The mononuclear title complex, [Mn(C
7H
4O
5S)(C
10H
8N
2)(H
2O)
3]·H
2O, was obtained from the hydrothermal reaction of manganese acetate, potassium hydrogen 4-sulfonatobenzoate and 2,2′-bipyridine. The geometry of the seven-coordinate Mn
II atom is a monocapped trigonal prismatic. Each 4-sulfonatobenzoate anion chelates to the metal atom
via its carboxyl O atoms. The crystal structure is stabilized by a three-dimensional O—H
O hydrogen-bond network.
Supporting information
CCDC reference: 274404
Key indicators
- Single-crystal X-ray study
- T = 295 K
- Mean (C-C) = 0.007 Å
- Disorder in main residue
- R factor = 0.076
- wR factor = 0.139
- Data-to-parameter ratio = 11.0
checkCIF/PLATON results
No syntax errors found
Alert level B
PLAT241_ALERT_2_B Check High Ueq as Compared to Neighbors for O2
Alert level C
PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O1
PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for Mn1
PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for S1
PLAT301_ALERT_3_C Main Residue Disorder ......................... 9.00 Perc.
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7
0 ALERT level A = In general: serious problem
1 ALERT level B = Potentially serious problem
5 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
4 ALERT type 2 Indicator that the structure model may be wrong or deficient
2 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).
Triaqua(2,2'-bipyridine)(4-sulfonatobenzoato)manganese(II) monohydrate
top
Crystal data top
[Mn(C7H4O5S)(C10H8N2)(H2O)3]·H2O | F(000) = 996 |
Mr = 483.35 | Dx = 1.587 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 4074 reflections |
a = 10.3822 (6) Å | θ = 2.3–27.7° |
b = 17.6359 (10) Å | µ = 0.81 mm−1 |
c = 11.4516 (7) Å | T = 295 K |
β = 105.191 (1)° | Block, pale yellow |
V = 2023.5 (2) Å3 | 0.32 × 0.26 × 0.22 mm |
Z = 4 | |
Data collection top
Bruker SMART area-detector diffractometer | 3560 independent reflections |
Radiation source: fine-focus sealed tube | 3452 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.024 |
φ and ω scans | θmax = 25.0°, θmin = 2.0° |
Absorption correction: multi-scan (SADABS; Bruker, 2002) | h = −12→12 |
Tmin = 0.782, Tmax = 0.842 | k = −20→13 |
10472 measured reflections | l = −13→13 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.077 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.139 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.30 | w = 1/[σ2(Fo2) + (0.0204P)2 + 6.1194P] where P = (Fo2 + 2Fc2)/3 |
3560 reflections | (Δ/σ)max < 0.001 |
323 parameters | Δρmax = 0.69 e Å−3 |
78 restraints | Δρmin = −0.42 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Mn1 | 0.19792 (7) | 0.06592 (4) | 0.69423 (6) | 0.0317 (2) | |
S1 | 0.25460 (13) | −0.42796 (7) | 0.66508 (13) | 0.0422 (3) | |
N1 | 0.1488 (4) | 0.1927 (2) | 0.6867 (4) | 0.0370 (10) | |
N2 | 0.2764 (4) | 0.1190 (2) | 0.5448 (4) | 0.0371 (10) | |
O1 | 0.2012 (4) | −0.0473 (2) | 0.6041 (4) | 0.0678 (13) | |
O2 | 0.3104 (5) | −0.0556 (2) | 0.7896 (5) | 0.0829 (16) | |
O3 | 0.3730 (4) | −0.4537 (2) | 0.7553 (4) | 0.0553 (15) | 0.889 (8) |
O4 | 0.1343 (4) | −0.4499 (3) | 0.6920 (5) | 0.0690 (18) | 0.889 (8) |
O5 | 0.2627 (5) | −0.4493 (3) | 0.5456 (4) | 0.0696 (17) | 0.889 (8) |
O3' | 0.3719 (19) | −0.4690 (17) | 0.660 (3) | 0.062 (12) | 0.111 (8) |
O4' | 0.217 (3) | −0.443 (2) | 0.7765 (18) | 0.073 (14) | 0.111 (8) |
O5' | 0.143 (2) | −0.444 (2) | 0.561 (2) | 0.089 (16) | 0.111 (8) |
O6 | 0.1387 (3) | 0.0539 (2) | 0.8663 (3) | 0.0461 (9) | |
O7 | −0.0192 (4) | 0.0509 (3) | 0.6150 (4) | 0.0707 (13) | |
O8 | 0.3957 (3) | 0.1041 (2) | 0.8062 (3) | 0.0419 (8) | |
O9 | 0.4425 (4) | 0.4209 (2) | 0.5482 (4) | 0.0527 (10) | |
C1 | 0.0759 (5) | 0.2271 (3) | 0.7515 (5) | 0.0456 (13) | |
H1 | 0.0364 | 0.1973 | 0.7995 | 0.055* | |
C2 | 0.0562 (5) | 0.3045 (3) | 0.7508 (6) | 0.0516 (15) | |
H2 | 0.0059 | 0.3264 | 0.7981 | 0.062* | |
C3 | 0.1124 (6) | 0.3478 (3) | 0.6791 (6) | 0.0558 (16) | |
H3 | 0.1007 | 0.4001 | 0.6767 | 0.067* | |
C4 | 0.1863 (6) | 0.3142 (3) | 0.6106 (5) | 0.0473 (13) | |
H4 | 0.2242 | 0.3434 | 0.5607 | 0.057* | |
C5 | 0.2044 (5) | 0.2358 (3) | 0.6164 (4) | 0.0346 (11) | |
C6 | 0.2824 (5) | 0.1952 (3) | 0.5439 (4) | 0.0335 (11) | |
C7 | 0.3568 (5) | 0.2333 (3) | 0.4781 (5) | 0.0447 (13) | |
H7 | 0.3618 | 0.2859 | 0.4804 | 0.054* | |
C8 | 0.4230 (5) | 0.1928 (3) | 0.4094 (5) | 0.0487 (14) | |
H8 | 0.4730 | 0.2177 | 0.3647 | 0.058* | |
C9 | 0.4145 (6) | 0.1152 (3) | 0.4075 (5) | 0.0492 (14) | |
H9 | 0.4574 | 0.0864 | 0.3609 | 0.059* | |
C10 | 0.3409 (6) | 0.0812 (3) | 0.4767 (5) | 0.0460 (13) | |
H10 | 0.3358 | 0.0286 | 0.4760 | 0.055* | |
C11 | 0.2597 (5) | −0.0862 (3) | 0.6930 (6) | 0.0471 (14) | |
C12 | 0.2619 (5) | −0.1711 (3) | 0.6816 (4) | 0.0327 (11) | |
C13 | 0.3192 (5) | −0.2139 (3) | 0.7832 (4) | 0.0403 (12) | |
H13 | 0.3592 | −0.1899 | 0.8560 | 0.048* | |
C14 | 0.3174 (5) | −0.2919 (3) | 0.7775 (4) | 0.0415 (12) | |
H14 | 0.3546 | −0.3204 | 0.8464 | 0.050* | |
C15 | 0.2604 (4) | −0.3276 (3) | 0.6693 (4) | 0.0328 (11) | |
C16 | 0.2051 (5) | −0.2855 (3) | 0.5670 (5) | 0.0421 (12) | |
H16 | 0.1669 | −0.3096 | 0.4939 | 0.051* | |
C17 | 0.2067 (5) | −0.2078 (3) | 0.5735 (5) | 0.0433 (12) | |
H17 | 0.1702 | −0.1794 | 0.5043 | 0.052* | |
H6A | 0.0574 (16) | 0.051 (3) | 0.867 (5) | 0.050* | |
H6B | 0.180 (4) | 0.019 (2) | 0.913 (4) | 0.050* | |
H7A | −0.073 (3) | 0.050 (3) | 0.659 (3) | 0.050* | |
H7B | −0.064 (4) | 0.050 (3) | 0.5418 (13) | 0.050* | |
H8A | 0.461 (3) | 0.087 (3) | 0.782 (4) | 0.050* | |
H8B | 0.413 (4) | 0.097 (3) | 0.8819 (13) | 0.050* | |
H9A | 0.521 (2) | 0.424 (3) | 0.595 (4) | 0.050* | |
H9B | 0.400 (4) | 0.4601 (18) | 0.559 (4) | 0.050* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Mn1 | 0.0327 (4) | 0.0290 (4) | 0.0342 (4) | −0.0042 (3) | 0.0100 (3) | −0.0007 (3) |
S1 | 0.0419 (7) | 0.0285 (7) | 0.0587 (8) | −0.0048 (6) | 0.0177 (6) | −0.0077 (6) |
N1 | 0.030 (2) | 0.040 (2) | 0.042 (2) | 0.0023 (18) | 0.0109 (18) | 0.0009 (19) |
N2 | 0.045 (2) | 0.031 (2) | 0.037 (2) | −0.0034 (19) | 0.0140 (19) | −0.0020 (18) |
O1 | 0.063 (3) | 0.034 (2) | 0.095 (3) | −0.002 (2) | 0.000 (2) | 0.012 (2) |
O2 | 0.099 (4) | 0.044 (3) | 0.092 (4) | 0.003 (2) | 0.000 (3) | −0.030 (3) |
O3 | 0.043 (2) | 0.039 (2) | 0.082 (4) | 0.0024 (19) | 0.014 (2) | 0.011 (2) |
O4 | 0.045 (3) | 0.046 (3) | 0.123 (5) | −0.014 (2) | 0.035 (3) | −0.010 (3) |
O5 | 0.091 (4) | 0.051 (3) | 0.072 (3) | −0.004 (3) | 0.030 (3) | −0.026 (2) |
O3' | 0.063 (15) | 0.062 (15) | 0.063 (15) | −0.008 (9) | 0.019 (10) | −0.005 (9) |
O4' | 0.076 (16) | 0.067 (16) | 0.076 (16) | −0.008 (10) | 0.020 (10) | −0.001 (10) |
O5' | 0.092 (18) | 0.075 (18) | 0.091 (18) | 0.002 (10) | 0.008 (10) | 0.001 (10) |
O6 | 0.0361 (19) | 0.057 (2) | 0.048 (2) | 0.0107 (18) | 0.0154 (17) | 0.0196 (18) |
O7 | 0.040 (2) | 0.108 (4) | 0.059 (3) | −0.017 (3) | 0.004 (2) | −0.006 (3) |
O8 | 0.0275 (18) | 0.047 (2) | 0.051 (2) | 0.0018 (16) | 0.0101 (16) | −0.0019 (18) |
O9 | 0.051 (2) | 0.040 (2) | 0.066 (3) | 0.0012 (18) | 0.013 (2) | −0.0068 (19) |
C1 | 0.037 (3) | 0.051 (3) | 0.053 (3) | 0.004 (2) | 0.019 (3) | 0.005 (3) |
C2 | 0.039 (3) | 0.050 (3) | 0.069 (4) | 0.012 (3) | 0.018 (3) | −0.010 (3) |
C3 | 0.055 (4) | 0.030 (3) | 0.081 (4) | 0.010 (3) | 0.015 (3) | −0.008 (3) |
C4 | 0.053 (3) | 0.030 (3) | 0.062 (4) | 0.000 (2) | 0.020 (3) | 0.005 (3) |
C5 | 0.028 (2) | 0.033 (3) | 0.039 (3) | −0.002 (2) | 0.003 (2) | 0.000 (2) |
C6 | 0.034 (3) | 0.032 (3) | 0.033 (3) | −0.003 (2) | 0.007 (2) | 0.000 (2) |
C7 | 0.046 (3) | 0.039 (3) | 0.049 (3) | −0.010 (2) | 0.013 (3) | 0.006 (2) |
C8 | 0.049 (3) | 0.054 (4) | 0.047 (3) | −0.010 (3) | 0.020 (3) | 0.004 (3) |
C9 | 0.058 (4) | 0.053 (4) | 0.044 (3) | −0.002 (3) | 0.026 (3) | −0.006 (3) |
C10 | 0.059 (3) | 0.031 (3) | 0.051 (3) | −0.001 (2) | 0.018 (3) | −0.004 (2) |
C11 | 0.033 (3) | 0.034 (3) | 0.075 (4) | 0.001 (2) | 0.016 (3) | 0.001 (3) |
C12 | 0.029 (2) | 0.030 (2) | 0.043 (3) | −0.003 (2) | 0.015 (2) | −0.003 (2) |
C13 | 0.050 (3) | 0.036 (3) | 0.032 (3) | −0.007 (2) | 0.005 (2) | −0.008 (2) |
C14 | 0.055 (3) | 0.035 (3) | 0.029 (3) | −0.003 (2) | 0.001 (2) | 0.001 (2) |
C15 | 0.027 (2) | 0.029 (2) | 0.042 (3) | −0.002 (2) | 0.009 (2) | −0.005 (2) |
C16 | 0.048 (3) | 0.040 (3) | 0.033 (3) | −0.004 (2) | 0.003 (2) | −0.009 (2) |
C17 | 0.046 (3) | 0.041 (3) | 0.039 (3) | 0.001 (2) | 0.005 (2) | 0.008 (2) |
Geometric parameters (Å, º) top
Mn1—O1 | 2.252 (4) | C1—C2 | 1.380 (8) |
Mn1—O2 | 2.545 (5) | C1—H1 | 0.9300 |
Mn1—O6 | 2.222 (4) | C2—C3 | 1.360 (8) |
Mn1—O7 | 2.214 (4) | C2—H2 | 0.9300 |
Mn1—O8 | 2.222 (3) | C3—C4 | 1.368 (8) |
Mn1—N1 | 2.291 (4) | C3—H3 | 0.9300 |
Mn1—N2 | 2.280 (4) | C4—C5 | 1.394 (7) |
S1—O4 | 1.417 (4) | C4—H4 | 0.9300 |
S1—O3' | 1.432 (8) | C5—C6 | 1.486 (7) |
S1—O5 | 1.443 (4) | C6—C7 | 1.385 (7) |
S1—O5' | 1.450 (8) | C7—C8 | 1.372 (8) |
S1—O4' | 1.452 (8) | C7—H7 | 0.9300 |
S1—O3 | 1.456 (4) | C8—C9 | 1.371 (8) |
S1—C15 | 1.771 (5) | C8—H8 | 0.9300 |
N1—C1 | 1.336 (6) | C9—C10 | 1.374 (7) |
N1—C5 | 1.343 (6) | C9—H9 | 0.9300 |
N2—C10 | 1.331 (6) | C10—H10 | 0.9300 |
N2—C6 | 1.346 (6) | C11—C12 | 1.504 (7) |
O1—C11 | 1.246 (7) | C12—C17 | 1.381 (7) |
O2—C11 | 1.219 (7) | C12—C13 | 1.384 (7) |
O6—H6A | 0.849 (10) | C13—C14 | 1.377 (7) |
O6—H6B | 0.85 (4) | C13—H13 | 0.9300 |
O7—H7A | 0.85 (3) | C14—C15 | 1.378 (7) |
O7—H7B | 0.847 (10) | C14—H14 | 0.9300 |
O8—H8A | 0.85 (4) | C15—C16 | 1.379 (7) |
O8—H8B | 0.848 (10) | C16—C17 | 1.372 (7) |
O9—H9A | 0.85 (3) | C16—H16 | 0.9300 |
O9—H9B | 0.85 (4) | C17—H17 | 0.9300 |
| | | |
O1—Mn1—O2 | 52.41 (15) | Mn1—O8—H8A | 114 (3) |
O6—Mn1—O1 | 111.27 (16) | Mn1—O8—H8B | 117 (4) |
O7—Mn1—O1 | 80.93 (18) | H8A—O8—H8B | 108 (4) |
O8—Mn1—O1 | 114.25 (15) | H9A—O9—H9B | 108 (4) |
O1—Mn1—N1 | 151.43 (16) | N1—C1—C2 | 123.4 (5) |
O1—Mn1—N2 | 88.18 (16) | N1—C1—H1 | 118.3 |
O6—Mn1—O2 | 75.03 (16) | C2—C1—H1 | 118.3 |
O7—Mn1—O2 | 112.26 (19) | C3—C2—C1 | 118.2 (5) |
O8—Mn1—O2 | 75.93 (14) | C3—C2—H2 | 120.9 |
N1—Mn1—O2 | 155.61 (15) | C1—C2—H2 | 120.9 |
N2—Mn1—O2 | 116.96 (17) | C2—C3—C4 | 119.7 (5) |
O7—Mn1—O6 | 82.17 (16) | C2—C3—H3 | 120.1 |
O8—Mn1—O6 | 86.88 (14) | C4—C3—H3 | 120.1 |
O6—Mn1—N1 | 90.92 (14) | C3—C4—C5 | 119.5 (5) |
O6—Mn1—N2 | 160.19 (15) | C3—C4—H4 | 120.3 |
O7—Mn1—O8 | 163.86 (17) | C5—C4—H4 | 120.3 |
O7—Mn1—N1 | 84.74 (18) | N1—C5—C4 | 121.0 (5) |
O7—Mn1—N2 | 105.48 (17) | N1—C5—C6 | 116.4 (4) |
O8—Mn1—N1 | 83.61 (14) | C4—C5—C6 | 122.6 (5) |
O8—Mn1—N2 | 81.42 (14) | N2—C6—C7 | 121.4 (5) |
N2—Mn1—N1 | 72.00 (14) | N2—C6—C5 | 116.4 (4) |
O4—S1—O3' | 132.8 (14) | C7—C6—C5 | 122.2 (4) |
O4—S1—O5 | 114.1 (3) | C8—C7—C6 | 119.6 (5) |
O3'—S1—O5 | 64.2 (12) | C8—C7—H7 | 120.2 |
O4—S1—O5' | 64.3 (14) | C6—C7—H7 | 120.2 |
O3'—S1—O5' | 112.0 (8) | C9—C8—C7 | 119.2 (5) |
O5—S1—O5' | 53.6 (13) | C9—C8—H8 | 120.4 |
O4—S1—O4' | 46.0 (13) | C7—C8—H8 | 120.4 |
O3'—S1—O4' | 111.7 (8) | C8—C9—C10 | 118.0 (5) |
O5—S1—O4' | 151.6 (16) | C8—C9—H9 | 121.0 |
O5'—S1—O4' | 110.2 (8) | C10—C9—H9 | 121.0 |
O4—S1—O3 | 112.9 (3) | N2—C10—C9 | 124.1 (5) |
O3'—S1—O3 | 45.9 (12) | N2—C10—H10 | 117.9 |
O5—S1—O3 | 110.1 (3) | C9—C10—H10 | 117.9 |
O5'—S1—O3 | 150.0 (15) | O2—C11—O1 | 120.0 (5) |
O4'—S1—O3 | 71.9 (13) | O2—C11—C12 | 120.4 (5) |
O4—S1—C15 | 107.0 (2) | O1—C11—C12 | 119.5 (5) |
O3'—S1—C15 | 118.9 (14) | C17—C12—C13 | 119.0 (4) |
O5—S1—C15 | 106.1 (3) | C17—C12—C11 | 122.1 (5) |
O5'—S1—C15 | 103.0 (16) | C13—C12—C11 | 118.9 (5) |
O4'—S1—C15 | 100.1 (15) | C14—C13—C12 | 120.5 (5) |
O3—S1—C15 | 106.0 (2) | C14—C13—H13 | 119.8 |
C1—N1—C5 | 118.1 (4) | C12—C13—H13 | 119.8 |
C1—N1—Mn1 | 125.1 (3) | C15—C14—C13 | 119.8 (5) |
C5—N1—Mn1 | 116.7 (3) | C15—C14—H14 | 120.1 |
C10—N2—C6 | 117.6 (4) | C13—C14—H14 | 120.1 |
C10—N2—Mn1 | 124.6 (3) | C14—C15—C16 | 120.2 (4) |
C6—N2—Mn1 | 116.2 (3) | C14—C15—S1 | 119.0 (4) |
C11—O1—Mn1 | 100.2 (4) | C16—C15—S1 | 120.8 (4) |
C11—O2—Mn1 | 86.7 (4) | C17—C16—C15 | 119.7 (5) |
Mn1—O6—H6A | 122 (3) | C17—C16—H16 | 120.2 |
Mn1—O6—H6B | 114 (3) | C15—C16—H16 | 120.2 |
H6A—O6—H6B | 107 (5) | C16—C17—C12 | 120.9 (5) |
Mn1—O7—H7A | 121 (3) | C16—C17—H17 | 119.6 |
Mn1—O7—H7B | 130 (3) | C12—C17—H17 | 119.6 |
H7A—O7—H7B | 108 (4) | | |
| | | |
O7—Mn1—N1—C1 | 66.2 (4) | C3—C4—C5—C6 | 179.5 (5) |
O8—Mn1—N1—C1 | −102.6 (4) | C10—N2—C6—C7 | −2.2 (7) |
O6—Mn1—N1—C1 | −15.9 (4) | Mn1—N2—C6—C7 | 164.2 (4) |
O1—Mn1—N1—C1 | 126.2 (4) | C10—N2—C6—C5 | 177.3 (4) |
N2—Mn1—N1—C1 | 174.3 (4) | Mn1—N2—C6—C5 | −16.3 (5) |
O2—Mn1—N1—C1 | −69.7 (6) | N1—C5—C6—N2 | 7.6 (6) |
O7—Mn1—N1—C5 | −117.8 (4) | C4—C5—C6—N2 | −170.9 (5) |
O8—Mn1—N1—C5 | 73.4 (3) | N1—C5—C6—C7 | −172.8 (5) |
O6—Mn1—N1—C5 | 160.2 (3) | C4—C5—C6—C7 | 8.7 (8) |
O1—Mn1—N1—C5 | −57.8 (5) | N2—C6—C7—C8 | 1.8 (8) |
N2—Mn1—N1—C5 | −9.6 (3) | C5—C6—C7—C8 | −177.7 (5) |
O2—Mn1—N1—C5 | 106.3 (5) | C6—C7—C8—C9 | −0.2 (8) |
O7—Mn1—N2—C10 | −101.9 (4) | C7—C8—C9—C10 | −0.9 (9) |
O8—Mn1—N2—C10 | 93.1 (4) | C6—N2—C10—C9 | 1.0 (8) |
O6—Mn1—N2—C10 | 147.5 (4) | Mn1—N2—C10—C9 | −164.1 (4) |
O1—Mn1—N2—C10 | −21.8 (4) | C8—C9—C10—N2 | 0.5 (9) |
N1—Mn1—N2—C10 | 179.1 (4) | Mn1—O2—C11—O1 | 8.1 (6) |
O2—Mn1—N2—C10 | 23.7 (5) | Mn1—O2—C11—C12 | −169.3 (4) |
O7—Mn1—N2—C6 | 92.8 (4) | Mn1—O1—C11—O2 | −9.3 (6) |
O8—Mn1—N2—C6 | −72.2 (4) | Mn1—O1—C11—C12 | 168.1 (4) |
O6—Mn1—N2—C6 | −17.8 (7) | O2—C11—C12—C17 | −179.3 (5) |
O1—Mn1—N2—C6 | 172.9 (4) | O1—C11—C12—C17 | 3.3 (8) |
N1—Mn1—N2—C6 | 13.8 (3) | O2—C11—C12—C13 | 1.8 (8) |
O2—Mn1—N2—C6 | −141.6 (3) | O1—C11—C12—C13 | −175.6 (5) |
O7—Mn1—O1—C11 | −122.5 (4) | C17—C12—C13—C14 | −2.0 (8) |
O8—Mn1—O1—C11 | 51.7 (4) | C11—C12—C13—C14 | 176.9 (5) |
O6—Mn1—O1—C11 | −44.7 (4) | C12—C13—C14—C15 | 1.2 (8) |
N2—Mn1—O1—C11 | 131.5 (4) | C13—C14—C15—C16 | 0.0 (8) |
N1—Mn1—O1—C11 | 176.7 (3) | C13—C14—C15—S1 | −178.0 (4) |
O2—Mn1—O1—C11 | 4.8 (3) | O4—S1—C15—C14 | 88.8 (5) |
O7—Mn1—O2—C11 | 53.1 (4) | O3'—S1—C15—C14 | −79.9 (15) |
O8—Mn1—O2—C11 | −141.5 (4) | O5—S1—C15—C14 | −149.0 (4) |
O6—Mn1—O2—C11 | 127.9 (4) | O5'—S1—C15—C14 | 155.6 (14) |
O1—Mn1—O2—C11 | −4.9 (3) | O4'—S1—C15—C14 | 42.0 (14) |
N2—Mn1—O2—C11 | −69.0 (4) | O3—S1—C15—C14 | −31.9 (5) |
N1—Mn1—O2—C11 | −175.4 (3) | O4—S1—C15—C16 | −89.1 (5) |
C5—N1—C1—C2 | −0.7 (8) | O3'—S1—C15—C16 | 102.1 (15) |
Mn1—N1—C1—C2 | 175.3 (4) | O5—S1—C15—C16 | 33.0 (5) |
N1—C1—C2—C3 | 0.9 (9) | O5'—S1—C15—C16 | −22.4 (15) |
C1—C2—C3—C4 | −0.2 (9) | O4'—S1—C15—C16 | −136.0 (14) |
C2—C3—C4—C5 | −0.8 (9) | O3—S1—C15—C16 | 150.1 (4) |
C1—N1—C5—C4 | −0.3 (7) | C14—C15—C16—C17 | −0.2 (8) |
Mn1—N1—C5—C4 | −176.6 (4) | S1—C15—C16—C17 | 177.7 (4) |
C1—N1—C5—C6 | −178.8 (4) | C15—C16—C17—C12 | −0.6 (8) |
Mn1—N1—C5—C6 | 4.8 (5) | C13—C12—C17—C16 | 1.7 (8) |
C3—C4—C5—N1 | 1.0 (8) | C11—C12—C17—C16 | −177.2 (5) |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O8—H8A···O3′i | 0.85 (4) | 1.96 (4) | 2.67 (3) | 141 (4) |
O8—H8A···O3i | 0.85 (4) | 2.02 (1) | 2.862 (5) | 174 (4) |
O6—H6B···O5ii | 0.85 (4) | 1.97 (2) | 2.808 (5) | 169 (5) |
O6—H6B···O5′ii | 0.85 (4) | 2.27 (4) | 2.95 (3) | 137 (4) |
O8—H8B···O9iii | 0.85 (1) | 1.87 (1) | 2.721 (6) | 177 (5) |
O9—H9B···O3′iv | 0.85 (4) | 1.78 (4) | 2.53 (2) | 148 (5) |
O9—H9B···O5iv | 0.85 (4) | 2.12 (1) | 2.948 (6) | 167 (4) |
O6—H6A···O4v | 0.85 (1) | 1.93 (2) | 2.738 (5) | 159 (5) |
O9—H9A···O2i | 0.85 (3) | 1.93 (4) | 2.776 (6) | 172 (4) |
O7—H7B···O1vi | 0.85 (1) | 1.89 (2) | 2.717 (6) | 166 (4) |
O7—H7A···O4′v | 0.85 (3) | 1.84 (3) | 2.67 (2) | 167 (5) |
O7—H7A···O4v | 0.85 (3) | 1.97 (2) | 2.775 (7) | 159 (4) |
Symmetry codes: (i) −x+1, y+1/2, −z+3/2; (ii) x, −y−1/2, z+1/2; (iii) x, −y+1/2, z+1/2; (iv) x, y+1, z; (v) −x, y+1/2, −z+3/2; (vi) −x, −y, −z+1. |