metal-organic compounds
An yttrium hydrosulfide complex, [Y(H2NCH2CH2NH2)4](SH)2.72I0.28, was synthesized by solvothermal methods. The Y(en)43+ and SH- ions are well separated, and the Y atom is coordinated in a distorted square antiprism by the eight nitrogen atoms and lies on a twofold axis. The Y-N distances are in the range 2.488 (4)-2.520 (4) Å. There are two hydrosulfide sites, the one on the twofold axis being partially occupied by an iodide ion.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129183