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The title compounds, poly[bis(benzimidazole-N3)copper(II)-μ-acetylenedicarboxylato-O:O′-μ-aqua], [Cu(C4O4)(C7H6N2)2(H2O)], (I), and poly[bis(benzimidazole-N3)copper(II)-μ-aqua-μ-fumarato-O:O′], [Cu(C4H2O4)(C7H6N2)2(H2O)], (II), have been synthesized, and their crystal structures determined by single-crystal X-ray diffraction at room temperature. Structures (I) and (II) are very similar. In both structures, the centrosymmetric Cu atoms are bridged by the dicarboxylic acid ions in a bis-monodentate fashion, forming polymeric chains. The Cu...Cu intrachain distances are 9.546 (1) Å in (I), and 9.276 (1) Å in (II). These chains are connected by bridging H2O molecules, which are located on the twofold axes by Cu–H2O bonds of 2.593 (1) Å in (I), and 2.668 (1) Å in (II). The Cu...Cu distances in the –Cu–H2O–Cu– chains are 5.090 (1) and 5.199 (1) Å, in (I) and (II), respectively. The base of the elongated octahedron of the CuII atoms is formed by two short Cu–O and two short Cu–N bonds [Cu–O = 1.970 (1) and 1.946 (2) Å, Cu–N = 2.005 (2) and 2.016 (2) Å, in (I) and (II), respectively]. The modes of coordination of the carboxylate groups, and of the hydrogen bonds, are discussed. The isostructurality of the title compounds and of their previously investigated homologue, (III), has been analysed.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, I, II

CCDC references: 130493; 130494

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