Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804029642/dn6178sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804029642/dn6178Isup2.hkl |
CCDC reference: 258701
Data collection: EXPOSE in IPDS Software (Stoe & Cie, 2000); cell refinement: CELL in IPDS Software; data reduction: INTEGRATE in IPDS Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997) and Mercury (Bruno et al., 2002); software used to prepare material for publication: SHELXL97.
[Ru3H3O(C10H14)2(C14H16O4)]BF4 | F(000) = 1856 |
Mr = 925.74 | Dx = 1.713 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 8000 reflections |
a = 13.592 (3) Å | θ = 1.8–28.5° |
b = 17.817 (4) Å | µ = 1.31 mm−1 |
c = 15.066 (4) Å | T = 153 K |
β = 100.238 (3)° | Block, orange |
V = 3590.4 (15) Å3 | 0.24 × 0.18 × 0.14 mm |
Z = 4 |
Stoe IPDS diffractometer | 5034 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.074 |
Graphite monochromator | θmax = 28.7°, θmin = 1.8° |
φ oscillation scans | h = −18→18 |
30927 measured reflections | k = −23→24 |
8673 independent reflections | l = −17→20 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.039 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.087 | H-atom parameters constrained |
S = 0.90 | w = 1/[σ2(Fo2) + (0.0313P)2] where P = (Fo2 + 2Fc2)/3 |
8673 reflections | (Δ/σ)max = 0.001 |
461 parameters | Δρmax = 1.25 e Å−3 |
0 restraints | Δρmin = −0.65 e Å−3 |
Experimental. A crystal was mounted at 153 K on a Stoe Image Plate Diffraction System (Stoe & Cie, 2000) using Mo Kα graphite monochromated radiation. Image plate distance 70 mm, φ oscillation scans 0 - 200°, step Δφ = 1.2°, 2 minutes per frame. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
C1 | −0.0194 (3) | 0.2067 (2) | 0.2922 (3) | 0.0217 (9) | |
C2 | 0.0759 (3) | 0.2357 (2) | 0.3322 (3) | 0.0241 (10) | |
C3 | 0.1322 (3) | 0.2758 (2) | 0.2773 (3) | 0.0279 (11) | |
H3 | 0.1941 | 0.2977 | 0.3041 | 0.033* | |
C4 | 0.0985 (3) | 0.2839 (2) | 0.1843 (3) | 0.0304 (11) | |
H4 | 0.1399 | 0.3083 | 0.1485 | 0.036* | |
C5 | 0.0041 (3) | 0.2565 (2) | 0.1430 (3) | 0.0278 (10) | |
H5 | −0.0207 | 0.2655 | 0.0809 | 0.033* | |
C6 | −0.0521 (3) | 0.2158 (2) | 0.1957 (3) | 0.0257 (10) | |
H6 | −0.1133 | 0.1936 | 0.1677 | 0.031* | |
C7 | −0.0869 (3) | 0.1688 (2) | 0.3458 (3) | 0.0259 (10) | |
C8 | −0.2387 (3) | 0.1017 (3) | 0.3375 (4) | 0.0464 (14) | |
H8A | −0.2615 | 0.1406 | 0.3761 | 0.056* | |
H8B | −0.2148 | 0.0576 | 0.3753 | 0.056* | |
C9 | −0.3222 (4) | 0.0796 (3) | 0.2626 (4) | 0.0567 (16) | |
H9A | −0.2969 | 0.0450 | 0.2204 | 0.068* | |
H9B | −0.3755 | 0.0536 | 0.2876 | 0.068* | |
C10 | −0.3355 (5) | 0.1588 (4) | 0.1341 (5) | 0.0621 (17) | |
C11 | −0.3723 (5) | 0.2332 (4) | 0.0929 (5) | 0.0657 (18) | |
C12 | −0.4230 (4) | 0.2789 (4) | 0.1359 (6) | 0.086 (2) | |
H12A | −0.4449 | 0.3260 | 0.1101 | 0.104* | |
H12B | −0.4378 | 0.2649 | 0.1930 | 0.104* | |
C13 | −0.3441 (5) | 0.2490 (4) | 0.0021 (4) | 0.088 (2) | |
H13A | −0.3641 | 0.3003 | −0.0166 | 0.132* | |
H13B | −0.3784 | 0.2134 | −0.0424 | 0.132* | |
H13C | −0.2717 | 0.2437 | 0.0066 | 0.132* | |
C14 | 0.1216 (3) | 0.2219 (3) | 0.4290 (3) | 0.0385 (12) | |
H14A | 0.1939 | 0.2305 | 0.4375 | 0.058* | |
H14B | 0.1088 | 0.1700 | 0.4451 | 0.058* | |
H14C | 0.0921 | 0.2563 | 0.4677 | 0.058* | |
C15 | 0.0316 (4) | −0.0532 (2) | 0.3116 (3) | 0.0354 (12) | |
C16 | 0.1259 (3) | −0.0865 (2) | 0.3060 (3) | 0.0317 (11) | |
C17 | 0.1443 (3) | −0.1099 (2) | 0.2211 (3) | 0.0298 (11) | |
H17 | 0.2068 | −0.1326 | 0.2179 | 0.036* | |
C18 | 0.0737 (4) | −0.1010 (2) | 0.1397 (3) | 0.0335 (12) | |
C19 | −0.0199 (4) | −0.0671 (2) | 0.1456 (3) | 0.0329 (12) | |
C20 | −0.0374 (3) | −0.0439 (2) | 0.2312 (3) | 0.0342 (12) | |
H20 | −0.0995 | −0.0206 | 0.2345 | 0.041* | |
C21 | 0.0093 (4) | −0.0243 (3) | 0.3999 (3) | 0.0511 (15) | |
H21A | 0.0059 | −0.0665 | 0.4409 | 0.077* | |
H21B | −0.0549 | 0.0023 | 0.3892 | 0.077* | |
H21C | 0.0624 | 0.0103 | 0.4269 | 0.077* | |
C22 | 0.2067 (4) | −0.0921 (3) | 0.3899 (3) | 0.0506 (14) | |
H22A | 0.2185 | −0.0424 | 0.4176 | 0.076* | |
H22B | 0.2687 | −0.1108 | 0.3731 | 0.076* | |
H22C | 0.1849 | −0.1268 | 0.4331 | 0.076* | |
C23 | 0.1013 (4) | −0.1287 (3) | 0.0524 (3) | 0.0451 (14) | |
H23A | 0.1723 | −0.1190 | 0.0527 | 0.068* | |
H23B | 0.0609 | −0.1024 | 0.0014 | 0.068* | |
H23C | 0.0885 | −0.1828 | 0.0464 | 0.068* | |
C24 | −0.1006 (4) | −0.0559 (3) | 0.0648 (3) | 0.0492 (15) | |
H24A | −0.1340 | −0.1038 | 0.0478 | 0.074* | |
H24B | −0.0709 | −0.0369 | 0.0144 | 0.074* | |
H24C | −0.1494 | −0.0195 | 0.0793 | 0.074* | |
C25 | 0.3957 (3) | 0.0379 (3) | 0.1504 (4) | 0.0411 (13) | |
C26 | 0.3858 (3) | 0.1127 (3) | 0.1187 (3) | 0.0383 (13) | |
C27 | 0.3859 (3) | 0.1711 (3) | 0.1816 (4) | 0.0386 (13) | |
H27 | 0.3749 | 0.2209 | 0.1595 | 0.046* | |
C28 | 0.4013 (3) | 0.1598 (3) | 0.2749 (4) | 0.0396 (12) | |
C29 | 0.4117 (3) | 0.0841 (3) | 0.3079 (3) | 0.0414 (13) | |
C30 | 0.4100 (3) | 0.0256 (3) | 0.2449 (4) | 0.0420 (13) | |
H30 | 0.4189 | −0.0244 | 0.2666 | 0.050* | |
C31 | 0.3937 (4) | −0.0283 (3) | 0.0893 (4) | 0.0707 (19) | |
H31A | 0.4570 | −0.0312 | 0.0669 | 0.106* | |
H31B | 0.3383 | −0.0228 | 0.0383 | 0.106* | |
H31C | 0.3844 | −0.0742 | 0.1226 | 0.106* | |
C32 | 0.3740 (4) | 0.1303 (4) | 0.0181 (4) | 0.0629 (18) | |
H32A | 0.3392 | 0.1784 | 0.0055 | 0.094* | |
H32B | 0.3350 | 0.0905 | −0.0167 | 0.094* | |
H32C | 0.4401 | 0.1334 | 0.0009 | 0.094* | |
C33 | 0.4024 (4) | 0.2255 (3) | 0.3379 (4) | 0.073 (2) | |
H33A | 0.4708 | 0.2341 | 0.3698 | 0.109* | |
H33B | 0.3589 | 0.2147 | 0.3817 | 0.109* | |
H33C | 0.3782 | 0.2703 | 0.3031 | 0.109* | |
C34 | 0.4214 (4) | 0.0666 (4) | 0.4062 (4) | 0.073 (2) | |
H34A | 0.4200 | 0.0121 | 0.4146 | 0.110* | |
H34B | 0.3658 | 0.0896 | 0.4298 | 0.110* | |
H34C | 0.4848 | 0.0867 | 0.4387 | 0.110* | |
O1 | 0.1768 (2) | 0.08599 (15) | 0.29130 (18) | 0.0240 (6) | |
O2 | −0.0801 (2) | 0.17322 (17) | 0.4268 (2) | 0.0391 (8) | |
O3 | −0.1599 (2) | 0.13069 (18) | 0.2938 (2) | 0.0358 (8) | |
O4 | −0.3618 (3) | 0.1470 (2) | 0.2153 (3) | 0.0657 (12) | |
O5 | −0.2846 (4) | 0.1165 (3) | 0.0979 (3) | 0.0785 (14) | |
B1 | 0.3278 (7) | 0.3981 (4) | 0.1331 (6) | 0.064 (2) | |
F1 | 0.3210 (3) | 0.33353 (18) | 0.0871 (3) | 0.0873 (12) | |
F2 | 0.4060 (9) | 0.4343 (7) | 0.1262 (11) | 0.079 (4) | 0.50 |
F3 | 0.3070 (16) | 0.3863 (10) | 0.2096 (10) | 0.117 (7) | 0.50 |
F4 | 0.2422 (9) | 0.4355 (6) | 0.0743 (8) | 0.113 (3) | 0.50 |
F5 | 0.4189 (13) | 0.3887 (9) | 0.2050 (14) | 0.192 (7) | 0.50 |
F6 | 0.3535 (16) | 0.4625 (7) | 0.0985 (11) | 0.124 (7) | 0.50 |
F7 | 0.2621 (14) | 0.4148 (8) | 0.1907 (16) | 0.120 (9) | 0.50 |
Ru1 | 0.09577 (2) | 0.163478 (18) | 0.21765 (2) | 0.01932 (9) | |
Ru2 | 0.10283 (3) | 0.008410 (18) | 0.21060 (2) | 0.02150 (9) | |
Ru3 | 0.27210 (2) | 0.091911 (19) | 0.20609 (2) | 0.02269 (9) | |
H1H | 0.0413 | 0.0880 | 0.1627 | 0.050* | |
H2H | 0.1824 | 0.1495 | 0.1644 | 0.050* | |
H3H | 0.1969 | 0.0285 | 0.1625 | 0.050* |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.025 (2) | 0.019 (2) | 0.022 (2) | 0.0052 (18) | 0.0077 (19) | −0.0021 (18) |
C2 | 0.024 (2) | 0.019 (2) | 0.030 (3) | 0.0027 (18) | 0.008 (2) | −0.0031 (19) |
C3 | 0.025 (2) | 0.017 (2) | 0.045 (3) | −0.0056 (19) | 0.015 (2) | −0.010 (2) |
C4 | 0.034 (3) | 0.021 (3) | 0.041 (3) | 0.006 (2) | 0.022 (2) | 0.008 (2) |
C5 | 0.039 (3) | 0.019 (2) | 0.028 (3) | 0.007 (2) | 0.013 (2) | 0.004 (2) |
C6 | 0.026 (2) | 0.020 (2) | 0.030 (3) | 0.0059 (19) | 0.004 (2) | 0.0019 (19) |
C7 | 0.023 (2) | 0.017 (2) | 0.039 (3) | 0.0014 (18) | 0.011 (2) | −0.002 (2) |
C8 | 0.029 (3) | 0.058 (4) | 0.056 (4) | −0.015 (3) | 0.018 (3) | 0.005 (3) |
C9 | 0.036 (3) | 0.053 (4) | 0.081 (4) | −0.007 (3) | 0.010 (3) | 0.020 (3) |
C10 | 0.043 (4) | 0.070 (5) | 0.068 (5) | −0.011 (3) | −0.004 (3) | 0.000 (4) |
C11 | 0.046 (4) | 0.069 (5) | 0.078 (5) | −0.021 (3) | 0.000 (3) | 0.010 (4) |
C12 | 0.043 (4) | 0.058 (5) | 0.162 (8) | −0.014 (3) | 0.029 (5) | 0.017 (5) |
C13 | 0.098 (6) | 0.084 (5) | 0.072 (5) | −0.020 (4) | −0.016 (4) | 0.007 (4) |
C14 | 0.037 (3) | 0.049 (3) | 0.029 (3) | −0.001 (2) | 0.003 (2) | −0.008 (2) |
C15 | 0.048 (3) | 0.020 (3) | 0.041 (3) | −0.003 (2) | 0.016 (3) | 0.007 (2) |
C16 | 0.045 (3) | 0.019 (2) | 0.033 (3) | 0.005 (2) | 0.011 (2) | 0.008 (2) |
C17 | 0.035 (3) | 0.016 (2) | 0.039 (3) | 0.0018 (19) | 0.008 (2) | 0.005 (2) |
C18 | 0.047 (3) | 0.017 (3) | 0.036 (3) | −0.007 (2) | 0.007 (2) | 0.000 (2) |
C19 | 0.037 (3) | 0.020 (2) | 0.040 (3) | −0.010 (2) | −0.001 (2) | 0.007 (2) |
C20 | 0.034 (3) | 0.026 (3) | 0.048 (3) | −0.006 (2) | 0.023 (3) | 0.003 (2) |
C21 | 0.078 (4) | 0.044 (3) | 0.040 (3) | 0.003 (3) | 0.035 (3) | 0.003 (3) |
C22 | 0.067 (4) | 0.039 (3) | 0.042 (3) | 0.008 (3) | 0.000 (3) | 0.012 (3) |
C23 | 0.074 (4) | 0.025 (3) | 0.037 (3) | −0.007 (3) | 0.012 (3) | −0.009 (2) |
C24 | 0.052 (3) | 0.042 (3) | 0.046 (3) | −0.021 (3) | −0.009 (3) | 0.007 (3) |
C25 | 0.021 (3) | 0.047 (3) | 0.059 (4) | 0.002 (2) | 0.017 (2) | −0.014 (3) |
C26 | 0.020 (2) | 0.053 (4) | 0.043 (3) | −0.001 (2) | 0.009 (2) | 0.001 (3) |
C27 | 0.023 (3) | 0.033 (3) | 0.062 (4) | −0.003 (2) | 0.014 (2) | 0.002 (3) |
C28 | 0.022 (2) | 0.046 (3) | 0.051 (3) | −0.002 (2) | 0.007 (2) | −0.008 (3) |
C29 | 0.017 (2) | 0.062 (4) | 0.043 (3) | 0.000 (2) | 0.002 (2) | 0.006 (3) |
C30 | 0.026 (3) | 0.035 (3) | 0.065 (4) | 0.008 (2) | 0.006 (3) | 0.008 (3) |
C31 | 0.053 (4) | 0.068 (4) | 0.096 (5) | 0.010 (3) | 0.028 (4) | −0.041 (4) |
C32 | 0.043 (3) | 0.104 (5) | 0.047 (4) | −0.012 (3) | 0.025 (3) | 0.011 (3) |
C33 | 0.039 (3) | 0.070 (4) | 0.102 (5) | −0.010 (3) | −0.006 (3) | −0.050 (4) |
C34 | 0.047 (4) | 0.128 (6) | 0.040 (4) | −0.004 (4) | −0.003 (3) | 0.019 (4) |
O1 | 0.0254 (15) | 0.0225 (16) | 0.0240 (16) | 0.0001 (13) | 0.0047 (12) | 0.0004 (13) |
O2 | 0.053 (2) | 0.043 (2) | 0.0250 (19) | −0.0073 (17) | 0.0161 (16) | −0.0041 (16) |
O3 | 0.0286 (18) | 0.049 (2) | 0.0319 (19) | −0.0136 (16) | 0.0109 (15) | 0.0001 (16) |
O4 | 0.032 (2) | 0.072 (3) | 0.095 (3) | 0.000 (2) | 0.016 (2) | 0.014 (3) |
O5 | 0.087 (4) | 0.082 (3) | 0.065 (3) | 0.000 (3) | 0.009 (3) | −0.006 (3) |
B1 | 0.079 (6) | 0.033 (4) | 0.086 (7) | −0.010 (4) | 0.033 (5) | −0.001 (4) |
F1 | 0.105 (3) | 0.041 (2) | 0.107 (3) | −0.008 (2) | −0.008 (2) | −0.003 (2) |
F2 | 0.062 (6) | 0.075 (10) | 0.107 (10) | −0.047 (6) | 0.038 (6) | −0.037 (8) |
F3 | 0.17 (2) | 0.124 (15) | 0.074 (7) | −0.069 (12) | 0.065 (10) | −0.001 (8) |
F4 | 0.105 (8) | 0.080 (7) | 0.146 (10) | 0.046 (6) | −0.001 (7) | −0.030 (6) |
F5 | 0.171 (15) | 0.151 (13) | 0.220 (17) | −0.004 (11) | −0.058 (14) | −0.078 (12) |
F6 | 0.25 (2) | 0.045 (7) | 0.111 (12) | −0.019 (9) | 0.113 (14) | −0.010 (6) |
F7 | 0.106 (11) | 0.055 (8) | 0.23 (2) | −0.035 (7) | 0.110 (13) | −0.048 (10) |
Ru1 | 0.02064 (18) | 0.01539 (18) | 0.02291 (19) | −0.00023 (14) | 0.00654 (14) | −0.00079 (15) |
Ru2 | 0.02349 (19) | 0.01512 (18) | 0.0268 (2) | −0.00006 (15) | 0.00690 (15) | 0.00208 (15) |
Ru3 | 0.01922 (18) | 0.02137 (19) | 0.0284 (2) | 0.00042 (16) | 0.00686 (14) | −0.00103 (16) |
C1—C2 | 1.425 (5) | C21—H21A | 0.9800 |
C1—C6 | 1.451 (5) | C21—H21B | 0.9800 |
C1—C7 | 1.487 (6) | C21—H21C | 0.9800 |
C1—Ru1 | 2.220 (4) | C22—H22A | 0.9800 |
C2—C3 | 1.417 (6) | C22—H22B | 0.9800 |
C2—C14 | 1.501 (6) | C22—H22C | 0.9800 |
C2—Ru1 | 2.207 (4) | C23—H23A | 0.9800 |
C3—C4 | 1.403 (6) | C23—H23B | 0.9800 |
C3—Ru1 | 2.214 (4) | C23—H23C | 0.9800 |
C3—H3 | 0.9500 | C24—H24A | 0.9800 |
C4—C5 | 1.410 (6) | C24—H24B | 0.9800 |
C4—Ru1 | 2.206 (4) | C24—H24C | 0.9800 |
C4—H4 | 0.9500 | C25—C26 | 1.414 (7) |
C5—C6 | 1.398 (6) | C25—C30 | 1.418 (7) |
C5—Ru1 | 2.251 (4) | C25—C31 | 1.493 (7) |
C5—H5 | 0.9500 | C25—Ru3 | 2.225 (4) |
C6—Ru1 | 2.187 (4) | C26—C27 | 1.409 (6) |
C6—H6 | 0.9500 | C26—C32 | 1.528 (7) |
C7—O2 | 1.210 (5) | C26—Ru3 | 2.233 (5) |
C7—O3 | 1.335 (5) | C27—C28 | 1.399 (7) |
C8—O3 | 1.448 (5) | C27—Ru3 | 2.173 (4) |
C8—C9 | 1.504 (7) | C27—H27 | 0.9500 |
C8—H8A | 0.9900 | C28—C29 | 1.435 (7) |
C8—H8B | 0.9900 | C28—C33 | 1.504 (7) |
C9—O4 | 1.450 (6) | C28—Ru3 | 2.231 (5) |
C9—H9A | 0.9900 | C29—C30 | 1.407 (7) |
C9—H9B | 0.9900 | C29—C34 | 1.497 (7) |
C10—O5 | 1.215 (7) | C29—Ru3 | 2.221 (4) |
C10—O4 | 1.350 (7) | C30—Ru3 | 2.205 (5) |
C10—C11 | 1.512 (9) | C30—H30 | 0.9500 |
C11—C12 | 1.309 (8) | C31—H31A | 0.9800 |
C11—C13 | 1.510 (8) | C31—H31B | 0.9800 |
C12—H12A | 0.9500 | C31—H31C | 0.9800 |
C12—H12B | 0.9500 | C32—H32A | 0.9800 |
C13—H13A | 0.9800 | C32—H32B | 0.9800 |
C13—H13B | 0.9800 | C32—H32C | 0.9800 |
C13—H13C | 0.9800 | C33—H33A | 0.9800 |
C14—H14A | 0.9800 | C33—H33B | 0.9800 |
C14—H14B | 0.9800 | C33—H33C | 0.9800 |
C14—H14C | 0.9800 | C34—H34A | 0.9800 |
C15—C20 | 1.404 (6) | C34—H34B | 0.9800 |
C15—C16 | 1.428 (6) | C34—H34C | 0.9800 |
C15—C21 | 1.506 (6) | O1—Ru1 | 1.979 (3) |
C15—Ru2 | 2.232 (5) | O1—Ru3 | 1.982 (3) |
C16—C17 | 1.409 (6) | O1—Ru2 | 1.991 (3) |
C16—C22 | 1.524 (6) | B1—F3 | 1.253 (15) |
C16—Ru2 | 2.205 (4) | B1—F2 | 1.264 (13) |
C17—C18 | 1.425 (6) | B1—F1 | 1.338 (8) |
C17—Ru2 | 2.180 (4) | B1—F4 | 1.489 (12) |
C17—H17 | 0.9500 | Ru1—Ru3 | 2.7476 (7) |
C18—C19 | 1.424 (6) | Ru1—Ru2 | 2.7672 (8) |
C18—C23 | 1.515 (6) | Ru1—H1H | 1.6805 |
C18—Ru2 | 2.223 (4) | Ru1—H2H | 1.5583 |
C19—C20 | 1.414 (6) | Ru2—Ru3 | 2.7508 (7) |
C19—C24 | 1.500 (6) | Ru2—H1H | 1.7368 |
C19—Ru2 | 2.230 (4) | Ru2—H3H | 1.6176 |
C20—Ru2 | 2.193 (4) | Ru3—H2H | 1.6315 |
C20—H20 | 0.9500 | Ru3—H3H | 1.5868 |
C2—C1—C6 | 118.5 (4) | H33A—C33—H33C | 109.5 |
C2—C1—C7 | 122.4 (4) | H33B—C33—H33C | 109.5 |
C6—C1—C7 | 119.1 (4) | C29—C34—H34A | 109.5 |
C2—C1—Ru1 | 70.7 (2) | C29—C34—H34B | 109.5 |
C6—C1—Ru1 | 69.5 (2) | H34A—C34—H34B | 109.5 |
C7—C1—Ru1 | 132.5 (3) | C29—C34—H34C | 109.5 |
C3—C2—C1 | 118.7 (4) | H34A—C34—H34C | 109.5 |
C3—C2—C14 | 118.4 (4) | H34B—C34—H34C | 109.5 |
C1—C2—C14 | 122.7 (4) | Ru1—O1—Ru3 | 87.85 (11) |
C3—C2—Ru1 | 71.6 (2) | Ru1—O1—Ru2 | 88.36 (11) |
C1—C2—Ru1 | 71.7 (2) | Ru3—O1—Ru2 | 87.63 (11) |
C14—C2—Ru1 | 125.3 (3) | C7—O3—C8 | 116.6 (3) |
C4—C3—C2 | 121.4 (4) | C10—O4—C9 | 116.0 (5) |
C4—C3—Ru1 | 71.2 (2) | F3—B1—F2 | 119.5 (13) |
C2—C3—Ru1 | 71.1 (2) | F3—B1—F1 | 109.0 (10) |
C4—C3—H3 | 119.3 | F2—B1—F1 | 112.2 (9) |
C2—C3—H3 | 119.3 | F3—B1—F4 | 110.1 (12) |
Ru1—C3—H3 | 131.4 | F2—B1—F4 | 107.6 (10) |
C3—C4—C5 | 121.0 (4) | F1—B1—F4 | 95.9 (7) |
C3—C4—Ru1 | 71.8 (2) | O1—Ru1—C6 | 141.94 (14) |
C5—C4—Ru1 | 73.3 (2) | O1—Ru1—C4 | 140.92 (14) |
C3—C4—H4 | 119.5 | C6—Ru1—C4 | 66.59 (16) |
C5—C4—H4 | 119.5 | O1—Ru1—C2 | 95.81 (13) |
Ru1—C4—H4 | 127.5 | C6—Ru1—C2 | 68.45 (15) |
C6—C5—C4 | 118.4 (4) | C4—Ru1—C2 | 67.72 (16) |
C6—C5—Ru1 | 69.2 (2) | O1—Ru1—C3 | 109.93 (14) |
C4—C5—Ru1 | 69.8 (2) | C6—Ru1—C3 | 78.98 (16) |
C6—C5—H5 | 120.8 | C4—Ru1—C3 | 37.02 (16) |
C4—C5—H5 | 120.8 | C2—Ru1—C3 | 37.37 (15) |
Ru1—C5—H5 | 133.1 | O1—Ru1—C1 | 109.32 (13) |
C5—C6—C1 | 121.7 (4) | C6—Ru1—C1 | 38.44 (14) |
C5—C6—Ru1 | 74.1 (3) | C4—Ru1—C1 | 79.61 (15) |
C1—C6—Ru1 | 72.0 (2) | C2—Ru1—C1 | 37.54 (14) |
C5—C6—H6 | 119.1 | C3—Ru1—C1 | 66.91 (15) |
C1—C6—H6 | 119.1 | O1—Ru1—C5 | 175.88 (13) |
Ru1—C6—H6 | 126.7 | C6—Ru1—C5 | 36.70 (14) |
O2—C7—O3 | 122.7 (4) | C4—Ru1—C5 | 36.85 (15) |
O2—C7—C1 | 125.0 (4) | C2—Ru1—C5 | 80.09 (15) |
O3—C7—C1 | 112.3 (4) | C3—Ru1—C5 | 66.50 (16) |
O3—C8—C9 | 105.9 (4) | C1—Ru1—C5 | 67.66 (15) |
O3—C8—H8A | 110.6 | O1—Ru1—Ru3 | 46.12 (8) |
C9—C8—H8A | 110.6 | C6—Ru1—Ru3 | 167.69 (11) |
O3—C8—H8B | 110.6 | C4—Ru1—Ru3 | 112.76 (11) |
C9—C8—H8B | 110.6 | C2—Ru1—Ru3 | 123.32 (11) |
H8A—C8—H8B | 108.7 | C3—Ru1—Ru3 | 108.09 (11) |
O4—C9—C8 | 108.5 (5) | C1—Ru1—Ru3 | 153.44 (11) |
O4—C9—H9A | 110.0 | C5—Ru1—Ru3 | 136.19 (11) |
C8—C9—H9A | 110.0 | O1—Ru1—Ru2 | 46.00 (8) |
O4—C9—H9B | 110.0 | C6—Ru1—Ru2 | 117.22 (11) |
C8—C9—H9B | 110.0 | C4—Ru1—Ru2 | 163.83 (12) |
H9A—C9—H9B | 108.4 | C2—Ru1—Ru2 | 128.43 (11) |
O5—C10—O4 | 125.0 (6) | C3—Ru1—Ru2 | 155.70 (12) |
O5—C10—C11 | 122.2 (7) | C1—Ru1—Ru2 | 113.47 (10) |
O4—C10—C11 | 112.7 (6) | C5—Ru1—Ru2 | 137.39 (11) |
C12—C11—C13 | 125.0 (7) | Ru3—Ru1—Ru2 | 59.842 (14) |
C12—C11—C10 | 120.4 (7) | O1—Ru1—H1H | 82.6 |
C13—C11—C10 | 114.6 (7) | C6—Ru1—H1H | 87.4 |
C11—C12—H12A | 120.0 | C4—Ru1—H1H | 133.6 |
C11—C12—H12B | 120.0 | C2—Ru1—H1H | 138.3 |
H12A—C12—H12B | 120.0 | C3—Ru1—H1H | 166.1 |
C11—C13—H13A | 109.5 | C1—Ru1—H1H | 103.8 |
C11—C13—H13B | 109.5 | C5—Ru1—H1H | 100.8 |
H13A—C13—H13B | 109.5 | Ru3—Ru1—H1H | 84.9 |
C11—C13—H13C | 109.5 | Ru2—Ru1—H1H | 36.6 |
H13A—C13—H13C | 109.5 | O1—Ru1—H2H | 77.3 |
H13B—C13—H13C | 109.5 | C6—Ru1—H2H | 138.5 |
C2—C14—H14A | 109.5 | C4—Ru1—H2H | 89.6 |
C2—C14—H14B | 109.5 | C2—Ru1—H2H | 134.8 |
H14A—C14—H14B | 109.5 | C3—Ru1—H2H | 102.6 |
C2—C14—H14C | 109.5 | C1—Ru1—H2H | 168.8 |
H14A—C14—H14C | 109.5 | C5—Ru1—H2H | 105.2 |
H14B—C14—H14C | 109.5 | Ru3—Ru1—H2H | 31.3 |
C20—C15—C16 | 117.8 (4) | Ru2—Ru1—H2H | 77.7 |
C20—C15—C21 | 120.9 (5) | H1H—Ru1—H2H | 85.7 |
C16—C15—C21 | 121.2 (4) | O1—Ru2—C17 | 122.06 (14) |
C20—C15—Ru2 | 70.0 (3) | O1—Ru2—C20 | 124.48 (15) |
C16—C15—Ru2 | 70.2 (3) | C17—Ru2—C20 | 78.39 (17) |
C21—C15—Ru2 | 127.8 (3) | O1—Ru2—C16 | 97.85 (14) |
C17—C16—C15 | 118.9 (4) | C17—Ru2—C16 | 37.48 (15) |
C17—C16—C22 | 121.1 (4) | C20—Ru2—C16 | 66.94 (17) |
C15—C16—C22 | 120.0 (4) | O1—Ru2—C18 | 158.29 (15) |
C17—C16—Ru2 | 70.3 (2) | C17—Ru2—C18 | 37.74 (16) |
C15—C16—Ru2 | 72.3 (2) | C20—Ru2—C18 | 67.05 (17) |
C22—C16—Ru2 | 126.1 (3) | C16—Ru2—C18 | 68.49 (17) |
C16—C17—C18 | 123.1 (4) | O1—Ru2—C19 | 160.78 (15) |
C16—C17—Ru2 | 72.2 (2) | C17—Ru2—C19 | 67.16 (16) |
C18—C17—Ru2 | 72.8 (2) | C20—Ru2—C19 | 37.27 (16) |
C16—C17—H17 | 118.4 | C16—Ru2—C19 | 80.32 (17) |
C18—C17—H17 | 118.4 | C18—Ru2—C19 | 37.31 (17) |
Ru2—C17—H17 | 129.1 | O1—Ru2—C15 | 99.09 (15) |
C19—C18—C17 | 117.8 (4) | C17—Ru2—C15 | 67.24 (17) |
C19—C18—C23 | 123.7 (4) | C20—Ru2—C15 | 37.00 (16) |
C17—C18—C23 | 118.5 (4) | C16—Ru2—C15 | 37.55 (16) |
C19—C18—Ru2 | 71.6 (3) | C18—Ru2—C15 | 80.48 (17) |
C17—C18—Ru2 | 69.5 (2) | C19—Ru2—C15 | 67.75 (18) |
C23—C18—Ru2 | 130.8 (3) | O1—Ru2—Ru3 | 46.04 (8) |
C20—C19—C18 | 118.5 (4) | C17—Ru2—Ru3 | 108.54 (12) |
C20—C19—C24 | 119.0 (5) | C20—Ru2—Ru3 | 170.15 (12) |
C18—C19—C24 | 122.5 (5) | C16—Ru2—Ru3 | 114.08 (12) |
C20—C19—Ru2 | 69.9 (3) | C18—Ru2—Ru3 | 122.73 (13) |
C18—C19—Ru2 | 71.1 (3) | C19—Ru2—Ru3 | 151.57 (13) |
C24—C19—Ru2 | 131.1 (3) | C15—Ru2—Ru3 | 138.47 (13) |
C15—C20—C19 | 123.9 (4) | O1—Ru2—Ru1 | 45.64 (8) |
C15—C20—Ru2 | 73.0 (3) | C17—Ru2—Ru1 | 166.59 (12) |
C19—C20—Ru2 | 72.8 (3) | C20—Ru2—Ru1 | 112.46 (12) |
C15—C20—H20 | 118.0 | C16—Ru2—Ru1 | 137.95 (12) |
C19—C20—H20 | 118.0 | C18—Ru2—Ru1 | 152.75 (12) |
Ru2—C20—H20 | 128.7 | C19—Ru2—Ru1 | 126.24 (12) |
C15—C21—H21A | 109.5 | C15—Ru2—Ru1 | 116.27 (12) |
C15—C21—H21B | 109.5 | Ru3—Ru2—Ru1 | 59.725 (15) |
H21A—C21—H21B | 109.5 | O1—Ru2—H1H | 80.8 |
C15—C21—H21C | 109.5 | C17—Ru2—H1H | 156.7 |
H21A—C21—H21C | 109.5 | C20—Ru2—H1H | 92.3 |
H21B—C21—H21C | 109.5 | C16—Ru2—H1H | 154.0 |
C16—C22—H22A | 109.5 | C18—Ru2—H1H | 119.0 |
C16—C22—H22B | 109.5 | C19—Ru2—H1H | 92.5 |
H22A—C22—H22B | 109.5 | C15—Ru2—H1H | 116.7 |
C16—C22—H22C | 109.5 | Ru3—Ru2—H1H | 83.8 |
H22A—C22—H22C | 109.5 | Ru1—Ru2—H1H | 35.2 |
H22B—C22—H22C | 109.5 | O1—Ru2—H3H | 76.5 |
C18—C23—H23A | 109.5 | C17—Ru2—H3H | 91.8 |
C18—C23—H23B | 109.5 | C20—Ru2—H3H | 158.9 |
H23A—C23—H23B | 109.5 | C16—Ru2—H3H | 115.4 |
C18—C23—H23C | 109.5 | C18—Ru2—H3H | 93.8 |
H23A—C23—H23C | 109.5 | C19—Ru2—H3H | 121.7 |
H23B—C23—H23C | 109.5 | C15—Ru2—H3H | 152.5 |
C19—C24—H24A | 109.5 | Ru3—Ru2—H3H | 30.5 |
C19—C24—H24B | 109.5 | Ru1—Ru2—H3H | 80.4 |
H24A—C24—H24B | 109.5 | H1H—Ru2—H3H | 89.6 |
C19—C24—H24C | 109.5 | O1—Ru3—C27 | 135.33 (16) |
H24A—C24—H24C | 109.5 | O1—Ru3—C30 | 114.99 (16) |
H24B—C24—H24C | 109.5 | C27—Ru3—C30 | 78.21 (18) |
C26—C25—C30 | 118.2 (5) | O1—Ru3—C29 | 97.22 (15) |
C26—C25—C31 | 123.0 (5) | C27—Ru3—C29 | 67.15 (19) |
C30—C25—C31 | 118.8 (5) | C30—Ru3—C29 | 37.06 (18) |
C26—C25—Ru3 | 71.8 (3) | O1—Ru3—C25 | 147.68 (17) |
C30—C25—Ru3 | 70.5 (3) | C27—Ru3—C25 | 67.00 (19) |
C31—C25—Ru3 | 129.9 (3) | C30—Ru3—C25 | 37.34 (18) |
C27—C26—C25 | 118.7 (5) | C29—Ru3—C25 | 67.90 (19) |
C27—C26—C32 | 120.2 (5) | O1—Ru3—C28 | 106.19 (15) |
C25—C26—C32 | 121.1 (5) | C27—Ru3—C28 | 37.00 (17) |
C27—C26—Ru3 | 69.1 (3) | C30—Ru3—C28 | 66.74 (18) |
C25—C26—Ru3 | 71.2 (3) | C29—Ru3—C28 | 37.61 (18) |
C32—C26—Ru3 | 131.1 (3) | C25—Ru3—C28 | 79.91 (18) |
C28—C27—C26 | 123.5 (5) | O1—Ru3—C26 | 172.58 (16) |
C28—C27—Ru3 | 73.7 (3) | C27—Ru3—C26 | 37.25 (17) |
C26—C27—Ru3 | 73.7 (3) | C30—Ru3—C26 | 66.42 (19) |
C28—C27—H27 | 118.2 | C29—Ru3—C26 | 79.74 (18) |
C26—C27—H27 | 118.2 | C25—Ru3—C26 | 36.99 (18) |
Ru3—C27—H27 | 126.4 | C28—Ru3—C26 | 67.29 (18) |
C27—C28—C29 | 118.1 (5) | O1—Ru3—Ru1 | 46.04 (8) |
C27—C28—C33 | 120.3 (5) | C27—Ru3—Ru1 | 111.37 (13) |
C29—C28—C33 | 121.6 (5) | C30—Ru3—Ru1 | 160.38 (15) |
C27—C28—Ru3 | 69.3 (3) | C29—Ru3—Ru1 | 129.25 (14) |
C29—C28—Ru3 | 70.8 (3) | C25—Ru3—Ru1 | 161.81 (14) |
C33—C28—Ru3 | 129.3 (3) | C28—Ru3—Ru1 | 110.03 (13) |
C30—C29—C28 | 118.3 (5) | C26—Ru3—Ru1 | 131.58 (13) |
C30—C29—C34 | 120.1 (5) | O1—Ru3—Ru2 | 46.33 (8) |
C28—C29—C34 | 121.6 (5) | C27—Ru3—Ru2 | 168.25 (13) |
C30—C29—Ru3 | 70.8 (3) | C30—Ru3—Ru2 | 112.29 (13) |
C28—C29—Ru3 | 71.5 (3) | C29—Ru3—Ru2 | 124.36 (13) |
C34—C29—Ru3 | 127.7 (3) | C25—Ru3—Ru2 | 117.79 (13) |
C29—C30—C25 | 123.1 (5) | C28—Ru3—Ru2 | 151.00 (14) |
C29—C30—Ru3 | 72.1 (3) | C26—Ru3—Ru2 | 140.72 (13) |
C25—C30—Ru3 | 72.1 (3) | Ru1—Ru3—Ru2 | 60.43 (2) |
C29—C30—H30 | 118.5 | O1—Ru3—H2H | 75.7 |
C25—C30—H30 | 118.5 | C27—Ru3—H2H | 91.8 |
Ru3—C30—H30 | 130.1 | C30—Ru3—H2H | 168.8 |
C25—C31—H31A | 109.5 | C29—Ru3—H2H | 142.5 |
C25—C31—H31B | 109.5 | C25—Ru3—H2H | 133.6 |
H31A—C31—H31B | 109.5 | C28—Ru3—H2H | 108.1 |
C25—C31—H31C | 109.5 | C26—Ru3—H2H | 102.5 |
H31A—C31—H31C | 109.5 | Ru1—Ru3—H2H | 29.8 |
H31B—C31—H31C | 109.5 | Ru2—Ru3—H2H | 77.2 |
C26—C32—H32A | 109.5 | O1—Ru3—H3H | 77.5 |
C26—C32—H32B | 109.5 | C27—Ru3—H3H | 144.9 |
H32A—C32—H32B | 109.5 | C30—Ru3—H3H | 100.6 |
C26—C32—H32C | 109.5 | C29—Ru3—H3H | 130.5 |
H32A—C32—H32C | 109.5 | C25—Ru3—H3H | 90.6 |
H32B—C32—H32C | 109.5 | C28—Ru3—H3H | 167.2 |
C28—C33—H33A | 109.5 | C26—Ru3—H3H | 109.7 |
C28—C33—H33B | 109.5 | Ru1—Ru3—H3H | 81.5 |
H33A—C33—H33B | 109.5 | Ru2—Ru3—H3H | 31.2 |
C28—C33—H33C | 109.5 | H2H—Ru3—H3H | 84.6 |
C6—C1—C2—C3 | 3.6 (6) | C20—C19—Ru2—Ru1 | −79.6 (3) |
C7—C1—C2—C3 | −175.4 (4) | C18—C19—Ru2—Ru1 | 149.0 (2) |
Ru1—C1—C2—C3 | 55.9 (3) | C24—C19—Ru2—Ru1 | 31.9 (5) |
C6—C1—C2—C14 | −173.1 (4) | C20—C15—Ru2—O1 | 137.8 (3) |
C7—C1—C2—C14 | 8.0 (6) | C16—C15—Ru2—O1 | −91.1 (3) |
Ru1—C1—C2—C14 | −120.8 (4) | C21—C15—Ru2—O1 | 23.6 (5) |
C6—C1—C2—Ru1 | −52.3 (3) | C20—C15—Ru2—C17 | −101.2 (3) |
C7—C1—C2—Ru1 | 128.7 (4) | C16—C15—Ru2—C17 | 30.0 (3) |
C1—C2—C3—C4 | −3.5 (6) | C21—C15—Ru2—C17 | 144.7 (5) |
C14—C2—C3—C4 | 173.3 (4) | C16—C15—Ru2—C20 | 131.2 (4) |
Ru1—C2—C3—C4 | 52.5 (4) | C21—C15—Ru2—C20 | −114.1 (6) |
C1—C2—C3—Ru1 | −56.0 (3) | C20—C15—Ru2—C16 | −131.2 (4) |
C14—C2—C3—Ru1 | 120.8 (4) | C21—C15—Ru2—C16 | 114.7 (6) |
C2—C3—C4—C5 | 4.2 (6) | C20—C15—Ru2—C18 | −64.2 (3) |
Ru1—C3—C4—C5 | 56.6 (4) | C16—C15—Ru2—C18 | 66.9 (3) |
C2—C3—C4—Ru1 | −52.4 (4) | C21—C15—Ru2—C18 | −178.4 (5) |
C3—C4—C5—C6 | −4.9 (6) | C20—C15—Ru2—C19 | −27.6 (3) |
Ru1—C4—C5—C6 | 51.0 (4) | C16—C15—Ru2—C19 | 103.5 (3) |
C3—C4—C5—Ru1 | −55.9 (4) | C21—C15—Ru2—C19 | −141.7 (5) |
C4—C5—C6—C1 | 5.1 (6) | C20—C15—Ru2—Ru3 | 166.1 (2) |
Ru1—C5—C6—C1 | 56.4 (3) | C16—C15—Ru2—Ru3 | −62.7 (3) |
C4—C5—C6—Ru1 | −51.3 (4) | C21—C15—Ru2—Ru3 | 52.0 (5) |
C2—C1—C6—C5 | −4.5 (6) | C20—C15—Ru2—Ru1 | 93.0 (3) |
C7—C1—C6—C5 | 174.5 (4) | C16—C15—Ru2—Ru1 | −135.8 (2) |
Ru1—C1—C6—C5 | −57.4 (4) | C21—C15—Ru2—Ru1 | −21.1 (5) |
C2—C1—C6—Ru1 | 52.9 (3) | C6—Ru1—Ru2—O1 | −137.24 (17) |
C7—C1—C6—Ru1 | −128.1 (3) | C4—Ru1—Ru2—O1 | 123.0 (4) |
C2—C1—C7—O2 | 17.5 (7) | C2—Ru1—Ru2—O1 | −54.09 (18) |
C6—C1—C7—O2 | −161.5 (4) | C3—Ru1—Ru2—O1 | −9.1 (3) |
Ru1—C1—C7—O2 | 110.4 (5) | C1—Ru1—Ru2—O1 | −94.71 (16) |
C2—C1—C7—O3 | −165.0 (4) | C5—Ru1—Ru2—O1 | −176.65 (19) |
C6—C1—C7—O3 | 16.1 (5) | Ru3—Ru1—Ru2—O1 | 56.40 (11) |
Ru1—C1—C7—O3 | −72.0 (5) | O1—Ru1—Ru2—C17 | −25.7 (5) |
O3—C8—C9—O4 | −66.4 (5) | C6—Ru1—Ru2—C17 | −163.0 (5) |
O5—C10—C11—C12 | −176.8 (6) | C4—Ru1—Ru2—C17 | 97.3 (7) |
O4—C10—C11—C12 | 0.7 (8) | C2—Ru1—Ru2—C17 | −79.8 (5) |
O5—C10—C11—C13 | 2.2 (8) | C3—Ru1—Ru2—C17 | −34.9 (6) |
O4—C10—C11—C13 | 179.7 (5) | C1—Ru1—Ru2—C17 | −120.5 (5) |
C20—C15—C16—C17 | −1.4 (6) | C5—Ru1—Ru2—C17 | 157.6 (5) |
C21—C15—C16—C17 | −177.5 (4) | Ru3—Ru1—Ru2—C17 | 30.6 (5) |
Ru2—C15—C16—C17 | −54.5 (4) | O1—Ru1—Ru2—C20 | 116.90 (18) |
C20—C15—C16—C22 | 175.1 (4) | C6—Ru1—Ru2—C20 | −20.34 (18) |
C21—C15—C16—C22 | −1.0 (7) | C4—Ru1—Ru2—C20 | −120.1 (4) |
Ru2—C15—C16—C22 | 122.0 (4) | C2—Ru1—Ru2—C20 | 62.81 (19) |
C20—C15—C16—Ru2 | 53.1 (4) | C3—Ru1—Ru2—C20 | 107.8 (3) |
C21—C15—C16—Ru2 | −123.0 (4) | C1—Ru1—Ru2—C20 | 22.19 (18) |
C15—C16—C17—C18 | 0.9 (6) | C5—Ru1—Ru2—C20 | −59.7 (2) |
C22—C16—C17—C18 | −175.5 (4) | Ru3—Ru1—Ru2—C20 | 173.30 (14) |
Ru2—C16—C17—C18 | −54.5 (4) | O1—Ru1—Ru2—C16 | 36.9 (2) |
C15—C16—C17—Ru2 | 55.4 (4) | C6—Ru1—Ru2—C16 | −100.3 (2) |
C22—C16—C17—Ru2 | −121.0 (4) | C4—Ru1—Ru2—C16 | 160.0 (5) |
C16—C17—C18—C19 | −0.4 (6) | C2—Ru1—Ru2—C16 | −17.1 (2) |
Ru2—C17—C18—C19 | −54.7 (3) | C3—Ru1—Ru2—C16 | 27.8 (3) |
C16—C17—C18—C23 | −179.6 (4) | C1—Ru1—Ru2—C16 | −57.8 (2) |
Ru2—C17—C18—C23 | 126.2 (4) | C5—Ru1—Ru2—C16 | −139.7 (2) |
C16—C17—C18—Ru2 | 54.3 (4) | Ru3—Ru1—Ru2—C16 | 93.34 (18) |
C17—C18—C19—C20 | 0.4 (6) | O1—Ru1—Ru2—C18 | −159.9 (3) |
C23—C18—C19—C20 | 179.5 (4) | C6—Ru1—Ru2—C18 | 62.8 (3) |
Ru2—C18—C19—C20 | −53.2 (4) | C4—Ru1—Ru2—C18 | −36.9 (5) |
C17—C18—C19—C24 | −179.1 (4) | C2—Ru1—Ru2—C18 | 146.0 (3) |
C23—C18—C19—C24 | 0.0 (7) | C3—Ru1—Ru2—C18 | −169.1 (4) |
Ru2—C18—C19—C24 | 127.3 (4) | C1—Ru1—Ru2—C18 | 105.4 (3) |
C17—C18—C19—Ru2 | 53.6 (3) | C5—Ru1—Ru2—C18 | 23.4 (3) |
C23—C18—C19—Ru2 | −127.2 (4) | Ru3—Ru1—Ru2—C18 | −103.5 (3) |
C16—C15—C20—C19 | 1.5 (7) | O1—Ru1—Ru2—C19 | 157.03 (19) |
C21—C15—C20—C19 | 177.6 (4) | C6—Ru1—Ru2—C19 | 19.8 (2) |
Ru2—C15—C20—C19 | 54.7 (4) | C4—Ru1—Ru2—C19 | −80.0 (5) |
C16—C15—C20—Ru2 | −53.2 (4) | C2—Ru1—Ru2—C19 | 102.9 (2) |
C21—C15—C20—Ru2 | 122.9 (4) | C3—Ru1—Ru2—C19 | 147.9 (3) |
C18—C19—C20—C15 | −1.0 (7) | C1—Ru1—Ru2—C19 | 62.3 (2) |
C24—C19—C20—C15 | 178.5 (4) | C5—Ru1—Ru2—C19 | −19.6 (2) |
Ru2—C19—C20—C15 | −54.8 (4) | Ru3—Ru1—Ru2—C19 | −146.57 (16) |
C18—C19—C20—Ru2 | 53.8 (4) | O1—Ru1—Ru2—C15 | 76.34 (18) |
C24—C19—C20—Ru2 | −126.7 (4) | C6—Ru1—Ru2—C15 | −60.90 (19) |
C30—C25—C26—C27 | −3.0 (7) | C4—Ru1—Ru2—C15 | −160.6 (4) |
C31—C25—C26—C27 | 178.2 (4) | C2—Ru1—Ru2—C15 | 22.25 (19) |
Ru3—C25—C26—C27 | 52.0 (4) | C3—Ru1—Ru2—C15 | 67.2 (3) |
C30—C25—C26—C32 | 177.8 (4) | C1—Ru1—Ru2—C15 | −18.37 (18) |
C31—C25—C26—C32 | −1.0 (7) | C5—Ru1—Ru2—C15 | −100.3 (2) |
Ru3—C25—C26—C32 | −127.3 (4) | Ru3—Ru1—Ru2—C15 | 132.74 (15) |
C30—C25—C26—Ru3 | −54.9 (4) | O1—Ru1—Ru2—Ru3 | −56.40 (11) |
C31—C25—C26—Ru3 | 126.3 (5) | C6—Ru1—Ru2—Ru3 | 166.36 (13) |
C25—C26—C27—C28 | 4.0 (7) | C4—Ru1—Ru2—Ru3 | 66.6 (4) |
C32—C26—C27—C28 | −176.7 (4) | C2—Ru1—Ru2—Ru3 | −110.49 (14) |
Ru3—C26—C27—C28 | 57.0 (4) | C3—Ru1—Ru2—Ru3 | −65.5 (3) |
C25—C26—C27—Ru3 | −53.0 (4) | C1—Ru1—Ru2—Ru3 | −151.11 (12) |
C32—C26—C27—Ru3 | 126.3 (4) | C5—Ru1—Ru2—Ru3 | 126.95 (16) |
C26—C27—C28—C29 | −3.9 (7) | Ru1—O1—Ru3—C27 | 75.2 (2) |
Ru3—C27—C28—C29 | 53.1 (4) | Ru2—O1—Ru3—C27 | 163.66 (19) |
C26—C27—C28—C33 | 178.7 (4) | Ru1—O1—Ru3—C30 | 173.88 (16) |
Ru3—C27—C28—C33 | −124.3 (4) | Ru2—O1—Ru3—C30 | −97.67 (17) |
C26—C27—C28—Ru3 | −57.0 (4) | Ru1—O1—Ru3—C29 | 139.82 (17) |
C27—C28—C29—C30 | 2.7 (6) | Ru2—O1—Ru3—C29 | −131.73 (17) |
C33—C28—C29—C30 | −180.0 (4) | Ru1—O1—Ru3—C25 | −160.8 (2) |
Ru3—C28—C29—C30 | 55.1 (4) | Ru2—O1—Ru3—C25 | −72.3 (3) |
C27—C28—C29—C34 | −175.8 (4) | Ru1—O1—Ru3—C28 | 102.45 (16) |
C33—C28—C29—C34 | 1.6 (7) | Ru2—O1—Ru3—C28 | −169.10 (15) |
Ru3—C28—C29—C34 | −123.4 (4) | Ru2—O1—Ru3—Ru1 | 88.45 (10) |
C27—C28—C29—Ru3 | −52.4 (4) | Ru1—O1—Ru3—Ru2 | −88.45 (10) |
C33—C28—C29—Ru3 | 125.0 (4) | C28—C27—Ru3—O1 | 46.9 (4) |
C28—C29—C30—C25 | −1.9 (7) | C26—C27—Ru3—O1 | −179.9 (2) |
C34—C29—C30—C25 | 176.6 (4) | C28—C27—Ru3—C30 | −66.8 (3) |
Ru3—C29—C30—C25 | 53.5 (4) | C26—C27—Ru3—C30 | 66.4 (3) |
C28—C29—C30—Ru3 | −55.4 (4) | C28—C27—Ru3—C29 | −29.6 (3) |
C34—C29—C30—Ru3 | 123.1 (4) | C26—C27—Ru3—C29 | 103.6 (3) |
C26—C25—C30—C29 | 2.1 (7) | C28—C27—Ru3—C25 | −104.3 (3) |
C31—C25—C30—C29 | −179.1 (4) | C26—C27—Ru3—C25 | 28.9 (3) |
Ru3—C25—C30—C29 | −53.5 (4) | C26—C27—Ru3—C28 | 133.2 (4) |
C26—C25—C30—Ru3 | 55.6 (4) | C28—C27—Ru3—C26 | −133.2 (4) |
C31—C25—C30—Ru3 | −125.6 (4) | C28—C27—Ru3—Ru1 | 95.3 (3) |
O2—C7—O3—C8 | 7.2 (6) | C26—C27—Ru3—Ru1 | −131.5 (3) |
C1—C7—O3—C8 | −170.5 (4) | C28—C27—Ru3—Ru2 | 139.2 (6) |
C9—C8—O3—C7 | 165.8 (4) | C26—C27—Ru3—Ru2 | −87.6 (7) |
O5—C10—O4—C9 | 2.3 (8) | C29—C30—Ru3—O1 | −67.2 (3) |
C11—C10—O4—C9 | −175.1 (4) | C25—C30—Ru3—O1 | 157.8 (3) |
C8—C9—O4—C10 | 104.6 (5) | C29—C30—Ru3—C27 | 67.5 (3) |
Ru3—O1—Ru1—C6 | 166.04 (19) | C25—C30—Ru3—C27 | −67.4 (3) |
Ru2—O1—Ru1—C6 | 78.4 (2) | C25—C30—Ru3—C29 | −134.9 (4) |
Ru3—O1—Ru1—C4 | −70.6 (2) | C29—C30—Ru3—C25 | 134.9 (4) |
Ru2—O1—Ru1—C4 | −158.25 (19) | C29—C30—Ru3—C28 | 30.5 (3) |
Ru3—O1—Ru1—C2 | −131.93 (13) | C25—C30—Ru3—C28 | −104.4 (3) |
Ru2—O1—Ru1—C2 | 140.38 (13) | C29—C30—Ru3—C26 | 104.8 (3) |
Ru3—O1—Ru1—C3 | −96.30 (14) | C25—C30—Ru3—C26 | −30.1 (3) |
Ru2—O1—Ru1—C3 | 176.01 (13) | C29—C30—Ru3—Ru1 | −54.0 (5) |
Ru3—O1—Ru1—C1 | −167.94 (12) | C25—C30—Ru3—Ru1 | 171.1 (3) |
Ru2—O1—Ru1—C1 | 104.37 (13) | C29—C30—Ru3—Ru2 | −118.0 (3) |
Ru2—O1—Ru1—Ru3 | −87.69 (10) | C25—C30—Ru3—Ru2 | 107.1 (3) |
Ru3—O1—Ru1—Ru2 | 87.69 (10) | C30—C29—Ru3—O1 | 122.6 (3) |
C5—C6—Ru1—O1 | 173.6 (2) | C28—C29—Ru3—O1 | −107.2 (3) |
C1—C6—Ru1—O1 | 41.7 (3) | C34—C29—Ru3—O1 | 8.9 (5) |
C5—C6—Ru1—C4 | 28.6 (3) | C30—C29—Ru3—C27 | −101.0 (3) |
C1—C6—Ru1—C4 | −103.3 (3) | C28—C29—Ru3—C27 | 29.2 (3) |
C5—C6—Ru1—C2 | 102.7 (3) | C34—C29—Ru3—C27 | 145.3 (6) |
C1—C6—Ru1—C2 | −29.1 (2) | C28—C29—Ru3—C30 | 130.2 (4) |
C5—C6—Ru1—C3 | 65.3 (3) | C34—C29—Ru3—C30 | −113.8 (7) |
C1—C6—Ru1—C3 | −66.6 (2) | C30—C29—Ru3—C25 | −27.6 (3) |
C5—C6—Ru1—C1 | 131.8 (4) | C28—C29—Ru3—C25 | 102.6 (3) |
C1—C6—Ru1—C5 | −131.8 (4) | C34—C29—Ru3—C25 | −141.4 (6) |
C5—C6—Ru1—Ru3 | −61.0 (6) | C30—C29—Ru3—C28 | −130.2 (4) |
C1—C6—Ru1—Ru3 | 167.1 (4) | C34—C29—Ru3—C28 | 116.1 (7) |
C5—C6—Ru1—Ru2 | −134.0 (2) | C30—C29—Ru3—C26 | −64.2 (3) |
C1—C6—Ru1—Ru2 | 94.1 (2) | C28—C29—Ru3—C26 | 65.9 (3) |
C3—C4—Ru1—O1 | −42.7 (3) | C34—C29—Ru3—C26 | −178.0 (6) |
C5—C4—Ru1—O1 | −174.4 (2) | C30—C29—Ru3—Ru1 | 159.5 (2) |
C3—C4—Ru1—C6 | 103.2 (3) | C28—C29—Ru3—Ru1 | −70.4 (3) |
C5—C4—Ru1—C6 | −28.5 (2) | C34—C29—Ru3—Ru1 | 45.7 (6) |
C3—C4—Ru1—C2 | 28.0 (2) | C30—C29—Ru3—Ru2 | 81.8 (3) |
C5—C4—Ru1—C2 | −103.7 (3) | C28—C29—Ru3—Ru2 | −148.1 (2) |
C5—C4—Ru1—C3 | −131.7 (4) | C34—C29—Ru3—Ru2 | −32.0 (6) |
C3—C4—Ru1—C1 | 65.2 (3) | C26—C25—Ru3—O1 | −169.8 (3) |
C5—C4—Ru1—C1 | −66.4 (3) | C30—C25—Ru3—O1 | −39.7 (4) |
C3—C4—Ru1—C5 | 131.7 (4) | C31—C25—Ru3—O1 | 72.0 (6) |
C3—C4—Ru1—Ru3 | −90.2 (2) | C26—C25—Ru3—C27 | −29.1 (3) |
C5—C4—Ru1—Ru3 | 138.2 (2) | C30—C25—Ru3—C27 | 101.0 (3) |
C3—C4—Ru1—Ru2 | −149.6 (3) | C31—C25—Ru3—C27 | −147.3 (6) |
C5—C4—Ru1—Ru2 | 78.8 (5) | C26—C25—Ru3—C30 | −130.1 (4) |
C3—C2—Ru1—O1 | 115.5 (2) | C31—C25—Ru3—C30 | 111.7 (7) |
C1—C2—Ru1—O1 | −114.4 (2) | C26—C25—Ru3—C29 | −102.7 (3) |
C14—C2—Ru1—O1 | 3.3 (4) | C30—C25—Ru3—C29 | 27.4 (3) |
C3—C2—Ru1—C6 | −100.3 (3) | C31—C25—Ru3—C29 | 139.1 (6) |
C1—C2—Ru1—C6 | 29.8 (2) | C26—C25—Ru3—C28 | −65.4 (3) |
C14—C2—Ru1—C6 | 147.4 (4) | C30—C25—Ru3—C28 | 64.6 (3) |
C3—C2—Ru1—C4 | −27.7 (2) | C31—C25—Ru3—C28 | 176.4 (6) |
C1—C2—Ru1—C4 | 102.3 (3) | C30—C25—Ru3—C26 | 130.1 (4) |
C14—C2—Ru1—C4 | −140.0 (4) | C31—C25—Ru3—C26 | −118.2 (7) |
C1—C2—Ru1—C3 | 130.1 (4) | C26—C25—Ru3—Ru1 | 59.5 (6) |
C14—C2—Ru1—C3 | −112.3 (5) | C30—C25—Ru3—Ru1 | −170.4 (3) |
C3—C2—Ru1—C1 | −130.1 (4) | C31—C25—Ru3—Ru1 | −58.7 (8) |
C14—C2—Ru1—C1 | 117.7 (5) | C26—C25—Ru3—Ru2 | 139.0 (2) |
C3—C2—Ru1—C5 | −64.0 (3) | C30—C25—Ru3—Ru2 | −90.9 (3) |
C1—C2—Ru1—C5 | 66.0 (2) | C31—C25—Ru3—Ru2 | 20.8 (6) |
C14—C2—Ru1—C5 | −176.3 (4) | C27—C28—Ru3—O1 | −147.7 (3) |
C3—C2—Ru1—Ru3 | 75.6 (3) | C29—C28—Ru3—O1 | 80.6 (3) |
C1—C2—Ru1—Ru3 | −154.32 (19) | C33—C28—Ru3—O1 | −34.9 (6) |
C14—C2—Ru1—Ru3 | −36.7 (4) | C29—C28—Ru3—C27 | −131.7 (4) |
C3—C2—Ru1—Ru2 | 151.4 (2) | C33—C28—Ru3—C27 | 112.7 (6) |
C1—C2—Ru1—Ru2 | −78.6 (2) | C27—C28—Ru3—C30 | 101.6 (3) |
C14—C2—Ru1—Ru2 | 39.1 (4) | C29—C28—Ru3—C30 | −30.1 (3) |
C4—C3—Ru1—O1 | 153.0 (2) | C33—C28—Ru3—C30 | −145.7 (6) |
C2—C3—Ru1—O1 | −72.7 (3) | C27—C28—Ru3—C29 | 131.7 (4) |
C4—C3—Ru1—C6 | −65.5 (3) | C33—C28—Ru3—C29 | −115.6 (6) |
C2—C3—Ru1—C6 | 68.8 (3) | C27—C28—Ru3—C25 | 65.0 (3) |
C2—C3—Ru1—C4 | 134.3 (4) | C29—C28—Ru3—C25 | −66.7 (3) |
C4—C3—Ru1—C2 | −134.3 (4) | C33—C28—Ru3—C25 | 177.7 (6) |
C4—C3—Ru1—C1 | −103.9 (3) | C27—C28—Ru3—C26 | 28.6 (3) |
C2—C3—Ru1—C1 | 30.5 (2) | C29—C28—Ru3—C26 | −103.1 (3) |
C4—C3—Ru1—C5 | −29.2 (2) | C33—C28—Ru3—C26 | 141.3 (6) |
C2—C3—Ru1—C5 | 105.1 (3) | C27—C28—Ru3—Ru1 | −99.3 (3) |
C4—C3—Ru1—Ru3 | 104.0 (2) | C29—C28—Ru3—Ru1 | 129.1 (3) |
C2—C3—Ru1—Ru3 | −121.6 (2) | C33—C28—Ru3—Ru1 | 13.5 (6) |
C4—C3—Ru1—Ru2 | 159.9 (2) | C27—C28—Ru3—Ru2 | −164.1 (2) |
C2—C3—Ru1—Ru2 | −65.7 (4) | C29—C28—Ru3—Ru2 | 64.3 (4) |
C2—C1—Ru1—O1 | 73.7 (3) | C33—C28—Ru3—Ru2 | −51.3 (7) |
C6—C1—Ru1—O1 | −154.2 (2) | C25—C26—Ru3—C27 | 132.3 (4) |
C7—C1—Ru1—O1 | −43.0 (4) | C32—C26—Ru3—C27 | −112.4 (6) |
C2—C1—Ru1—C6 | −132.0 (4) | C27—C26—Ru3—C30 | −101.9 (3) |
C7—C1—Ru1—C6 | 111.2 (5) | C25—C26—Ru3—C30 | 30.4 (3) |
C2—C1—Ru1—C4 | −66.8 (3) | C32—C26—Ru3—C30 | 145.7 (6) |
C6—C1—Ru1—C4 | 65.2 (2) | C27—C26—Ru3—C29 | −65.5 (3) |
C7—C1—Ru1—C4 | 176.4 (4) | C25—C26—Ru3—C29 | 66.7 (3) |
C6—C1—Ru1—C2 | 132.0 (4) | C32—C26—Ru3—C29 | −178.0 (5) |
C7—C1—Ru1—C2 | −116.8 (5) | C27—C26—Ru3—C25 | −132.3 (4) |
C2—C1—Ru1—C3 | −30.3 (2) | C32—C26—Ru3—C25 | 115.3 (6) |
C6—C1—Ru1—C3 | 101.7 (3) | C27—C26—Ru3—C28 | −28.4 (3) |
C7—C1—Ru1—C3 | −147.1 (4) | C25—C26—Ru3—C28 | 103.9 (3) |
C2—C1—Ru1—C5 | −103.3 (3) | C32—C26—Ru3—C28 | −140.8 (6) |
C6—C1—Ru1—C5 | 28.8 (2) | C27—C26—Ru3—Ru1 | 68.8 (3) |
C7—C1—Ru1—C5 | 140.0 (4) | C25—C26—Ru3—Ru1 | −158.9 (2) |
C2—C1—Ru1—Ru3 | 54.1 (4) | C32—C26—Ru3—Ru1 | −43.6 (6) |
C6—C1—Ru1—Ru3 | −173.9 (2) | C27—C26—Ru3—Ru2 | 161.2 (2) |
C7—C1—Ru1—Ru3 | −62.7 (5) | C25—C26—Ru3—Ru2 | −66.5 (3) |
C2—C1—Ru1—Ru2 | 123.2 (2) | C32—C26—Ru3—Ru2 | 48.8 (6) |
C6—C1—Ru1—Ru2 | −104.8 (2) | C6—Ru1—Ru3—O1 | −135.8 (5) |
C7—C1—Ru1—Ru2 | 6.4 (4) | C4—Ru1—Ru3—O1 | 139.86 (17) |
C4—C5—Ru1—C6 | 132.9 (4) | C2—Ru1—Ru3—O1 | 62.34 (17) |
C6—C5—Ru1—C4 | −132.9 (4) | C3—Ru1—Ru3—O1 | 100.56 (16) |
C6—C5—Ru1—C2 | −67.1 (3) | C1—Ru1—Ru3—O1 | 26.2 (3) |
C4—C5—Ru1—C2 | 65.9 (3) | C5—Ru1—Ru3—O1 | 175.17 (19) |
C6—C5—Ru1—C3 | −103.6 (3) | Ru2—Ru1—Ru3—O1 | −56.24 (11) |
C4—C5—Ru1—C3 | 29.4 (2) | O1—Ru1—Ru3—C27 | −133.12 (19) |
C6—C5—Ru1—C1 | −30.0 (2) | C6—Ru1—Ru3—C27 | 91.1 (5) |
C4—C5—Ru1—C1 | 102.9 (3) | C4—Ru1—Ru3—C27 | 6.7 (2) |
C6—C5—Ru1—Ru3 | 164.4 (2) | C2—Ru1—Ru3—C27 | −70.8 (2) |
C4—C5—Ru1—Ru3 | −62.7 (3) | C3—Ru1—Ru3—C27 | −32.56 (19) |
C6—C5—Ru1—Ru2 | 70.9 (3) | C1—Ru1—Ru3—C27 | −107.0 (3) |
C4—C5—Ru1—Ru2 | −156.2 (2) | C5—Ru1—Ru3—C27 | 42.1 (2) |
Ru1—O1—Ru2—C17 | 173.17 (15) | Ru2—Ru1—Ru3—C27 | 170.65 (15) |
Ru3—O1—Ru2—C17 | 85.26 (17) | O1—Ru1—Ru3—C30 | −16.7 (4) |
Ru1—O1—Ru2—C20 | −88.66 (18) | C6—Ru1—Ru3—C30 | −152.5 (6) |
Ru3—O1—Ru2—C20 | −176.58 (15) | C4—Ru1—Ru3—C30 | 123.1 (4) |
Ru1—O1—Ru2—C16 | −156.02 (14) | C2—Ru1—Ru3—C30 | 45.6 (4) |
Ru3—O1—Ru2—C16 | 116.07 (14) | C3—Ru1—Ru3—C30 | 83.8 (4) |
Ru1—O1—Ru2—C18 | 154.9 (3) | C1—Ru1—Ru3—C30 | 9.4 (5) |
Ru3—O1—Ru2—C18 | 66.9 (4) | C5—Ru1—Ru3—C30 | 158.4 (4) |
Ru1—O1—Ru2—C19 | −72.9 (4) | Ru2—Ru1—Ru3—C30 | −73.0 (4) |
Ru3—O1—Ru2—C19 | −160.8 (4) | O1—Ru1—Ru3—C29 | −55.8 (2) |
Ru1—O1—Ru2—C15 | −118.06 (15) | C6—Ru1—Ru3—C29 | 168.5 (5) |
Ru3—O1—Ru2—C15 | 154.03 (14) | C4—Ru1—Ru3—C29 | 84.1 (2) |
Ru1—O1—Ru2—Ru3 | 87.91 (10) | C2—Ru1—Ru3—C29 | 6.6 (2) |
Ru3—O1—Ru2—Ru1 | −87.91 (10) | C3—Ru1—Ru3—C29 | 44.8 (2) |
C16—C17—Ru2—O1 | 56.5 (3) | C1—Ru1—Ru3—C29 | −29.6 (3) |
C18—C17—Ru2—O1 | −169.1 (2) | C5—Ru1—Ru3—C29 | 119.4 (2) |
C16—C17—Ru2—C20 | −67.1 (3) | Ru2—Ru1—Ru3—C29 | −111.99 (18) |
C18—C17—Ru2—C20 | 67.4 (3) | O1—Ru1—Ru3—C25 | 145.7 (4) |
C18—C17—Ru2—C16 | 134.5 (4) | C6—Ru1—Ru3—C25 | 9.9 (7) |
C16—C17—Ru2—C18 | −134.5 (4) | C4—Ru1—Ru3—C25 | −74.5 (4) |
C16—C17—Ru2—C19 | −104.4 (3) | C2—Ru1—Ru3—C25 | −152.0 (4) |
C18—C17—Ru2—C19 | 30.0 (3) | C3—Ru1—Ru3—C25 | −113.8 (4) |
C16—C17—Ru2—C15 | −30.0 (3) | C1—Ru1—Ru3—C25 | 171.8 (5) |
C18—C17—Ru2—C15 | 104.4 (3) | C5—Ru1—Ru3—C25 | −39.1 (5) |
C16—C17—Ru2—Ru3 | 105.7 (3) | Ru2—Ru1—Ru3—C25 | 89.5 (4) |
C18—C17—Ru2—Ru3 | −119.9 (2) | O1—Ru1—Ru3—C28 | −93.48 (18) |
C16—C17—Ru2—Ru1 | 78.0 (6) | C6—Ru1—Ru3—C28 | 130.7 (5) |
C18—C17—Ru2—Ru1 | −147.6 (4) | C4—Ru1—Ru3—C28 | 46.4 (2) |
C15—C20—Ru2—O1 | −53.6 (3) | C2—Ru1—Ru3—C28 | −31.1 (2) |
C19—C20—Ru2—O1 | 171.5 (2) | C3—Ru1—Ru3—C28 | 7.1 (2) |
C15—C20—Ru2—C17 | 67.4 (3) | C1—Ru1—Ru3—C28 | −67.3 (3) |
C19—C20—Ru2—C17 | −67.4 (3) | C5—Ru1—Ru3—C28 | 81.7 (2) |
C15—C20—Ru2—C16 | 29.9 (3) | Ru2—Ru1—Ru3—C28 | −149.71 (15) |
C19—C20—Ru2—C16 | −104.9 (3) | O1—Ru1—Ru3—C26 | −170.4 (2) |
C15—C20—Ru2—C18 | 105.3 (3) | C6—Ru1—Ru3—C26 | 53.8 (6) |
C19—C20—Ru2—C18 | −29.6 (3) | C4—Ru1—Ru3—C26 | −30.6 (2) |
C15—C20—Ru2—C19 | 134.8 (4) | C2—Ru1—Ru3—C26 | −108.1 (2) |
C19—C20—Ru2—C15 | −134.8 (4) | C3—Ru1—Ru3—C26 | −69.9 (2) |
C15—C20—Ru2—Ru1 | −104.3 (3) | C1—Ru1—Ru3—C26 | −144.3 (3) |
C19—C20—Ru2—Ru1 | 120.9 (2) | C5—Ru1—Ru3—C26 | 4.7 (2) |
C17—C16—Ru2—O1 | −134.5 (3) | Ru2—Ru1—Ru3—C26 | 133.34 (17) |
C15—C16—Ru2—O1 | 94.7 (3) | O1—Ru1—Ru3—Ru2 | 56.24 (11) |
C22—C16—Ru2—O1 | −19.8 (4) | C6—Ru1—Ru3—Ru2 | −79.6 (5) |
C15—C16—Ru2—C17 | −130.8 (4) | C4—Ru1—Ru3—Ru2 | −163.90 (13) |
C22—C16—Ru2—C17 | 114.7 (5) | C2—Ru1—Ru3—Ru2 | 118.58 (13) |
C17—C16—Ru2—C20 | 101.3 (3) | C3—Ru1—Ru3—Ru2 | 156.79 (13) |
C15—C16—Ru2—C20 | −29.5 (3) | C1—Ru1—Ru3—Ru2 | 82.4 (2) |
C22—C16—Ru2—C20 | −144.0 (5) | C5—Ru1—Ru3—Ru2 | −128.60 (16) |
C17—C16—Ru2—C18 | 28.0 (3) | C17—Ru2—Ru3—O1 | −117.02 (16) |
C15—C16—Ru2—C18 | −102.8 (3) | C16—Ru2—Ru3—O1 | −77.09 (17) |
C22—C16—Ru2—C18 | 142.7 (5) | C18—Ru2—Ru3—O1 | −156.13 (18) |
C17—C16—Ru2—C19 | 64.9 (3) | C19—Ru2—Ru3—O1 | 166.9 (3) |
C15—C16—Ru2—C19 | −65.9 (3) | C15—Ru2—Ru3—O1 | −40.7 (2) |
C22—C16—Ru2—C19 | 179.6 (4) | Ru1—Ru2—Ru3—O1 | 55.82 (11) |
C17—C16—Ru2—C15 | 130.8 (4) | O1—Ru2—Ru3—C27 | −103.8 (7) |
C22—C16—Ru2—C15 | −114.5 (5) | C17—Ru2—Ru3—C27 | 139.2 (7) |
C17—C16—Ru2—Ru3 | −89.4 (3) | C16—Ru2—Ru3—C27 | 179.1 (7) |
C15—C16—Ru2—Ru3 | 139.8 (2) | C18—Ru2—Ru3—C27 | 100.1 (7) |
C22—C16—Ru2—Ru3 | 25.3 (4) | C19—Ru2—Ru3—C27 | 63.1 (7) |
C17—C16—Ru2—Ru1 | −160.2 (2) | C15—Ru2—Ru3—C27 | −144.5 (7) |
C15—C16—Ru2—Ru1 | 69.0 (3) | Ru1—Ru2—Ru3—C27 | −48.0 (7) |
C22—C16—Ru2—Ru1 | −45.5 (5) | O1—Ru2—Ru3—C30 | 103.9 (2) |
C19—C18—Ru2—O1 | 156.3 (3) | C17—Ru2—Ru3—C30 | −13.1 (2) |
C17—C18—Ru2—O1 | 25.8 (5) | C16—Ru2—Ru3—C30 | 26.8 (2) |
C23—C18—Ru2—O1 | −84.8 (6) | C18—Ru2—Ru3—C30 | −52.2 (2) |
C19—C18—Ru2—C17 | 130.5 (4) | C19—Ru2—Ru3—C30 | −89.2 (3) |
C23—C18—Ru2—C17 | −110.5 (6) | C15—Ru2—Ru3—C30 | 63.2 (2) |
C19—C18—Ru2—C20 | 29.5 (3) | Ru1—Ru2—Ru3—C30 | 159.70 (16) |
C17—C18—Ru2—C20 | −101.0 (3) | O1—Ru2—Ru3—C29 | 63.7 (2) |
C23—C18—Ru2—C20 | 148.5 (5) | C17—Ru2—Ru3—C29 | −53.3 (2) |
C19—C18—Ru2—C16 | 102.7 (3) | C16—Ru2—Ru3—C29 | −13.3 (2) |
C17—C18—Ru2—C16 | −27.8 (3) | C18—Ru2—Ru3—C29 | −92.4 (2) |
C23—C18—Ru2—C16 | −138.4 (5) | C19—Ru2—Ru3—C29 | −129.4 (3) |
C17—C18—Ru2—C19 | −130.5 (4) | C15—Ru2—Ru3—C29 | 23.0 (3) |
C23—C18—Ru2—C19 | 119.0 (6) | Ru1—Ru2—Ru3—C29 | 119.57 (17) |
C19—C18—Ru2—C15 | 65.6 (3) | O1—Ru2—Ru3—C25 | 144.8 (2) |
C17—C18—Ru2—C15 | −64.9 (3) | C17—Ru2—Ru3—C25 | 27.8 (2) |
C23—C18—Ru2—C15 | −175.4 (5) | C16—Ru2—Ru3—C25 | 67.7 (2) |
C19—C18—Ru2—Ru3 | −151.8 (2) | C18—Ru2—Ru3—C25 | −11.3 (2) |
C17—C18—Ru2—Ru3 | 77.7 (3) | C19—Ru2—Ru3—C25 | −48.3 (3) |
C23—C18—Ru2—Ru3 | −32.8 (5) | C15—Ru2—Ru3—C25 | 104.1 (2) |
C19—C18—Ru2—Ru1 | −65.3 (4) | Ru1—Ru2—Ru3—C25 | −159.34 (17) |
C17—C18—Ru2—Ru1 | 164.2 (2) | O1—Ru2—Ru3—C28 | 22.0 (3) |
C23—C18—Ru2—Ru1 | 53.7 (6) | C17—Ru2—Ru3—C28 | −95.0 (3) |
C20—C19—Ru2—O1 | −21.7 (6) | C16—Ru2—Ru3—C28 | −55.1 (3) |
C18—C19—Ru2—O1 | −153.1 (4) | C18—Ru2—Ru3—C28 | −134.1 (3) |
C24—C19—Ru2—O1 | 89.8 (6) | C19—Ru2—Ru3—C28 | −171.1 (4) |
C20—C19—Ru2—C17 | 101.1 (3) | C15—Ru2—Ru3—C28 | −18.7 (3) |
C18—C19—Ru2—C17 | −30.3 (3) | Ru1—Ru2—Ru3—C28 | 77.8 (3) |
C24—C19—Ru2—C17 | −147.4 (5) | O1—Ru2—Ru3—C26 | −176.6 (2) |
C18—C19—Ru2—C20 | −131.5 (4) | C17—Ru2—Ru3—C26 | 66.4 (2) |
C24—C19—Ru2—C20 | 111.5 (6) | C16—Ru2—Ru3—C26 | 106.3 (2) |
C20—C19—Ru2—C16 | 64.4 (3) | C18—Ru2—Ru3—C26 | 27.3 (2) |
C18—C19—Ru2—C16 | −67.0 (3) | C19—Ru2—Ru3—C26 | −9.7 (3) |
C24—C19—Ru2—C16 | 175.9 (5) | C15—Ru2—Ru3—C26 | 142.7 (3) |
C20—C19—Ru2—C18 | 131.5 (4) | Ru1—Ru2—Ru3—C26 | −120.8 (2) |
C24—C19—Ru2—C18 | −117.1 (6) | O1—Ru2—Ru3—Ru1 | −55.82 (11) |
C20—C19—Ru2—C15 | 27.5 (3) | C17—Ru2—Ru3—Ru1 | −172.83 (13) |
C18—C19—Ru2—C15 | −104.0 (3) | C16—Ru2—Ru3—Ru1 | −132.91 (13) |
C24—C19—Ru2—C15 | 138.9 (5) | C18—Ru2—Ru3—Ru1 | 148.05 (14) |
C20—C19—Ru2—Ru3 | −171.9 (2) | C19—Ru2—Ru3—Ru1 | 111.1 (2) |
C18—C19—Ru2—Ru3 | 56.6 (4) | C15—Ru2—Ru3—Ru1 | −96.53 (18) |
C24—C19—Ru2—Ru3 | −60.5 (6) |