metal-organic compounds
The central Sn atom in the title complex, [Sn(C4H9)2(C14H9N2S)2], is located on a twofold axis. The coordination polyhedron about the Sn atom is a skew-trapezoidal bipyramid. The trapezoidal plane is formed by the two 2-phenylquinazoline-4-thiolate resdues, which act as bidentate ligands with cis-Sn-S and cis-Sn-N bonds. The axial C atoms are shifted towards the half-sphere occupied by two N atoms, resulting in a C-Sn-C angle of 131.1 (2)°. Each phenyl substituent is twisted with respect to the mean plane of the quinazoline system.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 130745