(Na,Li)₃(Cl,OH)[Cu₃OAl(PO₄)₃]: a first salt-inclusion aluminophosphate oxocuprate with a new type of crystal structure

The synthesis and characterization of a first salt-inclusion aluminophosphate oxocuprate, (Na,Li)₃(Cl,OH)[Cu₃OAl(PO₄)₃], obtained as single crystals, is reported. A novel phase, with a strongly pseudo-orthorhombic structure, is described as a monoclinic crystal structure established by the study of a pseudomerohedric microtwin. It was investigated using scanning electron microscopy, microprobe analysis and low-temperature X-ray diffraction. The composite crystal structure represents an original framework assembled from Cu-centered polyhedra, AlO₆ octahedra and PO₄ tetrahedra with channels, which incorporate the Na/Li salt component [(Na,Li)₃(Cl,OH)]²⁺ that ensures electroneutrality of the compound. Layers of strongly corrugated chains of Cu-centered octahedra with shared edges and linked by PO₄ tetrahedra are shown to be topologically identical with the layers also built from Cu-centered polyhedra and AsO₄/VO₄ tetrahedra forming the crystal structure of a fumarolic mineral aleutite, (M_0.5Cl)[Cu₅O₂(AsO₄)(VO₄)] [Siidra et al. (2019). MinMag, 83, 847–853]. `Sawtooth chains' and pairs of Cu-centered octahedra inherent in the title structure may be of interest in solid-state physics, engaging studies in the field of low-dimensional and frustrated magnetism.

Computing details

Data collection: CrysAlis PRO 1.171.40.67a (Rigaku OD, 2019); cell refinement: CrysAlis PRO 1.171.40.67a (Rigaku OD, 2019); data reduction: CrysAlis PRO 1.171.40.67a (Rigaku OD, 2019); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2018/3 (Sheldrick, 2015b); molecular graphics: Diamond (Brandenburg, 2006).

sodium alumonophosphate oxocuprate chloride

Crystal data

Al8Cl7Cu24Li4.19Na19.81O105P24	F(000) = 2349
Mr = 4896.74	Dx = 3.601 Mg m^−3
Monoclinic, C2/m	Mo Kα radiation, λ = 0.71073 Å
a = 13.3428 (4) Å	Cell parameters from 6699 reflections
b = 18.9320 (5) Å	θ = 1.9–37.2°
c = 8.9404 (2) Å	µ = 6.49 mm^−1
β = 90.361 (2)°	T = 150 K
V = 2258.35 (10) Å^3	Prism, light-green
Z = 1	0.10 × 0.05 × 0.04 mm

Data collection

Xcalibur, AtlasS2, Gemini diffractometer	2646 independent reflections
Radiation source: fine-focus sealed X-ray tube	2542 reflections with I > 2σ(I)
Detector resolution: 5.2283 pixels mm^-1	Rint = 0.021
ω scans	θmax = 27.5°, θmin = 1.9°
Absorption correction: multi-scan CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.	h = −17→17
Tmin = 0.778, Tmax = 1.295	k = −24→22
7934 measured reflections	l = −11→11

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Primary atom site location: Direct
R[F^2 > 2σ(F^2)] = 0.039	Secondary atom site location: Diffmap
wR(F^2) = 0.110	w = 1/[σ^2(Fo^2) + (0.050P)^2 + 30.P] where P = (Fo^2 + 2Fc^2)/3
S = 1.17	(Δ/σ)max < 0.001
2646 reflections	Δρmax = 1.70 e Å^−3
247 parameters	Δρmin = −1.74 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refined as a 2-component twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cu1	0.250000	0.250000	0.500000	0.0109 (2)
Cu2	0.12705 (5)	0.41671 (3)	0.31049 (7)	0.01122 (16)
Cu3	0.000000	0.24835 (5)	0.500000	0.0138 (2)
Cu4	0.62554 (8)	0.74519 (3)	0.82896 (7)	0.02009 (19)
P1	0.12573 (12)	0.26303 (7)	0.19526 (14)	0.0112 (3)
P2	0.11905 (10)	0.61919 (6)	0.66727 (13)	0.0068 (2)
P3	0.63242 (10)	0.61716 (7)	0.65454 (13)	0.0080 (3)
Al1	0.24664 (16)	0.500000	0.5261 (2)	0.0073 (4)
Al2	0.000000	0.500000	0.500000	0.0060 (6)
Al3	0.500000	0.500000	0.500000	0.0086 (6)
Na1	0.000000	0.60798 (18)	1.000000	0.0116 (6)
Na2	0.74974 (18)	0.61404 (16)	1.0123 (3)	0.0231 (6)
Na3	0.6188 (3)	0.6185 (2)	0.3120 (4)	0.0129 (12)	0.556 (10)
Li1	0.6222 (17)	0.5757 (14)	0.300 (2)	0.0129 (12)	0.444 (10)
Na4	0.504 (2)	0.6190 (6)	1.0348 (16)	0.064 (6)	0.420 (15)
Li2	0.504 (2)	0.6190 (6)	1.0348 (16)	0.064 (6)	0.080 (15)
Cl2	0.6191 (3)	0.5102 (4)	1.0679 (3)	0.0147 (17)	0.375 (4)
O15	0.5411 (17)	0.500000	0.847 (2)	0.0147 (17)	0.251 (8)
Cl1	0.13134 (16)	0.500000	0.06802 (19)	0.0146 (4)
O1	0.3752 (4)	0.500000	0.5926 (5)	0.0088 (9)
O2	0.1252 (4)	0.500000	0.4326 (5)	0.0064 (9)
O3	0.2119 (3)	0.5716 (2)	0.6616 (4)	0.0113 (7)
O4	0.7272 (3)	0.5722 (2)	0.6287 (4)	0.0114 (8)
O5	0.0234 (3)	0.5724 (2)	0.6514 (4)	0.0082 (7)
O6	0.1167 (3)	0.65488 (18)	0.8223 (4)	0.0084 (7)
O7	0.6308 (3)	0.6793 (2)	0.5442 (4)	0.0182 (8)
O8	0.1191 (3)	0.6728 (2)	0.5402 (4)	0.0156 (8)
O9	0.5405 (3)	0.5711 (2)	0.6362 (4)	0.0136 (8)
O10	0.6358 (3)	0.64578 (18)	0.8147 (4)	0.0097 (7)
O11	0.2212 (3)	0.2434 (2)	0.2855 (5)	0.0147 (8)
O12	0.0305 (3)	0.2412 (2)	0.2816 (5)	0.0185 (9)
O13	0.1248 (3)	0.34339 (19)	0.1676 (4)	0.0102 (7)
O14	0.1273 (5)	0.2248 (2)	0.0484 (5)	0.0360 (12)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0121 (4)	0.0120 (5)	0.0086 (4)	0.0010 (3)	0.0023 (4)	0.0019 (3)
Cu2	0.0106 (3)	0.0121 (3)	0.0110 (3)	0.0003 (3)	0.0013 (3)	−0.0057 (2)
Cu3	0.0156 (5)	0.0147 (5)	0.0112 (5)	0.000	0.0003 (4)	0.000
Cu4	0.0481 (5)	0.0052 (3)	0.0070 (3)	0.0034 (3)	−0.0003 (4)	−0.0006 (2)
P1	0.0160 (6)	0.0103 (6)	0.0074 (5)	0.0013 (6)	0.0002 (6)	−0.0006 (4)
P2	0.0113 (6)	0.0047 (5)	0.0045 (5)	−0.0009 (5)	0.0009 (5)	−0.0002 (4)
P3	0.0115 (6)	0.0066 (6)	0.0059 (5)	0.0000 (5)	0.0018 (5)	−0.0015 (4)
Al1	0.0077 (10)	0.0077 (10)	0.0065 (9)	0.000	0.0008 (8)	0.000
Al2	0.0066 (13)	0.0063 (14)	0.0052 (13)	0.000	0.0009 (11)	0.000
Al3	0.0084 (14)	0.0098 (15)	0.0076 (14)	0.000	0.0022 (11)	0.000
Na1	0.0112 (14)	0.0132 (15)	0.0103 (13)	0.000	0.0001 (12)	0.000
Na2	0.0157 (11)	0.0266 (15)	0.0272 (14)	0.0006 (10)	−0.0028 (11)	−0.0016 (10)
Na3	0.0114 (18)	0.015 (2)	0.0124 (18)	0.0011 (17)	0.0048 (15)	0.0052 (16)
Li1	0.0114 (18)	0.015 (2)	0.0124 (18)	0.0011 (17)	0.0048 (15)	0.0052 (16)
Na4	0.017 (5)	0.083 (7)	0.091 (16)	0.001 (6)	0.016 (11)	−0.020 (6)
Li2	0.017 (5)	0.083 (7)	0.091 (16)	0.001 (6)	0.016 (11)	−0.020 (6)
Cl2	0.0218 (14)	0.013 (5)	0.0090 (12)	−0.0010 (16)	0.0038 (11)	0.0041 (14)
O15	0.0218 (14)	0.013 (5)	0.0090 (12)	−0.0010 (16)	0.0038 (11)	0.0041 (14)
Cl1	0.0225 (9)	0.0115 (8)	0.0097 (7)	0.000	−0.0004 (7)	0.000
O1	0.006 (2)	0.010 (2)	0.010 (2)	0.000	0.002 (2)	0.000
O2	0.009 (2)	0.006 (2)	0.004 (2)	0.000	0.0016 (19)	0.000
O3	0.0118 (17)	0.0094 (17)	0.0128 (18)	0.0004 (14)	0.0025 (14)	−0.0048 (14)
O4	0.0100 (17)	0.0101 (18)	0.0142 (18)	−0.0006 (14)	0.0044 (14)	−0.0057 (15)
O5	0.0088 (16)	0.0082 (17)	0.0075 (16)	0.0002 (13)	−0.0011 (13)	−0.0022 (14)
O6	0.0144 (17)	0.0060 (15)	0.0049 (15)	−0.0012 (14)	0.0005 (14)	−0.0011 (12)
O7	0.030 (2)	0.0143 (19)	0.0106 (17)	−0.0005 (19)	0.0032 (17)	0.0049 (15)
O8	0.027 (2)	0.0121 (18)	0.0078 (16)	−0.0058 (18)	−0.0004 (16)	0.0027 (14)
O9	0.0109 (17)	0.0149 (19)	0.0150 (18)	−0.0023 (15)	0.0031 (14)	−0.0072 (16)
O10	0.0159 (17)	0.0076 (16)	0.0057 (15)	0.0004 (15)	0.0018 (14)	−0.0020 (13)
O11	0.0158 (19)	0.016 (2)	0.0121 (19)	0.0069 (15)	0.0037 (15)	0.0042 (15)
O12	0.019 (2)	0.018 (2)	0.018 (2)	−0.0061 (17)	−0.0025 (17)	0.0075 (16)
O13	0.0126 (16)	0.0106 (17)	0.0074 (15)	0.0000 (15)	0.0018 (15)	−0.0026 (13)
O14	0.081 (4)	0.015 (2)	0.0115 (19)	0.009 (3)	−0.003 (3)	−0.0032 (16)

Geometric parameters (Å, º)

Cu1—O11^i	1.957 (4)	Al2—O2	1.780 (5)
Cu1—O11	1.958 (4)	Al2—O2^vi	1.780 (5)
Cu1—O7^ii	2.118 (4)	Al2—O5	1.950 (4)
Cu1—O7^iii	2.118 (4)	Al2—O5^vi	1.950 (4)
Cu1—O8^iv	2.308 (4)	Al2—O5^iv	1.950 (4)
Cu1—O8^v	2.308 (4)	Al2—O5^vii	1.950 (4)
Cu1—Na3^iii	3.471 (4)	Al3—O1^ii	1.864 (5)
Cu1—Na3^ii	3.471 (4)	Al3—O1	1.864 (5)
Cu2—O13	1.886 (3)	Al3—O9^ii	1.891 (4)
Cu2—O2	1.918 (3)	Al3—O9^iv	1.891 (4)
Cu2—O4^ii	2.027 (4)	Al3—O9^xiv	1.891 (4)
Cu2—O5^vi	2.048 (4)	Al3—O9	1.891 (4)
Cu2—Cl1	2.6815 (15)	Al3—Li1^iv	2.82 (2)
Cu2—Al2	2.8752 (6)	Al3—Li1^xiv	2.82 (2)
Cu2—Al1	2.951 (2)	Al3—Li1^ii	2.82 (2)
Cu2—Na1^vi	3.2770 (8)	Al3—Li1	2.82 (2)
Cu2—Na2^ii	3.381 (3)	Al3—Na3	3.226 (4)
Cu3—O12^vii	2.002 (5)	Al3—Na3^xiv	3.226 (4)
Cu3—O12	2.002 (5)	Na1—O6	2.402 (4)
Cu3—O8^iv	2.208 (4)	Na1—O6^xv	2.402 (4)
Cu3—O8^vi	2.208 (4)	Na1—O13^xvi	2.416 (4)
Cu3—O7^v	2.214 (5)	Na1—O13^vi	2.416 (4)
Cu3—O7^iii	2.214 (4)	Na1—Cl1^vi	2.758 (3)
Cu3—Na3^iii	3.379 (4)	Na1—Cl1^xvii	2.758 (3)
Cu3—Na3^v	3.379 (4)	Na1—Na2^xi	3.344 (2)
Cu4—O10	1.891 (4)	Na1—Na2^xviii	3.344 (2)
Cu4—O6^viii	1.896 (3)	Na2—O10	2.400 (4)
Cu4—O14^ix	1.999 (4)	Na2—O6^xi	2.434 (4)
Cu4—O12^x	2.301 (4)	Na2—O13^ii	2.464 (4)
Cu4—O11^ii	2.302 (4)	Na2—Cl2	2.676 (7)
Cu4—Na4^xi	3.198 (18)	Na2—O14^ix	2.678 (6)
Cu4—Na2	3.401 (3)	Na2—Cl1^ii	2.777 (3)
Cu4—Na4	3.427 (18)	Na2—Cl2^iv	2.972 (7)
Cu4—Na2^xii	3.443 (3)	Na2—Li1^xvii	3.18 (2)
Cu4—Na1^xiii	3.592 (3)	Na2—Na3^xvii	3.208 (5)
P1—O14	1.500 (4)	Na2—Na4	3.28 (3)
P1—O13	1.541 (4)	Na3—Li1	0.82 (3)
P1—O12	1.546 (4)	Na3—O9^xiv	2.357 (6)
P1—O11	1.549 (4)	Na3—O7	2.378 (6)
P1—Na3^iii	2.930 (4)	Na3—O1^ii	2.402 (4)
P1—Na2^ii	3.415 (3)	Na3—O3^xiv	2.437 (6)
P1—Na1^vi	3.433 (3)	Na3—O12^xix	2.618 (6)
P2—O8	1.524 (4)	Na3—O11^xix	2.741 (6)
P2—O3	1.533 (4)	Na3—Na4^xx	2.902 (18)
P2—O6	1.542 (3)	Na3—Cl2^xx	2.994 (7)
P2—O5	1.559 (4)	Li1—O1^ii	1.72 (2)
P2—Na2^xi	3.349 (3)	Li1—O3^xiv	2.24 (2)
P2—Na1	3.3877 (12)	Li1—O9^xiv	2.25 (2)
P3—O9	1.513 (4)	Li1—Cl2^xx	2.42 (2)
P3—O10	1.531 (4)	Li1—Cl2^xxi	2.64 (2)
P3—O7	1.535 (4)	Li1—Li1^iv	2.87 (5)
P3—O4	1.543 (4)	Li1—Na4^xx	2.95 (3)
P3—Na3	3.067 (4)	Li1—Na4^xiv	3.53 (3)
P3—Na4^xi	3.33 (2)	Na4—Na4^xi	0.63 (3)
P3—Na3^xiv	3.368 (4)	Na4—O10^xi	2.37 (2)
Al1—O1	1.812 (6)	Na4—O15^xxii	2.561 (17)
Al1—O2	1.818 (6)	Na4—Cl2	2.581 (18)
Al1—O3^iv	1.878 (4)	Na4—O14^ix	2.59 (2)
Al1—O3	1.878 (4)	Na4—O10	2.69 (2)
Al1—O4^ii	1.978 (4)	Na4—O14^x	2.764 (19)
Al1—O4^xiv	1.978 (4)	Na4—Cl2^xi	2.788 (19)
Al1—Li1^xiv	2.74 (2)	Na4—O15	2.851 (18)
Al1—Li1^ii	2.74 (2)	Na4—Cl2^iv	2.899 (17)
Al1—Na3^xiv	3.213 (4)	Cl2—Cl2^iv	0.387 (16)
Al1—Na3^ii	3.213 (4)
O11^i—Cu1—O11	180.0	O13^vi—Na1—P2	75.91 (9)
O11^i—Cu1—O7^ii	89.97 (16)	Cl1^vi—Na1—P2	98.83 (6)
O11—Cu1—O7^ii	90.03 (16)	Cl1^xvii—Na1—P2	86.52 (6)
O11^i—Cu1—O7^iii	90.03 (16)	Cu2^vi—Na1—P2	60.53 (2)
O11—Cu1—O7^iii	89.97 (16)	Cu2^xvi—Na1—P2	120.65 (3)
O7^ii—Cu1—O7^iii	180.00 (17)	Na2^xi—Na1—P2	59.67 (5)
O11^i—Cu1—O8^iv	87.20 (14)	Na2^xviii—Na1—P2	120.05 (5)
O11—Cu1—O8^iv	92.80 (14)	P2^xv—Na1—P2	172.82 (12)
O7^ii—Cu1—O8^iv	101.48 (16)	O10—Na2—O6^xi	145.63 (18)
O7^iii—Cu1—O8^iv	78.52 (16)	O10—Na2—O13^ii	82.37 (15)
O11^i—Cu1—O8^v	92.80 (14)	O6^xi—Na2—O13^ii	78.17 (13)
O11—Cu1—O8^v	87.20 (14)	O10—Na2—Cl2	84.84 (14)
O7^ii—Cu1—O8^v	78.52 (16)	O6^xi—Na2—Cl2	126.58 (15)
O7^iii—Cu1—O8^v	101.48 (16)	O13^ii—Na2—Cl2	143.84 (17)
O8^iv—Cu1—O8^v	180.0	O10—Na2—O14^ix	60.57 (15)
O11^i—Cu1—Na3^iii	127.99 (14)	O6^xi—Na2—O14^ix	97.06 (18)
O11—Cu1—Na3^iii	52.01 (14)	O13^ii—Na2—O14^ix	103.87 (18)
O7^ii—Cu1—Na3^iii	137.72 (12)	Cl2—Na2—O14^ix	98.9 (2)
O7^iii—Cu1—Na3^iii	42.28 (12)	O10—Na2—Cl1^ii	111.38 (13)
O8^iv—Cu1—Na3^iii	98.60 (12)	O6^xi—Na2—Cl1^ii	89.25 (12)
O8^v—Cu1—Na3^iii	81.40 (12)	O13^ii—Na2—Cl1^ii	72.17 (11)
O11^i—Cu1—Na3^ii	52.01 (14)	Cl2—Na2—Cl1^ii	81.43 (16)
O11—Cu1—Na3^ii	127.99 (14)	O14^ix—Na2—Cl1^ii	171.77 (15)
O7^ii—Cu1—Na3^ii	42.28 (12)	O10—Na2—Cl2^iv	87.23 (14)
O7^iii—Cu1—Na3^ii	137.72 (12)	O6^xi—Na2—Cl2^iv	125.31 (15)
O8^iv—Cu1—Na3^ii	81.40 (12)	O13^ii—Na2—Cl2^iv	140.31 (16)
O8^v—Cu1—Na3^ii	98.60 (12)	Cl2—Na2—Cl2^iv	5.1 (2)
Na3^iii—Cu1—Na3^ii	180.00 (9)	O14^ix—Na2—Cl2^iv	103.93 (19)
O13—Cu2—O2	171.92 (16)	Cl1^ii—Na2—Cl2^iv	76.38 (14)
O13—Cu2—O4^ii	105.60 (16)	O10—Na2—Li1^xvii	108.3 (4)
O2—Cu2—O4^ii	77.17 (19)	O6^xi—Na2—Li1^xvii	88.5 (4)
O13—Cu2—O5^vi	100.09 (15)	O13^ii—Na2—Li1^xvii	166.6 (5)
O2—Cu2—O5^vi	78.85 (19)	Cl2—Na2—Li1^xvii	47.9 (5)
O4^ii—Cu2—O5^vi	152.18 (14)	O14^ix—Na2—Li1^xvii	75.6 (5)
O13—Cu2—Cl1	83.43 (11)	Cl1^ii—Na2—Li1^xvii	110.0 (5)
O2—Cu2—Cl1	88.69 (11)	Cl2^iv—Na2—Li1^xvii	50.7 (5)
O4^ii—Cu2—Cl1	97.51 (12)	O10—Na2—Na3^xvii	105.21 (14)
O5^vi—Cu2—Cl1	95.82 (11)	O6^xi—Na2—Na3^xvii	83.38 (13)
O13—Cu2—Al2	142.71 (12)	O13^ii—Na2—Na3^xvii	155.79 (16)
O2—Cu2—Al2	37.26 (16)	Cl2—Na2—Na3^xvii	60.37 (13)
O4^ii—Cu2—Al2	110.70 (11)	O14^ix—Na2—Na3^xvii	62.82 (14)
O5^vi—Cu2—Al2	42.68 (10)	Cl1^ii—Na2—Na3^xvii	123.48 (12)
Cl1—Cu2—Al2	99.76 (4)	Cl2^iv—Na2—Na3^xvii	63.79 (12)
O13—Cu2—Al1	147.31 (12)	Li1^xvii—Na2—Na3^xvii	14.7 (5)
O2—Cu2—Al1	36.66 (16)	O10—Na2—Na4	53.9 (3)
O4^ii—Cu2—Al1	41.89 (11)	O6^xi—Na2—Na4	132.9 (3)
O5^vi—Cu2—Al1	111.35 (11)	O13^ii—Na2—Na4	135.4 (3)
Cl1—Cu2—Al1	101.51 (5)	Cl2—Na2—Na4	50.1 (2)
Al2—Cu2—Al1	68.93 (4)	O14^ix—Na2—Na4	50.3 (2)
O13—Cu2—Na1^vi	46.81 (12)	Cl1^ii—Na2—Na4	127.6 (2)
O2—Cu2—Na1^vi	126.23 (15)	Cl2^iv—Na2—Na4	55.0 (2)
O4^ii—Cu2—Na1^vi	137.09 (11)	Li1^xvii—Na2—Na4	54.4 (5)
O5^vi—Cu2—Na1^vi	69.70 (10)	Na3^xvii—Na2—Na4	53.1 (3)
Cl1—Cu2—Na1^vi	54.03 (6)	O10—Na2—Na1^xxiii	127.76 (13)
Al2—Cu2—Na1^vi	105.88 (4)	O6^xi—Na2—Na1^xxiii	45.86 (10)
Al1—Cu2—Na1^vi	154.72 (6)	O13^ii—Na2—Na1^xxiii	46.14 (10)
O13—Cu2—Na2^ii	45.66 (12)	Cl2—Na2—Na1^xxiii	129.27 (17)
O2—Cu2—Na2^ii	129.45 (14)	O14^ix—Na2—Na1^xxiii	129.84 (18)
O4^ii—Cu2—Na2^ii	77.06 (11)	Cl1^ii—Na2—Na1^xxiii	52.58 (8)
O5^vi—Cu2—Na2^ii	129.91 (11)	Cl2^iv—Na2—Na1^xxiii	124.43 (16)
Cl1—Cu2—Na2^ii	53.00 (6)	Li1^xvii—Na2—Na1^xxiii	124.0 (4)
Al2—Cu2—Na2^ii	152.76 (5)	Na3^xvii—Na2—Na1^xxiii	125.28 (11)
Al1—Cu2—Na2^ii	112.69 (6)	Na4—Na2—Na1^xxiii	178.3 (3)
Na1^vi—Cu2—Na2^ii	60.27 (4)	Li1—Na3—O9^xiv	72.4 (16)
O12^vii—Cu3—O12	172.3 (3)	Li1—Na3—O7	126.0 (16)
O12^vii—Cu3—O8^iv	92.15 (16)	O9^xiv—Na3—O7	93.9 (2)
O12—Cu3—O8^iv	93.07 (15)	Li1—Na3—O1^ii	28.2 (15)
O12^vii—Cu3—O8^vi	93.07 (15)	O9^xiv—Na3—O1^ii	66.54 (19)
O12—Cu3—O8^vi	92.15 (16)	O7—Na3—O1^ii	98.0 (2)
O8^iv—Cu3—O8^vi	94.9 (2)	Li1—Na3—O3^xiv	66.4 (17)
O12^vii—Cu3—O7^v	88.25 (16)	O9^xiv—Na3—O3^xiv	132.7 (2)
O12—Cu3—O7^v	87.19 (16)	O7—Na3—O3^xiv	92.0 (2)
O8^iv—Cu3—O7^v	173.64 (16)	O1^ii—Na3—O3^xiv	66.20 (19)
O8^vi—Cu3—O7^v	78.74 (16)	Li1—Na3—O12^xix	152.9 (17)
O12^vii—Cu3—O7^iii	87.19 (16)	O9^xiv—Na3—O12^xix	87.29 (19)
O12—Cu3—O7^iii	88.24 (16)	O7—Na3—O12^xix	71.88 (18)
O8^iv—Cu3—O7^iii	78.74 (16)	O1^ii—Na3—O12^xix	151.6 (2)
O8^vi—Cu3—O7^iii	173.64 (16)	O3^xiv—Na3—O12^xix	138.6 (2)
O7^v—Cu3—O7^iii	107.6 (2)	Li1—Na3—O11^xix	144.6 (16)
O12^vii—Cu3—Na3^iii	122.37 (14)	O9^xiv—Na3—O11^xix	142.8 (2)
O12—Cu3—Na3^iii	50.70 (14)	O7—Na3—O11^xix	68.13 (17)
O8^iv—Cu3—Na3^iii	103.50 (12)	O1^ii—Na3—O11^xix	145.2 (2)
O8^vi—Cu3—Na3^iii	138.63 (12)	O3^xiv—Na3—O11^xix	81.99 (17)
O7^v—Cu3—Na3^iii	81.57 (13)	O12^xix—Na3—O11^xix	56.63 (14)
O7^iii—Cu3—Na3^iii	44.56 (12)	Li1—Na3—Na4^xx	85.5 (17)
O12^vii—Cu3—Na3^v	50.70 (14)	O9^xiv—Na3—Na4^xx	72.5 (5)
O12—Cu3—Na3^v	122.37 (14)	O7—Na3—Na4^xx	140.9 (4)
O8^iv—Cu3—Na3^v	138.63 (12)	O1^ii—Na3—Na4^xx	108.8 (3)
O8^vi—Cu3—Na3^v	103.50 (12)	O3^xiv—Na3—Na4^xx	124.5 (5)
O7^v—Cu3—Na3^v	44.56 (12)	O12^xix—Na3—Na4^xx	71.0 (3)
O7^iii—Cu3—Na3^v	81.57 (13)	O11^xix—Na3—Na4^xx	100.6 (4)
Na3^iii—Cu3—Na3^v	86.65 (13)	Li1—Na3—P1^xix	151.3 (15)
O10—Cu4—O6^viii	174.30 (14)	O9^xiv—Na3—P1^xix	117.15 (18)
O10—Cu4—O14^ix	82.72 (17)	O7—Na3—P1^xix	81.78 (15)
O6^viii—Cu4—O14^ix	102.96 (17)	O1^ii—Na3—P1^xix	176.3 (2)
O10—Cu4—O12^x	90.24 (16)	O3^xiv—Na3—P1^xix	110.11 (17)
O6^viii—Cu4—O12^x	87.89 (16)	O12^xix—Na3—P1^xix	31.74 (11)
O14^ix—Cu4—O12^x	114.9 (2)	O11^xix—Na3—P1^xix	31.48 (10)
O10—Cu4—O11^ii	89.92 (15)	Na4^xx—Na3—P1^xix	73.2 (3)
O6^viii—Cu4—O11^ii	86.99 (15)	Li1—Na3—Cl2^xx	39.5 (15)
O14^ix—Cu4—O11^ii	116.7 (2)	O9^xiv—Na3—Cl2^xx	83.54 (18)
O12^x—Cu4—O11^ii	128.04 (14)	O7—Na3—Cl2^xx	165.3 (2)
O10—Cu4—Na4^xi	47.3 (4)	O1^ii—Na3—Cl2^xx	67.62 (19)
O6^viii—Cu4—Na4^xi	136.4 (4)	O3^xiv—Na3—Cl2^xx	79.38 (16)
O14^ix—Cu4—Na4^xi	59.0 (3)	O12^xix—Na3—Cl2^xx	122.3 (2)
O12^x—Cu4—Na4^xi	69.4 (4)	O11^xix—Na3—Cl2^xx	121.65 (19)
O11^ii—Cu4—Na4^xi	136.4 (4)	Na4^xx—Na3—Cl2^xx	51.9 (3)
O10—Cu4—Na2	43.18 (12)	P1^xix—Na3—Cl2^xx	112.31 (17)
O6^viii—Cu4—Na2	140.67 (13)	Li1—Na3—P3	96.7 (15)
O14^ix—Cu4—Na2	51.90 (16)	O9^xiv—Na3—P3	81.27 (15)
O12^x—Cu4—Na2	128.34 (13)	O7—Na3—P3	29.43 (11)
O11^ii—Cu4—Na2	81.45 (11)	O1^ii—Na3—P3	68.63 (15)
Na4^xi—Cu4—Na2	62.3 (4)	O3^xiv—Na3—P3	81.44 (15)
O10—Cu4—Na4	51.5 (3)	O12^xix—Na3—P3	97.75 (16)
O6^viii—Cu4—Na4	133.1 (3)	O11^xix—Na3—P3	93.85 (15)
O14^ix—Cu4—Na4	48.8 (3)	Na4^xx—Na3—P3	151.7 (5)
O12^x—Cu4—Na4	77.2 (4)	P1^xix—Na3—P3	111.20 (14)
O11^ii—Cu4—Na4	136.7 (4)	Cl2^xx—Na3—P3	136.19 (19)
Na4^xi—Cu4—Na4	10.2 (5)	Li1—Na3—Na2^xx	80.6 (15)
Na2—Cu4—Na4	57.5 (4)	O9^xiv—Na3—Na2^xx	130.6 (2)
O10—Cu4—Na2^xii	139.73 (13)	O7—Na3—Na2^xx	135.06 (19)
O6^viii—Cu4—Na2^xii	43.15 (12)	O1^ii—Na3—Na2^xx	104.78 (18)
O14^ix—Cu4—Na2^xii	75.09 (17)	O3^xiv—Na3—Na2^xx	64.03 (13)
O12^x—Cu4—Na2^xii	129.50 (12)	O12^xix—Na3—Na2^xx	100.59 (16)
O11^ii—Cu4—Na2^xii	71.47 (12)	O11^xix—Na3—Na2^xx	71.13 (13)
Na4^xi—Cu4—Na2^xii	133.1 (3)	Na4^xx—Na3—Na2^xx	64.7 (5)
Na2—Cu4—Na2^xii	97.69 (7)	P1^xix—Na3—Na2^xx	73.07 (10)
Na4—Cu4—Na2^xii	123.1 (2)	Cl2^xx—Na3—Na2^xx	50.97 (13)
O10—Cu4—Na1^xiii	146.39 (12)	P3—Na3—Na2^xx	143.56 (15)
O6^viii—Cu4—Na1^xiii	38.04 (11)	Na3—Li1—O1^ii	139 (2)
O14^ix—Cu4—Na1^xiii	74.62 (15)	Na3—Li1—O3^xiv	94.0 (18)
O12^x—Cu4—Na1^xiii	77.57 (11)	O1^ii—Li1—O3^xiv	82.5 (9)
O11^ii—Cu4—Na1^xiii	122.30 (11)	Na3—Li1—O9^xiv	87.3 (17)
Na4^xi—Cu4—Na1^xiii	99.2 (4)	O1^ii—Li1—O9^xiv	81.0 (9)
Na2—Cu4—Na1^xiii	125.94 (5)	O3^xiv—Li1—O9^xiv	156.2 (11)
Na4—Cu4—Na1^xiii	95.1 (3)	Na3—Li1—Cl2^xx	128.1 (19)
Na2^xii—Cu4—Na1^xiii	56.71 (5)	O1^ii—Li1—Cl2^xx	92.9 (11)
O14—P1—O13	109.7 (2)	O3^xiv—Li1—Cl2^xx	97.2 (8)
O14—P1—O12	108.9 (3)	O9^xiv—Li1—Cl2^xx	100.7 (9)
O13—P1—O12	109.7 (2)	Na3—Li1—Cl2^xxi	135.3 (19)
O14—P1—O11	108.9 (3)	O1^ii—Li1—Cl2^xxi	85.7 (10)
O13—P1—O11	109.0 (2)	O3^xiv—Li1—Cl2^xxi	96.3 (8)
O12—P1—O11	110.6 (2)	O9^xiv—Li1—Cl2^xxi	99.5 (9)
O14—P1—Na3^iii	82.0 (2)	Cl2^xx—Li1—Cl2^xxi	7.2 (3)
O13—P1—Na3^iii	168.12 (16)	Na3—Li1—Al1^ii	119 (2)
O12—P1—Na3^iii	62.95 (19)	O1^ii—Li1—Al1^ii	40.5 (5)
O11—P1—Na3^iii	67.54 (18)	O3^xiv—Li1—Al1^ii	42.9 (4)
O14—P1—Na2^ii	81.0 (2)	O9^xiv—Li1—Al1^ii	116.8 (9)
O13—P1—Na2^ii	40.85 (14)	Cl2^xx—Li1—Al1^ii	103.1 (9)
O12—P1—Na2^ii	149.00 (18)	Cl2^xxi—Li1—Al1^ii	97.5 (8)
O11—P1—Na2^ii	92.59 (17)	Na3—Li1—Al3	112.9 (18)
Na3^iii—P1—Na2^ii	147.83 (10)	O1^ii—Li1—Al3	40.0 (5)
O14—P1—Na1^vi	84.7 (2)	O3^xiv—Li1—Al3	117.4 (9)
O13—P1—Na1^vi	38.10 (15)	O9^xiv—Li1—Al3	42.0 (4)
O12—P1—Na1^vi	92.48 (17)	Cl2^xx—Li1—Al3	106.1 (9)
O11—P1—Na1^vi	146.43 (17)	Cl2^xxi—Li1—Al3	100.3 (8)
Na3^iii—P1—Na1^vi	145.98 (10)	Al1^ii—Li1—Al3	75.2 (6)
Na2^ii—P1—Na1^vi	58.45 (5)	Na3—Li1—Li1^iv	172.0 (15)
O8—P2—O3	111.3 (2)	O1^ii—Li1—Li1^iv	33.8 (8)
O8—P2—O6	112.2 (2)	O3^xiv—Li1—Li1^iv	88.0 (7)
O3—P2—O6	107.9 (2)	O9^xiv—Li1—Li1^iv	87.8 (7)
O8—P2—O5	108.3 (2)	Cl2^xx—Li1—Li1^iv	59.2 (6)
O3—P2—O5	108.9 (2)	Cl2^xxi—Li1—Li1^iv	51.9 (5)
O6—P2—O5	108.0 (2)	Al1^ii—Li1—Li1^iv	58.4 (5)
O8—P2—Na2^xi	130.91 (17)	Al3—Li1—Li1^iv	59.4 (5)
O3—P2—Na2^xi	65.98 (16)	Na3—Li1—Na4^xx	78.4 (16)
O6—P2—Na2^xi	42.06 (15)	O1^ii—Li1—Na4^xx	133.3 (13)
O5—P2—Na2^xi	118.99 (15)	O3^xiv—Li1—Na4^xx	130.7 (10)
O8—P2—Na1	134.34 (18)	O9^xiv—Li1—Na4^xx	72.8 (8)
O3—P2—Na1	112.06 (16)	Cl2^xx—Li1—Na4^xx	56.4 (6)
O6—P2—Na1	39.30 (14)	Cl2^xxi—Li1—Na4^xx	62.2 (6)
O5—P2—Na1	69.90 (14)	Al1^ii—Li1—Na4^xx	159.4 (10)
Na2^xi—P2—Na1	59.51 (5)	Al3—Li1—Na4^xx	110.1 (9)
O9—P3—O10	108.9 (2)	Li1^iv—Li1—Na4^xx	106.1 (6)
O9—P3—O7	111.3 (3)	Na3—Li1—Na2^xx	84.7 (15)
O10—P3—O7	109.3 (2)	O1^ii—Li1—Na2^xx	129.1 (11)
O9—P3—O4	109.3 (2)	O3^xiv—Li1—Na2^xx	66.3 (5)
O10—P3—O4	108.4 (2)	O9^xiv—Li1—Na2^xx	137.4 (9)
O7—P3—O4	109.6 (2)	Cl2^xx—Li1—Na2^xx	55.1 (4)
O9—P3—Na3	81.60 (18)	Cl2^xxi—Li1—Na2^xx	60.6 (4)
O10—P3—Na3	158.74 (17)	Al1^ii—Li1—Na2^xx	103.6 (7)
O7—P3—Na3	49.57 (17)	Al3—Li1—Na2^xx	160.8 (10)
O4—P3—Na3	84.16 (17)	Li1^iv—Li1—Na2^xx	103.2 (5)
O9—P3—Na4^xi	69.4 (4)	Na4^xx—Li1—Na2^xx	64.6 (7)
O10—P3—Na4^xi	39.7 (4)	Na3—Li1—Na4^xiv	81.5 (16)
O7—P3—Na4^xi	121.5 (3)	O1^ii—Li1—Na4^xiv	132.3 (12)
O4—P3—Na4^xi	125.8 (4)	O3^xiv—Li1—Na4^xiv	127.3 (9)
Na3—P3—Na4^xi	143.4 (4)	O9^xiv—Li1—Na4^xiv	76.5 (7)
O9—P3—Na3^xiv	37.58 (17)	Cl2^xx—Li1—Na4^xiv	52.0 (5)
O10—P3—Na3^xiv	86.42 (17)	Cl2^xxi—Li1—Na4^xiv	58.0 (5)
O7—P3—Na3^xiv	92.4 (2)	Al1^ii—Li1—Na4^xiv	154.8 (9)
O4—P3—Na3^xiv	146.60 (17)	Al3—Li1—Na4^xiv	112.4 (8)
Na3—P3—Na3^xiv	92.07 (10)	Li1^iv—Li1—Na4^xiv	103.4 (5)
Na4^xi—P3—Na3^xiv	51.3 (4)	Na4^xx—Li1—Na4^xiv	4.8 (7)
O1—Al1—O2	171.8 (3)	Na2^xx—Li1—Na4^xiv	61.0 (6)
O1—Al1—O3^iv	91.46 (18)	Na4^xi—Na4—O10^xi	115 (5)
O2—Al1—O3^iv	94.22 (17)	Na4^xi—Na4—O15^xxii	111.2 (18)
O1—Al1—O3	91.46 (18)	O10^xi—Na4—O15^xxii	76.4 (8)
O2—Al1—O3	94.22 (17)	Na4^xi—Na4—Cl2	103 (3)
O3^iv—Al1—O3	92.4 (3)	O10^xi—Na4—Cl2	125.2 (6)
O1—Al1—O4^ii	93.36 (18)	O15^xxii—Na4—Cl2	52.7 (5)
O2—Al1—O4^ii	80.74 (17)	Na4^xi—Na4—O14^ix	99 (3)
O3^iv—Al1—O4^ii	89.88 (17)	O10^xi—Na4—O14^ix	108.1 (5)
O3—Al1—O4^ii	174.6 (2)	O15^xxii—Na4—O14^ix	144.3 (9)
O1—Al1—O4^xiv	93.35 (18)	Cl2—Na4—O14^ix	103.7 (9)
O2—Al1—O4^xiv	80.74 (17)	Na4^xi—Na4—O10	53 (4)
O3^iv—Al1—O4^xiv	174.6 (2)	O10^xi—Na4—O10	153.6 (6)
O3—Al1—O4^xiv	89.88 (17)	O15^xxii—Na4—O10	128.6 (8)
O4^ii—Al1—O4^xiv	87.5 (2)	Cl2—Na4—O10	81.1 (7)
O1—Al1—Li1^xiv	38.1 (5)	O14^ix—Na4—O10	58.2 (5)
O2—Al1—Li1^xiv	145.6 (5)	Na4^xi—Na4—O14^x	68 (3)
O3^iv—Al1—Li1^xiv	99.9 (5)	O10^xi—Na4—O14^x	59.6 (5)
O3—Al1—Li1^xiv	54.3 (5)	O15^xxii—Na4—O14^x	126.6 (12)
O4^ii—Al1—Li1^xiv	130.1 (5)	Cl2—Na4—O14^x	169.9 (6)
O4^xiv—Al1—Li1^xiv	85.4 (5)	O14^ix—Na4—O14^x	81.6 (4)
O1—Al1—Li1^ii	38.1 (5)	O10—Na4—O14^x	94.7 (4)
O2—Al1—Li1^ii	145.6 (5)	Na4^xi—Na4—Cl2^xi	65 (3)
O3^iv—Al1—Li1^ii	54.3 (5)	O10^xi—Na4—Cl2^xi	83.0 (8)
O3—Al1—Li1^ii	99.9 (5)	O15^xxii—Na4—Cl2^xi	49.1 (6)
O4^ii—Al1—Li1^ii	85.4 (5)	Cl2—Na4—Cl2^xi	78.3 (4)
O4^xiv—Al1—Li1^ii	130.1 (5)	O14^ix—Na4—Cl2^xi	163.4 (7)
Li1^xiv—Al1—Li1^ii	63.1 (11)	O10—Na4—Cl2^xi	106.5 (5)
O1—Al1—Cu2	136.15 (12)	O14^x—Na4—Cl2^xi	94.2 (7)
O2—Al1—Cu2	39.04 (8)	Na4^xi—Na4—O15	56.9 (16)
O3^iv—Al1—Cu2	84.33 (13)	O10^xi—Na4—O15	130.0 (9)
O3—Al1—Cu2	132.24 (15)	O15^xxii—Na4—O15	65.8 (8)
O4^ii—Al1—Cu2	43.18 (12)	Cl2—Na4—O15	48.2 (5)
O4^xiv—Al1—Cu2	90.55 (14)	O14^ix—Na4—O15	121.8 (10)
Li1^xiv—Al1—Cu2	172.5 (4)	O10—Na4—O15	66.7 (6)
Li1^ii—Al1—Cu2	115.6 (5)	O14^x—Na4—O15	121.7 (7)
O1—Al1—Cu2^iv	136.15 (12)	Cl2^xi—Na4—O15	47.7 (5)
O2—Al1—Cu2^iv	39.04 (8)	Na4^xi—Na4—Cl2^iv	101 (3)
O3^iv—Al1—Cu2^iv	132.24 (15)	O10^xi—Na4—Cl2^iv	122.8 (6)
O3—Al1—Cu2^iv	84.33 (13)	O15^xxii—Na4—Cl2^iv	48.9 (5)
O4^ii—Al1—Cu2^iv	90.55 (14)	Cl2—Na4—Cl2^iv	4.6 (2)
O4^xiv—Al1—Cu2^iv	43.18 (12)	O14^ix—Na4—Cl2^iv	108.3 (9)
Li1^xiv—Al1—Cu2^iv	115.6 (5)	O10—Na4—Cl2^iv	83.6 (6)
Li1^ii—Al1—Cu2^iv	172.5 (4)	O14^x—Na4—Cl2^iv	166.7 (7)
Cu2—Al1—Cu2^iv	64.60 (5)	Cl2^xi—Na4—Cl2^iv	73.8 (3)
O1—Al1—Na3^xiv	47.70 (9)	O15—Na4—Cl2^iv	45.7 (5)
O2—Al1—Na3^xiv	134.50 (9)	Na4^xi—Na4—Na3^xvii	159 (5)
O3^iv—Al1—Na3^xiv	110.66 (17)	O10^xi—Na4—Na3^xvii	85.9 (5)
O3—Al1—Na3^xiv	49.06 (14)	O15^xxii—Na4—Na3^xvii	76.8 (6)
O4^ii—Al1—Na3^xiv	134.23 (15)	Cl2—Na4—Na3^xvii	65.9 (4)
O4^xiv—Al1—Na3^xiv	74.45 (14)	O14^ix—Na4—Na3^xvii	68.5 (5)
Li1^xiv—Al1—Na3^xiv	12.9 (5)	O10—Na4—Na3^xvii	106.5 (9)
Li1^ii—Al1—Na3^xiv	75.9 (6)	O14^x—Na4—Na3^xvii	124.2 (5)
Cu2—Al1—Na3^xiv	164.98 (10)	Cl2^xi—Na4—Na3^xvii	125.8 (5)
Cu2^iv—Al1—Na3^xiv	102.68 (8)	O15—Na4—Na3^xvii	114.1 (7)
O1—Al1—Na3^ii	47.70 (9)	Cl2^iv—Na4—Na3^xvii	68.7 (4)
O2—Al1—Na3^ii	134.50 (9)	Na4^xi—Na4—Li1^xvii	152 (4)
O3^iv—Al1—Na3^ii	49.06 (14)	O10^xi—Na4—Li1^xvii	91.2 (6)
O3—Al1—Na3^ii	110.66 (16)	O15^xxii—Na4—Li1^xvii	63.4 (8)
O4^ii—Al1—Na3^ii	74.45 (14)	Cl2—Na4—Li1^xvii	51.3 (6)
O4^xiv—Al1—Na3^ii	134.23 (15)	O14^ix—Na4—Li1^xvii	81.0 (8)
Li1^xiv—Al1—Na3^ii	75.9 (6)	O10—Na4—Li1^xvii	107.1 (10)
Li1^ii—Al1—Na3^ii	12.9 (5)	O14^x—Na4—Li1^xvii	138.7 (7)
Cu2—Al1—Na3^ii	102.68 (8)	Cl2^xi—Na4—Li1^xvii	111.7 (6)
Cu2^iv—Al1—Na3^ii	164.98 (10)	O15—Na4—Li1^xvii	99.2 (8)
Na3^xiv—Al1—Na3^ii	88.61 (16)	Cl2^iv—Na4—Li1^xvii	53.6 (6)
O2—Al2—O2^vi	180.0	Na3^xvii—Na4—Li1^xvii	16.0 (5)
O2—Al2—O5	95.08 (15)	Cl2^iv—Cl2—Li1^xvii	120.8 (6)
O2^vi—Al2—O5	84.92 (15)	Cl2^iv—Cl2—Na4	142.9 (5)
O2—Al2—O5^vi	84.92 (15)	Li1^xvii—Cl2—Na4	72.3 (7)
O2^vi—Al2—O5^vi	95.08 (15)	Cl2^iv—Cl2—Li1^xvi	51.9 (5)
O5—Al2—O5^vi	180.0	Li1^xvii—Cl2—Li1^xvi	68.9 (11)
O2—Al2—O5^iv	95.08 (15)	Na4—Cl2—Li1^xvi	126.1 (6)
O2^vi—Al2—O5^iv	84.92 (15)	Cl2^iv—Cl2—Na2	137.26 (14)
O5—Al2—O5^iv	89.3 (2)	Li1^xvii—Cl2—Na2	77.0 (6)
O5^vi—Al2—O5^iv	90.7 (2)	Na4—Cl2—Na2	77.3 (6)
O2—Al2—O5^vii	84.92 (15)	Li1^xvi—Cl2—Na2	126.3 (5)
O2^vi—Al2—O5^vii	95.08 (15)	Cl2^iv—Cl2—Na4^xi	137.6 (4)
O5—Al2—O5^vii	90.7 (2)	Li1^xvii—Cl2—Na4^xi	84.9 (7)
O5^vi—Al2—O5^vii	89.3 (2)	Na4—Cl2—Na4^xi	12.8 (6)
O5^iv—Al2—O5^vii	180.0	Li1^xvi—Cl2—Na4^xi	136.1 (7)
O2—Al2—Cu2	40.73 (8)	Na2—Cl2—Na4^xi	77.4 (5)
O2^vi—Al2—Cu2	139.27 (8)	Cl2^iv—Cl2—Na4^iv	32.5 (5)
O5—Al2—Cu2	134.60 (10)	Li1^xvii—Cl2—Na4^iv	121.7 (7)
O5^vi—Al2—Cu2	45.40 (10)	Na4—Cl2—Na4^iv	110.4 (10)
O5^iv—Al2—Cu2	86.04 (11)	Li1^xvi—Cl2—Na4^iv	64.3 (6)
O5^vii—Al2—Cu2	93.96 (11)	Na2—Cl2—Na4^iv	160.9 (4)
O2—Al2—Cu2^vii	139.27 (8)	Na4^xi—Cl2—Na4^iv	106.2 (3)
O2^vi—Al2—Cu2^vii	40.73 (8)	Cl2^iv—Cl2—Na2^iv	37.66 (12)
O5—Al2—Cu2^vii	93.96 (11)	Li1^xvii—Cl2—Na2^iv	122.8 (6)
O5^vi—Al2—Cu2^vii	86.04 (11)	Na4—Cl2—Na2^iv	163.8 (4)
O5^iv—Al2—Cu2^vii	45.40 (10)	Li1^xvi—Cl2—Na2^iv	68.7 (5)
O5^vii—Al2—Cu2^vii	134.60 (10)	Na2—Cl2—Na2^iv	99.60 (15)
Cu2—Al2—Cu2^vii	113.48 (3)	Na4^xi—Cl2—Na2^iv	151.1 (3)
O2—Al2—Cu2^vi	139.27 (8)	Na4^iv—Cl2—Na2^iv	68.0 (5)
O2^vi—Al2—Cu2^vi	40.73 (8)	Cl2^iv—Cl2—Na3^xvii	133.22 (14)
O5—Al2—Cu2^vi	45.40 (10)	Li1^xvii—Cl2—Na3^xvii	12.4 (6)
O5^vi—Al2—Cu2^vi	134.60 (10)	Na4—Cl2—Na3^xvii	62.2 (4)
O5^iv—Al2—Cu2^vi	93.96 (11)	Li1^xvi—Cl2—Na3^xvii	81.3 (5)
O5^vii—Al2—Cu2^vi	86.04 (11)	Na2—Cl2—Na3^xvii	68.66 (19)
Cu2—Al2—Cu2^vi	180.00 (2)	Na4^xi—Cl2—Na3^xvii	74.4 (3)
Cu2^vii—Al2—Cu2^vi	66.52 (3)	Na4^iv—Cl2—Na3^xvii	130.5 (4)
O2—Al2—Cu2^iv	40.73 (8)	Na2^iv—Cl2—Na3^xvii	131.85 (16)
O2^vi—Al2—Cu2^iv	139.27 (8)	Cl2^iv—Cl2—Na4^xxii	37.6 (4)
O5—Al2—Cu2^iv	86.04 (11)	Li1^xvii—Cl2—Na4^xxii	131.9 (7)
O5^vi—Al2—Cu2^iv	93.96 (11)	Na4—Cl2—Na4^xxii	106.5 (3)
O5^iv—Al2—Cu2^iv	134.60 (10)	Li1^xvi—Cl2—Na4^xxii	75.6 (6)
O5^vii—Al2—Cu2^iv	45.40 (10)	Na2—Cl2—Na4^xxii	151.0 (4)
Cu2—Al2—Cu2^iv	66.52 (3)	Na4^xi—Cl2—Na4^xxii	100.0 (7)
Cu2^vii—Al2—Cu2^iv	180.00 (2)	Na4^iv—Cl2—Na4^xxii	11.6 (5)
Cu2^vi—Al2—Cu2^iv	113.48 (3)	Na2^iv—Cl2—Na4^xxii	68.6 (5)
O1^ii—Al3—O1	180.0	Na3^xvii—Cl2—Na4^xxii	139.2 (4)
O1^ii—Al3—O9^ii	88.09 (16)	Cl2^iv—Cl2—Na3^xvi	41.84 (12)
O1—Al3—O9^ii	91.91 (16)	Li1^xvii—Cl2—Na3^xvi	79.0 (6)
O1^ii—Al3—O9^iv	91.91 (16)	Na4—Cl2—Na3^xvi	131.9 (5)
O1—Al3—O9^iv	88.09 (16)	Li1^xvi—Cl2—Na3^xvi	10.1 (5)
O9^ii—Al3—O9^iv	89.3 (3)	Na2—Cl2—Na3^xvi	132.41 (16)
O1^ii—Al3—O9^xiv	88.09 (16)	Na4^xi—Cl2—Na3^xvi	140.0 (5)
O1—Al3—O9^xiv	91.91 (16)	Na4^iv—Cl2—Na3^xvi	55.7 (3)
O9^ii—Al3—O9^xiv	90.7 (3)	Na2^iv—Cl2—Na3^xvi	61.62 (16)
O9^iv—Al3—O9^xiv	180.0	Na3^xvii—Cl2—Na3^xvi	91.38 (16)
O1^ii—Al3—O9	91.91 (16)	Na4^xxii—Cl2—Na3^xvi	66.7 (3)
O1—Al3—O9	88.09 (16)	Na4^xi—O15—Na4^xxii	123.1 (11)
O9^ii—Al3—O9	180.0	Na4^xi—O15—Na4	11.9 (6)
O9^iv—Al3—O9	90.7 (3)	Na4^xxii—O15—Na4	114.2 (8)
O9^xiv—Al3—O9	89.3 (3)	Na4^xi—O15—Na4^iv	114.2 (8)
O1^ii—Al3—Li1^iv	36.5 (5)	Na4^xxii—O15—Na4^iv	11.9 (6)
O1—Al3—Li1^iv	143.5 (5)	Na4—O15—Na4^iv	104.3 (9)
O9^ii—Al3—Li1^iv	52.7 (5)	Cu2^iv—Cl1—Cu2	72.04 (5)
O9^iv—Al3—Li1^iv	83.2 (5)	Cu2^iv—Cl1—Na1^vi	126.68 (7)
O9^xiv—Al3—Li1^iv	96.8 (5)	Cu2—Cl1—Na1^vi	74.08 (4)
O9—Al3—Li1^iv	127.3 (5)	Cu2^iv—Cl1—Na1^xx	74.08 (4)
O1^ii—Al3—Li1^xiv	143.5 (5)	Cu2—Cl1—Na1^xx	126.68 (7)
O1—Al3—Li1^xiv	36.5 (5)	Na1^vi—Cl1—Na1^xx	95.68 (11)
O9^ii—Al3—Li1^xiv	127.3 (5)	Cu2^iv—Cl1—Na2^xiv	76.53 (6)
O9^iv—Al3—Li1^xiv	96.8 (5)	Cu2—Cl1—Na2^xiv	132.96 (9)
O9^xiv—Al3—Li1^xiv	83.2 (5)	Na1^vi—Cl1—Na2^xiv	151.96 (9)
O9—Al3—Li1^xiv	52.7 (5)	Na1^xx—Cl1—Na2^xiv	74.33 (7)
Li1^iv—Al3—Li1^xiv	180.0	Cu2^iv—Cl1—Na2^ii	132.96 (9)
O1^ii—Al3—Li1^ii	143.5 (5)	Cu2—Cl1—Na2^ii	76.53 (6)
O1—Al3—Li1^ii	36.5 (5)	Na1^vi—Cl1—Na2^ii	74.33 (7)
O9^ii—Al3—Li1^ii	83.2 (5)	Na1^xx—Cl1—Na2^ii	151.96 (9)
O9^iv—Al3—Li1^ii	52.7 (5)	Na2^xiv—Cl1—Na2^ii	102.08 (13)
O9^xiv—Al3—Li1^ii	127.3 (5)	Li1^xiv—O1—Li1^ii	112.4 (16)
O9—Al3—Li1^ii	96.8 (5)	Li1^xiv—O1—Al1	101.4 (8)
Li1^iv—Al3—Li1^ii	118.8 (10)	Li1^ii—O1—Al1	101.4 (8)
Li1^xiv—Al3—Li1^ii	61.2 (10)	Li1^xiv—O1—Al3	103.4 (8)
O1^ii—Al3—Li1	36.5 (5)	Li1^ii—O1—Al3	103.4 (8)
O1—Al3—Li1	143.5 (5)	Al1—O1—Al3	134.5 (3)
O9^ii—Al3—Li1	96.8 (5)	Li1^xiv—O1—Na3^xiv	13.0 (8)
O9^iv—Al3—Li1	127.3 (5)	Li1^ii—O1—Na3^xiv	125.3 (9)
O9^xiv—Al3—Li1	52.7 (5)	Al1—O1—Na3^xiv	98.37 (17)
O9—Al3—Li1	83.2 (5)	Al3—O1—Na3^xiv	97.48 (17)
Li1^iv—Al3—Li1	61.2 (10)	Li1^xiv—O1—Na3^ii	125.3 (9)
Li1^xiv—Al3—Li1	118.8 (10)	Li1^ii—O1—Na3^ii	13.0 (8)
Li1^ii—Al3—Li1	180.0	Al1—O1—Na3^ii	98.37 (17)
O1^ii—Al3—Na3	47.57 (9)	Al3—O1—Na3^ii	97.48 (17)
O1—Al3—Na3	132.43 (9)	Na3^xiv—O1—Na3^ii	138.2 (3)
O9^ii—Al3—Na3	107.38 (14)	Al2—O2—Al1	132.8 (3)
O9^iv—Al3—Na3	133.70 (14)	Al2—O2—Cu2	102.01 (19)
O9^xiv—Al3—Na3	46.30 (14)	Al1—O2—Cu2	104.31 (19)
O9—Al3—Na3	72.62 (14)	Al2—O2—Cu2^iv	102.01 (19)
Li1^iv—Al3—Na3	74.7 (5)	Al1—O2—Cu2^iv	104.30 (19)
Li1^xiv—Al3—Na3	105.3 (5)	Cu2—O2—Cu2^iv	110.6 (2)
Li1^ii—Al3—Na3	166.5 (5)	P2—O3—Al1	130.4 (2)
Li1—Al3—Na3	13.5 (5)	P2—O3—Li1^xiv	140.6 (7)
O1^ii—Al3—Na3^xiv	132.43 (9)	Al1—O3—Li1^xiv	82.9 (6)
O1—Al3—Na3^xiv	47.57 (9)	P2—O3—Na3^xiv	122.1 (2)
O9^ii—Al3—Na3^xiv	133.70 (14)	Al1—O3—Na3^xiv	95.35 (18)
O9^iv—Al3—Na3^xiv	107.38 (14)	Li1^xiv—O3—Na3^xiv	19.6 (6)
O9^xiv—Al3—Na3^xiv	72.62 (14)	P3—O4—Al1^ii	129.4 (2)
O9—Al3—Na3^xiv	46.30 (14)	P3—O4—Cu2^ii	133.5 (2)
Li1^iv—Al3—Na3^xiv	166.5 (5)	Al1^ii—O4—Cu2^ii	94.93 (16)
Li1^xiv—Al3—Na3^xiv	13.5 (5)	P2—O5—Al2	126.1 (2)
Li1^ii—Al3—Na3^xiv	74.7 (5)	P2—O5—Cu2^vi	136.9 (2)
Li1—Al3—Na3^xiv	105.3 (5)	Al2—O5—Cu2^vi	91.92 (15)
Na3—Al3—Na3^xiv	91.86 (14)	P2—O6—Cu4^xxiv	117.6 (2)
O6—Na1—O6^xv	136.6 (2)	P2—O6—Na1	116.7 (2)
O6—Na1—O13^xvi	79.75 (12)	Cu4^xxiv—O6—Na1	112.85 (17)
O6^xv—Na1—O13^xvi	84.04 (13)	P2—O6—Na2^xi	112.8 (2)
O6—Na1—O13^vi	84.04 (13)	Cu4^xxiv—O6—Na2^xi	104.64 (17)
O6^xv—Na1—O13^vi	79.75 (12)	Na1—O6—Na2^xi	87.48 (13)
O13^xvi—Na1—O13^vi	135.2 (2)	P3—O7—Cu1^xix	126.6 (3)
O6—Na1—Cl1^vi	122.81 (10)	P3—O7—Cu3^xix	125.1 (3)
O6^xv—Na1—Cl1^vi	90.35 (10)	Cu1^xix—O7—Cu3^xix	100.69 (16)
O13^xvi—Na1—Cl1^vi	148.63 (13)	P3—O7—Na3	101.0 (2)
O13^vi—Na1—Cl1^vi	73.21 (10)	Cu1^xix—O7—Na3	100.90 (18)
O6—Na1—Cl1^xvii	90.35 (10)	Cu3^xix—O7—Na3	94.67 (18)
O6^xv—Na1—Cl1^xvii	122.81 (10)	P2—O8—Cu3^vi	124.6 (2)
O13^xvi—Na1—Cl1^xvii	73.21 (10)	P2—O8—Cu1^x	122.8 (2)
O13^vi—Na1—Cl1^xvii	148.63 (13)	Cu3^vi—O8—Cu1^x	95.23 (15)
Cl1^vi—Na1—Cl1^xvii	84.32 (11)	P3—O9—Al3	135.1 (2)
O6—Na1—Cu2^vi	80.01 (9)	P3—O9—Li1^xiv	137.1 (7)
O6^xv—Na1—Cu2^vi	106.19 (9)	Al3—O9—Li1^xiv	85.3 (6)
O13^xvi—Na1—Cu2^vi	158.56 (12)	P3—O9—Na3^xiv	119.4 (2)
O13^vi—Na1—Cu2^vi	34.70 (8)	Al3—O9—Na3^xiv	98.23 (19)
Cl1^vi—Na1—Cu2^vi	51.89 (4)	Li1^xiv—O9—Na3^xiv	20.3 (6)
Cl1^xvii—Na1—Cu2^vi	113.93 (9)	P3—O10—Cu4	114.4 (2)
O6—Na1—Cu2^xvi	106.19 (9)	P3—O10—Na4^xi	115.9 (4)
O6^xv—Na1—Cu2^xvi	80.01 (9)	Cu4—O10—Na4^xi	96.7 (3)
O13^xvi—Na1—Cu2^xvi	34.70 (8)	P3—O10—Na2	127.9 (2)
O13^vi—Na1—Cu2^xvi	158.56 (12)	Cu4—O10—Na2	104.20 (17)
Cl1^vi—Na1—Cu2^xvi	113.93 (9)	Na4^xi—O10—Na2	91.5 (5)
Cl1^xvii—Na1—Cu2^xvi	51.89 (4)	P3—O10—Na4	127.0 (4)
Cu2^vi—Na1—Cu2^xvi	163.60 (12)	Cu4—O10—Na4	95.2 (3)
O6—Na1—Na2^xi	46.66 (10)	Na4^xi—O10—Na4	12.3 (9)
O6^xv—Na1—Na2^xi	131.38 (12)	Na2—O10—Na4	80.0 (4)
O13^xvi—Na1—Na2^xi	47.37 (10)	P1—O11—Cu1	130.6 (2)
O13^vi—Na1—Na2^xi	130.63 (11)	P1—O11—Cu4^ii	118.4 (2)
Cl1^vi—Na1—Na2^xi	130.65 (12)	Cu1—O11—Cu4^ii	105.08 (18)
Cl1^xvii—Na1—Na2^xi	53.09 (6)	P1—O11—Na3^iii	80.98 (19)
Cu2^vi—Na1—Na2^xi	119.23 (5)	Cu1—O11—Na3^iii	93.75 (17)
Cu2^xvi—Na1—Na2^xi	61.41 (5)	Cu4^ii—O11—Na3^iii	124.32 (18)
O6—Na1—Na2^xviii	131.38 (12)	P1—O12—Cu3	129.9 (3)
O6^xv—Na1—Na2^xviii	46.66 (10)	P1—O12—Cu4^v	121.4 (2)
O13^xvi—Na1—Na2^xviii	130.63 (11)	Cu3—O12—Cu4^v	103.15 (19)
O13^vi—Na1—Na2^xviii	47.37 (10)	P1—O12—Na3^iii	85.3 (2)
Cl1^vi—Na1—Na2^xviii	53.09 (6)	Cu3—O12—Na3^iii	93.02 (18)
Cl1^xvii—Na1—Na2^xviii	130.65 (12)	Cu4^v—O12—Na3^iii	118.6 (2)
Cu2^vi—Na1—Na2^xviii	61.41 (5)	P1—O13—Cu2	128.1 (2)
Cu2^xvi—Na1—Na2^xviii	119.23 (5)	P1—O13—Na1^vi	118.7 (2)
Na2^xi—Na1—Na2^xviii	176.07 (16)	Cu2—O13—Na1^vi	98.49 (17)
O6—Na1—P2^xv	150.14 (14)	P1—O13—Na2^ii	115.0 (2)
O6^xv—Na1—P2^xv	24.01 (8)	Cu2—O13—Na2^ii	101.15 (17)
O13^xvi—Na1—P2^xv	75.91 (9)	Na1^vi—O13—Na2^ii	86.49 (13)
O13^vi—Na1—P2^xv	101.28 (9)	P1—O14—Cu4^xxv	139.9 (3)
Cl1^vi—Na1—P2^xv	86.52 (6)	P1—O14—Na4^xxv	113.7 (5)
Cl1^xvii—Na1—P2^xv	98.83 (6)	Cu4^xxv—O14—Na4^xxv	95.7 (4)
Cu2^vi—Na1—P2^xv	120.65 (3)	P1—O14—Na2^xxv	119.7 (3)
Cu2^xvi—Na1—P2^xv	60.53 (2)	Cu4^xxv—O14—Na2^xxv	92.12 (19)
Na2^xi—Na1—P2^xv	120.05 (5)	Na4^xxv—O14—Na2^xxv	77.0 (5)
Na2^xviii—Na1—P2^xv	59.67 (5)	P1—O14—Na4^v	125.0 (5)
O6—Na1—P2	24.00 (8)	Cu4^xxv—O14—Na4^v	82.7 (4)
O6^xv—Na1—P2	150.14 (14)	Na4^xxv—O14—Na4^v	13.1 (6)
O13^xvi—Na1—P2	101.28 (9)	Na2^xxv—O14—Na4^v	77.7 (5)

Symmetry codes: (i) −x+1/2, −y+1/2, −z+1; (ii) −x+1, −y+1, −z+1; (iii) x−1/2, y−1/2, z; (iv) x, −y+1, z; (v) −x+1/2, y−1/2, −z+1; (vi) −x, −y+1, −z+1; (vii) −x, y, −z+1; (viii) x+1/2, −y+3/2, z; (ix) x+1/2, y+1/2, z+1; (x) −x+1/2, y+1/2, −z+1; (xi) −x+1, y, −z+2; (xii) −x+3/2, −y+3/2, −z+2; (xiii) −x+1/2, −y+3/2, −z+2; (xiv) −x+1, y, −z+1; (xv) −x, y, −z+2; (xvi) x, −y+1, z+1; (xvii) x, y, z+1; (xviii) x−1, y, z; (xix) x+1/2, y+1/2, z; (xx) x, y, z−1; (xxi) x, −y+1, z−1; (xxii) −x+1, −y+1, −z+2; (xxiii) x+1, y, z; (xxiv) x−1/2, −y+3/2, z; (xxv) x−1/2, y−1/2, z−1.