(Di-tert-butyl­methyl­phosphane)(η²-di-tert-butyl­phosphanylphosphin­idene)(triphenyl­phosphane)platinum(0)

The crystal structure of the title compound, [Pt(C₈H₁₈P₂)(C₉H₂₁P)(C₁₈H₁₅P)] or [(Ph₃P)(^tBu₂PMe)Pt(η²-^tBu₂PP)], contains four mol­ecules in the asymmetric unit with slightly different conformations. The P—P distances in the ^tBu₂PP ligands are similar for all four mol­ecules [2.0661 (13)–2.0678 (13) Å] and indicate a multiple character of the P—P bond in the ^tBu₂PP ligand. Mol­ecules of the asymmetric unit can be assembled into a tetra­hedron that fulfils the requirements for a rhombic disphenoid. The coordination of the Pt atom in all four mol­ecules is square planar, with r.m.s. deviations from the PtP₄ planes in the range 0.03–0.05 Å. All planes of the PtP₄ groups are approximately parallel to the ab plane of the unit cell. The structure represents an unusual unsymmetrical platinum phosphin­idene derivative.

S1. Comment

In the course of our studies on the reactivity of phosphanylphosphinidenophosphorane, ^tBu₂P–P═ P^tBu₂(Me), towards platinum(0) complexes, the formation of side-on bonded complexes with the di-tert-butylphosphanylphosphinidene ligand (^tBu₂P═P) has been established (Krautscheid et al., 1997). The reaction of an excess of ^tBu₂PMe with [(Ph₃P)₂Pt(η²-^tBu₂P═P)] yields the title compound, (I), via a ligand-exchange process (Matern et al., 2000) (Fig. 1).

Only one isomer of (I) was found in the reaction mixture on the basis of the ³¹P{¹H} NMR spectrum. This regioselectivity is probably caused by two factors, firstly the steric hindrance of the bulky ^tBu₂P group and the planarity of the P₄Pt systems in (I), and secondly the difference in the trans effects of ^tBu₂P1 and atom P2. Thus, the observed Pt—P3 distance in (I) is longer than Pt—P4 and ^tBu₂PMe is more weakly bonded to the Pt atom than PPh₃. The same phenomenon is observed in [(EtPh₂P)₂Pt(η²-^tBu₂P═P)] (Krautscheid et al., 1997).

To date only three Pt⁰ complexes of this type have been structurally characterized, namely [(EtPh₂P)₂Pt(η²-^tBu₂P═P)] with a P—P distance of 2.071 (1) Å (Krautscheid et al., 1997), [(dppe)Pt(η²-^tBu₂P═P)] with a P—P distance of 2.072 (3) Å (dppe = Ph₂PCH₂CH₂PPh₂; Krautscheid et al., 1998), and [(Ph₃P)(^tBu₂PH)Pt(η²-^tBu₂P═P)] with a P—P distance of 2.067 (3) Å (Krautscheid et al., 2000). Three other complexes with phosphanylphosphinidene ligands, but with different side-on bonded metal centres, have been reported by Cummins and co-workers: [(ArNⁱPr)₃W(η²-Ph₂P═P)] (Ar = 3,5-Me₂C₆H₃) with a P—P distance of 2.097 (2) Å (Fox et al., 2007), [(ArNNp)₃Nb(η²-Ph₂P═P)] (Ar = 3,5-Me₂C₆H₃, Np = neopentyl) with a P—P distance of 2.073 (4) Å [Reference?] and [(ArNNp)₃Nb(η²-tBu₂P═P)] with a P—P distance of 2.089 (2) Å (Figueroa & Cummins, 2004).

The molecular structure of (I) is shown in Fig. 2. The geometry around the Pt atom in (I) is square planar with a small mean deviation from the PtP₄ plane. The P—P distance in the ^tBu₂P═P ligand in all molecules of (I) is significantly shorter than the P—P distances in side-on bonded diphosphenes, e.g. 2.121 (2) Å in [(Ph₃P)₂Pt(η²-PhP═ PPh)]. In the free molecule of Mes*P═PMes*, the P═P double bond is 2.034 (2) Å (Mes* = Please define; Chatt et al., 1982). This distance suggests a multiple P—P bond character in (I) with a multiplicity slightly greater than two. The short P—P distance in the ^tBu₂PP group can most probably be explained by a zwitterionic formula (see scheme). The Pt—PPh₃ (mean 2.302 Å), Pt—P^tBu₂Me (mean 2.323 Å) and Pt—P^tBu₂ distances (mean 2.329 Å; all s.u.'s for the Pt—P bonds are close to 0.001 Å) are in the typical range for trans-(R₃P)₂PtCl₂ [2.319 (1) Å; Johansson & Otto, 2000]. The Pt—P(unsubstituted) distance is significantly longer (mean 2.410 Å).

Molecules of (I) display slightly different conformations (Table 1). The Pt1—P14—C118—C123 torsion angle and analogous angles in the other three molecules are different, at -6.9 (3), -3.0 (3), 7.5 (3) and 3.4 (3)°, respectively, while the P14—Pt1—P13—C117 torsion angle and analogous angles in the other three molecules are 11.87 (14), 11.41 (15), -12.12 (15) and -11.70 (14)°, respectively.

There are only weak C—H···P interactions in each molecule of (I) (Table 2). The molecules of (I) can be assembled into a tetrahedron that nearly fulfils the requirements for a rhombic disphenoid, with two almost perpendicular longer edges [angle 89.95 (1)°] with Pt1—Pt2 = 12.4255 (8) Å and Pt3—Pt4 = 12.4293 (8) Å, and four shorter edges with distances in the range 11.7803 (11)–11.9164 (9) Å. Molecules in each tetrahedron interact through dispersion forces of the tert-butyl groups. The closest contacts between tetrahedra come from dispersion forces of the phenyl rings, but without stacking interactions. Fig. 3 shows the packing of Pt tetrahedra and molecules along the b axis.

S2. Experimental

Compound (I) was obtained by a ligand-exchange method from a di-tert-butylmethyl phospane and bis(triphenylphosphane)(η²-di-tert-butylphosphanylphosphinidene) platinum(0) according to the method of Matern et al. (2000). Single crystals of (I) were obtained by recrystallisation from which solvent? Spectroscopic analysis: ³¹P NMR (85% H₃PO₄ as an external reference standard, δ, p.p.m., J, Hz): 50.60 (P1), -54.98 (P2), 38.48 (P3), 20.34 (P4), ¹J(Pt—P1) = 1819.8, ¹J(Pt—P2) = -71.7, ¹J(Pt—P3) = 3445.4, ¹J(Pt—P4) = 3264.2, ¹J(P1—P2) = -605.5, ²J(P1—P3) = 205.1, ²J(P2—P3) = -17.8, ²J(P2—P4) = 13.6, ²J(P3—P4) = -1.1.

S3. Refinement

All H atoms were positioned geometrically and refined using a riding model, with C—H distances fixed according to temperature and type [Please give values used], with isotropic displacement parameters U_iso(H) = 1.2 (or 1.5 for CH₃ groups) U_eq(C).

Computing details

Data collection: CrysAlis CCD (Oxford Diffraction, 2005); cell refinement: CrysAlis RED (Oxford Diffraction, 2005); data reduction: CrysAlis RED (Oxford Diffraction, 2005); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: PLATON (Spek, 2003).

Figures

	Fig. 1. The reaction scheme for the synthesis of (I).
	Fig. 2. A view of molecule (Ia), showing the atom-labelling scheme, and the tetrahedral assembly of the four molecules. Displacement ellipsoids are drawn at the 50% probability level. H atoms have been omitted for clarity.
	Fig. 3. Views of the packing of (I) along the b axis. (a) Tetrahedra based on Pt atoms. (b) Molecules with H atoms omitted. [Part (b) is missing - please provide it by email with your proof corrections]

(Di-tert-butylmethylphosphane)(η²-di-tert- butylphosphanylphosphinidene)(triphenylphosphane)platinum(0)

Crystal data

[Pt(C8H18P2)(C9H21P)(C18H15P)]	F(000) = 12864
Mr = 793.74	Dx = 1.447 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -C 2yc	Cell parameters from 90443 reflections
a = 29.924 (2) Å	θ = 2.1–32.4°
b = 29.928 (2) Å	µ = 4.05 mm^−1
c = 33.233 (3) Å	T = 120 K
β = 101.646 (9)°	Plate, dark red
V = 29150 (4) Å^3	0.15 × 0.09 × 0.05 mm
Z = 32

Data collection

Kuma KM4 four-axis diffractometer with Sapphire2 CCD detector	20921 reflections with I > 2σ(I)
Detector resolution: 8.1883 pixels mm^-1	Rint = 0.026
ω scans	θmax = 25.1°, θmin = 2.3°
Absorption correction: analytical (CrysAlis RED; Oxford Diffraction, 2006) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by Clark & Reid (1995)	h = −28→35
Tmin = 0.414, Tmax = 0.672	k = −35→32
74063 measured reflections	l = −39→35
25787 independent reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.026	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.068	H-atom parameters constrained
S = 1.09	w = 1/[σ^2(Fo^2) + (0.0381P)^2 + 39.9739P] where P = (Fo^2 + 2Fc^2)/3
25787 reflections	(Δ/σ)max = 0.003
1493 parameters	Δρmax = 2.08 e Å^−3
0 restraints	Δρmin = −0.71 e Å^−3

Special details

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F² for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The observed criterion of F² > σ(F²) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.47982 (1)	0.15104 (1)	0.37178 (1)	0.0149 (1)
P11	0.55423 (3)	0.17625 (3)	0.37667 (3)	0.0173 (3)
P12	0.50620 (3)	0.22680 (3)	0.36802 (3)	0.0230 (3)
P13	0.40328 (3)	0.16987 (3)	0.36674 (3)	0.0175 (3)
P14	0.47776 (3)	0.07423 (3)	0.37580 (3)	0.0170 (3)
C101	0.59644 (12)	0.18023 (12)	0.42842 (11)	0.0223 (11)
C102	0.56866 (14)	0.17182 (15)	0.46229 (11)	0.0309 (14)
C103	0.61520 (14)	0.22812 (13)	0.43335 (13)	0.0322 (12)
C104	0.63613 (13)	0.14722 (13)	0.43370 (12)	0.0262 (11)
C105	0.58410 (12)	0.16379 (12)	0.33261 (11)	0.0200 (11)
C106	0.54783 (13)	0.16964 (14)	0.29279 (11)	0.0267 (12)
C107	0.62350 (13)	0.19647 (13)	0.33206 (12)	0.0254 (12)
C108	0.60136 (13)	0.11538 (12)	0.33396 (11)	0.0237 (11)
C109	0.39214 (13)	0.21288 (12)	0.40597 (12)	0.0241 (11)
C110	0.34247 (13)	0.21361 (14)	0.41207 (13)	0.0291 (12)
C111	0.40490 (15)	0.26024 (13)	0.39446 (15)	0.0371 (16)
C112	0.42276 (14)	0.20050 (14)	0.44782 (12)	0.0320 (12)
C113	0.37314 (13)	0.18682 (13)	0.31255 (11)	0.0242 (12)
C114	0.40060 (14)	0.22260 (14)	0.29464 (13)	0.0314 (12)
C115	0.37125 (14)	0.14436 (14)	0.28639 (12)	0.0301 (12)
C116	0.32377 (14)	0.20352 (15)	0.30934 (13)	0.0352 (14)
C117	0.36680 (12)	0.12333 (12)	0.37789 (12)	0.0227 (11)
C118	0.46247 (12)	0.05263 (12)	0.42336 (11)	0.0185 (11)
C119	0.45770 (12)	0.00686 (13)	0.43065 (12)	0.0238 (12)
C120	0.44656 (13)	−0.00744 (14)	0.46736 (13)	0.0321 (12)
C121	0.44147 (13)	0.02341 (16)	0.49731 (13)	0.0350 (14)
C122	0.44825 (13)	0.06858 (15)	0.49114 (12)	0.0315 (14)
C123	0.45847 (12)	0.08307 (13)	0.45428 (11)	0.0239 (12)
C124	0.53060 (12)	0.04080 (12)	0.37688 (11)	0.0202 (11)
C125	0.56629 (13)	0.04740 (12)	0.41098 (12)	0.0250 (12)
C126	0.60776 (14)	0.02529 (13)	0.41387 (14)	0.0316 (14)
C127	0.61416 (14)	−0.00395 (13)	0.38259 (14)	0.0335 (14)
C128	0.57858 (15)	−0.01135 (13)	0.34983 (14)	0.0342 (16)
C129	0.53700 (14)	0.01067 (12)	0.34696 (13)	0.0281 (12)
C130	0.43901 (12)	0.04665 (11)	0.33246 (11)	0.0197 (11)
C131	0.44688 (14)	0.05577 (12)	0.29273 (11)	0.0260 (11)
C132	0.42027 (15)	0.03583 (13)	0.25832 (12)	0.0316 (14)
C133	0.38492 (15)	0.00722 (13)	0.26238 (13)	0.0332 (12)
C134	0.37622 (14)	−0.00155 (13)	0.30103 (12)	0.0289 (12)
C135	0.40311 (12)	0.01781 (12)	0.33605 (11)	0.0218 (11)
Pt2	0.07441 (1)	0.24022 (1)	0.37239 (1)	0.0138 (1)
P21	0.00227 (3)	0.21384 (3)	0.37681 (3)	0.0155 (3)
P22	0.04682 (3)	0.16437 (3)	0.36638 (3)	0.0205 (3)
P23	0.14899 (3)	0.22206 (3)	0.36770 (3)	0.0166 (3)
P24	0.07696 (3)	0.31701 (3)	0.37628 (3)	0.0158 (3)
C201	−0.01577 (13)	0.20777 (12)	0.42880 (11)	0.0217 (11)
C202	0.02758 (14)	0.21422 (15)	0.46217 (11)	0.0305 (11)
C203	−0.03325 (14)	0.15947 (12)	0.43224 (12)	0.0279 (12)
C204	−0.05243 (14)	0.24097 (12)	0.43623 (12)	0.0261 (12)
C205	−0.04808 (12)	0.22704 (12)	0.33367 (10)	0.0191 (11)
C206	−0.03047 (13)	0.22242 (14)	0.29329 (11)	0.0263 (11)
C207	−0.08732 (12)	0.19388 (13)	0.33336 (12)	0.0248 (12)
C208	−0.06466 (13)	0.27544 (12)	0.33648 (11)	0.0246 (11)
C209	0.17761 (12)	0.17922 (12)	0.40765 (12)	0.0235 (12)
C210	0.23016 (13)	0.18028 (14)	0.41581 (13)	0.0312 (12)
C211	0.16144 (14)	0.13156 (13)	0.39525 (14)	0.0339 (14)
C212	0.16349 (14)	0.19046 (14)	0.44894 (12)	0.0319 (12)
C213	0.15604 (12)	0.20483 (13)	0.31402 (11)	0.0225 (11)
C214	0.12112 (14)	0.16870 (13)	0.29520 (12)	0.0281 (12)
C215	0.14620 (14)	0.24728 (13)	0.28716 (12)	0.0286 (12)
C216	0.20430 (14)	0.18807 (16)	0.31175 (13)	0.0366 (14)
C217	0.18994 (13)	0.26842 (12)	0.37834 (12)	0.0233 (11)
C218	0.11441 (12)	0.34146 (11)	0.42191 (10)	0.0166 (10)
C219	0.11869 (12)	0.38784 (12)	0.42797 (11)	0.0209 (11)
C220	0.14629 (13)	0.40472 (13)	0.46339 (11)	0.0250 (12)
C221	0.16982 (13)	0.37599 (13)	0.49337 (11)	0.0251 (11)
C222	0.16527 (13)	0.33027 (13)	0.48792 (11)	0.0258 (11)
C223	0.13759 (12)	0.31328 (12)	0.45264 (11)	0.0207 (11)
C224	0.02487 (12)	0.34916 (11)	0.38010 (12)	0.0212 (11)
C225	0.00679 (13)	0.34326 (13)	0.41533 (13)	0.0268 (12)
C226	−0.03245 (14)	0.36531 (13)	0.42029 (14)	0.0328 (14)
C227	−0.05508 (14)	0.39342 (13)	0.38940 (15)	0.0348 (14)
C228	−0.03693 (14)	0.40101 (13)	0.35485 (14)	0.0339 (14)
C229	0.00308 (13)	0.37906 (12)	0.34999 (12)	0.0254 (12)
C230	0.09421 (12)	0.34401 (11)	0.33174 (11)	0.0190 (11)
C231	0.06764 (13)	0.33401 (12)	0.29272 (11)	0.0237 (11)
C232	0.07810 (15)	0.35287 (13)	0.25733 (12)	0.0300 (14)
C233	0.11532 (15)	0.38108 (13)	0.26007 (12)	0.0312 (14)
C234	0.14204 (14)	0.39081 (13)	0.29834 (12)	0.0259 (12)
C235	0.13147 (12)	0.37252 (12)	0.33396 (12)	0.0213 (11)
Pt3	0.17972 (1)	−0.00829 (1)	0.13009 (1)	0.0149 (1)
P31	0.20405 (3)	−0.08164 (3)	0.12523 (3)	0.0173 (3)
P32	0.25638 (3)	−0.03538 (3)	0.13470 (3)	0.0236 (3)
P33	0.19943 (3)	0.06723 (3)	0.13525 (3)	0.0175 (3)
P34	0.10196 (3)	−0.00536 (3)	0.12539 (3)	0.0168 (3)
C301	0.19724 (14)	−0.11166 (12)	0.07335 (11)	0.0243 (11)
C302	0.18168 (15)	−0.07663 (13)	0.03956 (12)	0.0304 (14)
C303	0.24382 (14)	−0.12944 (14)	0.06857 (13)	0.0327 (14)
C304	0.16270 (14)	−0.15054 (13)	0.06742 (12)	0.0271 (12)
C305	0.20086 (12)	−0.12158 (12)	0.16920 (11)	0.0197 (11)
C306	0.21517 (14)	−0.09449 (13)	0.20924 (11)	0.0264 (12)
C307	0.23404 (13)	−0.16090 (12)	0.16986 (12)	0.0249 (11)
C308	0.15226 (13)	−0.13873 (13)	0.16718 (12)	0.0242 (12)
C309	0.23418 (13)	0.08696 (12)	0.09646 (12)	0.0241 (11)
C310	0.23328 (14)	0.13820 (12)	0.09030 (13)	0.0276 (12)
C311	0.28432 (14)	0.07195 (14)	0.10907 (15)	0.0369 (14)
C312	0.21313 (14)	0.06565 (13)	0.05459 (12)	0.0307 (12)
C313	0.22785 (13)	0.08565 (12)	0.18959 (12)	0.0245 (11)
C314	0.26745 (14)	0.05421 (14)	0.20828 (12)	0.0303 (12)
C315	0.19096 (14)	0.08191 (14)	0.21546 (12)	0.0310 (12)
C316	0.24584 (16)	0.13388 (14)	0.19280 (14)	0.0380 (16)
C317	0.15066 (13)	0.10569 (12)	0.12355 (12)	0.0228 (11)
C318	0.06975 (12)	0.02063 (11)	0.07795 (10)	0.0192 (11)
C319	0.02250 (13)	0.02708 (12)	0.07030 (12)	0.0235 (11)
C320	0.00008 (14)	0.04612 (13)	0.03336 (12)	0.0311 (12)
C321	0.02428 (15)	0.05768 (13)	0.00357 (12)	0.0329 (14)
C322	0.07089 (15)	0.04978 (13)	0.01001 (12)	0.0315 (14)
C323	0.09356 (14)	0.03142 (12)	0.04688 (11)	0.0238 (11)
C324	0.06828 (12)	−0.05790 (12)	0.12340 (11)	0.0205 (11)
C325	0.06745 (13)	−0.08581 (12)	0.08944 (12)	0.0237 (11)
C326	0.04452 (13)	−0.12666 (13)	0.08629 (13)	0.0304 (12)
C327	0.02213 (13)	−0.13989 (14)	0.11736 (14)	0.0338 (14)
C328	0.02131 (13)	−0.11216 (14)	0.14981 (14)	0.0331 (14)
C329	0.04406 (13)	−0.07108 (13)	0.15329 (12)	0.0260 (12)
C330	0.08357 (12)	0.02345 (12)	0.16855 (11)	0.0193 (11)
C331	0.10170 (13)	0.00633 (13)	0.20822 (12)	0.0252 (11)
C332	0.08961 (13)	0.02511 (15)	0.24302 (12)	0.0312 (14)
C333	0.06048 (14)	0.06181 (15)	0.23915 (13)	0.0328 (14)
C334	0.04274 (13)	0.07943 (13)	0.20024 (12)	0.0286 (12)
C335	0.05439 (12)	0.06045 (12)	0.16495 (12)	0.0218 (11)
Pt4	0.26841 (1)	0.39722 (1)	0.12603 (1)	0.0138 (1)
P41	0.24096 (3)	0.47031 (3)	0.12115 (3)	0.0160 (3)
P42	0.19370 (3)	0.42344 (3)	0.13132 (3)	0.0206 (3)
P43	0.25126 (3)	0.32163 (3)	0.13101 (3)	0.0166 (3)
P44	0.34439 (3)	0.39555 (3)	0.12251 (3)	0.0161 (3)
C401	0.22374 (13)	0.49983 (12)	0.06903 (11)	0.0212 (11)
C402	0.22299 (15)	0.46380 (14)	0.03563 (11)	0.0306 (11)
C403	0.17496 (13)	0.51785 (14)	0.06532 (12)	0.0288 (12)
C404	0.25553 (13)	0.53798 (13)	0.06171 (12)	0.0279 (12)
C405	0.26353 (12)	0.51107 (12)	0.16436 (11)	0.0196 (11)
C406	0.26767 (14)	0.48441 (13)	0.20484 (11)	0.0268 (11)
C407	0.31128 (13)	0.52827 (13)	0.16192 (12)	0.0250 (12)
C408	0.23075 (13)	0.55073 (12)	0.16442 (12)	0.0252 (12)
C409	0.19976 (13)	0.30180 (12)	0.09093 (11)	0.0226 (11)
C410	0.19914 (14)	0.25095 (13)	0.08318 (13)	0.0321 (12)
C411	0.15487 (13)	0.31523 (13)	0.10289 (14)	0.0322 (14)
C412	0.20209 (14)	0.32469 (14)	0.04983 (12)	0.0304 (12)
C413	0.24576 (13)	0.30286 (12)	0.18474 (11)	0.0215 (11)
C414	0.21351 (14)	0.33384 (13)	0.20289 (12)	0.0282 (12)
C415	0.29386 (14)	0.30720 (14)	0.21176 (12)	0.0303 (12)
C416	0.22988 (16)	0.25438 (13)	0.18718 (13)	0.0351 (14)
C417	0.29570 (12)	0.28310 (12)	0.12041 (12)	0.0222 (11)
C418	0.35891 (12)	0.36827 (11)	0.07668 (10)	0.0170 (10)
C419	0.40374 (12)	0.36540 (12)	0.07074 (11)	0.0207 (11)
C420	0.41286 (13)	0.34576 (12)	0.03538 (11)	0.0240 (12)
C421	0.37741 (14)	0.32932 (13)	0.00536 (11)	0.0259 (11)
C422	0.33286 (14)	0.33280 (13)	0.01062 (11)	0.0256 (11)
C423	0.32342 (13)	0.35252 (12)	0.04607 (11)	0.0212 (11)
C424	0.37616 (12)	0.44855 (12)	0.11934 (12)	0.0210 (11)
C425	0.36237 (13)	0.47430 (13)	0.08354 (12)	0.0267 (12)
C426	0.38345 (14)	0.51509 (13)	0.07906 (14)	0.0342 (14)
C427	0.41808 (14)	0.53090 (14)	0.11024 (15)	0.0361 (14)
C428	0.43273 (14)	0.50517 (14)	0.14483 (14)	0.0350 (14)
C429	0.41227 (13)	0.46382 (13)	0.14949 (12)	0.0271 (12)
C430	0.38145 (12)	0.36846 (12)	0.16701 (10)	0.0179 (10)
C431	0.37998 (13)	0.38595 (13)	0.20609 (11)	0.0244 (11)
C432	0.40691 (14)	0.36809 (15)	0.24160 (12)	0.0317 (14)
C433	0.43458 (13)	0.33134 (15)	0.23855 (12)	0.0320 (14)
C434	0.43586 (13)	0.31308 (13)	0.20056 (12)	0.0275 (12)
C435	0.40931 (12)	0.33162 (12)	0.16472 (11)	0.0204 (11)
H10A	0.55470	0.14210	0.45860	0.0460*
H10B	0.54470	0.19450	0.46040	0.0460*
H10C	0.58900	0.17360	0.48930	0.0460*
H10D	0.58980	0.24930	0.43030	0.0490*
H10E	0.63310	0.23400	0.41230	0.0490*
H10F	0.63470	0.23160	0.46070	0.0490*
H10G	0.62420	0.11660	0.43070	0.0390*
H10H	0.65550	0.15090	0.46100	0.0390*
H10I	0.65420	0.15290	0.41270	0.0390*
H10J	0.52190	0.14980	0.29350	0.0400*
H10K	0.56120	0.16210	0.26910	0.0400*
H10L	0.53730	0.20070	0.29050	0.0400*
H10M	0.61240	0.22720	0.33260	0.0380*
H10N	0.63550	0.19180	0.30710	0.0380*
H10O	0.64780	0.19130	0.35620	0.0380*
H10P	0.57570	0.09490	0.33320	0.0360*
H10Q	0.62400	0.11060	0.35930	0.0360*
H10R	0.61540	0.10980	0.31020	0.0360*
H11A	0.32220	0.22260	0.38640	0.0430*
H11B	0.33970	0.23490	0.43380	0.0430*
H11C	0.33390	0.18370	0.41990	0.0430*
H11D	0.38420	0.26970	0.36920	0.0560*
H11E	0.43630	0.26030	0.39020	0.0560*
H11F	0.40230	0.28090	0.41670	0.0560*
H11G	0.41370	0.17120	0.45670	0.0480*
H11H	0.41930	0.22310	0.46830	0.0480*
H11I	0.45470	0.19930	0.44500	0.0480*
H11J	0.40050	0.25050	0.31000	0.0470*
H11K	0.38670	0.22770	0.26570	0.0470*
H11L	0.43210	0.21230	0.29680	0.0470*
H11M	0.35170	0.12220	0.29600	0.0450*
H11N	0.40210	0.13210	0.28890	0.0450*
H11O	0.35880	0.15160	0.25760	0.0450*
H11P	0.30690	0.18230	0.32310	0.0530*
H11Q	0.30880	0.20600	0.28030	0.0530*
H11R	0.32420	0.23290	0.32250	0.0530*
H11S	0.37360	0.11710	0.40740	0.0340*
H11T	0.37290	0.09660	0.36290	0.0340*
H11U	0.33460	0.13170	0.36930	0.0340*
H119	0.46210	−0.01440	0.41060	0.0360*
H120	0.44240	−0.03840	0.47190	0.0480*
H121	0.43330	0.01360	0.52210	0.0530*
H122	0.44590	0.08960	0.51210	0.0380*
H123	0.46280	0.11400	0.45010	0.0290*
H125	0.56210	0.06720	0.43230	0.0300*
H126	0.63170	0.03000	0.43700	0.0380*
H127	0.64270	−0.01850	0.38400	0.0400*
H128	0.58240	−0.03180	0.32890	0.0410*
H129	0.51280	0.00490	0.32420	0.0340*
H131	0.47060	0.07570	0.28950	0.0310*
H132	0.42630	0.04180	0.23180	0.0380*
H133	0.36680	−0.00630	0.23880	0.0390*
H134	0.35180	−0.02080	0.30380	0.0340*
H135	0.39700	0.01140	0.36240	0.0260*
H20A	0.05040	0.19200	0.45850	0.0460*
H20B	0.02010	0.21050	0.48930	0.0460*
H20C	0.03980	0.24430	0.45990	0.0460*
H20D	−0.01000	0.13820	0.42730	0.0420*
H20E	−0.06140	0.15490	0.41170	0.0420*
H20F	−0.03940	0.15470	0.45980	0.0420*
H20G	−0.04300	0.27150	0.43120	0.0390*
H20H	−0.05630	0.23840	0.46470	0.0390*
H20I	−0.08140	0.23420	0.41760	0.0390*
H20J	−0.02070	0.19160	0.29030	0.0390*
H20K	−0.00460	0.24260	0.29390	0.0390*
H20L	−0.05500	0.23020	0.27000	0.0390*
H20M	−0.07590	0.16330	0.33260	0.0370*
H20N	−0.11140	0.19920	0.30910	0.0370*
H20O	−0.09970	0.19800	0.35820	0.0370*
H20P	−0.03950	0.29610	0.33550	0.0370*
H20Q	−0.07510	0.27950	0.36230	0.0370*
H20R	−0.08990	0.28150	0.31330	0.0370*
H21A	0.24050	0.17260	0.39050	0.0470*
H21B	0.24240	0.15860	0.43730	0.0470*
H21C	0.24090	0.21030	0.42480	0.0470*
H21D	0.12800	0.13050	0.38980	0.0510*
H21E	0.17380	0.11090	0.41760	0.0510*
H21F	0.17220	0.12290	0.37040	0.0510*
H21G	0.13010	0.19130	0.44480	0.0470*
H21H	0.17600	0.21970	0.45870	0.0470*
H21I	0.17540	0.16750	0.46930	0.0470*
H21J	0.12700	0.14120	0.31140	0.0420*
H21K	0.12400	0.16270	0.26690	0.0420*
H21L	0.09020	0.17930	0.29540	0.0420*
H21M	0.17010	0.26950	0.29650	0.0430*
H21N	0.11650	0.25960	0.28950	0.0430*
H21O	0.14580	0.23960	0.25840	0.0430*
H21P	0.22700	0.21010	0.32460	0.0550*
H21Q	0.20640	0.18400	0.28290	0.0550*
H21R	0.21010	0.15950	0.32630	0.0550*
H21S	0.17700	0.29500	0.36310	0.0350*
H21T	0.21830	0.26000	0.36980	0.0350*
H21U	0.19640	0.27500	0.40780	0.0350*
H219	0.10270	0.40770	0.40780	0.0250*
H220	0.14920	0.43610	0.46720	0.0300*
H221	0.18890	0.38770	0.51740	0.0300*
H222	0.18110	0.31050	0.50830	0.0310*
H223	0.13430	0.28180	0.44930	0.0250*
H225	0.02170	0.32370	0.43630	0.0320*
H226	−0.04390	0.36130	0.44470	0.0390*
H227	−0.08290	0.40730	0.39200	0.0420*
H228	−0.05160	0.42120	0.33430	0.0410*
H229	0.01540	0.38450	0.32630	0.0310*
H231	0.04240	0.31430	0.29050	0.0290*
H232	0.05960	0.34630	0.23120	0.0360*
H233	0.12250	0.39370	0.23590	0.0380*
H234	0.16770	0.41000	0.30030	0.0310*
H235	0.14990	0.37960	0.36000	0.0250*
H30A	0.20400	−0.05220	0.04260	0.0450*
H30B	0.15180	−0.06470	0.04200	0.0450*
H30C	0.17930	−0.09060	0.01250	0.0450*
H30D	0.25480	−0.15140	0.09020	0.0490*
H30E	0.26560	−0.10460	0.07080	0.0490*
H30F	0.24100	−0.14370	0.04160	0.0490*
H30G	0.17350	−0.17400	0.08760	0.0410*
H30H	0.15960	−0.16270	0.03960	0.0410*
H30I	0.13300	−0.13960	0.07130	0.0410*
H30J	0.19500	−0.06860	0.20860	0.0400*
H30K	0.24670	−0.08420	0.21180	0.0400*
H30L	0.21290	−0.11340	0.23280	0.0400*
H30M	0.22350	−0.18000	0.14590	0.0370*
H30N	0.23530	−0.17840	0.19500	0.0370*
H30O	0.26450	−0.14940	0.16910	0.0370*
H30P	0.14220	−0.15560	0.14170	0.0360*
H30Q	0.13170	−0.11330	0.16780	0.0360*
H30R	0.15170	−0.15820	0.19080	0.0360*
H31A	0.24750	0.15280	0.11610	0.0420*
H31B	0.20160	0.14830	0.08200	0.0420*
H31C	0.25020	0.14600	0.06890	0.0420*
H31D	0.29880	0.08740	0.13430	0.0550*
H31E	0.30050	0.07930	0.08710	0.0550*
H31F	0.28550	0.03960	0.11380	0.0550*
H31G	0.18160	0.07600	0.04570	0.0460*
H31H	0.21340	0.03300	0.05730	0.0460*
H31I	0.23100	0.07440	0.03420	0.0460*
H31J	0.29160	0.05630	0.19230	0.0450*
H31K	0.25620	0.02340	0.20760	0.0450*
H31L	0.27970	0.06300	0.23680	0.0450*
H31M	0.17810	0.05170	0.21290	0.0460*
H31N	0.16670	0.10370	0.20570	0.0460*
H31O	0.20450	0.08790	0.24430	0.0460*
H31P	0.27130	0.13640	0.17840	0.0570*
H31Q	0.25640	0.14180	0.22180	0.0570*
H31R	0.22130	0.15430	0.18030	0.0570*
H31S	0.13730	0.10440	0.09410	0.0340*
H31T	0.16100	0.13620	0.13090	0.0340*
H31U	0.12770	0.09700	0.13930	0.0340*
H319	0.00560	0.01850	0.09030	0.0280*
H320	−0.03190	0.05120	0.02870	0.0370*
H321	0.00900	0.07100	−0.02130	0.0400*
H322	0.08730	0.05690	−0.01080	0.0370*
H323	0.12550	0.02610	0.05110	0.0290*
H325	0.08270	−0.07680	0.06830	0.0280*
H326	0.04410	−0.14540	0.06310	0.0360*
H327	0.00750	−0.16820	0.11590	0.0400*
H328	0.00510	−0.12090	0.17030	0.0400*
H329	0.04310	−0.05210	0.17600	0.0310*
H331	0.12230	−0.01820	0.21120	0.0300*
H332	0.10130	0.01280	0.26940	0.0370*
H333	0.05270	0.07480	0.26290	0.0390*
H334	0.02270	0.10440	0.19760	0.0340*
H335	0.04240	0.07280	0.13860	0.0260*
H40A	0.25350	0.45060	0.03850	0.0460*
H40B	0.21400	0.47750	0.00840	0.0460*
H40C	0.20100	0.44040	0.03880	0.0460*
H40D	0.15490	0.49370	0.07070	0.0430*
H40E	0.16390	0.52950	0.03750	0.0430*
H40F	0.17500	0.54190	0.08530	0.0430*
H40G	0.28700	0.52700	0.06630	0.0420*
H40H	0.25350	0.56250	0.08080	0.0420*
H40I	0.24640	0.54870	0.03340	0.0420*
H40J	0.23730	0.47460	0.20790	0.0400*
H40K	0.28110	0.50350	0.22810	0.0400*
H40L	0.28720	0.45830	0.20410	0.0400*
H40M	0.31020	0.54260	0.13520	0.0370*
H40N	0.33270	0.50320	0.16500	0.0370*
H40O	0.32140	0.55000	0.18390	0.0370*
H40P	0.20030	0.53950	0.16550	0.0380*
H40Q	0.22920	0.56830	0.13930	0.0380*
H40R	0.24190	0.56960	0.18850	0.0380*
H41A	0.22730	0.24210	0.07450	0.0480*
H41B	0.17280	0.24330	0.06160	0.0480*
H41C	0.19700	0.23510	0.10850	0.0480*
H41D	0.15490	0.34750	0.10800	0.0480*
H41E	0.15160	0.29910	0.12780	0.0480*
H41F	0.12930	0.30770	0.08050	0.0480*
H41G	0.22950	0.31470	0.04060	0.0460*
H41H	0.20320	0.35720	0.05360	0.0460*
H41I	0.17500	0.31680	0.02920	0.0460*
H41J	0.18240	0.33100	0.18670	0.0420*
H41K	0.22370	0.36490	0.20200	0.0420*
H41L	0.21390	0.32530	0.23140	0.0420*
H41M	0.31410	0.28490	0.20320	0.0460*
H41N	0.29230	0.30220	0.24060	0.0460*
H41O	0.30580	0.33720	0.20860	0.0460*
H41P	0.24970	0.23450	0.17520	0.0530*
H41Q	0.19840	0.25140	0.17190	0.0530*
H41R	0.23140	0.24620	0.21600	0.0530*
H41S	0.29610	0.28370	0.09100	0.0330*
H41T	0.28910	0.25270	0.12850	0.0330*
H41U	0.32550	0.29250	0.13610	0.0330*
H419	0.42810	0.37690	0.09100	0.0250*
H420	0.44340	0.34360	0.03170	0.0290*
H421	0.38380	0.31570	−0.01870	0.0310*
H422	0.30860	0.32180	−0.00990	0.0310*
H423	0.29270	0.35520	0.04940	0.0250*
H425	0.33850	0.46380	0.06230	0.0320*
H426	0.37410	0.53210	0.05470	0.0410*
H427	0.43150	0.55920	0.10770	0.0430*
H428	0.45700	0.51560	0.16570	0.0420*
H429	0.42300	0.44620	0.17320	0.0320*
H431	0.36030	0.41030	0.20830	0.0290*
H432	0.40640	0.38090	0.26770	0.0380*
H433	0.45270	0.31870	0.26270	0.0380*
H434	0.45470	0.28800	0.19870	0.0330*
H435	0.41040	0.31890	0.13870	0.0240*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.0132 (1)	0.0124 (1)	0.0205 (1)	−0.0001 (1)	0.0064 (1)	−0.0002 (1)
P11	0.0142 (5)	0.0169 (5)	0.0214 (5)	−0.0010 (4)	0.0052 (4)	−0.0022 (4)
P12	0.0186 (5)	0.0128 (5)	0.0393 (6)	−0.0002 (4)	0.0102 (4)	−0.0007 (4)
P13	0.0141 (5)	0.0154 (5)	0.0245 (5)	−0.0001 (4)	0.0078 (4)	−0.0005 (4)
P14	0.0186 (5)	0.0116 (4)	0.0220 (5)	0.0010 (4)	0.0067 (4)	0.0018 (4)
C101	0.019 (2)	0.025 (2)	0.0234 (19)	−0.0038 (16)	0.0057 (15)	−0.0078 (16)
C102	0.026 (2)	0.044 (3)	0.023 (2)	−0.0017 (19)	0.0056 (17)	−0.0074 (18)
C103	0.029 (2)	0.030 (2)	0.036 (2)	−0.0052 (19)	0.0027 (18)	−0.0153 (19)
C104	0.025 (2)	0.030 (2)	0.0224 (19)	0.0014 (17)	0.0017 (16)	−0.0026 (16)
C105	0.0157 (19)	0.023 (2)	0.0227 (19)	−0.0022 (15)	0.0071 (15)	−0.0027 (15)
C106	0.025 (2)	0.033 (2)	0.023 (2)	−0.0006 (18)	0.0070 (16)	0.0007 (17)
C107	0.023 (2)	0.027 (2)	0.028 (2)	−0.0038 (17)	0.0094 (16)	−0.0006 (17)
C108	0.026 (2)	0.023 (2)	0.0243 (19)	−0.0026 (17)	0.0100 (16)	−0.0041 (16)
C109	0.022 (2)	0.0186 (19)	0.036 (2)	0.0006 (16)	0.0158 (17)	−0.0044 (17)
C110	0.025 (2)	0.029 (2)	0.037 (2)	0.0065 (18)	0.0148 (18)	−0.0012 (18)
C111	0.035 (3)	0.020 (2)	0.065 (3)	−0.0006 (19)	0.031 (2)	−0.005 (2)
C112	0.030 (2)	0.035 (2)	0.032 (2)	−0.0006 (19)	0.0088 (18)	−0.0159 (19)
C113	0.019 (2)	0.028 (2)	0.026 (2)	0.0047 (17)	0.0054 (16)	0.0052 (16)
C114	0.031 (2)	0.031 (2)	0.033 (2)	0.0047 (19)	0.0087 (18)	0.0090 (18)
C115	0.031 (2)	0.033 (2)	0.025 (2)	0.0017 (18)	0.0027 (17)	−0.0005 (17)
C116	0.023 (2)	0.046 (3)	0.036 (2)	0.010 (2)	0.0047 (18)	0.007 (2)
C117	0.0173 (19)	0.0184 (19)	0.034 (2)	−0.0042 (15)	0.0088 (16)	−0.0015 (16)
C118	0.0136 (18)	0.0200 (19)	0.0219 (18)	0.0024 (15)	0.0036 (14)	0.0029 (15)
C119	0.020 (2)	0.023 (2)	0.028 (2)	−0.0006 (16)	0.0038 (16)	0.0057 (16)
C120	0.022 (2)	0.035 (2)	0.039 (2)	−0.0006 (18)	0.0055 (18)	0.0174 (19)
C121	0.020 (2)	0.057 (3)	0.029 (2)	0.003 (2)	0.0071 (17)	0.017 (2)
C122	0.024 (2)	0.046 (3)	0.026 (2)	0.0041 (19)	0.0087 (17)	−0.0013 (19)
C123	0.020 (2)	0.027 (2)	0.026 (2)	0.0014 (16)	0.0079 (16)	−0.0006 (17)
C124	0.0154 (19)	0.0139 (18)	0.034 (2)	0.0045 (15)	0.0112 (16)	0.0090 (16)
C125	0.025 (2)	0.020 (2)	0.032 (2)	0.0002 (16)	0.0108 (17)	0.0081 (16)
C126	0.021 (2)	0.026 (2)	0.049 (3)	0.0007 (17)	0.0102 (19)	0.019 (2)
C127	0.025 (2)	0.019 (2)	0.062 (3)	0.0083 (17)	0.022 (2)	0.016 (2)
C128	0.039 (3)	0.018 (2)	0.053 (3)	0.0054 (18)	0.027 (2)	0.0005 (19)
C129	0.028 (2)	0.019 (2)	0.041 (2)	0.0050 (17)	0.0159 (18)	0.0014 (17)
C130	0.023 (2)	0.0121 (18)	0.0243 (19)	0.0040 (15)	0.0055 (15)	0.0010 (14)
C131	0.035 (2)	0.0181 (19)	0.026 (2)	0.0004 (17)	0.0087 (17)	0.0017 (16)
C132	0.049 (3)	0.024 (2)	0.022 (2)	0.008 (2)	0.0074 (19)	0.0010 (17)
C133	0.038 (2)	0.026 (2)	0.031 (2)	0.0060 (19)	−0.0038 (18)	−0.0099 (18)
C134	0.024 (2)	0.021 (2)	0.040 (2)	0.0007 (17)	0.0027 (18)	−0.0044 (18)
C135	0.022 (2)	0.0172 (19)	0.027 (2)	0.0033 (16)	0.0069 (16)	−0.0006 (15)
Pt2	0.0121 (1)	0.0118 (1)	0.0176 (1)	−0.0006 (1)	0.0034 (1)	−0.0002 (1)
P21	0.0133 (5)	0.0149 (4)	0.0191 (4)	−0.0007 (4)	0.0052 (4)	0.0008 (4)
P22	0.0172 (5)	0.0124 (5)	0.0325 (5)	−0.0004 (4)	0.0064 (4)	−0.0015 (4)
P23	0.0128 (5)	0.0155 (5)	0.0211 (5)	0.0001 (4)	0.0028 (4)	0.0009 (4)
P24	0.0168 (5)	0.0116 (4)	0.0188 (4)	−0.0002 (4)	0.0029 (4)	−0.0008 (3)
C201	0.026 (2)	0.0200 (19)	0.0211 (18)	−0.0027 (16)	0.0095 (16)	0.0022 (15)
C202	0.030 (2)	0.040 (2)	0.0211 (19)	0.0006 (19)	0.0044 (17)	0.0039 (18)
C203	0.033 (2)	0.022 (2)	0.032 (2)	0.0001 (17)	0.0146 (18)	0.0087 (17)
C204	0.032 (2)	0.023 (2)	0.027 (2)	−0.0022 (17)	0.0148 (17)	−0.0006 (16)
C205	0.0135 (18)	0.0236 (19)	0.0192 (18)	−0.0002 (15)	0.0010 (14)	0.0027 (15)
C206	0.024 (2)	0.034 (2)	0.0202 (19)	−0.0023 (18)	0.0029 (16)	0.0018 (17)
C207	0.019 (2)	0.027 (2)	0.027 (2)	−0.0052 (17)	0.0013 (16)	−0.0014 (17)
C208	0.026 (2)	0.023 (2)	0.0235 (19)	0.0008 (17)	0.0016 (16)	0.0069 (16)
C209	0.017 (2)	0.023 (2)	0.029 (2)	0.0019 (16)	0.0014 (16)	0.0038 (16)
C210	0.019 (2)	0.033 (2)	0.039 (2)	0.0018 (18)	−0.0006 (17)	0.0068 (19)
C211	0.027 (2)	0.021 (2)	0.051 (3)	0.0013 (18)	0.0018 (19)	0.0071 (19)
C212	0.034 (2)	0.033 (2)	0.028 (2)	0.0085 (19)	0.0047 (18)	0.0100 (18)
C213	0.019 (2)	0.026 (2)	0.0233 (19)	0.0022 (16)	0.0064 (15)	−0.0012 (16)
C214	0.031 (2)	0.028 (2)	0.026 (2)	0.0014 (18)	0.0071 (17)	−0.0076 (17)
C215	0.032 (2)	0.033 (2)	0.022 (2)	−0.0018 (19)	0.0081 (17)	0.0013 (17)
C216	0.026 (2)	0.047 (3)	0.038 (2)	0.007 (2)	0.0096 (19)	−0.005 (2)
C217	0.017 (2)	0.0186 (19)	0.035 (2)	−0.0013 (15)	0.0069 (16)	0.0040 (16)
C218	0.0151 (18)	0.0177 (18)	0.0181 (17)	−0.0018 (14)	0.0062 (14)	−0.0029 (14)
C219	0.022 (2)	0.0157 (18)	0.0253 (19)	0.0000 (15)	0.0055 (15)	0.0003 (15)
C220	0.027 (2)	0.022 (2)	0.028 (2)	−0.0058 (17)	0.0101 (17)	−0.0084 (16)
C221	0.024 (2)	0.030 (2)	0.0215 (19)	−0.0047 (17)	0.0049 (16)	−0.0078 (16)
C222	0.029 (2)	0.029 (2)	0.0185 (19)	0.0027 (18)	0.0027 (16)	0.0038 (16)
C223	0.023 (2)	0.0180 (19)	0.0217 (18)	−0.0009 (16)	0.0060 (15)	0.0001 (15)
C224	0.0141 (19)	0.0119 (18)	0.037 (2)	−0.0012 (14)	0.0036 (16)	−0.0060 (15)
C225	0.024 (2)	0.019 (2)	0.038 (2)	−0.0010 (16)	0.0076 (17)	−0.0055 (17)
C226	0.026 (2)	0.023 (2)	0.054 (3)	−0.0049 (18)	0.019 (2)	−0.012 (2)
C227	0.022 (2)	0.018 (2)	0.065 (3)	0.0028 (17)	0.010 (2)	−0.013 (2)
C228	0.023 (2)	0.019 (2)	0.055 (3)	0.0065 (17)	−0.003 (2)	−0.0030 (19)
C229	0.021 (2)	0.019 (2)	0.035 (2)	−0.0005 (16)	0.0029 (17)	−0.0032 (17)
C230	0.021 (2)	0.0147 (18)	0.0214 (18)	0.0057 (15)	0.0049 (15)	0.0030 (14)
C231	0.026 (2)	0.0191 (19)	0.025 (2)	0.0002 (16)	0.0027 (16)	0.0002 (16)
C232	0.044 (3)	0.025 (2)	0.0189 (19)	0.0060 (19)	0.0012 (18)	−0.0012 (16)
C233	0.043 (3)	0.026 (2)	0.028 (2)	0.0058 (19)	0.0154 (19)	0.0098 (18)
C234	0.025 (2)	0.022 (2)	0.033 (2)	0.0041 (17)	0.0110 (17)	0.0042 (17)
C235	0.020 (2)	0.0165 (18)	0.028 (2)	0.0014 (15)	0.0066 (16)	0.0014 (15)
Pt3	0.0136 (1)	0.0113 (1)	0.0203 (1)	0.0006 (1)	0.0049 (1)	0.0021 (1)
P31	0.0183 (5)	0.0126 (4)	0.0224 (5)	0.0013 (4)	0.0074 (4)	0.0008 (4)
P32	0.0151 (5)	0.0165 (5)	0.0402 (6)	0.0003 (4)	0.0080 (4)	0.0020 (4)
P33	0.0175 (5)	0.0107 (4)	0.0250 (5)	0.0002 (4)	0.0060 (4)	0.0031 (4)
P34	0.0140 (5)	0.0165 (5)	0.0196 (5)	0.0002 (4)	0.0030 (4)	0.0020 (4)
C301	0.033 (2)	0.0182 (19)	0.025 (2)	0.0015 (17)	0.0138 (17)	−0.0005 (16)
C302	0.044 (3)	0.026 (2)	0.024 (2)	0.0013 (19)	0.0139 (18)	0.0004 (17)
C303	0.036 (3)	0.031 (2)	0.036 (2)	0.0014 (19)	0.0193 (19)	−0.0047 (19)
C304	0.035 (2)	0.024 (2)	0.024 (2)	−0.0017 (18)	0.0100 (17)	−0.0028 (16)
C305	0.022 (2)	0.0162 (18)	0.0221 (18)	0.0037 (15)	0.0072 (15)	0.0035 (15)
C306	0.033 (2)	0.022 (2)	0.024 (2)	0.0038 (17)	0.0051 (17)	0.0033 (16)
C307	0.028 (2)	0.0186 (19)	0.029 (2)	0.0058 (17)	0.0080 (17)	0.0022 (16)
C308	0.026 (2)	0.023 (2)	0.026 (2)	0.0023 (17)	0.0110 (16)	0.0046 (16)
C309	0.020 (2)	0.0158 (19)	0.039 (2)	−0.0012 (16)	0.0117 (17)	0.0061 (17)
C310	0.028 (2)	0.020 (2)	0.035 (2)	−0.0037 (17)	0.0069 (18)	0.0070 (17)
C311	0.026 (2)	0.028 (2)	0.061 (3)	0.0026 (18)	0.019 (2)	0.018 (2)
C312	0.036 (2)	0.026 (2)	0.035 (2)	−0.0025 (18)	0.0187 (19)	0.0030 (18)
C313	0.025 (2)	0.0171 (19)	0.030 (2)	−0.0023 (16)	0.0021 (16)	0.0002 (16)
C314	0.028 (2)	0.030 (2)	0.030 (2)	−0.0044 (18)	−0.0009 (17)	0.0024 (18)
C315	0.035 (2)	0.031 (2)	0.026 (2)	−0.0026 (19)	0.0040 (18)	−0.0022 (18)
C316	0.046 (3)	0.024 (2)	0.041 (3)	−0.011 (2)	0.002 (2)	−0.0005 (19)
C317	0.022 (2)	0.0150 (19)	0.032 (2)	0.0009 (15)	0.0068 (16)	0.0033 (16)
C318	0.024 (2)	0.0125 (17)	0.0198 (18)	−0.0006 (15)	0.0013 (15)	−0.0005 (14)
C319	0.021 (2)	0.0180 (19)	0.030 (2)	−0.0008 (16)	0.0015 (16)	−0.0010 (16)
C320	0.029 (2)	0.020 (2)	0.038 (2)	0.0027 (17)	−0.0082 (18)	−0.0034 (18)
C321	0.048 (3)	0.019 (2)	0.025 (2)	0.0000 (19)	−0.0088 (19)	0.0021 (17)
C322	0.047 (3)	0.022 (2)	0.025 (2)	−0.0053 (19)	0.0064 (18)	0.0014 (16)
C323	0.027 (2)	0.0168 (19)	0.028 (2)	−0.0020 (16)	0.0065 (16)	0.0009 (16)
C324	0.0119 (18)	0.0135 (18)	0.034 (2)	−0.0005 (14)	0.0000 (15)	0.0067 (16)
C325	0.022 (2)	0.0175 (19)	0.030 (2)	0.0030 (16)	0.0018 (16)	0.0054 (16)
C326	0.024 (2)	0.019 (2)	0.043 (2)	0.0013 (17)	−0.0056 (18)	−0.0035 (18)
C327	0.013 (2)	0.021 (2)	0.063 (3)	−0.0014 (16)	−0.0025 (19)	0.012 (2)
C328	0.020 (2)	0.030 (2)	0.049 (3)	−0.0019 (18)	0.0064 (19)	0.018 (2)
C329	0.021 (2)	0.021 (2)	0.035 (2)	−0.0025 (16)	0.0034 (17)	0.0058 (17)
C330	0.0145 (18)	0.0184 (19)	0.0264 (19)	−0.0060 (15)	0.0076 (15)	0.0002 (15)
C331	0.0167 (19)	0.029 (2)	0.030 (2)	−0.0027 (16)	0.0052 (16)	0.0028 (17)
C332	0.025 (2)	0.045 (3)	0.024 (2)	−0.0071 (19)	0.0060 (17)	0.0025 (19)
C333	0.030 (2)	0.042 (3)	0.030 (2)	−0.008 (2)	0.0144 (18)	−0.0085 (19)
C334	0.025 (2)	0.025 (2)	0.039 (2)	−0.0023 (17)	0.0142 (18)	−0.0043 (18)
C335	0.0180 (19)	0.0195 (19)	0.029 (2)	−0.0027 (16)	0.0072 (15)	0.0010 (16)
Pt4	0.0130 (1)	0.0112 (1)	0.0174 (1)	0.0002 (1)	0.0040 (1)	−0.0007 (1)
P41	0.0163 (5)	0.0119 (4)	0.0197 (4)	0.0013 (4)	0.0033 (4)	0.0007 (4)
P42	0.0155 (5)	0.0152 (5)	0.0324 (5)	0.0004 (4)	0.0082 (4)	0.0004 (4)
P43	0.0170 (5)	0.0108 (4)	0.0217 (5)	0.0000 (4)	0.0035 (4)	−0.0015 (4)
P44	0.0134 (5)	0.0168 (5)	0.0184 (4)	−0.0007 (4)	0.0041 (4)	−0.0012 (4)
C401	0.023 (2)	0.0211 (19)	0.0187 (18)	0.0010 (16)	0.0020 (15)	0.0032 (15)
C402	0.039 (2)	0.030 (2)	0.0202 (19)	0.0042 (19)	0.0000 (17)	0.0019 (17)
C403	0.025 (2)	0.030 (2)	0.029 (2)	0.0037 (18)	−0.0002 (17)	0.0092 (17)
C404	0.027 (2)	0.028 (2)	0.029 (2)	0.0011 (18)	0.0063 (17)	0.0084 (17)
C405	0.022 (2)	0.0150 (18)	0.0214 (18)	0.0014 (15)	0.0032 (15)	−0.0031 (15)
C406	0.034 (2)	0.025 (2)	0.0207 (19)	0.0034 (18)	0.0036 (17)	−0.0012 (16)
C407	0.022 (2)	0.024 (2)	0.027 (2)	0.0017 (16)	0.0004 (16)	−0.0044 (16)
C408	0.027 (2)	0.019 (2)	0.030 (2)	0.0038 (16)	0.0064 (17)	−0.0033 (16)
C409	0.020 (2)	0.0175 (19)	0.029 (2)	−0.0026 (15)	0.0022 (16)	−0.0051 (16)
C410	0.032 (2)	0.022 (2)	0.041 (2)	−0.0046 (18)	0.0044 (19)	−0.0114 (18)
C411	0.021 (2)	0.023 (2)	0.052 (3)	−0.0028 (17)	0.0057 (19)	−0.0078 (19)
C412	0.029 (2)	0.033 (2)	0.025 (2)	−0.0045 (18)	−0.0048 (17)	−0.0034 (17)
C413	0.028 (2)	0.0175 (19)	0.0189 (18)	−0.0030 (16)	0.0046 (15)	0.0004 (15)
C414	0.032 (2)	0.029 (2)	0.026 (2)	−0.0024 (18)	0.0113 (17)	0.0003 (17)
C415	0.036 (2)	0.031 (2)	0.023 (2)	0.0023 (19)	0.0036 (17)	0.0039 (17)
C416	0.049 (3)	0.024 (2)	0.033 (2)	−0.010 (2)	0.010 (2)	0.0045 (18)
C417	0.020 (2)	0.0153 (19)	0.030 (2)	0.0026 (15)	0.0023 (16)	−0.0014 (16)
C418	0.0205 (19)	0.0136 (17)	0.0187 (17)	0.0013 (15)	0.0081 (14)	0.0019 (14)
C419	0.022 (2)	0.0212 (19)	0.0193 (18)	0.0001 (16)	0.0048 (15)	0.0011 (15)
C420	0.024 (2)	0.022 (2)	0.029 (2)	0.0019 (16)	0.0124 (16)	0.0032 (16)
C421	0.038 (2)	0.024 (2)	0.0189 (19)	−0.0001 (18)	0.0132 (17)	−0.0027 (16)
C422	0.030 (2)	0.028 (2)	0.0175 (18)	−0.0029 (17)	0.0017 (16)	−0.0017 (16)
C423	0.020 (2)	0.022 (2)	0.0216 (19)	−0.0009 (15)	0.0041 (15)	0.0004 (15)
C424	0.019 (2)	0.0142 (18)	0.035 (2)	−0.0010 (15)	0.0176 (16)	−0.0037 (16)
C425	0.023 (2)	0.022 (2)	0.037 (2)	0.0006 (17)	0.0107 (17)	−0.0007 (17)
C426	0.033 (2)	0.022 (2)	0.054 (3)	0.0039 (18)	0.024 (2)	0.009 (2)
C427	0.028 (2)	0.022 (2)	0.066 (3)	−0.0030 (18)	0.028 (2)	−0.005 (2)
C428	0.024 (2)	0.029 (2)	0.054 (3)	−0.0079 (18)	0.013 (2)	−0.014 (2)
C429	0.022 (2)	0.027 (2)	0.033 (2)	−0.0044 (17)	0.0072 (17)	−0.0049 (17)
C430	0.0144 (18)	0.0214 (19)	0.0179 (17)	−0.0034 (15)	0.0032 (14)	0.0004 (15)
C431	0.019 (2)	0.031 (2)	0.0236 (19)	−0.0021 (17)	0.0055 (16)	−0.0032 (17)
C432	0.028 (2)	0.047 (3)	0.020 (2)	−0.007 (2)	0.0045 (17)	−0.0028 (18)
C433	0.022 (2)	0.042 (3)	0.028 (2)	−0.0037 (19)	−0.0044 (17)	0.0109 (19)
C434	0.022 (2)	0.024 (2)	0.035 (2)	−0.0019 (17)	0.0023 (17)	0.0066 (17)
C435	0.0178 (19)	0.0219 (19)	0.0219 (18)	−0.0032 (16)	0.0047 (15)	−0.0001 (15)

Geometric parameters (Å, º)

Pt1—P11	2.3255 (10)	C214—H21J	0.9800
Pt1—P12	2.4125 (9)	C214—H21L	0.9800
Pt1—P13	2.3316 (10)	C215—H21O	0.9800
Pt1—P14	2.3041 (9)	C215—H21M	0.9800
Pt2—P21	2.3309 (9)	C215—H21N	0.9800
Pt2—P22	2.4099 (9)	C216—H21Q	0.9800
Pt2—P23	2.3324 (10)	C216—H21P	0.9800
Pt2—P24	2.3024 (9)	C216—H21R	0.9800
Pt3—P31	2.3288 (9)	C217—H21S	0.9800
Pt3—P32	2.4087 (10)	C217—H21U	0.9800
Pt3—P33	2.3333 (9)	C217—H21T	0.9800
Pt3—P34	2.3021 (10)	C219—H219	0.9500
Pt4—P41	2.3308 (9)	C220—H220	0.9500
Pt4—P42	2.4091 (10)	C221—H221	0.9500
Pt4—P43	2.3330 (9)	C222—H222	0.9500
Pt4—P44	2.3006 (10)	C223—H223	0.9500
P11—C105	1.900 (4)	C225—H225	0.9500
P11—P12	2.0665 (13)	C226—H226	0.9500
P11—C101	1.921 (4)	C227—H227	0.9500
P13—C113	1.913 (4)	C228—H228	0.9500
P13—C109	1.909 (4)	C229—H229	0.9500
P13—C117	1.853 (4)	C231—H231	0.9500
P14—C124	1.865 (4)	C232—H232	0.9500
P14—C130	1.851 (4)	C233—H233	0.9500
P14—C118	1.849 (4)	C234—H234	0.9500
P21—C201	1.920 (4)	C235—H235	0.9500
P21—P22	2.0678 (13)	C301—C304	1.542 (6)
P21—C205	1.900 (4)	C301—C303	1.530 (6)
P23—C217	1.838 (4)	C301—C302	1.538 (5)
P23—C213	1.909 (4)	C305—C308	1.531 (5)
P23—C209	1.919 (4)	C305—C307	1.537 (5)
P24—C230	1.849 (4)	C305—C306	1.543 (5)
P24—C218	1.845 (3)	C309—C311	1.541 (6)
P24—C224	1.858 (4)	C309—C312	1.545 (6)
P31—P32	2.0661 (13)	C309—C310	1.547 (5)
P31—C305	1.905 (4)	C313—C316	1.537 (6)
P31—C301	1.918 (4)	C313—C314	1.542 (6)
P33—C309	1.906 (4)	C313—C315	1.534 (6)
P33—C313	1.915 (4)	C318—C319	1.399 (5)
P33—C317	1.838 (4)	C318—C323	1.405 (5)
P34—C318	1.846 (3)	C319—C320	1.396 (6)
P34—C330	1.850 (4)	C320—C321	1.383 (6)
P34—C324	1.862 (4)	C321—C322	1.388 (6)
P41—C401	1.920 (4)	C322—C323	1.389 (5)
P41—C405	1.901 (4)	C324—C325	1.400 (5)
P41—P42	2.0676 (13)	C324—C329	1.399 (5)
P43—C417	1.847 (4)	C325—C326	1.396 (5)
P43—C409	1.916 (4)	C326—C327	1.397 (6)
P43—C413	1.910 (4)	C327—C328	1.365 (6)
P44—C418	1.855 (3)	C328—C329	1.399 (6)
P44—C430	1.847 (4)	C330—C331	1.416 (5)
P44—C424	1.863 (4)	C330—C335	1.400 (5)
C101—C102	1.549 (5)	C331—C332	1.398 (6)
C101—C104	1.528 (5)	C332—C333	1.392 (6)
C101—C103	1.536 (5)	C333—C334	1.398 (6)
C105—C107	1.535 (5)	C334—C335	1.409 (5)
C105—C108	1.536 (5)	C302—H30C	0.9800
C105—C106	1.543 (5)	C302—H30A	0.9800
C109—C110	1.540 (6)	C302—H30B	0.9800
C109—C112	1.548 (6)	C303—H30D	0.9800
C109—C111	1.536 (5)	C303—H30F	0.9800
C113—C114	1.541 (6)	C303—H30E	0.9800
C113—C115	1.534 (6)	C304—H30H	0.9800
C113—C116	1.543 (6)	C304—H30G	0.9800
C118—C123	1.396 (5)	C304—H30I	0.9800
C118—C119	1.403 (5)	C306—H30J	0.9800
C119—C120	1.395 (6)	C306—H30K	0.9800
C120—C121	1.388 (6)	C306—H30L	0.9800
C121—C122	1.388 (7)	C307—H30N	0.9800
C122—C123	1.391 (5)	C307—H30O	0.9800
C124—C129	1.384 (5)	C307—H30M	0.9800
C124—C125	1.405 (5)	C308—H30Q	0.9800
C125—C126	1.393 (6)	C308—H30R	0.9800
C126—C127	1.401 (6)	C308—H30P	0.9800
C127—C128	1.378 (6)	C310—H31C	0.9800
C128—C129	1.394 (6)	C310—H31A	0.9800
C130—C131	1.414 (5)	C310—H31B	0.9800
C130—C135	1.402 (5)	C311—H31E	0.9800
C131—C132	1.389 (5)	C311—H31D	0.9800
C132—C133	1.389 (6)	C311—H31F	0.9800
C133—C134	1.386 (6)	C312—H31G	0.9800
C134—C135	1.400 (5)	C312—H31H	0.9800
C102—H10B	0.9800	C312—H31I	0.9800
C102—H10A	0.9800	C314—H31K	0.9800
C102—H10C	0.9800	C314—H31L	0.9800
C103—H10D	0.9800	C314—H31J	0.9800
C103—H10E	0.9800	C315—H31M	0.9800
C103—H10F	0.9800	C315—H31N	0.9800
C104—H10G	0.9800	C315—H31O	0.9800
C104—H10H	0.9800	C316—H31R	0.9800
C104—H10I	0.9800	C316—H31Q	0.9800
C106—H10K	0.9800	C316—H31P	0.9800
C106—H10L	0.9800	C317—H31U	0.9800
C106—H10J	0.9800	C317—H31T	0.9800
C107—H10O	0.9800	C317—H31S	0.9800
C107—H10M	0.9800	C319—H319	0.9500
C107—H10N	0.9800	C320—H320	0.9500
C108—H10Q	0.9800	C321—H321	0.9500
C108—H10R	0.9800	C322—H322	0.9500
C108—H10P	0.9800	C323—H323	0.9500
C110—H11A	0.9800	C325—H325	0.9500
C110—H11C	0.9800	C326—H326	0.9500
C110—H11B	0.9800	C327—H327	0.9500
C111—H11D	0.9800	C328—H328	0.9500
C111—H11F	0.9800	C329—H329	0.9500
C111—H11E	0.9800	C331—H331	0.9500
C112—H11I	0.9800	C332—H332	0.9500
C112—H11H	0.9800	C333—H333	0.9500
C112—H11G	0.9800	C334—H334	0.9500
C114—H11J	0.9800	C335—H335	0.9500
C114—H11K	0.9800	C401—C402	1.544 (5)
C114—H11L	0.9800	C401—C403	1.538 (6)
C115—H11O	0.9800	C401—C404	1.537 (5)
C115—H11M	0.9800	C405—C406	1.547 (5)
C115—H11N	0.9800	C405—C407	1.536 (5)
C116—H11Q	0.9800	C405—C408	1.540 (5)
C116—H11P	0.9800	C409—C410	1.543 (5)
C116—H11R	0.9800	C409—C411	1.530 (6)
C117—H11T	0.9800	C409—C412	1.542 (5)
C117—H11U	0.9800	C413—C414	1.546 (6)
C117—H11S	0.9800	C413—C415	1.541 (6)
C119—H119	0.9500	C413—C416	1.534 (5)
C120—H120	0.9500	C418—C419	1.397 (5)
C121—H121	0.9500	C418—C423	1.396 (5)
C122—H122	0.9500	C419—C420	1.389 (5)
C123—H123	0.9500	C420—C421	1.391 (5)
C125—H125	0.9500	C421—C422	1.383 (6)
C126—H126	0.9500	C422—C423	1.397 (5)
C127—H127	0.9500	C424—C425	1.408 (5)
C128—H128	0.9500	C424—C429	1.394 (5)
C129—H129	0.9500	C425—C426	1.396 (6)
C131—H131	0.9500	C426—C427	1.392 (6)
C132—H132	0.9500	C427—C428	1.380 (6)
C133—H133	0.9500	C428—C429	1.403 (6)
C134—H134	0.9500	C430—C431	1.409 (5)
C135—H135	0.9500	C430—C435	1.394 (5)
C201—C202	1.539 (5)	C431—C432	1.394 (5)
C201—C203	1.549 (5)	C432—C433	1.393 (6)
C201—C204	1.537 (6)	C433—C434	1.383 (6)
C205—C206	1.544 (5)	C434—C435	1.406 (5)
C205—C208	1.540 (5)	C402—H40A	0.9800
C205—C207	1.536 (5)	C402—H40B	0.9800
C209—C211	1.536 (5)	C402—H40C	0.9800
C209—C212	1.552 (6)	C403—H40D	0.9800
C209—C210	1.541 (5)	C403—H40E	0.9800
C213—C216	1.545 (6)	C403—H40F	0.9800
C213—C214	1.546 (6)	C404—H40G	0.9800
C213—C215	1.546 (5)	C404—H40H	0.9800
C218—C219	1.405 (5)	C404—H40I	0.9800
C218—C223	1.396 (5)	C406—H40J	0.9800
C219—C220	1.389 (5)	C406—H40K	0.9800
C220—C221	1.395 (5)	C406—H40L	0.9800
C221—C222	1.383 (5)	C407—H40M	0.9800
C222—C223	1.388 (5)	C407—H40N	0.9800
C224—C229	1.401 (5)	C407—H40O	0.9800
C224—C225	1.397 (6)	C408—H40P	0.9800
C225—C226	1.386 (6)	C408—H40Q	0.9800
C226—C227	1.393 (6)	C408—H40R	0.9800
C227—C228	1.385 (6)	C410—H41A	0.9800
C228—C229	1.403 (6)	C410—H41B	0.9800
C230—C235	1.394 (5)	C410—H41C	0.9800
C230—C231	1.410 (5)	C411—H41D	0.9800
C231—C232	1.396 (5)	C411—H41E	0.9800
C232—C233	1.386 (6)	C411—H41F	0.9800
C233—C234	1.390 (6)	C412—H41G	0.9800
C234—C235	1.397 (6)	C412—H41H	0.9800
C202—H20B	0.9800	C412—H41I	0.9800
C202—H20A	0.9800	C414—H41J	0.9800
C202—H20C	0.9800	C414—H41K	0.9800
C203—H20E	0.9800	C414—H41L	0.9800
C203—H20D	0.9800	C415—H41M	0.9800
C203—H20F	0.9800	C415—H41N	0.9800
C204—H20G	0.9800	C415—H41O	0.9800
C204—H20I	0.9800	C416—H41P	0.9800
C204—H20H	0.9800	C416—H41Q	0.9800
C206—H20J	0.9800	C416—H41R	0.9800
C206—H20K	0.9800	C417—H41S	0.9800
C206—H20L	0.9800	C417—H41T	0.9800
C207—H20N	0.9800	C417—H41U	0.9800
C207—H20M	0.9800	C419—H419	0.9500
C207—H20O	0.9800	C420—H420	0.9500
C208—H20P	0.9800	C421—H421	0.9500
C208—H20Q	0.9800	C422—H422	0.9500
C208—H20R	0.9800	C423—H423	0.9500
C210—H21C	0.9800	C425—H425	0.9500
C210—H21A	0.9800	C426—H426	0.9500
C210—H21B	0.9800	C427—H427	0.9500
C211—H21D	0.9800	C428—H428	0.9500
C211—H21F	0.9800	C429—H429	0.9500
C211—H21E	0.9800	C431—H431	0.9500
C212—H21H	0.9800	C432—H432	0.9500
C212—H21G	0.9800	C433—H433	0.9500
C212—H21I	0.9800	C434—H434	0.9500
C214—H21K	0.9800	C435—H435	0.9500
Pt1—P14—C118	114.36 (12)	C213—C214—H21J	109.00
Pt2—P24—C218	116.73 (11)	C213—C214—H21L	109.00
Pt3—P34—C318	114.86 (12)	C213—C215—H21O	109.00
Pt4—P44—C418	116.67 (12)	H21M—C215—H21N	110.00
P11—Pt1—P13	147.08 (3)	H21N—C215—H21O	109.00
P21—Pt2—P23	146.73 (3)	H21M—C215—H21O	109.00
P31—Pt3—P33	147.17 (3)	C213—C215—H21N	109.00
P41—Pt4—P43	146.67 (3)	C213—C215—H21M	109.00
P11—Pt1—P14	110.86 (3)	C213—C216—H21P	109.00
P21—Pt2—P24	110.80 (3)	H21P—C216—H21R	109.00
P31—Pt3—P34	110.92 (3)	H21P—C216—H21Q	109.00
P41—Pt4—P44	110.79 (3)	C213—C216—H21R	109.00
P13—Pt1—P14	102.00 (3)	C213—C216—H21Q	109.00
P23—Pt2—P24	102.42 (3)	H21Q—C216—H21R	110.00
P33—Pt3—P34	101.84 (3)	P23—C217—H21T	109.00
P43—Pt4—P44	102.50 (3)	P23—C217—H21U	109.00
P11—Pt1—P12	51.68 (3)	H21S—C217—H21T	110.00
P12—Pt1—P13	95.51 (3)	H21S—C217—H21U	109.00
P12—Pt1—P14	162.46 (3)	H21T—C217—H21U	109.00
P21—Pt2—P22	51.69 (3)	P23—C217—H21S	110.00
P22—Pt2—P23	95.25 (3)	C220—C219—H219	120.00
P22—Pt2—P24	162.14 (3)	C218—C219—H219	120.00
P32—Pt3—P33	95.63 (3)	C219—C220—H220	120.00
P31—Pt3—P32	51.68 (3)	C221—C220—H220	120.00
P32—Pt3—P34	162.51 (3)	C220—C221—H221	120.00
P42—Pt4—P43	95.17 (3)	C222—C221—H221	120.00
P42—Pt4—P44	162.17 (3)	C223—C222—H222	120.00
P41—Pt4—P42	51.69 (3)	C221—C222—H222	120.00
P12—P11—C101	113.10 (12)	C222—C223—H223	119.00
Pt1—P11—P12	66.33 (4)	C218—C223—H223	119.00
Pt1—P11—C105	118.38 (12)	C224—C225—H225	119.00
C101—P11—C105	112.06 (16)	C226—C225—H225	119.00
Pt1—P11—C101	122.00 (12)	C225—C226—H226	120.00
P12—P11—C105	117.30 (12)	C227—C226—H226	120.00
Pt1—P12—P11	61.99 (4)	C228—C227—H227	120.00
Pt1—P13—C117	114.44 (12)	C226—C227—H227	120.00
Pt1—P13—C109	114.73 (13)	C229—C228—H228	120.00
Pt1—P13—C113	113.67 (13)	C227—C228—H228	120.00
C113—P13—C117	101.70 (17)	C228—C229—H229	120.00
C109—P13—C117	100.32 (17)	C224—C229—H229	120.00
C109—P13—C113	110.49 (17)	C230—C231—H231	120.00
Pt1—P14—C130	114.81 (11)	C232—C231—H231	120.00
Pt1—P14—C124	120.25 (12)	C233—C232—H232	120.00
C118—P14—C130	106.56 (16)	C231—C232—H232	120.00
C118—P14—C124	98.69 (16)	C234—C233—H233	120.00
C124—P14—C130	99.86 (16)	C232—C233—H233	120.00
C201—P21—C205	112.00 (16)	C233—C234—H234	120.00
Pt2—P21—C201	121.40 (12)	C235—C234—H234	120.00
Pt2—P21—C205	119.05 (12)	C234—C235—H235	120.00
Pt2—P21—P22	66.13 (4)	C230—C235—H235	120.00
P22—P21—C201	113.02 (12)	P31—C301—C302	107.4 (2)
P22—P21—C205	117.54 (12)	P31—C301—C303	108.8 (3)
Pt2—P22—P21	62.19 (4)	C302—C301—C303	108.0 (3)
Pt2—P23—C217	114.91 (13)	C302—C301—C304	108.9 (3)
C213—P23—C217	100.87 (17)	P31—C301—C304	114.5 (3)
Pt2—P23—C209	114.14 (12)	C303—C301—C304	109.0 (3)
Pt2—P23—C213	114.40 (12)	P31—C305—C308	111.8 (3)
C209—P23—C213	110.37 (17)	C306—C305—C307	108.9 (3)
C209—P23—C217	100.62 (17)	P31—C305—C307	111.0 (3)
Pt2—P24—C224	120.14 (11)	C307—C305—C308	110.4 (3)
C218—P24—C224	96.73 (17)	C306—C305—C308	108.1 (3)
C218—P24—C230	105.26 (16)	P31—C305—C306	106.5 (2)
Pt2—P24—C230	113.75 (11)	P33—C309—C310	113.5 (3)
C224—P24—C230	101.66 (16)	P33—C309—C312	107.6 (3)
Pt3—P31—C301	121.73 (12)	C310—C309—C311	108.4 (3)
C301—P31—C305	112.51 (16)	C310—C309—C312	107.3 (3)
Pt3—P31—P32	66.15 (4)	C311—C309—C312	108.8 (3)
P32—P31—C301	112.99 (13)	P33—C309—C311	111.1 (3)
Pt3—P31—C305	118.27 (12)	P33—C313—C314	111.3 (3)
P32—P31—C305	117.22 (12)	P33—C313—C315	105.9 (3)
Pt3—P32—P31	62.17 (4)	C315—C313—C316	108.1 (3)
Pt3—P33—C313	113.93 (12)	C314—C313—C316	108.4 (3)
C309—P33—C317	100.44 (17)	P33—C313—C316	114.7 (3)
Pt3—P33—C309	114.50 (12)	C314—C313—C315	108.1 (3)
C309—P33—C313	110.46 (17)	P34—C318—C323	118.0 (3)
C313—P33—C317	101.64 (17)	P34—C318—C319	123.2 (3)
Pt3—P33—C317	114.39 (12)	C319—C318—C323	118.6 (3)
Pt3—P34—C324	120.19 (12)	C318—C319—C320	120.3 (4)
C324—P34—C330	100.23 (16)	C319—C320—C321	120.2 (4)
C318—P34—C330	106.27 (16)	C320—C321—C322	120.1 (4)
Pt3—P34—C330	114.83 (12)	C321—C322—C323	120.0 (4)
C318—P34—C324	98.05 (16)	C318—C323—C322	120.6 (4)
C401—P41—C405	112.08 (16)	C325—C324—C329	118.5 (3)
P42—P41—C401	113.07 (13)	P34—C324—C325	117.0 (3)
P42—P41—C405	117.53 (12)	P34—C324—C329	124.6 (3)
Pt4—P41—C401	121.42 (12)	C324—C325—C326	120.8 (4)
Pt4—P41—P42	66.11 (4)	C325—C326—C327	119.7 (4)
Pt4—P41—C405	118.89 (12)	C326—C327—C328	120.0 (4)
Pt4—P42—P41	62.20 (4)	C327—C328—C329	120.9 (4)
Pt4—P43—C417	114.50 (12)	C324—C329—C328	120.2 (4)
C409—P43—C413	110.47 (17)	P34—C330—C331	115.8 (3)
C413—P43—C417	101.30 (17)	P34—C330—C335	125.5 (3)
C409—P43—C417	100.55 (17)	C331—C330—C335	118.7 (3)
Pt4—P43—C409	114.11 (12)	C330—C331—C332	120.7 (4)
Pt4—P43—C413	114.40 (12)	C331—C332—C333	120.2 (4)
C424—P44—C430	100.85 (17)	C332—C333—C334	119.8 (4)
C418—P44—C430	105.18 (16)	C333—C334—C335	120.4 (4)
Pt4—P44—C430	114.12 (12)	C330—C335—C334	120.2 (3)
Pt4—P44—C424	120.34 (12)	H30B—C302—H30C	109.00
C418—P44—C424	96.98 (16)	C301—C302—H30A	109.00
C102—C101—C104	109.3 (3)	C301—C302—H30B	110.00
P11—C101—C102	106.8 (2)	C301—C302—H30C	110.00
P11—C101—C103	108.3 (3)	H30A—C302—H30C	109.00
C102—C101—C103	108.2 (3)	H30A—C302—H30B	109.00
C103—C101—C104	109.4 (3)	H30D—C303—H30E	109.00
P11—C101—C104	114.7 (3)	H30D—C303—H30F	109.00
C107—C105—C108	110.3 (3)	C301—C303—H30F	110.00
C106—C105—C108	107.8 (3)	C301—C303—H30E	109.00
P11—C105—C106	106.3 (2)	C301—C303—H30D	110.00
P11—C105—C108	111.7 (2)	H30E—C303—H30F	109.00
C106—C105—C107	109.1 (3)	C301—C304—H30G	109.00
P11—C105—C107	111.5 (2)	C301—C304—H30H	110.00
P13—C109—C110	113.9 (3)	H30G—C304—H30H	110.00
C111—C109—C112	108.2 (3)	H30G—C304—H30I	109.00
C110—C109—C112	107.3 (3)	H30H—C304—H30I	109.00
P13—C109—C111	111.5 (3)	C301—C304—H30I	109.00
P13—C109—C112	107.4 (3)	C305—C306—H30K	110.00
C110—C109—C111	108.3 (3)	C305—C306—H30L	109.00
P13—C113—C115	105.7 (3)	C305—C306—H30J	110.00
P13—C113—C116	114.5 (3)	H30K—C306—H30L	109.00
C114—C113—C115	108.6 (3)	H30J—C306—H30L	109.00
P13—C113—C114	111.2 (3)	H30J—C306—H30K	109.00
C114—C113—C116	109.0 (3)	C305—C307—H30N	110.00
C115—C113—C116	107.7 (3)	C305—C307—H30M	110.00
P14—C118—C123	118.3 (3)	H30M—C307—H30O	109.00
C119—C118—C123	118.9 (3)	C305—C307—H30O	109.00
P14—C118—C119	122.7 (3)	H30M—C307—H30N	109.00
C118—C119—C120	120.1 (4)	H30N—C307—H30O	110.00
C119—C120—C121	120.2 (4)	C305—C308—H30Q	109.00
C120—C121—C122	120.1 (4)	C305—C308—H30R	109.00
C121—C122—C123	119.9 (4)	C305—C308—H30P	110.00
C118—C123—C122	120.8 (4)	H30P—C308—H30R	110.00
P14—C124—C129	125.1 (3)	H30Q—C308—H30R	109.00
C125—C124—C129	118.6 (3)	H30P—C308—H30Q	109.00
P14—C124—C125	116.3 (3)	H31A—C310—H31B	109.00
C124—C125—C126	120.7 (4)	H31A—C310—H31C	109.00
C125—C126—C127	119.9 (4)	H31B—C310—H31C	110.00
C126—C127—C128	119.1 (4)	C309—C310—H31A	109.00
C127—C128—C129	121.0 (4)	C309—C310—H31B	109.00
C124—C129—C128	120.7 (4)	C309—C310—H31C	110.00
C131—C130—C135	118.3 (3)	C309—C311—H31D	109.00
P14—C130—C135	125.4 (3)	C309—C311—H31E	109.00
P14—C130—C131	116.4 (3)	C309—C311—H31F	109.00
C130—C131—C132	120.7 (4)	H31D—C311—H31E	109.00
C131—C132—C133	120.4 (4)	H31D—C311—H31F	110.00
C132—C133—C134	119.7 (4)	H31E—C311—H31F	110.00
C133—C134—C135	120.5 (4)	C309—C312—H31G	109.00
C130—C135—C134	120.4 (3)	C309—C312—H31H	110.00
C101—C102—H10B	110.00	C309—C312—H31I	109.00
H10A—C102—H10B	109.00	H31G—C312—H31H	109.00
C101—C102—H10C	109.00	H31H—C312—H31I	110.00
H10A—C102—H10C	110.00	H31G—C312—H31I	109.00
H10B—C102—H10C	109.00	C313—C314—H31K	109.00
C101—C102—H10A	110.00	C313—C314—H31L	109.00
H10D—C103—H10E	110.00	C313—C314—H31J	109.00
C101—C103—H10D	109.00	H31J—C314—H31L	109.00
C101—C103—H10F	110.00	H31K—C314—H31L	110.00
C101—C103—H10E	109.00	H31J—C314—H31K	110.00
H10E—C103—H10F	110.00	C313—C315—H31M	109.00
H10D—C103—H10F	109.00	C313—C315—H31N	110.00
C101—C104—H10G	110.00	C313—C315—H31O	109.00
H10G—C104—H10I	109.00	H31M—C315—H31N	109.00
H10H—C104—H10I	109.00	H31M—C315—H31O	109.00
C101—C104—H10I	110.00	H31N—C315—H31O	110.00
H10G—C104—H10H	110.00	C313—C316—H31P	110.00
C101—C104—H10H	110.00	H31P—C316—H31R	110.00
H10K—C106—H10L	109.00	H31Q—C316—H31R	109.00
H10J—C106—H10K	109.00	H31P—C316—H31Q	109.00
H10J—C106—H10L	109.00	C313—C316—H31Q	110.00
C105—C106—H10J	109.00	C313—C316—H31R	110.00
C105—C106—H10K	109.00	P33—C317—H31T	110.00
C105—C106—H10L	110.00	H31S—C317—H31U	110.00
C105—C107—H10M	110.00	P33—C317—H31U	109.00
H10N—C107—H10O	109.00	H31S—C317—H31T	109.00
C105—C107—H10N	109.00	P33—C317—H31S	109.00
H10M—C107—H10O	109.00	H31T—C317—H31U	110.00
C105—C107—H10O	110.00	C320—C319—H319	120.00
H10M—C107—H10N	109.00	C318—C319—H319	120.00
H10P—C108—H10R	110.00	C319—C320—H320	120.00
C105—C108—H10Q	109.00	C321—C320—H320	120.00
H10Q—C108—H10R	109.00	C320—C321—H321	120.00
H10P—C108—H10Q	109.00	C322—C321—H321	120.00
C105—C108—H10R	109.00	C323—C322—H322	120.00
C105—C108—H10P	109.00	C321—C322—H322	120.00
H11B—C110—H11C	109.00	C322—C323—H323	120.00
C109—C110—H11A	109.00	C318—C323—H323	120.00
C109—C110—H11B	110.00	C324—C325—H325	120.00
H11A—C110—H11B	110.00	C326—C325—H325	120.00
H11A—C110—H11C	109.00	C327—C326—H326	120.00
C109—C110—H11C	109.00	C325—C326—H326	120.00
C109—C111—H11D	110.00	C328—C327—H327	120.00
H11E—C111—H11F	109.00	C326—C327—H327	120.00
C109—C111—H11E	109.00	C327—C328—H328	120.00
C109—C111—H11F	109.00	C329—C328—H328	120.00
H11D—C111—H11F	109.00	C328—C329—H329	120.00
H11D—C111—H11E	110.00	C324—C329—H329	120.00
H11G—C112—H11H	110.00	C330—C331—H331	120.00
C109—C112—H11H	109.00	C332—C331—H331	120.00
H11G—C112—H11I	109.00	C331—C332—H332	120.00
H11H—C112—H11I	109.00	C333—C332—H332	120.00
C109—C112—H11I	110.00	C332—C333—H333	120.00
C109—C112—H11G	110.00	C334—C333—H333	120.00
H11K—C114—H11L	109.00	C333—C334—H334	120.00
H11J—C114—H11L	110.00	C335—C334—H334	120.00
H11J—C114—H11K	109.00	C330—C335—H335	120.00
C113—C114—H11L	109.00	C334—C335—H335	120.00
C113—C114—H11J	109.00	P41—C401—C402	106.8 (2)
C113—C114—H11K	109.00	P41—C401—C403	108.1 (3)
H11M—C115—H11N	109.00	P41—C401—C404	115.0 (3)
C113—C115—H11M	109.00	C402—C401—C403	108.2 (3)
H11N—C115—H11O	109.00	C402—C401—C404	108.9 (3)
C113—C115—H11O	110.00	C403—C401—C404	109.6 (3)
C113—C115—H11N	110.00	P41—C405—C406	106.2 (2)
H11M—C115—H11O	110.00	P41—C405—C407	111.6 (3)
H11P—C116—H11Q	109.00	P41—C405—C408	111.5 (3)
C113—C116—H11P	110.00	C406—C405—C407	107.9 (3)
H11Q—C116—H11R	109.00	C406—C405—C408	109.6 (3)
C113—C116—H11R	109.00	C407—C405—C408	110.0 (3)
C113—C116—H11Q	109.00	P43—C409—C410	113.7 (3)
H11P—C116—H11R	110.00	P43—C409—C411	111.3 (3)
P13—C117—H11S	109.00	P43—C409—C412	107.7 (3)
P13—C117—H11U	109.00	C410—C409—C411	108.7 (3)
H11S—C117—H11T	109.00	C410—C409—C412	107.0 (3)
P13—C117—H11T	110.00	C411—C409—C412	108.2 (3)
H11T—C117—H11U	110.00	P43—C413—C414	111.5 (3)
H11S—C117—H11U	109.00	P43—C413—C415	105.9 (3)
C118—C119—H119	120.00	P43—C413—C416	114.4 (3)
C120—C119—H119	120.00	C414—C413—C415	107.8 (3)
C119—C120—H120	120.00	C414—C413—C416	108.8 (3)
C121—C120—H120	120.00	C415—C413—C416	108.2 (3)
C120—C121—H121	120.00	P44—C418—C419	122.3 (3)
C122—C121—H121	120.00	P44—C418—C423	118.5 (3)
C123—C122—H122	120.00	C419—C418—C423	119.2 (3)
C121—C122—H122	120.00	C418—C419—C420	120.2 (3)
C118—C123—H123	120.00	C419—C420—C421	120.3 (4)
C122—C123—H123	120.00	C420—C421—C422	119.8 (3)
C126—C125—H125	120.00	C421—C422—C423	120.2 (4)
C124—C125—H125	120.00	C418—C423—C422	120.3 (4)
C127—C126—H126	120.00	P44—C424—C425	116.6 (3)
C125—C126—H126	120.00	P44—C424—C429	124.7 (3)
C128—C127—H127	121.00	C425—C424—C429	118.7 (3)
C126—C127—H127	120.00	C424—C425—C426	120.5 (4)
C127—C128—H128	120.00	C425—C426—C427	120.2 (4)
C129—C128—H128	119.00	C426—C427—C428	119.6 (4)
C124—C129—H129	120.00	C427—C428—C429	120.8 (4)
C128—C129—H129	120.00	C424—C429—C428	120.1 (4)
C130—C131—H131	120.00	P44—C430—C431	116.7 (3)
C132—C131—H131	120.00	P44—C430—C435	124.9 (3)
C131—C132—H132	120.00	C431—C430—C435	118.3 (3)
C133—C132—H132	120.00	C430—C431—C432	121.2 (4)
C132—C133—H133	120.00	C431—C432—C433	119.5 (4)
C134—C133—H133	120.00	C432—C433—C434	120.3 (4)
C135—C134—H134	120.00	C433—C434—C435	120.2 (4)
C133—C134—H134	120.00	C430—C435—C434	120.5 (3)
C134—C135—H135	120.00	C401—C402—H40A	109.00
C130—C135—H135	120.00	C401—C402—H40B	109.00
P21—C201—C204	115.0 (3)	C401—C402—H40C	110.00
P21—C201—C203	108.4 (2)	H40A—C402—H40B	110.00
C202—C201—C204	109.2 (3)	H40A—C402—H40C	109.00
P21—C201—C202	106.7 (3)	H40B—C402—H40C	109.00
C203—C201—C204	109.2 (3)	C401—C403—H40D	109.00
C202—C201—C203	108.2 (3)	C401—C403—H40E	110.00
C206—C205—C207	109.3 (3)	C401—C403—H40F	109.00
P21—C205—C207	111.1 (2)	H40D—C403—H40E	109.00
P21—C205—C208	111.5 (2)	H40D—C403—H40F	110.00
C207—C205—C208	110.7 (3)	H40E—C403—H40F	109.00
C206—C205—C208	107.9 (3)	C401—C404—H40G	109.00
P21—C205—C206	106.2 (2)	C401—C404—H40H	109.00
P23—C209—C212	107.7 (3)	C401—C404—H40I	110.00
C211—C209—C212	108.1 (3)	H40G—C404—H40H	109.00
P23—C209—C211	111.3 (3)	H40G—C404—H40I	109.00
C210—C209—C212	106.9 (3)	H40H—C404—H40I	110.00
P23—C209—C210	113.9 (3)	C405—C406—H40J	109.00
C210—C209—C211	108.8 (3)	C405—C406—H40K	109.00
P23—C213—C214	112.0 (3)	C405—C406—H40L	109.00
C214—C213—C216	108.4 (3)	H40J—C406—H40K	110.00
C215—C213—C216	108.0 (3)	H40J—C406—H40L	110.00
C214—C213—C215	107.9 (3)	H40K—C406—H40L	109.00
P23—C213—C215	105.9 (3)	C405—C407—H40M	109.00
P23—C213—C216	114.5 (3)	C405—C407—H40N	110.00
P24—C218—C219	122.2 (3)	C405—C407—H40O	110.00
P24—C218—C223	119.4 (3)	H40M—C407—H40N	109.00
C219—C218—C223	118.3 (3)	H40M—C407—H40O	109.00
C218—C219—C220	120.1 (3)	H40N—C407—H40O	109.00
C219—C220—C221	120.6 (4)	C405—C408—H40P	109.00
C220—C221—C222	119.6 (3)	C405—C408—H40Q	109.00
C221—C222—C223	119.9 (3)	C405—C408—H40R	109.00
C218—C223—C222	121.3 (3)	H40P—C408—H40Q	109.00
C225—C224—C229	118.4 (3)	H40P—C408—H40R	109.00
P24—C224—C225	117.7 (3)	H40Q—C408—H40R	110.00
P24—C224—C229	123.9 (3)	C409—C410—H41A	109.00
C224—C225—C226	121.4 (4)	C409—C410—H41B	109.00
C225—C226—C227	119.9 (4)	C409—C410—H41C	110.00
C226—C227—C228	119.8 (4)	H41A—C410—H41B	109.00
C227—C228—C229	120.4 (4)	H41A—C410—H41C	109.00
C224—C229—C228	120.1 (4)	H41B—C410—H41C	109.00
C231—C230—C235	118.4 (3)	C409—C411—H41D	109.00
P24—C230—C235	125.1 (3)	C409—C411—H41E	109.00
P24—C230—C231	116.5 (3)	C409—C411—H41F	110.00
C230—C231—C232	120.6 (4)	H41D—C411—H41E	110.00
C231—C232—C233	120.3 (4)	H41D—C411—H41F	109.00
C232—C233—C234	119.6 (4)	H41E—C411—H41F	109.00
C233—C234—C235	120.4 (4)	C409—C412—H41G	109.00
C230—C235—C234	120.7 (4)	C409—C412—H41H	110.00
H20B—C202—H20C	109.00	C409—C412—H41I	110.00
C201—C202—H20A	109.00	H41G—C412—H41H	110.00
C201—C202—H20C	109.00	H41G—C412—H41I	110.00
H20A—C202—H20C	110.00	H41H—C412—H41I	109.00
H20A—C202—H20B	109.00	C413—C414—H41J	109.00
C201—C202—H20B	109.00	C413—C414—H41K	110.00
H20D—C203—H20F	110.00	C413—C414—H41L	110.00
C201—C203—H20F	110.00	H41J—C414—H41K	109.00
H20D—C203—H20E	109.00	H41J—C414—H41L	109.00
C201—C203—H20D	109.00	H41K—C414—H41L	109.00
H20E—C203—H20F	109.00	C413—C415—H41M	109.00
C201—C203—H20E	110.00	C413—C415—H41N	109.00
C201—C204—H20I	110.00	C413—C415—H41O	109.00
H20G—C204—H20I	109.00	H41M—C415—H41N	109.00
H20H—C204—H20I	109.00	H41M—C415—H41O	109.00
C201—C204—H20G	110.00	H41N—C415—H41O	110.00
C201—C204—H20H	109.00	C413—C416—H41P	109.00
H20G—C204—H20H	109.00	C413—C416—H41Q	110.00
C205—C206—H20K	110.00	C413—C416—H41R	110.00
C205—C206—H20L	109.00	H41P—C416—H41Q	109.00
H20K—C206—H20L	109.00	H41P—C416—H41R	109.00
H20J—C206—H20L	110.00	H41Q—C416—H41R	109.00
C205—C206—H20J	110.00	P43—C417—H41S	109.00
H20J—C206—H20K	109.00	P43—C417—H41T	110.00
C205—C207—H20N	110.00	P43—C417—H41U	109.00
C205—C207—H20M	110.00	H41S—C417—H41T	110.00
H20M—C207—H20O	109.00	H41S—C417—H41U	109.00
H20N—C207—H20O	109.00	H41T—C417—H41U	109.00
H20M—C207—H20N	109.00	C418—C419—H419	120.00
C205—C207—H20O	109.00	C420—C419—H419	120.00
H20P—C208—H20Q	110.00	C419—C420—H420	120.00
C205—C208—H20R	109.00	C421—C420—H420	120.00
C205—C208—H20P	109.00	C420—C421—H421	120.00
H20P—C208—H20R	109.00	C422—C421—H421	120.00
C205—C208—H20Q	110.00	C421—C422—H422	120.00
H20Q—C208—H20R	110.00	C423—C422—H422	120.00
H21B—C210—H21C	109.00	C418—C423—H423	120.00
C209—C210—H21C	109.00	C422—C423—H423	120.00
H21A—C210—H21B	110.00	C424—C425—H425	120.00
C209—C210—H21B	109.00	C426—C425—H425	120.00
C209—C210—H21A	109.00	C425—C426—H426	120.00
H21A—C210—H21C	110.00	C427—C426—H426	120.00
H21E—C211—H21F	110.00	C426—C427—H427	120.00
C209—C211—H21D	110.00	C428—C427—H427	120.00
C209—C211—H21E	109.00	C427—C428—H428	120.00
C209—C211—H21F	109.00	C429—C428—H428	120.00
H21D—C211—H21E	110.00	C424—C429—H429	120.00
H21D—C211—H21F	109.00	C428—C429—H429	120.00
C209—C212—H21I	109.00	C430—C431—H431	119.00
H21G—C212—H21H	109.00	C432—C431—H431	119.00
C209—C212—H21G	109.00	C431—C432—H432	120.00
H21H—C212—H21I	110.00	C433—C432—H432	120.00
C209—C212—H21H	109.00	C432—C433—H433	120.00
H21G—C212—H21I	109.00	C434—C433—H433	120.00
H21K—C214—H21L	109.00	C433—C434—H434	120.00
H21J—C214—H21L	109.00	C435—C434—H434	120.00
C213—C214—H21K	110.00	C430—C435—H435	120.00
H21J—C214—H21K	109.00	C434—C435—H435	120.00
P14—Pt1—P13—C117	11.87 (14)	P32—P31—C301—C304	172.6 (2)
P24—Pt2—P23—C217	11.40 (15)	P32—P31—C305—C307	−81.6 (3)
P34—Pt3—P33—C317	−12.09 (15)	C305—P31—C301—C303	−85.1 (3)
P44—Pt4—P43—C417	−11.70 (14)	C305—P31—C301—C304	37.1 (3)
P12—Pt1—P11—C101	103.37 (14)	Pt3—P31—C305—C306	−39.4 (3)
P12—Pt1—P11—C105	−109.41 (14)	Pt3—P31—C305—C307	−157.8 (2)
P13—Pt1—P11—P12	−5.47 (8)	Pt3—P31—C305—C308	78.4 (3)
P13—Pt1—P11—C101	97.90 (15)	P32—P31—C305—C306	36.8 (3)
P13—Pt1—P11—C105	−114.88 (14)	C305—P31—C301—C302	158.2 (3)
P14—Pt1—P11—P12	178.15 (4)	P32—P31—C305—C308	154.6 (2)
P14—Pt1—P11—C101	−78.48 (14)	C301—P31—C305—C306	170.3 (3)
P14—Pt1—P11—C105	68.74 (14)	C301—P31—C305—C307	51.9 (3)
P13—Pt1—P12—P11	177.02 (4)	C301—P31—C305—C308	−71.9 (3)
P11—Pt1—P13—C109	−49.45 (15)	Pt3—P31—C301—C304	−112.1 (3)
P11—Pt1—P13—C113	79.07 (15)	P32—P31—C301—C302	−66.3 (3)
P11—Pt1—P13—C117	−164.67 (14)	P32—P31—C301—C303	50.4 (3)
P12—Pt1—P13—C109	−53.76 (13)	Pt3—P31—C301—C302	9.0 (3)
P12—Pt1—P13—C113	74.76 (14)	C301—P31—P32—Pt3	115.91 (13)
P12—Pt1—P13—C117	−168.98 (14)	C305—P31—P32—Pt3	−110.79 (13)
P14—Pt1—P13—C109	127.09 (13)	Pt3—P31—C301—C303	125.7 (2)
P14—Pt1—P13—C113	−104.39 (14)	C313—P33—C309—C310	−69.0 (3)
P11—Pt1—P14—C118	111.04 (13)	C317—P33—C309—C312	−80.9 (3)
P11—Pt1—P14—C124	−6.10 (14)	Pt3—P33—C313—C314	50.1 (3)
P11—Pt1—P14—C130	−125.31 (13)	Pt3—P33—C309—C312	42.2 (3)
P13—Pt1—P14—C118	−66.95 (13)	C313—P33—C309—C311	53.4 (3)
P13—Pt1—P14—C124	175.91 (14)	C313—P33—C309—C312	172.4 (2)
P13—Pt1—P14—C130	56.70 (14)	C317—P33—C309—C310	37.7 (3)
P22—Pt2—P23—C217	−171.22 (14)	C317—P33—C309—C311	160.1 (3)
P24—Pt2—P23—C209	126.91 (13)	Pt3—P33—C309—C310	160.8 (2)
P24—Pt2—P23—C213	−104.63 (14)	Pt3—P33—C309—C311	−76.8 (3)
P21—Pt2—P24—C218	113.98 (13)	C317—P33—C313—C314	173.7 (3)
P21—Pt2—P24—C224	−2.39 (15)	C317—P33—C313—C316	−62.9 (3)
P21—Pt2—P24—C230	−123.10 (13)	Pt3—P33—C313—C315	−67.2 (3)
P23—Pt2—P24—C218	−64.18 (13)	Pt3—P33—C313—C316	173.6 (3)
P23—Pt2—P24—C224	179.46 (15)	C309—P33—C313—C314	−80.4 (3)
P23—Pt2—P24—C230	58.75 (13)	C309—P33—C313—C315	162.3 (2)
P23—Pt2—P22—P21	175.97 (4)	C309—P33—C313—C316	43.1 (3)
P21—Pt2—P23—C209	−49.95 (15)	C317—P33—C313—C315	56.4 (3)
P21—Pt2—P23—C213	78.51 (15)	C318—P34—C324—C329	−118.6 (3)
P21—Pt2—P23—C217	−165.46 (14)	C324—P34—C318—C319	54.0 (3)
P22—Pt2—P23—C209	−55.72 (13)	C324—P34—C318—C323	−121.2 (3)
P22—Pt2—P23—C213	72.75 (14)	C330—P34—C318—C319	−49.2 (3)
P24—Pt2—P21—C201	−80.70 (14)	C330—P34—C318—C323	135.6 (3)
P22—Pt2—P21—C201	103.34 (14)	Pt3—P34—C324—C325	−63.6 (3)
P22—Pt2—P21—C205	−109.42 (14)	Pt3—P34—C324—C329	116.5 (3)
P23—Pt2—P21—P22	−7.33 (8)	C318—P34—C324—C325	61.4 (3)
P23—Pt2—P21—C201	96.02 (15)	Pt3—P34—C318—C323	7.5 (3)
P23—Pt2—P21—C205	−116.75 (14)	C324—P34—C330—C335	−107.3 (3)
P24—Pt2—P21—P22	175.96 (4)	C330—P34—C324—C325	169.7 (3)
P24—Pt2—P21—C205	66.54 (13)	C330—P34—C324—C329	−10.3 (4)
P33—Pt3—P34—C324	−176.66 (14)	Pt3—P34—C330—C331	−56.5 (3)
P34—Pt3—P33—C313	104.24 (14)	Pt3—P34—C330—C335	122.4 (3)
P31—Pt3—P34—C318	−111.07 (12)	C318—P34—C330—C331	175.4 (3)
P31—Pt3—P34—C324	5.55 (14)	C318—P34—C330—C335	−5.7 (4)
P31—Pt3—P34—C330	125.25 (13)	C324—P34—C330—C331	73.8 (3)
P33—Pt3—P34—C318	66.72 (12)	Pt3—P34—C318—C319	−177.3 (3)
P34—Pt3—P31—C301	78.87 (16)	C401—P41—C405—C407	−72.7 (3)
P34—Pt3—P31—C305	−68.64 (14)	C401—P41—C405—C408	50.7 (3)
P33—Pt3—P32—P31	−176.69 (4)	Pt4—P41—C401—C403	127.0 (2)
P31—Pt3—P33—C309	48.93 (16)	Pt4—P41—C401—C404	−110.2 (3)
P31—Pt3—P33—C313	−79.57 (15)	P42—P41—C401—C402	−64.4 (3)
P31—Pt3—P33—C317	164.10 (14)	P42—P41—C401—C404	174.6 (2)
P32—Pt3—P33—C309	53.72 (14)	C401—P41—C405—C406	170.1 (2)
P32—Pt3—P33—C313	−74.78 (14)	C401—P41—P42—Pt4	115.53 (13)
P32—Pt3—P33—C317	168.89 (14)	C405—P41—P42—Pt4	−111.41 (13)
P34—Pt3—P33—C309	−127.26 (14)	Pt4—P41—C401—C402	10.8 (3)
P33—Pt3—P31—P32	6.08 (8)	C405—P41—C401—C404	39.0 (3)
P32—Pt3—P31—C301	−103.22 (16)	Pt4—P41—C405—C406	−39.9 (3)
P32—Pt3—P31—C305	109.28 (14)	Pt4—P41—C405—C407	77.4 (3)
P34—Pt3—P31—P32	−177.91 (4)	P42—P41—C401—C403	51.8 (3)
P33—Pt3—P31—C301	−97.14 (16)	P42—P41—C405—C406	36.6 (3)
P33—Pt3—P31—C305	115.35 (14)	C405—P41—C401—C402	160.0 (3)
P33—Pt3—P34—C330	−56.96 (13)	C405—P41—C401—C403	−83.8 (3)
P44—Pt4—P43—C409	−126.81 (13)	Pt4—P41—C405—C408	−159.3 (2)
P44—Pt4—P43—C413	104.61 (14)	P42—P41—C405—C407	153.9 (2)
P43—Pt4—P42—P41	−176.13 (4)	P42—P41—C405—C408	−82.8 (3)
P41—Pt4—P44—C418	−113.59 (12)	Pt4—P43—C409—C411	−78.7 (3)
P41—Pt4—P44—C424	3.26 (15)	C417—P43—C413—C416	−62.0 (3)
P41—Pt4—P44—C430	123.33 (13)	Pt4—P43—C409—C412	39.8 (3)
P43—Pt4—P44—C418	64.60 (13)	Pt4—P43—C409—C410	158.2 (2)
P43—Pt4—P44—C424	−178.56 (15)	Pt4—P43—C413—C415	−66.7 (3)
P43—Pt4—P44—C430	−58.49 (13)	Pt4—P43—C413—C416	174.3 (3)
P41—Pt4—P43—C409	50.10 (15)	C409—P43—C413—C414	−80.2 (3)
P41—Pt4—P43—C413	−78.49 (15)	C409—P43—C413—C415	162.9 (2)
P41—Pt4—P43—C417	165.21 (14)	C409—P43—C413—C416	43.9 (3)
P42—Pt4—P43—C409	55.64 (13)	C417—P43—C413—C414	174.0 (3)
P42—Pt4—P43—C413	−72.95 (14)	C417—P43—C413—C415	57.0 (3)
P42—Pt4—P43—C417	170.75 (14)	Pt4—P43—C413—C414	50.3 (3)
P44—Pt4—P41—P42	−176.19 (4)	C413—P43—C409—C410	−71.3 (3)
P44—Pt4—P41—C401	80.42 (15)	C413—P43—C409—C411	51.9 (3)
P42—Pt4—P41—C401	−103.39 (15)	C413—P43—C409—C412	170.4 (2)
P42—Pt4—P41—C405	109.45 (14)	C417—P43—C409—C410	35.1 (3)
P43—Pt4—P41—P42	7.03 (8)	C417—P43—C409—C411	158.3 (3)
P43—Pt4—P41—C401	−96.36 (15)	C417—P43—C409—C412	−83.2 (3)
P43—Pt4—P41—C405	116.48 (14)	C418—P44—C430—C435	−7.3 (4)
P44—Pt4—P41—C405	−66.74 (14)	C418—P44—C424—C425	61.0 (3)
C101—P11—P12—Pt1	−116.24 (13)	C418—P44—C424—C429	−118.5 (3)
C105—P11—C101—C104	−37.1 (3)	C430—P44—C424—C425	168.0 (3)
C105—P11—P12—Pt1	110.96 (13)	C430—P44—C424—C429	−11.5 (4)
Pt1—P11—C105—C107	158.0 (2)	Pt4—P44—C430—C431	−56.2 (3)
Pt1—P11—C105—C108	−78.1 (3)	Pt4—P44—C430—C435	121.8 (3)
P12—P11—C105—C106	−37.2 (3)	C418—P44—C430—C431	174.7 (3)
P12—P11—C105—C107	81.5 (3)	Pt4—P44—C424—C425	−65.6 (3)
P12—P11—C105—C108	−154.5 (2)	Pt4—P44—C418—C419	179.5 (2)
C101—P11—C105—C106	−170.4 (2)	Pt4—P44—C418—C423	3.3 (3)
Pt1—P11—C105—C106	39.3 (3)	C424—P44—C418—C419	50.3 (3)
C101—P11—C105—C108	72.2 (3)	C424—P44—C418—C423	−125.8 (3)
Pt1—P11—C101—C104	112.0 (3)	C430—P44—C418—C419	−52.9 (3)
P12—P11—C101—C102	66.4 (3)	C430—P44—C418—C423	130.9 (3)
P12—P11—C101—C103	−49.9 (3)	C424—P44—C430—C431	74.3 (3)
P12—P11—C101—C104	−172.4 (2)	Pt4—P44—C424—C429	115.0 (3)
C105—P11—C101—C102	−158.4 (2)	C424—P44—C430—C435	−107.7 (3)
C105—P11—C101—C103	85.4 (3)	P14—C118—C123—C122	−178.3 (3)
Pt1—P11—C101—C102	−9.3 (3)	C119—C118—C123—C122	−2.4 (6)
Pt1—P11—C101—C103	−125.6 (2)	C123—C118—C119—C120	3.6 (5)
C101—P11—C105—C107	−51.7 (3)	P14—C118—C119—C120	179.3 (3)
Pt1—P13—C113—C114	−50.6 (3)	C118—C119—C120—C121	−1.9 (6)
Pt1—P13—C113—C115	67.0 (3)	C119—C120—C121—C122	−1.2 (6)
Pt1—P13—C113—C116	−174.7 (2)	C120—C121—C122—C123	2.4 (6)
C109—P13—C113—C114	80.1 (3)	C121—C122—C123—C118	−0.6 (6)
C117—P13—C109—C110	−37.7 (3)	C125—C124—C129—C128	−2.4 (6)
C117—P13—C109—C111	−160.7 (3)	C129—C124—C125—C126	2.3 (6)
C117—P13—C109—C112	81.0 (3)	P14—C124—C129—C128	177.4 (3)
Pt1—P13—C109—C111	76.2 (3)	P14—C124—C125—C126	−177.6 (3)
Pt1—P13—C109—C112	−42.2 (3)	C124—C125—C126—C127	−0.1 (6)
C113—P13—C109—C110	69.1 (3)	C125—C126—C127—C128	−1.9 (6)
C113—P13—C109—C111	−53.9 (3)	C126—C127—C128—C129	1.7 (6)
C113—P13—C109—C112	−172.3 (3)	C127—C128—C129—C124	0.5 (6)
C117—P13—C113—C116	61.8 (3)	C135—C130—C131—C132	−1.4 (5)
C109—P13—C113—C115	−162.4 (3)	C131—C130—C135—C134	0.5 (5)
Pt1—P13—C109—C110	−160.9 (2)	P14—C130—C131—C132	178.5 (3)
C117—P13—C113—C114	−174.1 (3)	P14—C130—C135—C134	−179.3 (3)
C117—P13—C113—C115	−56.5 (3)	C130—C131—C132—C133	1.2 (6)
C109—P13—C113—C116	−44.0 (3)	C131—C132—C133—C134	−0.1 (6)
C130—P14—C118—C119	49.4 (4)	C132—C133—C134—C135	−0.7 (6)
C124—P14—C118—C119	−53.6 (3)	C133—C134—C135—C130	0.5 (6)
C118—P14—C124—C129	119.1 (3)	P24—C218—C219—C220	178.1 (3)
C124—P14—C118—C123	122.1 (3)	C223—C218—C219—C220	1.5 (5)
C130—P14—C124—C129	10.5 (4)	P24—C218—C223—C222	−178.5 (3)
C130—P14—C118—C123	−134.8 (3)	C219—C218—C223—C222	−1.8 (5)
Pt1—P14—C124—C125	63.8 (3)	C218—C219—C220—C221	−0.3 (6)
Pt1—P14—C124—C129	−116.0 (3)	C219—C220—C221—C222	−0.6 (6)
C118—P14—C124—C125	−61.1 (3)	C220—C221—C222—C223	0.4 (6)
Pt1—P14—C118—C123	−6.9 (3)	C221—C222—C223—C218	0.8 (6)
C124—P14—C130—C135	106.7 (3)	C229—C224—C225—C226	1.7 (6)
Pt1—P14—C118—C119	177.4 (3)	P24—C224—C229—C228	178.2 (3)
C130—P14—C124—C125	−169.7 (3)	C225—C224—C229—C228	−2.4 (5)
Pt1—P14—C130—C131	56.9 (3)	P24—C224—C225—C226	−178.8 (3)
Pt1—P14—C130—C135	−123.3 (3)	C224—C225—C226—C227	1.2 (6)
C118—P14—C130—C131	−175.4 (3)	C225—C226—C227—C228	−3.4 (6)
C118—P14—C130—C135	4.4 (4)	C226—C227—C228—C229	2.7 (6)
C124—P14—C130—C131	−73.2 (3)	C227—C228—C229—C224	0.2 (6)
C201—P21—C205—C206	−169.9 (2)	C231—C230—C235—C234	0.2 (5)
C201—P21—C205—C207	−51.1 (3)	C235—C230—C231—C232	−1.0 (5)
C201—P21—C205—C208	72.8 (3)	P24—C230—C235—C234	179.1 (3)
Pt2—P21—C201—C203	−127.0 (2)	P24—C230—C231—C232	180.0 (3)
Pt2—P21—C201—C204	110.5 (3)	C230—C231—C232—C233	1.2 (6)
P22—P21—C201—C202	64.5 (3)	C231—C232—C233—C234	−0.5 (6)
P22—P21—C201—C203	−51.8 (3)	C232—C233—C234—C235	−0.3 (6)
P22—P21—C201—C204	−174.3 (2)	C233—C234—C235—C230	0.4 (6)
C201—P21—P22—Pt2	−115.53 (13)	P34—C318—C319—C320	−178.7 (3)
C205—P21—P22—Pt2	111.59 (13)	P34—C318—C323—C322	178.0 (3)
Pt2—P21—C201—C202	−10.7 (3)	C319—C318—C323—C322	2.6 (5)
C205—P21—C201—C204	−38.8 (3)	C323—C318—C319—C320	−3.4 (5)
Pt2—P21—C205—C206	40.0 (3)	C318—C319—C320—C321	1.7 (6)
Pt2—P21—C205—C207	158.8 (2)	C319—C320—C321—C322	1.0 (6)
Pt2—P21—C205—C208	−77.3 (3)	C320—C321—C322—C323	−1.9 (6)
P22—P21—C205—C206	−36.6 (3)	C321—C322—C323—C318	0.1 (6)
P22—P21—C205—C207	82.2 (3)	P34—C324—C329—C328	−177.3 (3)
C205—P21—C201—C203	83.7 (3)	C325—C324—C329—C328	2.7 (6)
C205—P21—C201—C202	−160.0 (3)	C329—C324—C325—C326	−2.5 (6)
P22—P21—C205—C208	−153.9 (2)	P34—C324—C325—C326	177.5 (3)
Pt2—P23—C209—C211	78.6 (3)	C324—C325—C326—C327	0.0 (6)
Pt2—P23—C209—C212	−39.7 (3)	C325—C326—C327—C328	2.5 (6)
C213—P23—C209—C211	−51.9 (3)	C326—C327—C328—C329	−2.3 (6)
C213—P23—C209—C212	−170.2 (2)	C327—C328—C329—C324	−0.3 (6)
C213—P23—C209—C210	71.5 (3)	P34—C330—C331—C332	−179.1 (3)
Pt2—P23—C209—C210	−158.1 (2)	C331—C330—C335—C334	−1.3 (5)
C209—P23—C213—C216	−43.6 (3)	C335—C330—C331—C332	2.0 (6)
C217—P23—C213—C214	−174.0 (3)	P34—C330—C335—C334	179.8 (3)
C217—P23—C213—C215	−56.7 (3)	C330—C331—C332—C333	−1.8 (6)
C217—P23—C213—C216	62.2 (3)	C331—C332—C333—C334	1.0 (6)
Pt2—P23—C213—C215	67.2 (3)	C332—C333—C334—C335	−0.4 (6)
Pt2—P23—C213—C216	−173.9 (3)	C333—C334—C335—C330	0.6 (6)
C209—P23—C213—C215	−162.4 (2)	P44—C418—C419—C420	−178.2 (3)
C217—P23—C209—C210	−34.4 (3)	C423—C418—C419—C420	−2.1 (5)
C217—P23—C209—C211	−157.8 (3)	P44—C418—C423—C422	178.4 (3)
C217—P23—C209—C212	83.9 (3)	C419—C418—C423—C422	2.1 (5)
Pt2—P23—C213—C214	−50.1 (3)	C418—C419—C420—C421	0.8 (5)
C209—P23—C213—C214	80.3 (3)	C419—C420—C421—C422	0.4 (6)
C224—P24—C230—C231	−73.9 (3)	C420—C421—C422—C423	−0.4 (6)
C224—P24—C230—C235	107.2 (3)	C421—C422—C423—C418	−0.9 (6)
C230—P24—C224—C229	10.8 (3)	P44—C424—C425—C426	178.3 (3)
Pt2—P24—C230—C231	56.7 (3)	C429—C424—C425—C426	−2.2 (6)
Pt2—P24—C230—C235	−122.2 (3)	P44—C424—C429—C428	−177.4 (3)
C218—P24—C230—C231	−174.3 (3)	C425—C424—C429—C428	3.1 (6)
C218—P24—C230—C235	6.8 (4)	C424—C425—C426—C427	−0.7 (6)
Pt2—P24—C218—C219	−179.6 (3)	C425—C426—C427—C428	2.7 (6)
Pt2—P24—C218—C223	−3.0 (3)	C426—C427—C428—C429	−1.8 (7)
C218—P24—C224—C229	117.9 (3)	C427—C428—C429—C424	−1.1 (6)
C224—P24—C218—C223	125.7 (3)	P44—C430—C431—C432	−179.5 (3)
C230—P24—C218—C219	53.2 (3)	C435—C430—C431—C432	2.4 (6)
C230—P24—C218—C223	−130.2 (3)	P44—C430—C435—C434	−179.2 (3)
Pt2—P24—C224—C225	64.8 (3)	C431—C430—C435—C434	−1.2 (5)
Pt2—P24—C224—C229	−115.8 (3)	C430—C431—C432—C433	−2.3 (6)
C218—P24—C224—C225	−61.5 (3)	C431—C432—C433—C434	0.9 (6)
C224—P24—C218—C219	−50.9 (3)	C432—C433—C434—C435	0.2 (6)
C230—P24—C224—C225	−168.7 (3)	C433—C434—C435—C430	−0.1 (6)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C111—H11E···P12	0.98	2.56	3.470 (5)	155
C211—H21D···P22	0.98	2.60	3.510 (4)	154
C311—H31F···P32	0.98	2.55	3.468 (4)	155
C411—H41D···P42	0.98	2.60	3.505 (4)	154