Download citation
Download citation
link to html
The CuII ion of [Cu(C14H32N4)(ClO4)2], is six-coordinated in a distorted octahedral geometry with the four N atoms of the macrocyclic ligand equatorial and the two O atoms of the perchlorate ion axial. The quadridentate ligand adopts its most stable conformation with the two six-membered rings in chair forms and the two five-membered rings in gauche forms. The complex has a 1RS,4RS,8SR,11SR configuration for the four chiral N-atom centres and a 5SR,7RS,12RS,14SR configuration for the two chiral C-atom centres.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, structure

fcf

Structure factor file (CIF format)
Supplementary material

CCDC reference: 126583

-1
Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds