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The crystal structures of the complexes of 1,4-dicyanobenzene with silver(I) trifluoromethanesulphonate catena-poly[{μ-aqua-O'O)-bis[trifluoromethanesulphonato-O)silver(I)]}-di-μ-(1,4-dicyanobenzene-N:N')], [Ag2(CF3O3S)2(C8H4N2)2(H2O)]n, and catena-poly[[diμ(aqua-O,O)­disilver(I)]-μ-(1,4-benzenedinitrile-N:N')bis(hexafluorophosphate)][Ag2C8H4N2)2(H2O)2]n-(PF62n, show that irrespective of the counterion, the basic network that is formed is a chain structure. Water molecules located in the unit cell of these structures bridge a pair of adjacent chains by coordinating to silver(I) resulting in ladder-type motifs.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1, 2, global

sft

Structure factor file (SHELXL table format)
Supplementary material

sft

Structure factor file (SHELXL table format)
Supplementary material

CCDC reference: 1268824

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