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(N2H5)3[GaF6] contains GaF63− octahedra arranged in a distorted cubic close-packed manner and linked to hydrazinium(1+) ions via N—H...F hydrogen bonds. (N2H6)[GaF5(H2O)] contains [GaF5(H2O)]2− octahedra arranged in a similar distorted cubic close packing manner; in addition to N—H...F hydrogen bonds to hydrazinium(2+) ions, these octahedra are also linked directly via O—H...F hydrogen bonds.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, II, global

hkl

Structure factor file (CIF format)
Contains datablock I

hkl

Structure factor file (CIF format)
Contains datablock (II)

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