Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680402745X/dn6170sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S160053680402745X/dn6170Isup2.hkl |
CCDC reference: 250531
Data collection: EXPOSE in IPDS Software (Stoe & Cie, 2000); cell refinement: CELL in IPDS Software; data reduction: INTEGRATE in IPDS Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
C18H24Cl4Ru2·0.67CH2Cl2 | Z = 3 |
Mr = 640.93 | F(000) = 948 |
Triclinic, P1 | Dx = 1.886 Mg m−3 |
Hall symbol: -P 1 | Melting point: [Ru2 Cl4 (C9 H12)2], 0.67C H2 Cl2 K |
a = 9.9388 (11) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 12.3703 (13) Å | Cell parameters from 7734 reflections |
c = 14.4034 (17) Å | θ = 2.1–25.8° |
α = 97.105 (13)° | µ = 1.97 mm−1 |
β = 90.644 (13)° | T = 153 K |
γ = 105.358 (12)° | Plate, orange |
V = 1692.7 (3) Å3 | 0.57 × 0.36 × 0.14 mm |
Stoe IPDS diffractometer | 6090 independent reflections |
Radiation source: fine-focus sealed tube | 3899 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.062 |
φ scans | θmax = 25.8°, θmin = 2.1° |
Absorption correction: multi-scan (Blessing, 1995) | h = −12→12 |
Tmin = 0.463, Tmax = 0.759 | k = −14→14 |
12013 measured reflections | l = −17→17 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.053 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.136 | H-atom parameters constrained |
S = 0.93 | w = 1/[σ2(Fo2) + (0.0745P)2] where P = (Fo2 + 2Fc2)/3 |
6090 reflections | (Δ/σ)max < 0.001 |
361 parameters | Δρmax = 1.61 e Å−3 |
0 restraints | Δρmin = −1.37 e Å−3 |
Experimental. A crystal was mounted at 153 K on a Stoe Image Plate Diffraction System (Stoe & Cie, 2000) using Mo Kα graphite monochromated radiation. Image plate distance 70 mm, φ oscillation scans 0 - 200°, step Δφ = 1.6°, 1 minute per frame. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
C1 | 0.1255 (8) | 0.1103 (9) | 0.7401 (8) | 0.059 (3) | |
C2 | 0.1279 (8) | 0.0291 (10) | 0.6609 (6) | 0.055 (3) | |
C3 | 0.0877 (7) | −0.0878 (10) | 0.6739 (7) | 0.063 (3) | |
H3 | 0.0857 | −0.1430 | 0.6235 | 0.076* | |
C4 | 0.0507 (8) | −0.1201 (10) | 0.7639 (8) | 0.061 (3) | |
C5 | 0.0487 (8) | −0.0411 (10) | 0.8406 (8) | 0.064 (3) | |
H5 | 0.0226 | −0.0632 | 0.8987 | 0.076* | |
C6 | 0.0860 (8) | 0.0691 (11) | 0.8281 (7) | 0.063 (3) | |
H6 | 0.0863 | 0.1222 | 0.8798 | 0.076* | |
C7 | 0.1718 (10) | 0.2290 (11) | 0.7344 (10) | 0.093 (4) | |
H7A | 0.2649 | 0.2472 | 0.7124 | 0.139* | |
H7B | 0.1713 | 0.2704 | 0.7953 | 0.139* | |
H7C | 0.1104 | 0.2491 | 0.6918 | 0.139* | |
C8 | 0.1719 (10) | 0.0610 (11) | 0.5664 (7) | 0.085 (4) | |
H8A | 0.1866 | −0.0035 | 0.5278 | 0.127* | |
H8B | 0.2570 | 0.1208 | 0.5735 | 0.127* | |
H8C | 0.1001 | 0.0861 | 0.5374 | 0.127* | |
C9 | 0.0164 (15) | −0.2408 (16) | 0.7884 (11) | 0.145 (7) | |
H9A | 0.0253 | −0.2388 | 0.8551 | 0.217* | |
H9B | 0.0800 | −0.2793 | 0.7589 | 0.217* | |
H9C | −0.0775 | −0.2803 | 0.7668 | 0.217* | |
C10 | 0.6866 (8) | 0.5254 (9) | 0.5235 (9) | 0.069 (3) | |
C11 | 0.6678 (8) | 0.4616 (11) | 0.4324 (7) | 0.055 (3) | |
C12 | 0.6388 (8) | 0.3460 (10) | 0.4191 (7) | 0.061 (3) | |
H12 | 0.6335 | 0.3088 | 0.3584 | 0.073* | |
C13 | 0.6172 (7) | 0.2829 (9) | 0.4928 (5) | 0.049 (2) | |
C14 | 0.6326 (7) | 0.3426 (8) | 0.5866 (5) | 0.045 (2) | |
H14 | 0.6198 | 0.3010 | 0.6369 | 0.054* | |
C15 | 0.6665 (7) | 0.4618 (9) | 0.6051 (7) | 0.053 (2) | |
H15 | 0.6758 | 0.4988 | 0.6660 | 0.064* | |
C16 | 0.7256 (10) | 0.6494 (12) | 0.5466 (10) | 0.100 (4) | |
H16A | 0.8155 | 0.6808 | 0.5229 | 0.150* | |
H16B | 0.7294 | 0.6692 | 0.6134 | 0.150* | |
H16C | 0.6573 | 0.6792 | 0.5187 | 0.150* | |
C17 | 0.6960 (11) | 0.5261 (12) | 0.3475 (8) | 0.093 (4) | |
H17A | 0.7167 | 0.4777 | 0.2953 | 0.140* | |
H17B | 0.7741 | 0.5914 | 0.3622 | 0.140* | |
H17C | 0.6150 | 0.5496 | 0.3316 | 0.140* | |
C18 | 0.5893 (9) | 0.1576 (9) | 0.4761 (6) | 0.064 (3) | |
H18A | 0.4916 | 0.1234 | 0.4820 | 0.096* | |
H18B | 0.6427 | 0.1333 | 0.5214 | 0.096* | |
H18C | 0.6155 | 0.1352 | 0.4143 | 0.096* | |
C19 | 0.7873 (7) | 0.2514 (7) | 0.9430 (5) | 0.0368 (19) | |
C20 | 0.8349 (7) | 0.2710 (7) | 0.8499 (5) | 0.0337 (18) | |
C21 | 0.8107 (6) | 0.1786 (7) | 0.7789 (5) | 0.037 (2) | |
H21 | 0.8376 | 0.1918 | 0.7188 | 0.044* | |
C22 | 0.7463 (7) | 0.0642 (7) | 0.7951 (5) | 0.0327 (18) | |
C23 | 0.7037 (7) | 0.0466 (7) | 0.8850 (5) | 0.0348 (18) | |
H23 | 0.6620 | −0.0263 | 0.8980 | 0.042* | |
C24 | 0.7240 (7) | 0.1396 (7) | 0.9571 (5) | 0.0362 (18) | |
H24 | 0.6937 | 0.1256 | 1.0164 | 0.043* | |
C25 | 0.7993 (9) | 0.3469 (8) | 1.0198 (5) | 0.049 (2) | |
H25A | 0.7515 | 0.3186 | 1.0730 | 0.073* | |
H25B | 0.7580 | 0.4019 | 0.9985 | 0.073* | |
H25C | 0.8960 | 0.3816 | 1.0373 | 0.073* | |
C26 | 0.8995 (8) | 0.3874 (7) | 0.8277 (6) | 0.046 (2) | |
H26A | 0.9055 | 0.3860 | 0.7611 | 0.069* | |
H26B | 0.9914 | 0.4152 | 0.8571 | 0.069* | |
H26C | 0.8430 | 0.4362 | 0.8506 | 0.069* | |
C27 | 0.7201 (7) | −0.0280 (7) | 0.7158 (5) | 0.041 (2) | |
H27A | 0.7975 | −0.0609 | 0.7122 | 0.061* | |
H27B | 0.7095 | 0.0019 | 0.6586 | 0.061* | |
H27C | 0.6363 | −0.0848 | 0.7252 | 0.061* | |
C28 | 0.3694 (10) | 0.3691 (9) | 1.0527 (7) | 0.066 (3) | |
H28A | 0.4097 | 0.4496 | 1.0704 | 0.079* | |
H28B | 0.4222 | 0.3438 | 1.0023 | 0.079* | |
Cl1 | 0.36010 (19) | −0.14506 (18) | 0.79432 (13) | 0.0419 (5) | |
Cl2 | 0.39237 (17) | 0.10712 (17) | 0.91604 (12) | 0.0382 (5) | |
Cl3 | 0.46158 (16) | 0.09654 (17) | 0.70097 (12) | 0.0347 (4) | |
Cl4 | 0.54735 (19) | 0.34718 (18) | 0.83311 (13) | 0.0413 (5) | |
Cl5 | 1.01278 (17) | 0.5504 (2) | 0.60715 (13) | 0.0441 (5) | |
Cl6 | 0.92653 (19) | 0.2695 (2) | 0.55285 (14) | 0.0487 (5) | |
Cl7 | 0.3833 (4) | 0.2976 (3) | 1.1495 (3) | 0.1157 (13) | |
Cl8 | 0.1963 (3) | 0.3451 (3) | 1.0132 (2) | 0.0855 (9) | |
Ru1 | 0.25248 (6) | 0.00250 (6) | 0.77664 (4) | 0.0401 (2) | |
Ru2 | 0.61306 (5) | 0.17541 (5) | 0.84121 (4) | 0.02885 (17) | |
Ru3 | 0.81985 (6) | 0.41211 (6) | 0.51535 (4) | 0.0418 (2) |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.032 (4) | 0.053 (7) | 0.098 (8) | 0.025 (4) | −0.009 (4) | 0.004 (6) |
C2 | 0.035 (4) | 0.069 (8) | 0.064 (6) | 0.020 (4) | −0.002 (4) | 0.006 (6) |
C3 | 0.027 (4) | 0.091 (10) | 0.067 (6) | 0.020 (5) | −0.006 (4) | −0.017 (6) |
C4 | 0.030 (4) | 0.063 (8) | 0.084 (7) | 0.001 (4) | 0.009 (4) | 0.008 (6) |
C5 | 0.042 (5) | 0.065 (9) | 0.087 (7) | 0.022 (5) | 0.018 (4) | 0.004 (6) |
C6 | 0.037 (4) | 0.089 (10) | 0.077 (7) | 0.044 (5) | 0.012 (4) | 0.002 (6) |
C7 | 0.052 (6) | 0.091 (11) | 0.155 (11) | 0.031 (6) | −0.004 (6) | 0.067 (9) |
C8 | 0.059 (6) | 0.130 (12) | 0.075 (7) | 0.035 (6) | −0.012 (5) | 0.031 (7) |
C9 | 0.094 (10) | 0.19 (2) | 0.127 (13) | 0.012 (11) | 0.017 (9) | −0.006 (13) |
C10 | 0.024 (4) | 0.038 (7) | 0.152 (11) | 0.016 (4) | 0.018 (5) | 0.026 (7) |
C11 | 0.037 (4) | 0.081 (9) | 0.062 (6) | 0.034 (5) | 0.004 (4) | 0.021 (6) |
C12 | 0.031 (4) | 0.082 (9) | 0.071 (6) | 0.016 (5) | −0.008 (4) | 0.011 (6) |
C13 | 0.034 (4) | 0.068 (7) | 0.040 (4) | 0.005 (4) | 0.009 (3) | 0.004 (5) |
C14 | 0.031 (4) | 0.052 (7) | 0.050 (5) | 0.008 (4) | 0.017 (3) | 0.006 (4) |
C15 | 0.028 (4) | 0.059 (7) | 0.076 (6) | 0.015 (4) | 0.013 (4) | 0.009 (5) |
C16 | 0.045 (6) | 0.104 (12) | 0.161 (12) | 0.043 (7) | 0.011 (6) | 0.007 (9) |
C17 | 0.067 (6) | 0.130 (12) | 0.105 (9) | 0.043 (7) | 0.006 (6) | 0.064 (9) |
C18 | 0.057 (5) | 0.072 (9) | 0.052 (5) | 0.009 (5) | 0.003 (4) | −0.018 (5) |
C19 | 0.030 (3) | 0.039 (6) | 0.043 (4) | 0.011 (3) | −0.001 (3) | 0.007 (4) |
C20 | 0.032 (3) | 0.033 (5) | 0.038 (4) | 0.012 (3) | 0.000 (3) | 0.006 (4) |
C21 | 0.027 (3) | 0.054 (6) | 0.030 (4) | 0.016 (3) | 0.001 (3) | −0.003 (4) |
C22 | 0.031 (3) | 0.036 (5) | 0.039 (4) | 0.020 (3) | 0.006 (3) | 0.011 (4) |
C23 | 0.034 (4) | 0.031 (5) | 0.047 (4) | 0.021 (3) | −0.001 (3) | 0.006 (4) |
C24 | 0.041 (4) | 0.030 (5) | 0.040 (4) | 0.013 (3) | −0.001 (3) | 0.007 (4) |
C25 | 0.064 (5) | 0.039 (6) | 0.040 (4) | 0.014 (4) | −0.004 (4) | −0.006 (4) |
C26 | 0.043 (4) | 0.038 (6) | 0.057 (5) | 0.007 (4) | 0.007 (4) | 0.011 (4) |
C27 | 0.038 (4) | 0.037 (6) | 0.050 (5) | 0.019 (4) | 0.003 (3) | −0.002 (4) |
C28 | 0.081 (6) | 0.042 (7) | 0.078 (7) | 0.023 (5) | 0.035 (5) | 0.004 (5) |
Cl1 | 0.0482 (10) | 0.0348 (13) | 0.0452 (10) | 0.0159 (9) | 0.0099 (8) | 0.0039 (9) |
Cl2 | 0.0409 (9) | 0.0368 (13) | 0.0381 (10) | 0.0141 (8) | 0.0104 (7) | 0.0012 (9) |
Cl3 | 0.0338 (8) | 0.0376 (13) | 0.0346 (9) | 0.0133 (8) | 0.0004 (7) | 0.0036 (8) |
Cl4 | 0.0478 (10) | 0.0325 (13) | 0.0493 (11) | 0.0209 (9) | 0.0070 (8) | 0.0044 (9) |
Cl5 | 0.0343 (9) | 0.0623 (16) | 0.0385 (10) | 0.0144 (9) | 0.0077 (7) | 0.0137 (10) |
Cl6 | 0.0437 (10) | 0.0529 (16) | 0.0520 (12) | 0.0130 (9) | 0.0049 (8) | 0.0159 (11) |
Cl7 | 0.168 (4) | 0.087 (3) | 0.110 (3) | 0.059 (3) | −0.014 (2) | 0.029 (2) |
Cl8 | 0.104 (2) | 0.070 (2) | 0.096 (2) | 0.0490 (17) | 0.0157 (16) | 0.0076 (17) |
Ru1 | 0.0306 (3) | 0.0420 (5) | 0.0490 (4) | 0.0142 (3) | 0.0058 (2) | 0.0013 (3) |
Ru2 | 0.0323 (3) | 0.0260 (4) | 0.0312 (3) | 0.0133 (2) | 0.0042 (2) | 0.0026 (3) |
Ru3 | 0.0269 (3) | 0.0599 (6) | 0.0423 (4) | 0.0123 (3) | 0.0058 (2) | 0.0192 (3) |
C1—C2 | 1.429 (14) | C17—H17A | 0.9600 |
C1—C7 | 1.431 (14) | C17—H17B | 0.9600 |
C1—C6 | 1.444 (14) | C17—H17C | 0.9600 |
C1—Ru1 | 2.167 (9) | C18—H18A | 0.9600 |
C2—C3 | 1.432 (14) | C18—H18B | 0.9600 |
C2—C8 | 1.502 (13) | C18—H18C | 0.9600 |
C2—Ru1 | 2.174 (9) | C19—C24 | 1.401 (11) |
C3—C4 | 1.426 (14) | C19—C20 | 1.454 (10) |
C3—Ru1 | 2.165 (8) | C19—C25 | 1.494 (11) |
C3—H3 | 0.9300 | C19—Ru2 | 2.184 (7) |
C4—C5 | 1.386 (14) | C20—C21 | 1.403 (11) |
C4—C9 | 1.53 (2) | C20—C26 | 1.489 (11) |
C4—Ru1 | 2.161 (8) | C20—Ru2 | 2.203 (7) |
C5—C6 | 1.350 (14) | C21—C22 | 1.440 (11) |
C5—Ru1 | 2.198 (8) | C21—Ru2 | 2.162 (6) |
C5—H5 | 0.9300 | C21—H21 | 0.9300 |
C6—Ru1 | 2.136 (8) | C22—C23 | 1.391 (10) |
C6—H6 | 0.9300 | C22—C27 | 1.478 (11) |
C7—H7A | 0.9600 | C22—Ru2 | 2.201 (7) |
C7—H7B | 0.9600 | C23—C24 | 1.421 (11) |
C7—H7C | 0.9600 | C23—Ru2 | 2.178 (7) |
C8—H8A | 0.9600 | C23—H23 | 0.9300 |
C8—H8B | 0.9600 | C24—Ru2 | 2.144 (7) |
C8—H8C | 0.9600 | C24—H24 | 0.9300 |
C9—H9A | 0.9600 | C25—H25A | 0.9600 |
C9—H9B | 0.9600 | C25—H25B | 0.9600 |
C9—H9C | 0.9600 | C25—H25C | 0.9600 |
C10—C11 | 1.429 (15) | C26—H26A | 0.9600 |
C10—C16 | 1.473 (16) | C26—H26B | 0.9600 |
C10—C15 | 1.480 (14) | C26—H26C | 0.9600 |
C10—Ru3 | 2.163 (9) | C27—H27A | 0.9600 |
C11—C12 | 1.371 (14) | C27—H27B | 0.9600 |
C11—C17 | 1.530 (13) | C27—H27C | 0.9600 |
C11—Ru3 | 2.173 (8) | C28—Cl8 | 1.744 (10) |
C12—C13 | 1.380 (13) | C28—Cl7 | 1.763 (10) |
C12—Ru3 | 2.171 (8) | C28—H28A | 0.9700 |
C12—H12 | 0.9300 | C28—H28B | 0.9700 |
C13—C14 | 1.443 (11) | Cl1—Ru1 | 2.384 (2) |
C13—C18 | 1.489 (14) | Cl2—Ru1 | 2.446 (2) |
C13—Ru3 | 2.206 (8) | Cl2—Ru2 | 2.4461 (17) |
C14—C15 | 1.413 (12) | Cl3—Ru1 | 2.4380 (17) |
C14—Ru3 | 2.161 (7) | Cl3—Ru2 | 2.4423 (18) |
C14—H14 | 0.9300 | Cl4—Ru2 | 2.398 (2) |
C15—Ru3 | 2.171 (8) | Cl5—Ru3i | 2.4404 (18) |
C15—H15 | 0.9300 | Cl5—Ru3 | 2.449 (2) |
C16—H16A | 0.9600 | Cl6—Ru3 | 2.396 (2) |
C16—H16B | 0.9600 | Ru3—Cl5i | 2.4404 (18) |
C16—H16C | 0.9600 | ||
C2—C1—C7 | 121.0 (11) | C23—C24—Ru2 | 72.1 (4) |
C2—C1—C6 | 117.9 (10) | C19—C24—H24 | 118.5 |
C7—C1—C6 | 120.9 (11) | C23—C24—H24 | 118.5 |
C2—C1—Ru1 | 71.0 (5) | Ru2—C24—H24 | 129.4 |
C7—C1—Ru1 | 126.8 (6) | C19—C25—H25A | 109.5 |
C6—C1—Ru1 | 69.2 (5) | C19—C25—H25B | 109.5 |
C1—C2—C3 | 117.5 (9) | H25A—C25—H25B | 109.5 |
C1—C2—C8 | 123.2 (10) | C19—C25—H25C | 109.5 |
C3—C2—C8 | 119.3 (10) | H25A—C25—H25C | 109.5 |
C1—C2—Ru1 | 70.5 (5) | H25B—C25—H25C | 109.5 |
C3—C2—Ru1 | 70.4 (5) | C20—C26—H26A | 109.5 |
C8—C2—Ru1 | 129.5 (6) | C20—C26—H26B | 109.5 |
C4—C3—C2 | 120.4 (9) | H26A—C26—H26B | 109.5 |
C4—C3—Ru1 | 70.6 (5) | C20—C26—H26C | 109.5 |
C2—C3—Ru1 | 71.1 (5) | H26A—C26—H26C | 109.5 |
C4—C3—H3 | 119.8 | H26B—C26—H26C | 109.5 |
C2—C3—H3 | 119.8 | C22—C27—H27A | 109.5 |
Ru1—C3—H3 | 131.3 | C22—C27—H27B | 109.5 |
C5—C4—C3 | 121.9 (11) | H27A—C27—H27B | 109.5 |
C5—C4—C9 | 112.6 (11) | C22—C27—H27C | 109.5 |
C3—C4—C9 | 125.4 (11) | H27A—C27—H27C | 109.5 |
C5—C4—Ru1 | 72.9 (5) | H27B—C27—H27C | 109.5 |
C3—C4—Ru1 | 70.9 (5) | Cl8—C28—Cl7 | 111.9 (5) |
C9—C4—Ru1 | 127.1 (8) | Cl8—C28—H28A | 109.2 |
C6—C5—C4 | 117.6 (10) | Cl7—C28—H28A | 109.2 |
C6—C5—Ru1 | 69.4 (5) | Cl8—C28—H28B | 109.2 |
C4—C5—Ru1 | 70.0 (5) | Cl7—C28—H28B | 109.2 |
C6—C5—H5 | 121.2 | H28A—C28—H28B | 107.9 |
C4—C5—H5 | 121.2 | Ru1—Cl2—Ru2 | 98.13 (6) |
Ru1—C5—H5 | 132.0 | Ru1—Cl3—Ru2 | 98.44 (6) |
C5—C6—C1 | 124.7 (10) | Ru3i—Cl5—Ru3 | 99.36 (7) |
C5—C6—Ru1 | 74.3 (6) | C6—Ru1—C4 | 66.0 (4) |
C1—C6—Ru1 | 71.6 (5) | C6—Ru1—C3 | 80.0 (4) |
C5—C6—H6 | 117.7 | C4—Ru1—C3 | 38.5 (4) |
C1—C6—H6 | 117.7 | C6—Ru1—C1 | 39.2 (4) |
Ru1—C6—H6 | 129.1 | C4—Ru1—C1 | 81.1 (4) |
C1—C7—H7A | 109.5 | C3—Ru1—C1 | 68.7 (4) |
C1—C7—H7B | 109.5 | C6—Ru1—C2 | 69.6 (4) |
H7A—C7—H7B | 109.5 | C4—Ru1—C2 | 69.8 (4) |
C1—C7—H7C | 109.5 | C3—Ru1—C2 | 38.5 (4) |
H7A—C7—H7C | 109.5 | C1—Ru1—C2 | 38.4 (4) |
H7B—C7—H7C | 109.5 | C6—Ru1—C5 | 36.3 (4) |
C2—C8—H8A | 109.5 | C4—Ru1—C5 | 37.1 (4) |
C2—C8—H8B | 109.5 | C3—Ru1—C5 | 68.6 (4) |
H8A—C8—H8B | 109.5 | C1—Ru1—C5 | 69.1 (4) |
C2—C8—H8C | 109.5 | C2—Ru1—C5 | 82.6 (4) |
H8A—C8—H8C | 109.5 | C6—Ru1—Cl1 | 141.4 (3) |
H8B—C8—H8C | 109.5 | C4—Ru1—Cl1 | 89.4 (3) |
C4—C9—H9A | 109.5 | C3—Ru1—Cl1 | 99.4 (3) |
C4—C9—H9B | 109.5 | C1—Ru1—Cl1 | 168.1 (3) |
H9A—C9—H9B | 109.5 | C2—Ru1—Cl1 | 131.1 (3) |
C4—C9—H9C | 109.5 | C5—Ru1—Cl1 | 107.2 (3) |
H9A—C9—H9C | 109.5 | C6—Ru1—Cl3 | 128.8 (3) |
H9B—C9—H9C | 109.5 | C4—Ru1—Cl3 | 148.2 (3) |
C11—C10—C16 | 127.3 (11) | C3—Ru1—Cl3 | 111.0 (3) |
C11—C10—C15 | 117.5 (9) | C1—Ru1—Cl3 | 96.4 (3) |
C16—C10—C15 | 115.2 (12) | C2—Ru1—Cl3 | 88.5 (2) |
C11—C10—Ru3 | 71.1 (5) | C5—Ru1—Cl3 | 164.9 (3) |
C16—C10—Ru3 | 128.8 (6) | Cl1—Ru1—Cl3 | 87.82 (7) |
C15—C10—Ru3 | 70.3 (5) | C6—Ru1—Cl2 | 87.6 (3) |
C12—C11—C10 | 122.3 (9) | C4—Ru1—Cl2 | 130.3 (3) |
C12—C11—C17 | 119.2 (10) | C3—Ru1—Cl2 | 166.4 (2) |
C10—C11—C17 | 118.2 (11) | C1—Ru1—Cl2 | 104.8 (3) |
C12—C11—Ru3 | 71.5 (5) | C2—Ru1—Cl2 | 140.5 (3) |
C10—C11—Ru3 | 70.4 (5) | C5—Ru1—Cl2 | 98.1 (3) |
C17—C11—Ru3 | 126.8 (6) | Cl1—Ru1—Cl2 | 86.79 (7) |
C11—C12—C13 | 122.2 (10) | Cl3—Ru1—Cl2 | 81.11 (6) |
C11—C12—Ru3 | 71.7 (5) | C24—Ru2—C21 | 80.2 (3) |
C13—C12—Ru3 | 73.0 (5) | C24—Ru2—C23 | 38.4 (3) |
C11—C12—H12 | 118.9 | C21—Ru2—C23 | 67.8 (3) |
C13—C12—H12 | 118.9 | C24—Ru2—C19 | 37.8 (3) |
Ru3—C12—H12 | 128.8 | C21—Ru2—C19 | 68.9 (3) |
C12—C13—C14 | 118.0 (10) | C23—Ru2—C19 | 69.3 (3) |
C12—C13—C18 | 120.8 (9) | C24—Ru2—C22 | 68.3 (3) |
C14—C13—C18 | 121.1 (8) | C21—Ru2—C22 | 38.5 (3) |
C12—C13—Ru3 | 70.2 (5) | C23—Ru2—C22 | 37.0 (3) |
C14—C13—Ru3 | 69.0 (4) | C19—Ru2—C22 | 82.3 (3) |
C18—C13—Ru3 | 128.7 (6) | C24—Ru2—C20 | 68.2 (3) |
C15—C14—C13 | 122.5 (8) | C21—Ru2—C20 | 37.5 (3) |
C15—C14—Ru3 | 71.3 (4) | C23—Ru2—C20 | 81.0 (3) |
C13—C14—Ru3 | 72.4 (4) | C19—Ru2—C20 | 38.7 (3) |
C15—C14—H14 | 118.7 | C22—Ru2—C20 | 69.1 (3) |
C13—C14—H14 | 118.7 | C24—Ru2—Cl4 | 125.5 (2) |
Ru3—C14—H14 | 130.3 | C21—Ru2—Cl4 | 112.2 (2) |
C14—C15—C10 | 117.4 (9) | C23—Ru2—Cl4 | 163.7 (2) |
C14—C15—Ru3 | 70.6 (5) | C19—Ru2—Cl4 | 95.2 (2) |
C10—C15—Ru3 | 69.7 (5) | C22—Ru2—Cl4 | 149.38 (19) |
C14—C15—H15 | 121.3 | C20—Ru2—Cl4 | 89.9 (2) |
C10—C15—H15 | 121.3 | C24—Ru2—Cl3 | 146.1 (2) |
Ru3—C15—H15 | 130.8 | C21—Ru2—Cl3 | 97.95 (19) |
C10—C16—H16A | 109.5 | C23—Ru2—Cl3 | 109.4 (2) |
C10—C16—H16B | 109.5 | C19—Ru2—Cl3 | 166.50 (19) |
H16A—C16—H16B | 109.5 | C22—Ru2—Cl3 | 89.15 (19) |
C10—C16—H16C | 109.5 | C20—Ru2—Cl3 | 128.14 (19) |
H16A—C16—H16C | 109.5 | Cl4—Ru2—Cl3 | 86.82 (7) |
H16B—C16—H16C | 109.5 | C24—Ru2—Cl2 | 89.9 (2) |
C11—C17—H17A | 109.5 | C21—Ru2—Cl2 | 160.7 (2) |
C11—C17—H17B | 109.5 | C23—Ru2—Cl2 | 94.23 (19) |
H17A—C17—H17B | 109.5 | C19—Ru2—Cl2 | 112.40 (19) |
C11—C17—H17C | 109.5 | C22—Ru2—Cl2 | 122.3 (2) |
H17A—C17—H17C | 109.5 | C20—Ru2—Cl2 | 150.5 (2) |
H17B—C17—H17C | 109.5 | Cl4—Ru2—Cl2 | 86.97 (7) |
C13—C18—H18A | 109.5 | Cl3—Ru2—Cl2 | 81.01 (6) |
C13—C18—H18B | 109.5 | C14—Ru3—C10 | 69.7 (3) |
H18A—C18—H18B | 109.5 | C14—Ru3—C12 | 67.9 (3) |
C13—C18—H18C | 109.5 | C10—Ru3—C12 | 68.9 (4) |
H18A—C18—H18C | 109.5 | C14—Ru3—C15 | 38.1 (3) |
H18B—C18—H18C | 109.5 | C10—Ru3—C15 | 39.9 (4) |
C24—C19—C20 | 117.4 (7) | C12—Ru3—C15 | 82.1 (4) |
C24—C19—C25 | 121.0 (7) | C14—Ru3—C11 | 80.1 (3) |
C20—C19—C25 | 121.6 (7) | C10—Ru3—C11 | 38.5 (4) |
C24—C19—Ru2 | 69.5 (4) | C12—Ru3—C11 | 36.8 (4) |
C20—C19—Ru2 | 71.3 (4) | C15—Ru3—C11 | 69.9 (3) |
C25—C19—Ru2 | 127.8 (5) | C14—Ru3—C13 | 38.6 (3) |
C21—C20—C19 | 118.8 (7) | C10—Ru3—C13 | 82.1 (4) |
C21—C20—C26 | 120.0 (7) | C12—Ru3—C13 | 36.7 (3) |
C19—C20—C26 | 121.1 (7) | C15—Ru3—C13 | 69.8 (3) |
C21—C20—Ru2 | 69.7 (4) | C11—Ru3—C13 | 66.7 (4) |
C19—C20—Ru2 | 70.0 (4) | C14—Ru3—Cl6 | 92.7 (3) |
C26—C20—Ru2 | 129.0 (5) | C10—Ru3—Cl6 | 160.5 (3) |
C20—C21—C22 | 122.9 (7) | C12—Ru3—Cl6 | 113.1 (3) |
C20—C21—Ru2 | 72.8 (4) | C15—Ru3—Cl6 | 120.6 (3) |
C22—C21—Ru2 | 72.2 (4) | C11—Ru3—Cl6 | 149.5 (3) |
C20—C21—H21 | 118.6 | C13—Ru3—Cl6 | 89.3 (3) |
C22—C21—H21 | 118.6 | C14—Ru3—Cl5i | 161.5 (2) |
Ru2—C21—H21 | 128.9 | C10—Ru3—Cl5i | 111.6 (3) |
C23—C22—C21 | 117.6 (7) | C12—Ru3—Cl5i | 94.9 (3) |
C23—C22—C27 | 122.8 (7) | C15—Ru3—Cl5i | 150.4 (3) |
C21—C22—C27 | 119.5 (6) | C11—Ru3—Cl5i | 90.1 (2) |
C23—C22—Ru2 | 70.6 (4) | C13—Ru3—Cl5i | 123.0 (2) |
C21—C22—Ru2 | 69.3 (4) | Cl6—Ru3—Cl5i | 87.71 (7) |
C27—C22—Ru2 | 128.3 (5) | C14—Ru3—Cl5 | 117.9 (2) |
C22—C23—C24 | 120.2 (7) | C10—Ru3—Cl5 | 93.6 (3) |
C22—C23—Ru2 | 72.4 (4) | C12—Ru3—Cl5 | 159.2 (3) |
C24—C23—Ru2 | 69.5 (4) | C15—Ru3—Cl5 | 91.8 (2) |
C22—C23—H23 | 119.9 | C11—Ru3—Cl5 | 122.5 (3) |
C24—C23—H23 | 119.9 | C13—Ru3—Cl5 | 155.9 (2) |
Ru2—C23—H23 | 130.9 | Cl6—Ru3—Cl5 | 87.15 (7) |
C19—C24—C23 | 123.1 (7) | Cl5i—Ru3—Cl5 | 80.64 (7) |
C19—C24—Ru2 | 72.7 (4) | ||
C7—C1—C2—C3 | 176.3 (7) | C19—C24—Ru2—Cl2 | −128.6 (4) |
C6—C1—C2—C3 | 1.4 (10) | C23—C24—Ru2—Cl2 | 96.9 (4) |
Ru1—C1—C2—C3 | 54.1 (6) | C20—C21—Ru2—C24 | −66.9 (5) |
C7—C1—C2—C8 | −2.9 (12) | C22—C21—Ru2—C24 | 67.2 (4) |
C6—C1—C2—C8 | −177.8 (7) | C20—C21—Ru2—C23 | −104.8 (5) |
Ru1—C1—C2—C8 | −125.1 (8) | C22—C21—Ru2—C23 | 29.3 (4) |
C7—C1—C2—Ru1 | 122.2 (8) | C20—C21—Ru2—C19 | −29.4 (4) |
C6—C1—C2—Ru1 | −52.7 (6) | C22—C21—Ru2—C19 | 104.7 (5) |
C1—C2—C3—C4 | −1.7 (11) | C20—C21—Ru2—C22 | −134.1 (6) |
C8—C2—C3—C4 | 177.6 (7) | C22—C21—Ru2—C20 | 134.1 (6) |
Ru1—C2—C3—C4 | 52.6 (7) | C20—C21—Ru2—Cl4 | 57.6 (4) |
C1—C2—C3—Ru1 | −54.2 (6) | C22—C21—Ru2—Cl4 | −168.3 (3) |
C8—C2—C3—Ru1 | 125.0 (7) | C20—C21—Ru2—Cl3 | 147.4 (4) |
C2—C3—C4—C5 | 1.6 (12) | C22—C21—Ru2—Cl3 | −78.5 (4) |
Ru1—C3—C4—C5 | 54.4 (7) | C20—C21—Ru2—Cl2 | −127.1 (6) |
C2—C3—C4—C9 | −175.3 (9) | C22—C21—Ru2—Cl2 | 7.0 (8) |
Ru1—C3—C4—C9 | −122.5 (10) | C22—C23—Ru2—C24 | −133.1 (6) |
C2—C3—C4—Ru1 | −52.8 (7) | C22—C23—Ru2—C21 | −30.4 (4) |
C3—C4—C5—C6 | −1.3 (12) | C24—C23—Ru2—C21 | 102.7 (5) |
C9—C4—C5—C6 | 176.0 (9) | C22—C23—Ru2—C19 | −105.2 (5) |
Ru1—C4—C5—C6 | 52.2 (7) | C24—C23—Ru2—C19 | 27.8 (4) |
C3—C4—C5—Ru1 | −53.5 (7) | C24—C23—Ru2—C22 | 133.1 (6) |
C9—C4—C5—Ru1 | 123.8 (9) | C22—C23—Ru2—C20 | −67.0 (4) |
C4—C5—C6—C1 | 1.1 (13) | C24—C23—Ru2—C20 | 66.1 (4) |
Ru1—C5—C6—C1 | 53.6 (7) | C22—C23—Ru2—Cl4 | −123.9 (6) |
C4—C5—C6—Ru1 | −52.5 (7) | C24—C23—Ru2—Cl4 | 9.1 (9) |
C2—C1—C6—C5 | −1.2 (12) | C22—C23—Ru2—Cl3 | 60.4 (4) |
C7—C1—C6—C5 | −176.1 (8) | C24—C23—Ru2—Cl3 | −166.5 (4) |
Ru1—C1—C6—C5 | −54.8 (8) | C22—C23—Ru2—Cl2 | 142.4 (4) |
C2—C1—C6—Ru1 | 53.6 (6) | C24—C23—Ru2—Cl2 | −84.6 (4) |
C7—C1—C6—Ru1 | −121.3 (8) | C20—C19—Ru2—C24 | 130.1 (7) |
C16—C10—C11—C12 | 176.3 (8) | C25—C19—Ru2—C24 | −113.9 (8) |
C15—C10—C11—C12 | −3.1 (11) | C24—C19—Ru2—C21 | −101.6 (5) |
Ru3—C10—C11—C12 | 51.5 (7) | C20—C19—Ru2—C21 | 28.5 (5) |
C16—C10—C11—C17 | 2.8 (12) | C25—C19—Ru2—C21 | 144.5 (8) |
C15—C10—C11—C17 | −176.6 (7) | C24—C19—Ru2—C23 | −28.2 (4) |
Ru3—C10—C11—C17 | −122.1 (7) | C20—C19—Ru2—C23 | 101.8 (5) |
C16—C10—C11—Ru3 | 124.8 (8) | C25—C19—Ru2—C23 | −142.2 (7) |
C15—C10—C11—Ru3 | −54.6 (6) | C24—C19—Ru2—C22 | −64.1 (5) |
C10—C11—C12—C13 | 4.2 (12) | C20—C19—Ru2—C22 | 65.9 (5) |
C17—C11—C12—C13 | 177.6 (7) | C25—C19—Ru2—C22 | −178.1 (7) |
Ru3—C11—C12—C13 | 55.1 (7) | C24—C19—Ru2—C20 | −130.1 (7) |
C10—C11—C12—Ru3 | −51.0 (7) | C25—C19—Ru2—C20 | 116.0 (9) |
C17—C11—C12—Ru3 | 122.5 (7) | C24—C19—Ru2—Cl4 | 146.6 (4) |
C11—C12—C13—C14 | −3.0 (11) | C20—C19—Ru2—Cl4 | −83.3 (4) |
Ru3—C12—C13—C14 | 51.5 (6) | C25—C19—Ru2—Cl4 | 32.6 (7) |
C11—C12—C13—C18 | −178.5 (8) | C24—C19—Ru2—Cl3 | −115.4 (9) |
Ru3—C12—C13—C18 | −124.0 (7) | C20—C19—Ru2—Cl3 | 14.7 (12) |
C11—C12—C13—Ru3 | −54.5 (7) | C25—C19—Ru2—Cl3 | 130.7 (8) |
C12—C13—C14—C15 | 1.0 (11) | C24—C19—Ru2—Cl2 | 57.7 (5) |
C18—C13—C14—C15 | 176.6 (7) | C20—C19—Ru2—Cl2 | −172.2 (4) |
Ru3—C13—C14—C15 | 53.1 (6) | C25—C19—Ru2—Cl2 | −56.2 (7) |
C12—C13—C14—Ru3 | −52.1 (6) | C23—C22—Ru2—C24 | 29.2 (4) |
C18—C13—C14—Ru3 | 123.4 (7) | C21—C22—Ru2—C24 | −102.0 (4) |
C13—C14—C15—C10 | −0.2 (10) | C27—C22—Ru2—C24 | 146.2 (7) |
Ru3—C14—C15—C10 | 53.4 (6) | C23—C22—Ru2—C21 | 131.2 (6) |
C13—C14—C15—Ru3 | −53.6 (6) | C27—C22—Ru2—C21 | −111.9 (8) |
C11—C10—C15—C14 | 1.1 (10) | C21—C22—Ru2—C23 | −131.2 (6) |
C16—C10—C15—C14 | −178.4 (7) | C27—C22—Ru2—C23 | 116.9 (8) |
Ru3—C10—C15—C14 | −53.8 (6) | C23—C22—Ru2—C19 | 65.6 (5) |
C11—C10—C15—Ru3 | 55.0 (6) | C21—C22—Ru2—C19 | −65.6 (4) |
C16—C10—C15—Ru3 | −124.5 (7) | C27—C22—Ru2—C19 | −177.5 (7) |
C24—C19—C20—C21 | 2.3 (9) | C23—C22—Ru2—C20 | 103.3 (5) |
C25—C19—C20—C21 | −175.0 (7) | C21—C22—Ru2—C20 | −27.9 (4) |
Ru2—C19—C20—C21 | −51.5 (6) | C27—C22—Ru2—C20 | −139.8 (7) |
C24—C19—C20—C26 | 178.1 (7) | C23—C22—Ru2—Cl4 | 152.8 (4) |
C25—C19—C20—C26 | 0.7 (10) | C21—C22—Ru2—Cl4 | 21.6 (6) |
Ru2—C19—C20—C26 | 124.3 (7) | C27—C22—Ru2—Cl4 | −90.3 (7) |
C24—C19—C20—Ru2 | 53.8 (6) | C23—C22—Ru2—Cl3 | −124.9 (4) |
C25—C19—C20—Ru2 | −123.5 (7) | C21—C22—Ru2—Cl3 | 103.9 (4) |
C19—C20—C21—C22 | −2.9 (10) | C27—C22—Ru2—Cl3 | −7.9 (6) |
C26—C20—C21—C22 | −178.7 (6) | C23—C22—Ru2—Cl2 | −46.1 (5) |
Ru2—C20—C21—C22 | −54.5 (6) | C21—C22—Ru2—Cl2 | −177.3 (3) |
C19—C20—C21—Ru2 | 51.6 (6) | C27—C22—Ru2—Cl2 | 70.9 (7) |
C26—C20—C21—Ru2 | −124.2 (6) | C21—C20—Ru2—C24 | 102.7 (5) |
C20—C21—C22—C23 | 1.6 (10) | C19—C20—Ru2—C24 | −30.3 (5) |
Ru2—C21—C22—C23 | −53.2 (5) | C26—C20—Ru2—C24 | −144.6 (8) |
C20—C21—C22—C27 | 177.9 (6) | C19—C20—Ru2—C21 | −133.0 (7) |
Ru2—C21—C22—C27 | 123.1 (6) | C26—C20—Ru2—C21 | 112.7 (8) |
C20—C21—C22—Ru2 | 54.8 (6) | C21—C20—Ru2—C23 | 65.0 (5) |
C21—C22—C23—C24 | 0.2 (9) | C19—C20—Ru2—C23 | −68.0 (5) |
C27—C22—C23—C24 | −176.0 (6) | C26—C20—Ru2—C23 | 177.7 (7) |
Ru2—C22—C23—C24 | −52.4 (6) | C21—C20—Ru2—C19 | 133.0 (7) |
C21—C22—C23—Ru2 | 52.6 (5) | C26—C20—Ru2—C19 | −114.3 (9) |
C27—C22—C23—Ru2 | −123.6 (6) | C21—C20—Ru2—C22 | 28.6 (4) |
C20—C19—C24—C23 | −0.6 (10) | C19—C20—Ru2—C22 | −104.4 (5) |
C25—C19—C24—C23 | 176.7 (7) | C26—C20—Ru2—C22 | 141.3 (7) |
Ru2—C19—C24—C23 | 54.1 (6) | C21—C20—Ru2—Cl4 | −128.6 (4) |
C20—C19—C24—Ru2 | −54.7 (5) | C19—C20—Ru2—Cl4 | 98.4 (4) |
C25—C19—C24—Ru2 | 122.6 (7) | C26—C20—Ru2—Cl4 | −15.9 (7) |
C22—C23—C24—C19 | −0.6 (10) | C21—C20—Ru2—Cl3 | −42.7 (5) |
Ru2—C23—C24—C19 | −54.3 (6) | C19—C20—Ru2—Cl3 | −175.7 (4) |
C22—C23—C24—Ru2 | 53.7 (6) | C26—C20—Ru2—Cl3 | 70.0 (8) |
C5—C6—Ru1—C4 | 29.6 (6) | C21—C20—Ru2—Cl2 | 147.7 (4) |
C1—C6—Ru1—C4 | −106.1 (7) | C19—C20—Ru2—Cl2 | 14.7 (7) |
C5—C6—Ru1—C3 | 67.3 (7) | C26—C20—Ru2—Cl2 | −99.6 (7) |
C1—C6—Ru1—C3 | −68.5 (6) | Ru1—Cl3—Ru2—C24 | 67.6 (4) |
C5—C6—Ru1—C1 | 135.7 (9) | Ru1—Cl3—Ru2—C21 | 151.8 (2) |
C5—C6—Ru1—C2 | 105.8 (7) | Ru1—Cl3—Ru2—C23 | 82.6 (2) |
C1—C6—Ru1—C2 | −29.9 (6) | Ru1—Cl3—Ru2—C19 | 164.8 (10) |
C1—C6—Ru1—C5 | −135.7 (9) | Ru1—Cl3—Ru2—C22 | 114.2 (2) |
C5—C6—Ru1—Cl1 | −25.3 (9) | Ru1—Cl3—Ru2—C20 | 176.5 (3) |
C1—C6—Ru1—Cl1 | −161.0 (4) | Ru1—Cl3—Ru2—Cl4 | −96.15 (7) |
C5—C6—Ru1—Cl3 | 176.3 (5) | Ru1—Cl3—Ru2—Cl2 | −8.72 (7) |
C1—C6—Ru1—Cl3 | 40.6 (7) | Ru1—Cl2—Ru2—C24 | −138.5 (2) |
C5—C6—Ru1—Cl2 | −107.1 (6) | Ru1—Cl2—Ru2—C21 | −79.7 (6) |
C1—C6—Ru1—Cl2 | 117.2 (6) | Ru1—Cl2—Ru2—C23 | −100.3 (2) |
C5—C4—Ru1—C6 | −29.0 (6) | Ru1—Cl2—Ru2—C19 | −169.7 (2) |
C3—C4—Ru1—C6 | 104.8 (7) | Ru1—Cl2—Ru2—C22 | −74.5 (2) |
C9—C4—Ru1—C6 | −134.8 (12) | Ru1—Cl2—Ru2—C20 | −179.6 (4) |
C5—C4—Ru1—C3 | −133.8 (10) | Ru1—Cl2—Ru2—Cl4 | 95.95 (8) |
C9—C4—Ru1—C3 | 120.4 (13) | Ru1—Cl2—Ru2—Cl3 | 8.69 (7) |
C5—C4—Ru1—C1 | −66.9 (7) | C15—C14—Ru3—C10 | −31.3 (6) |
C3—C4—Ru1—C1 | 66.9 (6) | C13—C14—Ru3—C10 | 103.3 (6) |
C9—C4—Ru1—C1 | −172.7 (12) | C15—C14—Ru3—C12 | −106.1 (6) |
C5—C4—Ru1—C2 | −105.0 (7) | C13—C14—Ru3—C12 | 28.6 (6) |
C3—C4—Ru1—C2 | 28.8 (6) | C13—C14—Ru3—C15 | 134.6 (8) |
C9—C4—Ru1—C2 | 149.2 (12) | C15—C14—Ru3—C11 | −69.8 (6) |
C3—C4—Ru1—C5 | 133.8 (10) | C13—C14—Ru3—C11 | 64.8 (6) |
C9—C4—Ru1—C5 | −105.8 (13) | C15—C14—Ru3—C13 | −134.6 (8) |
C5—C4—Ru1—Cl1 | 120.3 (6) | C15—C14—Ru3—Cl6 | 140.0 (5) |
C3—C4—Ru1—Cl1 | −105.9 (6) | C13—C14—Ru3—Cl6 | −85.4 (5) |
C9—C4—Ru1—Cl1 | 14.5 (11) | C15—C14—Ru3—Cl5i | −129.0 (7) |
C5—C4—Ru1—Cl3 | −154.7 (6) | C13—C14—Ru3—Cl5i | 5.6 (12) |
C3—C4—Ru1—Cl3 | −21.0 (10) | C15—C14—Ru3—Cl5 | 51.8 (6) |
C9—C4—Ru1—Cl3 | 99.4 (11) | C13—C14—Ru3—Cl5 | −173.6 (5) |
C5—C4—Ru1—Cl2 | 35.0 (8) | C11—C10—Ru3—C14 | −99.9 (6) |
C3—C4—Ru1—Cl2 | 168.8 (5) | C16—C10—Ru3—C14 | 137.0 (13) |
C9—C4—Ru1—Cl2 | −70.8 (12) | C15—C10—Ru3—C14 | 30.0 (5) |
C4—C3—Ru1—C6 | −63.7 (6) | C11—C10—Ru3—C12 | −26.6 (5) |
C2—C3—Ru1—C6 | 69.7 (6) | C16—C10—Ru3—C12 | −149.7 (13) |
C2—C3—Ru1—C4 | 133.4 (8) | C15—C10—Ru3—C12 | 103.3 (6) |
C4—C3—Ru1—C1 | −102.9 (7) | C11—C10—Ru3—C15 | −129.9 (8) |
C2—C3—Ru1—C1 | 30.6 (5) | C16—C10—Ru3—C15 | 107.0 (15) |
C4—C3—Ru1—C2 | −133.4 (8) | C16—C10—Ru3—C11 | −123.1 (14) |
C4—C3—Ru1—C5 | −27.9 (6) | C15—C10—Ru3—C11 | 129.9 (8) |
C2—C3—Ru1—C5 | 105.6 (6) | C11—C10—Ru3—C13 | −62.1 (6) |
C4—C3—Ru1—Cl1 | 77.1 (6) | C16—C10—Ru3—C13 | 174.8 (13) |
C2—C3—Ru1—Cl1 | −149.5 (5) | C15—C10—Ru3—C13 | 67.8 (5) |
C4—C3—Ru1—Cl3 | 168.3 (5) | C11—C10—Ru3—Cl6 | −126.6 (9) |
C2—C3—Ru1—Cl3 | −58.2 (5) | C16—C10—Ru3—Cl6 | 110.3 (11) |
C4—C3—Ru1—Cl2 | −39.2 (17) | C15—C10—Ru3—Cl6 | 3.3 (13) |
C2—C3—Ru1—Cl2 | 94.3 (14) | C11—C10—Ru3—Cl5i | 60.3 (6) |
C2—C1—Ru1—C6 | −131.2 (8) | C16—C10—Ru3—Cl5i | −62.8 (13) |
C7—C1—Ru1—C6 | 113.7 (13) | C15—C10—Ru3—Cl5i | −169.8 (5) |
C2—C1—Ru1—C4 | −68.6 (6) | C11—C10—Ru3—Cl5 | 141.7 (5) |
C7—C1—Ru1—C4 | 176.4 (12) | C16—C10—Ru3—Cl5 | 18.6 (12) |
C6—C1—Ru1—C4 | 62.7 (6) | C15—C10—Ru3—Cl5 | −88.4 (5) |
C2—C1—Ru1—C3 | −30.7 (5) | C11—C12—Ru3—C14 | 103.5 (6) |
C7—C1—Ru1—C3 | −145.7 (12) | C13—C12—Ru3—C14 | −29.9 (6) |
C6—C1—Ru1—C3 | 100.6 (7) | C11—C12—Ru3—C10 | 27.7 (5) |
C7—C1—Ru1—C2 | −115.1 (13) | C13—C12—Ru3—C10 | −105.7 (7) |
C6—C1—Ru1—C2 | 131.2 (8) | C11—C12—Ru3—C15 | 66.8 (6) |
C2—C1—Ru1—C5 | −105.0 (6) | C13—C12—Ru3—C15 | −66.6 (6) |
C7—C1—Ru1—C5 | 139.9 (12) | C13—C12—Ru3—C11 | −133.4 (9) |
C6—C1—Ru1—C5 | 26.3 (6) | C11—C12—Ru3—C13 | 133.4 (9) |
C2—C1—Ru1—Cl1 | −31.0 (17) | C11—C12—Ru3—Cl6 | −173.2 (5) |
C7—C1—Ru1—Cl1 | −146.1 (10) | C13—C12—Ru3—Cl6 | 53.4 (6) |
C6—C1—Ru1—Cl1 | 100.2 (15) | C11—C12—Ru3—Cl5i | −83.6 (5) |
C2—C1—Ru1—Cl3 | 79.4 (5) | C13—C12—Ru3—Cl5i | 143.0 (6) |
C7—C1—Ru1—Cl3 | −35.6 (11) | C11—C12—Ru3—Cl5 | −7.0 (11) |
C6—C1—Ru1—Cl3 | −149.3 (6) | C13—C12—Ru3—Cl5 | −140.5 (6) |
C2—C1—Ru1—Cl2 | 161.9 (5) | C10—C15—Ru3—C14 | −130.5 (8) |
C7—C1—Ru1—Cl2 | 46.8 (11) | C14—C15—Ru3—C10 | 130.5 (8) |
C6—C1—Ru1—Cl2 | −66.9 (6) | C14—C15—Ru3—C12 | 64.0 (6) |
C1—C2—Ru1—C6 | 30.5 (6) | C10—C15—Ru3—C12 | −66.5 (6) |
C3—C2—Ru1—C6 | −99.8 (6) | C14—C15—Ru3—C11 | 99.9 (6) |
C8—C2—Ru1—C6 | 147.9 (12) | C10—C15—Ru3—C11 | −30.6 (6) |
C1—C2—Ru1—C4 | 101.5 (6) | C14—C15—Ru3—C13 | 28.2 (5) |
C3—C2—Ru1—C4 | −28.8 (5) | C10—C15—Ru3—C13 | −102.3 (6) |
C8—C2—Ru1—C4 | −141.1 (12) | C14—C15—Ru3—Cl6 | −48.2 (6) |
C1—C2—Ru1—C3 | 130.3 (8) | C10—C15—Ru3—Cl6 | −178.7 (5) |
C8—C2—Ru1—C3 | −112.3 (13) | C14—C15—Ru3—Cl5i | 150.0 (4) |
C3—C2—Ru1—C1 | −130.3 (8) | C10—C15—Ru3—Cl5i | 19.5 (8) |
C8—C2—Ru1—C1 | 117.4 (13) | C14—C15—Ru3—Cl5 | −136.0 (5) |
C1—C2—Ru1—C5 | 65.5 (6) | C10—C15—Ru3—Cl5 | 93.5 (5) |
C3—C2—Ru1—C5 | −64.8 (6) | C12—C11—Ru3—C14 | −66.1 (6) |
C8—C2—Ru1—C5 | −177.1 (11) | C10—C11—Ru3—C14 | 69.7 (5) |
C1—C2—Ru1—Cl1 | 171.9 (4) | C17—C11—Ru3—C14 | −179.2 (12) |
C3—C2—Ru1—Cl1 | 41.7 (6) | C12—C11—Ru3—C10 | −135.8 (8) |
C8—C2—Ru1—Cl1 | −70.6 (11) | C17—C11—Ru3—C10 | 111.1 (14) |
C1—C2—Ru1—Cl3 | −102.3 (5) | C10—C11—Ru3—C12 | 135.8 (8) |
C3—C2—Ru1—Cl3 | 127.5 (5) | C17—C11—Ru3—C12 | −113.1 (13) |
C8—C2—Ru1—Cl3 | 15.2 (11) | C12—C11—Ru3—C15 | −104.2 (6) |
C1—C2—Ru1—Cl2 | −28.2 (7) | C10—C11—Ru3—C15 | 31.6 (5) |
C3—C2—Ru1—Cl2 | −158.4 (4) | C17—C11—Ru3—C15 | 142.8 (12) |
C8—C2—Ru1—Cl2 | 89.3 (11) | C12—C11—Ru3—C13 | −28.2 (5) |
C4—C5—Ru1—C6 | 131.6 (10) | C10—C11—Ru3—C13 | 107.6 (6) |
C6—C5—Ru1—C4 | −131.6 (10) | C17—C11—Ru3—C13 | −141.3 (12) |
C6—C5—Ru1—C3 | −102.7 (7) | C12—C11—Ru3—Cl6 | 12.4 (8) |
C4—C5—Ru1—C3 | 28.9 (7) | C10—C11—Ru3—Cl6 | 148.2 (5) |
C6—C5—Ru1—C1 | −28.2 (6) | C17—C11—Ru3—Cl6 | −100.7 (12) |
C4—C5—Ru1—C1 | 103.4 (7) | C12—C11—Ru3—Cl5i | 98.1 (5) |
C6—C5—Ru1—C2 | −65.5 (7) | C10—C11—Ru3—Cl5i | −126.1 (5) |
C4—C5—Ru1—C2 | 66.1 (7) | C17—C11—Ru3—Cl5i | −15.0 (11) |
C6—C5—Ru1—Cl1 | 163.8 (6) | C12—C11—Ru3—Cl5 | 177.0 (5) |
C4—C5—Ru1—Cl1 | −64.7 (7) | C10—C11—Ru3—Cl5 | −47.1 (6) |
C6—C5—Ru1—Cl3 | −11.1 (15) | C17—C11—Ru3—Cl5 | 64.0 (12) |
C4—C5—Ru1—Cl3 | 120.5 (11) | C12—C13—Ru3—C14 | 132.2 (9) |
C6—C5—Ru1—Cl2 | 74.6 (6) | C18—C13—Ru3—C14 | −113.6 (10) |
C4—C5—Ru1—Cl2 | −153.8 (6) | C12—C13—Ru3—C10 | 65.1 (7) |
Ru2—Cl3—Ru1—C6 | 88.3 (3) | C14—C13—Ru3—C10 | −67.2 (6) |
Ru2—Cl3—Ru1—C4 | −163.8 (6) | C18—C13—Ru3—C10 | 179.2 (8) |
Ru2—Cl3—Ru1—C3 | −177.6 (3) | C14—C13—Ru3—C12 | −132.2 (9) |
Ru2—Cl3—Ru1—C1 | 112.8 (3) | C18—C13—Ru3—C12 | 114.2 (10) |
Ru2—Cl3—Ru1—C2 | 150.4 (3) | C12—C13—Ru3—C15 | 104.3 (7) |
Ru2—Cl3—Ru1—C5 | 96.7 (11) | C14—C13—Ru3—C15 | −27.9 (5) |
Ru2—Cl3—Ru1—Cl1 | −78.38 (8) | C18—C13—Ru3—C15 | −141.5 (8) |
Ru2—Cl3—Ru1—Cl2 | 8.72 (7) | C12—C13—Ru3—C11 | 28.3 (6) |
Ru2—Cl2—Ru1—C6 | −138.6 (3) | C14—C13—Ru3—C11 | −104.0 (6) |
Ru2—Cl2—Ru1—C4 | 166.1 (4) | C18—C13—Ru3—C11 | 142.4 (8) |
Ru2—Cl2—Ru1—C3 | −162.8 (14) | C12—C13—Ru3—Cl6 | −132.4 (6) |
Ru2—Cl2—Ru1—C1 | −103.1 (3) | C14—C13—Ru3—Cl6 | 95.3 (5) |
Ru2—Cl2—Ru1—C2 | −85.4 (4) | C18—C13—Ru3—Cl6 | −18.3 (7) |
Ru2—Cl2—Ru1—C5 | −173.4 (3) | C12—C13—Ru3—Cl5i | −45.7 (7) |
Ru2—Cl2—Ru1—Cl1 | 79.59 (7) | C14—C13—Ru3—Cl5i | −177.9 (4) |
Ru2—Cl2—Ru1—Cl3 | −8.70 (7) | C18—C13—Ru3—Cl5i | 68.5 (8) |
C19—C24—Ru2—C21 | 68.1 (5) | C12—C13—Ru3—Cl5 | 146.3 (6) |
C23—C24—Ru2—C21 | −66.5 (4) | C14—C13—Ru3—Cl5 | 14.0 (10) |
C19—C24—Ru2—C23 | 134.5 (6) | C18—C13—Ru3—Cl5 | −99.6 (9) |
C23—C24—Ru2—C19 | −134.5 (6) | Ru3i—Cl5—Ru3—C14 | 179.7 (3) |
C19—C24—Ru2—C22 | 106.2 (5) | Ru3i—Cl5—Ru3—C10 | −111.3 (3) |
C23—C24—Ru2—C22 | −28.3 (4) | Ru3i—Cl5—Ru3—C12 | −79.1 (7) |
C19—C24—Ru2—C20 | 31.0 (4) | Ru3i—Cl5—Ru3—C15 | −151.3 (3) |
C23—C24—Ru2—C20 | −103.5 (5) | Ru3i—Cl5—Ru3—C11 | −84.1 (3) |
C19—C24—Ru2—Cl4 | −42.3 (5) | Ru3i—Cl5—Ru3—C13 | 169.9 (6) |
C23—C24—Ru2—Cl4 | −176.9 (3) | Ru3i—Cl5—Ru3—Cl6 | 88.14 (8) |
C19—C24—Ru2—Cl3 | 157.8 (3) | Ru3i—Cl5—Ru3—Cl5i | 0.0 |
C23—C24—Ru2—Cl3 | 23.2 (6) |
Symmetry code: (i) −x+2, −y+1, −z+1. |