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In the binuclear title complex, [W2O(C5H5)2(C5H6)(CO)2], the W centres are bridged by a 1,4-pentadien-1,4-diyl ligand. The W—W distance of 2.9426 (5) Å is in accord with a W—W single bond, the W—O distance of 1.678 (5) Å corresponds to a W=O double bond.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock C~17~H~16~W~2~O~3~

hkl

Structure factor file (CIF format)
Contains datablock I

CCDC reference: 128973

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