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The title compound, [Sn4(C4H9)8(C7H3N2O6)4O2], is a cluster built up by inversion symmetry around the central Sn2O2 ring. Both unique SnO3C2 centres have distorted trigonal–bipyramidal geometry with O atoms in the axial positions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806008567/hb2018sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806008567/hb2018Isup2.hkl
Contains datablock I

CCDC reference: 605072

Key indicators

  • Single-crystal X-ray study
  • T = 298 K
  • Mean [sigma](C-C) = 0.014 Å
  • R factor = 0.048
  • wR factor = 0.149
  • Data-to-parameter ratio = 14.6

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.95 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.19 Ratio PLAT220_ALERT_2_C Large Non-Solvent O Ueq(max)/Ueq(min) ... 2.53 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.45 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O2 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for Sn1 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N1 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N2 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C25 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C29 PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 14 PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C17 - C18 ... 1.38 Ang. PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C20 - C21 ... 1.42 Ang.
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 13 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 10 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXL97.

Octabutyl-1κ2C,2κ2C,3κ2C,4κ2C-di-µ2-3,5-dinitrobenzoato- 1:2κ2O:O';3:4κ2O:O'-bis(3,5-dinitrobenzoato)-1κO,4κO-di-µ3-oxo- 1:2:3κ3O:O:O;2:3:4κ3O:O:O-tetratin(IV) top
Crystal data top
[Sn4(C4H9)8(C7H3N2O6)4O2]Z = 1
Mr = 1808.11F(000) = 908
Triclinic, P1Dx = 1.613 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.705 (2) ÅCell parameters from 3347 reflections
b = 13.333 (3) Åθ = 2.4–25.0°
c = 14.360 (3) ŵ = 1.41 mm1
α = 68.892 (3)°T = 298 K
β = 78.297 (3)°Block, colourless
γ = 80.285 (3)°0.46 × 0.40 × 0.37 mm
V = 1862.0 (7) Å3
Data collection top
Bruker SMART CCD
diffractometer
6473 independent reflections
Radiation source: fine-focus sealed tube4391 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.028
φ and ω scansθmax = 25.0°, θmin = 1.8°
Absorption correction: multi-scan
(SADABS; Bruker, 1998)
h = 1112
Tmin = 0.564, Tmax = 0.624k = 1515
9788 measured reflectionsl = 1716
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.048Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.149H-atom parameters constrained
S = 1.01 w = 1/[σ2(Fo2) + (0.0672P)2 + 5.5003P]
where P = (Fo2 + 2Fc2)/3
6473 reflections(Δ/σ)max = 0.001
442 parametersΔρmax = 1.03 e Å3
1138 restraintsΔρmin = 0.93 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.93792 (5)0.25076 (4)0.04339 (4)0.04818 (19)
Sn20.92654 (5)0.49788 (4)0.11367 (3)0.04630 (18)
N10.4648 (9)0.2985 (8)0.5355 (7)0.088 (2)
N20.6709 (9)0.0557 (7)0.5353 (7)0.085 (2)
N30.9865 (9)0.1835 (8)0.4806 (6)0.0826 (19)
N41.1790 (8)0.4945 (7)0.4917 (6)0.0710 (17)
O10.8861 (5)0.2147 (5)0.2135 (4)0.0627 (12)
O20.7962 (6)0.3739 (5)0.2242 (4)0.0668 (13)
O30.4501 (9)0.3920 (7)0.4888 (7)0.129 (3)
O40.4032 (8)0.2553 (7)0.6147 (6)0.121 (3)
O50.6046 (9)0.0935 (6)0.6169 (6)0.124 (3)
O60.7363 (8)0.1084 (6)0.4884 (7)0.113 (3)
O71.0057 (6)0.3101 (5)0.1204 (4)0.0622 (13)
O80.9585 (7)0.1513 (5)0.1130 (5)0.0769 (14)
O90.9385 (10)0.0998 (8)0.4292 (6)0.120 (3)
O101.0028 (8)0.2150 (7)0.5709 (5)0.105 (2)
O111.1965 (7)0.5212 (6)0.5821 (5)0.093 (2)
O121.2025 (7)0.5468 (6)0.4452 (5)0.0877 (19)
O130.9660 (5)0.4039 (4)0.0229 (4)0.0514 (11)
C10.8096 (8)0.2698 (7)0.2576 (6)0.0533 (14)
C20.7299 (8)0.2188 (7)0.3568 (6)0.0580 (16)
C30.6418 (8)0.2824 (7)0.4015 (6)0.0633 (17)
H30.63380.35730.37250.076*
C40.5657 (8)0.2310 (7)0.4908 (6)0.0652 (18)
C50.5751 (9)0.1230 (8)0.5372 (7)0.0739 (19)
H50.52400.09090.59820.089*
C60.6645 (9)0.0621 (7)0.4896 (7)0.0674 (18)
C70.7422 (8)0.1086 (7)0.4007 (6)0.0613 (17)
H70.80230.06590.37060.074*
C80.9950 (9)0.2405 (8)0.1609 (6)0.0644 (16)
C91.0310 (9)0.2752 (7)0.2752 (6)0.0632 (16)
C100.9972 (9)0.2138 (8)0.3238 (7)0.0697 (17)
H100.95720.15140.28760.084*
C111.0245 (9)0.2477 (8)0.4273 (6)0.0662 (17)
C121.0860 (9)0.3363 (8)0.4838 (7)0.0671 (17)
H121.10470.35680.55380.080*
C131.1190 (9)0.3937 (7)0.4318 (6)0.0635 (17)
C141.0917 (8)0.3650 (7)0.3300 (6)0.0614 (16)
H141.11440.40670.29750.074*
C151.1005 (9)0.1362 (8)0.0739 (7)0.0800 (19)
H15A1.07400.06480.09080.096*
H15B1.16220.14920.01230.096*
C161.1663 (10)0.1345 (10)0.1548 (8)0.101 (2)
H16A1.11330.10320.21930.121*
H16B1.17440.20840.14760.121*
C171.3020 (12)0.0700 (11)0.1564 (11)0.139 (4)
H17A1.34990.09060.08860.166*
H17B1.34770.08850.19880.166*
C181.2949 (16)0.0400 (11)0.1924 (13)0.170 (6)
H18A1.38000.07710.19120.255*
H18B1.24960.05850.15060.255*
H18C1.25030.06110.26050.255*
C190.7423 (8)0.2508 (7)0.0366 (7)0.0659 (15)
H19A0.69470.31310.05190.079*
H19B0.73470.26040.03230.079*
C200.6794 (10)0.1529 (7)0.1048 (9)0.095 (2)
H20A0.65270.16190.17030.113*
H20B0.60180.15420.07920.113*
C210.7449 (11)0.0473 (8)0.1220 (9)0.101 (3)
H21A0.82070.04610.14980.121*
H21B0.77520.04050.05590.121*
C220.6869 (13)0.0523 (9)0.1850 (12)0.139 (5)
H22A0.74930.11350.18650.209*
H22B0.61490.05760.15720.209*
H22C0.65870.05080.25240.209*
C231.0653 (7)0.4341 (7)0.2125 (6)0.0616 (17)
H23A1.04960.47320.25990.074*
H23B1.05200.35930.25130.074*
C241.2005 (8)0.4381 (8)0.1653 (7)0.079 (2)
H24A1.21820.51310.13780.095*
H24B1.21240.41160.10900.095*
C251.2977 (8)0.3749 (9)0.2327 (7)0.087 (3)
H25A1.29710.40900.28220.104*
H25B1.27280.30260.26900.104*
C261.4307 (10)0.3669 (12)0.1772 (10)0.127 (4)
H26A1.48780.32490.22420.191*
H26B1.45750.43800.14320.191*
H26C1.43250.33250.12850.191*
C270.7487 (8)0.5954 (7)0.0920 (6)0.067 (2)
H27A0.76860.66670.04640.080*
H27B0.70450.56590.05660.080*
C280.6551 (8)0.6110 (9)0.1786 (7)0.083 (2)
H28A0.69400.64720.21140.100*
H28B0.63680.54060.22720.100*
C290.5288 (9)0.6764 (9)0.1496 (8)0.095 (3)
H29A0.54560.75030.11020.114*
H29B0.49800.64740.10640.114*
C300.4270 (12)0.6779 (13)0.2338 (11)0.158 (6)
H30A0.35150.71990.20830.237*
H30B0.45450.70950.27570.237*
H30C0.40810.60530.27300.237*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.0516 (3)0.0487 (3)0.0374 (3)0.0035 (2)0.0026 (2)0.0122 (2)
Sn20.0478 (3)0.0512 (3)0.0318 (3)0.0015 (2)0.0041 (2)0.0116 (2)
N10.082 (4)0.083 (4)0.071 (4)0.004 (3)0.021 (3)0.011 (3)
N20.084 (4)0.072 (4)0.073 (4)0.010 (3)0.010 (3)0.006 (3)
N30.099 (4)0.093 (4)0.059 (3)0.022 (3)0.008 (3)0.026 (3)
N40.080 (4)0.077 (4)0.049 (3)0.004 (3)0.002 (3)0.022 (3)
O10.063 (2)0.068 (2)0.048 (2)0.001 (2)0.006 (2)0.019 (2)
O20.065 (2)0.063 (2)0.054 (2)0.006 (2)0.015 (2)0.012 (2)
O30.125 (5)0.103 (5)0.113 (5)0.018 (4)0.035 (4)0.025 (4)
O40.113 (5)0.115 (5)0.091 (5)0.003 (4)0.055 (4)0.025 (4)
O50.140 (6)0.083 (5)0.096 (5)0.017 (4)0.027 (5)0.012 (4)
O60.118 (5)0.068 (4)0.113 (5)0.005 (4)0.027 (5)0.008 (4)
O70.076 (3)0.065 (3)0.042 (2)0.006 (2)0.003 (2)0.021 (2)
O80.092 (3)0.077 (3)0.056 (3)0.015 (3)0.002 (2)0.019 (2)
O90.161 (6)0.133 (6)0.084 (5)0.065 (5)0.010 (5)0.040 (4)
O100.139 (6)0.130 (5)0.060 (4)0.038 (5)0.017 (4)0.036 (4)
O110.110 (5)0.098 (5)0.052 (4)0.019 (4)0.010 (3)0.010 (3)
O120.108 (5)0.085 (4)0.067 (4)0.018 (4)0.001 (4)0.025 (3)
O130.055 (2)0.054 (2)0.041 (2)0.006 (2)0.0008 (19)0.0168 (19)
C10.054 (3)0.058 (3)0.043 (3)0.001 (2)0.001 (2)0.018 (2)
C20.060 (3)0.061 (3)0.046 (3)0.008 (3)0.004 (3)0.014 (3)
C30.064 (3)0.062 (3)0.052 (3)0.004 (3)0.008 (3)0.015 (3)
C40.065 (3)0.067 (3)0.052 (3)0.003 (3)0.010 (3)0.018 (3)
C50.073 (3)0.070 (3)0.060 (3)0.009 (3)0.010 (3)0.010 (3)
C60.068 (3)0.062 (3)0.057 (3)0.007 (3)0.005 (3)0.010 (3)
C70.062 (3)0.060 (3)0.052 (3)0.005 (3)0.005 (3)0.015 (3)
C80.076 (3)0.069 (3)0.047 (3)0.008 (3)0.001 (3)0.021 (3)
C90.075 (3)0.074 (3)0.043 (3)0.007 (3)0.005 (3)0.026 (3)
C100.079 (3)0.078 (3)0.051 (3)0.012 (3)0.001 (3)0.023 (3)
C110.079 (3)0.079 (3)0.047 (3)0.009 (3)0.008 (3)0.028 (3)
C120.077 (3)0.080 (3)0.046 (3)0.007 (3)0.002 (3)0.027 (3)
C130.071 (3)0.071 (3)0.047 (3)0.006 (3)0.001 (3)0.023 (3)
C140.070 (3)0.069 (3)0.047 (3)0.005 (3)0.003 (3)0.026 (3)
C150.078 (3)0.077 (3)0.065 (3)0.009 (3)0.001 (3)0.015 (3)
C160.094 (5)0.114 (5)0.078 (4)0.015 (4)0.016 (4)0.022 (4)
C170.124 (6)0.137 (7)0.115 (6)0.020 (6)0.020 (6)0.009 (6)
C180.159 (10)0.146 (10)0.164 (10)0.009 (9)0.008 (9)0.015 (9)
C190.0573 (17)0.070 (3)0.061 (3)0.011 (3)0.005 (3)0.012 (3)
C200.076 (4)0.088 (4)0.095 (4)0.012 (4)0.003 (4)0.006 (4)
C210.089 (4)0.086 (4)0.098 (4)0.012 (4)0.005 (4)0.005 (4)
C220.103 (8)0.106 (8)0.162 (10)0.030 (7)0.014 (8)0.000 (8)
C230.062 (3)0.069 (3)0.047 (3)0.002 (3)0.006 (3)0.017 (3)
C240.072 (4)0.091 (4)0.060 (4)0.001 (4)0.011 (4)0.011 (4)
C250.076 (5)0.102 (6)0.070 (5)0.012 (5)0.014 (4)0.022 (4)
C260.091 (8)0.168 (10)0.109 (8)0.014 (8)0.021 (7)0.039 (8)
C270.056 (4)0.068 (4)0.057 (4)0.004 (3)0.006 (3)0.012 (3)
C280.072 (4)0.088 (4)0.071 (4)0.009 (4)0.003 (4)0.020 (4)
C290.070 (5)0.099 (6)0.093 (6)0.011 (5)0.001 (5)0.021 (5)
C300.099 (9)0.174 (11)0.147 (10)0.027 (8)0.017 (8)0.028 (9)
Geometric parameters (Å, º) top
Sn1—O132.021 (5)C15—C161.467 (12)
Sn1—C192.116 (8)C15—H15A0.9700
Sn1—C152.118 (9)C15—H15B0.9700
Sn1—O72.202 (5)C16—C171.558 (13)
Sn1—O12.281 (5)C16—H16A0.9700
Sn1—O82.949 (6)C16—H16B0.9700
Sn2—O132.055 (5)C17—C181.379 (14)
Sn2—C232.123 (8)C17—H17A0.9700
Sn2—C272.127 (8)C17—H17B0.9700
Sn2—O13i2.151 (5)C18—H18A0.9600
Sn2—O22.277 (5)C18—H18B0.9600
Sn2—O7i2.815 (6)C18—H18C0.9600
N1—O31.183 (10)C19—C201.491 (11)
N1—O41.189 (10)C19—H19A0.9700
N1—C41.481 (12)C19—H19B0.9700
N2—O61.193 (10)C20—C211.423 (12)
N2—O51.220 (10)C20—H20A0.9700
N2—C61.463 (12)C20—H20B0.9700
N3—O101.195 (10)C21—C221.466 (12)
N3—O91.226 (11)C21—H21A0.9700
N3—C111.483 (12)C21—H21B0.9700
N4—O111.199 (9)C22—H22A0.9600
N4—O121.208 (9)C22—H22B0.9600
N4—C131.481 (12)C22—H22C0.9600
C1—O11.238 (9)C23—C241.469 (10)
C1—O21.288 (9)C23—H23A0.9700
C8—O71.290 (10)C23—H23B0.9700
C8—O81.224 (10)C24—C251.502 (11)
O13—Sn2i2.151 (5)C24—H24A0.9700
C1—C21.491 (11)C24—H24B0.9700
C2—C71.369 (11)C25—C261.491 (12)
C2—C31.378 (11)C25—H25A0.9700
C3—C41.382 (11)C25—H25B0.9700
C3—H30.9300C26—H26A0.9600
C4—C51.348 (12)C26—H26B0.9600
C5—C61.383 (12)C26—H26C0.9600
C5—H50.9300C27—C281.484 (10)
C6—C71.371 (11)C27—H27A0.9700
C7—H70.9300C27—H27B0.9700
C8—C91.520 (11)C28—C291.527 (11)
C9—C141.362 (12)C28—H28A0.9700
C9—C101.379 (12)C28—H28B0.9700
C10—C111.372 (12)C29—C301.458 (12)
C10—H100.9300C29—H29A0.9700
C11—C121.357 (12)C29—H29B0.9700
C12—C131.371 (12)C30—H30A0.9600
C12—H120.9300C30—H30B0.9600
C13—C141.353 (11)C30—H30C0.9600
C14—H140.9300
O13—Sn1—C19107.3 (3)C16—C15—H15B108.0
O13—Sn1—C15114.8 (3)Sn1—C15—H15B108.0
C19—Sn1—C15137.7 (4)H15A—C15—H15B107.3
O13—Sn1—O779.4 (2)C15—C16—C17114.5 (9)
C19—Sn1—O797.6 (3)C15—C16—H16A108.6
C15—Sn1—O793.4 (3)C17—C16—H16A108.6
O13—Sn1—O190.7 (2)C15—C16—H16B108.6
C19—Sn1—O189.0 (3)C17—C16—H16B108.6
C15—Sn1—O187.2 (3)H16A—C16—H16B107.6
O7—Sn1—O1169.4 (2)C18—C17—C16111.7 (12)
O13—Sn1—O8127.56 (18)C18—C17—H17A109.3
C19—Sn1—O878.7 (3)C16—C17—H17A109.3
C15—Sn1—O878.6 (3)C18—C17—H17B109.3
O7—Sn1—O848.44 (19)C16—C17—H17B109.3
O1—Sn1—O8141.73 (19)H17A—C17—H17B107.9
O13—Sn2—C23103.9 (3)C17—C18—H18A109.5
O13—Sn2—C27110.4 (3)C17—C18—H18B109.5
C23—Sn2—C27144.1 (3)H18A—C18—H18B109.5
O13—Sn2—O13i76.3 (2)C17—C18—H18C109.5
C23—Sn2—O13i102.8 (3)H18A—C18—H18C109.5
C27—Sn2—O13i95.4 (3)H18B—C18—H18C109.5
O13—Sn2—O288.1 (2)C20—C19—Sn1116.7 (6)
C23—Sn2—O288.6 (3)C20—C19—H19A108.1
C27—Sn2—O282.4 (3)Sn1—C19—H19A108.1
O13i—Sn2—O2162.4 (2)C20—C19—H19B108.1
O13—Sn2—O7i139.97 (18)Sn1—C19—H19B108.1
C23—Sn2—O7i79.4 (3)H19A—C19—H19B107.3
C27—Sn2—O7i81.1 (3)C21—C20—C19121.4 (9)
O13i—Sn2—O7i64.31 (17)C21—C20—H20A107.0
O2—Sn2—O7i131.91 (18)C19—C20—H20A107.0
O3—N1—O4124.5 (10)C21—C20—H20B107.0
O3—N1—C4117.4 (8)C19—C20—H20B107.0
O4—N1—C4118.0 (9)H20A—C20—H20B106.7
O6—N2—O5124.2 (9)C20—C21—C22124.1 (10)
O6—N2—C6117.9 (8)C20—C21—H21A106.3
O5—N2—C6117.9 (9)C22—C21—H21A106.3
O10—N3—O9122.7 (9)C20—C21—H21B106.3
O10—N3—C11119.5 (9)C22—C21—H21B106.3
O9—N3—C11117.8 (8)H21A—C21—H21B106.4
O11—N4—O12124.3 (9)C21—C22—H22A109.5
O11—N4—C13118.9 (8)C21—C22—H22B109.5
O12—N4—C13116.8 (7)H22A—C22—H22B109.5
C1—O1—Sn1127.2 (5)C21—C22—H22C109.5
C1—O2—Sn2132.3 (5)H22A—C22—H22C109.5
C8—O7—Sn1110.8 (5)H22B—C22—H22C109.5
C8—O8—Sn176.7 (5)C24—C23—Sn2116.5 (6)
Sn1—O13—Sn2134.2 (3)C24—C23—H23A108.2
Sn1—O13—Sn2i121.8 (2)Sn2—C23—H23A108.2
Sn2—O13—Sn2i103.7 (2)C24—C23—H23B108.2
O1—C1—O2123.2 (7)Sn2—C23—H23B108.2
O1—C1—C2121.5 (7)H23A—C23—H23B107.3
O2—C1—C2115.2 (7)C23—C24—C25116.2 (8)
C7—C2—C3120.7 (8)C23—C24—H24A108.2
C7—C2—C1119.4 (7)C25—C24—H24A108.2
C3—C2—C1119.8 (8)C23—C24—H24B108.2
C2—C3—C4117.7 (8)C25—C24—H24B108.2
C2—C3—H3121.1H24A—C24—H24B107.4
C4—C3—H3121.1C26—C25—C24113.5 (9)
C5—C4—C3123.6 (8)C26—C25—H25A108.9
C5—C4—N1118.4 (8)C24—C25—H25A108.9
C3—C4—N1117.9 (8)C26—C25—H25B108.9
C4—C5—C6116.8 (8)C24—C25—H25B108.9
C4—C5—H5121.6H25A—C25—H25B107.7
C6—C5—H5121.6C25—C26—H26A109.5
C7—C6—C5122.2 (9)C25—C26—H26B109.5
C7—C6—N2120.1 (8)H26A—C26—H26B109.5
C5—C6—N2117.7 (8)C25—C26—H26C109.5
C2—C7—C6119.0 (8)H26A—C26—H26C109.5
C2—C7—H7120.5H26B—C26—H26C109.5
C6—C7—H7120.5C28—C27—Sn2121.5 (6)
O8—C8—O7124.0 (8)C28—C27—H27A107.0
O8—C8—C9120.2 (8)Sn2—C27—H27A107.0
O7—C8—C9115.8 (8)C28—C27—H27B107.0
C14—C9—C10119.7 (8)Sn2—C27—H27B107.0
C14—C9—C8122.4 (8)H27A—C27—H27B106.7
C10—C9—C8117.9 (8)C27—C28—C29114.2 (8)
C11—C10—C9118.0 (9)C27—C28—H28A108.7
C11—C10—H10121.0C29—C28—H28A108.7
C9—C10—H10121.0C27—C28—H28B108.7
C12—C11—C10123.5 (9)C29—C28—H28B108.7
C12—C11—N3118.0 (8)H28A—C28—H28B107.6
C10—C11—N3118.5 (9)C30—C29—C28115.5 (10)
C11—C12—C13116.2 (8)C30—C29—H29A108.4
C11—C12—H12121.9C28—C29—H29A108.4
C13—C12—H12121.9C30—C29—H29B108.4
C14—C13—C12122.5 (9)C28—C29—H29B108.4
C14—C13—N4120.0 (8)H29A—C29—H29B107.5
C12—C13—N4117.4 (8)C29—C30—H30A109.5
C13—C14—C9120.0 (8)C29—C30—H30B109.5
C13—C14—H14120.0H30A—C30—H30B109.5
C9—C14—H14120.0C29—C30—H30C109.5
C16—C15—Sn1117.0 (7)H30A—C30—H30C109.5
C16—C15—H15A108.0H30B—C30—H30C109.5
Sn1—C15—H15A108.0
Symmetry code: (i) x+2, y+1, z.
 

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