v138.6 (3)
Ag2xii—Cu2—Ag3viii66.62 (18)Ag2xviii—S3—Ag3xxi78.0 (4)
Ag2xii—Cu2—Ag3ix74.0 (4)Ag2xviii—S3—Ag3xxii71.3 (3)
Ag2xii—Cu2—Ag3x106.0 (4)Ag2xviii—S3—Ag3xxiii124.3 (4)
Ag2xii—Cu2—Ag3xi46.3 (4)Ag2ii—S3—Ag277.0 (5)
Ag2xii—Cu2—Ag3v133.7 (4)Ag2ii—S3—Ag2xviii108.8 (4)
Ag2xii—Cu2—Ag3xii27.3 (4)Ag2ii—S3—Ag2xix22.0 (7)
Ag2xii—Cu2—Ag3xiii152.7 (4)Ag2ii—S3—Ag2iv94.9 (5)
Ag2xii—Cu2—Ag3iv56.0 (4)Ag2ii—S3—Ag2xx94.9 (5)
Ag2xii—Cu2—Ag3xiv124.0 (4)Ag2ii—S3—Ag3vii71.30 (16)
Ag2xii—Cu2—Ag3vi118.84 (13)Ag2ii—S3—Ag3x138.6 (5)
Ag2xii—Cu2—Ag3xv61.16 (13)Ag2ii—S3—Ag3v105.7 (4)
Ag2xii—Cu2—S157.79 (7)Ag2ii—S3—Ag3xxi124.3 (4)
Ag2xii—Cu2—S1viii122.21 (7)Ag2ii—S3—Ag3xxii158.6 (4)
Ag2xiii—Cu2—Ag285.8 (4)Ag2ii—S3—Ag3xxiii78.0 (2)
Ag2xiii—Cu2—Ag2viii94.2 (4)Ag2xix—S3—Ag294.9 (5)
Ag2xiii—Cu2—Ag2ix85.8 (5)Ag2xix—S3—Ag2xviii94.9 (4)
Ag2xiii—Cu2—Ag2x94.2 (5)Ag2xix—S3—Ag2ii22.0 (7)
Ag2xiii—Cu2—Ag2xi160.9 (6)Ag2xix—S3—Ag2iv108.8 (4)
Ag2xiii—Cu2—Ag2v19.1 (6)Ag2xix—S3—Ag2xx77.0 (5)
Ag2xiii—Cu2—Ag2xii180Ag2xix—S3—Ag3vii78.0 (2)
Ag2xiii—Cu2—Ag2iv101.1 (5)Ag2xix—S3—Ag3x158.6 (4)
Ag2xiii—Cu2—Ag2xiv78.9 (5)Ag2xix—S3—Ag3v124.3 (4)
Ag2xiii—Cu2—Ag2vi73.5 (4)Ag2xix—S3—Ag3xxi105.7 (4)
Ag2xiii—Cu2—Ag2xv106.5 (4)Ag2xix—S3—Ag3xxii138.6 (5)
Ag2xiii—Cu2—Ag366.62 (18)Ag2xix—S3—Ag3xxiii71.30 (16)
Ag2xiii—Cu2—Ag3viii113.38 (18)Ag2iv—S3—Ag222.0 (7)
Ag2xiii—Cu2—Ag3ix106.0 (4)Ag2iv—S3—Ag2xviii77.0 (5)
Ag2xiii—Cu2—Ag3x74.0 (4)Ag2iv—S3—Ag2ii94.9 (5)
Ag2xiii—Cu2—Ag3xi133.7 (4)Ag2iv—S3—Ag2xix108.8 (4)
Ag2xiii—Cu2—Ag3v46.3 (4)Ag2iv—S3—Ag2xx94.9 (4)
Ag2xiii—Cu2—Ag3xii152.7 (4)Ag2iv—S3—Ag3vii124.3 (4)
Ag2xiii—Cu2—Ag3xiii27.3 (4)Ag2iv—S3—Ag3x71.30 (16)
Ag2xiii—Cu2—Ag3iv124.0 (4)Ag2iv—S3—Ag3v78.0 (2)
Ag2xiii—Cu2—Ag3xiv56.0 (4)Ag2iv—S3—Ag3xxi138.6 (5)
Ag2xiii—Cu2—Ag3vi61.16 (13)Ag2iv—S3—Ag3xxii105.7 (4)
Ag2xiii—Cu2—Ag3xv118.84 (13)Ag2iv—S3—Ag3xxiii158.6 (4)
Ag2xiii—Cu2—S1122.21 (7)Ag2xx—S3—Ag2108.8 (4)
Ag2xiii—Cu2—S1viii57.79 (7)Ag2xx—S3—Ag2xviii22.0 (5)
Ag2iv—Cu2—Ag219.1 (6)Ag2xx—S3—Ag2ii94.9 (5)
Ag2iv—Cu2—Ag2viii160.9 (6)Ag2xx—S3—Ag2xix77.0 (5)
Ag2iv—Cu2—Ag2ix106.5 (4)Ag2xx—S3—Ag2iv94.9 (4)
Ag2iv—Cu2—Ag2x73.5 (4)Ag2xx—S3—Ag3vii138.6 (3)
Ag2iv—Cu2—Ag2xi94.2 (4)Ag2xx—S3—Ag3x124.3 (4)
Ag2iv—Cu2—Ag2v85.8 (4)Ag2xx—S3—Ag3v158.6 (4)
Ag2iv—Cu2—Ag2xii78.9 (5)Ag2xx—S3—Ag3xxi71.3 (3)
Ag2iv—Cu2—Ag2xiii101.1 (5)Ag2xx—S3—Ag3xxii78.0 (4)
Ag2iv—Cu2—Ag2xiv180Ag2xx—S3—Ag3xxiii105.7 (4)
Ag2iv—Cu2—Ag2vi94.2 (5)Ag3vii—S3—Ag3x84.6 (2)
Ag2iv—Cu2—Ag2xv85.8 (5)Ag3vii—S3—Ag3v56.71 (16)
Ag2iv—Cu2—Ag346.3 (4)Ag3vii—S3—Ag3xxi84.6 (2)
Ag2iv—Cu2—Ag3viii133.7 (4)Ag3vii—S3—Ag3xxii100.7 (2)
Ag2iv—Cu2—Ag3ix118.84 (13)Ag3vii—S3—Ag3xxiii34.3 (3)
Ag2iv—Cu2—Ag3x61.16 (13)Ag3x—S3—Ag3vii84.6 (2)
Ag2iv—Cu2—Ag3xi113.38 (18)Ag3x—S3—Ag3v34.3 (3)
Ag2iv—Cu2—Ag3v66.62 (18)Ag3x—S3—Ag3xxi84.6 (2)
Ag2iv—Cu2—Ag3xii56.0 (4)Ag3x—S3—Ag3xxii56.7 (2)
Ag2iv—Cu2—Ag3xiii124.0 (4)Ag3x—S3—Ag3xxiii100.72 (17)
Ag2iv—Cu2—Ag3iv27.3 (4)Ag3v—S3—Ag3vii56.71 (16)
Ag2iv—Cu2—Ag3xiv152.7 (4)Ag3v—S3—Ag3x34.3 (3)
Ag2iv—Cu2—Ag3vi74.0 (4)Ag3v—S3—Ag3xxi100.7 (2)
Ag2iv—Cu2—Ag3xv106.0 (4)Ag3v—S3—Ag3xxii84.6 (2)
Ag2iv—Cu2—S157.79 (7)Ag3v—S3—Ag3xxiii84.6 (2)
Ag2iv—Cu2—S1viii122.21 (7)Ag3xxi—S3—Ag3vii84.6 (2)
Ag2xiv—Cu2—Ag2160.9 (6)Ag3xxi—S3—Ag3x84.6 (2)
Ag2xiv—Cu2—Ag2viii19.1 (6)Ag3xxi—S3—Ag3v100.7 (2)
Ag2xiv—Cu2—Ag2ix73.5 (4)Ag3xxi—S3—Ag3xxii34.34 (16)
Ag2xiv—Cu2—Ag2x106.5 (4)Ag3xxi—S3—Ag3xxiii56.7 (2)
Ag2xiv—Cu2—Ag2xi85.8 (4)Ag3xxii—S3—Ag3vii100.7 (2)
Ag2xiv—Cu2—Ag2v94.2 (4)Ag3xxii—S3—Ag3x56.7 (2)
Ag2xiv—Cu2—Ag2xii101.1 (5)Ag3xxii—S3—Ag3v84.6 (2)
Ag2xiv—Cu2—Ag2xiii78.9 (5)Ag3xxii—S3—Ag3xxi34.34 (16)
Ag2xiv—Cu2—Ag2iv180Ag3xxii—S3—Ag3xxiii84.6 (2)
Ag2xiv—Cu2—Ag2vi85.8 (5)Ag3xxiii—S3—Ag3vii34.3 (3)
Ag2xiv—Cu2—Ag2xv94.2 (5)Ag3xxiii—S3—Ag3x100.72 (17)
Ag2xiv—Cu2—Ag3133.7 (4)Ag3xxiii—S3—Ag3v84.6 (2)
Ag2xiv—Cu2—Ag3viii46.3 (4)Ag3xxiii—S3—Ag3xxi56.7 (2)
Ag2xiv—Cu2—Ag3ix61.16 (13)Ag3xxiii—S3—Ag3xxii84.6 (2)
Ag2xiv—Cu2—Ag3x118.84 (13)Ag1—S4—Ag1xxiv180
Ag2xiv—Cu2—Ag3xi66.62 (18)Ag1—S4—Ag1ix89.92 (5)
Ag2xiv—Cu2—Ag3v113.38 (18)Ag1—S4—Ag1xxv90.08 (5)
Ag2xiv—Cu2—Ag3xii124.0 (4)Ag1—S4—Ag1xi89.92 (3)
Ag2xiv—Cu2—Ag3xiii56.0 (4)Ag1—S4—Ag1xxvi90.08 (3)
Ag2xiv—Cu2—Ag3iv152.7 (4)Ag1—S4—Cu10
Ag2xiv—Cu2—Ag3xiv27.3 (4)Ag1—S4—Cu1xxiv180
Ag2xiv—Cu2—Ag3vi106.0 (4)Ag1—S4—Cu1ix89.92 (4)
Ag2xiv—Cu2—Ag3xv74.0 (4)Ag1—S4—Cu1xxv90.08 (4)
Ag2xiv—Cu2—S1122.21 (7)Ag1—S4—Cu1xi89.92 (2)
Ag2xiv—Cu2—S1viii57.79 (7)Ag1—S4—Cu1xxvi90.08 (2)
Ag2vi—Cu2—Ag278.9 (5)Ag1xxiv—S4—Ag1180
Ag2vi—Cu2—Ag2viii101.1 (5)Ag1xxiv—S4—Ag1ix90.08 (5)
Ag2vi—Cu2—Ag2ix19.1 (4)Ag1xxiv—S4—Ag1xxv89.92 (5)
Ag2vi—Cu2—Ag2x160.9 (4)Ag1xxiv—S4—Ag1xi90.08 (3)
Ag2vi—Cu2—Ag2xi94.2 (4)Ag1xxiv—S4—Ag1xxvi89.92 (3)
Ag2vi—Cu2—Ag2v85.8 (4)Ag1xxiv—S4—Cu1180
Ag2vi—Cu2—Ag2xii106.5 (4)Ag1xxiv—S4—Cu1xxiv0
Ag2vi—Cu2—Ag2xiii73.5 (4)Ag1xxiv—S4—Cu1ix90.08 (4)
Ag2vi—Cu2—Ag2iv94.2 (5)Ag1xxiv—S4—Cu1xxv89.92 (4)
Ag2vi—Cu2—Ag2xiv85.8 (5)Ag1xxiv—S4—Cu1xi90.08 (2)
Ag2vi—Cu2—Ag2xv180Ag1xxiv—S4—Cu1xxvi89.92 (2)
Ag2vi—Cu2—Ag356.0 (3)Ag1ix—S4—Ag189.92 (5)
Ag2vi—Cu2—Ag3viii124.0 (3)Ag1ix—S4—Ag1xxiv90.08 (5)
Ag2vi—Cu2—Ag3ix46.3 (3)Ag1ix—S4—Ag1xxv180
Ag2vi—Cu2—Ag3x133.7 (3)Ag1ix—S4—Ag1xi89.92 (6)
Ag2vi—Cu2—Ag3xi74.0 (3)Ag1ix—S4—Ag1xxvi90.08 (6)
Ag2vi—Cu2—Ag3v106.0 (3)Ag1ix—S4—Cu189.92 (2)
Ag2vi—Cu2—Ag3xii118.8 (3)Ag1ix—S4—Cu1xxiv90.08 (2)
Ag2vi—Cu2—Ag3xiii61.2 (3)Ag1ix—S4—Cu1ix0
Ag2vi—Cu2—Ag3iv113.4 (3)Ag1ix—S4—Cu1xxv180
Ag2vi—Cu2—Ag3xiv66.6 (3)Ag1ix—S4—Cu1xi89.92 (4)
Ag2vi—Cu2—Ag3vi27.3 (3)Ag1ix—S4—Cu1xxvi90.08 (4)
Ag2vi—Cu2—Ag3xv152.7 (3)Ag1xxv—S4—Ag190.08 (5)
Ag2vi—Cu2—S157.8 (3)Ag1xxv—S4—Ag1xxiv89.92 (5)
Ag2vi—Cu2—S1viii122.2 (3)Ag1xxv—S4—Ag1ix180
Ag2xv—Cu2—Ag2101.1 (5)Ag1xxv—S4—Ag1xi90.08 (6)
Ag2xv—Cu2—Ag2viii78.9 (5)Ag1xxv—S4—Ag1xxvi89.92 (6)
Ag2xv—Cu2—Ag2ix160.9 (4)Ag1xxv—S4—Cu190.08 (2)
Ag2xv—Cu2—Ag2x19.1 (4)Ag1xxv—S4—Cu1xxiv89.92 (2)
Ag2xv—Cu2—Ag2xi85.8 (4)Ag1xxv—S4—Cu1ix180
Ag2xv—Cu2—Ag2v94.2 (4)Ag1xxv—S4—Cu1xxv0
Ag2xv—Cu2—Ag2xii73.5 (4)Ag1xxv—S4—Cu1xi90.08 (4)
Ag2xv—Cu2—Ag2xiii106.5 (4)Ag1xxv—S4—Cu1xxvi89.92 (4)
Ag2xv—Cu2—Ag2iv85.8 (5)Ag1xi—S4—Ag189.92 (3)
Ag2xv—Cu2—Ag2xiv94.2 (5)Ag1xi—S4—Ag1xxiv90.08 (3)
Ag2xv—Cu2—Ag2vi180Ag1xi—S4—Ag1ix89.92 (6)
Ag2xv—Cu2—Ag3124.0 (3)Ag1xi—S4—Ag1xxv90.08 (6)
Ag2xv—Cu2—Ag3viii56.0 (3)Ag1xi—S4—Ag1xxvi180
Ag2xv—Cu2—Ag3ix133.7 (3)Ag1xi—S4—Cu189.92 (2)
Ag2xv—Cu2—Ag3x46.3 (3)Ag1xi—S4—Cu1xxiv90.08 (2)
Ag2xv—Cu2—Ag3xi106.0 (3)Ag1xi—S4—Cu1ix89.92 (4)
Ag2xv—Cu2—Ag3v74.0 (3)Ag1xi—S4—Cu1xxv90.08 (4)
Ag2xv—Cu2—Ag3xii61.2 (3)Ag1xi—S4—Cu1xi0
Ag2xv—Cu2—Ag3xiii118.8 (3)Ag1xi—S4—Cu1xxvi180
Ag2xv—Cu2—Ag3iv66.6 (3)Ag1xxvi—S4—Ag190.08 (3)
Ag2xv—Cu2—Ag3xiv113.4 (3)Ag1xxvi—S4—Ag1xxiv89.92 (3)
Ag2xv—Cu2—Ag3vi152.7 (3)Ag1xxvi—S4—Ag1ix90.08 (6)
Ag2xv—Cu2—Ag3xv27.3 (3)Ag1xxvi—S4—Ag1xxv89.92 (6)
Ag2xv—Cu2—S1122.2 (3)Ag1xxvi—S4—Ag1xi180
Ag2xv—Cu2—S1viii57.8 (3)Ag1xxvi—S4—Cu190.08 (2)
Ag3—Cu2—Ag3viii180Ag1xxvi—S4—Cu1xxiv89.92 (2)
Ag3—Cu2—Ag3ix98.88 (17)Ag1xxvi—S4—Cu1ix90.08 (4)
Ag3—Cu2—Ag3x81.12 (17)Ag1xxvi—S4—Cu1xxv89.92 (4)
Ag3—Cu2—Ag3xi117.57 (12)Ag1xxvi—S4—Cu1xi180
Ag3—Cu2—Ag3v62.43 (12)Ag1xxvi—S4—Cu1xxvi0
Ag3—Cu2—Ag3xii98.88 (16)Cu1—S4—Cu1xxiv180
Ag3—Cu2—Ag3xiii81.12 (16)Cu1—S4—Cu1ix89.919
Ag3—Cu2—Ag3iv73.3 (2)Cu1—S4—Cu1xxv90.081
Ag3—Cu2—Ag3xiv106.7 (2)Cu1—S4—Cu1xi89.919
Ag3—Cu2—Ag3vi30.0 (2)Cu1—S4—Cu1xxvi90.081
Ag3—Cu2—Ag3xv150.0 (2)Cu1xxiv—S4—Cu1180
Ag3—Cu2—S161.31 (7)Cu1xxiv—S4—Cu1ix90.081
Ag3—Cu2—S1viii118.69 (7)Cu1xxiv—S4—Cu1xxv89.919
Ag3viii—Cu2—Ag3180Cu1xxiv—S4—Cu1xi90.081
Ag3viii—Cu2—Ag3ix81.12 (17)Cu1xxiv—S4—Cu1xxvi89.919
Ag3viii—Cu2—Ag3x98.88 (17)Cu1ix—S4—Cu189.919
Ag3viii—Cu2—Ag3xi62.43 (12)Cu1ix—S4—Cu1xxiv90.081
Ag3viii—Cu2—Ag3v117.57 (12)Cu1ix—S4—Cu1xxv180
Ag3viii—Cu2—Ag3xii81.12 (16)Cu1ix—S4—Cu1xi89.919
Ag3viii—Cu2—Ag3xiii98.88 (16)Cu1ix—S4—Cu1xxvi90.081
Ag3viii—Cu2—Ag3iv106.7 (2)Cu1xxv—S4—Cu190.081
Ag3viii—Cu2—Ag3xiv73.3 (2)Cu1xxv—S4—Cu1xxiv89.919
Ag3viii—Cu2—Ag3vi150.0 (2)Cu1xxv—S4—Cu1ix180
Ag3viii—Cu2—Ag3xv30.0 (2)Cu1xxv—S4—Cu1xi90.081
Ag3viii—Cu2—S1118.69 (7)Cu1xxv—S4—Cu1xxvi89.919
Ag3viii—Cu2—S1viii61.31 (7)Cu1xi—S4—Cu189.919
Ag3ix—Cu2—Ag398.88 (17)Cu1xi—S4—Cu1xxiv90.081
Ag3ix—Cu2—Ag3viii81.12 (17)Cu1xi—S4—Cu1ix89.919
Ag3ix—Cu2—Ag3x180Cu1xi—S4—Cu1xxv90.081
Ag3ix—Cu2—Ag3xi30.0 (2)Cu1xi—S4—Cu1xxvi180
Ag3ix—Cu2—Ag3v150.0 (2)Cu1xxvi—S4—Cu190.081
Ag3ix—Cu2—Ag3xii98.9 (2)Cu1xxvi—S4—Cu1xxiv89.919
Ag3ix—Cu2—Ag3xiii81.1 (2)Cu1xxvi—S4—Cu1ix90.081
Ag3ix—Cu2—Ag3iv117.57 (15)Cu1xxvi—S4—Cu1xxv89.919
Ag3ix—Cu2—Ag3xiv62.43 (15)Cu1xxvi—S4—Cu1xi180
Ag3ix—Cu2—Ag3vi73.3 (2)
Symmetry codes: (i) y+1, xy+1, z; (ii) y+1, x+1, z; (iii) y+1, x, z; (iv) x, xy, z; (v) y, x, z; (vi) x+y, y, z; (vii) x+1, y+1, z; (viii) x, y, z; (ix) y, xy, z; (x) y, x+y, z; (xi) y, x, z; (xii) x+y, x, z; (xiii) xy, x, z; (xiv) x, x+y, z; (xv) xy, y, z; (xvi) y, x+1, z; (xvii) x+y, x+1, z; (xviii) y+1, xy, z; (xix) x+y+1, x+1, z; (xx) x+y+1, y, z; (xxi) xy+1, x, z; (xxii) x+1, x+y, z; (xxiii) xy+1, y+1, z; (xxiv) x, y, z+1; (xxv) y, x+y, z+1; (xxvi) y, x, z+1.
Selected bond lengths (Å) for (120K) top
As—Sb0Ag2—Ag42.78 (3)
As—S22.3161 (11)Ag2—Ag4xii2.10 (2)
As—S2i2.3161 (12)Ag2—Cu22.731 (4)
As—S2ii2.3161 (11)Ag2—S12.408 (4)
Sb—S22.3161 (11)Ag2—S2i2.865 (13)
Sb—S2i2.3161 (12)Ag2—S32.352 (5)
Sb—S2ii2.3161 (11)Ag3—Ag3ii2.504 (3)
Ag1—Cu10Ag3—Ag3x2.965 (4)
Ag1—S2i2.4469 (13)Ag3—Ag3xi1.452 (6)
Ag1—S2iii2.4469 (17)Ag3—Ag4v2.33 (2)
Ag1—S41.951 (3)Ag3—Ag4xii1.253 (10)
Ag1—S4iv2.825 (4)Ag3—Cu22.850 (2)
Ag1—S4v2.4272 (18)Ag3—S12.621 (2)
Ag1—S4vi2.4272 (16)Ag3—S2i2.677 (3)
Ag1—S4vii2.825 (4)Ag3—S3xiii2.570 (3)
Ag1—S4viii1.951 (4)Ag4—Ag4xiv2.933 (11)
Cu1—S2i2.4469 (11)Ag4—Ag4xv2.664 (15)
Cu1—S2iii2.4469 (11)Ag4—Ag4xvi2.66 (2)
Cu1—S41.951 (3)Ag4—S2iii2.398 (7)
Cu1—S4iv2.825 (4)Ag4—S32.932 (13)
Cu1—S4v2.4272 (12)Ag4—S3xiv2.209 (11)
Cu1—S4vi2.4272 (12)Cu2—S12.1610 (16)
Cu1—S4vii2.825 (3)Cu2—S1xvii2.1610 (16)
Cu1—S4viii1.951 (3)S4—S4iv1.258 (7)
Ag2—Ag2ix0.70 (3)S4—S4v1.089 (6)
Ag2—Ag31.43 (2)S4—S4vi0.629 (3)
Ag2—Ag3x2.861 (4)S4—S4vii1.089 (6)
Ag2—Ag3ix2.11 (2)S4—S4viii0.629 (6)
Ag2—Ag3xi2.696 (19)
Symmetry codes: (i) y+1, xy+1, z; (ii) y+1, x+1, z; (iii) y+1, x, z; (iv) x, y, z+1; (v) y, xy, z; (vi) y, x+y, z+1; (vii) x+y, x, z; (viii) xy, x, z+1; (ix) x, xy, z; (x) y, x, z; (xi) x+y, y, z; (xii) x+y+1, x+1, z; (xiii) x+1, y+1, z; (xiv) x+1, y, z; (xv) y, xy1, z; (xvi) x+y+1, x, z; (xvii) x, y, z.
Selected bond lengths (Å) for (15K) top
As—Sb0Ag2—Ag6xviii2.507 (16)
As—Ag1i3.3758 (19)Ag2—Cu22.750 (2)
As—Ag1ii3.376 (2)Ag2—S12.429 (3)
As—Ag1iii3.3757 (19)Ag2—S2iv2.880 (4)
As—Cu1i3.3758 (7)Ag2—S2x3.263 (5)
As—Cu1ii3.3757 (7)Ag2—S32.326 (3)
As—Cu1iii3.3757 (7)Ag3—Ag3xix3.451 (5)
As—S22.341 (2)Ag3—Ag3v2.205 (7)
As—S2iv2.341 (2)Ag3—Ag3xv2.655 (5)
As—S2v2.341 (2)Ag3—Ag3ix2.962 (14)
Sb—Ag1i3.3758 (18)Ag3—Ag3xviii2.222 (13)
Sb—Ag1ii3.376 (2)Ag3—Ag41.194 (10)
Sb—Ag1iii3.3757 (18)Ag3—Ag4xix3.003 (8)
Sb—Cu1i3.3758Ag3—Ag4xx2.655 (16)
Sb—Cu1ii3.3757Ag3—Ag50.649 (14)
Sb—Cu1iii3.3757Ag3—Ag5v2.467 (8)
Sb—S22.341 (2)Ag3—Ag5xv2.773 (5)
Sb—S2iv2.341 (2)Ag3—Ag5xxi3.396 (9)
Sb—S2v2.341 (2)Ag3—Ag5ix2.354 (15)
Ag1—Ag1vi3.313 (3)Ag3—Ag5xviii2.699 (13)
Ag1—Ag1vii3.316 (2)Ag3—Ag60.688 (17)
Ag1—Ag1viii3.3131 (17)Ag3—Ag6iv3.218 (15)
Ag1—Ag1iii3.316 (3)Ag3—Ag6xvii3.361 (12)
Ag1—Cu10Ag3—Ag6v2.541 (13)
Ag1—Cu1vi3.313 (2)Ag3—Ag6xv2.948 (9)
Ag1—Cu1vii3.3156 (15)Ag3—Ag6ix3.422 (19)
Ag1—Cu1viii3.3131 (12)Ag3—Ag6xviii1.559 (18)
Ag1—Cu1iii3.3156 (18)Ag3—Cu22.912 (5)
Ag1—Ag23.129 (3)Ag3—S12.736 (6)
Ag1—Ag2ix3.129 (3)Ag3—S2iv2.622 (4)
Ag1—Ag53.243 (5)Ag3—S32.802 (7)
Ag1—Ag5ix3.243 (5)Ag3—S3xix2.707 (8)
Ag1—S13.064 (3)Ag4—Ag4xix2.995 (11)
Ag1—S2iv2.453 (2)Ag4—Ag4iv2.531 (16)
Ag1—S2x2.453 (3)Ag4—Ag4xx2.531 (16)
Ag1—S41.946 (5)Ag4—Ag51.672 (12)
Ag1—S4xi2.829 (8)Ag4—Ag5xix3.083 (8)
Ag1—S4vi2.428 (3)Ag4—Ag5iv3.259 (12)
Ag1—S4vii2.428 (3)Ag4—Ag5v1.672 (12)
Ag1—S4xii2.829 (7)Ag4—Ag5xv3.083 (8)
Ag1—S4xiii1.946 (7)Ag4—Ag5xvi3.346 (14)
Cu1—Cu1vi3.3131Ag4—Ag5ix3.346 (14)
Cu1—Cu1vii3.3156Ag4—Ag5xviii3.259 (12)
Cu1—Cu1viii3.3131Ag4—Ag61.370 (11)
Cu1—Cu1iii3.3156Ag4—Ag6xix3.435 (13)
Cu1—Ag23.129 (2)Ag4—Ag6iv2.027 (15)
Cu1—Ag2ix3.129 (3)Ag4—Ag6v1.370 (11)
Cu1—Ag53.243 (5)Ag4—Ag6xv3.435 (13)
Cu1—Ag5ix3.243 (5)Ag4—Ag6xx3.31 (2)
Cu1—S13.064 (2)Ag4—Ag6xxii3.31 (2)
Cu1—S2iv2.453 (2)Ag4—Ag6xviii2.027 (15)
Cu1—S2x2.453 (2)Ag4—S2iv2.417 (8)
Cu1—S41.946 (5)Ag4—S33.009 (10)
Cu1—S4xi2.829 (8)Ag4—S3xix2.158 (9)
Cu1—S4vi2.428 (3)Ag5—Ag5v2.569 (8)
Cu1—S4vii2.428 (3)Ag5—Ag5xv3.006 (7)
Cu1—S4xii2.829 (7)Ag5—Ag5ix1.729 (16)
Cu1—S4xiii1.946 (7)Ag5—Ag5xviii3.090 (14)
Ag2—Ag2xiv3.433 (7)Ag5—Ag61.237 (17)
Ag2—Ag2v3.088 (4)Ag5—Ag6xvii3.167 (10)
Ag2—Ag2xv3.427 (5)Ag5—Ag6v2.916 (15)
Ag2—Ag2xvi3.433 (4)Ag5—Ag6xv2.917 (7)
Ag2—Ag2ix0.609 (8)Ag5—Ag6ix2.845 (19)
Ag2—Ag31.199 (11)Ag5—Ag6xviii2.062 (18)
Ag2—Ag3xiv3.375 (13)Ag5—Cu22.840 (5)
Ag2—Ag3xvii3.115 (7)Ag5—S12.543 (5)
Ag2—Ag3v2.872 (5)Ag5—S2iv2.624 (6)
Ag2—Ag3xv2.890 (5)Ag5—S32.474 (6)
Ag2—Ag3ix1.800 (12)Ag5—S3xix3.304 (9)
Ag2—Ag3xviii3.105 (13)Ag6—Ag6iv3.245 (12)
Ag2—Ag42.200 (10)Ag6—Ag6v2.714 (11)
Ag2—Ag4xix3.208 (8)Ag6—Ag6xv3.319 (11)
Ag2—Ag4xiv2.792 (14)Ag6—Ag6xx3.24 (2)
Ag2—Ag4xvii3.440 (10)Ag6—Ag6xviii0.88 (2)
Ag2—Ag50.561 (12)Ag6—Cu22.867 (4)
Ag2—Ag5xiv3.297 (13)Ag6—S12.589 (4)
Ag2—Ag5xvii3.478 (8)Ag6—S23.254 (11)
Ag2—Ag5v2.872 (6)Ag6—S2iv2.735 (9)
Ag2—Ag5xv3.196 (6)Ag6—S33.476 (15)
Ag2—Ag5ix1.169 (13)Ag6—S3xix2.516 (6)
Ag2—Ag5xviii3.424 (13)Cu2—S12.161 (3)
Ag2—Ag61.742 (14)Cu2—S1xxiii2.161 (3)
Ag2—Ag6xvii2.993 (7)S4—S4xi1.273 (14)
Ag2—Ag6v3.378 (14)S4—S4vi1.102 (12)
Ag2—Ag6xv2.901 (5)S4—S4vii0.636 (7)
Ag2—Ag6xii3.022 (14)S4—S4xii1.102 (12)
Ag2—Ag6ix2.312 (16)S4—S4xiii0.636 (12)
Symmetry codes: (i) x+1, y+1, z+1; (ii) y, x+y+1, z+1; (iii) y, x, z+1; (iv) y+1, xy+1, z; (v) y+1, x+1, z; (vi) y, xy, z; (vii) y, x+y, z+1; (viii) y, x, z; (ix) x, xy, z; (x) y+1, x, z; (xi) x, y, z+1; (xii) x+y, x, z; (xiii) xy, x, z+1; (xiv) y+1, xy, z; (xv) y, x, z; (xvi) x+y+1, x+1, z; (xvii) y, x+y, z; (xviii) x+y, y, z; (xix) x+1, y+1, z; (xx) x+y, x+1, z; (xxi) xy, x, z; (xxii) x, xy+1, z; (xxiii) x, y, z.
 

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