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The solvent-free title compound, [Rh2(C2H5O)2(C8H12)2], was obtained by reaction of [(cod)Rh(OH)]2 (cod is cyclooctadiene) with Ti(OC2H5)4. The coordination of the Rh atoms is essentially square planar. The Rh and O atoms form a folded four-membered ring.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock global

fcf

Structure factor file (CIF format)
Contains datablock sel

CCDC reference: 128131

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