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The synthesis and crystal structure of a new allotropic form (violet crystals) of [PtCl2(creatinine)2].2H2O (creatinine is 2-amino-1-methyl-1,5-dihydro-4H-imidazol-4-one, C4H7N3O) are reported. This form differs from the two previously studied crystal forms (yellow and green crystals) by having a different intermolecular hydrogen-bonding scheme. The crystal structure of the new form is isomorphous with that reported for the corresponding palladium complex trans-[PdCl2(C4H7N3O)2].2H2O.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, global

CCDC reference: 128003

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