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The title compounds, C6H14NO2+.Br and C8H18NO2+.Br, each crystallize forming three-dimensional networks of Br...N+ contacts and Br...H—O hydrogen bonds. n-Butyl(carboxymethyl)dimethylammonium bromide has two molecules in the asymmetric unit. The orientation of the alkyl chain relative to the polar part of the molecule is different in the two compounds.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, beh2n, ruvo4

hkl

Structure factor file (CIF format)
Contains datablock beh2n

hkl

Structure factor file (CIF format)
Contains datablock ruvo4

CCDC references: 126441; 126442

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