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An yttrium hydrosulfide complex, [Y(H2NCH2CH2NH2)4](SH)2.72I0.28, was synthesized by solvothermal methods. The Y(en)43+ and SH- ions are well separated, and the Y atom is coordinated in a distorted square antiprism by the eight nitrogen atoms and lies on a twofold axis. The Y-N distances are in the range 2.488 (4)-2.520 (4) Å. There are two hydrosulfide sites, the one on the twofold axis being partially occupied by an iodide ion.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks pur47mo, global

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 129183

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