Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804012474/dn6138sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804012474/dn6138Isup2.hkl |
CCDC reference: 242287
Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
[Os(C10H14)Cl2(C18H31P)] | F(000) = 2704 |
Mr = 673.71 | Dx = 1.453 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 6588 reflections |
a = 15.3347 (2) Å | θ = 1.3–26.7° |
b = 13.0280 (2) Å | µ = 4.38 mm−1 |
c = 31.6125 (4) Å | T = 150 K |
β = 102.678 (1)° | Rod, orange |
V = 6161.58 (15) Å3 | 0.28 × 0.20 × 0.03 mm |
Z = 8 |
Siemens SMART CCD area-detector diffractometer | 6510 independent reflections |
Radiation source: fine-focus sealed tube | 5767 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.028 |
ω scans | θmax = 26.7°, θmin = 1.3° |
Absorption correction: multi-scan (Blessing, 1995) | h = −19→19 |
Tmin = 0.374, Tmax = 0.880 | k = −16→10 |
18106 measured reflections | l = −37→40 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.031 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.081 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.19 | w = 1/[σ2(Fo2) + (0.0385P)2 + 8.2375P] where P = (Fo2 + 2Fc2)/3 |
6510 reflections | (Δ/σ)max = 0.023 |
337 parameters | Δρmax = 1.01 e Å−3 |
72 restraints | Δρmin = −1.05 e Å−3 |
Experimental. A void of 150 e/Å3 corresponding to a dichloromethane molecule was found and removed from the structure. The data were treated with the SQUEEZE routine program within PLATON (Spek, 2002). |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Os | 0.210556 (9) | 0.591523 (12) | 0.055462 (5) | 0.01886 (6) | |
Cl1 | 0.20290 (8) | 0.50837 (9) | −0.01337 (3) | 0.0310 (2) | |
Cl2 | 0.08135 (7) | 0.68720 (8) | 0.01823 (4) | 0.0276 (2) | |
P | 0.10235 (7) | 0.46941 (8) | 0.06318 (3) | 0.0204 (2) | |
H2 | 0.017 (3) | 0.501 (3) | 0.0529 (14) | 0.024* | |
H1 | 0.092 (3) | 0.393 (3) | 0.0384 (15) | 0.024* | |
C1 | 0.2034 (3) | 0.8307 (4) | 0.09602 (18) | 0.0375 (11) | |
H1A | 0.1463 | 0.8147 | 0.1022 | 0.056* | |
H1B | 0.1947 | 0.8660 | 0.0688 | 0.056* | |
H1C | 0.2365 | 0.8737 | 0.1186 | 0.056* | |
C2 | 0.2546 (3) | 0.7325 (3) | 0.09375 (14) | 0.0261 (9) | |
C3 | 0.3076 (3) | 0.7224 (3) | 0.06175 (14) | 0.0246 (9) | |
H3 | 0.3115 | 0.7766 | 0.0431 | 0.030* | |
C4 | 0.3534 (3) | 0.6304 (3) | 0.05863 (14) | 0.0252 (9) | |
H4 | 0.3874 | 0.6247 | 0.0377 | 0.030* | |
C5 | 0.3492 (3) | 0.5452 (4) | 0.08674 (16) | 0.0287 (10) | |
C6 | 0.2964 (3) | 0.5575 (4) | 0.11798 (14) | 0.0273 (9) | |
H6 | 0.2913 | 0.5030 | 0.1363 | 0.033* | |
C7 | 0.2514 (3) | 0.6506 (4) | 0.12210 (14) | 0.0284 (10) | |
H7 | 0.2194 | 0.6574 | 0.1438 | 0.034* | |
C8 | 0.4017 (3) | 0.4459 (4) | 0.0875 (2) | 0.0436 (13) | |
H8 | 0.3632 | 0.3896 | 0.0929 | 0.052* | |
C9 | 0.4841 (4) | 0.4477 (5) | 0.1252 (2) | 0.0521 (15) | |
H9A | 0.5152 | 0.3835 | 0.1264 | 0.078* | |
H9B | 0.4655 | 0.4582 | 0.1520 | 0.078* | |
H9C | 0.5231 | 0.5025 | 0.1209 | 0.078* | |
C10 | 0.4287 (4) | 0.4237 (5) | 0.0452 (2) | 0.0632 (19) | |
H10A | 0.3766 | 0.4244 | 0.0219 | 0.095* | |
H10B | 0.4566 | 0.3574 | 0.0467 | 0.095* | |
H10C | 0.4700 | 0.4751 | 0.0401 | 0.095* | |
C11 | 0.1206 (2) | 0.4097 (3) | 0.11692 (13) | 0.0189 (8) | |
C12 | 0.1774 (3) | 0.3214 (3) | 0.12621 (14) | 0.0213 (8) | |
C13 | 0.2274 (3) | 0.3116 (3) | 0.16844 (14) | 0.0263 (9) | |
H13 | 0.2671 | 0.2569 | 0.1746 | 0.032* | |
C14 | 0.2216 (3) | 0.3784 (4) | 0.20202 (14) | 0.0265 (9) | |
C15 | 0.1525 (3) | 0.4504 (3) | 0.19347 (14) | 0.0261 (9) | |
H15 | 0.1416 | 0.4897 | 0.2163 | 0.031* | |
C16 | 0.0990 (3) | 0.4661 (3) | 0.15219 (13) | 0.0207 (8) | |
C17 | 0.1775 (3) | 0.2331 (3) | 0.09361 (15) | 0.0268 (9) | |
C18 | 0.2189 (4) | 0.1350 (4) | 0.11660 (19) | 0.0444 (13) | |
H18A | 0.2105 | 0.0792 | 0.0963 | 0.067* | |
H18B | 0.1903 | 0.1191 | 0.1400 | 0.067* | |
H18C | 0.2816 | 0.1455 | 0.1279 | 0.067* | |
C19 | 0.0792 (3) | 0.2048 (3) | 0.07328 (16) | 0.0322 (10) | |
H19A | 0.0777 | 0.1471 | 0.0542 | 0.048* | |
H19B | 0.0500 | 0.2623 | 0.0571 | 0.048* | |
H19C | 0.0489 | 0.1875 | 0.0959 | 0.048* | |
C20 | 0.2304 (4) | 0.2562 (5) | 0.05848 (19) | 0.0495 (15) | |
H20A | 0.2931 | 0.2578 | 0.0714 | 0.074* | |
H20B | 0.2122 | 0.3215 | 0.0454 | 0.074* | |
H20C | 0.2187 | 0.2037 | 0.0367 | 0.074* | |
C21 | 0.0130 (3) | 0.5322 (3) | 0.14711 (14) | 0.0262 (9) | |
C22 | −0.0664 (3) | 0.4671 (4) | 0.12280 (17) | 0.0330 (11) | |
H22A | −0.1203 | 0.5069 | 0.1185 | 0.049* | |
H22B | −0.0725 | 0.4071 | 0.1396 | 0.049* | |
H22C | −0.0559 | 0.4467 | 0.0952 | 0.049* | |
C23 | −0.0076 (3) | 0.5561 (4) | 0.19176 (17) | 0.0380 (11) | |
H23A | 0.0381 | 0.6001 | 0.2079 | 0.057* | |
H23B | −0.0091 | 0.4932 | 0.2074 | 0.057* | |
H23C | −0.0645 | 0.5897 | 0.1877 | 0.057* | |
C24 | 0.0167 (3) | 0.6364 (4) | 0.12505 (16) | 0.0330 (10) | |
H24A | 0.0363 | 0.6269 | 0.0985 | 0.050* | |
H24B | 0.0579 | 0.6806 | 0.1439 | 0.050* | |
H24C | −0.0416 | 0.6670 | 0.1189 | 0.050* | |
C25 | 0.2869 (4) | 0.3701 (5) | 0.24629 (16) | 0.0422 (11) | |
C26A | 0.2770 (7) | 0.2587 (6) | 0.2640 (3) | 0.053 (2) | 0.70 |
H26A | 0.2176 | 0.2497 | 0.2685 | 0.079* | 0.70 |
H26B | 0.3195 | 0.2494 | 0.2910 | 0.079* | 0.70 |
H26C | 0.2880 | 0.2091 | 0.2433 | 0.079* | 0.70 |
C27A | 0.2697 (8) | 0.4493 (8) | 0.2791 (4) | 0.053 (3) | 0.70 |
H27A | 0.2782 | 0.5171 | 0.2687 | 0.079* | 0.70 |
H27B | 0.3107 | 0.4383 | 0.3064 | 0.079* | 0.70 |
H27C | 0.2095 | 0.4425 | 0.2828 | 0.079* | 0.70 |
C28A | 0.3819 (5) | 0.3777 (9) | 0.2402 (3) | 0.054 (2) | 0.70 |
H28A | 0.3947 | 0.3198 | 0.2238 | 0.081* | 0.70 |
H28B | 0.4225 | 0.3784 | 0.2680 | 0.081* | 0.70 |
H28C | 0.3887 | 0.4398 | 0.2249 | 0.081* | 0.70 |
C26B | 0.3316 (18) | 0.2659 (14) | 0.2581 (8) | 0.077 (5) | 0.30 |
H26D | 0.2871 | 0.2161 | 0.2611 | 0.115* | 0.30 |
H26E | 0.3748 | 0.2716 | 0.2850 | 0.115* | 0.30 |
H26F | 0.3608 | 0.2445 | 0.2357 | 0.115* | 0.30 |
C27B | 0.249 (2) | 0.419 (2) | 0.2823 (9) | 0.055 (5) | 0.30 |
H27D | 0.2218 | 0.4838 | 0.2725 | 0.082* | 0.30 |
H27E | 0.2964 | 0.4301 | 0.3074 | 0.082* | 0.30 |
H27F | 0.2049 | 0.3745 | 0.2898 | 0.082* | 0.30 |
C28B | 0.3670 (14) | 0.4428 (19) | 0.2437 (8) | 0.072 (5) | 0.30 |
H28D | 0.3925 | 0.4224 | 0.2198 | 0.108* | 0.30 |
H28E | 0.4116 | 0.4382 | 0.2702 | 0.108* | 0.30 |
H28F | 0.3460 | 0.5122 | 0.2394 | 0.108* | 0.30 |
U11 | U22 | U33 | U12 | U13 | U23 | |
Os | 0.01838 (9) | 0.01866 (10) | 0.01856 (10) | −0.00014 (6) | 0.00193 (6) | 0.00196 (6) |
Cl1 | 0.0409 (6) | 0.0322 (6) | 0.0198 (5) | −0.0001 (5) | 0.0063 (4) | −0.0023 (4) |
Cl2 | 0.0240 (5) | 0.0264 (5) | 0.0293 (6) | 0.0022 (4) | −0.0009 (4) | 0.0091 (4) |
P | 0.0202 (5) | 0.0206 (5) | 0.0176 (5) | −0.0020 (4) | −0.0016 (4) | 0.0022 (4) |
C1 | 0.037 (3) | 0.026 (2) | 0.050 (3) | −0.001 (2) | 0.010 (2) | −0.009 (2) |
C2 | 0.023 (2) | 0.025 (2) | 0.029 (2) | −0.0030 (17) | 0.0038 (17) | −0.0085 (18) |
C3 | 0.026 (2) | 0.021 (2) | 0.025 (2) | −0.0081 (17) | 0.0012 (16) | 0.0025 (17) |
C4 | 0.0187 (19) | 0.028 (2) | 0.030 (2) | −0.0037 (17) | 0.0069 (17) | −0.0026 (18) |
C5 | 0.0176 (19) | 0.026 (2) | 0.039 (3) | 0.0034 (17) | −0.0025 (17) | −0.0006 (19) |
C6 | 0.024 (2) | 0.030 (2) | 0.023 (2) | −0.0067 (18) | −0.0063 (17) | 0.0075 (18) |
C7 | 0.026 (2) | 0.036 (3) | 0.021 (2) | −0.0052 (19) | 0.0015 (17) | −0.0043 (18) |
C8 | 0.026 (2) | 0.028 (3) | 0.074 (4) | 0.002 (2) | 0.005 (2) | −0.005 (3) |
C9 | 0.033 (3) | 0.046 (3) | 0.072 (4) | 0.011 (2) | 0.000 (3) | 0.020 (3) |
C10 | 0.051 (4) | 0.054 (4) | 0.081 (5) | 0.019 (3) | 0.006 (3) | −0.027 (3) |
C11 | 0.0148 (17) | 0.019 (2) | 0.021 (2) | −0.0008 (15) | −0.0001 (14) | 0.0023 (16) |
C12 | 0.0179 (18) | 0.017 (2) | 0.028 (2) | −0.0020 (15) | 0.0026 (16) | 0.0007 (16) |
C13 | 0.026 (2) | 0.021 (2) | 0.030 (2) | 0.0027 (17) | 0.0015 (17) | 0.0062 (17) |
C14 | 0.023 (2) | 0.033 (2) | 0.020 (2) | 0.0014 (18) | −0.0023 (16) | 0.0067 (18) |
C15 | 0.030 (2) | 0.027 (2) | 0.020 (2) | 0.0006 (18) | 0.0041 (17) | −0.0002 (18) |
C16 | 0.0199 (19) | 0.017 (2) | 0.024 (2) | 0.0000 (15) | 0.0039 (16) | 0.0028 (16) |
C17 | 0.026 (2) | 0.017 (2) | 0.034 (3) | −0.0003 (17) | 0.0014 (18) | −0.0022 (18) |
C18 | 0.043 (3) | 0.026 (3) | 0.057 (4) | 0.008 (2) | −0.004 (2) | −0.009 (2) |
C19 | 0.035 (2) | 0.020 (2) | 0.038 (3) | −0.0068 (18) | −0.002 (2) | −0.0019 (19) |
C20 | 0.053 (3) | 0.042 (3) | 0.059 (4) | −0.007 (3) | 0.024 (3) | −0.025 (3) |
C21 | 0.022 (2) | 0.028 (2) | 0.029 (2) | 0.0048 (17) | 0.0052 (17) | 0.0019 (18) |
C22 | 0.019 (2) | 0.035 (3) | 0.045 (3) | 0.0004 (18) | 0.0059 (19) | 0.004 (2) |
C23 | 0.033 (3) | 0.048 (3) | 0.036 (3) | 0.009 (2) | 0.012 (2) | 0.000 (2) |
C24 | 0.030 (2) | 0.027 (2) | 0.043 (3) | 0.0104 (19) | 0.008 (2) | 0.005 (2) |
C25 | 0.042 (3) | 0.058 (3) | 0.020 (2) | 0.012 (2) | −0.0070 (19) | 0.004 (2) |
C26A | 0.060 (5) | 0.061 (4) | 0.029 (4) | 0.018 (4) | −0.007 (4) | 0.022 (3) |
C27A | 0.053 (6) | 0.068 (6) | 0.027 (4) | 0.012 (5) | −0.012 (4) | −0.008 (5) |
C28A | 0.030 (3) | 0.086 (6) | 0.037 (4) | 0.007 (4) | −0.012 (3) | −0.009 (5) |
C26B | 0.079 (10) | 0.078 (7) | 0.053 (9) | 0.033 (7) | −0.030 (9) | 0.003 (7) |
C27B | 0.057 (10) | 0.080 (11) | 0.020 (7) | 0.009 (8) | −0.008 (6) | 0.000 (8) |
C28B | 0.046 (8) | 0.109 (9) | 0.051 (9) | −0.011 (8) | −0.012 (7) | 0.003 (10) |
Os—C6 | 2.167 (4) | C17—C20 | 1.541 (7) |
Os—C7 | 2.201 (4) | C17—C19 | 1.548 (6) |
Os—C2 | 2.221 (4) | C18—H18A | 0.9600 |
Os—C5 | 2.223 (4) | C18—H18B | 0.9600 |
Os—C4 | 2.229 (4) | C18—H18C | 0.9600 |
Os—C3 | 2.243 (4) | C19—H19A | 0.9600 |
Os—P | 2.3498 (10) | C19—H19B | 0.9600 |
Os—Cl1 | 2.4103 (11) | C19—H19C | 0.9600 |
Os—Cl2 | 2.4168 (10) | C20—H20A | 0.9600 |
P—C11 | 1.833 (4) | C20—H20B | 0.9600 |
P—H2 | 1.35 (4) | C20—H20C | 0.9600 |
P—H1 | 1.25 (4) | C21—C24 | 1.533 (6) |
C1—C2 | 1.512 (6) | C21—C23 | 1.544 (6) |
C1—H1A | 0.9600 | C21—C22 | 1.544 (6) |
C1—H1B | 0.9600 | C22—H22A | 0.9600 |
C1—H1C | 0.9600 | C22—H22B | 0.9600 |
C2—C7 | 1.401 (6) | C22—H22C | 0.9600 |
C2—C3 | 1.435 (6) | C23—H23A | 0.9600 |
C3—C4 | 1.403 (6) | C23—H23B | 0.9600 |
C3—H3 | 0.9300 | C23—H23C | 0.9600 |
C4—C5 | 1.433 (6) | C24—H24A | 0.9600 |
C4—H4 | 0.9300 | C24—H24B | 0.9600 |
C5—C6 | 1.417 (6) | C24—H24C | 0.9600 |
C5—C8 | 1.521 (6) | C25—C28A | 1.514 (9) |
C6—C7 | 1.415 (7) | C25—C27A | 1.526 (10) |
C6—H6 | 0.9300 | C25—C27B | 1.528 (16) |
C7—H7 | 0.9300 | C25—C26B | 1.531 (15) |
C8—C10 | 1.513 (9) | C25—C28B | 1.568 (16) |
C8—C9 | 1.535 (8) | C25—C26A | 1.575 (9) |
C8—H8 | 0.9800 | C26A—H26A | 0.9600 |
C9—H9A | 0.9600 | C26A—H26B | 0.9600 |
C9—H9B | 0.9600 | C26A—H26C | 0.9600 |
C9—H9C | 0.9600 | C27A—H27A | 0.9600 |
C10—H10A | 0.9600 | C27A—H27B | 0.9600 |
C10—H10B | 0.9600 | C27A—H27C | 0.9600 |
C10—H10C | 0.9600 | C28A—H28A | 0.9600 |
C11—C12 | 1.433 (5) | C28A—H28B | 0.9600 |
C11—C16 | 1.434 (6) | C28A—H28C | 0.9600 |
C12—C13 | 1.392 (6) | C26B—H26D | 0.9600 |
C12—C17 | 1.545 (6) | C26B—H26E | 0.9600 |
C13—C14 | 1.390 (6) | C26B—H26F | 0.9600 |
C13—H13 | 0.9300 | C27B—H27D | 0.9600 |
C14—C15 | 1.397 (6) | C27B—H27E | 0.9600 |
C14—C25 | 1.535 (6) | C27B—H27F | 0.9600 |
C15—C16 | 1.395 (6) | C28B—H28D | 0.9600 |
C15—H15 | 0.9300 | C28B—H28E | 0.9600 |
C16—C21 | 1.554 (5) | C28B—H28F | 0.9600 |
C17—C18 | 1.536 (7) | ||
C6—Os—C7 | 37.81 (18) | C14—C13—C12 | 124.1 (4) |
C6—Os—C2 | 67.70 (17) | C14—C13—H13 | 117.9 |
C7—Os—C2 | 36.94 (17) | C12—C13—H13 | 117.9 |
C6—Os—C5 | 37.64 (17) | C13—C14—C15 | 116.5 (4) |
C7—Os—C5 | 68.02 (17) | C13—C14—C25 | 120.9 (4) |
C2—Os—C5 | 80.52 (16) | C15—C14—C25 | 122.6 (4) |
C6—Os—C4 | 67.10 (16) | C16—C15—C14 | 123.0 (4) |
C7—Os—C4 | 78.88 (16) | C16—C15—H15 | 118.5 |
C2—Os—C4 | 66.99 (16) | C14—C15—H15 | 118.5 |
C5—Os—C4 | 37.54 (17) | C15—C16—C11 | 117.6 (4) |
C6—Os—C3 | 79.39 (16) | C15—C16—C21 | 119.3 (4) |
C7—Os—C3 | 66.77 (16) | C11—C16—C21 | 122.7 (4) |
C2—Os—C3 | 37.51 (15) | C18—C17—C20 | 106.0 (4) |
C5—Os—C3 | 67.41 (16) | C18—C17—C12 | 111.4 (4) |
C4—Os—C3 | 36.57 (16) | C20—C17—C12 | 114.4 (4) |
C6—Os—P | 93.94 (12) | C18—C17—C19 | 105.2 (4) |
C7—Os—P | 101.33 (12) | C20—C17—C19 | 111.4 (4) |
C2—Os—P | 129.82 (11) | C12—C17—C19 | 108.1 (3) |
C5—Os—P | 113.47 (12) | C17—C18—H18A | 109.5 |
C4—Os—P | 149.16 (12) | C17—C18—H18B | 109.5 |
C3—Os—P | 167.24 (11) | H18A—C18—H18B | 109.5 |
C6—Os—Cl1 | 129.13 (13) | C17—C18—H18C | 109.5 |
C7—Os—Cl1 | 165.59 (12) | H18A—C18—H18C | 109.5 |
C2—Os—Cl1 | 144.30 (12) | H18B—C18—H18C | 109.5 |
C5—Os—Cl1 | 97.57 (13) | C17—C19—H19A | 109.5 |
C4—Os—Cl1 | 89.74 (12) | C17—C19—H19B | 109.5 |
C3—Os—Cl1 | 108.76 (11) | H19A—C19—H19B | 109.5 |
P—Os—Cl1 | 83.91 (4) | C17—C19—H19C | 109.5 |
C6—Os—Cl2 | 144.97 (13) | H19A—C19—H19C | 109.5 |
C7—Os—Cl2 | 108.45 (12) | H19B—C19—H19C | 109.5 |
C2—Os—Cl2 | 87.59 (12) | C17—C20—H20A | 109.5 |
C5—Os—Cl2 | 163.48 (12) | C17—C20—H20B | 109.5 |
C4—Os—Cl2 | 126.67 (12) | H20A—C20—H20B | 109.5 |
C3—Os—Cl2 | 96.21 (11) | C17—C20—H20C | 109.5 |
P—Os—Cl2 | 82.97 (4) | H20A—C20—H20C | 109.5 |
Cl1—Os—Cl2 | 85.41 (4) | H20B—C20—H20C | 109.5 |
C11—P—Os | 114.57 (13) | C24—C21—C23 | 105.9 (4) |
C11—P—H2 | 107.3 (18) | C24—C21—C22 | 111.4 (4) |
Os—P—H2 | 116.2 (18) | C23—C21—C22 | 105.6 (4) |
C11—P—H1 | 103 (2) | C24—C21—C16 | 115.0 (3) |
Os—P—H1 | 118 (2) | C23—C21—C16 | 110.9 (4) |
H2—P—H1 | 96 (3) | C22—C21—C16 | 107.8 (3) |
C2—C1—H1A | 109.5 | C21—C22—H22A | 109.5 |
C2—C1—H1B | 109.5 | C21—C22—H22B | 109.5 |
H1A—C1—H1B | 109.5 | H22A—C22—H22B | 109.5 |
C2—C1—H1C | 109.5 | C21—C22—H22C | 109.5 |
H1A—C1—H1C | 109.5 | H22A—C22—H22C | 109.5 |
H1B—C1—H1C | 109.5 | H22B—C22—H22C | 109.5 |
C7—C2—C3 | 119.1 (4) | C21—C23—H23A | 109.5 |
C7—C2—C1 | 121.5 (4) | C21—C23—H23B | 109.5 |
C3—C2—C1 | 119.5 (4) | H23A—C23—H23B | 109.5 |
C7—C2—Os | 70.7 (3) | C21—C23—H23C | 109.5 |
C3—C2—Os | 72.0 (2) | H23A—C23—H23C | 109.5 |
C1—C2—Os | 128.8 (3) | H23B—C23—H23C | 109.5 |
C4—C3—C2 | 119.8 (4) | C21—C24—H24A | 109.5 |
C4—C3—Os | 71.2 (2) | C21—C24—H24B | 109.5 |
C2—C3—Os | 70.4 (2) | H24A—C24—H24B | 109.5 |
C4—C3—H3 | 120.1 | C21—C24—H24C | 109.5 |
C2—C3—H3 | 120.1 | H24A—C24—H24C | 109.5 |
Os—C3—H3 | 130.9 | H24B—C24—H24C | 109.5 |
C3—C4—C5 | 121.8 (4) | C28A—C25—C27A | 110.9 (7) |
C3—C4—Os | 72.2 (2) | C28A—C25—C27B | 127.0 (14) |
C5—C4—Os | 71.0 (2) | C27A—C25—C27B | 20.0 (12) |
C3—C4—H4 | 119.1 | C28A—C25—C26B | 72.4 (12) |
C5—C4—H4 | 119.1 | C27A—C25—C26B | 124.7 (12) |
Os—C4—H4 | 130.4 | C27B—C25—C26B | 114.3 (15) |
C6—C5—C4 | 117.0 (4) | C28A—C25—C14 | 109.4 (5) |
C6—C5—C8 | 117.9 (4) | C27A—C25—C14 | 113.4 (6) |
C4—C5—C8 | 125.0 (4) | C27B—C25—C14 | 111.8 (14) |
C6—C5—Os | 69.0 (2) | C26B—C25—C14 | 116.9 (10) |
C4—C5—Os | 71.5 (2) | C28A—C25—C28B | 33.5 (10) |
C8—C5—Os | 133.6 (3) | C27A—C25—C28B | 83.2 (12) |
C7—C6—C5 | 121.8 (4) | C27B—C25—C28B | 102.6 (14) |
C7—C6—Os | 72.4 (2) | C26B—C25—C28B | 103.5 (14) |
C5—C6—Os | 73.3 (3) | C14—C25—C28B | 105.8 (10) |
C7—C6—H6 | 119.1 | C28A—C25—C26A | 106.0 (6) |
C5—C6—H6 | 119.1 | C27A—C25—C26A | 109.7 (7) |
Os—C6—H6 | 127.3 | C27B—C25—C26A | 92.2 (13) |
C2—C7—C6 | 120.4 (4) | C26B—C25—C26A | 33.7 (11) |
C2—C7—Os | 72.3 (3) | C14—C25—C26A | 107.1 (5) |
C6—C7—Os | 69.8 (2) | C28B—C25—C26A | 135.4 (11) |
C2—C7—H7 | 119.8 | C25—C26A—H26A | 109.5 |
C6—C7—H7 | 119.8 | C25—C26A—H26B | 109.5 |
Os—C7—H7 | 130.8 | C25—C26A—H26C | 109.5 |
C10—C8—C5 | 113.3 (5) | C25—C27A—H27A | 109.5 |
C10—C8—C9 | 110.6 (5) | C25—C27A—H27B | 109.5 |
C5—C8—C9 | 110.0 (4) | C25—C27A—H27C | 109.5 |
C10—C8—H8 | 107.6 | C25—C28A—H28A | 109.5 |
C5—C8—H8 | 107.6 | C25—C28A—H28B | 109.5 |
C9—C8—H8 | 107.6 | C25—C28A—H28C | 109.5 |
C8—C9—H9A | 109.5 | C25—C26B—H26D | 109.4 |
C8—C9—H9B | 109.5 | C25—C26B—H26E | 109.5 |
H9A—C9—H9B | 109.5 | H26D—C26B—H26E | 109.5 |
C8—C9—H9C | 109.5 | C25—C26B—H26F | 109.5 |
H9A—C9—H9C | 109.5 | H26D—C26B—H26F | 109.5 |
H9B—C9—H9C | 109.5 | H26E—C26B—H26F | 109.5 |
C8—C10—H10A | 109.5 | C25—C27B—H27D | 109.5 |
C8—C10—H10B | 109.5 | C25—C27B—H27E | 109.5 |
H10A—C10—H10B | 109.5 | H27D—C27B—H27E | 109.5 |
C8—C10—H10C | 109.5 | C25—C27B—H27F | 109.5 |
H10A—C10—H10C | 109.5 | H27D—C27B—H27F | 109.5 |
H10B—C10—H10C | 109.5 | H27E—C27B—H27F | 109.5 |
C12—C11—C16 | 119.0 (4) | C25—C28B—H28D | 109.5 |
C12—C11—P | 119.5 (3) | C25—C28B—H28E | 109.5 |
C16—C11—P | 119.3 (3) | H28D—C28B—H28E | 109.5 |
C13—C12—C11 | 116.9 (4) | C25—C28B—H28F | 109.5 |
C13—C12—C17 | 119.3 (4) | H28D—C28B—H28F | 109.5 |
C11—C12—C17 | 123.4 (4) | H28E—C28B—H28F | 109.5 |