Di­chloro({N-[2-(di­phenyl­phosphino-κP)benzyl]benzylamino}­di­phenyl­phosphine-κP)palladium(II) toluene solvate

The title compound, [PdCl₂(C₃₈H₃₃NP₂)]·C₇H₈, crystallizes with an accompanying toluene solvent mol­ecule. Important geometrical parameters are Pd—P = 2.2556 (8) and 2.2749 (8) Å, Pd—Cl = 2.3521 (9) and 2.3338 (8) Å, P—Pd—P = 96.31 (3)°, and Cl—Pd—Cl = 89.59 (3)°.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.005 Å
• R factor = 0.041
• wR factor = 0.088
• Data-to-parameter ratio = 21.3

checkCIF/PLATON results

No syntax errors found





Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.00 Ratio
PLAT230_ALERT_2_C Hirshfeld Test Diff for    C50    -   C64     ..       6.40 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Pd     -   Cl2     ..       6.08 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Pd     -   P2      ..       5.22 su
PLAT244_ALERT_4_C Low  Solvent U(eq) as Compared to Neighbors  for        C02
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C02    -C03           1.37 Ang.
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         21

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   7 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: SMART-NT (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 1998); data reduction: SAINT-Plus and XPREP (Bruker, 1998); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Berndt, 2001); software used to prepare material for publication: WinGX (Farrugia, 1999).

(III)

Crystal data

C38H33Cl2NP2Pd·C7H8	F(000) = 1712
Mr = 835.03	Dx = 1.397 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 1002 reflections
a = 13.261 (3) Å	θ = 2.9–25.8°
b = 21.510 (4) Å	µ = 0.72 mm^−1
c = 13.978 (3) Å	T = 293 K
β = 95.30 (3)°	Rectangular block, yellow
V = 3970.0 (14) Å^3	0.54 × 0.18 × 0.16 mm
Z = 4

Data collection

Bruker SMART CCD 1K diffractometer	6070 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.047
ω scans	θmax = 28.3°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Bruker, 1998)	h = −17→17
Tmin = 0.699, Tmax = 0.894	k = −28→18
27177 measured reflections	l = −18→15
9803 independent reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.041	w = 1/[σ^2(Fo^2) + (0.036P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.088	(Δ/σ)max = 0.001
S = 0.98	Δρmax = 0.37 e Å^−3
9803 reflections	Δρmin = −0.59 e Å^−3
461 parameters

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pd	0.267295 (15)	0.254284 (9)	0.126220 (14)	0.03323 (7)
P1	0.15571 (5)	0.31675 (3)	0.04101 (5)	0.03078 (16)
P2	0.26069 (5)	0.17525 (3)	0.01766 (5)	0.03548 (17)
Cl1	0.37127 (6)	0.18594 (4)	0.22255 (6)	0.0557 (2)
Cl2	0.28178 (6)	0.32741 (4)	0.25008 (5)	0.0540 (2)
N	0.17706 (16)	0.32996 (9)	−0.07318 (14)	0.0334 (5)
C46	0.1770 (2)	0.17723 (13)	−0.09472 (19)	0.0380 (7)
C22	−0.0273 (2)	0.25405 (13)	−0.0210 (2)	0.0428 (7)
H22	−0.012	0.2602	−0.0839	0.051*
C31	0.1565 (2)	0.40477 (12)	−0.20917 (19)	0.0382 (7)
CN1	0.1049 (2)	0.36818 (13)	−0.13536 (18)	0.0390 (7)
HN1A	0.0705	0.3968	−0.0956	0.047*
HN1B	0.0541	0.3412	−0.1681	0.047*
C45	0.1141 (2)	0.12739 (14)	−0.1236 (2)	0.0494 (8)
H45	0.1115	0.0928	−0.0839	0.059*
C21	0.03464 (19)	0.27883 (12)	0.05401 (19)	0.0326 (6)
C25	−0.0758 (3)	0.23615 (16)	0.1647 (2)	0.0599 (9)
H25	−0.0926	0.2309	0.2273	0.072*
CN2	0.2387 (2)	0.28607 (12)	−0.12506 (18)	0.0365 (6)
HN2A	0.2984	0.2744	−0.0835	0.044*
HN2B	0.2611	0.3067	−0.1811	0.044*
C11	0.1419 (2)	0.39565 (12)	0.08379 (18)	0.0363 (6)
C41	0.1808 (2)	0.22843 (13)	−0.15636 (19)	0.0377 (7)
C26	0.0099 (2)	0.26922 (14)	0.1478 (2)	0.0457 (7)
H26	0.0514	0.2852	0.1993	0.055*
C16	0.0513 (2)	0.41974 (14)	0.1075 (2)	0.0485 (8)
H16	−0.0059	0.3946	0.1047	0.058*
C51	0.2241 (2)	0.10366 (13)	0.0723 (2)	0.0421 (7)
C42	0.1227 (2)	0.22782 (15)	−0.2439 (2)	0.0498 (8)
H42	0.1268	0.2612	−0.2857	0.06*
C12	0.2257 (3)	0.43441 (14)	0.0878 (2)	0.0504 (8)
H12	0.2873	0.4189	0.0716	0.06*
C61	0.3838 (2)	0.16336 (13)	−0.0281 (2)	0.0411 (7)
C56	0.2879 (3)	0.05275 (14)	0.0848 (2)	0.0530 (8)
H56	0.3537	0.0554	0.0671	0.064*
C52	0.1270 (3)	0.09906 (17)	0.1022 (3)	0.0704 (11)
H52	0.0836	0.1331	0.0967	0.085*
C62	0.3942 (3)	0.12028 (17)	−0.0999 (2)	0.0648 (10)
H62	0.3394	0.0958	−0.1228	0.078*
C13	0.2188 (3)	0.49565 (15)	0.1156 (2)	0.0671 (10)
H13	0.2756	0.5212	0.1183	0.081*
C23	−0.1124 (2)	0.21990 (16)	−0.0030 (2)	0.0580 (9)
H23	−0.1534	0.203	−0.054	0.07*
C36	0.2434 (2)	0.43794 (15)	−0.1854 (2)	0.0563 (9)
H36	0.2704	0.4391	−0.1216	0.068*
C35	0.2920 (3)	0.46983 (17)	−0.2543 (3)	0.0711 (11)
H35	0.3511	0.4919	−0.2368	0.085*
C33	0.1637 (3)	0.43692 (17)	−0.3729 (2)	0.0727 (11)
H33	0.1353	0.437	−0.4362	0.087*
C32	0.1163 (3)	0.40479 (14)	−0.3037 (2)	0.0550 (9)
H32	0.0568	0.3831	−0.3212	0.066*
C44	0.0554 (2)	0.12893 (16)	−0.2109 (2)	0.0594 (9)
H44	0.0132	0.0956	−0.2292	0.071*
C55	0.2550 (3)	−0.00199 (16)	0.1232 (3)	0.0741 (11)
H55	0.2983	−0.036	0.1305	0.089*
C24	−0.1366 (2)	0.21087 (17)	0.0896 (3)	0.0651 (10)
H24	−0.1936	0.1879	0.1013	0.078*
C14	0.1285 (4)	0.51863 (16)	0.1393 (2)	0.0748 (12)
H14	0.1238	0.5599	0.1581	0.09*
C15	0.0453 (3)	0.48154 (16)	0.1355 (2)	0.0679 (10)
H15	−0.016	0.4976	0.1517	0.081*
C02	0.6808 (3)	0.3810 (2)	0.0153 (4)	0.0835 (12)
C64	0.5663 (3)	0.1509 (3)	−0.1071 (3)	0.0982 (18)
H64	0.6279	0.1468	−0.1333	0.118*
C43	0.0594 (3)	0.17919 (16)	−0.2704 (2)	0.0608 (9)
H43	0.0193	0.1804	−0.3286	0.073*
C34	0.2519 (3)	0.46846 (16)	−0.3486 (3)	0.0711 (11)
H34	0.2847	0.4889	−0.3956	0.085*
C54	0.1603 (4)	−0.0061 (2)	0.1501 (3)	0.0902 (14)
H54	0.1387	−0.0432	0.1756	0.108*
C63	0.4871 (3)	0.1137 (2)	−0.1378 (3)	0.0901 (15)
H63	0.495	0.0837	−0.1844	0.108*
C48	0.4654 (2)	0.20058 (16)	0.0021 (2)	0.0591 (9)
H48	0.4594	0.2301	0.0498	0.071*
C05	0.5251 (5)	0.3759 (3)	−0.1290 (4)	0.126 (2)
H05	0.472	0.3739	−0.1772	0.151*
C50	0.5555 (3)	0.1940 (2)	−0.0382 (3)	0.0818 (13)
H50	0.6099	0.2196	−0.0178	0.098*
C04	0.6134 (6)	0.3464 (2)	−0.1403 (4)	0.1197 (19)
H04	0.6207	0.3247	−0.1967	0.144*
C07	0.5915 (4)	0.4112 (2)	0.0238 (3)	0.0972 (15)
H07	0.5835	0.4341	0.079	0.117*
C53	0.0954 (3)	0.0434 (2)	0.1404 (3)	0.0921 (14)
H53	0.0302	0.0398	0.1592	0.11*
C03	0.6917 (4)	0.3482 (2)	−0.0701 (5)	0.1021 (15)
H03	0.7521	0.3279	−0.0786	0.123*
C06	0.5139 (4)	0.4084 (3)	−0.0474 (4)	0.1144 (17)
H06	0.4532	0.4287	−0.04	0.137*
C01	0.7670 (3)	0.3861 (2)	0.0922 (4)	0.1282 (19)
H01A	0.7967	0.4267	0.0901	0.192*
H01B	0.8171	0.3552	0.0818	0.192*
H01C	0.7424	0.3797	0.1539	0.192*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pd	0.02933 (10)	0.03490 (13)	0.03490 (12)	0.00409 (10)	−0.00003 (8)	0.00107 (10)
P1	0.0298 (4)	0.0294 (4)	0.0332 (4)	0.0024 (3)	0.0033 (3)	0.0004 (3)
P2	0.0343 (4)	0.0316 (4)	0.0410 (4)	0.0051 (3)	0.0055 (3)	0.0025 (3)
Cl1	0.0531 (5)	0.0522 (5)	0.0581 (5)	0.0123 (4)	−0.0157 (4)	0.0070 (4)
Cl2	0.0589 (5)	0.0587 (5)	0.0423 (4)	0.0116 (4)	−0.0070 (4)	−0.0108 (4)
N	0.0335 (12)	0.0315 (12)	0.0355 (12)	0.0058 (10)	0.0044 (10)	0.0037 (10)
C46	0.0379 (16)	0.0361 (16)	0.0401 (16)	0.0061 (13)	0.0042 (13)	−0.0064 (13)
C22	0.0389 (15)	0.0458 (18)	0.0442 (16)	0.0006 (15)	0.0061 (13)	0.0024 (15)
C31	0.0463 (17)	0.0306 (15)	0.0372 (16)	0.0060 (13)	0.0011 (13)	0.0044 (13)
CN1	0.0368 (16)	0.0409 (16)	0.0388 (16)	0.0064 (14)	0.0001 (13)	0.0032 (13)
C45	0.0492 (19)	0.0392 (17)	0.059 (2)	0.0046 (15)	0.0022 (16)	−0.0023 (15)
C21	0.0301 (14)	0.0306 (14)	0.0373 (16)	0.0039 (12)	0.0032 (12)	0.0039 (12)
C25	0.053 (2)	0.077 (3)	0.053 (2)	−0.0042 (19)	0.0176 (17)	0.0144 (18)
CN2	0.0378 (15)	0.0372 (15)	0.0353 (15)	0.0072 (13)	0.0085 (12)	0.0047 (13)
C11	0.0482 (17)	0.0306 (15)	0.0301 (15)	0.0036 (14)	0.0035 (13)	0.0016 (12)
C41	0.0406 (16)	0.0383 (16)	0.0344 (16)	0.0101 (13)	0.0051 (13)	−0.0038 (13)
C26	0.0402 (16)	0.0535 (19)	0.0436 (17)	0.0006 (14)	0.0049 (14)	0.0035 (14)
C16	0.0560 (19)	0.0389 (17)	0.0513 (19)	0.0102 (16)	0.0093 (16)	−0.0003 (15)
C51	0.0492 (18)	0.0365 (17)	0.0413 (17)	−0.0003 (14)	0.0078 (14)	0.0016 (13)
C42	0.059 (2)	0.0454 (18)	0.0448 (18)	0.0083 (16)	0.0039 (16)	−0.0040 (15)
C12	0.062 (2)	0.0433 (19)	0.0458 (18)	−0.0047 (17)	0.0039 (16)	−0.0036 (15)
C61	0.0389 (16)	0.0416 (17)	0.0442 (17)	0.0134 (14)	0.0119 (14)	0.0072 (14)
C56	0.067 (2)	0.0406 (18)	0.0507 (19)	0.0049 (17)	0.0036 (16)	0.0064 (15)
C52	0.073 (3)	0.057 (2)	0.086 (3)	−0.002 (2)	0.033 (2)	0.006 (2)
C62	0.059 (2)	0.081 (3)	0.056 (2)	0.019 (2)	0.0151 (18)	−0.0012 (19)
C13	0.093 (3)	0.041 (2)	0.066 (2)	−0.015 (2)	0.005 (2)	−0.0025 (18)
C23	0.0427 (19)	0.066 (2)	0.064 (2)	−0.0121 (17)	−0.0009 (16)	−0.0043 (18)
C36	0.065 (2)	0.055 (2)	0.0463 (19)	−0.0123 (18)	−0.0060 (16)	0.0090 (16)
C35	0.072 (2)	0.068 (2)	0.073 (3)	−0.025 (2)	0.002 (2)	0.022 (2)
C33	0.106 (3)	0.067 (2)	0.043 (2)	−0.018 (2)	−0.006 (2)	0.0159 (18)
C32	0.068 (2)	0.051 (2)	0.0438 (19)	−0.0140 (17)	−0.0079 (16)	0.0086 (16)
C44	0.054 (2)	0.049 (2)	0.072 (2)	−0.0010 (17)	−0.0120 (18)	−0.0146 (19)
C55	0.108 (3)	0.042 (2)	0.071 (3)	0.008 (2)	0.004 (2)	0.0131 (19)
C24	0.044 (2)	0.070 (2)	0.083 (3)	−0.0174 (18)	0.0145 (19)	0.008 (2)
C14	0.128 (4)	0.0323 (19)	0.064 (2)	0.006 (2)	0.011 (2)	−0.0081 (17)
C15	0.093 (3)	0.046 (2)	0.067 (2)	0.026 (2)	0.020 (2)	−0.0008 (18)
C02	0.068 (3)	0.069 (3)	0.113 (4)	−0.006 (2)	0.008 (3)	0.029 (3)
C64	0.068 (3)	0.137 (5)	0.097 (4)	0.046 (3)	0.050 (3)	0.070 (3)
C43	0.063 (2)	0.061 (2)	0.055 (2)	0.0101 (19)	−0.0157 (17)	−0.0110 (18)
C34	0.099 (3)	0.058 (2)	0.058 (2)	−0.015 (2)	0.017 (2)	0.0181 (19)
C54	0.131 (4)	0.058 (3)	0.084 (3)	−0.021 (3)	0.020 (3)	0.018 (2)
C63	0.089 (3)	0.123 (4)	0.062 (3)	0.049 (3)	0.031 (3)	0.004 (2)
C48	0.0433 (19)	0.053 (2)	0.083 (3)	0.0066 (17)	0.0129 (18)	0.0128 (18)
C05	0.118 (5)	0.113 (5)	0.141 (6)	−0.003 (4)	−0.021 (4)	0.008 (4)
C50	0.048 (2)	0.085 (3)	0.117 (4)	0.009 (2)	0.028 (2)	0.038 (3)
C04	0.162 (6)	0.078 (4)	0.117 (5)	−0.007 (4)	0.000 (4)	−0.001 (3)
C07	0.079 (3)	0.125 (4)	0.089 (3)	0.018 (3)	0.015 (3)	0.025 (3)
C53	0.095 (3)	0.080 (3)	0.108 (3)	−0.022 (3)	0.043 (3)	0.019 (3)
C03	0.105 (4)	0.055 (3)	0.150 (5)	−0.001 (3)	0.032 (4)	0.012 (3)
C06	0.086 (4)	0.139 (5)	0.117 (4)	0.014 (3)	0.003 (3)	0.010 (4)
C01	0.080 (3)	0.121 (4)	0.177 (5)	0.000 (3)	−0.024 (3)	0.022 (4)

Geometric parameters (Å, º)

Pd—P1	2.2556 (8)	C62—C63	1.393 (5)
Pd—P2	2.2749 (8)	C62—H62	0.9300
Pd—Cl2	2.3338 (8)	C13—C14	1.365 (5)
Pd—Cl1	2.3521 (9)	C13—H13	0.9300
P1—N	1.671 (2)	C23—C24	1.376 (4)
P1—C11	1.814 (3)	C23—H23	0.9300
P1—C21	1.825 (3)	C36—C35	1.389 (4)
P2—C51	1.805 (3)	C36—H36	0.9300
P2—C61	1.826 (3)	C35—C34	1.375 (4)
P2—C46	1.838 (3)	C35—H35	0.9300
N—CN1	1.481 (3)	C33—C34	1.368 (5)
N—CN2	1.481 (3)	C33—C32	1.386 (4)
C46—C45	1.395 (4)	C33—H33	0.9300
C46—C41	1.402 (4)	C32—H32	0.9300
C22—C21	1.378 (4)	C44—C43	1.368 (4)
C22—C23	1.389 (4)	C44—H44	0.9300
C22—H22	0.9300	C55—C54	1.346 (5)
C31—C36	1.370 (4)	C55—H55	0.9300
C31—C32	1.378 (4)	C24—H24	0.9300
C31—CN1	1.511 (4)	C14—C15	1.359 (5)
CN1—HN1A	0.9700	C14—H14	0.9300
CN1—HN1B	0.9700	C15—H15	0.9300
C45—C44	1.386 (4)	C02—C07	1.365 (5)
C45—H45	0.9300	C02—C03	1.404 (6)
C21—C26	1.396 (4)	C02—C01	1.499 (6)
C25—C24	1.375 (5)	C64—C50	1.354 (6)
C25—C26	1.379 (4)	C64—C63	1.358 (6)
C25—H25	0.9300	C64—H64	0.9300
CN2—C41	1.502 (4)	C43—H43	0.9300
CN2—HN2A	0.9700	C34—H34	0.9300
CN2—HN2B	0.9700	C54—C53	1.367 (6)
C11—C16	1.376 (4)	C54—H54	0.9300
C11—C12	1.386 (4)	C63—H63	0.9300
C41—C42	1.384 (4)	C48—C50	1.375 (4)
C26—H26	0.9300	C48—H48	0.9300
C16—C15	1.390 (4)	C05—C04	1.353 (7)
C16—H16	0.9300	C05—C06	1.357 (6)
C51—C56	1.385 (4)	C05—H05	0.9300
C51—C52	1.393 (4)	C50—H50	0.9300
C42—C43	1.371 (4)	C04—C03	1.362 (7)
C42—H42	0.9300	C04—H04	0.9300
C12—C13	1.379 (4)	C07—C06	1.366 (6)
C12—H12	0.9300	C07—H07	0.9300
C61—C48	1.380 (4)	C53—H53	0.9300
C61—C62	1.382 (4)	C03—H03	0.9300
C56—C55	1.381 (4)	C06—H06	0.9300
C56—H56	0.9300	C01—H01A	0.9600
C52—C53	1.392 (5)	C01—H01B	0.9600
C52—H52	0.9300	C01—H01C	0.9600
P1—Pd—P2	96.31 (3)	C63—C62—H62	120.2
P1—Pd—Cl2	89.73 (3)	C14—C13—C12	119.8 (4)
P2—Pd—Cl2	173.65 (3)	C14—C13—H13	120.1
P1—Pd—Cl1	174.78 (3)	C12—C13—H13	120.1
P2—Pd—Cl1	84.21 (3)	C24—C23—C22	120.6 (3)
Cl2—Pd—Cl1	89.59 (3)	C24—C23—H23	119.7
N—P1—C11	100.78 (11)	C22—C23—H23	119.7
N—P1—C21	113.55 (12)	C31—C36—C35	121.5 (3)
C11—P1—C21	105.57 (12)	C31—C36—H36	119.2
N—P1—Pd	116.42 (8)	C35—C36—H36	119.2
C11—P1—Pd	117.68 (9)	C34—C35—C36	119.4 (3)
C21—P1—Pd	102.80 (9)	C34—C35—H35	120.3
C51—P2—C61	108.22 (13)	C36—C35—H35	120.3
C51—P2—C46	102.53 (13)	C34—C33—C32	120.5 (3)
C61—P2—C46	101.10 (13)	C34—C33—H33	119.8
C51—P2—Pd	110.51 (9)	C32—C33—H33	119.8
C61—P2—Pd	110.97 (10)	C31—C32—C33	120.6 (3)
C46—P2—Pd	122.40 (9)	C31—C32—H32	119.7
CN1—N—CN2	115.0 (2)	C33—C32—H32	119.7
CN1—N—P1	119.84 (16)	C43—C44—C45	120.3 (3)
CN2—N—P1	120.59 (17)	C43—C44—H44	119.8
C45—C46—C41	118.7 (3)	C45—C44—H44	119.8
C45—C46—P2	121.8 (2)	C54—C55—C56	120.0 (4)
C41—C46—P2	119.4 (2)	C54—C55—H55	120
C21—C22—C23	120.3 (3)	C56—C55—H55	120
C21—C22—H22	119.9	C25—C24—C23	119.4 (3)
C23—C22—H22	119.9	C25—C24—H24	120.3
C36—C31—C32	118.3 (3)	C23—C24—H24	120.3
C36—C31—CN1	122.0 (3)	C15—C14—C13	120.4 (3)
C32—C31—CN1	119.7 (3)	C15—C14—H14	119.8
N—CN1—C31	112.4 (2)	C13—C14—H14	119.8
N—CN1—HN1A	109.1	C14—C15—C16	120.3 (3)
C31—CN1—HN1A	109.1	C14—C15—H15	119.9
N—CN1—HN1B	109.1	C16—C15—H15	119.9
C31—CN1—HN1B	109.1	C07—C02—C03	118.1 (5)
HN1A—CN1—HN1B	107.9	C07—C02—C01	120.8 (5)
C44—C45—C46	120.6 (3)	C03—C02—C01	121.0 (5)
C44—C45—H45	119.7	C50—C64—C63	119.9 (4)
C46—C45—H45	119.7	C50—C64—H64	120
C22—C21—C26	118.8 (3)	C63—C64—H64	120
C22—C21—P1	124.4 (2)	C44—C43—C42	119.7 (3)
C26—C21—P1	116.4 (2)	C44—C43—H43	120.2
C24—C25—C26	120.5 (3)	C42—C43—H43	120.2
C24—C25—H25	119.7	C33—C34—C35	119.6 (3)
C26—C25—H25	119.7	C33—C34—H34	120.2
N—CN2—C41	112.2 (2)	C35—C34—H34	120.2
N—CN2—HN2A	109.2	C55—C54—C53	121.1 (4)
C41—CN2—HN2A	109.2	C55—C54—H54	119.5
N—CN2—HN2B	109.2	C53—C54—H54	119.5
C41—CN2—HN2B	109.2	C64—C63—C62	120.4 (4)
HN2A—CN2—HN2B	107.9	C64—C63—H63	119.8
C16—C11—C12	118.5 (3)	C62—C63—H63	119.8
C16—C11—P1	123.3 (2)	C50—C48—C61	120.1 (4)
C12—C11—P1	118.1 (2)	C50—C48—H48	119.9
C42—C41—C46	119.2 (3)	C61—C48—H48	119.9
C42—C41—CN2	119.5 (3)	C04—C05—C06	120.2 (6)
C46—C41—CN2	121.0 (2)	C04—C05—H05	119.9
C25—C26—C21	120.4 (3)	C06—C05—H05	119.9
C25—C26—H26	119.8	C64—C50—C48	121.0 (4)
C21—C26—H26	119.8	C64—C50—H50	119.5
C11—C16—C15	120.2 (3)	C48—C50—H50	119.5
C11—C16—H16	119.9	C05—C04—C03	120.8 (6)
C15—C16—H16	119.9	C05—C04—H04	119.6
C56—C51—C52	118.5 (3)	C03—C04—H04	119.6
C56—C51—P2	122.9 (2)	C02—C07—C06	121.1 (5)
C52—C51—P2	118.6 (2)	C02—C07—H07	119.4
C43—C42—C41	121.6 (3)	C06—C07—H07	119.4
C43—C42—H42	119.2	C54—C53—C52	119.9 (4)
C41—C42—H42	119.2	C54—C53—H53	120
C13—C12—C11	120.8 (3)	C52—C53—H53	120
C13—C12—H12	119.6	C04—C03—C02	119.7 (5)
C11—C12—H12	119.6	C04—C03—H03	120.2
C48—C61—C62	118.9 (3)	C02—C03—H03	120.2
C48—C61—P2	120.8 (2)	C05—C06—C07	120.1 (6)
C62—C61—P2	120.0 (2)	C05—C06—H06	120
C55—C56—C51	120.8 (3)	C07—C06—H06	120
C55—C56—H56	119.6	C02—C01—H01A	109.5
C51—C56—H56	119.6	C02—C01—H01B	109.5
C53—C52—C51	119.7 (4)	H01A—C01—H01B	109.5
C53—C52—H52	120.1	C02—C01—H01C	109.5
C51—C52—H52	120.1	H01A—C01—H01C	109.5
C61—C62—C63	119.7 (4)	H01B—C01—H01C	109.5
C61—C62—H62	120.2
Cl2—Pd—P1—C11	11.15 (10)	Cl1—Pd—P2—C46	172.76 (11)
Cl2—Pd—P1—C21	−104.32 (9)	P2—C46—C41—CN2	−10.3 (3)
Cl2—Pd—P1—N	130.91 (9)	P1—N—CN2—C41	76.8 (3)
Cl1—Pd—P2—C51	51.98 (11)	C46—C41—CN2—N	−86.6 (3)
Cl1—Pd—P2—C61	−68.08 (10)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
CN1—HN1B···Cl1^i	0.97	2.81	3.709 (3)	155
C64—H64···Cl2^ii	0.93	2.78	3.664 (4)	159

Symmetry codes: (i) x−1/2, −y+1/2, z−1/2; (ii) x+1/2, −y+1/2, z−1/2.