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The C2 symmetric bisphosphine rac-Fe(C5H4PMePh)2 (rac-mppf) forms a PdII complex [(rac-mppf)Pd(acac)]BF4. The coordination geometry of the Pd centre is square planar while the ring-ring conformation of the rac-mppf ligand is intermediate between synperiplanar and synclinal eclipsed with a torsion angle of 16.4°.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, 2

hkl

Structure factor file (CIF format)
Contains datablock 2

CCDC reference: 126725

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