Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806044217/hb2180sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806044217/hb2180Isup2.hkl |
CCDC reference: 627780
Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO; data reduction: PROCESS-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL-Plus (Sheldrick, 1990); software used to prepare material for publication: SHELXL97.
[Zn(C8H4O4)(C18H10N4)] | Z = 2 |
Mr = 511.78 | F(000) = 520 |
Triclinic, P1 | Dx = 1.689 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 5.8461 (12) Å | Cell parameters from 7326 reflections |
b = 10.884 (2) Å | θ = 3.0–27.4° |
c = 16.607 (3) Å | µ = 1.27 mm−1 |
α = 89.79 (3)° | T = 292 K |
β = 80.44 (3)° | Block, yellow |
γ = 75.10 (3)° | 0.31 × 0.29 × 0.27 mm |
V = 1006.1 (4) Å3 |
Rigaku R-AXIS RAPID diffractometer | 4548 independent reflections |
Radiation source: rotorating anode | 3496 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.058 |
Detector resolution: 10.0 pixels mm-1 | θmax = 27.4°, θmin = 3.1° |
ω scans | h = −7→6 |
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) | k = −14→14 |
Tmin = 0.668, Tmax = 0.719 | l = −21→21 |
10000 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.053 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.103 | H-atom parameters constrained |
S = 1.02 | w = 1/[σ2(Fo2) + (0.0316P)2 + 1.2149P] where P = (Fo2 + 2Fc2)/3 |
4548 reflections | (Δ/σ)max = 0.001 |
316 parameters | Δρmax = 0.52 e Å−3 |
0 restraints | Δρmin = −0.49 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
C1 | 0.4950 (6) | 0.5387 (3) | 0.2295 (2) | 0.0285 (8) | |
H1 | 0.3632 | 0.5885 | 0.2645 | 0.034* | |
C2 | 0.4821 (7) | 0.5296 (4) | 0.1465 (2) | 0.0341 (9) | |
H2 | 0.3453 | 0.5733 | 0.1267 | 0.041* | |
C3 | 0.6752 (6) | 0.4548 (3) | 0.0950 (2) | 0.0318 (8) | |
H3 | 0.6689 | 0.4461 | 0.0397 | 0.038* | |
C4 | 0.8807 (6) | 0.3918 (3) | 0.1253 (2) | 0.0260 (8) | |
C5 | 0.8796 (6) | 0.4091 (3) | 0.20893 (19) | 0.0226 (7) | |
C6 | 1.0908 (6) | 0.3493 (3) | 0.24441 (18) | 0.0216 (7) | |
C7 | 1.2666 (6) | 0.3234 (3) | 0.3600 (2) | 0.0270 (8) | |
H7 | 1.2596 | 0.3427 | 0.4150 | 0.032* | |
C8 | 1.4734 (6) | 0.2399 (3) | 0.3172 (2) | 0.0285 (8) | |
H8 | 1.6009 | 0.2033 | 0.3438 | 0.034* | |
C9 | 1.4877 (6) | 0.2121 (3) | 0.2357 (2) | 0.0289 (8) | |
H9 | 1.6242 | 0.1561 | 0.2067 | 0.035* | |
C10 | 1.2951 (6) | 0.2688 (3) | 0.19691 (19) | 0.0249 (7) | |
C11 | 1.2981 (6) | 0.2511 (3) | 0.1094 (2) | 0.0277 (8) | |
C12 | 1.0943 (6) | 0.3102 (3) | 0.0746 (2) | 0.0287 (8) | |
C13 | 1.2946 (7) | 0.2215 (4) | −0.0509 (2) | 0.0321 (9) | |
C14 | 1.3016 (8) | 0.2037 (4) | −0.1360 (2) | 0.0410 (10) | |
H14 | 1.1665 | 0.2387 | −0.1593 | 0.049* | |
C15 | 1.5085 (8) | 0.1346 (4) | −0.1832 (2) | 0.0494 (12) | |
H15 | 1.5134 | 0.1225 | −0.2389 | 0.059* | |
C16 | 1.7138 (9) | 0.0816 (5) | −0.1489 (2) | 0.0539 (12) | |
H16 | 1.8531 | 0.0354 | −0.1823 | 0.065* | |
C17 | 1.7126 (8) | 0.0965 (4) | −0.0677 (2) | 0.0468 (11) | |
H17 | 1.8505 | 0.0612 | −0.0460 | 0.056* | |
C18 | 1.5004 (7) | 0.1663 (4) | −0.0161 (2) | 0.0347 (9) | |
C19 | 0.7198 (5) | 0.3398 (3) | 0.52943 (19) | 0.0200 (7) | |
C20 | 0.8038 (5) | 0.2119 (3) | 0.56427 (19) | 0.0205 (7) | |
C21 | 0.6956 (6) | 0.1165 (3) | 0.5498 (2) | 0.0282 (8) | |
H21 | 0.5769 | 0.1317 | 0.5173 | 0.034* | |
C22 | 0.7628 (7) | −0.0009 (3) | 0.5833 (2) | 0.0327 (8) | |
H22 | 0.6914 | −0.0649 | 0.5727 | 0.039* | |
C23 | 0.9369 (6) | −0.0231 (3) | 0.6328 (2) | 0.0311 (8) | |
H23 | 0.9814 | −0.1018 | 0.6560 | 0.037* | |
C24 | 1.0443 (6) | 0.0718 (3) | 0.6477 (2) | 0.0279 (8) | |
H24 | 1.1619 | 0.0563 | 0.6807 | 0.033* | |
C25 | 0.9790 (6) | 0.1901 (3) | 0.61420 (19) | 0.0217 (7) | |
C26 | 1.0936 (6) | 0.2931 (3) | 0.6337 (2) | 0.0253 (7) | |
N1 | 0.6864 (5) | 0.4795 (3) | 0.26031 (16) | 0.0236 (6) | |
N2 | 1.0790 (5) | 0.3763 (3) | 0.32434 (16) | 0.0238 (6) | |
N3 | 1.0899 (5) | 0.2953 (3) | −0.00518 (17) | 0.0327 (7) | |
N4 | 1.5014 (5) | 0.1810 (3) | 0.06476 (18) | 0.0347 (7) | |
O1 | 0.7469 (4) | 0.3419 (2) | 0.45269 (13) | 0.0270 (5) | |
O2 | 0.6281 (4) | 0.4342 (2) | 0.57844 (13) | 0.0251 (5) | |
O3 | 1.1586 (4) | 0.3595 (2) | 0.57504 (14) | 0.0255 (5) | |
O4 | 1.1146 (6) | 0.3094 (3) | 0.70472 (17) | 0.0599 (9) | |
Zn1 | 0.73539 (7) | 0.49682 (4) | 0.38454 (2) | 0.01995 (12) |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.0282 (19) | 0.027 (2) | 0.0272 (18) | −0.0043 (15) | −0.0022 (15) | 0.0017 (15) |
C2 | 0.033 (2) | 0.040 (2) | 0.032 (2) | −0.0094 (17) | −0.0135 (17) | 0.0070 (17) |
C3 | 0.038 (2) | 0.037 (2) | 0.0218 (17) | −0.0105 (17) | −0.0083 (16) | −0.0004 (16) |
C4 | 0.0304 (19) | 0.0275 (19) | 0.0209 (16) | −0.0081 (15) | −0.0055 (14) | 0.0037 (14) |
C5 | 0.0281 (18) | 0.0248 (18) | 0.0168 (15) | −0.0114 (15) | −0.0024 (14) | 0.0009 (13) |
C6 | 0.0255 (18) | 0.0233 (18) | 0.0168 (15) | −0.0094 (14) | −0.0010 (13) | 0.0011 (13) |
C7 | 0.033 (2) | 0.029 (2) | 0.0223 (17) | −0.0135 (16) | −0.0061 (15) | 0.0031 (15) |
C8 | 0.0298 (19) | 0.029 (2) | 0.0288 (18) | −0.0083 (15) | −0.0106 (15) | 0.0073 (15) |
C9 | 0.0292 (19) | 0.026 (2) | 0.0288 (18) | −0.0042 (15) | −0.0021 (15) | −0.0010 (15) |
C10 | 0.0305 (19) | 0.0271 (19) | 0.0187 (16) | −0.0108 (15) | −0.0039 (14) | −0.0011 (14) |
C11 | 0.033 (2) | 0.028 (2) | 0.0221 (17) | −0.0095 (16) | −0.0024 (15) | −0.0021 (15) |
C12 | 0.034 (2) | 0.033 (2) | 0.0201 (17) | −0.0131 (16) | −0.0017 (15) | −0.0005 (15) |
C13 | 0.040 (2) | 0.040 (2) | 0.0178 (17) | −0.0158 (18) | 0.0000 (15) | −0.0046 (15) |
C14 | 0.053 (3) | 0.050 (3) | 0.0199 (18) | −0.014 (2) | −0.0043 (17) | −0.0018 (17) |
C15 | 0.066 (3) | 0.058 (3) | 0.0215 (19) | −0.017 (2) | 0.002 (2) | −0.0091 (19) |
C16 | 0.056 (3) | 0.065 (3) | 0.032 (2) | −0.011 (2) | 0.010 (2) | −0.016 (2) |
C17 | 0.043 (3) | 0.057 (3) | 0.032 (2) | −0.005 (2) | 0.0038 (19) | −0.009 (2) |
C18 | 0.045 (2) | 0.035 (2) | 0.0237 (18) | −0.0132 (18) | 0.0016 (17) | −0.0045 (16) |
C19 | 0.0143 (16) | 0.0232 (18) | 0.0239 (17) | −0.0062 (13) | −0.0050 (13) | 0.0033 (14) |
C20 | 0.0200 (17) | 0.0202 (17) | 0.0196 (15) | −0.0039 (13) | −0.0001 (13) | −0.0003 (13) |
C21 | 0.0308 (19) | 0.031 (2) | 0.0266 (18) | −0.0131 (16) | −0.0088 (15) | 0.0038 (15) |
C22 | 0.041 (2) | 0.027 (2) | 0.037 (2) | −0.0191 (17) | −0.0070 (17) | 0.0055 (16) |
C23 | 0.036 (2) | 0.0214 (19) | 0.034 (2) | −0.0042 (16) | −0.0047 (16) | 0.0065 (15) |
C24 | 0.0292 (19) | 0.028 (2) | 0.0280 (18) | −0.0064 (15) | −0.0103 (15) | 0.0087 (15) |
C25 | 0.0227 (17) | 0.0238 (18) | 0.0193 (16) | −0.0086 (14) | −0.0015 (13) | −0.0003 (13) |
C26 | 0.0250 (18) | 0.0247 (19) | 0.0281 (18) | −0.0051 (14) | −0.0123 (15) | 0.0027 (15) |
N1 | 0.0268 (15) | 0.0245 (16) | 0.0207 (14) | −0.0091 (12) | −0.0038 (12) | 0.0003 (12) |
N2 | 0.0298 (16) | 0.0244 (16) | 0.0187 (14) | −0.0101 (12) | −0.0034 (12) | −0.0008 (11) |
N3 | 0.0396 (18) | 0.0415 (19) | 0.0185 (14) | −0.0135 (15) | −0.0044 (13) | −0.0015 (13) |
N4 | 0.0350 (18) | 0.0396 (19) | 0.0257 (16) | −0.0073 (15) | 0.0017 (13) | −0.0070 (14) |
O1 | 0.0361 (14) | 0.0239 (13) | 0.0187 (11) | −0.0033 (10) | −0.0054 (10) | 0.0057 (10) |
O2 | 0.0225 (12) | 0.0234 (13) | 0.0282 (12) | −0.0044 (10) | −0.0029 (10) | −0.0050 (10) |
O3 | 0.0267 (13) | 0.0249 (13) | 0.0269 (12) | −0.0109 (10) | −0.0034 (10) | −0.0007 (10) |
O4 | 0.110 (3) | 0.061 (2) | 0.0361 (16) | −0.055 (2) | −0.0403 (17) | 0.0137 (15) |
Zn1 | 0.0226 (2) | 0.0218 (2) | 0.01601 (18) | −0.00655 (15) | −0.00352 (14) | −0.00003 (14) |
C1—N1 | 1.321 (4) | C15—C16 | 1.402 (6) |
C1—C2 | 1.397 (5) | C15—H15 | 0.9300 |
C1—H1 | 0.9300 | C16—C17 | 1.356 (6) |
C2—C3 | 1.372 (5) | C16—H16 | 0.9300 |
C2—H2 | 0.9300 | C17—C18 | 1.421 (5) |
C3—C4 | 1.394 (5) | C17—H17 | 0.9300 |
C3—H3 | 0.9300 | C18—N4 | 1.353 (4) |
C4—C5 | 1.401 (4) | C19—O2 | 1.258 (4) |
C4—C12 | 1.464 (5) | C19—O1 | 1.259 (4) |
C5—N1 | 1.353 (4) | C19—C20 | 1.500 (4) |
C5—C6 | 1.456 (5) | C20—C21 | 1.388 (5) |
C6—N2 | 1.347 (4) | C20—C25 | 1.396 (5) |
C6—C10 | 1.404 (4) | C21—C22 | 1.380 (5) |
C7—N2 | 1.332 (4) | C21—H21 | 0.9300 |
C7—C8 | 1.395 (5) | C22—C23 | 1.386 (5) |
C7—H7 | 0.9300 | C22—H22 | 0.9300 |
C8—C9 | 1.372 (5) | C23—C24 | 1.382 (5) |
C8—H8 | 0.9300 | C23—H23 | 0.9300 |
C9—C10 | 1.395 (5) | C24—C25 | 1.388 (5) |
C9—H9 | 0.9300 | C24—H24 | 0.9300 |
C10—C11 | 1.464 (4) | C25—C26 | 1.507 (5) |
C11—N4 | 1.338 (4) | C26—O4 | 1.224 (4) |
C11—C12 | 1.413 (5) | C26—O3 | 1.276 (4) |
C12—N3 | 1.341 (4) | Zn1—N1 | 2.145 (3) |
C13—N3 | 1.364 (5) | Zn1—N2 | 2.178 (3) |
C13—C18 | 1.414 (5) | Zn1—O1 | 2.020 (2) |
C13—C14 | 1.419 (5) | Zn1—O2i | 2.051 (2) |
C14—C15 | 1.366 (6) | Zn1—O3ii | 1.981 (2) |
C14—H14 | 0.9300 | ||
N1—C1—C2 | 122.9 (3) | C18—C17—H17 | 120.0 |
N1—C1—H1 | 118.6 | N4—C18—C13 | 121.6 (3) |
C2—C1—H1 | 118.6 | N4—C18—C17 | 119.4 (4) |
C3—C2—C1 | 118.6 (3) | C13—C18—C17 | 119.0 (3) |
C3—C2—H2 | 120.7 | O2—C19—O1 | 126.0 (3) |
C1—C2—H2 | 120.7 | O2—C19—C20 | 118.1 (3) |
C2—C3—C4 | 120.0 (3) | O1—C19—C20 | 116.0 (3) |
C2—C3—H3 | 120.0 | C21—C20—C25 | 119.9 (3) |
C4—C3—H3 | 120.0 | C21—C20—C19 | 119.0 (3) |
C3—C4—C5 | 117.3 (3) | C25—C20—C19 | 121.0 (3) |
C3—C4—C12 | 123.6 (3) | C22—C21—C20 | 120.5 (3) |
C5—C4—C12 | 119.1 (3) | C22—C21—H21 | 119.7 |
N1—C5—C4 | 122.7 (3) | C20—C21—H21 | 119.7 |
N1—C5—C6 | 117.0 (3) | C21—C22—C23 | 119.8 (3) |
C4—C5—C6 | 120.3 (3) | C21—C22—H22 | 120.1 |
N2—C6—C10 | 122.4 (3) | C23—C22—H22 | 120.1 |
N2—C6—C5 | 116.5 (3) | C24—C23—C22 | 119.9 (3) |
C10—C6—C5 | 121.1 (3) | C24—C23—H23 | 120.1 |
N2—C7—C8 | 121.9 (3) | C22—C23—H23 | 120.1 |
N2—C7—H7 | 119.0 | C23—C24—C25 | 120.9 (3) |
C8—C7—H7 | 119.0 | C23—C24—H24 | 119.6 |
C9—C8—C7 | 119.7 (3) | C25—C24—H24 | 119.6 |
C9—C8—H8 | 120.2 | C24—C25—C20 | 119.0 (3) |
C7—C8—H8 | 120.2 | C24—C25—C26 | 119.7 (3) |
C8—C9—C10 | 119.2 (3) | C20—C25—C26 | 121.3 (3) |
C8—C9—H9 | 120.4 | O4—C26—O3 | 124.1 (3) |
C10—C9—H9 | 120.4 | O4—C26—C25 | 118.2 (3) |
C9—C10—C6 | 117.8 (3) | O3—C26—C25 | 117.6 (3) |
C9—C10—C11 | 123.4 (3) | C1—N1—C5 | 118.4 (3) |
C6—C10—C11 | 118.7 (3) | C1—N1—Zn1 | 126.0 (2) |
N4—C11—C12 | 122.5 (3) | C5—N1—Zn1 | 115.3 (2) |
N4—C11—C10 | 117.3 (3) | C7—N2—C6 | 118.9 (3) |
C12—C11—C10 | 120.2 (3) | C7—N2—Zn1 | 126.2 (2) |
N3—C12—C11 | 121.8 (3) | C6—N2—Zn1 | 114.8 (2) |
N3—C12—C4 | 117.8 (3) | C12—N3—C13 | 116.1 (3) |
C11—C12—C4 | 120.4 (3) | C11—N4—C18 | 116.3 (3) |
N3—C13—C18 | 121.6 (3) | C19—O1—Zn1 | 126.6 (2) |
N3—C13—C14 | 118.6 (4) | C19—O2—Zn1i | 123.1 (2) |
C18—C13—C14 | 119.7 (3) | C26—O3—Zn1ii | 111.3 (2) |
C15—C14—C13 | 119.4 (4) | O3ii—Zn1—O1 | 119.18 (10) |
C15—C14—H14 | 120.3 | O3ii—Zn1—O2i | 98.97 (9) |
C13—C14—H14 | 120.3 | O1—Zn1—O2i | 92.38 (10) |
C14—C15—C16 | 121.0 (4) | O3ii—Zn1—N1 | 122.10 (10) |
C14—C15—H15 | 119.5 | O1—Zn1—N1 | 117.20 (10) |
C16—C15—H15 | 119.5 | O2i—Zn1—N1 | 90.78 (10) |
C17—C16—C15 | 121.1 (4) | O3ii—Zn1—N2 | 100.24 (10) |
C17—C16—H16 | 119.5 | O1—Zn1—N2 | 80.99 (10) |
C15—C16—H16 | 119.5 | O2i—Zn1—N2 | 160.54 (10) |
C16—C17—C18 | 119.9 (4) | N1—Zn1—N2 | 76.34 (11) |
C16—C17—H17 | 120.0 | ||
N1—C1—C2—C3 | 0.8 (6) | C21—C20—C25—C24 | 0.9 (5) |
C1—C2—C3—C4 | −1.3 (5) | C19—C20—C25—C24 | 177.4 (3) |
C2—C3—C4—C5 | −0.3 (5) | C21—C20—C25—C26 | −177.7 (3) |
C2—C3—C4—C12 | 179.9 (3) | C19—C20—C25—C26 | −1.2 (5) |
C3—C4—C5—N1 | 2.5 (5) | C24—C25—C26—O4 | −44.3 (5) |
C12—C4—C5—N1 | −177.7 (3) | C20—C25—C26—O4 | 134.3 (4) |
C3—C4—C5—C6 | −178.1 (3) | C24—C25—C26—O3 | 137.0 (3) |
C12—C4—C5—C6 | 1.7 (5) | C20—C25—C26—O3 | −44.4 (4) |
N1—C5—C6—N2 | −4.0 (4) | C2—C1—N1—C5 | 1.3 (5) |
C4—C5—C6—N2 | 176.6 (3) | C2—C1—N1—Zn1 | 175.5 (3) |
N1—C5—C6—C10 | 176.4 (3) | C4—C5—N1—C1 | −3.0 (5) |
C4—C5—C6—C10 | −3.0 (5) | C6—C5—N1—C1 | 177.6 (3) |
N2—C7—C8—C9 | 1.0 (5) | C4—C5—N1—Zn1 | −177.8 (3) |
C7—C8—C9—C10 | 0.4 (5) | C6—C5—N1—Zn1 | 2.8 (4) |
C8—C9—C10—C6 | −2.0 (5) | C8—C7—N2—C6 | −0.8 (5) |
C8—C9—C10—C11 | 176.4 (3) | C8—C7—N2—Zn1 | 175.2 (2) |
N2—C6—C10—C9 | 2.3 (5) | C10—C6—N2—C7 | −0.9 (5) |
C5—C6—C10—C9 | −178.2 (3) | C5—C6—N2—C7 | 179.5 (3) |
N2—C6—C10—C11 | −176.2 (3) | C10—C6—N2—Zn1 | −177.3 (2) |
C5—C6—C10—C11 | 3.4 (5) | C5—C6—N2—Zn1 | 3.1 (4) |
C9—C10—C11—N4 | −3.0 (5) | C11—C12—N3—C13 | −0.9 (5) |
C6—C10—C11—N4 | 175.4 (3) | C4—C12—N3—C13 | 178.2 (3) |
C9—C10—C11—C12 | 179.0 (3) | C18—C13—N3—C12 | −1.3 (5) |
C6—C10—C11—C12 | −2.6 (5) | C14—C13—N3—C12 | −179.2 (3) |
N4—C11—C12—N3 | 2.6 (6) | C12—C11—N4—C18 | −1.8 (5) |
C10—C11—C12—N3 | −179.5 (3) | C10—C11—N4—C18 | −179.7 (3) |
N4—C11—C12—C4 | −176.5 (3) | C13—C18—N4—C11 | −0.5 (5) |
C10—C11—C12—C4 | 1.4 (5) | C17—C18—N4—C11 | 177.9 (4) |
C3—C4—C12—N3 | −0.3 (5) | O2—C19—O1—Zn1 | 17.2 (5) |
C5—C4—C12—N3 | 179.9 (3) | C20—C19—O1—Zn1 | −163.3 (2) |
C3—C4—C12—C11 | 178.9 (3) | O1—C19—O2—Zn1i | 83.3 (4) |
C5—C4—C12—C11 | −1.0 (5) | C20—C19—O2—Zn1i | −96.1 (3) |
N3—C13—C14—C15 | 177.2 (4) | O4—C26—O3—Zn1ii | −6.1 (4) |
C18—C13—C14—C15 | −0.8 (6) | C25—C26—O3—Zn1ii | 172.5 (2) |
C13—C14—C15—C16 | −0.2 (7) | C19—O1—Zn1—O3ii | 31.0 (3) |
C14—C15—C16—C17 | 0.4 (7) | C19—O1—Zn1—O2i | −70.7 (3) |
C15—C16—C17—C18 | 0.4 (7) | C19—O1—Zn1—N1 | −162.8 (2) |
N3—C13—C18—N4 | 2.1 (6) | C19—O1—Zn1—N2 | 127.7 (3) |
C14—C13—C18—N4 | 180.0 (3) | C1—N1—Zn1—O3ii | −81.6 (3) |
N3—C13—C18—C17 | −176.3 (4) | C5—N1—Zn1—O3ii | 92.7 (2) |
C14—C13—C18—C17 | 1.6 (6) | C1—N1—Zn1—O1 | 112.6 (3) |
C16—C17—C18—N4 | −179.8 (4) | C5—N1—Zn1—O1 | −73.1 (2) |
C16—C17—C18—C13 | −1.4 (6) | C1—N1—Zn1—O2i | 19.5 (3) |
O2—C19—C20—C21 | 117.2 (3) | C5—N1—Zn1—O2i | −166.2 (2) |
O1—C19—C20—C21 | −62.2 (4) | C1—N1—Zn1—N2 | −175.3 (3) |
O2—C19—C20—C25 | −59.4 (4) | C5—N1—Zn1—N2 | −0.9 (2) |
O1—C19—C20—C25 | 121.2 (3) | C7—N2—Zn1—O3ii | 61.8 (3) |
C25—C20—C21—C22 | −1.1 (5) | C6—N2—Zn1—O3ii | −122.0 (2) |
C19—C20—C21—C22 | −177.7 (3) | C7—N2—Zn1—O1 | −56.4 (3) |
C20—C21—C22—C23 | 1.0 (5) | C6—N2—Zn1—O1 | 119.7 (2) |
C21—C22—C23—C24 | −0.7 (5) | C7—N2—Zn1—O2i | −127.6 (3) |
C22—C23—C24—C25 | 0.5 (5) | C6—N2—Zn1—O2i | 48.5 (4) |
C23—C24—C25—C20 | −0.6 (5) | C7—N2—Zn1—N1 | −177.4 (3) |
C23—C24—C25—C26 | 178.1 (3) | C6—N2—Zn1—N1 | −1.2 (2) |
Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+2, −y+1, −z+1. |