[1L-3,4-Bis-O-(diphenyl­phosphino)-1,2,5,6-tetra-O-methyl-chiro-inositol-κ²P,P′][η⁴-(Z,Z)-cyclo­octa-1,5-diene]rhodium(I) tetra­fluorido­borate chloro­form solvate

The title compound, [Rh(C₈H₁₂)(C₃₄H₃₈O₆P₂)]BF₄·CHCl₃, a novel asymmetric hydrogenation catalyst, crystallizes with two independent almost identical cations and anions. Cell-packing inter­actions are provided by nonclassical hydrogen bonding between phenyl and chloro­form H atoms and fluoro and chloro donors of the BF₄⁻ anion and the chloro­form solvent mol­ecule.

S1. Comment

This study is part of a programme aimed at developing new catalysts for the asymmetric hydrogenation of alkenes based on carbohydrate precursor molecules (Gainsford et al., 2000; Falshaw et al., 1999, 2007). Only a few structures of related catalysts have been reported [in the following, refcodes in the Cambridge Structural Database (CSD; Version 5.28, updates January 2007; Allen, 2002) are given in capitals]. A preliminary report of this study was given by Gainsford et al. (2005).

The asymmetric unit contains two independent Rh^I complexes containing the novel ligand CANDYPHOS (CP), BF₄^- anions and chloroform solvation molecules. Both chloroform molecules show some disorder, which was modelled using two full Cl atoms and two linked positions (approximately 0.5 occupancy each) for the remaining H and Cl atoms. The CP ligands were confirmed to have absolute carbon configurations of SSRRRR (C21–C26, C31–C36). The independent [Rh^I(CP)(COD)]⁺ cations (one is shown in Fig. 1) are essentially identical with a close superposition overlap of the final models possible (Fig. 2). The r.m.s. fit of coordinates one to the other was 0.223 Å, with bond and angle r.m.s. values of 0.023 Å and 1.43° (Spek, 2003). Minor orientational differences of the phenyl rings are seen; for example, the O1—P1—C111—C112 and O3—P3—C311—C312 dihedral angles are -117.6 (7) and -112.6 (7)°, respectively.

The seven-membered chelate rings are in the δ-twist-chair conformation (Kadyrov et al., 1999; Anconi et al., 2006). The P-aryl ring conformations are somewhat similar to those reported in QAHZEF (Aghmiz et al., 2004) with α(f), β(r), α' and β' angles [as defined by Seebach et al. (1992) and RajanBabu et al. (1997)] of 15.3 (2) and 16.2 (2), 66.5 (3) and 65.4 (3), 55.0 (3) and 51.5 (3), and 50.0 (3) and 54.1 (3)°, respectively (calculated using PLATON; Spek, 2003). There seems some disparity between reported values in these two reference papers and the deposited coordinates in the CSD, but it is also clear that there is a considerable variation observed in such Rh complexes with angles ranging from 11.2 (QAHZEF) to 75.0° (NIJMUO; RajanBabu et al., 1997). The chiro-inositol rings are closest to chair conformations, with atoms C22 and C32 at the foot and atoms C25 and C35 at the head positions; the displacement Q and θ values (Cremer & Pople, 1975) for the C21–C26 and C31–C36 rings are 0.569 (8) and 0.577 (8) Å and 11.2 (8) and 9.5 (8)°, respectively.

The Rh—P bonds range from 2.255 (2) to 2.2719 (18) Å, within the ranges noted in the closely-related structures ZATSAO {phenyl [2,3-bis(O-diphenylphosphino)-β-D-glucopyranoside-P,P']- [η⁴-(Z,Z)-cycloocta-1,5-diene]rhodium(I) tetrafluoroborate; 2.250 and 2.275 Å; Kempe et al., 1995}, NIJMUO {(1S,2S)-(η²,η²-cycloocta-1,5-diene)[1,2-bis(diphenylphosphiono)oxy]cyclohexanerhodium(I) hexfluorantimonate benzene solvate; 2.250 and 2.238 Å} and QAHZEF [(η⁴-(Z,Z)-cycloocta-1,5-diene)-3,4-bis-O-(diphenylphosphino) -1,6-dideoxy-2,5-anhydro-L-iditolrhodium(I) tetrafluoroborate dichloromethane solvate; 2.288–2.311 Å] [please check locations of brackets in compound names; why give the names here when other compounds are cited only by refcode?]. The P—O distances here [average 1.617 (4) Å] are self-consistent and within the range noted in these papers (1.610–1.642 Å).

The Rh—cyclo-1,5-diene bond-distance ranges [2.227 (8)–2.293 (10) Å] are within the ranges observed previously, viz. 2.238–2.317 Å (QOPKEL; Kempe et al., 2001) and 2.219–2.305 Å (POTGEK; Kempe et al., 1998). The octa-1,5-diene (COD) rings have twisted boat conformations (Bats et al., 2004), and are skewed with regard to the RhP₂ plane, similar to the configuration observed in, for example, CACNAW (Holz et al., 2001). A CSD survey of related (L)Rh(COD)⁺ compounds, where L is a bis(phosphine) ligand linked into a seven-membered ring by four atoms (17 hits), shows that the COD-coordinated C atoms are always asymmetrically placed with respect to the RhP₂ plane (with bond mid-points out of plane from 0.06 to 0.60 Å (PUHPAJ; Borns et al., 1998). In our case the mid-point of one C═C set is coplanar [the out-of-RhP₂-plane values are 0.015 (8) and 0.033 (8) Å], while the other set is 0.355 (8) and 0.248 (8) Å, respectively, from the plane. These values are very similar to those in the bis(phosphine) complex BEDPIJ (Anderson & Pignolet, 1981) and in one of the two cations in QAHZEF; the COD atomic disorder found in this latter study suggests that other close intramolecular interactions may be the cause for the COD rotational skewness observed both here and in other related compounds (e.g. CACNAW).

The crystalline packing is stabilized by weak but significant hydrogen-bonding interactions between the cations and the chloroform and fluoroborate anions (Table 2). The H124···Cl71 interaction, involving the trans-to-P phenyl H atom, has been noted in several compounds [e.g. H···Cl = 2.76 Å and C—H···Cl = 161° in a ruthenium–triphenylphosphine complex (VAKFAP; Snelgrove et al., 2003)]. Interactions between solvent chloroform molecules and tetrafluoroborate anions similar to those reported here have also been observed [e.g. in LUBTAD (Moores et al., 2002), with H···F = 2.34 Å and C—H···F = 171°]. Significant interactions of phenyl H atoms in the meta position with fluoroborate anions (H113, H115, H313 and H315) have been noted in at least ten CSD structures since 2003. The parameters observed in a copper(I) salt (AVEXUU; Fournier et al., 2004) and a ruthenium(I) salt (EWOJAB; Keisham et al., 2004) are H···F distances of 2.38 and 2.37 Å and C—H···F angles of 169 and 153°, respectively. Finally there are at least three C—H···π attractive interactions (the last three entries of Table 2; Cg1, Cg2 and Cg3 are the centres of the phenyl rings C321–C326, C121–C126 and C411–C416, respectively) and a close contact between the methoxy atom O33 and chloroform atom Cl8A at (-x + 1, y + 1/2, -z + 1) [2.930 (9) Å]. Fig. 2 does not show these intermolecular interactions but visually confirms that the estimated potential solvent area of 166 Å (Spek,2 003) is not localized in the lattice.

Related literature

For related literature, see: Aghmiz et al. (2004); Allen (2002); Anconi et al. (2006); Anderson & Pignolet (1981); Bats et al. (2004); Borns et al. (1998); Cremer & Pople (1975); Falshaw et al. (1999, 2007); Fournier et al. (2004); Gainsford et al. (2000, 2005); Holz et al. (2001); Kadyrov et al. (1999); Keisham et al. (2004); Kempe et al. (1995, 1998, 2001); Moores et al. (2002); RajanBabu, Ayers, Halloday, You & Calabrese (1997); Seebach et al. (1992); Snelgrove et al. (2003); Spek (2003).

S2. Experimental

A solution of 1L-3,4-bis(O-diphenylphosphino)-1,2,5,6-tetra-O-methyl-chiro-inositol (122 mg, O.20 mmol) in tetrahydrofuran (5 ml) was added dropwise to a solution of (RhCODCl)₂ (49 mg, 0.10 mmol) in tetrahydrofuran (5 ml). The reaction mixture was stirred at room temperature for 17 h. AgBF₄ (0.039 g, 0.2 mmol) was added and the reaction mixture stirred for 2 h. Filtration and removal of the solvent yielded an orange solid. Crystallization from CHCl₃/pentane yielded the pure title compound as a CHCl₃ solvate (0.078 g, 76%). ³¹P NMR (CDCl₃): 134.8 (J_Rh—P = 178 Hz). Analysis calculated for C₄₃H₅₁BCl₃F₄O₆P₂Rh: C 50.54, H 5.03%; found: C 50.44, H 5.00%.

S3. Refinement

The disorder of the chloroform atoms was modelled using two-position linked atoms for one H and one Cl atom in each of the two molecules; H atoms were positioned (C—H = 1.03 Å) and fixed in the final refinement cycles with one common U_iso value. Identical anisotropic displacement parameters were used for disordered chloroform atoms Cl8A and Cl8B and for Cl7Aand Cl7B. The final major occupancies for the linked atoms were 0.564 (10) and 0.534 (6) for the C7 and C8 molecules, respectively. All other C-bound H atoms were constrained to their expected geometries (C—H = 0.95–1.00 Å) and were refined with U_iso(H) values of 1.2 or 1.5 times U_eq of their parent C atom. Only selected non-H atoms were refined with anisotropic thermal parameters in order to maintain a reasonable data/parameter ratio. There is a strong suggestion of the presence of a minor crystal fragment contributing to some of the data. The worst fit data (the top 35 reflections) have F_o >> F_c; removal of data for which F_o > 1.5F_c (830 data with R around 20%) improved agreement R₁ (0.064 to 0.055) but with only insigificant changes in the model. Given no definitive experimental evidence for this, the full collected data results are presented here.

Computing details

Data collection: SMART (Siemens, 2001); cell refinement: SMART; data reduction: SAINT (Siemens, 2001) and SADABS (Sheldrick, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997) and Mercury (Bruno et al., 2002); software used to prepare material for publication: SHELXL97.

Figures

	Fig. 1. An ORTEP-3 view (Farrugia, 1997) of the molecular structure of (I), with displacement ellipsoids shown at the 30% probability level. H atoms have been excluded for clarity.
	Fig. 2. A Mercury (Bruno et al., 2002) view of the superimposed independent cations in (I).
	Fig. 3. An ORTEP-3 (Farrugia, 1997) packing view down the a axis, with displacement ellipsoids shown at the 50% probability level. Key asymmetric atoms are labelled; only the chloroform H atoms and the major conformation of the chloroform molecules are shown for clarity.

[1L-3,4-Bis(O-diphenylphosphino)-1,2,5,6-tetra-O-methyl-chiro-inositol- κ²P,P'][η⁴-(Z,Z)-cycloocta-1,5-diene]rhodium(I) tetrafluoroborate chloroform solvate

Crystal data

[Rh(C8H12)(C34H38O6P2)]BF4·CHCl3	F(000) = 2096
Mr = 1021.85	Dx = 1.502 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 6137 reflections
a = 9.3231 (17) Å	θ = 2.2–26.2°
b = 26.611 (6) Å	µ = 0.69 mm^−1
c = 18.218 (4) Å	T = 158 K
β = 91.596 (7)°	Plate, orange
V = 4518.0 (16) Å^3	0.9 × 0.4 × 0.04 mm
Z = 4

Data collection

Bruker SMART CCD area-detector diffractometer	15833 independent reflections
Radiation source: fine-focus sealed tube	13832 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.026
Detector resolution: 8.192 pixels mm^-1	θmax = 26.4°, θmin = 2.2°
ϕ and ω scans	h = −4→10
Absorption correction: multi-scan (Blessing, 1995)	k = −33→33
Tmin = 0.785, Tmax = 0.973	l = −22→21
19306 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.064	H-atom parameters constrained
wR(F^2) = 0.150	w = 1/[σ^2(Fo^2) + (0.0443P)^2 + 25.1837P] where P = (Fo^2 + 2Fc^2)/3
S = 1.07	(Δ/σ)max = 0.004
15833 reflections	Δρmax = 0.83 e Å^−3
645 parameters	Δρmin = −1.48 e Å^−3
1 restraint	Absolute structure: Flack (1983), 6332 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.05 (3)

Special details

Experimental. Crystal decay was monitored by repeating the initial 10 frames at the end of the data collection and analyzing duplicate reflections. The standard 0.8 mm diameter collimator was used. 1L-3,4-bis(O-diphenylphosphino)-1,2,5,6-tetra-O-methyl-chiro- inositol Rhodium cyclo-octadiene tetrafluoroborate).

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Rh1	0.79986 (6)	0.16998 (2)	0.56130 (3)	0.02033 (13)
P1	0.7879 (2)	0.16528 (7)	0.43676 (9)	0.0190 (4)
P2	0.5596 (2)	0.17944 (7)	0.56520 (10)	0.0182 (4)
Cl71	0.7359 (6)	−0.08922 (15)	0.6771 (3)	0.1038 (14)
Cl72	0.9682 (8)	−0.0222 (2)	0.6549 (4)	0.169 (3)
Cl81	0.7140 (5)	0.04991 (14)	0.8207 (2)	0.0986 (14)
Cl82	0.9926 (8)	0.0106 (3)	0.8583 (3)	0.162 (3)
B1	0.8989 (13)	0.1007 (4)	0.0609 (6)	0.038 (2)
B2	0.9632 (14)	0.3830 (4)	0.5478 (6)	0.042 (3)
F11	0.9317 (12)	0.0881 (4)	0.1306 (4)	0.120 (4)
F12	0.9946 (10)	0.0780 (3)	0.0125 (5)	0.095 (3)
F13	0.9057 (8)	0.1513 (2)	0.0499 (4)	0.0635 (18)
F14	0.7679 (8)	0.0816 (2)	0.0424 (4)	0.069 (2)
F21	0.9553 (8)	0.3308 (2)	0.5526 (4)	0.071 (2)
F22	0.8930 (9)	0.3989 (3)	0.4854 (4)	0.079 (2)
F23	1.1047 (8)	0.3969 (2)	0.5454 (5)	0.073 (2)
F24	0.9002 (10)	0.4062 (3)	0.6054 (5)	0.097 (3)
O1	0.6387 (6)	0.17863 (18)	0.3941 (2)	0.0226 (11)*
O2	0.4517 (6)	0.14528 (18)	0.5155 (3)	0.0251 (11)*
O23	0.3797 (7)	0.0456 (2)	0.5082 (3)	0.0349 (13)*
O24	0.5174 (7)	0.0198 (2)	0.3702 (3)	0.0358 (14)*
O25	0.2570 (7)	0.1107 (2)	0.3073 (3)	0.0315 (13)*
O26	0.5277 (6)	0.15250 (18)	0.2582 (3)	0.0270 (12)*
C11	0.8148 (10)	0.1993 (3)	0.6775 (4)	0.0264 (17)*
H11	0.7182	0.2105	0.6742	0.032*
C12	0.8350 (10)	0.1490 (3)	0.6788 (4)	0.0304 (19)*
H12	0.7534	0.1279	0.6720	0.037*
C13	0.9817 (10)	0.1241 (3)	0.6905 (5)	0.038 (2)*
H13A	1.0439	0.1468	0.7204	0.045*
H13B	0.9693	0.0927	0.7188	0.045*
C14	1.0572 (11)	0.1117 (3)	0.6195 (5)	0.037 (2)*
H14A	1.1616	0.1090	0.6305	0.044*
H14B	1.0236	0.0784	0.6019	0.044*
C15	1.0342 (10)	0.1484 (3)	0.5602 (5)	0.0292 (18)*
H15	1.0209	0.1351	0.5121	0.035*
C16	1.0296 (10)	0.2006 (3)	0.5666 (4)	0.0264 (17)*
H16	1.0051	0.2200	0.5244	0.032*
C17	1.0622 (10)	0.2275 (3)	0.6386 (4)	0.0329 (19)*
H17A	1.1265	0.2062	0.6696	0.040*
H17B	1.1137	0.2592	0.6284	0.040*
C18	0.9289 (10)	0.2395 (3)	0.6806 (5)	0.0352 (19)*
H18A	0.9571	0.2455	0.7327	0.042*
H18B	0.8870	0.2711	0.6610	0.042*
C21	0.5121 (8)	0.1466 (3)	0.3861 (4)	0.0192 (14)*
H21	0.4272	0.1694	0.3812	0.023*
C22	0.4910 (8)	0.1149 (3)	0.4545 (4)	0.0208 (15)*
H22	0.5827	0.0971	0.4672	0.025*
C23	0.3711 (9)	0.0763 (3)	0.4454 (4)	0.0232 (15)*
H23	0.2768	0.0942	0.4445	0.028*
C27	0.2550 (11)	0.0153 (4)	0.5183 (5)	0.043 (2)
H27A	0.2688	−0.0054	0.5624	0.065*
H27B	0.2393	−0.0064	0.4754	0.065*
H27C	0.1713	0.0371	0.5241	0.065*
C24	0.3843 (9)	0.0471 (3)	0.3737 (4)	0.0294 (17)*
H24	0.3020	0.0232	0.3679	0.035*
C28	0.5146 (14)	−0.0298 (3)	0.3971 (7)	0.064 (3)
H28A	0.6091	−0.0453	0.3917	0.096*
H28B	0.4424	−0.0493	0.3691	0.096*
H28C	0.4902	−0.0294	0.4490	0.096*
C25	0.3846 (9)	0.0828 (3)	0.3084 (4)	0.0238 (15)*
H25	0.3900	0.0629	0.2620	0.029*
C29	0.2057 (9)	0.1239 (4)	0.2364 (4)	0.036 (2)
H29A	0.1170	0.1434	0.2401	0.055*
H29B	0.1864	0.0933	0.2078	0.055*
H29C	0.2781	0.1441	0.2119	0.055*
C26	0.5183 (9)	0.1173 (3)	0.3163 (4)	0.0225 (15)*
H26	0.6067	0.0959	0.3177	0.027*
C30	0.5789 (11)	0.1324 (3)	0.1925 (4)	0.036 (2)
H30A	0.5807	0.1588	0.1550	0.055*
H30B	0.5155	0.1051	0.1756	0.055*
H30C	0.6761	0.1193	0.2011	0.055*
C111	0.8450 (9)	0.1052 (3)	0.4003 (4)	0.0249 (16)*
C112	0.8570 (9)	0.0641 (3)	0.4472 (4)	0.0299 (17)*
H112	0.8394	0.0682	0.4980	0.036*
C113	0.8946 (11)	0.0171 (4)	0.4205 (5)	0.043 (2)*
H113	0.9029	−0.0109	0.4526	0.051*
C114	0.9196 (11)	0.0118 (4)	0.3462 (5)	0.042 (2)*
H114	0.9432	−0.0203	0.3274	0.051*
C115	0.9108 (10)	0.0529 (3)	0.2985 (5)	0.038 (2)*
H115	0.9305	0.0488	0.2480	0.046*
C116	0.8731 (9)	0.0996 (3)	0.3252 (4)	0.0301 (18)*
H116	0.8663	0.1277	0.2931	0.036*
C121	0.9026 (9)	0.2113 (3)	0.3961 (4)	0.0224 (15)*
C122	1.0417 (9)	0.1990 (3)	0.3766 (4)	0.0275 (17)*
H122	1.0720	0.1649	0.3772	0.033*
C123	1.1377 (11)	0.2373 (3)	0.3559 (5)	0.040 (2)*
H123	1.2330	0.2291	0.3432	0.048*
C124	1.0926 (12)	0.2864 (4)	0.3541 (5)	0.046 (2)*
H124	1.1565	0.3122	0.3400	0.055*
C125	0.9545 (10)	0.2983 (3)	0.3729 (4)	0.0357 (19)*
H125	0.9253	0.3325	0.3716	0.043*
C126	0.8564 (10)	0.2620 (3)	0.3936 (4)	0.0287 (17)*
H126	0.7613	0.2710	0.4058	0.034*
C211	0.4748 (7)	0.1683 (3)	0.6509 (3)	0.0204 (13)*
C212	0.4313 (9)	0.2070 (3)	0.6986 (4)	0.0255 (16)*
H212	0.4429	0.2409	0.6838	0.031*
C213	0.3716 (10)	0.1971 (3)	0.7672 (5)	0.0346 (19)*
H213	0.3414	0.2239	0.7975	0.042*
C214	0.3576 (11)	0.1480 (3)	0.7896 (5)	0.040 (2)*
H214	0.3193	0.1404	0.8361	0.048*
C215	0.4018 (12)	0.1085 (4)	0.7415 (5)	0.046 (2)*
H215	0.3911	0.0745	0.7565	0.056*
C216	0.4580 (10)	0.1183 (3)	0.6760 (5)	0.0326 (19)*
H216	0.4870	0.0912	0.6459	0.039*
C221	0.5097 (9)	0.2433 (3)	0.5414 (4)	0.0274 (17)*
C222	0.6146 (10)	0.2814 (3)	0.5416 (4)	0.0274 (17)*
H222	0.7121	0.2737	0.5531	0.033*
C223	0.5738 (10)	0.3309 (3)	0.5247 (5)	0.035 (2)*
H223	0.6433	0.3570	0.5263	0.042*
C224	0.4342 (10)	0.3416 (3)	0.5060 (4)	0.0331 (18)*
H224	0.4078	0.3751	0.4936	0.040*
C225	0.3305 (10)	0.3040 (4)	0.5049 (4)	0.0354 (18)*
H225	0.2335	0.3122	0.4928	0.042*
C226	0.3677 (9)	0.2548 (3)	0.5215 (4)	0.0267 (17)*
H226	0.2971	0.2291	0.5193	0.032*
Rh2	0.08715 (6)	0.30622 (2)	0.05804 (3)	0.02121 (13)
P3	0.0865 (2)	0.31006 (8)	−0.06624 (9)	0.0189 (4)
P4	0.3257 (2)	0.29197 (7)	0.06169 (10)	0.0206 (4)
O3	0.2297 (6)	0.29477 (17)	−0.1100 (3)	0.0232 (11)*
O4	0.4324 (6)	0.32300 (18)	0.0098 (3)	0.0273 (12)*
O33	0.5282 (6)	0.4199 (2)	0.0068 (3)	0.0319 (13)*
O34	0.3799 (7)	0.4545 (2)	−0.1177 (3)	0.0328 (13)*
O35	0.6005 (6)	0.3578 (2)	−0.1984 (3)	0.0298 (12)*
O36	0.3114 (6)	0.32666 (19)	−0.2456 (3)	0.0291 (12)*
C41	0.0759 (9)	0.2769 (3)	0.1748 (4)	0.0251 (17)*
H41	0.1683	0.2623	0.1707	0.030*
C42	0.0700 (10)	0.3275 (3)	0.1769 (4)	0.0263 (17)*
H42	0.1575	0.3452	0.1713	0.032*
C43	−0.0647 (10)	0.3589 (3)	0.1876 (5)	0.0334 (19)*
H43A	−0.1308	0.3395	0.2185	0.040*
H43B	−0.0372	0.3897	0.2151	0.040*
C44	−0.1453 (11)	0.3743 (3)	0.1181 (5)	0.037 (2)*
H44A	−0.1037	0.4060	0.0999	0.044*
H44B	−0.2465	0.3811	0.1299	0.044*
C45	−0.1421 (9)	0.3353 (3)	0.0572 (4)	0.0246 (17)*
H45	−0.1329	0.3475	0.0086	0.030*
C46	−0.1509 (10)	0.2857 (3)	0.0652 (5)	0.035 (2)*
H46	−0.1330	0.2654	0.0236	0.042*
C47	−0.1873 (10)	0.2591 (3)	0.1361 (4)	0.0327 (18)*
H47A	−0.2488	0.2296	0.1248	0.039*
H47B	−0.2417	0.2822	0.1676	0.039*
C48	−0.0483 (9)	0.2414 (3)	0.1783 (4)	0.0305 (18)*
H48A	−0.0712	0.2362	0.2305	0.037*
H48B	−0.0189	0.2086	0.1582	0.037*
C31	0.3540 (9)	0.3259 (3)	−0.1172 (4)	0.0240 (16)*
H31	0.4362	0.3025	−0.1248	0.029*
C32	0.3924 (9)	0.3561 (3)	−0.0486 (4)	0.0217 (15)*
H32	0.3071	0.3762	−0.0342	0.026*
C33	0.5192 (9)	0.3913 (3)	−0.0587 (4)	0.0244 (16)*
H33	0.6086	0.3709	−0.0629	0.029*
C37	0.6370 (11)	0.4574 (3)	0.0078 (5)	0.042 (2)
H37A	0.6358	0.4756	0.0546	0.063*
H37B	0.6193	0.4809	−0.0327	0.063*
H37C	0.7309	0.4414	0.0024	0.063*
C34	0.5004 (9)	0.4240 (3)	−0.1269 (4)	0.0239 (15)*
H34	0.5875	0.4454	−0.1331	0.029*
C38	0.3697 (14)	0.4972 (4)	−0.1641 (7)	0.065 (3)
H38A	0.2820	0.5159	−0.1537	0.098*
H38B	0.3666	0.4863	−0.2155	0.098*
H38C	0.4533	0.5189	−0.1552	0.098*
C35	0.4783 (9)	0.3893 (3)	−0.1940 (4)	0.0237 (15)*
H35	0.4693	0.4102	−0.2395	0.028*
C39	0.6391 (11)	0.3443 (4)	−0.2718 (5)	0.040 (2)
H39A	0.7248	0.3229	−0.2697	0.060*
H39B	0.6592	0.3748	−0.2998	0.060*
H39C	0.5597	0.3259	−0.2958	0.060*
C36	0.3433 (8)	0.3590 (3)	−0.1856 (4)	0.0208 (14)*
H36	0.2611	0.3827	−0.1801	0.025*
C40	0.2590 (11)	0.3526 (3)	−0.3098 (4)	0.039 (2)
H40A	0.2391	0.3283	−0.3492	0.058*
H40B	0.3313	0.3767	−0.3256	0.058*
H40C	0.1705	0.3706	−0.2985	0.058*
C311	0.0235 (9)	0.3696 (3)	−0.1056 (4)	0.0234 (15)*
C312	0.0305 (10)	0.4123 (3)	−0.0621 (4)	0.0315 (18)*
H312	0.0632	0.4100	−0.0123	0.038*
C313	−0.0104 (11)	0.4589 (4)	−0.0915 (5)	0.044 (2)*
H313	−0.0047	0.4885	−0.0625	0.053*
C314	−0.0593 (12)	0.4610 (4)	−0.1635 (5)	0.046 (2)*
H314	−0.0910	0.4923	−0.1831	0.055*
C315	−0.0636 (11)	0.4191 (3)	−0.2079 (5)	0.042 (2)*
H315	−0.0954	0.4218	−0.2578	0.050*
C316	−0.0214 (10)	0.3731 (3)	−0.1795 (4)	0.0307 (18)*
H316	−0.0228	0.3440	−0.2098	0.037*
C321	−0.0304 (8)	0.2626 (3)	−0.1047 (4)	0.0217 (15)*
C322	−0.1741 (9)	0.2731 (3)	−0.1235 (4)	0.0268 (16)*
H322	−0.2068	0.3069	−0.1229	0.032*
C323	−0.2696 (10)	0.2351 (3)	−0.1431 (4)	0.0343 (19)*
H323	−0.3672	0.2425	−0.1547	0.041*
C324	−0.2196 (10)	0.1859 (3)	−0.1454 (5)	0.0341 (19)*
H324	−0.2837	0.1596	−0.1593	0.041*
C325	−0.0778 (9)	0.1746 (3)	−0.1275 (4)	0.0350 (18)*
H325	−0.0459	0.1407	−0.1286	0.042*
C326	0.0176 (10)	0.2125 (3)	−0.1082 (4)	0.0291 (17)*
H326	0.1153	0.2047	−0.0973	0.035*
C411	0.4206 (8)	0.3030 (3)	0.1489 (3)	0.0209 (13)*
C412	0.4654 (10)	0.3524 (3)	0.1646 (4)	0.0306 (18)*
H412	0.4506	0.3784	0.1296	0.037*
C413	0.5318 (10)	0.3625 (3)	0.2323 (4)	0.0340 (19)*
H413	0.5626	0.3957	0.2435	0.041*
C414	0.5535 (10)	0.3247 (3)	0.2837 (5)	0.0355 (19)*
H414	0.5969	0.3321	0.3302	0.043*
C415	0.5115 (10)	0.2758 (3)	0.2669 (5)	0.0332 (18)*
H415	0.5269	0.2496	0.3017	0.040*
C416	0.4478 (8)	0.2654 (3)	0.1997 (4)	0.0218 (15)*
H416	0.4218	0.2318	0.1880	0.026*
C421	0.3663 (9)	0.2276 (3)	0.0387 (4)	0.0247 (16)*
C422	0.2635 (10)	0.1906 (3)	0.0437 (4)	0.0300 (17)*
H422	0.1697	0.1987	0.0589	0.036*
C423	0.2984 (11)	0.1411 (4)	0.0261 (5)	0.041 (2)*
H423	0.2273	0.1157	0.0292	0.050*
C424	0.4348 (10)	0.1285 (3)	0.0042 (5)	0.0362 (19)*
H424	0.4577	0.0946	−0.0071	0.043*
C425	0.5361 (10)	0.1652 (3)	−0.0011 (4)	0.0379 (19)*
H425	0.6295	0.1567	−0.0166	0.045*
C426	0.5050 (9)	0.2151 (3)	0.0157 (4)	0.0285 (17)*
H426	0.5765	0.2403	0.0118	0.034*
C7	0.816 (2)	−0.0490 (5)	0.6177 (8)	0.090 (5)
C8	0.8153 (17)	0.0220 (4)	0.8885 (7)	0.072 (4)
Cl7A	0.6659 (10)	−0.0086 (3)	0.5805 (5)	0.0881 (16)*	0.564 (10)
Cl8A	0.7082 (9)	−0.0225 (2)	0.9321 (4)	0.0829 (17)	0.534 (6)
H7A	0.8471	−0.0705	0.5737	0.11 (4)*	0.564 (10)
H8A	0.8273	0.0498	0.9275	0.11 (4)*	0.534 (6)
Cl7B	0.7224 (13)	0.0063 (4)	0.6036 (6)	0.0881 (16)*	0.436 (10)
Cl8B	0.7818 (10)	−0.0464 (3)	0.8923 (5)	0.0829 (17)	0.466 (6)
H7B	0.8352	−0.0665	0.5681	0.11 (4)*	0.436 (10)
H8B	0.8101	0.0400	0.9385	0.11 (4)*	0.466 (6)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Rh1	0.0163 (3)	0.0237 (3)	0.0208 (3)	0.0020 (2)	−0.0024 (2)	−0.0020 (2)
P1	0.0154 (11)	0.0205 (9)	0.0209 (8)	0.0018 (7)	−0.0004 (7)	0.0010 (8)
P2	0.0098 (11)	0.0242 (11)	0.0206 (8)	−0.0008 (7)	−0.0004 (7)	−0.0023 (7)
Cl71	0.121 (4)	0.069 (2)	0.123 (3)	−0.003 (2)	0.035 (3)	0.039 (2)
Cl72	0.190 (7)	0.132 (5)	0.186 (6)	−0.085 (5)	0.051 (5)	−0.024 (4)
Cl81	0.107 (3)	0.074 (2)	0.113 (3)	−0.010 (2)	−0.029 (3)	0.033 (2)
Cl82	0.155 (6)	0.198 (6)	0.134 (5)	0.099 (5)	0.020 (4)	0.003 (4)
B1	0.030 (7)	0.044 (6)	0.039 (5)	−0.007 (4)	0.004 (4)	0.001 (4)
B2	0.047 (8)	0.034 (5)	0.046 (6)	−0.008 (5)	−0.004 (5)	−0.001 (5)
F11	0.168 (10)	0.130 (8)	0.059 (5)	−0.044 (7)	−0.052 (6)	0.040 (5)
F12	0.086 (7)	0.069 (5)	0.132 (7)	−0.012 (4)	0.050 (5)	−0.027 (5)
F13	0.078 (5)	0.038 (3)	0.075 (4)	−0.006 (3)	0.001 (4)	−0.004 (3)
F14	0.055 (5)	0.053 (4)	0.098 (5)	−0.004 (3)	−0.007 (4)	−0.002 (4)
F21	0.076 (6)	0.035 (3)	0.100 (5)	−0.009 (3)	−0.020 (4)	0.018 (3)
F22	0.105 (7)	0.061 (4)	0.069 (4)	0.023 (4)	−0.031 (4)	0.005 (3)
F23	0.056 (5)	0.039 (3)	0.126 (6)	−0.004 (3)	0.002 (4)	0.008 (4)
F24	0.101 (8)	0.105 (6)	0.087 (6)	−0.023 (5)	0.031 (5)	−0.046 (5)
C27	0.041 (7)	0.039 (5)	0.051 (6)	−0.014 (4)	0.016 (4)	−0.002 (4)
C28	0.090 (10)	0.022 (5)	0.082 (8)	0.019 (5)	0.026 (7)	−0.002 (5)
C29	0.019 (5)	0.065 (6)	0.025 (4)	0.002 (4)	−0.005 (3)	0.008 (4)
C30	0.040 (6)	0.045 (5)	0.024 (4)	−0.004 (4)	−0.001 (4)	−0.004 (4)
Rh2	0.0153 (3)	0.0270 (3)	0.0212 (3)	−0.0017 (2)	−0.0020 (2)	0.0028 (2)
P3	0.0169 (11)	0.0196 (9)	0.0201 (8)	−0.0020 (8)	−0.0017 (6)	0.0032 (8)
P4	0.0157 (12)	0.0242 (10)	0.0217 (9)	−0.0017 (7)	−0.0021 (7)	0.0047 (7)
C37	0.048 (7)	0.031 (5)	0.047 (5)	−0.018 (4)	−0.010 (4)	0.000 (4)
C38	0.076 (10)	0.049 (6)	0.071 (8)	0.017 (6)	0.016 (6)	0.028 (6)
C39	0.040 (7)	0.048 (5)	0.031 (4)	−0.003 (4)	0.014 (4)	−0.003 (4)
C40	0.050 (7)	0.043 (5)	0.023 (4)	−0.004 (4)	−0.007 (4)	0.002 (4)
C7	0.127 (15)	0.048 (7)	0.095 (11)	0.003 (8)	0.043 (10)	0.011 (7)
C8	0.112 (12)	0.046 (6)	0.058 (7)	−0.023 (7)	−0.013 (7)	0.010 (5)
Cl8A	0.096 (5)	0.060 (3)	0.091 (4)	−0.014 (3)	−0.018 (3)	0.035 (3)
Cl8B	0.096 (5)	0.060 (3)	0.091 (4)	−0.014 (3)	−0.018 (3)	0.035 (3)

Geometric parameters (Å, º)

Rh1—C12	2.227 (8)	C225—H225	0.9500
Rh1—C11	2.256 (8)	C226—H226	0.9500
Rh1—P2	2.257 (2)	Rh2—C42	2.249 (8)
Rh1—C15	2.259 (9)	Rh2—P4	2.255 (2)
Rh1—P1	2.2719 (18)	Rh2—P3	2.2662 (18)
Rh1—C16	2.291 (9)	Rh2—C41	2.271 (8)
P1—O1	1.613 (5)	Rh2—C45	2.273 (8)
P1—C121	1.799 (8)	Rh2—C46	2.293 (10)
P1—C111	1.816 (8)	P3—O3	1.625 (6)
P2—O2	1.614 (5)	P3—C321	1.797 (7)
P2—C211	1.795 (7)	P3—C311	1.830 (7)
P2—C221	1.811 (8)	P4—O4	1.618 (6)
Cl71—C7	1.707 (14)	P4—C421	1.805 (8)
Cl72—C7	1.713 (19)	P4—C411	1.820 (7)
Cl81—C8	1.705 (13)	O3—C31	1.433 (9)
Cl82—C8	1.783 (17)	O4—C32	1.423 (8)
B1—F11	1.339 (12)	O33—C33	1.415 (9)
B1—F14	1.356 (13)	O33—C37	1.422 (10)
B1—F13	1.362 (12)	O34—C34	1.400 (9)
B1—F12	1.407 (13)	O34—C38	1.418 (11)
B2—F22	1.363 (13)	O35—C35	1.419 (9)
B2—F24	1.365 (14)	O35—C39	1.440 (10)
B2—F23	1.373 (14)	O36—C36	1.416 (8)
B2—F21	1.393 (12)	O36—C40	1.433 (9)
O1—C21	1.460 (9)	C41—C42	1.348 (10)
O2—C22	1.431 (8)	C41—C48	1.497 (11)
O23—C23	1.408 (9)	C41—H41	0.9500
O23—C27	1.430 (11)	C42—C43	1.525 (12)
O24—C28	1.409 (11)	C42—H42	0.9500
O24—C24	1.441 (10)	C43—C44	1.511 (12)
O25—C25	1.402 (10)	C43—H43A	0.9900
O25—C29	1.410 (9)	C43—H43B	0.9900
O26—C30	1.407 (10)	C44—C45	1.520 (11)
O26—C26	1.418 (8)	C44—H44A	0.9900
C11—C12	1.352 (11)	C44—H44B	0.9900
C11—C18	1.509 (12)	C45—C46	1.331 (11)
C11—H11	0.9500	C45—H45	0.9500
C12—C13	1.529 (12)	C46—C47	1.519 (12)
C12—H12	0.9500	C46—H46	0.9500
C13—C14	1.526 (12)	C47—C48	1.560 (11)
C13—H13A	0.9900	C47—H47A	0.9900
C13—H13B	0.9900	C47—H47B	0.9900
C14—C15	1.468 (11)	C48—H48A	0.9900
C14—H14A	0.9900	C48—H48B	0.9900
C14—H14B	0.9900	C31—C32	1.521 (10)
C15—C16	1.395 (10)	C31—C36	1.526 (9)
C15—H15	0.9500	C31—H31	1.0000
C16—C17	1.518 (11)	C32—C33	1.523 (10)
C16—H16	0.9500	C32—H32	1.0000
C17—C18	1.512 (12)	C33—C34	1.523 (10)
C17—H17A	0.9900	C33—H33	1.0000
C17—H17B	0.9900	C37—H37A	0.9800
C18—H18A	0.9900	C37—H37B	0.9800
C18—H18B	0.9900	C37—H37C	0.9800
C21—C26	1.495 (9)	C34—C35	1.541 (10)
C21—C22	1.521 (9)	C34—H34	1.0000
C21—H21	1.0000	C38—H38A	0.9800
C22—C23	1.525 (10)	C38—H38B	0.9800
C22—H22	1.0000	C38—H38C	0.9800
C23—C24	1.527 (10)	C35—C36	1.507 (10)
C23—H23	1.0000	C35—H35	1.0000
C27—H27A	0.9800	C39—H39A	0.9800
C27—H27B	0.9800	C39—H39B	0.9800
C27—H27C	0.9800	C39—H39C	0.9800
C24—C25	1.522 (10)	C36—H36	1.0000
C24—H24	1.0000	C40—H40A	0.9800
C28—H28A	0.9800	C40—H40B	0.9800
C28—H28B	0.9800	C40—H40C	0.9800
C28—H28C	0.9800	C311—C312	1.386 (10)
C25—C26	1.552 (11)	C311—C316	1.402 (11)
C25—H25	1.0000	C312—C313	1.401 (12)
C29—H29A	0.9800	C312—H312	0.9500
C29—H29B	0.9800	C313—C314	1.376 (13)
C29—H29C	0.9800	C313—H313	0.9500
C26—H26	1.0000	C314—C315	1.379 (13)
C30—H30A	0.9800	C314—H314	0.9500
C30—H30B	0.9800	C315—C316	1.383 (12)
C30—H30C	0.9800	C315—H315	0.9500
C111—C112	1.391 (10)	C316—H316	0.9500
C111—C116	1.408 (11)	C321—C322	1.401 (11)
C112—C113	1.390 (12)	C321—C326	1.411 (10)
C112—H112	0.9500	C322—C323	1.387 (11)
C113—C114	1.386 (13)	C322—H322	0.9500
C113—H113	0.9500	C323—C324	1.391 (12)
C114—C115	1.398 (12)	C323—H323	0.9500
C114—H114	0.9500	C324—C325	1.385 (12)
C115—C116	1.384 (12)	C324—H324	0.9500
C115—H115	0.9500	C325—C326	1.382 (12)
C116—H116	0.9500	C325—H325	0.9500
C121—C122	1.393 (12)	C326—H326	0.9500
C121—C126	1.418 (10)	C411—C416	1.382 (10)
C122—C123	1.415 (12)	C411—C412	1.405 (11)
C122—H122	0.9500	C412—C413	1.391 (11)
C123—C124	1.374 (13)	C412—H412	0.9500
C123—H123	0.9500	C413—C414	1.384 (11)
C124—C125	1.377 (14)	C413—H413	0.9500
C124—H124	0.9500	C414—C415	1.390 (11)
C125—C126	1.388 (12)	C414—H414	0.9500
C125—H125	0.9500	C415—C416	1.373 (11)
C126—H126	0.9500	C415—H415	0.9500
C211—C212	1.415 (10)	C416—H416	0.9500
C211—C216	1.417 (11)	C421—C422	1.379 (11)
C212—C213	1.406 (11)	C421—C426	1.411 (12)
C212—H212	0.9500	C422—C423	1.396 (12)
C213—C214	1.378 (12)	C422—H422	0.9500
C213—H213	0.9500	C423—C424	1.385 (14)
C214—C215	1.437 (13)	C423—H423	0.9500
C214—H214	0.9500	C424—C425	1.364 (13)
C215—C216	1.343 (13)	C424—H424	0.9500
C215—H215	0.9500	C425—C426	1.394 (12)
C216—H216	0.9500	C425—H425	0.9500
C221—C226	1.397 (11)	C426—H426	0.9500
C221—C222	1.409 (11)	C7—Cl7B	1.726 (17)
C222—C223	1.402 (11)	C7—Cl7A	1.875 (18)
C222—H222	0.9500	C7—H7A	1.034
C223—C224	1.366 (13)	C7—H7B	1.037
C223—H223	0.9500	C8—Cl8A	1.752 (14)
C224—C225	1.391 (12)	C8—Cl8B	1.847 (13)
C224—H224	0.9500	C8—H8A	1.029
C225—C226	1.387 (12)	C8—H8B	1.031
C12—Rh1—C11	35.1 (3)	P4—Rh2—C45	169.7 (2)
C12—Rh1—P2	96.7 (2)	P3—Rh2—C45	90.1 (2)
C11—Rh1—P2	88.1 (2)	C41—Rh2—C45	93.2 (3)
C12—Rh1—C15	80.1 (3)	C42—Rh2—C46	84.8 (3)
C11—Rh1—C15	93.5 (3)	P4—Rh2—C46	156.0 (2)
P2—Rh1—C15	171.6 (2)	P3—Rh2—C46	95.3 (2)
C12—Rh1—P1	161.4 (2)	C41—Rh2—C46	78.1 (3)
C11—Rh1—P1	162.9 (2)	C45—Rh2—C46	33.9 (3)
P2—Rh1—P1	90.93 (7)	O3—P3—C321	97.5 (3)
C15—Rh1—P1	89.9 (2)	O3—P3—C311	106.5 (3)
C12—Rh1—C16	86.4 (3)	C321—P3—C311	105.7 (4)
C11—Rh1—C16	78.7 (3)	O3—P3—Rh2	120.00 (19)
P2—Rh1—C16	152.4 (2)	C321—P3—Rh2	110.1 (2)
C15—Rh1—C16	35.7 (3)	C311—P3—Rh2	115.0 (2)
P1—Rh1—C16	94.7 (2)	O4—P4—C421	102.3 (3)
O1—P1—C121	99.6 (3)	O4—P4—C411	97.8 (3)
O1—P1—C111	106.0 (3)	C421—P4—C411	104.8 (3)
C121—P1—C111	105.3 (4)	O4—P4—Rh2	121.2 (2)
O1—P1—Rh1	119.12 (19)	C421—P4—Rh2	111.4 (3)
C121—P1—Rh1	111.1 (2)	C411—P4—Rh2	117.0 (2)
C111—P1—Rh1	114.0 (2)	C31—O3—P3	125.3 (4)
O2—P2—C211	96.4 (3)	C32—O4—P4	126.9 (5)
O2—P2—C221	104.0 (3)	C33—O33—C37	114.5 (7)
C211—P2—C221	104.3 (4)	C34—O34—C38	115.7 (7)
O2—P2—Rh1	121.5 (2)	C35—O35—C39	115.0 (6)
C211—P2—Rh1	118.1 (2)	C36—O36—C40	113.4 (6)
C221—P2—Rh1	110.2 (3)	C42—C41—C48	126.6 (8)
F11—B1—F14	108.8 (9)	C42—C41—Rh2	71.7 (5)
F11—B1—F13	112.1 (9)	C48—C41—Rh2	108.2 (5)
F14—B1—F13	112.2 (9)	C42—C41—H41	116.7
F11—B1—F12	110.8 (11)	C48—C41—H41	116.7
F14—B1—F12	105.4 (9)	Rh2—C41—H41	90.0
F13—B1—F12	107.4 (9)	C41—C42—C43	125.8 (8)
F22—B2—F24	107.1 (11)	C41—C42—Rh2	73.5 (5)
F22—B2—F23	109.1 (10)	C43—C42—Rh2	110.0 (5)
F24—B2—F23	109.7 (9)	C41—C42—H42	117.1
F22—B2—F21	109.7 (8)	C43—C42—H42	117.1
F24—B2—F21	112.3 (10)	Rh2—C42—H42	86.3
F23—B2—F21	108.9 (9)	C44—C43—C42	115.7 (7)
C21—O1—P1	127.1 (4)	C44—C43—H43A	108.3
C22—O2—P2	125.8 (5)	C42—C43—H43A	108.3
C23—O23—C27	113.8 (7)	C44—C43—H43B	108.3
C28—O24—C24	115.7 (7)	C42—C43—H43B	108.3
C25—O25—C29	114.2 (6)	H43A—C43—H43B	107.4
C30—O26—C26	114.3 (6)	C43—C44—C45	114.0 (7)
C12—C11—C18	127.2 (9)	C43—C44—H44A	108.8
C12—C11—Rh1	71.3 (5)	C45—C44—H44A	108.8
C18—C11—Rh1	107.8 (5)	C43—C44—H44B	108.8
C12—C11—H11	116.4	C45—C44—H44B	108.8
C18—C11—H11	116.4	H44A—C44—H44B	107.7
Rh1—C11—H11	90.9	C46—C45—C44	126.5 (8)
C11—C12—C13	123.7 (8)	C46—C45—Rh2	73.9 (6)
C11—C12—Rh1	73.6 (5)	C44—C45—Rh2	105.4 (5)
C13—C12—Rh1	110.5 (6)	C46—C45—H45	116.7
C11—C12—H12	118.2	C44—C45—H45	116.7
C13—C12—H12	118.2	Rh2—C45—H45	90.8
Rh1—C12—H12	85.9	C45—C46—C47	124.8 (8)
C14—C13—C12	114.0 (7)	C45—C46—Rh2	72.2 (6)
C14—C13—H13A	108.7	C47—C46—Rh2	113.5 (6)
C12—C13—H13A	108.7	C45—C46—H46	117.6
C14—C13—H13B	108.7	C47—C46—H46	117.6
C12—C13—H13B	108.7	Rh2—C46—H46	84.2
H13A—C13—H13B	107.6	C46—C47—C48	110.9 (7)
C15—C14—C13	114.7 (8)	C46—C47—H47A	109.5
C15—C14—H14A	108.6	C48—C47—H47A	109.5
C13—C14—H14A	108.6	C46—C47—H47B	109.5
C15—C14—H14B	108.6	C48—C47—H47B	109.5
C13—C14—H14B	108.6	H47A—C47—H47B	108.0
H14A—C14—H14B	107.6	C41—C48—C47	115.0 (7)
C16—C15—C14	127.3 (8)	C41—C48—H48A	108.5
C16—C15—Rh1	73.4 (5)	C47—C48—H48A	108.5
C14—C15—Rh1	106.5 (6)	C41—C48—H48B	108.5
C16—C15—H15	116.4	C47—C48—H48B	108.5
C14—C15—H15	116.4	H48A—C48—H48B	107.5
Rh1—C15—H15	90.1	O3—C31—C32	113.8 (6)
C15—C16—C17	122.4 (8)	O3—C31—C36	111.9 (6)
C15—C16—Rh1	70.9 (5)	C32—C31—C36	111.9 (6)
C17—C16—Rh1	111.7 (6)	O3—C31—H31	106.2
C15—C16—H16	118.8	C32—C31—H31	106.2
C17—C16—H16	118.8	C36—C31—H31	106.2
Rh1—C16—H16	87.5	O4—C32—C31	109.7 (5)
C18—C17—C16	112.9 (7)	O4—C32—C33	106.5 (6)
C18—C17—H17A	109.0	C31—C32—C33	113.1 (6)
C16—C17—H17A	109.0	O4—C32—H32	109.2
C18—C17—H17B	109.0	C31—C32—H32	109.2
C16—C17—H17B	109.0	C33—C32—H32	109.2
H17A—C17—H17B	107.8	O33—C33—C32	104.9 (6)
C11—C18—C17	114.8 (7)	O33—C33—C34	112.5 (6)
C11—C18—H18A	108.6	C32—C33—C34	112.2 (6)
C17—C18—H18A	108.6	O33—C33—H33	109.0
C11—C18—H18B	108.6	C32—C33—H33	109.0
C17—C18—H18B	108.6	C34—C33—H33	109.0
H18A—C18—H18B	107.5	O33—C37—H37A	109.5
O1—C21—C26	109.8 (6)	O33—C37—H37B	109.5
O1—C21—C22	111.4 (5)	H37A—C37—H37B	109.5
C26—C21—C22	114.6 (6)	O33—C37—H37C	109.5
O1—C21—H21	106.9	H37A—C37—H37C	109.5
C26—C21—H21	106.9	H37B—C37—H37C	109.5
C22—C21—H21	106.9	O34—C34—C33	107.9 (6)
O2—C22—C21	111.4 (5)	O34—C34—C35	110.7 (6)
O2—C22—C23	105.2 (6)	C33—C34—C35	108.3 (6)
C21—C22—C23	113.3 (6)	O34—C34—H34	110.0
O2—C22—H22	108.9	C33—C34—H34	110.0
C21—C22—H22	108.9	C35—C34—H34	110.0
C23—C22—H22	108.9	O34—C38—H38A	109.5
O23—C23—C22	106.2 (6)	O34—C38—H38B	109.5
O23—C23—C24	113.4 (6)	H38A—C38—H38B	109.5
C22—C23—C24	111.0 (6)	O34—C38—H38C	109.5
O23—C23—H23	108.7	H38A—C38—H38C	109.5
C22—C23—H23	108.7	H38B—C38—H38C	109.5
C24—C23—H23	108.7	O35—C35—C36	111.3 (6)
O23—C27—H27A	109.5	O35—C35—C34	108.0 (6)
O23—C27—H27B	109.5	C36—C35—C34	109.5 (6)
H27A—C27—H27B	109.5	O35—C35—H35	109.3
O23—C27—H27C	109.5	C36—C35—H35	109.3
H27A—C27—H27C	109.5	C34—C35—H35	109.3
H27B—C27—H27C	109.5	O35—C39—H39A	109.5
O24—C24—C25	105.0 (6)	O35—C39—H39B	109.5
O24—C24—C23	112.6 (6)	H39A—C39—H39B	109.5
C25—C24—C23	110.7 (6)	O35—C39—H39C	109.5
O24—C24—H24	109.4	H39A—C39—H39C	109.5
C25—C24—H24	109.4	H39B—C39—H39C	109.5
C23—C24—H24	109.4	O36—C36—C35	113.9 (6)
O24—C28—H28A	109.5	O36—C36—C31	106.7 (5)
O24—C28—H28B	109.5	C35—C36—C31	110.9 (6)
H28A—C28—H28B	109.5	O36—C36—H36	108.4
O24—C28—H28C	109.5	C35—C36—H36	108.4
H28A—C28—H28C	109.5	C31—C36—H36	108.4
H28B—C28—H28C	109.5	O36—C40—H40A	109.5
O25—C25—C24	108.7 (6)	O36—C40—H40B	109.5
O25—C25—C26	111.6 (6)	H40A—C40—H40B	109.5
C24—C25—C26	108.3 (6)	O36—C40—H40C	109.5
O25—C25—H25	109.4	H40A—C40—H40C	109.5
C24—C25—H25	109.4	H40B—C40—H40C	109.5
C26—C25—H25	109.4	C312—C311—C316	120.3 (7)
O25—C29—H29A	109.5	C312—C311—P3	118.4 (6)
O25—C29—H29B	109.5	C316—C311—P3	121.1 (6)
H29A—C29—H29B	109.5	C311—C312—C313	119.9 (8)
O25—C29—H29C	109.5	C311—C312—H312	120.0
H29A—C29—H29C	109.5	C313—C312—H312	120.0
H29B—C29—H29C	109.5	C314—C313—C312	118.7 (9)
O26—C26—C21	107.1 (5)	C314—C313—H313	120.7
O26—C26—C25	112.8 (6)	C312—C313—H313	120.7
C21—C26—C25	109.7 (6)	C313—C314—C315	122.0 (9)
O26—C26—H26	109.1	C313—C314—H314	119.0
C21—C26—H26	109.1	C315—C314—H314	119.0
C25—C26—H26	109.1	C314—C315—C316	119.6 (9)
O26—C30—H30A	109.5	C314—C315—H315	120.2
O26—C30—H30B	109.5	C316—C315—H315	120.2
H30A—C30—H30B	109.5	C315—C316—C311	119.4 (8)
O26—C30—H30C	109.5	C315—C316—H316	120.3
H30A—C30—H30C	109.5	C311—C316—H316	120.3
H30B—C30—H30C	109.5	C322—C321—C326	118.6 (7)
C112—C111—C116	120.0 (7)	C322—C321—P3	121.5 (6)
C112—C111—P1	119.2 (6)	C326—C321—P3	119.5 (6)
C116—C111—P1	120.8 (6)	C323—C322—C321	121.4 (8)
C113—C112—C111	120.6 (8)	C323—C322—H322	119.3
C113—C112—H112	119.7	C321—C322—H322	119.3
C111—C112—H112	119.7	C322—C323—C324	118.7 (9)
C114—C113—C112	118.9 (9)	C322—C323—H323	120.6
C114—C113—H113	120.5	C324—C323—H323	120.6
C112—C113—H113	120.5	C325—C324—C323	121.0 (9)
C113—C114—C115	121.3 (9)	C325—C324—H324	119.5
C113—C114—H114	119.4	C323—C324—H324	119.5
C115—C114—H114	119.4	C326—C325—C324	120.4 (9)
C116—C115—C114	119.7 (8)	C326—C325—H325	119.8
C116—C115—H115	120.2	C324—C325—H325	119.8
C114—C115—H115	120.2	C325—C326—C321	119.9 (8)
C115—C116—C111	119.5 (8)	C325—C326—H326	120.1
C115—C116—H116	120.3	C321—C326—H326	120.1
C111—C116—H116	120.3	C416—C411—C412	119.5 (6)
C122—C121—C126	120.0 (7)	C416—C411—P4	122.9 (6)
C122—C121—P1	120.9 (6)	C412—C411—P4	117.6 (5)
C126—C121—P1	118.5 (6)	C413—C412—C411	118.9 (7)
C121—C122—C123	119.9 (8)	C413—C412—H412	120.5
C121—C122—H122	120.0	C411—C412—H412	120.5
C123—C122—H122	120.0	C414—C413—C412	120.8 (8)
C124—C123—C122	119.8 (10)	C414—C413—H413	119.6
C124—C123—H123	120.1	C412—C413—H413	119.6
C122—C123—H123	120.1	C413—C414—C415	119.8 (8)
C123—C124—C125	120.0 (10)	C413—C414—H414	120.1
C123—C124—H124	120.0	C415—C414—H414	120.1
C125—C124—H124	120.0	C416—C415—C414	119.7 (8)
C124—C125—C126	122.4 (9)	C416—C415—H415	120.1
C124—C125—H125	118.8	C414—C415—H415	120.1
C126—C125—H125	118.8	C415—C416—C411	121.2 (7)
C125—C126—C121	117.9 (8)	C415—C416—H416	119.4
C125—C126—H126	121.1	C411—C416—H416	119.4
C121—C126—H126	121.1	C422—C421—C426	119.6 (7)
C212—C211—C216	116.7 (7)	C422—C421—P4	120.8 (6)
C212—C211—P2	123.7 (6)	C426—C421—P4	119.6 (6)
C216—C211—P2	119.4 (6)	C421—C422—C423	119.5 (9)
C213—C212—C211	122.5 (7)	C421—C422—H422	120.2
C213—C212—H212	118.8	C423—C422—H422	120.2
C211—C212—H212	118.8	C424—C423—C422	121.1 (9)
C214—C213—C212	118.9 (8)	C424—C423—H423	119.5
C214—C213—H213	120.5	C422—C423—H423	119.5
C212—C213—H213	120.5	C425—C424—C423	119.3 (9)
C213—C214—C215	118.9 (9)	C425—C424—H424	120.3
C213—C214—H214	120.6	C423—C424—H424	120.3
C215—C214—H214	120.6	C424—C425—C426	121.2 (9)
C216—C215—C214	121.7 (9)	C424—C425—H425	119.4
C216—C215—H215	119.1	C426—C425—H425	119.4
C214—C215—H215	119.1	C425—C426—C421	119.3 (8)
C215—C216—C211	121.2 (8)	C425—C426—H426	120.4
C215—C216—H216	119.4	C421—C426—H426	120.4
C211—C216—H216	119.4	Cl71—C7—Cl72	112.5 (10)
C226—C221—C222	119.7 (7)	Cl71—C7—Cl7B	113.7 (10)
C226—C221—P2	120.2 (6)	Cl72—C7—Cl7B	96.5 (9)
C222—C221—P2	120.1 (6)	Cl71—C7—Cl7A	104.8 (9)
C223—C222—C221	119.4 (8)	Cl72—C7—Cl7A	120.4 (8)
C223—C222—H222	120.3	Cl71—C7—H7A	106.4 (10)
C221—C222—H222	120.3	Cl72—C7—H7A	106.7 (13)
C224—C223—C222	120.1 (8)	Cl7B—C7—H7A	120.6 (13)
C224—C223—H223	119.9	Cl7A—C7—H7A	105.1 (12)
C222—C223—H223	119.9	Cl71—C7—H7B	111.1 (10)
C223—C224—C225	120.7 (8)	Cl72—C7—H7B	111.6 (13)
C223—C224—H224	119.7	Cl7B—C7—H7B	110.7 (12)
C225—C224—H224	119.7	Cl7A—C7—H7B	95.1 (12)
C226—C225—C224	120.4 (8)	Cl81—C8—Cl8A	108.2 (8)
C226—C225—H225	119.8	Cl81—C8—Cl82	110.5 (8)
C224—C225—H225	119.8	Cl8A—C8—Cl82	124.7 (8)
C225—C226—C221	119.6 (8)	Cl81—C8—Cl8B	111.4 (7)
C225—C226—H226	120.2	Cl82—C8—Cl8B	90.2 (8)
C221—C226—H226	120.2	Cl81—C8—H8A	103.5 (9)
C42—Rh2—P4	96.3 (2)	Cl8A—C8—H8A	103.0 (10)
C42—Rh2—P3	162.3 (2)	Cl82—C8—H8A	104.6 (10)
P4—Rh2—P3	90.69 (7)	Cl8B—C8—H8A	134.2 (10)
C42—Rh2—C41	34.7 (3)	Cl81—C8—H8B	113.5 (11)
P4—Rh2—C41	89.2 (2)	Cl8A—C8—H8B	82.6 (8)
P3—Rh2—C41	162.2 (2)	Cl82—C8—H8B	114.7 (11)
C42—Rh2—C45	80.1 (3)	Cl8B—C8—H8B	114.3 (9)
C12—Rh1—P1—O1	124.6 (8)	C45—Rh2—P3—O3	178.5 (3)
C11—Rh1—P1—O1	−76.6 (8)	C46—Rh2—P3—O3	−148.0 (3)
P2—Rh1—P1—O1	10.1 (2)	C42—Rh2—P3—C321	−125.9 (8)
C15—Rh1—P1—O1	−178.3 (3)	P4—Rh2—P3—C321	120.5 (3)
C16—Rh1—P1—O1	−142.9 (3)	C41—Rh2—P3—C321	31.0 (8)
C12—Rh1—P1—C121	−120.6 (8)	C45—Rh2—P3—C321	−69.8 (3)
C11—Rh1—P1—C121	38.2 (9)	C46—Rh2—P3—C321	−36.2 (4)
P2—Rh1—P1—C121	124.9 (3)	C42—Rh2—P3—C311	−6.7 (8)
C15—Rh1—P1—C121	−63.5 (3)	P4—Rh2—P3—C311	−120.3 (3)
C16—Rh1—P1—C121	−28.1 (3)	C41—Rh2—P3—C311	150.2 (8)
C12—Rh1—P1—C111	−1.8 (8)	C45—Rh2—P3—C311	49.4 (4)
C11—Rh1—P1—C111	157.0 (8)	C46—Rh2—P3—C311	83.0 (4)
P2—Rh1—P1—C111	−116.3 (3)	C42—Rh2—P4—O4	−121.1 (3)
C15—Rh1—P1—C111	55.3 (4)	P3—Rh2—P4—O4	42.7 (2)
C16—Rh1—P1—C111	90.7 (4)	C41—Rh2—P4—O4	−155.1 (3)
C12—Rh1—P2—O2	−118.9 (3)	C45—Rh2—P4—O4	−51.7 (12)
C11—Rh1—P2—O2	−152.9 (3)	C46—Rh2—P4—O4	147.4 (6)
P1—Rh1—P2—O2	44.1 (2)	C42—Rh2—P4—C421	118.6 (3)
C16—Rh1—P2—O2	146.1 (5)	P3—Rh2—P4—C421	−77.7 (3)
C12—Rh1—P2—C211	−0.5 (4)	C41—Rh2—P4—C421	84.6 (3)
C11—Rh1—P2—C211	−34.5 (3)	C45—Rh2—P4—C421	−172.1 (11)
P1—Rh1—P2—C211	162.5 (3)	C46—Rh2—P4—C421	27.0 (6)
C16—Rh1—P2—C211	−95.5 (5)	C42—Rh2—P4—C411	−2.0 (3)
C12—Rh1—P2—C221	119.2 (3)	P3—Rh2—P4—C411	161.8 (3)
C11—Rh1—P2—C221	85.1 (3)	C41—Rh2—P4—C411	−36.0 (3)
P1—Rh1—P2—C221	−77.8 (3)	C45—Rh2—P4—C411	67.4 (12)
C16—Rh1—P2—C221	24.2 (5)	C46—Rh2—P4—C411	−93.5 (6)
C121—P1—O1—C21	161.1 (5)	C321—P3—O3—C31	164.0 (5)
C111—P1—O1—C21	52.0 (6)	C311—P3—O3—C31	55.1 (6)
Rh1—P1—O1—C21	−78.0 (5)	Rh2—P3—O3—C31	−77.7 (5)
C211—P2—O2—C22	−143.3 (5)	C421—P4—O4—C32	115.7 (6)
C221—P2—O2—C22	110.2 (6)	C411—P4—O4—C32	−137.2 (6)
Rh1—P2—O2—C22	−14.7 (6)	Rh2—P4—O4—C32	−9.0 (6)
P2—Rh1—C11—C12	104.5 (6)	P4—Rh2—C41—C42	102.4 (6)
C15—Rh1—C11—C12	−67.3 (6)	P3—Rh2—C41—C42	−167.9 (5)
P1—Rh1—C11—C12	−168.4 (6)	C45—Rh2—C41—C42	−67.6 (6)
C16—Rh1—C11—C12	−99.9 (6)	C46—Rh2—C41—C42	−98.2 (6)
C12—Rh1—C11—C18	124.2 (9)	C42—Rh2—C41—C48	123.5 (9)
P2—Rh1—C11—C18	−131.3 (6)	P4—Rh2—C41—C48	−134.1 (5)
C15—Rh1—C11—C18	56.9 (6)	P3—Rh2—C41—C48	−44.4 (11)
P1—Rh1—C11—C18	−44.2 (12)	C45—Rh2—C41—C48	55.9 (6)
C16—Rh1—C11—C18	24.3 (6)	C46—Rh2—C41—C48	25.4 (6)
C18—C11—C12—C13	5.5 (14)	C48—C41—C42—C43	3.5 (14)
Rh1—C11—C12—C13	104.0 (8)	Rh2—C41—C42—C43	103.0 (8)
C18—C11—C12—Rh1	−98.6 (8)	C48—C41—C42—Rh2	−99.5 (8)
P2—Rh1—C12—C11	−77.0 (6)	P4—Rh2—C42—C41	−79.3 (6)
C15—Rh1—C12—C11	110.9 (6)	P3—Rh2—C42—C41	167.8 (5)
P1—Rh1—C12—C11	169.4 (6)	C45—Rh2—C42—C41	110.5 (6)
C16—Rh1—C12—C11	75.5 (6)	C46—Rh2—C42—C41	76.6 (6)
C11—Rh1—C12—C13	−120.4 (9)	P4—Rh2—C42—C43	157.9 (5)
P2—Rh1—C12—C13	162.5 (5)	P3—Rh2—C42—C43	45.0 (11)
C15—Rh1—C12—C13	−9.6 (6)	C41—Rh2—C42—C43	−122.8 (9)
P1—Rh1—C12—C13	48.9 (11)	C45—Rh2—C42—C43	−12.3 (5)
C16—Rh1—C12—C13	−45.0 (6)	C46—Rh2—C42—C43	−46.2 (6)
C11—C12—C13—C14	−93.1 (10)	C41—C42—C43—C44	−91.0 (11)
Rh1—C12—C13—C14	−9.6 (9)	Rh2—C42—C43—C44	−7.3 (9)
C12—C13—C14—C15	35.8 (11)	C42—C43—C44—C45	34.7 (11)
C13—C14—C15—C16	39.8 (14)	C43—C44—C45—C46	38.8 (13)
C13—C14—C15—Rh1	−41.7 (9)	C43—C44—C45—Rh2	−42.3 (9)
C12—Rh1—C15—C16	−97.6 (5)	C42—Rh2—C45—C46	−95.5 (6)
C11—Rh1—C15—C16	−65.0 (5)	P4—Rh2—C45—C46	−166.2 (9)
P1—Rh1—C15—C16	98.2 (5)	P3—Rh2—C45—C46	99.4 (5)
C12—Rh1—C15—C14	27.2 (6)	C41—Rh2—C45—C46	−63.2 (6)
C11—Rh1—C15—C14	59.8 (6)	C42—Rh2—C45—C44	28.8 (5)
P1—Rh1—C15—C14	−137.0 (5)	P4—Rh2—C45—C44	−41.9 (14)
C16—Rh1—C15—C14	124.8 (8)	P3—Rh2—C45—C44	−136.4 (5)
C14—C15—C16—C17	5.7 (15)	C41—Rh2—C45—C44	61.1 (5)
Rh1—C15—C16—C17	104.1 (8)	C46—Rh2—C45—C44	124.2 (8)
C14—C15—C16—Rh1	−98.4 (10)	C44—C45—C46—C47	9.3 (16)
C12—Rh1—C16—C15	78.1 (5)	Rh2—C45—C46—C47	106.7 (9)
C11—Rh1—C16—C15	112.7 (5)	C44—C45—C46—Rh2	−97.4 (9)
P2—Rh1—C16—C15	175.6 (4)	C42—Rh2—C46—C45	80.0 (5)
P1—Rh1—C16—C15	−83.2 (5)	P4—Rh2—C46—C45	174.0 (4)
C12—Rh1—C16—C17	−40.1 (6)	P3—Rh2—C46—C45	−82.3 (5)
C11—Rh1—C16—C17	−5.6 (6)	C41—Rh2—C46—C45	114.4 (6)
P2—Rh1—C16—C17	57.4 (8)	C42—Rh2—C46—C47	−41.0 (6)
C15—Rh1—C16—C17	−118.2 (8)	P4—Rh2—C46—C47	53.0 (10)
P1—Rh1—C16—C17	158.5 (5)	P3—Rh2—C46—C47	156.8 (6)
C15—C16—C17—C18	−95.3 (10)	C41—Rh2—C46—C47	−6.5 (6)
Rh1—C16—C17—C18	−14.7 (9)	C45—Rh2—C46—C47	−120.9 (9)
C12—C11—C18—C17	38.1 (12)	C45—C46—C47—C48	−97.2 (11)
Rh1—C11—C18—C17	−41.7 (8)	Rh2—C46—C47—C48	−13.1 (9)
C16—C17—C18—C11	38.4 (10)	C42—C41—C48—C47	38.2 (12)
P1—O1—C21—C26	−92.8 (6)	Rh2—C41—C48—C47	−42.2 (8)
P1—O1—C21—C22	35.2 (8)	C46—C47—C48—C41	37.5 (10)
P2—O2—C22—C21	−77.8 (7)	P3—O3—C31—C32	37.8 (8)
P2—O2—C22—C23	159.0 (5)	P3—O3—C31—C36	−90.4 (6)
O1—C21—C22—O2	68.5 (8)	P4—O4—C32—C31	−80.3 (7)
C26—C21—C22—O2	−166.0 (6)	P4—O4—C32—C33	157.1 (5)
O1—C21—C22—C23	−173.0 (6)	O3—C31—C32—O4	64.8 (8)
C26—C21—C22—C23	−47.5 (9)	C36—C31—C32—O4	−167.1 (6)
C27—O23—C23—C22	165.1 (7)	O3—C31—C32—C33	−176.5 (6)
C27—O23—C23—C24	−72.7 (9)	C36—C31—C32—C33	−48.4 (9)
O2—C22—C23—O23	−66.6 (7)	C37—O33—C33—C32	−177.3 (7)
C21—C22—C23—O23	171.4 (6)	C37—O33—C33—C34	−55.0 (9)
O2—C22—C23—C24	169.7 (6)	O4—C32—C33—O33	−65.9 (7)
C21—C22—C23—C24	47.7 (8)	C31—C32—C33—O33	173.5 (6)
C28—O24—C24—C25	−148.8 (8)	O4—C32—C33—C34	171.6 (6)
C28—O24—C24—C23	90.6 (9)	C31—C32—C33—C34	51.1 (8)
O23—C23—C24—O24	−58.8 (9)	C38—O34—C34—C33	162.0 (8)
C22—C23—C24—O24	60.6 (8)	C38—O34—C34—C35	−79.7 (9)
O23—C23—C24—C25	−176.1 (7)	O33—C33—C34—O34	−55.2 (8)
C22—C23—C24—C25	−56.6 (9)	C32—C33—C34—O34	62.8 (8)
C29—O25—C25—C24	−148.0 (7)	O33—C33—C34—C35	−175.0 (6)
C29—O25—C25—C26	92.6 (8)	C32—C33—C34—C35	−57.0 (8)
O24—C24—C25—O25	179.4 (6)	C39—O35—C35—C36	92.6 (8)
C23—C24—C25—O25	−58.7 (8)	C39—O35—C35—C34	−147.1 (7)
O24—C24—C25—C26	−59.2 (7)	O34—C34—C35—O35	−177.2 (6)
C23—C24—C25—C26	62.7 (8)	C33—C34—C35—O35	−59.1 (8)
C30—O26—C26—C21	161.1 (7)	O34—C34—C35—C36	−55.8 (8)
C30—O26—C26—C25	−78.1 (8)	C33—C34—C35—C36	62.2 (8)
O1—C21—C26—O26	−57.9 (7)	C40—O36—C36—C35	−73.7 (8)
C22—C21—C26—O26	175.8 (6)	C40—O36—C36—C31	163.6 (7)
O1—C21—C26—C25	179.3 (5)	O35—C35—C36—O36	−62.1 (8)
C22—C21—C26—C25	53.1 (8)	C34—C35—C36—O36	178.5 (6)
O25—C25—C26—O26	−59.7 (8)	O35—C35—C36—C31	58.2 (8)
C24—C25—C26—O26	−179.3 (6)	C34—C35—C36—C31	−61.2 (7)
O25—C25—C26—C21	59.6 (7)	O3—C31—C36—O36	−52.6 (8)
C24—C25—C26—C21	−60.0 (8)	C32—C31—C36—O36	178.3 (6)
O1—P1—C111—C112	−117.6 (7)	O3—C31—C36—C35	−177.1 (6)
C121—P1—C111—C112	137.5 (7)	C32—C31—C36—C35	53.8 (8)
Rh1—P1—C111—C112	15.4 (8)	O3—P3—C311—C312	−112.6 (7)
O1—P1—C111—C116	60.6 (8)	C321—P3—C311—C312	144.4 (7)
C121—P1—C111—C116	−44.3 (8)	Rh2—P3—C311—C312	22.8 (8)
Rh1—P1—C111—C116	−166.4 (6)	O3—P3—C311—C316	62.8 (7)
C116—C111—C112—C113	−1.0 (13)	C321—P3—C311—C316	−40.1 (8)
P1—C111—C112—C113	177.2 (7)	Rh2—P3—C311—C316	−161.7 (6)
C111—C112—C113—C114	−0.1 (14)	C316—C311—C312—C313	1.5 (13)
C112—C113—C114—C115	1.4 (15)	P3—C311—C312—C313	177.0 (7)
C113—C114—C115—C116	−1.5 (15)	C311—C312—C313—C314	1.0 (14)
C114—C115—C116—C111	0.4 (13)	C312—C313—C314—C315	−2.6 (16)
C112—C111—C116—C115	0.8 (13)	C313—C314—C315—C316	1.7 (16)
P1—C111—C116—C115	−177.3 (7)	C314—C315—C316—C311	0.8 (14)
O1—P1—C121—C122	−139.1 (6)	C312—C311—C316—C315	−2.4 (13)
C111—P1—C121—C122	−29.4 (7)	P3—C311—C316—C315	−177.8 (7)
Rh1—P1—C121—C122	94.5 (6)	O3—P3—C321—C322	−140.6 (6)
O1—P1—C121—C126	49.6 (6)	C311—P3—C321—C322	−31.1 (7)
C111—P1—C121—C126	159.2 (6)	Rh2—P3—C321—C322	93.6 (6)
Rh1—P1—C121—C126	−76.8 (6)	O3—P3—C321—C326	47.0 (6)
C126—C121—C122—C123	1.4 (11)	C311—P3—C321—C326	156.5 (6)
P1—C121—C122—C123	−169.8 (6)	Rh2—P3—C321—C326	−78.8 (6)
C121—C122—C123—C124	−0.9 (13)	C326—C321—C322—C323	2.0 (11)
C122—C123—C124—C125	0.4 (14)	P3—C321—C322—C323	−170.5 (6)
C123—C124—C125—C126	−0.3 (14)	C321—C322—C323—C324	−1.4 (12)
C124—C125—C126—C121	0.8 (12)	C322—C323—C324—C325	0.9 (12)
C122—C121—C126—C125	−1.3 (11)	C323—C324—C325—C326	−1.1 (12)
P1—C121—C126—C125	170.1 (6)	C324—C325—C326—C321	1.7 (12)
O2—P2—C211—C212	−127.9 (6)	C322—C321—C326—C325	−2.1 (11)
C221—P2—C211—C212	−21.6 (7)	P3—C321—C326—C325	170.5 (6)
Rh1—P2—C211—C212	101.1 (6)	O4—P4—C411—C416	−134.5 (6)
O2—P2—C211—C216	56.7 (6)	C421—P4—C411—C416	−29.6 (7)
C221—P2—C211—C216	162.9 (6)	Rh2—P4—C411—C416	94.4 (6)
Rh1—P2—C211—C216	−74.4 (6)	O4—P4—C411—C412	46.4 (7)
C216—C211—C212—C213	−1.2 (12)	C421—P4—C411—C412	151.4 (6)
P2—C211—C212—C213	−176.7 (7)	Rh2—P4—C411—C412	−84.6 (6)
C211—C212—C213—C214	1.4 (14)	C416—C411—C412—C413	−2.2 (12)
C212—C213—C214—C215	−1.2 (14)	P4—C411—C412—C413	176.8 (7)
C213—C214—C215—C216	0.9 (16)	C411—C412—C413—C414	−0.1 (13)
C214—C215—C216—C211	−0.7 (15)	C412—C413—C414—C415	1.5 (14)
C212—C211—C216—C215	0.8 (12)	C413—C414—C415—C416	−0.5 (14)
P2—C211—C216—C215	176.5 (8)	C414—C415—C416—C411	−1.8 (13)
O2—P2—C221—C226	31.4 (7)	C412—C411—C416—C415	3.2 (12)
C211—P2—C221—C226	−69.1 (7)	P4—C411—C416—C415	−175.8 (6)
Rh1—P2—C221—C226	163.2 (5)	O4—P4—C421—C422	−150.9 (6)
O2—P2—C221—C222	−147.4 (6)	C411—P4—C421—C422	107.5 (7)
C211—P2—C221—C222	112.1 (7)	Rh2—P4—C421—C422	−20.0 (7)
Rh1—P2—C221—C222	−15.6 (7)	O4—P4—C421—C426	29.4 (7)
C226—C221—C222—C223	2.7 (12)	C411—P4—C421—C426	−72.2 (7)
P2—C221—C222—C223	−178.6 (6)	Rh2—P4—C421—C426	160.3 (5)
C221—C222—C223—C224	−2.1 (13)	C426—C421—C422—C423	0.2 (12)
C222—C223—C224—C225	1.4 (13)	P4—C421—C422—C423	−179.5 (7)
C223—C224—C225—C226	−1.3 (12)	C421—C422—C423—C424	0.4 (13)
C224—C225—C226—C221	1.9 (12)	C422—C423—C424—C425	−0.8 (14)
C222—C221—C226—C225	−2.6 (11)	C423—C424—C425—C426	0.6 (13)
P2—C221—C226—C225	178.7 (6)	C424—C425—C426—C421	0.0 (12)
C42—Rh2—P3—O3	122.4 (8)	C422—C421—C426—C425	−0.4 (11)
P4—Rh2—P3—O3	8.7 (2)	P4—C421—C426—C425	179.3 (6)
C41—Rh2—P3—O3	−80.8 (8)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C7—H7A···F23^i	1.03	2.39	3.402 (17)	166
C8—H8A···F12^ii	1.03	2.29	3.148 (16)	139
C8—H8A···F14^ii	1.03	2.34	3.262 (14)	149
C113—H113···F23^i	0.95	2.45	3.258 (12)	142
C115—H115···F11	0.95	2.38	3.210 (12)	146
C124—H124···Cl71^iii	0.95	2.83	3.726 (12)	158
C313—H313···F12^iv	0.95	2.55	3.482 (13)	167
C315—H315···F24^v	0.95	2.53	3.426 (13)	158
C423—H423···F12^vi	0.95	2.40	3.296 (14)	157
C18—H18A···Cg1^vii	0.99	2.77	3.607 (10)	142
C48—H48A···Cg2^vi	0.99	2.71	3.600 (8)	150
C47—H47B···Cg3^vi	0.99	2.82	3.693 (10)	147

Symmetry codes: (i) −x+2, y−1/2, −z+1; (ii) x, y, z+1; (iii) −x+2, y+1/2, −z+1; (iv) −x+1, y+1/2, −z; (v) x−1, y, z−1; (vi) x−1, y, z; (vii) x+1, y, z+1.