Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805010743/hb6174sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805010743/hb6174Isup2.hkl |
CCDC reference: 271881
Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
[Ru(C25H46P2)2Cl2] | F(000) = 2120 |
Mr = 989.09 | Dx = 1.226 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 858 reflections |
a = 24.120 (11) Å | θ = 2.7–26.3° |
b = 10.732 (5) Å | µ = 0.54 mm−1 |
c = 21.780 (11) Å | T = 293 K |
β = 108.098 (8)° | Block, orange |
V = 5359 (4) Å3 | 0.30 × 0.18 × 0.12 mm |
Z = 4 |
Bruker SMART CCD diffractometer | 4717 independent reflections |
Radiation source: fine-focus sealed tube | 3644 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.040 |
ω scans | θmax = 25.0°, θmin = 2.0° |
Absorption correction: multi-scan (SADABS; Bruker, 1998) | h = −28→24 |
Tmin = 0.796, Tmax = 0.937 | k = −12→12 |
13674 measured reflections | l = −25→21 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.032 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.083 | H-atom parameters constrained |
S = 1.09 | w = 1/[σ2(Fo2) + (0.0366P)2 + 1.6382P] where P = (Fo2 + 2Fc2)/3 |
4717 reflections | (Δ/σ)max = 0.001 |
259 parameters | Δρmax = 0.30 e Å−3 |
0 restraints | Δρmin = −0.42 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Ru1 | 0.5000 | 1.0000 | 0.0000 | 0.02355 (10) | |
P1 | 0.44129 (3) | 0.91073 (6) | 0.05829 (3) | 0.02707 (17) | |
P2 | 0.55080 (3) | 1.01477 (6) | 0.11180 (3) | 0.02706 (17) | |
Cl1 | 0.45482 (3) | 1.19734 (6) | 0.01211 (3) | 0.03483 (18) | |
C1 | 0.44881 (12) | 0.7423 (2) | 0.07839 (13) | 0.0320 (6) | |
H1 | 0.4909 | 0.7270 | 0.0918 | 0.038* | |
C2 | 0.42999 (15) | 0.6997 (3) | 0.13569 (16) | 0.0519 (9) | |
H2A | 0.4469 | 0.7542 | 0.1723 | 0.062* | |
H2B | 0.3879 | 0.7049 | 0.1246 | 0.062* | |
C3 | 0.44952 (17) | 0.5662 (3) | 0.15408 (18) | 0.0651 (10) | |
H3A | 0.4918 | 0.5624 | 0.1682 | 0.078* | |
H3B | 0.4363 | 0.5400 | 0.1898 | 0.078* | |
C4 | 0.42556 (18) | 0.4785 (3) | 0.09782 (19) | 0.0644 (11) | |
H4A | 0.3834 | 0.4742 | 0.0871 | 0.077* | |
H4B | 0.4411 | 0.3956 | 0.1100 | 0.077* | |
C5 | 0.44154 (17) | 0.5217 (3) | 0.03885 (18) | 0.0599 (10) | |
H5A | 0.4833 | 0.5136 | 0.0475 | 0.072* | |
H5B | 0.4225 | 0.4682 | 0.0025 | 0.072* | |
C6 | 0.42390 (14) | 0.6554 (3) | 0.02102 (15) | 0.0441 (8) | |
H6A | 0.3817 | 0.6616 | 0.0065 | 0.053* | |
H6B | 0.4378 | 0.6808 | −0.0143 | 0.053* | |
C7 | 0.36543 (11) | 0.9644 (3) | 0.04876 (14) | 0.0354 (7) | |
H7 | 0.3642 | 1.0503 | 0.0331 | 0.042* | |
C8 | 0.34868 (14) | 0.9746 (3) | 0.11041 (16) | 0.0558 (9) | |
H8A | 0.3786 | 1.0203 | 0.1427 | 0.067* | |
H8B | 0.3461 | 0.8918 | 0.1272 | 0.067* | |
C9 | 0.29017 (14) | 1.0411 (4) | 0.0976 (2) | 0.0701 (11) | |
H9A | 0.2795 | 1.0428 | 0.1371 | 0.084* | |
H9B | 0.2940 | 1.1266 | 0.0850 | 0.084* | |
C10 | 0.24279 (15) | 0.9781 (4) | 0.0455 (2) | 0.0775 (13) | |
H10A | 0.2072 | 1.0265 | 0.0364 | 0.093* | |
H10B | 0.2354 | 0.8965 | 0.0604 | 0.093* | |
C11 | 0.25912 (14) | 0.9641 (4) | −0.01534 (19) | 0.0724 (12) | |
H11A | 0.2612 | 1.0459 | −0.0334 | 0.087* | |
H11B | 0.2290 | 0.9170 | −0.0467 | 0.087* | |
C12 | 0.31793 (12) | 0.8975 (3) | −0.00307 (16) | 0.0507 (8) | |
H12A | 0.3147 | 0.8124 | 0.0104 | 0.061* | |
H12B | 0.3281 | 0.8951 | −0.0428 | 0.061* | |
C13 | 0.48444 (11) | 0.9853 (2) | 0.13472 (13) | 0.0310 (6) | |
H13A | 0.4666 | 1.0616 | 0.1433 | 0.037* | |
H13B | 0.4916 | 0.9294 | 0.1714 | 0.037* | |
C14 | 0.60040 (11) | 0.8843 (3) | 0.14725 (13) | 0.0334 (6) | |
H14 | 0.5804 | 0.8110 | 0.1238 | 0.040* | |
C15 | 0.65766 (12) | 0.8886 (3) | 0.13140 (16) | 0.0479 (8) | |
H15A | 0.6825 | 0.9535 | 0.1566 | 0.058* | |
H15B | 0.6500 | 0.9080 | 0.0860 | 0.058* | |
C16 | 0.68857 (15) | 0.7628 (4) | 0.14665 (18) | 0.0645 (10) | |
H16A | 0.6653 | 0.6999 | 0.1181 | 0.077* | |
H16B | 0.7258 | 0.7678 | 0.1385 | 0.077* | |
C17 | 0.69845 (15) | 0.7244 (4) | 0.21538 (19) | 0.0675 (11) | |
H17A | 0.7262 | 0.7810 | 0.2438 | 0.081* | |
H17B | 0.7151 | 0.6414 | 0.2220 | 0.081* | |
C18 | 0.64246 (16) | 0.7251 (3) | 0.23263 (18) | 0.0665 (11) | |
H18A | 0.6510 | 0.7070 | 0.2783 | 0.080* | |
H18B | 0.6168 | 0.6604 | 0.2085 | 0.080* | |
C19 | 0.61168 (15) | 0.8507 (3) | 0.21771 (16) | 0.0570 (9) | |
H19A | 0.5750 | 0.8470 | 0.2271 | 0.068* | |
H19B | 0.6357 | 0.9145 | 0.2449 | 0.068* | |
C20 | 0.57681 (12) | 1.1626 (3) | 0.15535 (14) | 0.0370 (7) | |
H20 | 0.5465 | 1.2232 | 0.1343 | 0.044* | |
C21 | 0.57884 (14) | 1.1659 (3) | 0.22569 (15) | 0.0497 (8) | |
H21A | 0.6101 | 1.1125 | 0.2507 | 0.060* | |
H21B | 0.5425 | 1.1337 | 0.2294 | 0.060* | |
C22 | 0.58848 (17) | 1.2972 (3) | 0.25312 (19) | 0.0684 (11) | |
H22A | 0.5546 | 1.3478 | 0.2320 | 0.082* | |
H22B | 0.5926 | 1.2944 | 0.2988 | 0.082* | |
C23 | 0.64155 (16) | 1.3561 (3) | 0.24406 (18) | 0.0656 (10) | |
H23A | 0.6760 | 1.3141 | 0.2714 | 0.079* | |
H23B | 0.6435 | 1.4426 | 0.2576 | 0.079* | |
C24 | 0.64144 (16) | 1.3502 (3) | 0.17453 (18) | 0.0632 (10) | |
H24A | 0.6784 | 1.3811 | 0.1718 | 0.076* | |
H24B | 0.6108 | 1.4037 | 0.1482 | 0.076* | |
C25 | 0.63184 (14) | 1.2179 (3) | 0.14798 (16) | 0.0517 (8) | |
H25A | 0.6293 | 1.2187 | 0.1026 | 0.062* | |
H25B | 0.6649 | 1.1665 | 0.1708 | 0.062* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ru1 | 0.02779 (17) | 0.01840 (15) | 0.02548 (17) | 0.00164 (12) | 0.00976 (13) | −0.00191 (13) |
P1 | 0.0305 (4) | 0.0248 (4) | 0.0279 (4) | −0.0004 (3) | 0.0120 (3) | −0.0022 (3) |
P2 | 0.0290 (4) | 0.0268 (4) | 0.0259 (4) | 0.0011 (3) | 0.0092 (3) | −0.0028 (3) |
Cl1 | 0.0441 (4) | 0.0238 (3) | 0.0386 (4) | 0.0075 (3) | 0.0158 (3) | −0.0025 (3) |
C1 | 0.0360 (15) | 0.0270 (14) | 0.0361 (16) | 0.0007 (11) | 0.0158 (13) | 0.0019 (12) |
C2 | 0.084 (2) | 0.0372 (18) | 0.046 (2) | −0.0074 (16) | 0.0373 (19) | −0.0004 (15) |
C3 | 0.106 (3) | 0.043 (2) | 0.056 (2) | 0.0030 (19) | 0.039 (2) | 0.0180 (19) |
C4 | 0.093 (3) | 0.0301 (19) | 0.085 (3) | −0.0001 (16) | 0.050 (2) | 0.0081 (18) |
C5 | 0.095 (3) | 0.0331 (19) | 0.066 (2) | 0.0002 (16) | 0.047 (2) | −0.0036 (16) |
C6 | 0.061 (2) | 0.0308 (16) | 0.0448 (19) | −0.0044 (14) | 0.0231 (16) | −0.0037 (14) |
C7 | 0.0318 (15) | 0.0376 (16) | 0.0390 (17) | 0.0022 (12) | 0.0143 (14) | −0.0033 (13) |
C8 | 0.0434 (19) | 0.081 (3) | 0.047 (2) | 0.0084 (16) | 0.0198 (16) | −0.0120 (18) |
C9 | 0.051 (2) | 0.091 (3) | 0.078 (3) | 0.0111 (19) | 0.034 (2) | −0.021 (2) |
C10 | 0.0360 (19) | 0.107 (3) | 0.093 (3) | 0.006 (2) | 0.025 (2) | −0.019 (3) |
C11 | 0.0367 (19) | 0.108 (3) | 0.067 (3) | 0.0056 (19) | 0.0086 (19) | −0.018 (2) |
C12 | 0.0378 (17) | 0.066 (2) | 0.048 (2) | −0.0040 (15) | 0.0145 (16) | −0.0118 (18) |
C13 | 0.0340 (15) | 0.0311 (15) | 0.0304 (15) | 0.0025 (11) | 0.0135 (12) | −0.0022 (12) |
C14 | 0.0344 (15) | 0.0355 (16) | 0.0309 (16) | 0.0042 (12) | 0.0110 (13) | 0.0009 (13) |
C15 | 0.0393 (17) | 0.055 (2) | 0.051 (2) | 0.0102 (15) | 0.0166 (16) | 0.0088 (17) |
C16 | 0.055 (2) | 0.076 (3) | 0.069 (3) | 0.0275 (19) | 0.028 (2) | 0.008 (2) |
C17 | 0.058 (2) | 0.066 (2) | 0.074 (3) | 0.0295 (18) | 0.015 (2) | 0.017 (2) |
C18 | 0.076 (3) | 0.070 (3) | 0.057 (2) | 0.030 (2) | 0.026 (2) | 0.029 (2) |
C19 | 0.065 (2) | 0.070 (2) | 0.041 (2) | 0.0292 (18) | 0.0238 (18) | 0.0202 (18) |
C20 | 0.0451 (17) | 0.0339 (15) | 0.0327 (17) | −0.0015 (13) | 0.0131 (14) | −0.0082 (13) |
C21 | 0.064 (2) | 0.0510 (19) | 0.0397 (19) | −0.0137 (16) | 0.0236 (17) | −0.0161 (16) |
C22 | 0.083 (3) | 0.068 (3) | 0.059 (2) | −0.011 (2) | 0.028 (2) | −0.034 (2) |
C23 | 0.079 (3) | 0.047 (2) | 0.068 (3) | −0.0145 (18) | 0.019 (2) | −0.0285 (19) |
C24 | 0.077 (3) | 0.047 (2) | 0.067 (3) | −0.0214 (18) | 0.024 (2) | −0.0141 (19) |
C25 | 0.067 (2) | 0.048 (2) | 0.047 (2) | −0.0184 (16) | 0.0279 (18) | −0.0128 (16) |
Ru1—P2i | 2.3668 (13) | C11—C12 | 1.536 (4) |
Ru1—P2 | 2.3669 (12) | C11—H11A | 0.9700 |
Ru1—P1i | 2.3775 (9) | C11—H11B | 0.9700 |
Ru1—P1 | 2.3775 (10) | C12—H12A | 0.9700 |
Ru1—Cl1i | 2.4333 (11) | C12—H12B | 0.9700 |
Ru1—Cl1 | 2.4334 (11) | C13—H13A | 0.9700 |
P1—C13 | 1.849 (3) | C13—H13B | 0.9700 |
P1—C1 | 1.855 (3) | C14—C19 | 1.517 (4) |
P1—C7 | 1.867 (3) | C14—C15 | 1.525 (4) |
P2—C13 | 1.846 (3) | C14—H14 | 0.9800 |
P2—C14 | 1.848 (3) | C15—C16 | 1.528 (4) |
P2—C20 | 1.855 (3) | C15—H15A | 0.9700 |
C1—C2 | 1.525 (4) | C15—H15B | 0.9700 |
C1—C6 | 1.526 (4) | C16—C17 | 1.498 (5) |
C1—H1 | 0.9800 | C16—H16A | 0.9700 |
C2—C3 | 1.523 (4) | C16—H16B | 0.9700 |
C2—H2A | 0.9700 | C17—C18 | 1.510 (5) |
C2—H2B | 0.9700 | C17—H17A | 0.9700 |
C3—C4 | 1.510 (5) | C17—H17B | 0.9700 |
C3—H3A | 0.9700 | C18—C19 | 1.524 (4) |
C3—H3B | 0.9700 | C18—H18A | 0.9700 |
C4—C5 | 1.524 (5) | C18—H18B | 0.9700 |
C4—H4A | 0.9700 | C19—H19A | 0.9700 |
C4—H4B | 0.9700 | C19—H19B | 0.9700 |
C5—C6 | 1.512 (4) | C20—C25 | 1.507 (4) |
C5—H5A | 0.9700 | C20—C21 | 1.518 (4) |
C5—H5B | 0.9700 | C20—H20 | 0.9800 |
C6—H6A | 0.9700 | C21—C22 | 1.519 (4) |
C6—H6B | 0.9700 | C21—H21A | 0.9700 |
C7—C12 | 1.516 (4) | C21—H21B | 0.9700 |
C7—C8 | 1.522 (4) | C22—C23 | 1.495 (5) |
C7—H7 | 0.9800 | C22—H22A | 0.9700 |
C8—C9 | 1.528 (5) | C22—H22B | 0.9700 |
C8—H8A | 0.9700 | C23—C24 | 1.515 (5) |
C8—H8B | 0.9700 | C23—H23A | 0.9700 |
C9—C10 | 1.499 (5) | C23—H23B | 0.9700 |
C9—H9A | 0.9700 | C24—C25 | 1.523 (4) |
C9—H9B | 0.9700 | C24—H24A | 0.9700 |
C10—C11 | 1.502 (5) | C24—H24B | 0.9700 |
C10—H10A | 0.9700 | C25—H25A | 0.9700 |
C10—H10B | 0.9700 | C25—H25B | 0.9700 |
P2i—Ru1—P2 | 180.0 | C12—C11—H11A | 109.2 |
P2i—Ru1—P1i | 71.43 (4) | C10—C11—H11B | 109.2 |
P2—Ru1—P1i | 108.57 (4) | C12—C11—H11B | 109.2 |
P2i—Ru1—P1 | 108.58 (4) | H11A—C11—H11B | 107.9 |
P2—Ru1—P1 | 71.42 (4) | C7—C12—C11 | 110.7 (3) |
P1i—Ru1—P1 | 180.0 | C7—C12—H12A | 109.5 |
P2i—Ru1—Cl1i | 86.35 (3) | C11—C12—H12A | 109.5 |
P2—Ru1—Cl1i | 93.65 (3) | C7—C12—H12B | 109.5 |
P1i—Ru1—Cl1i | 86.09 (3) | C11—C12—H12B | 109.5 |
P1—Ru1—Cl1i | 93.91 (3) | H12A—C12—H12B | 108.1 |
P2i—Ru1—Cl1 | 93.65 (3) | P2—C13—P1 | 97.10 (13) |
P2—Ru1—Cl1 | 86.35 (3) | P2—C13—H13A | 112.3 |
P1i—Ru1—Cl1 | 93.91 (3) | P1—C13—H13A | 112.3 |
P1—Ru1—Cl1 | 86.09 (3) | P2—C13—H13B | 112.3 |
Cl1i—Ru1—Cl1 | 180.0 | P1—C13—H13B | 112.3 |
C13—P1—C1 | 102.87 (13) | H13A—C13—H13B | 109.9 |
C13—P1—C7 | 103.00 (12) | C19—C14—C15 | 110.2 (2) |
C1—P1—C7 | 110.32 (12) | C19—C14—P2 | 119.50 (19) |
C13—P1—Ru1 | 92.54 (9) | C15—C14—P2 | 113.39 (19) |
C1—P1—Ru1 | 119.19 (9) | C19—C14—H14 | 103.9 |
C7—P1—Ru1 | 122.82 (10) | C15—C14—H14 | 103.9 |
C13—P2—C14 | 105.09 (12) | P2—C14—H14 | 103.9 |
C13—P2—C20 | 101.09 (12) | C14—C15—C16 | 109.8 (3) |
C14—P2—C20 | 111.25 (13) | C14—C15—H15A | 109.7 |
C13—P2—Ru1 | 92.95 (9) | C16—C15—H15A | 109.7 |
C14—P2—Ru1 | 116.11 (9) | C14—C15—H15B | 109.7 |
C20—P2—Ru1 | 124.61 (10) | C16—C15—H15B | 109.7 |
C2—C1—C6 | 110.2 (2) | H15A—C15—H15B | 108.2 |
C2—C1—P1 | 116.96 (19) | C17—C16—C15 | 112.1 (3) |
C6—C1—P1 | 114.7 (2) | C17—C16—H16A | 109.2 |
C2—C1—H1 | 104.5 | C15—C16—H16A | 109.2 |
C6—C1—H1 | 104.5 | C17—C16—H16B | 109.2 |
P1—C1—H1 | 104.5 | C15—C16—H16B | 109.2 |
C3—C2—C1 | 110.6 (3) | H16A—C16—H16B | 107.9 |
C3—C2—H2A | 109.5 | C16—C17—C18 | 111.7 (3) |
C1—C2—H2A | 109.5 | C16—C17—H17A | 109.3 |
C3—C2—H2B | 109.5 | C18—C17—H17A | 109.3 |
C1—C2—H2B | 109.5 | C16—C17—H17B | 109.3 |
H2A—C2—H2B | 108.1 | C18—C17—H17B | 109.3 |
C4—C3—C2 | 111.3 (3) | H17A—C17—H17B | 107.9 |
C4—C3—H3A | 109.4 | C17—C18—C19 | 111.4 (3) |
C2—C3—H3A | 109.4 | C17—C18—H18A | 109.3 |
C4—C3—H3B | 109.4 | C19—C18—H18A | 109.3 |
C2—C3—H3B | 109.4 | C17—C18—H18B | 109.3 |
H3A—C3—H3B | 108.0 | C19—C18—H18B | 109.3 |
C3—C4—C5 | 111.2 (3) | H18A—C18—H18B | 108.0 |
C3—C4—H4A | 109.4 | C14—C19—C18 | 110.4 (3) |
C5—C4—H4A | 109.4 | C14—C19—H19A | 109.6 |
C3—C4—H4B | 109.4 | C18—C19—H19A | 109.6 |
C5—C4—H4B | 109.4 | C14—C19—H19B | 109.6 |
H4A—C4—H4B | 108.0 | C18—C19—H19B | 109.6 |
C6—C5—C4 | 112.4 (3) | H19A—C19—H19B | 108.1 |
C6—C5—H5A | 109.1 | C25—C20—C21 | 110.2 (2) |
C4—C5—H5A | 109.1 | C25—C20—P2 | 116.8 (2) |
C6—C5—H5B | 109.1 | C21—C20—P2 | 115.8 (2) |
C4—C5—H5B | 109.1 | C25—C20—H20 | 104.1 |
H5A—C5—H5B | 107.9 | C21—C20—H20 | 104.1 |
C5—C6—C1 | 111.2 (3) | P2—C20—H20 | 104.1 |
C5—C6—H6A | 109.4 | C20—C21—C22 | 111.8 (3) |
C1—C6—H6A | 109.4 | C20—C21—H21A | 109.3 |
C5—C6—H6B | 109.4 | C22—C21—H21A | 109.3 |
C1—C6—H6B | 109.4 | C20—C21—H21B | 109.3 |
H6A—C6—H6B | 108.0 | C22—C21—H21B | 109.3 |
C12—C7—C8 | 110.2 (2) | H21A—C21—H21B | 107.9 |
C12—C7—P1 | 115.1 (2) | C23—C22—C21 | 111.9 (3) |
C8—C7—P1 | 116.3 (2) | C23—C22—H22A | 109.2 |
C12—C7—H7 | 104.6 | C21—C22—H22A | 109.2 |
C8—C7—H7 | 104.6 | C23—C22—H22B | 109.2 |
P1—C7—H7 | 104.6 | C21—C22—H22B | 109.2 |
C7—C8—C9 | 110.9 (3) | H22A—C22—H22B | 107.9 |
C7—C8—H8A | 109.5 | C22—C23—C24 | 112.2 (3) |
C9—C8—H8A | 109.5 | C22—C23—H23A | 109.2 |
C7—C8—H8B | 109.5 | C24—C23—H23A | 109.2 |
C9—C8—H8B | 109.5 | C22—C23—H23B | 109.2 |
H8A—C8—H8B | 108.1 | C24—C23—H23B | 109.2 |
C10—C9—C8 | 111.7 (3) | H23A—C23—H23B | 107.9 |
C10—C9—H9A | 109.3 | C23—C24—C25 | 111.8 (3) |
C8—C9—H9A | 109.3 | C23—C24—H24A | 109.3 |
C10—C9—H9B | 109.3 | C25—C24—H24A | 109.3 |
C8—C9—H9B | 109.3 | C23—C24—H24B | 109.3 |
H9A—C9—H9B | 107.9 | C25—C24—H24B | 109.3 |
C9—C10—C11 | 111.5 (3) | H24A—C24—H24B | 107.9 |
C9—C10—H10A | 109.3 | C20—C25—C24 | 111.2 (3) |
C11—C10—H10A | 109.3 | C20—C25—H25A | 109.4 |
C9—C10—H10B | 109.3 | C24—C25—H25A | 109.4 |
C11—C10—H10B | 109.3 | C20—C25—H25B | 109.4 |
H10A—C10—H10B | 108.0 | C24—C25—H25B | 109.4 |
C10—C11—C12 | 112.0 (3) | H25A—C25—H25B | 108.0 |
C10—C11—H11A | 109.2 | ||
P2i—Ru1—P1—C13 | −163.49 (8) | Ru1—P1—C7—C8 | −138.9 (2) |
P2—Ru1—P1—C13 | 16.51 (8) | C12—C7—C8—C9 | −56.9 (4) |
Cl1i—Ru1—P1—C13 | 109.05 (9) | P1—C7—C8—C9 | 169.7 (2) |
Cl1—Ru1—P1—C13 | −70.95 (9) | C7—C8—C9—C10 | 56.1 (5) |
P2i—Ru1—P1—C1 | 90.25 (11) | C8—C9—C10—C11 | −54.5 (5) |
P2—Ru1—P1—C1 | −89.75 (11) | C9—C10—C11—C12 | 54.2 (5) |
Cl1i—Ru1—P1—C1 | 2.78 (11) | C8—C7—C12—C11 | 56.4 (4) |
Cl1—Ru1—P1—C1 | −177.21 (11) | P1—C7—C12—C11 | −169.6 (2) |
P2i—Ru1—P1—C7 | −56.24 (11) | C10—C11—C12—C7 | −55.5 (4) |
P2—Ru1—P1—C7 | 123.76 (11) | C14—P2—C13—P1 | −97.58 (14) |
Cl1i—Ru1—P1—C7 | −143.71 (11) | C20—P2—C13—P1 | 146.61 (12) |
Cl1—Ru1—P1—C7 | 36.30 (11) | Ru1—P2—C13—P1 | 20.48 (10) |
P1i—Ru1—P2—C13 | 163.46 (8) | C1—P1—C13—P2 | 100.35 (13) |
P1—Ru1—P2—C13 | −16.55 (8) | C7—P1—C13—P2 | −144.92 (12) |
Cl1i—Ru1—P2—C13 | −109.45 (9) | Ru1—P1—C13—P2 | −20.37 (10) |
Cl1—Ru1—P2—C13 | 70.55 (8) | C13—P2—C14—C19 | −49.6 (3) |
P1i—Ru1—P2—C14 | −88.15 (10) | C20—P2—C14—C19 | 59.0 (3) |
P1—Ru1—P2—C14 | 91.85 (10) | Ru1—P2—C14—C19 | −150.7 (2) |
Cl1i—Ru1—P2—C14 | −1.05 (10) | C13—P2—C14—C15 | 177.7 (2) |
Cl1—Ru1—P2—C14 | 178.94 (10) | C20—P2—C14—C15 | −73.7 (2) |
P1i—Ru1—P2—C20 | 57.82 (11) | Ru1—P2—C14—C15 | 76.7 (2) |
P1—Ru1—P2—C20 | −122.18 (11) | C19—C14—C15—C16 | 57.9 (4) |
Cl1i—Ru1—P2—C20 | 144.91 (11) | P2—C14—C15—C16 | −165.2 (2) |
Cl1—Ru1—P2—C20 | −35.09 (11) | C14—C15—C16—C17 | −56.0 (4) |
C13—P1—C1—C2 | 56.4 (2) | C15—C16—C17—C18 | 54.2 (4) |
C7—P1—C1—C2 | −52.9 (3) | C16—C17—C18—C19 | −54.1 (4) |
Ru1—P1—C1—C2 | 156.78 (19) | C15—C14—C19—C18 | −58.4 (4) |
C13—P1—C1—C6 | −172.3 (2) | P2—C14—C19—C18 | 167.6 (2) |
C7—P1—C1—C6 | 78.4 (2) | C17—C18—C19—C14 | 56.2 (4) |
Ru1—P1—C1—C6 | −71.9 (2) | C13—P2—C20—C25 | −179.9 (2) |
C6—C1—C2—C3 | 57.6 (4) | C14—P2—C20—C25 | 69.0 (3) |
P1—C1—C2—C3 | −169.0 (2) | Ru1—P2—C20—C25 | −78.4 (3) |
C1—C2—C3—C4 | −57.5 (4) | C13—P2—C20—C21 | 47.8 (2) |
C2—C3—C4—C5 | 54.8 (4) | C14—P2—C20—C21 | −63.4 (3) |
C3—C4—C5—C6 | −53.4 (4) | Ru1—P2—C20—C21 | 149.24 (19) |
C4—C5—C6—C1 | 54.2 (4) | C25—C20—C21—C22 | 56.3 (4) |
C2—C1—C6—C5 | −56.1 (3) | P2—C20—C21—C22 | −168.3 (2) |
P1—C1—C6—C5 | 169.4 (2) | C20—C21—C22—C23 | −54.4 (4) |
C13—P1—C7—C12 | −168.2 (2) | C21—C22—C23—C24 | 52.2 (4) |
C1—P1—C7—C12 | −59.0 (3) | C22—C23—C24—C25 | −52.7 (4) |
Ru1—P1—C7—C12 | 90.1 (2) | C21—C20—C25—C24 | −56.5 (4) |
C13—P1—C7—C8 | −37.2 (3) | P2—C20—C25—C24 | 168.6 (2) |
C1—P1—C7—C8 | 72.0 (2) | C23—C24—C25—C20 | 55.0 (4) |
Symmetry code: (i) −x+1, −y+2, −z. |