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The crystal structure of title compound, N-Benzyl-N′,N′-dimethyl-N-(2-pyridinio)-1,2-ethanediammonium tetratetrachlorocobaltate(II), (C16H23N3)[CoCl4], contains the dihydro cation of tripelennamine, an anti-allergic drug effective on H1-type receptors. The molecular dimensions in the cation are normal. Two Cl atoms of the anion are involved in hydrogen bonds with different cations, with N...Cl distances of 3.099 (5) and 3.225 (5) Å. The CoCl42− anion exhibits a slightly distorted tetrahedral geometry.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks Global, Tripelennamine_dication

hkl

Structure factor file (CIF format)
Contains datablock a

CCDC reference: 130726

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