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The molecule [Au2(μ-C3S5){P(p-C6H4OCH3)3}2] consists of two AuPR3 fragments bridged by one dmit group. Although the Au—S [2.327 (2) and 2.331 (2) Å] and Au—P [2.264 (2) and 2.265 (2) Å] bond lengths are similar to those observed in related dithiolate complexes, the intramolecular Au...S [3.013 (2) Å] and Au...Au [3.2217 (8) Å] contacts are longer.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks lola5, global

fcf

Structure factor file (CIF format)
Contains datablock lola5

CCDC reference: 129541

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