In the title compound, [Mn(C
7H
4O
5S)(C
12H
8N
2)
2(H
2O)]·3H
2O, the Mn
II atom displays an octahedral MnN
4O
2 configuration, defined by four N atoms from two 1,10-phenanthroline ligands, one carboxyl O atom belonging to a 2-sulfobenzoate dianion and one aqua O atom. O—H
O hydrogen bonds involving 2-sulfobenzoate dianions, aqua ligands and uncoordinated water molecules link the mononuclear units into a three-dimensional network structure.
Supporting information
CCDC reference: 271865
Key indicators
- Single-crystal X-ray study
- T = 298 K
- Mean (C-C) = 0.008 Å
- R factor = 0.073
- wR factor = 0.154
- Data-to-parameter ratio = 12.7
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 8
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
2 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
0 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP in SHELXTL (Bruker, 2002); software used to prepare material for publication: SHELXL97.
[Aquabis(1,10-phenanthroline-
κ2N,
N')(2-sulfobenzoato-
κO)manganese(II)] trihydrate
top
Crystal data top
[Mn(C12H8N2)2(C7H4SO5)(H2O)]·3H2O | Z = 2 |
Mr = 687.57 | F(000) = 710 |
Triclinic, P1 | Dx = 1.483 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 10.2204 (11) Å | Cell parameters from 1690 reflections |
b = 12.4047 (13) Å | θ = 2.2–21.1° |
c = 13.7842 (15) Å | µ = 0.56 mm−1 |
α = 106.505 (2)° | T = 298 K |
β = 94.417 (2)° | Rod, yellow |
γ = 110.455 (2)° | 0.39 × 0.18 × 0.16 mm |
V = 1539.4 (3) Å3 | |
Data collection top
Bruker SMART CCD area-detector diffractometer | 5575 independent reflections |
Radiation source: fine-focus sealed tube | 4185 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.045 |
φ and ω scans | θmax = 25.3°, θmin = 1.9° |
Absorption correction: multi-scan (SADABS; Bruker, 2002) | h = −12→12 |
Tmin = 0.812, Tmax = 0.916 | k = −14→14 |
11511 measured reflections | l = −16→16 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.073 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.154 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.12 | w = 1/[σ2(Fo2) + (0.0587P)2 + 0.7094P] where P = (Fo2 + 2Fc2)/3 |
5575 reflections | (Δ/σ)max = 0.003 |
439 parameters | Δρmax = 0.45 e Å−3 |
9 restraints | Δρmin = −0.43 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Mn1 | 0.76836 (7) | 0.95273 (6) | 0.24448 (5) | 0.0281 (2) | |
S1 | 0.87676 (12) | 0.70189 (10) | 0.39829 (8) | 0.0347 (3) | |
O1 | 0.8370 (3) | 0.8073 (3) | 0.2128 (2) | 0.0381 (7) | |
O2 | 0.6471 (4) | 0.6488 (3) | 0.1125 (3) | 0.0589 (10) | |
O3 | 0.7336 (3) | 0.6963 (3) | 0.3798 (2) | 0.0489 (9) | |
O4 | 0.9842 (3) | 0.8252 (3) | 0.4244 (2) | 0.0417 (8) | |
O5 | 0.9004 (4) | 0.6446 (3) | 0.4713 (3) | 0.0559 (9) | |
O6 | 0.9404 (4) | 1.0152 (3) | 0.3748 (2) | 0.0462 (9) | |
O7 | 0.4290 (6) | 0.4383 (5) | 0.1076 (4) | 0.1107 (19) | |
O8 | 0.4822 (6) | 0.4638 (6) | 0.3176 (5) | 0.122 (2) | |
O9 | 0.7911 (6) | 0.5734 (6) | 0.6361 (4) | 0.1104 (17) | |
N1 | 0.6392 (4) | 0.9073 (3) | 0.0837 (3) | 0.0348 (9) | |
N2 | 0.9124 (4) | 1.0677 (3) | 0.1618 (3) | 0.0331 (8) | |
N3 | 0.7182 (4) | 1.1170 (3) | 0.3311 (3) | 0.0340 (9) | |
N4 | 0.5617 (4) | 0.8780 (3) | 0.2986 (3) | 0.0334 (9) | |
C1 | 0.7671 (5) | 0.6946 (4) | 0.1691 (3) | 0.0352 (11) | |
C2 | 0.8400 (5) | 0.6109 (4) | 0.1838 (3) | 0.0344 (11) | |
C3 | 0.8999 (4) | 0.6132 (4) | 0.2789 (3) | 0.0337 (10) | |
C4 | 0.9719 (5) | 0.5386 (4) | 0.2836 (4) | 0.0437 (12) | |
H4 | 1.0124 | 0.5409 | 0.3473 | 0.052* | |
C5 | 0.9840 (6) | 0.4599 (5) | 0.1934 (5) | 0.0590 (15) | |
H5 | 1.0339 | 0.4107 | 0.1968 | 0.071* | |
C6 | 0.9229 (6) | 0.4552 (5) | 0.1004 (5) | 0.0604 (16) | |
H6 | 0.9298 | 0.4016 | 0.0401 | 0.072* | |
C7 | 0.8502 (6) | 0.5301 (4) | 0.0949 (4) | 0.0495 (13) | |
H7 | 0.8081 | 0.5257 | 0.0309 | 0.059* | |
C8 | 0.5097 (5) | 0.8246 (5) | 0.0430 (4) | 0.0477 (13) | |
H8 | 0.4619 | 0.7807 | 0.0831 | 0.057* | |
C9 | 0.4401 (6) | 0.7989 (5) | −0.0569 (4) | 0.0606 (15) | |
H9 | 0.3481 | 0.7399 | −0.0822 | 0.073* | |
C10 | 0.5078 (6) | 0.8608 (5) | −0.1160 (4) | 0.0592 (15) | |
H10 | 0.4624 | 0.8447 | −0.1827 | 0.071* | |
C11 | 0.6466 (5) | 0.9496 (5) | −0.0777 (4) | 0.0460 (13) | |
C12 | 0.7265 (6) | 1.0171 (6) | −0.1356 (4) | 0.0604 (15) | |
H12 | 0.6846 | 1.0051 | −0.2022 | 0.073* | |
C13 | 0.8611 (6) | 1.0980 (5) | −0.0969 (4) | 0.0581 (15) | |
H13 | 0.9103 | 1.1414 | −0.1367 | 0.070* | |
C14 | 0.9292 (5) | 1.1181 (4) | 0.0042 (4) | 0.0415 (12) | |
C15 | 1.0714 (6) | 1.1966 (4) | 0.0470 (4) | 0.0511 (14) | |
H15 | 1.1258 | 1.2403 | 0.0093 | 0.061* | |
C16 | 1.1298 (5) | 1.2091 (4) | 0.1431 (4) | 0.0510 (14) | |
H16 | 1.2243 | 1.2611 | 0.1717 | 0.061* | |
C17 | 1.0475 (5) | 1.1435 (4) | 0.1988 (4) | 0.0455 (12) | |
H17 | 1.0888 | 1.1532 | 0.2649 | 0.055* | |
C18 | 0.8530 (5) | 1.0542 (4) | 0.0651 (3) | 0.0332 (10) | |
C19 | 0.7090 (5) | 0.9692 (4) | 0.0241 (3) | 0.0359 (11) | |
C20 | 0.7977 (5) | 1.2348 (4) | 0.3518 (4) | 0.0452 (12) | |
H20 | 0.8861 | 1.2556 | 0.3326 | 0.054* | |
C21 | 0.7555 (6) | 1.3279 (5) | 0.4004 (4) | 0.0575 (15) | |
H21 | 0.8150 | 1.4089 | 0.4136 | 0.069* | |
C22 | 0.6262 (6) | 1.2995 (5) | 0.4285 (4) | 0.0524 (14) | |
H22 | 0.5960 | 1.3610 | 0.4602 | 0.063* | |
C23 | 0.5386 (5) | 1.1767 (4) | 0.4095 (3) | 0.0411 (11) | |
C24 | 0.4032 (6) | 1.1397 (5) | 0.4393 (4) | 0.0502 (13) | |
H24 | 0.3680 | 1.1979 | 0.4705 | 0.060* | |
C25 | 0.3271 (5) | 1.0215 (5) | 0.4225 (4) | 0.0481 (13) | |
H25 | 0.2395 | 0.9993 | 0.4428 | 0.058* | |
C26 | 0.3757 (5) | 0.9283 (4) | 0.3744 (3) | 0.0383 (11) | |
C27 | 0.2986 (5) | 0.8035 (5) | 0.3570 (4) | 0.0497 (13) | |
H27 | 0.2103 | 0.7778 | 0.3757 | 0.060* | |
C28 | 0.3537 (5) | 0.7213 (5) | 0.3129 (4) | 0.0500 (13) | |
H28 | 0.3040 | 0.6386 | 0.3014 | 0.060* | |
C29 | 0.4858 (5) | 0.7618 (4) | 0.2849 (4) | 0.0429 (12) | |
H29 | 0.5227 | 0.7043 | 0.2550 | 0.051* | |
C30 | 0.5075 (4) | 0.9614 (4) | 0.3439 (3) | 0.0311 (10) | |
C31 | 0.5913 (5) | 1.0885 (4) | 0.3617 (3) | 0.0324 (10) | |
H6A | 0.960 (5) | 0.958 (3) | 0.381 (4) | 0.049* | |
H6B | 0.961 (5) | 1.064 (3) | 0.4351 (19) | 0.049* | |
H7A | 0.407 (5) | 0.395 (4) | 0.0444 (18) | 0.049* | |
H7B | 0.476 (5) | 0.509 (2) | 0.109 (4) | 0.049* | |
H8A | 0.477 (5) | 0.452 (5) | 0.2538 (17) | 0.049* | |
H8B | 0.557 (3) | 0.528 (3) | 0.340 (4) | 0.049* | |
H9A | 0.713 (3) | 0.593 (5) | 0.636 (3) | 0.049* | |
H9B | 0.821 (4) | 0.596 (4) | 0.584 (3) | 0.049* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Mn1 | 0.0273 (4) | 0.0291 (4) | 0.0273 (4) | 0.0102 (3) | 0.0067 (3) | 0.0091 (3) |
S1 | 0.0365 (7) | 0.0337 (6) | 0.0333 (7) | 0.0136 (5) | 0.0084 (5) | 0.0097 (5) |
O1 | 0.0455 (19) | 0.0260 (17) | 0.0402 (19) | 0.0154 (15) | 0.0048 (15) | 0.0066 (14) |
O2 | 0.057 (2) | 0.045 (2) | 0.055 (2) | 0.0144 (19) | −0.0133 (19) | 0.0028 (18) |
O3 | 0.0400 (19) | 0.061 (2) | 0.042 (2) | 0.0222 (17) | 0.0150 (15) | 0.0056 (17) |
O4 | 0.0463 (19) | 0.0324 (17) | 0.0341 (18) | 0.0098 (15) | 0.0018 (14) | 0.0016 (14) |
O5 | 0.076 (3) | 0.054 (2) | 0.046 (2) | 0.030 (2) | 0.0143 (18) | 0.0224 (18) |
O6 | 0.062 (2) | 0.034 (2) | 0.0333 (19) | 0.0220 (18) | −0.0106 (17) | −0.0010 (15) |
O7 | 0.119 (4) | 0.089 (4) | 0.059 (3) | −0.023 (3) | 0.007 (3) | 0.012 (3) |
O8 | 0.091 (4) | 0.135 (5) | 0.102 (4) | −0.016 (3) | 0.009 (4) | 0.060 (4) |
O9 | 0.136 (5) | 0.137 (5) | 0.076 (4) | 0.059 (4) | 0.036 (3) | 0.050 (3) |
N1 | 0.037 (2) | 0.035 (2) | 0.032 (2) | 0.0126 (18) | 0.0091 (17) | 0.0116 (17) |
N2 | 0.031 (2) | 0.030 (2) | 0.036 (2) | 0.0117 (17) | 0.0108 (17) | 0.0088 (17) |
N3 | 0.035 (2) | 0.032 (2) | 0.034 (2) | 0.0123 (17) | 0.0087 (17) | 0.0095 (17) |
N4 | 0.035 (2) | 0.033 (2) | 0.032 (2) | 0.0114 (18) | 0.0098 (16) | 0.0108 (17) |
C1 | 0.047 (3) | 0.032 (3) | 0.025 (2) | 0.016 (2) | 0.014 (2) | 0.005 (2) |
C2 | 0.041 (3) | 0.024 (2) | 0.035 (3) | 0.009 (2) | 0.017 (2) | 0.0076 (19) |
C3 | 0.034 (2) | 0.023 (2) | 0.042 (3) | 0.0075 (19) | 0.016 (2) | 0.010 (2) |
C4 | 0.036 (3) | 0.034 (3) | 0.063 (3) | 0.015 (2) | 0.014 (2) | 0.016 (2) |
C5 | 0.059 (4) | 0.039 (3) | 0.089 (5) | 0.028 (3) | 0.035 (3) | 0.021 (3) |
C6 | 0.079 (4) | 0.039 (3) | 0.065 (4) | 0.029 (3) | 0.041 (3) | 0.007 (3) |
C7 | 0.066 (4) | 0.037 (3) | 0.046 (3) | 0.020 (3) | 0.027 (3) | 0.011 (2) |
C8 | 0.042 (3) | 0.056 (3) | 0.044 (3) | 0.013 (3) | 0.003 (2) | 0.022 (3) |
C9 | 0.048 (3) | 0.066 (4) | 0.053 (4) | 0.012 (3) | −0.009 (3) | 0.015 (3) |
C10 | 0.055 (4) | 0.082 (4) | 0.041 (3) | 0.031 (3) | −0.002 (3) | 0.018 (3) |
C11 | 0.054 (3) | 0.061 (3) | 0.040 (3) | 0.036 (3) | 0.012 (2) | 0.023 (3) |
C12 | 0.070 (4) | 0.093 (5) | 0.040 (3) | 0.042 (4) | 0.020 (3) | 0.039 (3) |
C13 | 0.078 (4) | 0.073 (4) | 0.057 (4) | 0.043 (4) | 0.038 (3) | 0.048 (3) |
C14 | 0.053 (3) | 0.039 (3) | 0.046 (3) | 0.027 (2) | 0.025 (2) | 0.019 (2) |
C15 | 0.068 (4) | 0.042 (3) | 0.062 (4) | 0.030 (3) | 0.040 (3) | 0.027 (3) |
C16 | 0.040 (3) | 0.038 (3) | 0.066 (4) | 0.007 (2) | 0.024 (3) | 0.013 (3) |
C17 | 0.045 (3) | 0.039 (3) | 0.044 (3) | 0.014 (2) | 0.010 (2) | 0.005 (2) |
C18 | 0.048 (3) | 0.030 (2) | 0.035 (3) | 0.026 (2) | 0.019 (2) | 0.014 (2) |
C19 | 0.041 (3) | 0.041 (3) | 0.035 (3) | 0.024 (2) | 0.012 (2) | 0.016 (2) |
C20 | 0.045 (3) | 0.038 (3) | 0.050 (3) | 0.011 (2) | 0.014 (2) | 0.016 (2) |
C21 | 0.070 (4) | 0.031 (3) | 0.068 (4) | 0.015 (3) | 0.022 (3) | 0.013 (3) |
C22 | 0.074 (4) | 0.042 (3) | 0.048 (3) | 0.032 (3) | 0.017 (3) | 0.011 (2) |
C23 | 0.052 (3) | 0.048 (3) | 0.032 (3) | 0.028 (3) | 0.014 (2) | 0.015 (2) |
C24 | 0.061 (3) | 0.063 (4) | 0.042 (3) | 0.040 (3) | 0.021 (3) | 0.016 (3) |
C25 | 0.041 (3) | 0.070 (4) | 0.048 (3) | 0.031 (3) | 0.022 (2) | 0.025 (3) |
C26 | 0.033 (3) | 0.052 (3) | 0.035 (3) | 0.017 (2) | 0.012 (2) | 0.020 (2) |
C27 | 0.035 (3) | 0.062 (4) | 0.057 (3) | 0.014 (3) | 0.020 (2) | 0.030 (3) |
C28 | 0.041 (3) | 0.042 (3) | 0.058 (3) | 0.004 (2) | 0.015 (3) | 0.018 (3) |
C29 | 0.046 (3) | 0.035 (3) | 0.047 (3) | 0.013 (2) | 0.011 (2) | 0.016 (2) |
C30 | 0.033 (2) | 0.039 (3) | 0.021 (2) | 0.015 (2) | 0.0008 (18) | 0.0107 (19) |
C31 | 0.037 (3) | 0.041 (3) | 0.023 (2) | 0.019 (2) | 0.0049 (19) | 0.012 (2) |
Geometric parameters (Å, º) top
Mn1—O1 | 2.103 (3) | C8—H8 | 0.9300 |
Mn1—O6 | 2.165 (3) | C9—C10 | 1.343 (7) |
Mn1—N4 | 2.268 (3) | C9—H9 | 0.9300 |
Mn1—N2 | 2.284 (3) | C10—C11 | 1.402 (7) |
Mn1—N3 | 2.299 (3) | C10—H10 | 0.9300 |
Mn1—N1 | 2.301 (4) | C11—C19 | 1.413 (6) |
S1—O5 | 1.438 (3) | C11—C12 | 1.417 (7) |
S1—O3 | 1.440 (3) | C12—C13 | 1.342 (7) |
S1—O4 | 1.459 (3) | C12—H12 | 0.9300 |
S1—C3 | 1.785 (4) | C13—C14 | 1.421 (7) |
O1—C1 | 1.258 (5) | C13—H13 | 0.9300 |
O2—C1 | 1.245 (5) | C14—C15 | 1.401 (7) |
O6—H6A | 0.83 (4) | C14—C18 | 1.409 (6) |
O6—H6B | 0.84 (2) | C15—C16 | 1.354 (7) |
O7—H7A | 0.85 (2) | C15—H15 | 0.9300 |
O7—H7B | 0.84 (2) | C16—C17 | 1.392 (7) |
O8—H8A | 0.85 (2) | C16—H16 | 0.9300 |
O8—H8B | 0.84 (4) | C17—H17 | 0.9300 |
O9—H9A | 0.91 (4) | C18—C19 | 1.431 (6) |
O9—H9B | 0.88 (4) | C20—C21 | 1.386 (7) |
N1—C8 | 1.315 (6) | C20—H20 | 0.9300 |
N1—C19 | 1.355 (5) | C21—C22 | 1.361 (7) |
N2—C17 | 1.328 (5) | C21—H21 | 0.9300 |
N2—C18 | 1.360 (5) | C22—C23 | 1.404 (7) |
N3—C20 | 1.332 (5) | C22—H22 | 0.9300 |
N3—C31 | 1.354 (5) | C23—C31 | 1.407 (6) |
N4—C29 | 1.325 (5) | C23—C24 | 1.430 (7) |
N4—C30 | 1.362 (5) | C24—C25 | 1.338 (7) |
C1—C2 | 1.521 (6) | C24—H24 | 0.9300 |
C2—C7 | 1.382 (6) | C25—C26 | 1.428 (6) |
C2—C3 | 1.392 (6) | C25—H25 | 0.9300 |
C3—C4 | 1.380 (6) | C26—C30 | 1.400 (6) |
C4—C5 | 1.390 (7) | C26—C27 | 1.408 (6) |
C4—H4 | 0.9300 | C27—C28 | 1.353 (7) |
C5—C6 | 1.359 (8) | C27—H27 | 0.9300 |
C5—H5 | 0.9300 | C28—C29 | 1.393 (6) |
C6—C7 | 1.391 (7) | C28—H28 | 0.9300 |
C6—H6 | 0.9300 | C29—H29 | 0.9300 |
C7—H7 | 0.9300 | C30—C31 | 1.443 (6) |
C8—C9 | 1.395 (7) | | |
| | | |
O1—Mn1—O6 | 77.97 (12) | C9—C10—C11 | 120.3 (5) |
O1—Mn1—N4 | 103.12 (12) | C9—C10—H10 | 119.8 |
O6—Mn1—N4 | 107.20 (14) | C11—C10—H10 | 119.8 |
O1—Mn1—N2 | 99.11 (12) | C10—C11—C19 | 116.8 (5) |
O6—Mn1—N2 | 91.79 (14) | C10—C11—C12 | 123.9 (5) |
N4—Mn1—N2 | 153.24 (13) | C19—C11—C12 | 119.3 (5) |
O1—Mn1—N3 | 162.04 (12) | C13—C12—C11 | 121.7 (5) |
O6—Mn1—N3 | 86.39 (12) | C13—C12—H12 | 119.1 |
N4—Mn1—N3 | 72.96 (13) | C11—C12—H12 | 119.1 |
N2—Mn1—N3 | 90.07 (12) | C12—C13—C14 | 120.8 (5) |
O1—Mn1—N1 | 99.12 (12) | C12—C13—H13 | 119.6 |
O6—Mn1—N1 | 163.50 (14) | C14—C13—H13 | 119.6 |
N4—Mn1—N1 | 89.30 (13) | C15—C14—C18 | 117.1 (5) |
N2—Mn1—N1 | 72.49 (13) | C15—C14—C13 | 123.5 (5) |
N3—Mn1—N1 | 98.36 (13) | C18—C14—C13 | 119.4 (5) |
O5—S1—O3 | 113.7 (2) | C16—C15—C14 | 120.1 (4) |
O5—S1—O4 | 111.6 (2) | C16—C15—H15 | 120.0 |
O3—S1—O4 | 112.9 (2) | C14—C15—H15 | 120.0 |
O5—S1—C3 | 105.1 (2) | C15—C16—C17 | 119.5 (5) |
O3—S1—C3 | 105.8 (2) | C15—C16—H16 | 120.3 |
O4—S1—C3 | 106.93 (19) | C17—C16—H16 | 120.3 |
C1—O1—Mn1 | 130.0 (3) | N2—C17—C16 | 122.8 (5) |
Mn1—O6—H6A | 111 (3) | N2—C17—H17 | 118.6 |
Mn1—O6—H6B | 134 (3) | C16—C17—H17 | 118.6 |
H6A—O6—H6B | 104 (5) | N2—C18—C14 | 122.4 (4) |
H7A—O7—H7B | 105 (5) | N2—C18—C19 | 117.9 (4) |
H8A—O8—H8B | 99 (5) | C14—C18—C19 | 119.7 (4) |
H9A—O9—H9B | 99 (2) | N1—C19—C11 | 122.5 (4) |
C8—N1—C19 | 117.8 (4) | N1—C19—C18 | 118.4 (4) |
C8—N1—Mn1 | 126.8 (3) | C11—C19—C18 | 119.0 (4) |
C19—N1—Mn1 | 115.3 (3) | N3—C20—C21 | 123.4 (5) |
C17—N2—C18 | 118.1 (4) | N3—C20—H20 | 118.3 |
C17—N2—Mn1 | 125.9 (3) | C21—C20—H20 | 118.3 |
C18—N2—Mn1 | 116.0 (3) | C22—C21—C20 | 119.4 (5) |
C20—N3—C31 | 117.5 (4) | C22—C21—H21 | 120.3 |
C20—N3—Mn1 | 127.4 (3) | C20—C21—H21 | 120.3 |
C31—N3—Mn1 | 115.1 (3) | C21—C22—C23 | 119.6 (5) |
C29—N4—C30 | 117.7 (4) | C21—C22—H22 | 120.2 |
C29—N4—Mn1 | 126.5 (3) | C23—C22—H22 | 120.2 |
C30—N4—Mn1 | 115.7 (3) | C22—C23—C31 | 117.1 (4) |
O2—C1—O1 | 124.7 (4) | C22—C23—C24 | 123.0 (5) |
O2—C1—C2 | 118.8 (4) | C31—C23—C24 | 119.8 (4) |
O1—C1—C2 | 116.4 (4) | C25—C24—C23 | 120.2 (5) |
C7—C2—C3 | 118.9 (4) | C25—C24—H24 | 119.9 |
C7—C2—C1 | 116.4 (4) | C23—C24—H24 | 119.9 |
C3—C2—C1 | 124.7 (4) | C24—C25—C26 | 122.2 (5) |
C4—C3—C2 | 120.1 (4) | C24—C25—H25 | 118.9 |
C4—C3—S1 | 117.2 (4) | C26—C25—H25 | 118.9 |
C2—C3—S1 | 122.5 (3) | C30—C26—C27 | 117.5 (4) |
C3—C4—C5 | 120.3 (5) | C30—C26—C25 | 119.1 (4) |
C3—C4—H4 | 119.9 | C27—C26—C25 | 123.4 (4) |
C5—C4—H4 | 119.9 | C28—C27—C26 | 119.7 (4) |
C6—C5—C4 | 119.8 (5) | C28—C27—H27 | 120.2 |
C6—C5—H5 | 120.1 | C26—C27—H27 | 120.2 |
C4—C5—H5 | 120.1 | C27—C28—C29 | 119.2 (5) |
C5—C6—C7 | 120.3 (5) | C27—C28—H28 | 120.4 |
C5—C6—H6 | 119.8 | C29—C28—H28 | 120.4 |
C7—C6—H6 | 119.8 | N4—C29—C28 | 123.4 (5) |
C2—C7—C6 | 120.5 (5) | N4—C29—H29 | 118.3 |
C2—C7—H7 | 119.7 | C28—C29—H29 | 118.3 |
C6—C7—H7 | 119.7 | N4—C30—C26 | 122.5 (4) |
N1—C8—C9 | 123.6 (5) | N4—C30—C31 | 118.1 (4) |
N1—C8—H8 | 118.2 | C26—C30—C31 | 119.5 (4) |
C9—C8—H8 | 118.2 | N3—C31—C23 | 123.0 (4) |
C10—C9—C8 | 119.0 (5) | N3—C31—C30 | 117.8 (4) |
C10—C9—H9 | 120.5 | C23—C31—C30 | 119.2 (4) |
C8—C9—H9 | 120.5 | | |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O9—H9B···O5 | 0.88 (4) | 1.95 (4) | 2.832 (6) | 176 (4) |
O9—H9A···O8i | 0.91 (4) | 2.08 (3) | 2.822 (8) | 137 (4) |
O8—H8B···O3 | 0.84 (4) | 2.12 (2) | 2.955 (6) | 171 (5) |
O8—H8A···O7 | 0.85 (2) | 1.98 (2) | 2.809 (7) | 167 (5) |
O7—H7B···O2 | 0.84 (2) | 1.97 (3) | 2.757 (6) | 157 (5) |
O7—H7A···O2ii | 0.85 (2) | 2.05 (3) | 2.858 (6) | 158 (5) |
O6—H6B···O4iii | 0.84 (2) | 1.93 (2) | 2.770 (4) | 177 (5) |
O6—H6A···O4 | 0.83 (4) | 1.98 (2) | 2.798 (4) | 167 (5) |
Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, −y+1, −z; (iii) −x+2, −y+2, −z+1. |