Download citation
Download citation
link to html
The title compound, triammonium dizinc vanadium bis(phosphate) bis(hydrogen phosphate), (NH4)3[Zn2V(PO4)2(HPO4)2], is the first ammonium zinc vanadium phosphate. It is built up from a three-dimensional network of vertex-sharing VO6 octahedra, and ZnO4, PO4, and HPO4 tetahedra, fused together via V—O—P and Zn—O—P bonds [dav(V—O) = 2.001 (2), dav(Zn—O) = 1.949 (2) and dav(P—O) = 1.538 (2) Å; θav(V—O—P) = 142.5 and θav(Zn—O—P) = 131.6°]. NH4+ cations occupy two different types of interstices in the Zn—V—P—O framework.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock ZnVPO

hkl

Structure factor file (CIF format)
Contains datablock ZnVPO

-1
Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds