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A new perylene salt, (C20H12)2[Cu(C8H4N2S2)2], (per)2[Cu(qdt)2], has been prepared by electrocrystallization and characterized by single-crystal X-ray diffraction. The crystal structure consists of tetramerized stacks of perylene species along the c axis, with three crystallographically independent interplanar distances: 3.50 (1), 3.42 (1), and 3.55 (1) Å, respectively. These tetramers are flanked by a centrosymmetrically related pair of [Cu(qdt)2]- anions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks per, global

hkl

Structure factor file (CIF format)
Contains datablock {sys$sysdevice:[isabel.cudtqper]percub}

CCDC reference: 129425

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