The non-isomorphous crystal structures of NHC-Au-Cl and NHC-Au-Br (NHC is 1,3-dibenzyl-4,5-di­phenyl­imidazol-2-yl­idene)

Gold monochloride and monobromide can be transformed into monomeric complexes by ligands such as CO, PPh₃ or Me₂S, and such ligand-stabilized gold monochloride compounds have been investigated as catalysts, luminescent materials and anti­cancer drugs, especially when coordinated to a lipophilic benzyl-substituted N-heterocyclic carbene (NHC) ligand. The triclinic structures of NHC-Au-Cl {chlorido­(1,3-dibenzyl-4,5-di­phenyl­imidazol-2-yl­idene)gold, [AuCl(C₂₉H₂₄N₂)]} and NHC-Au-Br {bromido­(1,3-dibenzyl-4,5-di­phenyl­imidazol-2-yl­idene)gold, [AuBr(C₂₉H₂₄N₂)]}, determined by X-ray crystallography at 100 K, have one and four mol­ecules, respectively, in their asymmetric units. The chloride compound shows an almost linear C-Au-Cl fragment [179.76 (8)°], with an Au-C distance of 1.976 (3) Å and an Au-Cl distance of 2.3013 (6) Å, while the bromide compound shows surprisingly large geometry deviations, from 1.969 (12) to 2.016 (10) Å for the Au-C distance and from 2.4279 (14) to 2.4796 (12) Å for the Au-Br distance, in the four independent mol­ecules.

Computing details

Data collection: CrysAlis PRO (Agilent, 2014) for (1); CrysAlis PRO (Rigaku Oxford Diffraction, 2015) for (2). Cell refinement: CrysAlis PRO (Agilent, 2014) for (1); CrysAlis PRO (Rigaku Oxford Diffraction, 2015) for (2). Data reduction: CrysAlis PRO (Agilent, 2014) for (1); CrysAlis PRO (Rigaku Oxford Diffraction, 2015) for (2). For both compounds, program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: publCIF (Westrip, 2010).

(1) Chlorido(1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene)gold

Crystal data

[AuCl(C29H24N2)]	Z = 2
Mr = 632.92	F(000) = 616
Triclinic, P1	Dx = 1.755 Mg m^−3
Hall symbol: -P 1	Cu Kα radiation, λ = 1.54184 Å
a = 6.9686 (1) Å	Cell parameters from 19517 reflections
b = 11.8758 (2) Å	θ = 4.4–76.8°
c = 15.1008 (2) Å	µ = 12.71 mm^−1
α = 98.249 (2)°	T = 100 K
β = 95.337 (2)°	Needle, colourless
γ = 102.467 (2)°	0.15 × 0.03 × 0.02 mm
V = 1197.63 (3) Å^3

Data collection

Agilent SuperNova Dual (Cu at zero) Source diffractometer with an Atlas detector	5011 independent reflections
Radiation source: SuperNova (Cu) X-ray Source	4649 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.060
Detector resolution: 10.3196 pixels mm^-1	θmax = 76.7°, θmin = 3.9°
ω scans	h = −8→8
Absorption correction: analytical [CrysAlis PRO (Agilent, 2014), based on expressions derived by Clark & Reid (1995)]	k = −14→13
Tmin = 0.307, Tmax = 0.786	l = −18→19
47539 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.020	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.048	H-atom parameters constrained
S = 1.07	w = 1/[σ^2(Fo^2) + (0.0241P)^2 + 0.6779P] where P = (Fo^2 + 2Fc^2)/3
5011 reflections	(Δ/σ)max = 0.004
298 parameters	Δρmax = 0.84 e Å^−3
0 restraints	Δρmin = −0.85 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au1	0.255623 (16)	1.012733 (11)	0.473642 (8)	0.01793 (4)
Cl1	0.27277 (9)	1.05921 (6)	0.33134 (4)	0.02018 (13)
C1	0.3856 (4)	1.3206 (3)	0.8164 (2)	0.0236 (6)
H1	0.2572	1.3310	0.8259	0.028*
C2	0.5491 (5)	1.3815 (3)	0.8778 (2)	0.0272 (6)
H2	0.5314	1.4326	0.9292	0.033*
C3	0.7367 (5)	1.3681 (3)	0.8645 (2)	0.0304 (7)
H3	0.8478	1.4086	0.9071	0.036*
C4	0.7616 (5)	1.2950 (3)	0.7883 (3)	0.0354 (8)
H4	0.8908	1.2873	0.7779	0.042*
C5	0.5982 (4)	1.2328 (3)	0.7270 (2)	0.0279 (7)
H5	0.6162	1.1821	0.6753	0.033*
C6	0.4091 (4)	1.2448 (3)	0.74136 (19)	0.0200 (5)
C7	0.2302 (4)	1.1694 (3)	0.67845 (19)	0.0198 (5)
H7A	0.1072	1.1838	0.7009	0.024*
H7B	0.2333	1.1909	0.6175	0.024*
N1	0.2302 (3)	1.0447 (2)	0.67305 (15)	0.0166 (4)
C8	0.2404 (4)	0.9721 (2)	0.59558 (18)	0.0157 (5)
C9	0.2262 (4)	0.9865 (3)	0.74598 (19)	0.0188 (5)
C11	0.2250 (4)	1.0439 (3)	0.83980 (18)	0.0187 (5)
C12	0.3987 (4)	1.0682 (3)	0.90049 (19)	0.0220 (6)
H12	0.5130	1.0449	0.8822	0.026*
C13	0.4039 (5)	1.1264 (3)	0.9875 (2)	0.0258 (6)
H13	0.5222	1.1436	1.0286	0.031*
C14	0.2365 (5)	1.1597 (3)	1.0144 (2)	0.0285 (7)
H14	0.2407	1.1998	1.0740	0.034*
C15	0.0629 (5)	1.1347 (3)	0.9549 (2)	0.0301 (7)
H15	−0.0519	1.1568	0.9739	0.036*
C16	0.0571 (4)	1.0771 (3)	0.8673 (2)	0.0248 (6)
H16	−0.0612	1.0606	0.8262	0.030*
C10	0.2358 (4)	0.8762 (3)	0.71339 (18)	0.0171 (5)
C17	0.2350 (4)	0.7779 (3)	0.76422 (18)	0.0195 (5)
C18	0.3948 (4)	0.7249 (3)	0.77107 (19)	0.0219 (6)
H18	0.5064	0.7496	0.7410	0.026*
C19	0.3908 (5)	0.6357 (3)	0.8220 (2)	0.0257 (6)
H19	0.4989	0.5990	0.8260	0.031*
C20	0.2292 (5)	0.6004 (3)	0.8670 (2)	0.0288 (7)
H20	0.2272	0.5397	0.9019	0.035*
C21	0.0706 (5)	0.6533 (3)	0.8611 (2)	0.0317 (7)
H21	−0.0393	0.6294	0.8924	0.038*
C22	0.0722 (5)	0.7410 (3)	0.8095 (2)	0.0269 (6)
H22	−0.0376	0.7763	0.8048	0.032*
N2	0.2429 (3)	0.8686 (2)	0.62143 (15)	0.0179 (5)
C23	0.2595 (4)	0.7665 (3)	0.55930 (19)	0.0195 (5)
H23A	0.3197	0.7153	0.5940	0.023*
H23B	0.3507	0.7927	0.5159	0.023*
C24	0.0645 (4)	0.6950 (3)	0.50668 (19)	0.0186 (5)
C25	−0.1168 (4)	0.6976 (3)	0.5366 (2)	0.0217 (6)
H25	−0.1225	0.7475	0.5909	0.026*
C26	−0.2912 (4)	0.6267 (3)	0.4870 (2)	0.0254 (6)
H26	−0.4152	0.6288	0.5078	0.030*
C27	−0.2842 (5)	0.5536 (3)	0.4078 (2)	0.0265 (6)
H27	−0.4031	0.5058	0.3742	0.032*
C28	−0.1022 (5)	0.5504 (3)	0.3778 (2)	0.0278 (7)
H28	−0.0964	0.5004	0.3236	0.033*
C29	0.0710 (4)	0.6207 (3)	0.4274 (2)	0.0236 (6)
H29	0.1951	0.6180	0.4070	0.028*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.01714 (6)	0.02168 (7)	0.01443 (6)	0.00492 (4)	0.00176 (4)	0.00082 (4)
Cl1	0.0189 (3)	0.0282 (4)	0.0134 (3)	0.0053 (2)	0.0019 (2)	0.0036 (2)
C1	0.0253 (14)	0.0200 (15)	0.0257 (14)	0.0083 (11)	0.0021 (11)	0.0009 (12)
C2	0.0331 (15)	0.0214 (16)	0.0243 (14)	0.0064 (12)	−0.0012 (12)	−0.0021 (12)
C3	0.0269 (15)	0.0229 (17)	0.0356 (17)	−0.0008 (12)	−0.0055 (12)	0.0022 (13)
C4	0.0204 (14)	0.035 (2)	0.049 (2)	0.0049 (13)	0.0048 (13)	0.0020 (16)
C5	0.0245 (14)	0.0280 (17)	0.0290 (15)	0.0037 (12)	0.0077 (12)	−0.0018 (13)
C6	0.0245 (13)	0.0139 (14)	0.0219 (13)	0.0040 (10)	0.0029 (10)	0.0044 (11)
C7	0.0204 (12)	0.0187 (14)	0.0206 (13)	0.0063 (10)	−0.0005 (10)	0.0036 (11)
N1	0.0171 (10)	0.0180 (12)	0.0141 (10)	0.0049 (8)	0.0013 (8)	0.0004 (9)
C8	0.0107 (10)	0.0127 (13)	0.0222 (13)	0.0007 (9)	0.0006 (9)	0.0027 (10)
C9	0.0182 (12)	0.0205 (15)	0.0178 (13)	0.0060 (10)	0.0024 (10)	0.0017 (11)
C11	0.0250 (13)	0.0173 (14)	0.0134 (12)	0.0039 (11)	0.0030 (10)	0.0018 (10)
C12	0.0266 (14)	0.0210 (15)	0.0194 (13)	0.0083 (11)	0.0017 (11)	0.0031 (11)
C13	0.0315 (15)	0.0258 (16)	0.0174 (13)	0.0062 (12)	−0.0033 (11)	−0.0002 (12)
C14	0.0351 (16)	0.0266 (17)	0.0196 (14)	0.0031 (13)	0.0055 (12)	−0.0045 (12)
C15	0.0261 (14)	0.0358 (19)	0.0248 (15)	0.0049 (13)	0.0085 (12)	−0.0061 (13)
C16	0.0228 (13)	0.0266 (16)	0.0221 (14)	0.0032 (11)	0.0030 (11)	−0.0021 (12)
C10	0.0159 (11)	0.0187 (14)	0.0154 (12)	0.0035 (10)	0.0004 (9)	0.0007 (10)
C17	0.0256 (13)	0.0147 (14)	0.0163 (12)	0.0036 (10)	0.0008 (10)	−0.0008 (10)
C18	0.0231 (13)	0.0194 (15)	0.0203 (13)	0.0037 (11)	−0.0021 (10)	−0.0009 (11)
C19	0.0309 (15)	0.0213 (16)	0.0223 (14)	0.0059 (12)	−0.0041 (11)	0.0002 (12)
C20	0.0465 (18)	0.0171 (15)	0.0215 (14)	0.0062 (13)	0.0022 (13)	0.0026 (12)
C21	0.0414 (18)	0.0265 (18)	0.0303 (16)	0.0088 (14)	0.0165 (14)	0.0057 (13)
C22	0.0303 (15)	0.0248 (17)	0.0289 (15)	0.0092 (12)	0.0123 (12)	0.0055 (13)
N2	0.0184 (10)	0.0181 (12)	0.0159 (10)	0.0039 (9)	0.0021 (8)	−0.0005 (9)
C23	0.0207 (12)	0.0185 (14)	0.0183 (12)	0.0055 (10)	0.0028 (10)	−0.0021 (11)
C24	0.0218 (13)	0.0162 (14)	0.0181 (12)	0.0046 (10)	0.0027 (10)	0.0030 (10)
C25	0.0238 (13)	0.0193 (15)	0.0210 (13)	0.0055 (11)	0.0022 (10)	0.0003 (11)
C26	0.0217 (13)	0.0231 (16)	0.0323 (16)	0.0070 (11)	0.0048 (11)	0.0039 (12)
C27	0.0249 (14)	0.0209 (16)	0.0301 (15)	0.0014 (11)	−0.0032 (11)	0.0028 (12)
C28	0.0322 (15)	0.0251 (17)	0.0217 (14)	0.0039 (12)	0.0020 (12)	−0.0048 (12)
C29	0.0226 (13)	0.0256 (16)	0.0212 (13)	0.0046 (11)	0.0042 (11)	−0.0003 (12)

Geometric parameters (Å, º)

Au1—C8	1.976 (3)	C15—H15	0.9500
Au1—Cl1	2.3013 (6)	C16—H16	0.9500
C1—C6	1.388 (4)	C10—N2	1.385 (3)
C1—C2	1.391 (4)	C10—C17	1.486 (4)
C1—H1	0.9500	C17—C18	1.395 (4)
C2—C3	1.380 (5)	C17—C22	1.401 (4)
C2—H2	0.9500	C18—C19	1.392 (5)
C3—C4	1.386 (5)	C18—H18	0.9500
C3—H3	0.9500	C19—C20	1.387 (5)
C4—C5	1.395 (5)	C19—H19	0.9500
C4—H4	0.9500	C20—C21	1.386 (5)
C5—C6	1.389 (4)	C20—H20	0.9500
C5—H5	0.9500	C21—C22	1.387 (5)
C6—C7	1.520 (4)	C21—H21	0.9500
C7—N1	1.471 (4)	C22—H22	0.9500
C7—H7A	0.9900	N2—C23	1.455 (4)
C7—H7B	0.9900	C23—C24	1.519 (4)
N1—C8	1.367 (3)	C23—H23A	0.9900
N1—C9	1.381 (4)	C23—H23B	0.9900
C8—N2	1.346 (4)	C24—C25	1.385 (4)
C9—C10	1.350 (4)	C24—C29	1.392 (4)
C9—C11	1.483 (4)	C25—C26	1.398 (4)
C11—C16	1.393 (4)	C25—H25	0.9500
C11—C12	1.398 (4)	C26—C27	1.385 (5)
C12—C13	1.387 (4)	C26—H26	0.9500
C12—H12	0.9500	C27—C28	1.392 (5)
C13—C14	1.387 (5)	C27—H27	0.9500
C13—H13	0.9500	C28—C29	1.390 (4)
C14—C15	1.388 (5)	C28—H28	0.9500
C14—H14	0.9500	C29—H29	0.9500
C15—C16	1.392 (4)
C8—Au1—Cl1	179.76 (8)	C15—C16—H16	120.0
C6—C1—C2	120.3 (3)	C11—C16—H16	120.0
C6—C1—H1	119.8	C9—C10—N2	107.6 (3)
C2—C1—H1	119.8	C9—C10—C17	127.6 (3)
C3—C2—C1	120.5 (3)	N2—C10—C17	124.8 (3)
C3—C2—H2	119.7	C18—C17—C22	119.3 (3)
C1—C2—H2	119.7	C18—C17—C10	121.9 (3)
C2—C3—C4	119.4 (3)	C22—C17—C10	118.7 (3)
C2—C3—H3	120.3	C19—C18—C17	120.0 (3)
C4—C3—H3	120.3	C19—C18—H18	120.0
C3—C4—C5	120.4 (3)	C17—C18—H18	120.0
C3—C4—H4	119.8	C20—C19—C18	120.2 (3)
C5—C4—H4	119.8	C20—C19—H19	119.9
C6—C5—C4	120.1 (3)	C18—C19—H19	119.9
C6—C5—H5	120.0	C21—C20—C19	120.2 (3)
C4—C5—H5	120.0	C21—C20—H20	119.9
C1—C6—C5	119.3 (3)	C19—C20—H20	119.9
C1—C6—C7	120.9 (3)	C20—C21—C22	120.0 (3)
C5—C6—C7	119.8 (3)	C20—C21—H21	120.0
N1—C7—C6	110.5 (2)	C22—C21—H21	120.0
N1—C7—H7A	109.6	C21—C22—C17	120.3 (3)
C6—C7—H7A	109.6	C21—C22—H22	119.9
N1—C7—H7B	109.6	C17—C22—H22	119.9
C6—C7—H7B	109.6	C8—N2—C10	110.6 (2)
H7A—C7—H7B	108.1	C8—N2—C23	122.8 (2)
C8—N1—C9	111.1 (2)	C10—N2—C23	126.5 (3)
C8—N1—C7	124.4 (2)	N2—C23—C24	114.6 (2)
C9—N1—C7	124.5 (2)	N2—C23—H23A	108.6
N2—C8—N1	104.7 (2)	C24—C23—H23A	108.6
N2—C8—Au1	128.0 (2)	N2—C23—H23B	108.6
N1—C8—Au1	127.3 (2)	C24—C23—H23B	108.6
C10—C9—N1	106.0 (2)	H23A—C23—H23B	107.6
C10—C9—C11	130.4 (3)	C25—C24—C29	119.4 (3)
N1—C9—C11	123.5 (3)	C25—C24—C23	122.5 (3)
C16—C11—C12	119.8 (3)	C29—C24—C23	118.0 (2)
C16—C11—C9	121.3 (3)	C24—C25—C26	120.1 (3)
C12—C11—C9	118.9 (3)	C24—C25—H25	119.9
C13—C12—C11	120.0 (3)	C26—C25—H25	119.9
C13—C12—H12	120.0	C27—C26—C25	120.3 (3)
C11—C12—H12	120.0	C27—C26—H26	119.8
C14—C13—C12	120.0 (3)	C25—C26—H26	119.8
C14—C13—H13	120.0	C26—C27—C28	119.7 (3)
C12—C13—H13	120.0	C26—C27—H27	120.2
C13—C14—C15	120.4 (3)	C28—C27—H27	120.2
C13—C14—H14	119.8	C29—C28—C27	119.8 (3)
C15—C14—H14	119.8	C29—C28—H28	120.1
C14—C15—C16	119.9 (3)	C27—C28—H28	120.1
C14—C15—H15	120.0	C28—C29—C24	120.7 (3)
C16—C15—H15	120.0	C28—C29—H29	119.7
C15—C16—C11	119.9 (3)	C24—C29—H29	119.7
C6—C1—C2—C3	0.5 (5)	N1—C9—C10—C17	−179.6 (3)
C1—C2—C3—C4	1.2 (5)	C11—C9—C10—C17	4.3 (5)
C2—C3—C4—C5	−1.9 (6)	C9—C10—C17—C18	−117.8 (3)
C3—C4—C5—C6	0.8 (6)	N2—C10—C17—C18	63.6 (4)
C2—C1—C6—C5	−1.7 (5)	C9—C10—C17—C22	59.5 (4)
C2—C1—C6—C7	174.3 (3)	N2—C10—C17—C22	−119.1 (3)
C4—C5—C6—C1	1.0 (5)	C22—C17—C18—C19	0.4 (4)
C4—C5—C6—C7	−175.0 (3)	C10—C17—C18—C19	177.7 (3)
C1—C6—C7—N1	−121.6 (3)	C17—C18—C19—C20	−0.8 (4)
C5—C6—C7—N1	54.4 (4)	C18—C19—C20—C21	0.3 (5)
C6—C7—N1—C8	−118.6 (3)	C19—C20—C21—C22	0.6 (5)
C6—C7—N1—C9	59.3 (3)	C20—C21—C22—C17	−1.0 (5)
C9—N1—C8—N2	−0.1 (3)	C18—C17—C22—C21	0.4 (5)
C7—N1—C8—N2	178.0 (2)	C10—C17—C22—C21	−177.0 (3)
C9—N1—C8—Au1	−178.54 (18)	N1—C8—N2—C10	−0.4 (3)
C7—N1—C8—Au1	−0.4 (4)	Au1—C8—N2—C10	178.02 (18)
C8—N1—C9—C10	0.6 (3)	N1—C8—N2—C23	−178.0 (2)
C7—N1—C9—C10	−177.6 (2)	Au1—C8—N2—C23	0.4 (4)
C8—N1—C9—C11	177.0 (2)	C9—C10—N2—C8	0.8 (3)
C7—N1—C9—C11	−1.2 (4)	C17—C10—N2—C8	179.6 (2)
C10—C9—C11—C16	−111.8 (4)	C9—C10—N2—C23	178.2 (2)
N1—C9—C11—C16	72.7 (4)	C17—C10—N2—C23	−2.9 (4)
C10—C9—C11—C12	70.4 (4)	C8—N2—C23—C24	−84.5 (3)
N1—C9—C11—C12	−105.1 (3)	C10—N2—C23—C24	98.4 (3)
C16—C11—C12—C13	−0.7 (5)	N2—C23—C24—C25	−23.0 (4)
C9—C11—C12—C13	177.1 (3)	N2—C23—C24—C29	159.8 (3)
C11—C12—C13—C14	0.5 (5)	C29—C24—C25—C26	−0.5 (5)
C12—C13—C14—C15	0.2 (5)	C23—C24—C25—C26	−177.7 (3)
C13—C14—C15—C16	−0.8 (5)	C24—C25—C26—C27	0.0 (5)
C14—C15—C16—C11	0.6 (5)	C25—C26—C27—C28	0.2 (5)
C12—C11—C16—C15	0.1 (5)	C26—C27—C28—C29	0.0 (5)
C9—C11—C16—C15	−177.6 (3)	C27—C28—C29—C24	−0.4 (5)
N1—C9—C10—N2	−0.8 (3)	C25—C24—C29—C28	0.7 (5)
C11—C9—C10—N2	−176.9 (3)	C23—C24—C29—C28	178.0 (3)

(2) Bromido(1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene)gold

Crystal data

[AuBr(C29H24N2)]	Z = 8
Mr = 677.38	F(000) = 2608
Triclinic, P1	Dx = 1.816 Mg m^−3
Hall symbol: -P 1	Cu Kα radiation, λ = 1.54184 Å
a = 7.0973 (2) Å	Cell parameters from 33633 reflections
b = 15.3919 (3) Å	θ = 3.9–76.2°
c = 45.4224 (6) Å	µ = 13.19 mm^−1
α = 87.896 (2)°	T = 100 K
β = 87.876 (2)°	Irregular, colourless
γ = 89.871 (2)°	0.17 × 0.07 × 0.04 mm
V = 4955.23 (18) Å^3

Data collection

Agilent SuperNova Dual (Cu at zero) Source diffractometer with an Atlas detector	20595 independent reflections
Radiation source: SuperNova (Cu) X-ray Source	18809 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.055
Detector resolution: 10.3196 pixels mm^-1	θmax = 76.8°, θmin = 3.0°
ω scans	h = −8→8
Absorption correction: analytical [(CrysAlis PRO; Rigaku Oxford Diffraction, 2015), based on expressions derived by Clark & Reid (1995)]	k = −19→19
Tmin = 0.281, Tmax = 0.653	l = −56→48
106224 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.073	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.150	H-atom parameters constrained
S = 1.30	w = 1/[σ^2(Fo^2) + (0.P)^2 + 125.0771P] where P = (Fo^2 + 2Fc^2)/3
20595 reflections	(Δ/σ)max = 0.006
1189 parameters	Δρmax = 3.07 e Å^−3
0 restraints	Δρmin = −3.44 e Å^−3

Special details

Experimental. Absorption correction: Rigaku Oxford Diffraction (2015). Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by Clark & Reid (1995). Multi-scan absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1A	0.3431 (18)	0.8202 (8)	0.8456 (3)	0.030 (3)
H1A	0.4702	0.8055	0.8494	0.036*
C2A	0.215 (2)	0.8304 (8)	0.8690 (3)	0.040 (3)
H2A	0.2548	0.8224	0.8887	0.047*
C3A	0.029 (2)	0.8523 (8)	0.8637 (3)	0.039 (3)
H3A	−0.0576	0.8601	0.8798	0.047*
C4A	−0.030 (2)	0.8627 (8)	0.8351 (3)	0.037 (3)
H4A	−0.1571	0.8773	0.8315	0.044*
C5A	0.093 (2)	0.8523 (7)	0.8124 (3)	0.034 (3)
H5A	0.0495	0.8591	0.7929	0.040*
C6A	0.2873 (17)	0.8313 (6)	0.8162 (3)	0.025 (2)
C7A	0.4327 (15)	0.8254 (7)	0.7921 (2)	0.023 (2)
H7A	0.5139	0.8777	0.7922	0.028*
H7B	0.5132	0.7742	0.7963	0.028*
N1A	0.3605 (13)	0.8184 (6)	0.76246 (19)	0.0230 (19)
C8A	0.3300 (14)	0.8870 (6)	0.7437 (2)	0.020 (2)
Au1A	0.33493 (7)	1.01196 (3)	0.754069 (10)	0.02393 (10)
Br1A	0.33379 (17)	1.16683 (7)	0.76731 (3)	0.0279 (2)
C9A	0.3399 (18)	0.7405 (7)	0.7478 (2)	0.027 (2)
C11A	0.3480 (17)	0.6528 (7)	0.7628 (2)	0.026 (2)
C12A	0.1830 (19)	0.6195 (8)	0.7760 (3)	0.036 (3)
H12A	0.0707	0.6533	0.7762	0.043*
C13A	0.183 (2)	0.5366 (8)	0.7891 (3)	0.038 (3)
H13A	0.0700	0.5130	0.7979	0.045*
C14A	0.345 (2)	0.4889 (8)	0.7893 (3)	0.035 (3)
H14A	0.3440	0.4323	0.7984	0.042*
C15A	0.513 (2)	0.5218 (8)	0.7766 (3)	0.035 (3)
H15A	0.6250	0.4881	0.7769	0.042*
C16A	0.5132 (19)	0.6049 (8)	0.7634 (3)	0.033 (3)
H16A	0.6267	0.6287	0.7548	0.039*
C10A	0.3015 (16)	0.7628 (7)	0.7196 (2)	0.023 (2)
C17A	0.282 (2)	0.7048 (8)	0.6944 (3)	0.038 (3)
C18A	0.107 (3)	0.6929 (11)	0.6825 (3)	0.060 (5)
H18A	−0.0008	0.7230	0.6898	0.072*
C19A	0.091 (4)	0.6348 (14)	0.6590 (4)	0.081 (7)
H19A	−0.0267	0.6256	0.6504	0.097*
C20A	0.250 (4)	0.5922 (11)	0.6489 (4)	0.080 (7)
H20A	0.2400	0.5529	0.6334	0.095*
C21A	0.421 (4)	0.6047 (10)	0.6604 (3)	0.076 (7)
H21A	0.5289	0.5743	0.6531	0.091*
C22A	0.438 (3)	0.6627 (10)	0.6832 (3)	0.059 (5)
H22A	0.5579	0.6730	0.6909	0.071*
N2A	0.2920 (14)	0.8522 (5)	0.7176 (2)	0.0240 (19)
C23A	0.2358 (18)	0.9032 (7)	0.6914 (2)	0.029 (2)
H23A	0.2118	0.9640	0.6968	0.034*
H23B	0.1168	0.8793	0.6843	0.034*
C24A	0.3856 (19)	0.9021 (7)	0.6666 (3)	0.031 (3)
C25A	0.570 (2)	0.9275 (8)	0.6711 (3)	0.038 (3)
H25A	0.6064	0.9429	0.6901	0.045*
C26A	0.702 (2)	0.9305 (9)	0.6477 (3)	0.046 (3)
H26A	0.8280	0.9476	0.6508	0.055*
C27A	0.652 (2)	0.9088 (9)	0.6199 (3)	0.047 (4)
H27A	0.7422	0.9115	0.6039	0.057*
C28A	0.470 (2)	0.8831 (9)	0.6154 (3)	0.048 (4)
H28A	0.4353	0.8673	0.5963	0.057*
C29A	0.338 (2)	0.8802 (8)	0.6387 (3)	0.037 (3)
H29A	0.2128	0.8629	0.6354	0.045*
C1B	0.4427 (18)	0.9524 (7)	0.1697 (3)	0.030 (3)
H1B	0.4536	0.9822	0.1875	0.036*
C2B	0.5945 (19)	0.9509 (8)	0.1497 (3)	0.036 (3)
H2B	0.7082	0.9800	0.1537	0.043*
C3B	0.580 (2)	0.9073 (8)	0.1241 (3)	0.040 (3)
H3B	0.6838	0.9061	0.1103	0.048*
C4B	0.414 (2)	0.8651 (9)	0.1183 (3)	0.045 (3)
H4B	0.4055	0.8349	0.1005	0.054*
C5B	0.261 (2)	0.8663 (8)	0.1381 (3)	0.034 (3)
H5B	0.1484	0.8370	0.1339	0.041*
C6B	0.2735 (18)	0.9107 (7)	0.1642 (2)	0.028 (2)
C7B	0.1098 (18)	0.9125 (7)	0.1863 (2)	0.027 (2)
H7C	0.0788	0.9738	0.1904	0.033*
H7D	−0.0016	0.8863	0.1776	0.033*
N1B	0.1484 (15)	0.8658 (6)	0.2140 (2)	0.028 (2)
C8B	0.1816 (17)	0.9026 (7)	0.2393 (2)	0.025 (2)
Au1B	0.18212 (7)	1.02978 (3)	0.248238 (10)	0.02357 (10)
Br1B	0.17498 (15)	1.18536 (7)	0.26054 (3)	0.0233 (2)
C9B	0.1545 (18)	0.7761 (7)	0.2179 (2)	0.027 (2)
C11B	0.137 (2)	0.7159 (7)	0.1936 (3)	0.036 (3)
C12B	−0.032 (2)	0.7021 (8)	0.1797 (3)	0.041 (3)
H12B	−0.1421	0.7329	0.1856	0.049*
C13B	−0.038 (3)	0.6435 (10)	0.1573 (3)	0.053 (4)
H13B	−0.1534	0.6341	0.1480	0.064*
C14B	0.121 (3)	0.5988 (9)	0.1484 (3)	0.062 (5)
H14B	0.1137	0.5586	0.1331	0.074*
C15B	0.290 (3)	0.6120 (10)	0.1615 (3)	0.065 (6)
H15B	0.3999	0.5817	0.1552	0.079*
C16B	0.298 (3)	0.6703 (8)	0.1842 (3)	0.046 (4)
H16B	0.4137	0.6793	0.1935	0.055*
C10B	0.1910 (16)	0.7581 (7)	0.2463 (3)	0.027 (2)
C17B	0.2020 (19)	0.6717 (7)	0.2621 (2)	0.029 (3)
C18B	0.366 (2)	0.6433 (7)	0.2750 (3)	0.033 (3)
H18B	0.4759	0.6784	0.2741	0.040*
C19B	0.364 (2)	0.5610 (8)	0.2895 (3)	0.041 (3)
H19B	0.4751	0.5411	0.2988	0.050*
C20B	0.209 (2)	0.5087 (8)	0.2905 (3)	0.038 (3)
H20B	0.2115	0.4534	0.3005	0.045*
C21B	0.047 (2)	0.5368 (8)	0.2771 (3)	0.040 (3)
H21B	−0.0614	0.5005	0.2774	0.048*
C22B	0.044 (2)	0.6191 (7)	0.2631 (3)	0.034 (3)
H22B	−0.0684	0.6393	0.2543	0.040*
N2B	0.2084 (14)	0.8378 (6)	0.25939 (19)	0.025 (2)
C23B	0.264 (2)	0.8501 (7)	0.2895 (3)	0.033 (3)
H23C	0.3372	0.9048	0.2900	0.039*
H23D	0.3489	0.8018	0.2954	0.039*
C24B	0.103 (2)	0.8539 (7)	0.3117 (3)	0.032 (3)
C25B	0.139 (3)	0.8545 (11)	0.3419 (3)	0.053 (4)
H25B	0.2650	0.8494	0.3482	0.064*
C26B	−0.013 (3)	0.8626 (11)	0.3629 (3)	0.059 (5)
H26B	0.0129	0.8626	0.3833	0.071*
C27B	−0.191 (3)	0.8703 (10)	0.3545 (4)	0.059 (5)
H27B	−0.2899	0.8775	0.3688	0.071*
C28B	−0.230 (3)	0.8677 (9)	0.3255 (3)	0.051 (4)
H28B	−0.3567	0.8711	0.3194	0.061*
C29B	−0.076 (2)	0.8597 (9)	0.3041 (3)	0.043 (3)
H29B	−0.1040	0.8586	0.2838	0.051*
C1C	0.5116 (17)	0.7562 (8)	1.0067 (3)	0.033 (3)
H1C	0.4675	0.7017	1.0006	0.040*
C2C	0.381 (2)	0.8212 (10)	1.0132 (4)	0.047 (4)
H2C	0.2502	0.8115	1.0111	0.056*
C3C	0.445 (2)	0.9002 (9)	1.0226 (3)	0.044 (3)
H3C	0.3573	0.9450	1.0272	0.053*
C4C	0.634 (3)	0.9133 (10)	1.0252 (4)	0.058 (5)
H4C	0.6774	0.9671	1.0320	0.070*
C5C	0.764 (2)	0.8488 (8)	1.0180 (3)	0.044 (3)
H5C	0.8950	0.8596	1.0194	0.053*
C6C	0.7023 (17)	0.7686 (7)	1.0088 (2)	0.026 (2)
C7C	0.8403 (17)	0.6980 (8)	1.0018 (2)	0.028 (2)
H7E	0.9680	0.7236	0.9993	0.033*
H7F	0.8416	0.6555	1.0187	0.033*
N1C	0.7981 (14)	0.6523 (6)	0.97526 (19)	0.0234 (19)
C8C	0.7602 (13)	0.5679 (6)	0.9750 (2)	0.0167 (19)
Au1C	0.74818 (6)	0.47981 (3)	1.008950 (10)	0.02272 (10)
Br1C	0.72632 (17)	0.37071 (8)	1.04914 (3)	0.0301 (3)
C9C	0.7922 (16)	0.6885 (7)	0.9469 (2)	0.025 (2)
C11C	0.8128 (18)	0.7834 (7)	0.9403 (2)	0.027 (2)
C12C	0.661 (2)	0.8277 (8)	0.9283 (3)	0.039 (3)
H12C	0.5492	0.7969	0.9246	0.046*
C13C	0.672 (2)	0.9168 (9)	0.9216 (4)	0.051 (4)
H13C	0.5675	0.9466	0.9134	0.062*
C14C	0.833 (3)	0.9609 (9)	0.9269 (3)	0.060 (5)
H14C	0.8394	1.0217	0.9226	0.071*
C15C	0.988 (3)	0.9181 (10)	0.9387 (3)	0.056 (4)
H15C	1.1003	0.9490	0.9421	0.067*
C16C	0.975 (2)	0.8294 (9)	0.9453 (3)	0.043 (3)
H16C	1.0800	0.7998	0.9535	0.051*
C10C	0.7561 (16)	0.6236 (7)	0.9291 (2)	0.026 (2)
C17C	0.7538 (19)	0.6256 (7)	0.8963 (2)	0.030 (3)
C18C	0.588 (2)	0.6130 (8)	0.8815 (3)	0.034 (3)
H18C	0.4723	0.6021	0.8922	0.041*
C19C	0.592 (2)	0.6164 (8)	0.8508 (3)	0.040 (3)
H19C	0.4790	0.6083	0.8407	0.048*
C20C	0.760 (2)	0.6317 (8)	0.8349 (3)	0.040 (3)
H20C	0.7621	0.6332	0.8140	0.047*
C21C	0.925 (2)	0.6448 (8)	0.8497 (3)	0.038 (3)
H21C	1.0404	0.6562	0.8391	0.045*
C22C	0.918 (2)	0.6409 (8)	0.8806 (3)	0.036 (3)
H22C	1.0305	0.6493	0.8908	0.043*
N2C	0.7387 (13)	0.5491 (6)	0.94676 (19)	0.0225 (19)
C23C	0.6857 (16)	0.4633 (7)	0.9368 (3)	0.026 (2)
H23E	0.6152	0.4712	0.9185	0.031*
H23F	0.5994	0.4354	0.9520	0.031*
C24C	0.8503 (18)	0.4022 (7)	0.9310 (2)	0.029 (2)
C25C	1.0318 (16)	0.4336 (7)	0.9252 (2)	0.025 (2)
H25C	1.0561	0.4942	0.9258	0.030*
C26C	1.1783 (18)	0.3763 (9)	0.9186 (3)	0.035 (3)
H26C	1.3022	0.3978	0.9145	0.042*
C27C	1.144 (2)	0.2886 (9)	0.9181 (3)	0.040 (3)
H27C	1.2443	0.2499	0.9137	0.048*
C28C	0.968 (2)	0.2565 (8)	0.9237 (3)	0.042 (3)
H28C	0.9451	0.1958	0.9232	0.051*
C29C	0.818 (2)	0.3142 (8)	0.9303 (3)	0.034 (3)
H29C	0.6942	0.2921	0.9343	0.040*
C1D	0.818 (2)	0.3224 (8)	0.4247 (3)	0.043 (3)
H1D	0.6916	0.3022	0.4274	0.052*
C2D	0.960 (3)	0.2647 (10)	0.4180 (4)	0.056 (4)
H2D	0.9314	0.2048	0.4165	0.067*
C3D	1.144 (2)	0.2925 (10)	0.4132 (4)	0.053 (4)
H3D	1.2409	0.2526	0.4082	0.063*
C4D	1.184 (2)	0.3801 (9)	0.4161 (3)	0.041 (3)
H4D	1.3100	0.3999	0.4131	0.049*
C5D	1.043 (2)	0.4387 (8)	0.4230 (3)	0.036 (3)
H5D	1.0722	0.4984	0.4246	0.043*
C6D	0.8578 (18)	0.4105 (7)	0.4277 (2)	0.028 (2)
C7D	0.6953 (18)	0.4729 (7)	0.4342 (3)	0.030 (3)
H7G	0.6274	0.4845	0.4158	0.036*
H7H	0.6057	0.4443	0.4487	0.036*
N1D	0.7538 (14)	0.5558 (6)	0.4456 (2)	0.0248 (19)
C8D	0.7812 (15)	0.5676 (8)	0.4746 (3)	0.026 (2)
Au1D	0.74653 (7)	0.48120 (3)	0.507417 (10)	0.02840 (11)
Br1D	0.70158 (19)	0.37241 (10)	0.54711 (3)	0.0378 (3)
C9D	0.7804 (17)	0.6319 (7)	0.4287 (2)	0.025 (2)
C11D	0.7668 (17)	0.6376 (7)	0.3962 (2)	0.026 (2)
C12D	0.9307 (19)	0.6365 (8)	0.3785 (3)	0.033 (3)
H12D	1.0494	0.6326	0.3874	0.040*
C13D	0.925 (2)	0.6409 (9)	0.3480 (3)	0.038 (3)
H13D	1.0372	0.6392	0.3361	0.046*
C14D	0.750 (2)	0.6478 (8)	0.3353 (3)	0.039 (3)
H14D	0.7436	0.6519	0.3144	0.046*
C15D	0.585 (2)	0.6489 (9)	0.3525 (3)	0.041 (3)
H15D	0.4665	0.6528	0.3435	0.050*
C16D	0.5951 (19)	0.6442 (8)	0.3830 (3)	0.033 (3)
H16D	0.4823	0.6455	0.3950	0.040*
C10D	0.8214 (17)	0.6933 (8)	0.4479 (2)	0.029 (2)
C17D	0.852 (2)	0.7895 (8)	0.4429 (3)	0.035 (3)
C18D	1.024 (2)	0.8274 (10)	0.4463 (3)	0.049 (4)
H18D	1.1290	0.7929	0.4517	0.059*
C19D	1.043 (3)	0.9178 (11)	0.4416 (4)	0.062 (5)
H19D	1.1618	0.9447	0.4441	0.074*
C20D	0.891 (4)	0.9669 (11)	0.4336 (4)	0.075 (7)
H20D	0.9048	1.0280	0.4306	0.090*
C21D	0.720 (3)	0.9297 (9)	0.4298 (3)	0.065 (6)
H21D	0.6166	0.9648	0.4239	0.077*
C22D	0.696 (3)	0.8391 (8)	0.4346 (3)	0.046 (4)
H22D	0.5773	0.8125	0.4322	0.055*
N2D	0.8220 (15)	0.6538 (6)	0.4757 (2)	0.030 (2)
C23D	0.8654 (19)	0.6967 (8)	0.5030 (2)	0.033 (3)
H23G	0.9917	0.7238	0.5006	0.039*
H23H	0.8693	0.6526	0.5194	0.039*
C24D	0.7224 (18)	0.7653 (8)	0.5107 (2)	0.032 (3)
C25D	0.778 (3)	0.8494 (9)	0.5159 (3)	0.051 (4)
H25D	0.9087	0.8637	0.5152	0.062*
C26D	0.645 (3)	0.9131 (11)	0.5222 (4)	0.069 (6)
H26D	0.6843	0.9706	0.5257	0.082*
C27D	0.454 (3)	0.8929 (11)	0.5233 (4)	0.066 (5)
H27D	0.3628	0.9363	0.5276	0.079*
C28D	0.398 (2)	0.8103 (11)	0.5180 (4)	0.056 (4)
H28D	0.2678	0.7961	0.5185	0.067*
C29D	0.532 (2)	0.7470 (8)	0.5120 (3)	0.042 (3)
H29D	0.4921	0.6895	0.5087	0.050*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1A	0.035 (7)	0.028 (6)	0.028 (6)	−0.003 (5)	−0.006 (5)	0.000 (5)
C2A	0.061 (9)	0.035 (7)	0.022 (6)	−0.011 (6)	0.000 (6)	0.000 (5)
C3A	0.062 (9)	0.027 (6)	0.026 (6)	−0.004 (6)	0.012 (6)	−0.004 (5)
C4A	0.046 (8)	0.021 (6)	0.043 (7)	−0.004 (5)	0.008 (6)	−0.001 (5)
C5A	0.055 (8)	0.022 (6)	0.023 (6)	0.008 (5)	0.004 (5)	0.001 (4)
C6A	0.035 (6)	0.010 (4)	0.032 (6)	0.000 (4)	−0.007 (5)	−0.007 (4)
C7A	0.021 (5)	0.022 (5)	0.028 (6)	0.003 (4)	0.000 (4)	−0.003 (4)
N1A	0.027 (5)	0.023 (4)	0.020 (4)	0.006 (4)	−0.001 (4)	−0.005 (3)
C8A	0.017 (5)	0.016 (5)	0.027 (5)	−0.001 (4)	0.001 (4)	−0.007 (4)
Au1A	0.0293 (2)	0.0163 (2)	0.0264 (2)	0.00075 (17)	0.00005 (17)	−0.00331 (16)
Br1A	0.0273 (6)	0.0182 (5)	0.0382 (6)	−0.0004 (4)	0.0008 (5)	−0.0058 (4)
C9A	0.043 (7)	0.015 (5)	0.022 (5)	−0.010 (5)	0.003 (5)	−0.006 (4)
C11A	0.038 (7)	0.025 (6)	0.016 (5)	0.005 (5)	−0.003 (4)	0.000 (4)
C12A	0.041 (8)	0.024 (6)	0.041 (7)	0.008 (5)	0.014 (6)	0.002 (5)
C13A	0.045 (8)	0.024 (6)	0.044 (8)	0.001 (5)	0.008 (6)	0.007 (5)
C14A	0.059 (9)	0.026 (6)	0.021 (6)	0.000 (6)	−0.004 (5)	0.002 (4)
C15A	0.047 (8)	0.024 (6)	0.035 (7)	0.007 (5)	−0.003 (6)	0.002 (5)
C16A	0.043 (7)	0.025 (6)	0.031 (6)	0.001 (5)	−0.005 (5)	0.004 (5)
C10A	0.027 (6)	0.016 (5)	0.027 (6)	0.002 (4)	0.002 (4)	−0.004 (4)
C17A	0.074 (10)	0.020 (6)	0.021 (6)	−0.013 (6)	−0.004 (6)	0.003 (4)
C18A	0.090 (13)	0.062 (10)	0.027 (7)	−0.033 (9)	0.006 (8)	−0.010 (7)
C19A	0.14 (2)	0.076 (13)	0.030 (8)	−0.064 (14)	0.001 (10)	−0.005 (8)
C20A	0.18 (2)	0.035 (8)	0.026 (8)	−0.020 (11)	−0.009 (12)	−0.005 (6)
C21A	0.16 (2)	0.040 (9)	0.031 (8)	0.039 (11)	−0.022 (11)	−0.012 (7)
C22A	0.103 (14)	0.043 (8)	0.033 (8)	0.042 (9)	−0.022 (8)	−0.017 (6)
N2A	0.035 (5)	0.013 (4)	0.025 (5)	−0.008 (4)	−0.004 (4)	−0.003 (3)
C23A	0.038 (7)	0.024 (5)	0.024 (6)	0.002 (5)	0.001 (5)	0.000 (4)
C24A	0.043 (7)	0.022 (5)	0.027 (6)	0.005 (5)	−0.007 (5)	−0.001 (4)
C25A	0.043 (8)	0.032 (7)	0.038 (7)	−0.008 (6)	0.007 (6)	0.003 (5)
C26A	0.042 (8)	0.040 (8)	0.055 (9)	−0.001 (6)	0.009 (7)	0.001 (6)
C27A	0.069 (11)	0.033 (7)	0.037 (8)	0.009 (7)	0.020 (7)	0.005 (6)
C28A	0.073 (11)	0.040 (8)	0.029 (7)	0.015 (7)	0.007 (7)	0.000 (6)
C29A	0.056 (9)	0.031 (6)	0.025 (6)	0.004 (6)	−0.006 (6)	0.000 (5)
C1B	0.041 (7)	0.022 (5)	0.027 (6)	0.003 (5)	−0.009 (5)	−0.002 (4)
C2B	0.035 (7)	0.029 (6)	0.044 (7)	−0.002 (5)	−0.001 (6)	−0.001 (5)
C3B	0.042 (8)	0.034 (7)	0.042 (8)	0.007 (6)	0.008 (6)	0.001 (5)
C4B	0.060 (10)	0.042 (8)	0.033 (7)	−0.005 (7)	0.004 (6)	−0.011 (6)
C5B	0.046 (8)	0.028 (6)	0.030 (6)	−0.002 (5)	−0.005 (5)	−0.005 (5)
C6B	0.043 (7)	0.018 (5)	0.024 (6)	0.004 (5)	−0.005 (5)	0.002 (4)
C7B	0.040 (7)	0.017 (5)	0.026 (6)	0.005 (5)	−0.007 (5)	0.001 (4)
N1B	0.042 (6)	0.019 (4)	0.023 (5)	0.003 (4)	−0.006 (4)	−0.002 (4)
C8B	0.035 (6)	0.022 (5)	0.020 (5)	0.009 (4)	−0.003 (4)	−0.008 (4)
Au1B	0.0284 (2)	0.0167 (2)	0.0259 (2)	0.00010 (16)	−0.00121 (17)	−0.00330 (16)
Br1B	0.0186 (5)	0.0169 (5)	0.0345 (6)	−0.0001 (4)	0.0005 (4)	−0.0041 (4)
C9B	0.043 (7)	0.016 (5)	0.022 (5)	−0.001 (5)	−0.004 (5)	−0.001 (4)
C11B	0.071 (10)	0.015 (5)	0.021 (6)	−0.005 (5)	−0.008 (6)	0.000 (4)
C12B	0.068 (10)	0.032 (7)	0.022 (6)	−0.016 (6)	−0.003 (6)	0.003 (5)
C13B	0.091 (13)	0.045 (8)	0.024 (7)	−0.033 (8)	−0.007 (7)	0.000 (6)
C14B	0.137 (18)	0.020 (6)	0.028 (7)	−0.015 (8)	−0.011 (9)	−0.004 (5)
C15B	0.128 (17)	0.033 (8)	0.038 (8)	0.026 (9)	−0.023 (10)	−0.005 (6)
C16B	0.082 (11)	0.026 (6)	0.031 (7)	0.013 (7)	−0.013 (7)	−0.007 (5)
C10B	0.026 (6)	0.023 (5)	0.033 (6)	0.017 (4)	0.001 (5)	−0.005 (4)
C17B	0.050 (8)	0.013 (5)	0.023 (5)	0.000 (5)	0.002 (5)	−0.006 (4)
C18B	0.046 (8)	0.019 (5)	0.036 (7)	0.005 (5)	−0.013 (6)	0.001 (5)
C19B	0.068 (10)	0.024 (6)	0.032 (7)	0.007 (6)	−0.007 (6)	0.002 (5)
C20B	0.067 (10)	0.021 (6)	0.025 (6)	0.001 (6)	−0.003 (6)	0.002 (4)
C21B	0.059 (9)	0.024 (6)	0.035 (7)	−0.004 (6)	0.006 (6)	0.000 (5)
C22B	0.045 (8)	0.021 (6)	0.036 (7)	−0.001 (5)	−0.005 (5)	−0.001 (5)
N2B	0.038 (6)	0.021 (4)	0.018 (4)	0.000 (4)	−0.003 (4)	−0.002 (3)
C23B	0.054 (8)	0.020 (5)	0.025 (6)	−0.001 (5)	−0.012 (5)	−0.001 (4)
C24B	0.054 (8)	0.022 (6)	0.020 (6)	−0.006 (5)	−0.002 (5)	0.001 (4)
C25B	0.072 (12)	0.058 (10)	0.031 (7)	−0.016 (8)	−0.006 (7)	−0.005 (6)
C26B	0.099 (15)	0.055 (10)	0.024 (7)	−0.020 (9)	0.004 (8)	−0.007 (6)
C27B	0.085 (14)	0.043 (9)	0.047 (9)	−0.007 (8)	0.016 (9)	−0.003 (7)
C28B	0.075 (11)	0.034 (7)	0.041 (8)	0.012 (7)	0.015 (7)	0.009 (6)
C29B	0.056 (9)	0.038 (7)	0.033 (7)	0.009 (6)	−0.001 (6)	0.008 (6)
C1C	0.026 (6)	0.023 (6)	0.050 (8)	0.002 (5)	0.010 (5)	−0.011 (5)
C2C	0.038 (8)	0.043 (8)	0.060 (9)	0.006 (6)	0.010 (7)	−0.012 (7)
C3C	0.053 (9)	0.035 (7)	0.045 (8)	0.015 (6)	−0.006 (7)	−0.010 (6)
C4C	0.068 (11)	0.036 (8)	0.076 (12)	0.013 (7)	−0.025 (9)	−0.029 (8)
C5C	0.049 (9)	0.028 (6)	0.058 (9)	−0.002 (6)	−0.022 (7)	−0.013 (6)
C6C	0.030 (6)	0.028 (6)	0.020 (5)	0.006 (5)	−0.004 (4)	−0.001 (4)
C7C	0.033 (6)	0.031 (6)	0.019 (5)	0.005 (5)	−0.008 (4)	−0.004 (4)
N1C	0.033 (5)	0.018 (4)	0.020 (4)	0.002 (4)	−0.008 (4)	−0.003 (3)
C8C	0.003 (4)	0.014 (4)	0.033 (6)	−0.002 (3)	−0.005 (4)	−0.005 (4)
Au1C	0.0233 (2)	0.0203 (2)	0.0244 (2)	0.00140 (17)	−0.00110 (17)	0.00043 (16)
Br1C	0.0260 (6)	0.0347 (6)	0.0295 (6)	−0.0004 (5)	−0.0018 (5)	0.0035 (5)
C9C	0.028 (6)	0.018 (5)	0.028 (6)	0.008 (4)	0.005 (4)	−0.001 (4)
C11C	0.040 (7)	0.018 (5)	0.023 (6)	0.000 (5)	0.001 (5)	−0.004 (4)
C12C	0.042 (8)	0.029 (6)	0.044 (8)	0.007 (5)	0.010 (6)	0.003 (5)
C13C	0.067 (11)	0.027 (7)	0.058 (10)	0.017 (7)	0.019 (8)	0.006 (6)
C14C	0.115 (16)	0.021 (6)	0.040 (8)	0.001 (8)	0.027 (9)	−0.003 (6)
C15C	0.091 (13)	0.033 (8)	0.044 (9)	−0.024 (8)	0.000 (8)	−0.011 (6)
C16C	0.068 (10)	0.033 (7)	0.027 (6)	−0.012 (6)	−0.008 (6)	0.002 (5)
C10C	0.026 (6)	0.025 (5)	0.026 (6)	−0.001 (4)	−0.004 (4)	−0.001 (4)
C17C	0.047 (8)	0.020 (5)	0.022 (6)	0.010 (5)	−0.006 (5)	−0.002 (4)
C18C	0.044 (8)	0.029 (6)	0.031 (6)	0.011 (5)	−0.007 (5)	−0.006 (5)
C19C	0.059 (9)	0.032 (7)	0.032 (7)	0.012 (6)	−0.015 (6)	−0.011 (5)
C20C	0.067 (10)	0.029 (6)	0.024 (6)	0.007 (6)	−0.006 (6)	−0.002 (5)
C21C	0.056 (9)	0.027 (6)	0.029 (6)	−0.002 (6)	0.005 (6)	−0.001 (5)
C22C	0.055 (9)	0.026 (6)	0.025 (6)	−0.001 (6)	−0.001 (6)	0.000 (5)
N2C	0.029 (5)	0.018 (4)	0.020 (4)	0.006 (4)	−0.002 (4)	0.000 (3)
C23C	0.021 (6)	0.021 (5)	0.036 (6)	0.004 (4)	−0.005 (5)	−0.001 (4)
C24C	0.041 (7)	0.026 (6)	0.021 (5)	0.000 (5)	−0.008 (5)	0.003 (4)
C25C	0.026 (6)	0.023 (5)	0.028 (6)	0.003 (4)	−0.008 (4)	−0.002 (4)
C26C	0.028 (7)	0.048 (8)	0.029 (6)	0.002 (5)	−0.002 (5)	−0.005 (5)
C27C	0.046 (8)	0.035 (7)	0.039 (7)	0.016 (6)	−0.006 (6)	−0.016 (5)
C28C	0.058 (9)	0.024 (6)	0.045 (8)	0.010 (6)	−0.010 (7)	−0.006 (5)
C29C	0.046 (8)	0.023 (6)	0.033 (6)	−0.001 (5)	−0.005 (5)	−0.001 (5)
C1D	0.046 (8)	0.027 (6)	0.057 (9)	0.001 (6)	−0.011 (7)	−0.003 (6)
C2D	0.071 (12)	0.029 (7)	0.070 (11)	0.010 (7)	−0.020 (9)	−0.015 (7)
C3D	0.061 (11)	0.046 (8)	0.053 (9)	0.024 (8)	−0.010 (8)	−0.020 (7)
C4D	0.040 (8)	0.046 (8)	0.038 (7)	0.009 (6)	−0.009 (6)	−0.009 (6)
C5D	0.045 (8)	0.032 (6)	0.030 (6)	0.007 (6)	−0.002 (5)	−0.005 (5)
C6D	0.039 (7)	0.023 (5)	0.022 (5)	0.004 (5)	−0.003 (5)	−0.002 (4)
C7D	0.045 (7)	0.025 (6)	0.021 (5)	−0.006 (5)	−0.002 (5)	0.002 (4)
N1D	0.031 (5)	0.022 (4)	0.021 (5)	0.004 (4)	−0.001 (4)	−0.001 (3)
C8D	0.011 (5)	0.037 (6)	0.030 (6)	0.012 (4)	−0.005 (4)	−0.007 (5)
Au1D	0.0335 (3)	0.0281 (2)	0.0234 (2)	0.00435 (19)	−0.00027 (19)	0.00187 (18)
Br1D	0.0332 (7)	0.0502 (8)	0.0291 (6)	0.0015 (6)	0.0015 (5)	0.0060 (5)
C9D	0.036 (6)	0.016 (5)	0.023 (5)	0.003 (4)	0.004 (4)	−0.002 (4)
C11D	0.039 (7)	0.016 (5)	0.025 (6)	0.001 (4)	−0.002 (5)	−0.001 (4)
C12D	0.035 (7)	0.033 (6)	0.032 (6)	0.003 (5)	−0.003 (5)	−0.004 (5)
C13D	0.051 (9)	0.038 (7)	0.026 (6)	0.001 (6)	0.003 (6)	−0.006 (5)
C14D	0.066 (10)	0.025 (6)	0.024 (6)	0.005 (6)	−0.004 (6)	−0.004 (5)
C15D	0.047 (8)	0.046 (8)	0.030 (7)	0.002 (6)	−0.002 (6)	0.000 (6)
C16D	0.040 (7)	0.032 (6)	0.029 (6)	0.003 (5)	−0.003 (5)	−0.003 (5)
C10D	0.029 (6)	0.037 (6)	0.021 (5)	0.005 (5)	−0.010 (4)	−0.004 (5)
C17D	0.059 (9)	0.030 (6)	0.017 (5)	−0.001 (6)	0.001 (5)	−0.004 (4)
C18D	0.066 (11)	0.046 (8)	0.036 (8)	−0.013 (7)	−0.006 (7)	−0.005 (6)
C19D	0.102 (15)	0.040 (9)	0.044 (9)	−0.028 (9)	0.003 (9)	−0.005 (7)
C20D	0.15 (2)	0.027 (8)	0.045 (10)	−0.017 (11)	0.024 (11)	−0.016 (7)
C21D	0.136 (18)	0.024 (7)	0.033 (8)	0.018 (9)	0.014 (9)	−0.003 (6)
C22D	0.085 (12)	0.023 (6)	0.029 (7)	0.007 (7)	0.001 (7)	−0.003 (5)
N2D	0.036 (6)	0.029 (5)	0.025 (5)	0.005 (4)	0.001 (4)	−0.004 (4)
C23D	0.046 (8)	0.037 (7)	0.016 (5)	0.004 (5)	−0.012 (5)	−0.003 (5)
C24D	0.038 (7)	0.041 (7)	0.017 (5)	0.001 (5)	0.001 (5)	−0.001 (5)
C25D	0.069 (11)	0.038 (8)	0.050 (9)	0.005 (7)	−0.021 (8)	−0.016 (6)
C26D	0.097 (16)	0.045 (9)	0.067 (12)	0.013 (9)	−0.026 (11)	−0.031 (8)
C27D	0.097 (15)	0.047 (9)	0.055 (10)	0.033 (10)	−0.016 (10)	−0.023 (8)
C28D	0.053 (10)	0.068 (11)	0.049 (9)	0.014 (8)	−0.001 (7)	−0.016 (8)
C29D	0.060 (9)	0.027 (6)	0.038 (7)	0.009 (6)	0.008 (6)	−0.009 (5)

Geometric parameters (Å, º)

C1A—C2A	1.385 (18)	C1C—C6C	1.375 (17)
C1A—C6A	1.412 (16)	C1C—C2C	1.394 (17)
C1A—H1A	0.9500	C1C—H1C	0.9500
C2A—C3A	1.39 (2)	C2C—C3C	1.38 (2)
C2A—H2A	0.9500	C2C—H2C	0.9500
C3A—C4A	1.387 (19)	C3C—C4C	1.37 (2)
C3A—H3A	0.9500	C3C—H3C	0.9500
C4A—C5A	1.340 (18)	C4C—C5C	1.39 (2)
C4A—H4A	0.9500	C4C—H4C	0.9500
C5A—C6A	1.430 (18)	C5C—C6C	1.394 (17)
C5A—H5A	0.9500	C5C—H5C	0.9500
C6A—C7A	1.481 (16)	C6C—C7C	1.497 (16)
C7A—N1A	1.466 (14)	C7C—N1C	1.460 (13)
C7A—H7A	0.9900	C7C—H7E	0.9900
C7A—H7B	0.9900	C7C—H7F	0.9900
N1A—C8A	1.354 (14)	N1C—C8C	1.328 (13)
N1A—C9A	1.404 (13)	N1C—C9C	1.385 (14)
C8A—N2A	1.356 (13)	C8C—N2C	1.339 (13)
C8A—Au1A	1.997 (10)	C8C—Au1C	2.016 (10)
Au1A—Br1A	2.4796 (12)	Au1C—Br1C	2.4354 (13)
C9A—C10A	1.349 (16)	C9C—C10C	1.341 (15)
C9A—C11A	1.491 (15)	C9C—C11C	1.486 (15)
C11A—C16A	1.384 (17)	C11C—C16C	1.385 (19)
C11A—C12A	1.387 (18)	C11C—C12C	1.390 (18)
C12A—C13A	1.387 (16)	C12C—C13C	1.396 (18)
C12A—H12A	0.9500	C12C—H12C	0.9500
C13A—C14A	1.365 (19)	C13C—C14C	1.36 (3)
C13A—H13A	0.9500	C13C—H13C	0.9500
C14A—C15A	1.389 (19)	C14C—C15C	1.40 (3)
C14A—H14A	0.9500	C14C—H14C	0.9500
C15A—C16A	1.394 (16)	C15C—C16C	1.389 (19)
C15A—H15A	0.9500	C15C—H15C	0.9500
C16A—H16A	0.9500	C16C—H16C	0.9500
C10A—N2A	1.377 (13)	C10C—N2C	1.379 (14)
C10A—C17A	1.491 (15)	C10C—C17C	1.487 (15)
C17A—C22A	1.37 (2)	C17C—C22C	1.360 (19)
C17A—C18A	1.39 (2)	C17C—C18C	1.398 (18)
C18A—C19A	1.42 (2)	C18C—C19C	1.391 (18)
C18A—H18A	0.9500	C18C—H18C	0.9500
C19A—C20A	1.38 (3)	C19C—C20C	1.39 (2)
C19A—H19A	0.9500	C19C—H19C	0.9500
C20A—C21A	1.36 (3)	C20C—C21C	1.39 (2)
C20A—H20A	0.9500	C20C—H20C	0.9500
C21A—C22A	1.40 (2)	C21C—C22C	1.401 (17)
C21A—H21A	0.9500	C21C—H21C	0.9500
C22A—H22A	0.9500	C22C—H22C	0.9500
N2A—C23A	1.470 (14)	N2C—C23C	1.466 (14)
C23A—C24A	1.520 (17)	C23C—C24C	1.519 (16)
C23A—H23A	0.9900	C23C—H23E	0.9900
C23A—H23B	0.9900	C23C—H23F	0.9900
C24A—C29A	1.376 (17)	C24C—C29C	1.376 (16)
C24A—C25A	1.394 (19)	C24C—C25C	1.390 (17)
C25A—C26A	1.389 (19)	C25C—C26C	1.393 (17)
C25A—H25A	0.9500	C25C—H25C	0.9500
C26A—C27A	1.38 (2)	C26C—C27C	1.374 (19)
C26A—H26A	0.9500	C26C—H26C	0.9500
C27A—C28A	1.37 (2)	C27C—C28C	1.36 (2)
C27A—H27A	0.9500	C27C—H27C	0.9500
C28A—C29A	1.39 (2)	C28C—C29C	1.414 (19)
C28A—H28A	0.9500	C28C—H28C	0.9500
C29A—H29A	0.9500	C29C—H29C	0.9500
C1B—C2B	1.384 (18)	C1D—C2D	1.38 (2)
C1B—C6B	1.397 (17)	C1D—C6D	1.399 (17)
C1B—H1B	0.9500	C1D—H1D	0.9500
C2B—C3B	1.371 (19)	C2D—C3D	1.38 (2)
C2B—H2B	0.9500	C2D—H2D	0.9500
C3B—C4B	1.38 (2)	C3D—C4D	1.39 (2)
C3B—H3B	0.9500	C3D—H3D	0.9500
C4B—C5B	1.383 (19)	C4D—C5D	1.383 (18)
C4B—H4B	0.9500	C4D—H4D	0.9500
C5B—C6B	1.395 (16)	C5D—C6D	1.390 (19)
C5B—H5B	0.9500	C5D—H5D	0.9500
C6B—C7B	1.508 (17)	C6D—C7D	1.526 (17)
C7B—N1B	1.463 (14)	C7D—N1D	1.462 (14)
C7B—H7C	0.9900	C7D—H7G	0.9900
C7B—H7D	0.9900	C7D—H7H	0.9900
N1B—C8B	1.328 (14)	N1D—C8D	1.359 (14)
N1B—C9B	1.386 (14)	N1D—C9D	1.386 (14)
C8B—N2B	1.345 (14)	C8D—N2D	1.361 (15)
C8B—Au1B	2.013 (11)	C8D—Au1D	1.969 (12)
Au1B—Br1B	2.4789 (11)	Au1D—Br1D	2.4279 (14)
C9B—C10B	1.343 (16)	C9D—C10D	1.350 (16)
C9B—C11B	1.476 (15)	C9D—C11D	1.482 (15)
C11B—C12B	1.39 (2)	C11D—C16D	1.379 (17)
C11B—C16B	1.40 (2)	C11D—C12D	1.391 (17)
C12B—C13B	1.386 (19)	C12D—C13D	1.386 (17)
C12B—H12B	0.9500	C12D—H12D	0.9500
C13B—C14B	1.37 (3)	C13D—C14D	1.39 (2)
C13B—H13B	0.9500	C13D—H13D	0.9500
C14B—C15B	1.38 (3)	C14D—C15D	1.38 (2)
C14B—H14B	0.9500	C14D—H14D	0.9500
C15B—C16B	1.395 (19)	C15D—C16D	1.392 (18)
C15B—H15B	0.9500	C15D—H15D	0.9500
C16B—H16B	0.9500	C16D—H16D	0.9500
C10B—N2B	1.391 (14)	C10D—N2D	1.382 (15)
C10B—C17B	1.492 (15)	C10D—C17D	1.504 (17)
C17B—C18B	1.385 (17)	C17D—C18D	1.37 (2)
C17B—C22B	1.385 (18)	C17D—C22D	1.40 (2)
C18B—C19B	1.405 (16)	C18D—C19D	1.40 (2)
C18B—H18B	0.9500	C18D—H18D	0.9500
C19B—C20B	1.37 (2)	C19D—C20D	1.37 (3)
C19B—H19B	0.9500	C19D—H19D	0.9500
C20B—C21B	1.38 (2)	C20D—C21D	1.36 (3)
C20B—H20B	0.9500	C20D—H20D	0.9500
C21B—C22B	1.396 (17)	C21D—C22D	1.415 (19)
C21B—H21B	0.9500	C21D—H21D	0.9500
C22B—H22B	0.9500	C22D—H22D	0.9500
N2B—C23B	1.458 (14)	N2D—C23D	1.467 (14)
C23B—C24B	1.501 (18)	C23D—C24D	1.506 (18)
C23B—H23C	0.9900	C23D—H23G	0.9900
C23B—H23D	0.9900	C23D—H23H	0.9900
C24B—C29B	1.33 (2)	C24D—C29D	1.38 (2)
C24B—C25B	1.402 (18)	C24D—C25D	1.386 (19)
C25B—C26B	1.42 (2)	C25D—C26D	1.39 (2)
C25B—H25B	0.9500	C25D—H25D	0.9500
C26B—C27B	1.34 (3)	C26D—C27D	1.39 (3)
C26B—H26B	0.9500	C26D—H26D	0.9500
C27B—C28B	1.36 (2)	C27D—C28D	1.37 (2)
C27B—H27B	0.9500	C27D—H27D	0.9500
C28B—C29B	1.44 (2)	C28D—C29D	1.39 (2)
C28B—H28B	0.9500	C28D—H28D	0.9500
C29B—H29B	0.9500	C29D—H29D	0.9500
C2A—C1A—C6A	121.0 (12)	C6C—C1C—C2C	121.9 (12)
C2A—C1A—H1A	119.5	C6C—C1C—H1C	119.0
C6A—C1A—H1A	119.5	C2C—C1C—H1C	119.0
C1A—C2A—C3A	120.0 (12)	C3C—C2C—C1C	119.2 (14)
C1A—C2A—H2A	120.0	C3C—C2C—H2C	120.4
C3A—C2A—H2A	120.0	C1C—C2C—H2C	120.4
C4A—C3A—C2A	120.2 (12)	C4C—C3C—C2C	119.6 (13)
C4A—C3A—H3A	119.9	C4C—C3C—H3C	120.2
C2A—C3A—H3A	119.9	C2C—C3C—H3C	120.2
C5A—C4A—C3A	120.0 (14)	C3C—C4C—C5C	120.8 (14)
C5A—C4A—H4A	120.0	C3C—C4C—H4C	119.6
C3A—C4A—H4A	120.0	C5C—C4C—H4C	119.6
C4A—C5A—C6A	122.7 (12)	C4C—C5C—C6C	120.3 (14)
C4A—C5A—H5A	118.6	C4C—C5C—H5C	119.8
C6A—C5A—H5A	118.6	C6C—C5C—H5C	119.8
C1A—C6A—C5A	116.1 (11)	C1C—C6C—C5C	118.1 (11)
C1A—C6A—C7A	118.6 (11)	C1C—C6C—C7C	121.2 (11)
C5A—C6A—C7A	125.2 (10)	C5C—C6C—C7C	120.7 (12)
N1A—C7A—C6A	115.4 (9)	N1C—C7C—C6C	113.5 (9)
N1A—C7A—H7A	108.4	N1C—C7C—H7E	108.9
C6A—C7A—H7A	108.4	C6C—C7C—H7E	108.9
N1A—C7A—H7B	108.4	N1C—C7C—H7F	108.9
C6A—C7A—H7B	108.4	C6C—C7C—H7F	108.9
H7A—C7A—H7B	107.5	H7E—C7C—H7F	107.7
C8A—N1A—C9A	109.9 (9)	C8C—N1C—C9C	109.8 (9)
C8A—N1A—C7A	124.3 (9)	C8C—N1C—C7C	123.9 (9)
C9A—N1A—C7A	125.2 (9)	C9C—N1C—C7C	126.3 (9)
N1A—C8A—N2A	105.5 (8)	N1C—C8C—N2C	106.6 (9)
N1A—C8A—Au1A	125.7 (8)	N1C—C8C—Au1C	128.8 (8)
N2A—C8A—Au1A	128.8 (8)	N2C—C8C—Au1C	124.5 (7)
C8A—Au1A—Br1A	178.7 (3)	C8C—Au1C—Br1C	178.2 (3)
C10A—C9A—N1A	106.6 (9)	C10C—C9C—N1C	106.9 (9)
C10A—C9A—C11A	129.8 (10)	C10C—C9C—C11C	130.3 (11)
N1A—C9A—C11A	123.5 (10)	N1C—C9C—C11C	122.7 (10)
C16A—C11A—C12A	120.4 (11)	C16C—C11C—C12C	118.6 (12)
C16A—C11A—C9A	121.7 (11)	C16C—C11C—C9C	123.4 (11)
C12A—C11A—C9A	117.9 (11)	C12C—C11C—C9C	118.0 (11)
C11A—C12A—C13A	119.5 (12)	C11C—C12C—C13C	120.8 (14)
C11A—C12A—H12A	120.3	C11C—C12C—H12C	119.6
C13A—C12A—H12A	120.3	C13C—C12C—H12C	119.6
C14A—C13A—C12A	120.1 (13)	C14C—C13C—C12C	119.5 (15)
C14A—C13A—H13A	119.9	C14C—C13C—H13C	120.3
C12A—C13A—H13A	119.9	C12C—C13C—H13C	120.3
C13A—C14A—C15A	121.1 (12)	C13C—C14C—C15C	121.0 (13)
C13A—C14A—H14A	119.4	C13C—C14C—H14C	119.5
C15A—C14A—H14A	119.4	C15C—C14C—H14C	119.5
C14A—C15A—C16A	119.0 (12)	C16C—C15C—C14C	118.8 (15)
C14A—C15A—H15A	120.5	C16C—C15C—H15C	120.6
C16A—C15A—H15A	120.5	C14C—C15C—H15C	120.6
C11A—C16A—C15A	119.8 (12)	C11C—C16C—C15C	121.2 (15)
C11A—C16A—H16A	120.1	C11C—C16C—H16C	119.4
C15A—C16A—H16A	120.1	C15C—C16C—H16C	119.4
C9A—C10A—N2A	107.1 (9)	C9C—C10C—N2C	106.6 (10)
C9A—C10A—C17A	128.2 (10)	C9C—C10C—C17C	128.8 (11)
N2A—C10A—C17A	124.6 (10)	N2C—C10C—C17C	124.3 (10)
C22A—C17A—C18A	120.3 (14)	C22C—C17C—C18C	119.5 (11)
C22A—C17A—C10A	119.5 (13)	C22C—C17C—C10C	118.8 (11)
C18A—C17A—C10A	120.2 (14)	C18C—C17C—C10C	121.7 (12)
C17A—C18A—C19A	118.9 (19)	C19C—C18C—C17C	119.7 (13)
C17A—C18A—H18A	120.5	C19C—C18C—H18C	120.2
C19A—C18A—H18A	120.5	C17C—C18C—H18C	120.2
C20A—C19A—C18A	119 (2)	C20C—C19C—C18C	120.6 (13)
C20A—C19A—H19A	120.6	C20C—C19C—H19C	119.7
C18A—C19A—H19A	120.6	C18C—C19C—H19C	119.7
C21A—C20A—C19A	121.9 (16)	C19C—C20C—C21C	119.7 (12)
C21A—C20A—H20A	119.0	C19C—C20C—H20C	120.1
C19A—C20A—H20A	119.0	C21C—C20C—H20C	120.1
C20A—C21A—C22A	119.4 (19)	C20C—C21C—C22C	119.0 (13)
C20A—C21A—H21A	120.3	C20C—C21C—H21C	120.5
C22A—C21A—H21A	120.3	C22C—C21C—H21C	120.5
C17A—C22A—C21A	120.5 (18)	C17C—C22C—C21C	121.6 (13)
C17A—C22A—H22A	119.8	C17C—C22C—H22C	119.2
C21A—C22A—H22A	119.8	C21C—C22C—H22C	119.2
C8A—N2A—C10A	110.9 (9)	C8C—N2C—C10C	110.0 (9)
C8A—N2A—C23A	124.2 (9)	C8C—N2C—C23C	124.3 (9)
C10A—N2A—C23A	124.8 (9)	C10C—N2C—C23C	125.4 (9)
N2A—C23A—C24A	112.2 (10)	N2C—C23C—C24C	114.8 (9)
N2A—C23A—H23A	109.2	N2C—C23C—H23E	108.6
C24A—C23A—H23A	109.2	C24C—C23C—H23E	108.6
N2A—C23A—H23B	109.2	N2C—C23C—H23F	108.6
C24A—C23A—H23B	109.2	C24C—C23C—H23F	108.6
H23A—C23A—H23B	107.9	H23E—C23C—H23F	107.6
C29A—C24A—C25A	118.5 (13)	C29C—C24C—C25C	119.2 (12)
C29A—C24A—C23A	120.2 (12)	C29C—C24C—C23C	119.3 (12)
C25A—C24A—C23A	121.2 (11)	C25C—C24C—C23C	121.4 (10)
C26A—C25A—C24A	120.0 (14)	C24C—C25C—C26C	120.0 (11)
C26A—C25A—H25A	120.0	C24C—C25C—H25C	120.0
C24A—C25A—H25A	120.0	C26C—C25C—H25C	120.0
C27A—C26A—C25A	120.6 (15)	C27C—C26C—C25C	120.0 (12)
C27A—C26A—H26A	119.7	C27C—C26C—H26C	120.0
C25A—C26A—H26A	119.7	C25C—C26C—H26C	120.0
C28A—C27A—C26A	119.7 (14)	C28C—C27C—C26C	121.0 (12)
C28A—C27A—H27A	120.2	C28C—C27C—H27C	119.5
C26A—C27A—H27A	120.2	C26C—C27C—H27C	119.5
C27A—C28A—C29A	119.9 (14)	C27C—C28C—C29C	119.5 (12)
C27A—C28A—H28A	120.0	C27C—C28C—H28C	120.3
C29A—C28A—H28A	120.0	C29C—C28C—H28C	120.3
C24A—C29A—C28A	121.3 (15)	C24C—C29C—C28C	120.3 (13)
C24A—C29A—H29A	119.4	C24C—C29C—H29C	119.9
C28A—C29A—H29A	119.4	C28C—C29C—H29C	119.9
C2B—C1B—C6B	121.2 (11)	C2D—C1D—C6D	120.4 (14)
C2B—C1B—H1B	119.4	C2D—C1D—H1D	119.8
C6B—C1B—H1B	119.4	C6D—C1D—H1D	119.8
C3B—C2B—C1B	119.7 (12)	C1D—C2D—C3D	121.1 (14)
C3B—C2B—H2B	120.2	C1D—C2D—H2D	119.5
C1B—C2B—H2B	120.2	C3D—C2D—H2D	119.5
C2B—C3B—C4B	120.1 (13)	C2D—C3D—C4D	118.7 (14)
C2B—C3B—H3B	119.9	C2D—C3D—H3D	120.7
C4B—C3B—H3B	119.9	C4D—C3D—H3D	120.7
C3B—C4B—C5B	120.8 (13)	C5D—C4D—C3D	120.9 (15)
C3B—C4B—H4B	119.6	C5D—C4D—H4D	119.5
C5B—C4B—H4B	119.6	C3D—C4D—H4D	119.5
C4B—C5B—C6B	119.9 (13)	C4D—C5D—C6D	120.2 (13)
C4B—C5B—H5B	120.1	C4D—C5D—H5D	119.9
C6B—C5B—H5B	120.1	C6D—C5D—H5D	119.9
C5B—C6B—C1B	118.4 (12)	C5D—C6D—C1D	118.7 (12)
C5B—C6B—C7B	121.1 (11)	C5D—C6D—C7D	122.4 (11)
C1B—C6B—C7B	120.5 (10)	C1D—C6D—C7D	118.8 (12)
N1B—C7B—C6B	112.9 (10)	N1D—C7D—C6D	114.1 (10)
N1B—C7B—H7C	109.0	N1D—C7D—H7G	108.7
C6B—C7B—H7C	109.0	C6D—C7D—H7G	108.7
N1B—C7B—H7D	109.0	N1D—C7D—H7H	108.7
C6B—C7B—H7D	109.0	C6D—C7D—H7H	108.7
H7C—C7B—H7D	107.8	H7G—C7D—H7H	107.6
C8B—N1B—C9B	109.7 (9)	C8D—N1D—C9D	112.0 (9)
C8B—N1B—C7B	125.4 (9)	C8D—N1D—C7D	123.2 (9)
C9B—N1B—C7B	124.9 (9)	C9D—N1D—C7D	124.8 (9)
N1B—C8B—N2B	106.9 (9)	N1D—C8D—N2D	103.9 (10)
N1B—C8B—Au1B	128.7 (8)	N1D—C8D—Au1D	127.2 (9)
N2B—C8B—Au1B	124.3 (8)	N2D—C8D—Au1D	128.7 (8)
C8B—Au1B—Br1B	178.1 (3)	C8D—Au1D—Br1D	178.8 (3)
C10B—C9B—N1B	107.4 (9)	C10D—C9D—N1D	105.5 (10)
C10B—C9B—C11B	129.0 (10)	C10D—C9D—C11D	130.7 (10)
N1B—C9B—C11B	123.5 (10)	N1D—C9D—C11D	123.8 (9)
C12B—C11B—C16B	118.7 (12)	C16D—C11D—C12D	119.0 (11)
C12B—C11B—C9B	123.3 (13)	C16D—C11D—C9D	121.6 (11)
C16B—C11B—C9B	118.0 (12)	C12D—C11D—C9D	119.4 (11)
C13B—C12B—C11B	120.0 (16)	C13D—C12D—C11D	121.4 (12)
C13B—C12B—H12B	120.0	C13D—C12D—H12D	119.3
C11B—C12B—H12B	120.0	C11D—C12D—H12D	119.3
C14B—C13B—C12B	120.9 (16)	C12D—C13D—C14D	118.5 (13)
C14B—C13B—H13B	119.6	C12D—C13D—H13D	120.8
C12B—C13B—H13B	119.6	C14D—C13D—H13D	120.8
C13B—C14B—C15B	120.4 (14)	C15D—C14D—C13D	121.2 (12)
C13B—C14B—H14B	119.8	C15D—C14D—H14D	119.4
C15B—C14B—H14B	119.8	C13D—C14D—H14D	119.4
C14B—C15B—C16B	119.3 (18)	C14D—C15D—C16D	119.3 (13)
C14B—C15B—H15B	120.4	C14D—C15D—H15D	120.4
C16B—C15B—H15B	120.4	C16D—C15D—H15D	120.4
C15B—C16B—C11B	120.8 (16)	C11D—C16D—C15D	120.7 (13)
C15B—C16B—H16B	119.6	C11D—C16D—H16D	119.7
C11B—C16B—H16B	119.6	C15D—C16D—H16D	119.7
C9B—C10B—N2B	106.3 (10)	C9D—C10D—N2D	107.7 (11)
C9B—C10B—C17B	128.8 (10)	C9D—C10D—C17D	130.0 (10)
N2B—C10B—C17B	124.9 (10)	N2D—C10D—C17D	122.1 (10)
C18B—C17B—C22B	120.3 (11)	C18D—C17D—C22D	121.0 (13)
C18B—C17B—C10B	121.6 (11)	C18D—C17D—C10D	121.9 (13)
C22B—C17B—C10B	118.1 (11)	C22D—C17D—C10D	117.1 (12)
C17B—C18B—C19B	118.1 (13)	C17D—C18D—C19D	119.4 (17)
C17B—C18B—H18B	121.0	C17D—C18D—H18D	120.3
C19B—C18B—H18B	121.0	C19D—C18D—H18D	120.3
C20B—C19B—C18B	121.9 (13)	C20D—C19D—C18D	119.8 (18)
C20B—C19B—H19B	119.0	C20D—C19D—H19D	120.1
C18B—C19B—H19B	119.0	C18D—C19D—H19D	120.1
C19B—C20B—C21B	119.7 (12)	C21D—C20D—C19D	121.3 (16)
C19B—C20B—H20B	120.2	C21D—C20D—H20D	119.4
C21B—C20B—H20B	120.2	C19D—C20D—H20D	119.4
C20B—C21B—C22B	119.4 (13)	C20D—C21D—C22D	120.1 (18)
C20B—C21B—H21B	120.3	C20D—C21D—H21D	120.0
C22B—C21B—H21B	120.3	C22D—C21D—H21D	120.0
C17B—C22B—C21B	120.6 (13)	C17D—C22D—C21D	118.4 (17)
C17B—C22B—H22B	119.7	C17D—C22D—H22D	120.8
C21B—C22B—H22B	119.7	C21D—C22D—H22D	120.8
C8B—N2B—C10B	109.6 (9)	C8D—N2D—C10D	110.8 (10)
C8B—N2B—C23B	124.6 (9)	C8D—N2D—C23D	123.6 (10)
C10B—N2B—C23B	125.6 (9)	C10D—N2D—C23D	125.5 (10)
N2B—C23B—C24B	114.4 (11)	N2D—C23D—C24D	112.2 (10)
N2B—C23B—H23C	108.7	N2D—C23D—H23G	109.2
C24B—C23B—H23C	108.7	C24D—C23D—H23G	109.2
N2B—C23B—H23D	108.7	N2D—C23D—H23H	109.2
C24B—C23B—H23D	108.7	C24D—C23D—H23H	109.2
H23C—C23B—H23D	107.6	H23G—C23D—H23H	107.9
C29B—C24B—C25B	117.6 (14)	C29D—C24D—C25D	118.2 (13)
C29B—C24B—C23B	122.8 (11)	C29D—C24D—C23D	121.0 (12)
C25B—C24B—C23B	119.5 (13)	C25D—C24D—C23D	120.7 (13)
C24B—C25B—C26B	119.8 (16)	C24D—C25D—C26D	120.4 (17)
C24B—C25B—H25B	120.1	C24D—C25D—H25D	119.8
C26B—C25B—H25B	120.1	C26D—C25D—H25D	119.8
C27B—C26B—C25B	121.0 (15)	C27D—C26D—C25D	120.2 (16)
C27B—C26B—H26B	119.5	C27D—C26D—H26D	119.9
C25B—C26B—H26B	119.5	C25D—C26D—H26D	119.9
C26B—C27B—C28B	120.2 (17)	C28D—C27D—C26D	119.6 (16)
C26B—C27B—H27B	119.9	C28D—C27D—H27D	120.2
C28B—C27B—H27B	119.9	C26D—C27D—H27D	120.2
C27B—C28B—C29B	118.8 (17)	C27D—C28D—C29D	119.8 (17)
C27B—C28B—H28B	120.6	C27D—C28D—H28D	120.1
C29B—C28B—H28B	120.6	C29D—C28D—H28D	120.1
C24B—C29B—C28B	122.5 (14)	C24D—C29D—C28D	121.8 (14)
C24B—C29B—H29B	118.8	C24D—C29D—H29D	119.1
C28B—C29B—H29B	118.8	C28D—C29D—H29D	119.1
C6A—C1A—C2A—C3A	−0.3 (18)	C6C—C1C—C2C—C3C	−1 (2)
C1A—C2A—C3A—C4A	0.9 (19)	C1C—C2C—C3C—C4C	0 (2)
C2A—C3A—C4A—C5A	−0.4 (18)	C2C—C3C—C4C—C5C	1 (3)
C3A—C4A—C5A—C6A	−0.7 (18)	C3C—C4C—C5C—C6C	−2 (3)
C2A—C1A—C6A—C5A	−0.7 (16)	C2C—C1C—C6C—C5C	1 (2)
C2A—C1A—C6A—C7A	175.9 (11)	C2C—C1C—C6C—C7C	179.9 (13)
C4A—C5A—C6A—C1A	1.3 (16)	C4C—C5C—C6C—C1C	1 (2)
C4A—C5A—C6A—C7A	−175.1 (11)	C4C—C5C—C6C—C7C	−178.3 (14)
C1A—C6A—C7A—N1A	167.1 (9)	C1C—C6C—C7C—N1C	43.3 (16)
C5A—C6A—C7A—N1A	−16.6 (15)	C5C—C6C—C7C—N1C	−137.3 (12)
C6A—C7A—N1A—C8A	92.5 (13)	C6C—C7C—N1C—C8C	−118.7 (12)
C6A—C7A—N1A—C9A	−97.5 (12)	C6C—C7C—N1C—C9C	61.6 (16)
C9A—N1A—C8A—N2A	−0.4 (12)	C9C—N1C—C8C—N2C	2.8 (12)
C7A—N1A—C8A—N2A	170.9 (9)	C7C—N1C—C8C—N2C	−176.9 (10)
C9A—N1A—C8A—Au1A	178.1 (8)	C9C—N1C—C8C—Au1C	179.8 (8)
C7A—N1A—C8A—Au1A	−10.6 (15)	C7C—N1C—C8C—Au1C	0.1 (16)
C8A—N1A—C9A—C10A	1.6 (13)	C8C—N1C—C9C—C10C	−2.1 (13)
C7A—N1A—C9A—C10A	−169.6 (10)	C7C—N1C—C9C—C10C	177.5 (11)
C8A—N1A—C9A—C11A	−174.5 (11)	C8C—N1C—C9C—C11C	174.8 (10)
C7A—N1A—C9A—C11A	14.2 (18)	C7C—N1C—C9C—C11C	−5.5 (18)
C10A—C9A—C11A—C16A	90.0 (17)	C10C—C9C—C11C—C16C	−120.3 (15)
N1A—C9A—C11A—C16A	−94.8 (15)	N1C—C9C—C11C—C16C	63.6 (17)
C10A—C9A—C11A—C12A	−89.4 (16)	C10C—C9C—C11C—C12C	59.2 (18)
N1A—C9A—C11A—C12A	85.9 (15)	N1C—C9C—C11C—C12C	−116.9 (13)
C16A—C11A—C12A—C13A	−2.1 (19)	C16C—C11C—C12C—C13C	−0.5 (19)
C9A—C11A—C12A—C13A	177.2 (12)	C9C—C11C—C12C—C13C	−180.0 (12)
C11A—C12A—C13A—C14A	1 (2)	C11C—C12C—C13C—C14C	0 (2)
C12A—C13A—C14A—C15A	0 (2)	C12C—C13C—C14C—C15C	1 (2)
C13A—C14A—C15A—C16A	−0.1 (19)	C13C—C14C—C15C—C16C	−1 (2)
C12A—C11A—C16A—C15A	1.9 (18)	C12C—C11C—C16C—C15C	0 (2)
C9A—C11A—C16A—C15A	−177.4 (11)	C9C—C11C—C16C—C15C	179.8 (12)
C14A—C15A—C16A—C11A	−0.8 (19)	C14C—C15C—C16C—C11C	0 (2)
N1A—C9A—C10A—N2A	−2.2 (13)	N1C—C9C—C10C—N2C	0.6 (13)
C11A—C9A—C10A—N2A	173.7 (12)	C11C—C9C—C10C—N2C	−176.0 (12)
N1A—C9A—C10A—C17A	174.8 (12)	N1C—C9C—C10C—C17C	−173.3 (12)
C11A—C9A—C10A—C17A	−9 (2)	C11C—C9C—C10C—C17C	10 (2)
C9A—C10A—C17A—C22A	−68.6 (19)	C9C—C10C—C17C—C22C	65.5 (17)
N2A—C10A—C17A—C22A	107.8 (15)	N2C—C10C—C17C—C22C	−107.5 (14)
C9A—C10A—C17A—C18A	110.8 (16)	C9C—C10C—C17C—C18C	−113.8 (15)
N2A—C10A—C17A—C18A	−72.8 (17)	N2C—C10C—C17C—C18C	73.2 (16)
C22A—C17A—C18A—C19A	2 (2)	C22C—C17C—C18C—C19C	−0.1 (17)
C10A—C17A—C18A—C19A	−177.9 (13)	C10C—C17C—C18C—C19C	179.2 (11)
C17A—C18A—C19A—C20A	0 (2)	C17C—C18C—C19C—C20C	0.4 (18)
C18A—C19A—C20A—C21A	−1 (3)	C18C—C19C—C20C—C21C	−0.9 (19)
C19A—C20A—C21A—C22A	0 (3)	C19C—C20C—C21C—C22C	0.9 (19)
C18A—C17A—C22A—C21A	−3 (2)	C18C—C17C—C22C—C21C	0.2 (18)
C10A—C17A—C22A—C21A	176.9 (14)	C10C—C17C—C22C—C21C	−179.1 (11)
C20A—C21A—C22A—C17A	2 (3)	C20C—C21C—C22C—C17C	−0.6 (19)
N1A—C8A—N2A—C10A	−1.0 (12)	N1C—C8C—N2C—C10C	−2.4 (12)
Au1A—C8A—N2A—C10A	−179.5 (8)	Au1C—C8C—N2C—C10C	−179.6 (7)
N1A—C8A—N2A—C23A	175.2 (10)	N1C—C8C—N2C—C23C	−176.7 (9)
Au1A—C8A—N2A—C23A	−3.3 (16)	Au1C—C8C—N2C—C23C	6.1 (14)
C9A—C10A—N2A—C8A	2.0 (13)	C9C—C10C—N2C—C8C	1.1 (13)
C17A—C10A—N2A—C8A	−175.0 (12)	C17C—C10C—N2C—C8C	175.4 (11)
C9A—C10A—N2A—C23A	−174.1 (11)	C9C—C10C—N2C—C23C	175.4 (10)
C17A—C10A—N2A—C23A	8.8 (19)	C17C—C10C—N2C—C23C	−10.3 (18)
C8A—N2A—C23A—C24A	112.6 (12)	C8C—N2C—C23C—C24C	−88.0 (13)
C10A—N2A—C23A—C24A	−71.8 (14)	C10C—N2C—C23C—C24C	98.5 (13)
N2A—C23A—C24A—C29A	128.5 (12)	N2C—C23C—C24C—C29C	160.6 (10)
N2A—C23A—C24A—C25A	−55.1 (15)	N2C—C23C—C24C—C25C	−21.8 (15)
C29A—C24A—C25A—C26A	0.0 (19)	C29C—C24C—C25C—C26C	0.5 (17)
C23A—C24A—C25A—C26A	−176.5 (12)	C23C—C24C—C25C—C26C	−177.2 (11)
C24A—C25A—C26A—C27A	0 (2)	C24C—C25C—C26C—C27C	−0.6 (18)
C25A—C26A—C27A—C28A	−1 (2)	C25C—C26C—C27C—C28C	0 (2)
C26A—C27A—C28A—C29A	1 (2)	C26C—C27C—C28C—C29C	0 (2)
C25A—C24A—C29A—C28A	0.1 (19)	C25C—C24C—C29C—C28C	−0.3 (18)
C23A—C24A—C29A—C28A	176.6 (11)	C23C—C24C—C29C—C28C	177.4 (11)
C27A—C28A—C29A—C24A	−1 (2)	C27C—C28C—C29C—C24C	0 (2)
C6B—C1B—C2B—C3B	−0.5 (18)	C6D—C1D—C2D—C3D	−2 (2)
C1B—C2B—C3B—C4B	0 (2)	C1D—C2D—C3D—C4D	1 (2)
C2B—C3B—C4B—C5B	0 (2)	C2D—C3D—C4D—C5D	−1 (2)
C3B—C4B—C5B—C6B	0 (2)	C3D—C4D—C5D—C6D	1 (2)
C4B—C5B—C6B—C1B	−0.6 (18)	C4D—C5D—C6D—C1D	−1.1 (19)
C4B—C5B—C6B—C7B	−179.5 (11)	C4D—C5D—C6D—C7D	−177.2 (11)
C2B—C1B—C6B—C5B	0.8 (17)	C2D—C1D—C6D—C5D	2 (2)
C2B—C1B—C6B—C7B	179.7 (10)	C2D—C1D—C6D—C7D	177.8 (13)
C5B—C6B—C7B—N1B	113.2 (12)	C5D—C6D—C7D—N1D	−21.5 (16)
C1B—C6B—C7B—N1B	−65.7 (13)	C1D—C6D—C7D—N1D	162.4 (11)
C6B—C7B—N1B—C8B	106.3 (13)	C6D—C7D—N1D—C8D	−85.1 (13)
C6B—C7B—N1B—C9B	−74.1 (15)	C6D—C7D—N1D—C9D	97.6 (13)
C9B—N1B—C8B—N2B	−0.2 (14)	C9D—N1D—C8D—N2D	1.3 (12)
C7B—N1B—C8B—N2B	179.4 (11)	C7D—N1D—C8D—N2D	−176.3 (10)
C9B—N1B—C8B—Au1B	−177.5 (9)	C9D—N1D—C8D—Au1D	176.4 (8)
C7B—N1B—C8B—Au1B	2.1 (19)	C7D—N1D—C8D—Au1D	−1.2 (15)
C8B—N1B—C9B—C10B	0.5 (14)	C8D—N1D—C9D—C10D	−1.4 (13)
C7B—N1B—C9B—C10B	−179.2 (11)	C7D—N1D—C9D—C10D	176.1 (11)
C8B—N1B—C9B—C11B	−175.6 (12)	C8D—N1D—C9D—C11D	177.7 (11)
C7B—N1B—C9B—C11B	5 (2)	C7D—N1D—C9D—C11D	−4.8 (18)
C10B—C9B—C11B—C12B	113.5 (16)	C10D—C9D—C11D—C16D	−100.2 (16)
N1B—C9B—C11B—C12B	−71.4 (17)	N1D—C9D—C11D—C16D	81.0 (15)
C10B—C9B—C11B—C16B	−66.3 (19)	C10D—C9D—C11D—C12D	79.7 (17)
N1B—C9B—C11B—C16B	108.8 (14)	N1D—C9D—C11D—C12D	−99.1 (14)
C16B—C11B—C12B—C13B	0.7 (18)	C16D—C11D—C12D—C13D	−0.7 (18)
C9B—C11B—C12B—C13B	−179.1 (11)	C9D—C11D—C12D—C13D	179.4 (11)
C11B—C12B—C13B—C14B	0 (2)	C11D—C12D—C13D—C14D	0.9 (19)
C12B—C13B—C14B—C15B	0 (2)	C12D—C13D—C14D—C15D	−1.0 (19)
C13B—C14B—C15B—C16B	1 (2)	C13D—C14D—C15D—C16D	1 (2)
C14B—C15B—C16B—C11B	−1 (2)	C12D—C11D—C16D—C15D	0.5 (18)
C12B—C11B—C16B—C15B	0 (2)	C9D—C11D—C16D—C15D	−179.6 (11)
C9B—C11B—C16B—C15B	179.5 (13)	C14D—C15D—C16D—C11D	−1 (2)
N1B—C9B—C10B—N2B	−0.5 (14)	N1D—C9D—C10D—N2D	1.0 (13)
C11B—C9B—C10B—N2B	175.2 (13)	C11D—C9D—C10D—N2D	−178.0 (12)
N1B—C9B—C10B—C17B	176.5 (12)	N1D—C9D—C10D—C17D	−175.5 (13)
C11B—C9B—C10B—C17B	−8 (2)	C11D—C9D—C10D—C17D	6 (2)
C9B—C10B—C17B—C18B	119.2 (15)	C9D—C10D—C17D—C18D	−113.5 (16)
N2B—C10B—C17B—C18B	−64.3 (16)	N2D—C10D—C17D—C18D	70.5 (17)
C9B—C10B—C17B—C22B	−59.8 (18)	C9D—C10D—C17D—C22D	66.5 (18)
N2B—C10B—C17B—C22B	116.7 (13)	N2D—C10D—C17D—C22D	−109.5 (13)
C22B—C17B—C18B—C19B	−1.1 (18)	C22D—C17D—C18D—C19D	1 (2)
C10B—C17B—C18B—C19B	−180.0 (11)	C10D—C17D—C18D—C19D	−179.2 (13)
C17B—C18B—C19B—C20B	1 (2)	C17D—C18D—C19D—C20D	0 (2)
C18B—C19B—C20B—C21B	0 (2)	C18D—C19D—C20D—C21D	0 (3)
C19B—C20B—C21B—C22B	−1.4 (19)	C19D—C20D—C21D—C22D	1 (2)
C18B—C17B—C22B—C21B	−0.3 (18)	C18D—C17D—C22D—C21D	−0.2 (19)
C10B—C17B—C22B—C21B	178.7 (11)	C10D—C17D—C22D—C21D	179.8 (11)
C20B—C21B—C22B—C17B	1.5 (19)	C20D—C21D—C22D—C17D	−1 (2)
N1B—C8B—N2B—C10B	−0.2 (14)	N1D—C8D—N2D—C10D	−0.6 (12)
Au1B—C8B—N2B—C10B	177.3 (8)	Au1D—C8D—N2D—C10D	−175.7 (8)
N1B—C8B—N2B—C23B	174.7 (11)	N1D—C8D—N2D—C23D	−179.1 (11)
Au1B—C8B—N2B—C23B	−7.9 (17)	Au1D—C8D—N2D—C23D	5.9 (17)
C9B—C10B—N2B—C8B	0.4 (14)	C9D—C10D—N2D—C8D	−0.2 (14)
C17B—C10B—N2B—C8B	−176.7 (11)	C17D—C10D—N2D—C8D	176.6 (11)
C9B—C10B—N2B—C23B	−174.3 (12)	C9D—C10D—N2D—C23D	178.2 (11)
C17B—C10B—N2B—C23B	8.5 (19)	C17D—C10D—N2D—C23D	−5.0 (19)
C8B—N2B—C23B—C24B	94.0 (14)	C8D—N2D—C23D—C24D	−116.9 (12)
C10B—N2B—C23B—C24B	−92.0 (14)	C10D—N2D—C23D—C24D	64.9 (16)
N2B—C23B—C24B—C29B	−10.3 (17)	N2D—C23D—C24D—C29D	51.5 (16)
N2B—C23B—C24B—C25B	171.9 (11)	N2D—C23D—C24D—C25D	−126.5 (13)
C29B—C24B—C25B—C26B	−1 (2)	C29D—C24D—C25D—C26D	0 (2)
C23B—C24B—C25B—C26B	176.8 (13)	C23D—C24D—C25D—C26D	178.0 (14)
C24B—C25B—C26B—C27B	0 (2)	C24D—C25D—C26D—C27D	0 (3)
C25B—C26B—C27B—C28B	2 (3)	C25D—C26D—C27D—C28D	0 (3)
C26B—C27B—C28B—C29B	−2 (2)	C26D—C27D—C28D—C29D	1 (3)
C25B—C24B—C29B—C28B	1 (2)	C25D—C24D—C29D—C28D	1 (2)
C23B—C24B—C29B—C28B	−176.9 (12)	C23D—C24D—C29D—C28D	−177.5 (13)
C27B—C28B—C29B—C24B	1 (2)	C27D—C28D—C29D—C24D	−1 (2)