Communication between cation environments in aluminosilicate frameworks: incommensurately modulated crystal structure of an e-plagioclase

Fredrickson, R.T.; Fredrickson, D.C.

doi:10.1107/S2052520616010350

Communication between cation environments in aluminosilicate frameworks: incommensurately modulated crystal structure of an e-plagioclase

Despite being one of the most common minerals in the earth's crust the crystal structure of intermediate e-plagioclase remains only partially understood, due in a large part to its complex diffraction patterns including satellite reflections. In this article we present a detailed analysis of the structure of e-plagioclase (An₄₄) using single-crystal X-ray diffraction measured at ambient and low temperature (T = 100 K), in which the full modulated structure is successfully refined. As in earlier studies, the diffraction pattern exhibits strong main a-reflections and weak e-satellite reflections. The average structure could be solved in terms of an albite-like basic cell with the triclinic centrosymmetric and non-centrosymmetric space groups $P \bar 1$ and P1 (treated in its $C \bar 1$ and C1 setting, respectively, to follow conventions in the literature), while the incommensurately modulated structure was modeled in (3 + 1)D superspace, employing both the centro- and non-centrosymmetric superspace groups $X \bar 1$ (αβγ)0 and X1(αβγ)0, where X refers to a special (3 + 1)D lattice centering with centering vectors (0 0 ½ ½), (½ ½ 0 ½), and (½ ½ ½ 0). Individual positional and occupational modulations for Ca/Na were refined with deeper insights being revealed in the non-centrosymmetric structure model. Through the structural details emerging from this model, the origin of the modulation can be traced to the communication between Ca/Na site positions through their bridging aluminosilicate (Si/Al)O₄ tetrahedra.

Keywords: incommensurability; modulated structure; superspace groups; single-crystal X-ray diffraction; plagioclase.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2052520616010350/dk5046sup1.cif Contains datablocks global, I, II, III, IV, V
	Structure factor file (CIF format) https://doi.org/10.1107/S2052520616010350/dk5046Isup2.hkl Contains datablock I
	Structure factor file (CIF format) https://doi.org/10.1107/S2052520616010350/dk5046IIsup3.hkl Contains datablock II
	Structure factor file (CIF format) https://doi.org/10.1107/S2052520616010350/dk5046IIIsup4.hkl Contains datablock I
	Structure factor file (CIF format) https://doi.org/10.1107/S2052520616010350/dk5046IVsup5.hkl Contains datablock IV
	Structure factor file (CIF format) https://doi.org/10.1107/S2052520616010350/dk5046Vsup6.hkl Contains datablock V
	Portable Document Format (PDF) file https://doi.org/10.1107/S2052520616010350/dk5046sup7.pdf Supporting tables and figures

B-IncStrDB reference: 12192ErztPu

CCDC references: 1487811; 1487812; 1487813; 1487814; 1487815

Computing details top

(I) top

Crystal data top

Al_1.544Ca_0.458Na_0.542O₈Si_2.456	Z = 4
M_r = 269.4	F(000) = 536
Triclinic, C1	D_x = 2.657 Mg m⁻³
Hall symbol: C 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.1846 (4) Å	Cell parameters from 3089 reflections
b = 12.9037 (6) Å	θ = 3.2–28.3°
c = 7.1202 (7) Å	µ = 1.21 mm⁻¹
α = 93.508 (6)°	T = 293 K
β = 116.170 (7)°	Irregular, colourless
γ = 89.708 (5)°	0.18 × 0.10 × 0.05 mm
V = 673.43 (9) Å³

Data collection top

Oxford Diffraction CCD diffractometer	1430 independent reflections
Radiation source: X-ray tube	1546 reflections with I > 3σ(I)
Graphite monochromator	R_int = 0.012
Detector resolution: 16.1500 pixels mm^-1	θ_max = 28.7°, θ_min = 3.2°
ω scans	h = −10→10
Absorption correction: analytical CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)	k = −17→17
T_min = 0.846, T_max = 0.949	l = −8→9
3089 measured reflections

Refinement top

Refinement on F²	105 constraints
R[F² > 2σ(F²)] = 0.027	Weighting scheme based on measured s.u.'s w = 1/(σ²(I) + 0.0004I²)
wR(F²) = 0.076	(Δ/σ)_max = 0.048
S = 1.80	Δρ_max = 0.35 e Å⁻³
2879 reflections	Δρ_min = −0.28 e Å⁻³
246 parameters	Absolute structure: 1333 of Friedel pairs used in the refinement
0 restraints	Absolute structure parameter: 0.35 (12)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ca11	0.0474 (5)	0.9672 (3)	0.8704 (6)	0.0323 (8)	0.28 (3)
Na11	0.0474 (5)	0.9672 (3)	0.8704 (6)	0.0323 (8)	0.38 (5)
Ca12	0.0399 (6)	1.0289 (4)	0.7995 (8)	0.0323 (8)	0.26 (3)
Na12	0.0399 (6)	1.0289 (4)	0.7995 (8)	0.0323 (8)	0.08 (7)
Ca21	0.5870 (5)	1.0203 (3)	0.0813 (6)	0.0174 (10)	0.375 (5)
Na22	0.5797 (4)	0.9754 (4)	0.1442 (6)	0.0174 (10)	0.626 (5)
Si1	0.3148 (3)	0.17484 (16)	0.7483 (3)	0.0154 (8)	0.7664
Al1	0.3148 (3)	0.17484 (16)	0.7483 (3)	0.0154 (8)	0.2335
Si2	0.9995 (3)	0.87268 (15)	0.3379 (3)	0.0129 (7)	0.6546
Al2	0.9995 (3)	0.87268 (15)	0.3379 (3)	0.0129 (7)	0.3454
Si3	0.1313 (3)	0.38322 (15)	0.6636 (3)	0.0123 (7)	0.7237
Al3	0.1313 (3)	0.38322 (15)	0.6636 (3)	0.0123 (7)	0.2763
Si4	0.6354 (3)	0.11321 (16)	0.6240 (3)	0.0133 (7)	0.7056
Al4	0.6354 (3)	0.11321 (16)	0.6240 (3)	0.0133 (7)	0.2944
Si5	0.0046 (3)	0.10228 (16)	0.2977 (3)	0.0132 (7)	0.7122
Al5	0.0046 (3)	0.10228 (16)	0.2977 (3)	0.0132 (7)	0.2878
Si6	0.8109 (3)	0.32791 (17)	0.7662 (3)	0.0151 (8)	0.4441
Al6	0.8109 (3)	0.32791 (17)	0.7662 (3)	0.0151 (8)	0.5559
Si7	0.3240 (3)	0.15845 (16)	0.1937 (3)	0.0150 (8)	0.3026
Al7	0.3240 (3)	0.15845 (16)	0.1937 (3)	0.0150 (8)	0.6974
Si8	0.3213 (3)	0.81053 (16)	0.2123 (3)	0.0135 (7)	0.602
Al8	0.3213 (3)	0.81053 (16)	0.2123 (3)	0.0135 (7)	0.398
O1	0.1358 (9)	0.8486 (5)	0.2302 (11)	0.026 (2)
O2	0.3115 (9)	0.8633 (5)	0.0037 (11)	0.025 (2)
O3	0.0050 (8)	0.3585 (5)	0.4076 (10)	0.025 (2)
O4	0.9014 (8)	0.9865 (4)	0.2583 (10)	0.019 (2)
O5	0.5175 (9)	0.1006 (5)	0.3630 (9)	0.025 (2)
O6	0.8012 (9)	0.1973 (4)	0.6975 (11)	0.027 (2)
O7	0.8322 (9)	0.1793 (5)	0.2003 (11)	0.028 (2)
O8	0.0014 (8)	0.3837 (4)	0.7857 (9)	0.0202 (19)
O9	0.1257 (8)	0.0971 (4)	0.1649 (11)	0.023 (2)
O10	0.2348 (7)	0.4994 (4)	0.7019 (9)	0.0157 (18)
O11	0.3004 (9)	0.3013 (5)	0.7638 (11)	0.028 (2)
O12	0.1269 (8)	0.1236 (4)	0.5450 (10)	0.024 (2)
O13	0.1199 (8)	0.8836 (4)	0.5947 (9)	0.021 (2)
O14	0.3304 (8)	0.2851 (4)	0.2542 (10)	0.021 (2)
O15	0.3174 (9)	0.1226 (5)	0.9587 (10)	0.026 (2)
O16	0.5021 (9)	0.1427 (5)	0.7393 (11)	0.029 (2)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ca11	0.0163 (10)	0.0337 (11)	0.0336 (13)	0.0094 (8)	0.0015 (8)	−0.0176 (10)
Na11	0.0163 (10)	0.0337 (11)	0.0336 (13)	0.0094 (8)	0.0015 (8)	−0.0176 (10)
Ca12	0.0163 (10)	0.0337 (11)	0.0336 (13)	0.0094 (8)	0.0015 (8)	−0.0176 (10)
Na12	0.0163 (10)	0.0337 (11)	0.0336 (13)	0.0094 (8)	0.0015 (8)	−0.0176 (10)
Ca21	0.0077 (11)	0.0310 (17)	0.0134 (15)	−0.0013 (11)	0.0050 (10)	−0.0035 (11)
Na22	0.0077 (11)	0.0310 (17)	0.0134 (15)	−0.0013 (11)	0.0050 (10)	−0.0035 (11)
Si1	0.0168 (11)	0.0181 (9)	0.0096 (10)	0.0058 (8)	0.0045 (9)	−0.0006 (8)
Al1	0.0168 (11)	0.0181 (9)	0.0096 (10)	0.0058 (8)	0.0045 (9)	−0.0006 (8)
Si2	0.0138 (10)	0.0128 (8)	0.0121 (10)	−0.0018 (7)	0.0053 (8)	0.0031 (8)
Al2	0.0138 (10)	0.0128 (8)	0.0121 (10)	−0.0018 (7)	0.0053 (8)	0.0031 (8)
Si3	0.0126 (9)	0.0116 (9)	0.0119 (10)	0.0008 (6)	0.0049 (8)	−0.0009 (7)
Al3	0.0126 (9)	0.0116 (9)	0.0119 (10)	0.0008 (6)	0.0049 (8)	−0.0009 (7)
Si4	0.0111 (9)	0.0173 (9)	0.0105 (10)	0.0002 (7)	0.0040 (8)	0.0010 (8)
Al4	0.0111 (9)	0.0173 (9)	0.0105 (10)	0.0002 (7)	0.0040 (8)	0.0010 (8)
Si5	0.0121 (9)	0.0144 (9)	0.0118 (10)	0.0007 (7)	0.0042 (8)	0.0003 (7)
Al5	0.0121 (9)	0.0144 (9)	0.0118 (10)	0.0007 (7)	0.0042 (8)	0.0003 (7)
Si6	0.0115 (11)	0.0234 (10)	0.0107 (10)	−0.0061 (8)	0.0051 (8)	0.0020 (8)
Al6	0.0115 (11)	0.0234 (10)	0.0107 (10)	−0.0061 (8)	0.0051 (8)	0.0020 (8)
Si7	0.0160 (12)	0.0184 (9)	0.0095 (10)	−0.0034 (8)	0.0044 (8)	0.0024 (8)
Al7	0.0160 (12)	0.0184 (9)	0.0095 (10)	−0.0034 (8)	0.0044 (8)	0.0024 (8)
Si8	0.0101 (10)	0.0217 (10)	0.0087 (10)	0.0049 (8)	0.0042 (9)	0.0012 (8)
Al8	0.0101 (10)	0.0217 (10)	0.0087 (10)	0.0049 (8)	0.0042 (9)	0.0012 (8)
O1	0.025 (3)	0.026 (3)	0.036 (4)	0.001 (2)	0.022 (3)	−0.005 (2)
O2	0.032 (3)	0.034 (3)	0.017 (3)	−0.001 (2)	0.017 (2)	0.004 (2)
O3	0.017 (3)	0.032 (3)	0.014 (3)	0.000 (2)	−0.002 (2)	−0.007 (2)
O4	0.024 (3)	0.015 (2)	0.021 (3)	−0.002 (2)	0.013 (2)	0.002 (2)
O5	0.019 (3)	0.036 (3)	0.016 (3)	0.001 (2)	0.003 (2)	0.009 (2)
O6	0.024 (3)	0.035 (3)	0.022 (3)	−0.004 (3)	0.007 (3)	0.009 (3)
O7	0.023 (3)	0.035 (3)	0.018 (3)	0.011 (2)	0.003 (2)	−0.003 (2)
O8	0.021 (3)	0.024 (2)	0.018 (3)	−0.0019 (19)	0.011 (2)	0.000 (2)
O9	0.022 (3)	0.020 (2)	0.030 (3)	−0.0060 (19)	0.013 (2)	−0.003 (2)
O10	0.012 (2)	0.020 (2)	0.010 (3)	−0.0030 (19)	0.0001 (19)	0.002 (2)
O11	0.025 (3)	0.028 (3)	0.022 (3)	0.012 (2)	0.002 (2)	−0.011 (2)
O12	0.023 (3)	0.023 (3)	0.020 (3)	0.003 (2)	0.003 (2)	−0.001 (2)
O13	0.022 (3)	0.022 (3)	0.013 (3)	−0.005 (2)	0.003 (2)	−0.005 (2)
O14	0.020 (3)	0.024 (3)	0.019 (3)	−0.011 (2)	0.009 (2)	−0.002 (2)
O15	0.026 (3)	0.041 (3)	0.010 (3)	0.002 (3)	0.008 (2)	0.005 (2)
O16	0.021 (3)	0.026 (3)	0.039 (4)	0.002 (2)	0.013 (3)	−0.002 (3)

Geometric parameters (Å, º) top

Ca11—O2ⁱ	2.385 (8)	Si3—O3	1.662 (6)
Ca11—O9ⁱⁱ	2.452 (7)	Si3—O8	1.644 (8)
Ca11—O10ⁱⁱⁱ	2.346 (6)	Si3—O10	1.673 (6)
Ca11—O13	2.476 (8)	Si3—O11	1.658 (7)
Ca12—O9ⁱⁱ	2.481 (9)	Si4—O5	1.672 (6)
Ca12—O10ⁱⁱⁱ	2.304 (7)	Si4—O6	1.616 (7)
Ca12—O13	2.562 (8)	Si4—O10^ix	1.678 (6)
Ca12—O15^iv	2.344 (8)	Si4—O16	1.659 (9)
Ca21—O4	2.365 (6)	Si5—O4^x	1.666 (6)
Ca21—O5^iv	2.483 (9)	Si5—O7^xi	1.633 (7)
Ca21—O8^v	2.507 (7)	Si5—O9	1.643 (9)
Ca21—O15^vi	2.405 (8)	Si5—O12	1.602 (6)
Na22—O2	2.415 (8)	Si6—O2^xii	1.722 (9)
Na22—O4	2.391 (7)	Si6—O6	1.718 (6)
Na22—O5^iv	2.383 (9)	Si6—O8^vii	1.667 (7)
Na22—O8^v	2.554 (8)	Si6—O13^ix	1.693 (6)
Si1—O11	1.636 (7)	Si7—O5	1.712 (6)
Si1—O12	1.682 (5)	Si7—O9	1.733 (7)
Si1—O15	1.672 (8)	Si7—O14	1.660 (6)
Si1—O16	1.614 (8)	Si7—O15^xiii	1.686 (8)
Si2—O1^vii	1.628 (9)	Si8—O1	1.649 (8)
Si2—O4	1.677 (6)	Si8—O2	1.642 (8)
Si2—O13^vii	1.647 (6)	Si8—O3^viii	1.624 (5)
Si2—O14^viii	1.659 (6)	Si8—O7ⁱⁱⁱ	1.694 (7)

Na11—Ca11—Ca12	0	Si8—Na22—O4	132.8 (2)
Na11—Ca11—Na12	0	Si8—Na22—O5^iv	89.3 (2)
Na11—Ca11—Ca21ⁱ	0	Si8—Na22—O8^v	89.2 (2)
Na11—Ca11—Na22ⁱ	0	Al8—Na22—O2	29.88 (19)
Na11—Ca11—Si3ⁱⁱⁱ	0	Al8—Na22—O4	132.8 (2)
Na11—Ca11—Al3ⁱⁱⁱ	0	Al8—Na22—O5^iv	89.3 (2)
Na11—Ca11—Al4^xiv	0	Al8—Na22—O8^v	89.2 (2)
Na11—Ca11—Al5ⁱⁱ	0	O2—Na22—O4	146.1 (3)
Na11—Ca11—Si6ⁱⁱⁱ	0	O2—Na22—O5^iv	102.8 (3)
Na11—Ca11—Al6ⁱⁱⁱ	0	O2—Na22—O8^v	64.7 (3)
Na11—Ca11—Si7ⁱⁱ	0	O4—Na22—O5^iv	105.7 (3)
Na11—Ca11—Al7ⁱⁱ	0	O4—Na22—O8^v	96.3 (3)
Na11—Ca11—Si8ⁱ	0	O5^iv—Na22—O8^v	151.2 (2)
Na11—Ca11—Al8ⁱ	0	Ca12^xvii—Si1—Na12^xvii	0.0 (5)
Na11—Ca11—O2ⁱ	0	Ca12^xvii—Si1—Ca21^xviii	78.93 (12)
Na11—Ca11—O9ⁱⁱ	0	Ca12^xvii—Si1—Al1	0
Na11—Ca11—O10ⁱⁱⁱ	0	Ca12^xvii—Si1—O11	121.9 (3)
Na11—Ca11—O13	0	Ca12^xvii—Si1—O12	56.7 (3)
Ca12—Ca11—Na12	0.0 (5)	Ca12^xvii—Si1—O15	48.3 (2)
Ca12—Ca11—Ca21ⁱ	82.5 (3)	Ca12^xvii—Si1—O16	127.0 (3)
Ca12—Ca11—Na22ⁱ	93.4 (3)	Na12^xvii—Si1—Ca21^xviii	78.93 (12)
Ca12—Ca11—Si3ⁱⁱⁱ	102.8 (3)	Na12^xvii—Si1—Al1	0
Ca12—Ca11—Al3ⁱⁱⁱ	102.8 (3)	Na12^xvii—Si1—O11	121.9 (3)
Ca12—Ca11—Al4^xiv	56.2 (3)	Na12^xvii—Si1—O12	56.7 (3)
Ca12—Ca11—Al5ⁱⁱ	93.7 (4)	Na12^xvii—Si1—O15	48.3 (2)
Ca12—Ca11—Si6ⁱⁱⁱ	104.4 (5)	Na12^xvii—Si1—O16	127.0 (3)
Ca12—Ca11—Al6ⁱⁱⁱ	104.4 (5)	Ca21^xviii—Si1—Al1	0
Ca12—Ca11—Si7ⁱⁱ	68.0 (3)	Ca21^xviii—Si1—O11	130.7 (2)
Ca12—Ca11—Al7ⁱⁱ	68.0 (3)	Ca21^xviii—Si1—O12	118.4 (2)
Ca12—Ca11—Si8ⁱ	145.4 (4)	Ca21^xviii—Si1—O15	46.4 (3)
Ca12—Ca11—Al8ⁱ	145.4 (4)	Ca21^xviii—Si1—O16	60.3 (3)
Ca12—Ca11—O2ⁱ	123.3 (5)	Al1—Si1—O11	0
Ca12—Ca11—O9ⁱⁱ	80.5 (4)	Al1—Si1—O12	0
Ca12—Ca11—O10ⁱⁱⁱ	75.7 (4)	Al1—Si1—O15	0
Ca12—Ca11—O13	84.2 (5)	Al1—Si1—O16	0
Na12—Ca11—Ca21ⁱ	82.5 (3)	O11—Si1—O12	109.6 (3)
Na12—Ca11—Na22ⁱ	93.4 (3)	O11—Si1—O15	111.6 (4)
Na12—Ca11—Si3ⁱⁱⁱ	102.8 (3)	O11—Si1—O16	110.4 (4)
Na12—Ca11—Al3ⁱⁱⁱ	102.8 (3)	O12—Si1—O15	104.8 (3)
Na12—Ca11—Al4^xiv	56.2 (3)	O12—Si1—O16	113.8 (4)
Na12—Ca11—Al5ⁱⁱ	93.7 (4)	O15—Si1—O16	106.5 (4)
Na12—Ca11—Si6ⁱⁱⁱ	104.4 (5)	Ca12^xvii—Al1—Na12^xvii	0.0 (5)
Na12—Ca11—Al6ⁱⁱⁱ	104.4 (5)	Ca12^xvii—Al1—Ca21^xviii	78.93 (12)
Na12—Ca11—Si7ⁱⁱ	68.0 (3)	Ca12^xvii—Al1—Si1	0
Na12—Ca11—Al7ⁱⁱ	68.0 (3)	Ca12^xvii—Al1—Al3	104.85 (12)
Na12—Ca11—Si8ⁱ	145.4 (4)	Ca12^xvii—Al1—O11	121.9 (3)
Na12—Ca11—Al8ⁱ	145.4 (4)	Ca12^xvii—Al1—O12	56.7 (3)
Na12—Ca11—O2ⁱ	123.3 (5)	Ca12^xvii—Al1—O15	48.3 (2)
Na12—Ca11—O9ⁱⁱ	80.5 (4)	Ca12^xvii—Al1—O16	127.0 (3)
Na12—Ca11—O10ⁱⁱⁱ	75.7 (4)	Na12^xvii—Al1—Ca21^xviii	78.93 (12)
Na12—Ca11—O13	84.2 (5)	Na12^xvii—Al1—Si1	0
Ca21ⁱ—Ca11—Na22ⁱ	11.00 (10)	Na12^xvii—Al1—Al3	104.85 (12)
Ca21ⁱ—Ca11—Si3ⁱⁱⁱ	168.90 (14)	Na12^xvii—Al1—O11	121.9 (3)
Ca21ⁱ—Ca11—Al3ⁱⁱⁱ	168.90 (14)	Na12^xvii—Al1—O12	56.7 (3)
Ca21ⁱ—Ca11—Al4^xiv	136.81 (12)	Na12^xvii—Al1—O15	48.3 (2)
Ca21ⁱ—Ca11—Al5ⁱⁱ	96.91 (10)	Na12^xvii—Al1—O16	127.0 (3)
Ca21ⁱ—Ca11—Si6ⁱⁱⁱ	54.04 (9)	Ca21^xviii—Al1—Si1	0
Ca21ⁱ—Ca11—Al6ⁱⁱⁱ	54.04 (9)	Ca21^xviii—Al1—Al3	148.90 (11)
Ca21ⁱ—Ca11—Si7ⁱⁱ	48.94 (8)	Ca21^xviii—Al1—O11	130.7 (2)
Ca21ⁱ—Ca11—Al7ⁱⁱ	48.94 (8)	Ca21^xviii—Al1—O12	118.4 (2)
Ca21ⁱ—Ca11—Si8ⁱ	63.13 (9)	Ca21^xviii—Al1—O15	46.4 (3)
Ca21ⁱ—Ca11—Al8ⁱ	63.13 (9)	Ca21^xviii—Al1—O16	60.3 (3)
Ca21ⁱ—Ca11—O2ⁱ	44.76 (19)	Si1—Al1—Al3	0
Ca21ⁱ—Ca11—O9ⁱⁱ	75.88 (19)	Si1—Al1—O11	0
Ca21ⁱ—Ca11—O10ⁱⁱⁱ	158.0 (2)	Si1—Al1—O12	0
Ca21ⁱ—Ca11—O13	75.38 (18)	Si1—Al1—O15	0
Na22ⁱ—Ca11—Si3ⁱⁱⁱ	161.79 (14)	Si1—Al1—O16	0
Na22ⁱ—Ca11—Al3ⁱⁱⁱ	161.79 (14)	Al3—Al1—O11	23.1 (2)
Na22ⁱ—Ca11—Al4^xiv	146.57 (13)	Al3—Al1—O12	87.3 (2)
Na22ⁱ—Ca11—Al5ⁱⁱ	94.72 (10)	Al3—Al1—O15	113.4 (3)
Na22ⁱ—Ca11—Si6ⁱⁱⁱ	51.77 (9)	Al3—Al1—O16	127.7 (3)
Na22ⁱ—Ca11—Al6ⁱⁱⁱ	51.77 (9)	O11—Al1—O12	109.6 (3)
Na22ⁱ—Ca11—Si7ⁱⁱ	52.52 (9)	O11—Al1—O15	111.6 (4)
Na22ⁱ—Ca11—Al7ⁱⁱ	52.52 (9)	O11—Al1—O16	110.4 (4)
Na22ⁱ—Ca11—Si8ⁱ	52.16 (10)	O12—Al1—O15	104.8 (3)
Na22ⁱ—Ca11—Al8ⁱ	52.16 (10)	O12—Al1—O16	113.8 (4)
Na22ⁱ—Ca11—O2ⁱ	35.72 (19)	O15—Al1—O16	106.5 (4)
Na22ⁱ—Ca11—O9ⁱⁱ	76.12 (19)	Na22—Si2—Al2	0
Na22ⁱ—Ca11—O10ⁱⁱⁱ	168.1 (2)	Na22—Si2—O1^vii	131.1 (2)
Na22ⁱ—Ca11—O13	77.95 (17)	Na22—Si2—O4	41.1 (2)
Si3ⁱⁱⁱ—Ca11—Al3ⁱⁱⁱ	0.0 (5)	Na22—Si2—O13^vii	116.4 (3)
Si3ⁱⁱⁱ—Ca11—Al4^xiv	51.61 (7)	Na22—Si2—O14^viii	65.8 (2)
Si3ⁱⁱⁱ—Ca11—Al5ⁱⁱ	92.50 (13)	Al2—Si2—O1^vii	0
Si3ⁱⁱⁱ—Ca11—Si6ⁱⁱⁱ	114.91 (12)	Al2—Si2—O4	0
Si3ⁱⁱⁱ—Ca11—Al6ⁱⁱⁱ	114.91 (12)	Al2—Si2—O13^vii	0
Si3ⁱⁱⁱ—Ca11—Si7ⁱⁱ	142.07 (15)	Al2—Si2—O14^viii	0
Si3ⁱⁱⁱ—Ca11—Al7ⁱⁱ	142.07 (15)	O1^vii—Si2—O4	108.0 (4)
Si3ⁱⁱⁱ—Ca11—Si8ⁱ	111.72 (13)	O1^vii—Si2—O13^vii	109.0 (3)
Si3ⁱⁱⁱ—Ca11—Al8ⁱ	111.72 (13)	O1^vii—Si2—O14^viii	111.3 (4)
Si3ⁱⁱⁱ—Ca11—O2ⁱ	126.1 (2)	O4—Si2—O13^vii	108.5 (3)
Si3ⁱⁱⁱ—Ca11—O9ⁱⁱ	114.4 (2)	O4—Si2—O14^viii	105.8 (3)
Si3ⁱⁱⁱ—Ca11—O10ⁱⁱⁱ	30.09 (14)	O13^vii—Si2—O14^viii	114.0 (4)
Si3ⁱⁱⁱ—Ca11—O13	95.29 (17)	Ca12^vii—Al2—Na12^vii	0.0 (5)
Al3ⁱⁱⁱ—Ca11—Al4^xiv	51.61 (7)	Ca12^vii—Al2—Ca21	82.68 (10)
Al3ⁱⁱⁱ—Ca11—Al5ⁱⁱ	92.50 (13)	Ca12^vii—Al2—Na22	80.39 (11)
Al3ⁱⁱⁱ—Ca11—Si6ⁱⁱⁱ	114.91 (12)	Ca12^vii—Al2—Si2	0
Al3ⁱⁱⁱ—Ca11—Al6ⁱⁱⁱ	114.91 (12)	Ca12^vii—Al2—Al5^xv	65.76 (10)
Al3ⁱⁱⁱ—Ca11—Si7ⁱⁱ	142.07 (15)	Ca12^vii—Al2—Al6^viii	61.56 (9)
Al3ⁱⁱⁱ—Ca11—Al7ⁱⁱ	142.07 (15)	Ca12^vii—Al2—Al7^viii	126.41 (13)
Al3ⁱⁱⁱ—Ca11—Si8ⁱ	111.72 (13)	Ca12^vii—Al2—O1^vii	134.0 (2)
Al3ⁱⁱⁱ—Ca11—Al8ⁱ	111.72 (13)	Ca12^vii—Al2—O4	72.4 (3)
Al3ⁱⁱⁱ—Ca11—O2ⁱ	126.1 (2)	Ca12^vii—Al2—O13^vii	38.6 (2)
Al3ⁱⁱⁱ—Ca11—O9ⁱⁱ	114.4 (2)	Ca12^vii—Al2—O14^viii	112.6 (3)
Al3ⁱⁱⁱ—Ca11—O10ⁱⁱⁱ	30.09 (14)	Na12^vii—Al2—Ca21	82.68 (10)
Al3ⁱⁱⁱ—Ca11—O13	95.29 (17)	Na12^vii—Al2—Na22	80.39 (11)
Al4^xiv—Ca11—Al5ⁱⁱ	75.71 (9)	Na12^vii—Al2—Si2	0
Al4^xiv—Ca11—Si6ⁱⁱⁱ	141.89 (14)	Na12^vii—Al2—Al5^xv	65.76 (10)
Al4^xiv—Ca11—Al6ⁱⁱⁱ	141.89 (14)	Na12^vii—Al2—Al6^viii	61.56 (9)
Al4^xiv—Ca11—Si7ⁱⁱ	98.84 (10)	Na12^vii—Al2—Al7^viii	126.41 (13)
Al4^xiv—Ca11—Al7ⁱⁱ	98.84 (10)	Na12^vii—Al2—O1^vii	134.0 (2)
Al4^xiv—Ca11—Si8ⁱ	154.37 (17)	Na12^vii—Al2—O4	72.4 (3)
Al4^xiv—Ca11—Al8ⁱ	154.37 (17)	Na12^vii—Al2—O13^vii	38.6 (2)
Al4^xiv—Ca11—O2ⁱ	175.0 (2)	Na12^vii—Al2—O14^viii	112.6 (3)
Al4^xiv—Ca11—O9ⁱⁱ	84.51 (17)	Ca21—Al2—Na22	11.87 (11)
Al4^xiv—Ca11—O10ⁱⁱⁱ	21.53 (14)	Ca21—Al2—Si2	0
Al4^xiv—Ca11—O13	108.96 (17)	Ca21—Al2—Al5^xv	57.00 (8)
Al5ⁱⁱ—Ca11—Si6ⁱⁱⁱ	141.98 (11)	Ca21—Al2—Al6^viii	143.93 (12)
Al5ⁱⁱ—Ca11—Al6ⁱⁱⁱ	141.98 (11)	Ca21—Al2—Al7^viii	97.20 (9)
Al5ⁱⁱ—Ca11—Si7ⁱⁱ	53.38 (8)	Ca21—Al2—O1^vii	121.8 (2)
Al5ⁱⁱ—Ca11—Al7ⁱⁱ	53.38 (8)	Ca21—Al2—O4	30.8 (2)
Al5ⁱⁱ—Ca11—Si8ⁱ	87.02 (11)	Ca21—Al2—O13^vii	120.8 (3)
Al5ⁱⁱ—Ca11—Al8ⁱ	87.02 (11)	Ca21—Al2—O14^viii	75.1 (2)
Al5ⁱⁱ—Ca11—O2ⁱ	109.2 (2)	Na22—Al2—Si2	0
Al5ⁱⁱ—Ca11—O9ⁱⁱ	23.6 (2)	Na22—Al2—Al5^xv	66.82 (10)
Al5ⁱⁱ—Ca11—O10ⁱⁱⁱ	81.4 (2)	Na22—Al2—Al6^viii	138.67 (13)
Al5ⁱⁱ—Ca11—O13	172.20 (19)	Na22—Al2—Al7^viii	89.18 (10)
Si6ⁱⁱⁱ—Ca11—Al6ⁱⁱⁱ	0.0 (5)	Na22—Al2—O1^vii	131.1 (2)
Si6ⁱⁱⁱ—Ca11—Si7ⁱⁱ	102.97 (11)	Na22—Al2—O4	41.1 (2)
Si6ⁱⁱⁱ—Ca11—Al7ⁱⁱ	102.97 (11)	Na22—Al2—O13^vii	116.4 (3)
Si6ⁱⁱⁱ—Ca11—Si8ⁱ	59.24 (9)	Na22—Al2—O14^viii	65.8 (2)
Si6ⁱⁱⁱ—Ca11—Al8ⁱ	59.24 (9)	Si2—Al2—Al5^xv	0
Si6ⁱⁱⁱ—Ca11—O2ⁱ	33.4 (2)	Si2—Al2—Al6^viii	0
Si6ⁱⁱⁱ—Ca11—O9ⁱⁱ	127.68 (19)	Si2—Al2—Al7^viii	0
Si6ⁱⁱⁱ—Ca11—O10ⁱⁱⁱ	135.1 (2)	Si2—Al2—O1^vii	0
Si6ⁱⁱⁱ—Ca11—O13	32.93 (14)	Si2—Al2—O4	0
Al6ⁱⁱⁱ—Ca11—Si7ⁱⁱ	102.97 (11)	Si2—Al2—O13^vii	0
Al6ⁱⁱⁱ—Ca11—Al7ⁱⁱ	102.97 (11)	Si2—Al2—O14^viii	0
Al6ⁱⁱⁱ—Ca11—Si8ⁱ	59.24 (9)	Al5^xv—Al2—Al6^viii	107.27 (8)
Al6ⁱⁱⁱ—Ca11—Al8ⁱ	59.24 (9)	Al5^xv—Al2—Al7^viii	152.00 (8)
Al6ⁱⁱⁱ—Ca11—O2ⁱ	33.4 (2)	Al5^xv—Al2—O1^vii	94.1 (2)
Al6ⁱⁱⁱ—Ca11—O9ⁱⁱ	127.68 (19)	Al5^xv—Al2—O4	26.2 (2)
Al6ⁱⁱⁱ—Ca11—O10ⁱⁱⁱ	135.1 (2)	Al5^xv—Al2—O13^vii	93.3 (2)
Al6ⁱⁱⁱ—Ca11—O13	32.93 (14)	Al5^xv—Al2—O14^viii	132.1 (2)
Si7ⁱⁱ—Ca11—Al7ⁱⁱ	0.0 (5)	Al6^viii—Al2—Al7^viii	100.28 (8)
Si7ⁱⁱ—Ca11—Si8ⁱ	85.29 (9)	Al6^viii—Al2—O1^vii	89.2 (2)
Si7ⁱⁱ—Ca11—Al8ⁱ	85.29 (9)	Al6^viii—Al2—O4	128.0 (2)
Si7ⁱⁱ—Ca11—O2ⁱ	85.10 (17)	Al6^viii—Al2—O13^vii	23.2 (2)
Si7ⁱⁱ—Ca11—O9ⁱⁱ	29.83 (19)	Al6^viii—Al2—O14^viii	112.8 (2)
Si7ⁱⁱ—Ca11—O10ⁱⁱⁱ	117.51 (19)	Al7^viii—Al2—O1^vii	91.2 (2)
Si7ⁱⁱ—Ca11—O13	119.1 (2)	Al7^viii—Al2—O4	127.0 (2)
Al7ⁱⁱ—Ca11—Si8ⁱ	85.29 (9)	Al7^viii—Al2—O13^vii	110.9 (2)
Al7ⁱⁱ—Ca11—Al8ⁱ	85.29 (9)	Al7^viii—Al2—O14^viii	24.3 (2)
Al7ⁱⁱ—Ca11—O2ⁱ	85.10 (17)	O1^vii—Al2—O4	108.0 (4)
Al7ⁱⁱ—Ca11—O9ⁱⁱ	29.83 (19)	O1^vii—Al2—O13^vii	109.0 (3)
Al7ⁱⁱ—Ca11—O10ⁱⁱⁱ	117.51 (19)	O1^vii—Al2—O14^viii	111.3 (4)
Al7ⁱⁱ—Ca11—O13	119.1 (2)	O4—Al2—O13^vii	108.5 (3)
Si8ⁱ—Ca11—Al8ⁱ	0.0 (5)	O4—Al2—O14^viii	105.8 (3)
Si8ⁱ—Ca11—O2ⁱ	28.4 (2)	O13^vii—Al2—O14^viii	114.0 (4)
Si8ⁱ—Ca11—O9ⁱⁱ	87.05 (17)	Ca11^ix—Si3—Na11^ix	0.0 (5)
Si8ⁱ—Ca11—O10ⁱⁱⁱ	138.2 (2)	Ca11^ix—Si3—Al3	0
Si8ⁱ—Ca11—O13	90.47 (17)	Ca11^ix—Si3—O3	124.1 (3)
Al8ⁱ—Ca11—O2ⁱ	28.4 (2)	Ca11^ix—Si3—O8	124.7 (2)
Al8ⁱ—Ca11—O9ⁱⁱ	87.05 (17)	Ca11^ix—Si3—O10	44.7 (2)
Al8ⁱ—Ca11—O10ⁱⁱⁱ	138.2 (2)	Ca11^ix—Si3—O11	59.8 (2)
Al8ⁱ—Ca11—O13	90.47 (17)	Na11^ix—Si3—Al3	0
O2ⁱ—Ca11—O9ⁱⁱ	100.4 (2)	Na11^ix—Si3—O3	124.1 (3)
O2ⁱ—Ca11—O10ⁱⁱⁱ	156.0 (3)	Na11^ix—Si3—O8	124.7 (2)
O2ⁱ—Ca11—O13	66.3 (2)	Na11^ix—Si3—O10	44.7 (2)
O9ⁱⁱ—Ca11—O10ⁱⁱⁱ	97.0 (3)	Na11^ix—Si3—O11	59.8 (2)
O9ⁱⁱ—Ca11—O13	148.9 (3)	Al3—Si3—O3	0
O10ⁱⁱⁱ—Ca11—O13	105.2 (2)	Al3—Si3—O8	0
Ca11—Na11—Ca12	0	Al3—Si3—O10	0
Ca11—Na11—Na12	0	Al3—Si3—O11	0
Ca11—Na11—Ca21ⁱ	0	O3—Si3—O8	109.8 (3)
Ca11—Na11—Na22ⁱ	0	O3—Si3—O10	108.5 (3)
Ca11—Na11—Si3ⁱⁱⁱ	0	O3—Si3—O11	112.5 (4)
Ca11—Na11—Al3ⁱⁱⁱ	0	O8—Si3—O10	110.0 (3)
Ca11—Na11—Al4^xiv	0	O8—Si3—O11	111.3 (4)
Ca11—Na11—Al5ⁱⁱ	0	O10—Si3—O11	104.5 (3)
Ca11—Na11—Si6ⁱⁱⁱ	0	Ca11^ix—Al3—Na11^ix	0.0 (5)
Ca11—Na11—Al6ⁱⁱⁱ	0	Ca11^ix—Al3—Ca12^ix	15.19 (10)
Ca11—Na11—Si7ⁱⁱ	0	Ca11^ix—Al3—Na12^ix	15.19 (10)
Ca11—Na11—Al7ⁱⁱ	0	Ca11^ix—Al3—Ca21^xix	87.47 (11)
Ca11—Na11—Si8ⁱ	0	Ca11^ix—Al3—Al1	81.93 (9)
Ca11—Na11—Al8ⁱ	0	Ca11^ix—Al3—Si3	0
Ca11—Na11—O2ⁱ	0	Ca11^ix—Al3—Al4ⁱⁱⁱ	71.15 (8)
Ca11—Na11—O9ⁱⁱ	0	Ca11^ix—Al3—Al6^xi	143.29 (12)
Ca11—Na11—O10ⁱⁱⁱ	0	Ca11^ix—Al3—O3	124.1 (3)
Ca11—Na11—O13	0	Ca11^ix—Al3—O8	124.7 (2)
Ca12—Na11—Na12	0.0 (5)	Ca11^ix—Al3—O10	44.7 (2)
Ca12—Na11—Ca21ⁱ	82.5 (3)	Ca11^ix—Al3—O11	59.8 (2)
Ca12—Na11—Na22ⁱ	93.4 (3)	Na11^ix—Al3—Ca12^ix	15.19 (10)
Ca12—Na11—Si3ⁱⁱⁱ	102.8 (3)	Na11^ix—Al3—Na12^ix	15.19 (10)
Ca12—Na11—Al3ⁱⁱⁱ	102.8 (3)	Na11^ix—Al3—Ca21^xix	87.47 (11)
Ca12—Na11—Al4^xiv	56.2 (3)	Na11^ix—Al3—Al1	81.93 (9)
Ca12—Na11—Al5ⁱⁱ	93.7 (4)	Na11^ix—Al3—Si3	0
Ca12—Na11—Si6ⁱⁱⁱ	104.4 (5)	Na11^ix—Al3—Al4ⁱⁱⁱ	71.15 (8)
Ca12—Na11—Al6ⁱⁱⁱ	104.4 (5)	Na11^ix—Al3—Al6^xi	143.29 (12)
Ca12—Na11—Si7ⁱⁱ	68.0 (3)	Na11^ix—Al3—O3	124.1 (3)
Ca12—Na11—Al7ⁱⁱ	68.0 (3)	Na11^ix—Al3—O8	124.7 (2)
Ca12—Na11—Si8ⁱ	145.4 (4)	Na11^ix—Al3—O10	44.7 (2)
Ca12—Na11—Al8ⁱ	145.4 (4)	Na11^ix—Al3—O11	59.8 (2)
Ca12—Na11—O2ⁱ	123.3 (5)	Ca12^ix—Al3—Na12^ix	0.0 (5)
Ca12—Na11—O9ⁱⁱ	80.5 (4)	Ca12^ix—Al3—Ca21^xix	88.46 (12)
Ca12—Na11—O10ⁱⁱⁱ	75.7 (4)	Ca12^ix—Al3—Al1	94.89 (10)
Ca12—Na11—O13	84.2 (5)	Ca12^ix—Al3—Si3	0
Na12—Na11—Ca21ⁱ	82.5 (3)	Ca12^ix—Al3—Al4ⁱⁱⁱ	57.53 (9)
Na12—Na11—Na22ⁱ	93.4 (3)	Ca12^ix—Al3—Al6^xi	148.54 (12)
Na12—Na11—Si3ⁱⁱⁱ	102.8 (3)	Ca12^ix—Al3—O3	114.8 (3)
Na12—Na11—Al3ⁱⁱⁱ	102.8 (3)	Ca12^ix—Al3—O8	128.5 (2)
Na12—Na11—Al4^xiv	56.2 (3)	Ca12^ix—Al3—O10	31.6 (2)
Na12—Na11—Al5ⁱⁱ	93.7 (4)	Ca12^ix—Al3—O11	73.6 (3)
Na12—Na11—Si6ⁱⁱⁱ	104.4 (5)	Na12^ix—Al3—Ca21^xix	88.46 (12)
Na12—Na11—Al6ⁱⁱⁱ	104.4 (5)	Na12^ix—Al3—Al1	94.89 (10)
Na12—Na11—Si7ⁱⁱ	68.0 (3)	Na12^ix—Al3—Si3	0
Na12—Na11—Al7ⁱⁱ	68.0 (3)	Na12^ix—Al3—Al4ⁱⁱⁱ	57.53 (9)
Na12—Na11—Si8ⁱ	145.4 (4)	Na12^ix—Al3—Al6^xi	148.54 (12)
Na12—Na11—Al8ⁱ	145.4 (4)	Na12^ix—Al3—O3	114.8 (3)
Na12—Na11—O2ⁱ	123.3 (5)	Na12^ix—Al3—O8	128.5 (2)
Na12—Na11—O9ⁱⁱ	80.5 (4)	Na12^ix—Al3—O10	31.6 (2)
Na12—Na11—O10ⁱⁱⁱ	75.7 (4)	Na12^ix—Al3—O11	73.6 (3)
Na12—Na11—O13	84.2 (5)	Ca21^xix—Al3—Al1	117.51 (10)
Ca21ⁱ—Na11—Na22ⁱ	11.00 (10)	Ca21^xix—Al3—Si3	0
Ca21ⁱ—Na11—Si3ⁱⁱⁱ	168.90 (14)	Ca21^xix—Al3—Al4ⁱⁱⁱ	68.95 (10)
Ca21ⁱ—Na11—Al3ⁱⁱⁱ	168.90 (14)	Ca21^xix—Al3—Al6^xi	60.21 (9)
Ca21ⁱ—Na11—Al4^xiv	136.81 (12)	Ca21^xix—Al3—O3	137.3 (3)
Ca21ⁱ—Na11—Al5ⁱⁱ	96.91 (10)	Ca21^xix—Al3—O8	40.35 (19)
Ca21ⁱ—Na11—Si6ⁱⁱⁱ	54.04 (9)	Ca21^xix—Al3—O10	72.3 (3)
Ca21ⁱ—Na11—Al6ⁱⁱⁱ	54.04 (9)	Ca21^xix—Al3—O11	108.2 (3)
Ca21ⁱ—Na11—Si7ⁱⁱ	48.94 (8)	Al1—Al3—Si3	0
Ca21ⁱ—Na11—Al7ⁱⁱ	48.94 (8)	Al1—Al3—Al4ⁱⁱⁱ	152.25 (11)
Ca21ⁱ—Na11—Si8ⁱ	63.13 (9)	Al1—Al3—Al6^xi	97.22 (9)
Ca21ⁱ—Na11—Al8ⁱ	63.13 (9)	Al1—Al3—O3	96.7 (2)
Ca21ⁱ—Na11—O2ⁱ	44.76 (19)	Al1—Al3—O8	104.2 (2)
Ca21ⁱ—Na11—O9ⁱⁱ	75.88 (19)	Al1—Al3—O10	126.4 (2)
Ca21ⁱ—Na11—O10ⁱⁱⁱ	158.0 (2)	Al1—Al3—O11	22.7 (2)
Ca21ⁱ—Na11—O13	75.38 (18)	Si3—Al3—Al4ⁱⁱⁱ	0
Na22ⁱ—Na11—Si3ⁱⁱⁱ	161.79 (14)	Si3—Al3—Al6^xi	0
Na22ⁱ—Na11—Al3ⁱⁱⁱ	161.79 (14)	Si3—Al3—O3	0
Na22ⁱ—Na11—Al4^xiv	146.57 (13)	Si3—Al3—O8	0
Na22ⁱ—Na11—Al5ⁱⁱ	94.72 (10)	Si3—Al3—O10	0
Na22ⁱ—Na11—Si6ⁱⁱⁱ	51.77 (9)	Si3—Al3—O11	0
Na22ⁱ—Na11—Al6ⁱⁱⁱ	51.77 (9)	Al4ⁱⁱⁱ—Al3—Al6^xi	108.30 (10)
Na22ⁱ—Na11—Si7ⁱⁱ	52.52 (9)	Al4ⁱⁱⁱ—Al3—O3	93.0 (2)
Na22ⁱ—Na11—Al7ⁱⁱ	52.52 (9)	Al4ⁱⁱⁱ—Al3—O8	96.8 (2)
Na22ⁱ—Na11—Si8ⁱ	52.16 (10)	Al4ⁱⁱⁱ—Al3—O10	26.49 (18)
Na22ⁱ—Na11—Al8ⁱ	52.16 (10)	Al4ⁱⁱⁱ—Al3—O11	130.9 (3)
Na22ⁱ—Na11—O2ⁱ	35.72 (19)	Al6^xi—Al3—O3	92.5 (3)
Na22ⁱ—Na11—O9ⁱⁱ	76.12 (19)	Al6^xi—Al3—O8	19.99 (18)
Na22ⁱ—Na11—O10ⁱⁱⁱ	168.1 (2)	Al6^xi—Al3—O10	126.9 (3)
Na22ⁱ—Na11—O13	77.95 (17)	Al6^xi—Al3—O11	111.4 (3)
Si3ⁱⁱⁱ—Na11—Al3ⁱⁱⁱ	0.0 (5)	O3—Al3—O8	109.8 (3)
Si3ⁱⁱⁱ—Na11—Al4^xiv	51.61 (7)	O3—Al3—O10	108.5 (3)
Si3ⁱⁱⁱ—Na11—Al5ⁱⁱ	92.50 (13)	O3—Al3—O11	112.5 (4)
Si3ⁱⁱⁱ—Na11—Si6ⁱⁱⁱ	114.91 (12)	O8—Al3—O10	110.0 (3)
Si3ⁱⁱⁱ—Na11—Al6ⁱⁱⁱ	114.91 (12)	O8—Al3—O11	111.3 (4)
Si3ⁱⁱⁱ—Na11—Si7ⁱⁱ	142.07 (15)	O10—Al3—O11	104.5 (3)
Si3ⁱⁱⁱ—Na11—Al7ⁱⁱ	142.07 (15)	Ca12^xx—Si4—Na12^xx	0.0 (5)
Si3ⁱⁱⁱ—Na11—Si8ⁱ	111.72 (13)	Ca12^xx—Si4—Al4	0
Si3ⁱⁱⁱ—Na11—Al8ⁱ	111.72 (13)	Ca12^xx—Si4—O5	114.4 (3)
Si3ⁱⁱⁱ—Na11—O2ⁱ	126.1 (2)	Ca12^xx—Si4—O6	62.1 (2)
Si3ⁱⁱⁱ—Na11—O9ⁱⁱ	114.4 (2)	Ca12^xx—Si4—O10^ix	44.1 (2)
Si3ⁱⁱⁱ—Na11—O10ⁱⁱⁱ	30.09 (14)	Ca12^xx—Si4—O16	132.2 (3)
Si3ⁱⁱⁱ—Na11—O13	95.29 (17)	Na12^xx—Si4—Al4	0
Al3ⁱⁱⁱ—Na11—Al4^xiv	51.61 (7)	Na12^xx—Si4—O5	114.4 (3)
Al3ⁱⁱⁱ—Na11—Al5ⁱⁱ	92.50 (13)	Na12^xx—Si4—O6	62.1 (2)
Al3ⁱⁱⁱ—Na11—Si6ⁱⁱⁱ	114.91 (12)	Na12^xx—Si4—O10^ix	44.1 (2)
Al3ⁱⁱⁱ—Na11—Al6ⁱⁱⁱ	114.91 (12)	Na12^xx—Si4—O16	132.2 (3)
Al3ⁱⁱⁱ—Na11—Si7ⁱⁱ	142.07 (15)	Al4—Si4—O5	0
Al3ⁱⁱⁱ—Na11—Al7ⁱⁱ	142.07 (15)	Al4—Si4—O6	0
Al3ⁱⁱⁱ—Na11—Si8ⁱ	111.72 (13)	Al4—Si4—O10^ix	0
Al3ⁱⁱⁱ—Na11—Al8ⁱ	111.72 (13)	Al4—Si4—O16	0
Al3ⁱⁱⁱ—Na11—O2ⁱ	126.1 (2)	O5—Si4—O6	111.7 (4)
Al3ⁱⁱⁱ—Na11—O9ⁱⁱ	114.4 (2)	O5—Si4—O10^ix	107.2 (3)
Al3ⁱⁱⁱ—Na11—O10ⁱⁱⁱ	30.09 (14)	O5—Si4—O16	111.8 (3)
Al3ⁱⁱⁱ—Na11—O13	95.29 (17)	O6—Si4—O10^ix	105.3 (3)
Al4^xiv—Na11—Al5ⁱⁱ	75.71 (9)	O6—Si4—O16	110.7 (4)
Al4^xiv—Na11—Si6ⁱⁱⁱ	141.89 (14)	O10^ix—Si4—O16	109.9 (4)
Al4^xiv—Na11—Al6ⁱⁱⁱ	141.89 (14)	Ca11^xx—Al4—Na11^xx	0.0 (5)
Al4^xiv—Na11—Si7ⁱⁱ	98.84 (10)	Ca11^xx—Al4—Ca12^xx	14.41 (12)
Al4^xiv—Na11—Al7ⁱⁱ	98.84 (10)	Ca11^xx—Al4—Na12^xx	14.41 (12)
Al4^xiv—Na11—Si8ⁱ	154.37 (17)	Ca11^xx—Al4—Ca21^xviii	78.93 (10)
Al4^xiv—Na11—Al8ⁱ	154.37 (17)	Ca11^xx—Al4—Na22^xvii	85.49 (10)
Al4^xiv—Na11—O2ⁱ	175.0 (2)	Ca11^xx—Al4—Al3^ix	57.24 (8)
Al4^xiv—Na11—O9ⁱⁱ	84.51 (17)	Ca11^xx—Al4—Si4	0
Al4^xiv—Na11—O10ⁱⁱⁱ	21.53 (14)	Ca11^xx—Al4—Al6	97.14 (8)
Al4^xiv—Na11—O13	108.96 (17)	Ca11^xx—Al4—Al7	142.89 (12)
Al5ⁱⁱ—Na11—Si6ⁱⁱⁱ	141.98 (11)	Ca11^xx—Al4—O5	118.5 (3)
Al5ⁱⁱ—Na11—Al6ⁱⁱⁱ	141.98 (11)	Ca11^xx—Al4—O6	74.4 (2)
Al5ⁱⁱ—Na11—Si7ⁱⁱ	53.38 (8)	Ca11^xx—Al4—O10^ix	30.9 (2)
Al5ⁱⁱ—Na11—Al7ⁱⁱ	53.38 (8)	Ca11^xx—Al4—O16	122.9 (2)
Al5ⁱⁱ—Na11—Si8ⁱ	87.02 (11)	Na11^xx—Al4—Ca12^xx	14.41 (12)
Al5ⁱⁱ—Na11—Al8ⁱ	87.02 (11)	Na11^xx—Al4—Na12^xx	14.41 (12)
Al5ⁱⁱ—Na11—O2ⁱ	109.2 (2)	Na11^xx—Al4—Ca21^xviii	78.93 (10)
Al5ⁱⁱ—Na11—O9ⁱⁱ	23.6 (2)	Na11^xx—Al4—Na22^xvii	85.49 (10)
Al5ⁱⁱ—Na11—O10ⁱⁱⁱ	81.4 (2)	Na11^xx—Al4—Al3^ix	57.24 (8)
Al5ⁱⁱ—Na11—O13	172.20 (19)	Na11^xx—Al4—Si4	0
Si6ⁱⁱⁱ—Na11—Al6ⁱⁱⁱ	0.0 (5)	Na11^xx—Al4—Al6	97.14 (8)
Si6ⁱⁱⁱ—Na11—Si7ⁱⁱ	102.97 (11)	Na11^xx—Al4—Al7	142.89 (12)
Si6ⁱⁱⁱ—Na11—Al7ⁱⁱ	102.97 (11)	Na11^xx—Al4—O5	118.5 (3)
Si6ⁱⁱⁱ—Na11—Si8ⁱ	59.24 (9)	Na11^xx—Al4—O6	74.4 (2)
Si6ⁱⁱⁱ—Na11—Al8ⁱ	59.24 (9)	Na11^xx—Al4—O10^ix	30.9 (2)
Si6ⁱⁱⁱ—Na11—O2ⁱ	33.4 (2)	Na11^xx—Al4—O16	122.9 (2)
Si6ⁱⁱⁱ—Na11—O9ⁱⁱ	127.68 (19)	Ca12^xx—Al4—Na12^xx	0.0 (5)
Si6ⁱⁱⁱ—Na11—O10ⁱⁱⁱ	135.1 (2)	Ca12^xx—Al4—Ca21^xviii	90.89 (13)
Si6ⁱⁱⁱ—Na11—O13	32.93 (14)	Ca12^xx—Al4—Na22^xvii	83.60 (12)
Al6ⁱⁱⁱ—Na11—Si7ⁱⁱ	102.97 (11)	Ca12^xx—Al4—Al3^ix	70.00 (10)
Al6ⁱⁱⁱ—Na11—Al7ⁱⁱ	102.97 (11)	Ca12^xx—Al4—Si4	0
Al6ⁱⁱⁱ—Na11—Si8ⁱ	59.24 (9)	Ca12^xx—Al4—Al6	86.27 (10)
Al6ⁱⁱⁱ—Na11—Al8ⁱ	59.24 (9)	Ca12^xx—Al4—Al7	137.32 (15)
Al6ⁱⁱⁱ—Na11—O2ⁱ	33.4 (2)	Ca12^xx—Al4—O5	114.4 (3)
Al6ⁱⁱⁱ—Na11—O9ⁱⁱ	127.68 (19)	Ca12^xx—Al4—O6	62.1 (2)
Al6ⁱⁱⁱ—Na11—O10ⁱⁱⁱ	135.1 (2)	Ca12^xx—Al4—O10^ix	44.1 (2)
Al6ⁱⁱⁱ—Na11—O13	32.93 (14)	Ca12^xx—Al4—O16	132.2 (3)
Si7ⁱⁱ—Na11—Al7ⁱⁱ	0.0 (5)	Na12^xx—Al4—Ca21^xviii	90.89 (13)
Si7ⁱⁱ—Na11—Si8ⁱ	85.29 (9)	Na12^xx—Al4—Na22^xvii	83.60 (12)
Si7ⁱⁱ—Na11—Al8ⁱ	85.29 (9)	Na12^xx—Al4—Al3^ix	70.00 (10)
Si7ⁱⁱ—Na11—O2ⁱ	85.10 (17)	Na12^xx—Al4—Si4	0
Si7ⁱⁱ—Na11—O9ⁱⁱ	29.83 (19)	Na12^xx—Al4—Al6	86.27 (10)
Si7ⁱⁱ—Na11—O10ⁱⁱⁱ	117.51 (19)	Na12^xx—Al4—Al7	137.32 (15)
Si7ⁱⁱ—Na11—O13	119.1 (2)	Na12^xx—Al4—O5	114.4 (3)
Al7ⁱⁱ—Na11—Si8ⁱ	85.29 (9)	Na12^xx—Al4—O6	62.1 (2)
Al7ⁱⁱ—Na11—Al8ⁱ	85.29 (9)	Na12^xx—Al4—O10^ix	44.1 (2)
Al7ⁱⁱ—Na11—O2ⁱ	85.10 (17)	Na12^xx—Al4—O16	132.2 (3)
Al7ⁱⁱ—Na11—O9ⁱⁱ	29.83 (19)	Ca21^xviii—Al4—Na22^xvii	130.29 (12)
Al7ⁱⁱ—Na11—O10ⁱⁱⁱ	117.51 (19)	Ca21^xviii—Al4—Al3^ix	62.18 (9)
Al7ⁱⁱ—Na11—O13	119.1 (2)	Ca21^xviii—Al4—Si4	0
Si8ⁱ—Na11—Al8ⁱ	0.0 (5)	Ca21^xviii—Al4—Al6	105.30 (10)
Si8ⁱ—Na11—O2ⁱ	28.4 (2)	Ca21^xviii—Al4—Al7	126.74 (10)
Si8ⁱ—Na11—O9ⁱⁱ	87.05 (17)	Ca21^xviii—Al4—O5	136.6 (3)
Si8ⁱ—Na11—O10ⁱⁱⁱ	138.2 (2)	Ca21^xviii—Al4—O6	111.3 (3)
Si8ⁱ—Na11—O13	90.47 (17)	Ca21^xviii—Al4—O10^ix	66.3 (3)
Al8ⁱ—Na11—O2ⁱ	28.4 (2)	Ca21^xviii—Al4—O16	45.2 (2)
Al8ⁱ—Na11—O9ⁱⁱ	87.05 (17)	Na22^xvii—Al4—Al3^ix	69.64 (10)
Al8ⁱ—Na11—O10ⁱⁱⁱ	138.2 (2)	Na22^xvii—Al4—Si4	0
Al8ⁱ—Na11—O13	90.47 (17)	Na22^xvii—Al4—Al6	123.43 (13)
O2ⁱ—Na11—O9ⁱⁱ	100.4 (2)	Na22^xvii—Al4—Al7	57.64 (8)
O2ⁱ—Na11—O10ⁱⁱⁱ	156.0 (3)	Na22^xvii—Al4—O5	33.3 (2)
O2ⁱ—Na11—O13	66.3 (2)	Na22^xvii—Al4—O6	109.3 (3)
O9ⁱⁱ—Na11—O10ⁱⁱⁱ	97.0 (3)	Na22^xvii—Al4—O10^ix	76.3 (2)
O9ⁱⁱ—Na11—O13	148.9 (3)	Na22^xvii—Al4—O16	135.9 (2)
O10ⁱⁱⁱ—Na11—O13	105.2 (2)	Al3^ix—Al4—Si4	0
Ca11—Ca12—Na11	0.0 (5)	Al3^ix—Al4—Al6	152.13 (8)
Ca11—Ca12—Na12	0	Al3^ix—Al4—Al7	107.37 (8)
Ca11—Ca12—Ca21ⁱ	83.9 (3)	Al3^ix—Al4—O5	92.7 (2)
Ca11—Ca12—Na22ⁱ	73.1 (3)	Al3^ix—Al4—O6	131.7 (2)
Ca11—Ca12—Si1^iv	135.7 (4)	Al3^ix—Al4—O10^ix	26.40 (19)
Ca11—Ca12—Al1^iv	135.7 (4)	Al3^ix—Al4—O16	96.4 (3)
Ca11—Ca12—Al2^xi	90.2 (4)	Si4—Al4—Al6	0
Ca11—Ca12—Al3ⁱⁱⁱ	62.0 (3)	Si4—Al4—Al7	0
Ca11—Ca12—Si4^xiv	109.4 (4)	Si4—Al4—O5	0
Ca11—Ca12—Al4^xiv	109.4 (4)	Si4—Al4—O6	0
Ca11—Ca12—Al5^iv	138.8 (5)	Si4—Al4—O10^ix	0
Ca11—Ca12—Al6ⁱⁱⁱ	60.1 (4)	Si4—Al4—O16	0
Ca11—Ca12—Si7ⁱⁱ	95.5 (3)	Al6—Al4—Al7	99.94 (8)
Ca11—Ca12—Al7ⁱⁱ	95.5 (3)	Al6—Al4—O5	110.8 (3)
Ca11—Ca12—O9ⁱⁱ	77.2 (4)	Al6—Al4—O6	25.5 (3)
Ca11—Ca12—O10ⁱⁱⁱ	80.6 (4)	Al6—Al4—O10^ix	126.95 (19)
Ca11—Ca12—O13	74.1 (4)	Al6—Al4—O16	88.8 (2)
Ca11—Ca12—O15^iv	110.3 (4)	Al7—Al4—O5	24.4 (2)
Na11—Ca12—Na12	0	Al7—Al4—O6	111.5 (3)
Na11—Ca12—Ca21ⁱ	83.9 (3)	Al7—Al4—O10^ix	127.9 (2)
Na11—Ca12—Na22ⁱ	73.1 (3)	Al7—Al4—O16	90.3 (2)
Na11—Ca12—Si1^iv	135.7 (4)	O5—Al4—O6	111.7 (4)
Na11—Ca12—Al1^iv	135.7 (4)	O5—Al4—O10^ix	107.2 (3)
Na11—Ca12—Al2^xi	90.2 (4)	O5—Al4—O16	111.8 (3)
Na11—Ca12—Al3ⁱⁱⁱ	62.0 (3)	O6—Al4—O10^ix	105.3 (3)
Na11—Ca12—Si4^xiv	109.4 (4)	O6—Al4—O16	110.7 (4)
Na11—Ca12—Al4^xiv	109.4 (4)	O10^ix—Al4—O16	109.9 (4)
Na11—Ca12—Al5^iv	138.8 (5)	Ca21^x—Si5—Al5	0
Na11—Ca12—Al6ⁱⁱⁱ	60.1 (4)	Ca21^x—Si5—O4^x	45.3 (2)
Na11—Ca12—Si7ⁱⁱ	95.5 (3)	Ca21^x—Si5—O7^xi	56.9 (2)
Na11—Ca12—Al7ⁱⁱ	95.5 (3)	Ca21^x—Si5—O9	120.5 (2)
Na11—Ca12—O9ⁱⁱ	77.2 (4)	Ca21^x—Si5—O12	125.1 (3)
Na11—Ca12—O10ⁱⁱⁱ	80.6 (4)	Al5—Si5—O4^x	0
Na11—Ca12—O13	74.1 (4)	Al5—Si5—O7^xi	0
Na11—Ca12—O15^iv	110.3 (4)	Al5—Si5—O9	0
Na12—Ca12—Ca21ⁱ	0	Al5—Si5—O12	0
Na12—Ca12—Na22ⁱ	0	O4^x—Si5—O7^xi	102.1 (3)
Na12—Ca12—Si1^iv	0	O4^x—Si5—O9	106.9 (3)
Na12—Ca12—Al1^iv	0	O4^x—Si5—O12	107.8 (3)
Na12—Ca12—Al2^xi	0	O7^xi—Si5—O9	112.7 (4)
Na12—Ca12—Al3ⁱⁱⁱ	0	O7^xi—Si5—O12	113.7 (4)
Na12—Ca12—Si4^xiv	0	O9—Si5—O12	112.8 (4)
Na12—Ca12—Al4^xiv	0	Ca11^xxi—Al5—Na11^xxi	0.0 (5)
Na12—Ca12—Al5^iv	0	Ca11^xxi—Al5—Ca12^xvii	134.44 (11)
Na12—Ca12—Al6ⁱⁱⁱ	0	Ca11^xxi—Al5—Na12^xvii	134.44 (11)
Na12—Ca12—Si7ⁱⁱ	0	Ca11^xxi—Al5—Ca21^x	86.74 (11)
Na12—Ca12—Al7ⁱⁱ	0	Ca11^xxi—Al5—Na22^x	89.69 (10)
Na12—Ca12—O9ⁱⁱ	0	Ca11^xxi—Al5—Al2^x	70.00 (9)
Na12—Ca12—O10ⁱⁱⁱ	0	Ca11^xxi—Al5—Si5	0
Na12—Ca12—O13	0	Ca11^xxi—Al5—Al7	59.92 (9)
Na12—Ca12—O15^iv	0	Ca11^xxi—Al5—Al8^xxii	116.51 (10)
Ca21ⁱ—Ca12—Na22ⁱ	10.90 (10)	Ca11^xxi—Al5—O4^x	72.7 (3)
Ca21ⁱ—Ca12—Si1^iv	52.00 (10)	Ca11^xxi—Al5—O7^xi	107.8 (3)
Ca21ⁱ—Ca12—Al1^iv	52.00 (10)	Ca11^xxi—Al5—O9	36.69 (19)
Ca21ⁱ—Ca12—Al2^xi	93.49 (14)	Ca11^xxi—Al5—O12	137.1 (3)
Ca21ⁱ—Ca12—Al3ⁱⁱⁱ	144.57 (15)	Na11^xxi—Al5—Ca12^xvii	134.44 (11)
Ca21ⁱ—Ca12—Si4^xiv	161.39 (16)	Na11^xxi—Al5—Na12^xvii	134.44 (11)
Ca21ⁱ—Ca12—Al4^xiv	161.39 (16)	Na11^xxi—Al5—Ca21^x	86.74 (11)
Ca21ⁱ—Ca12—Al5^iv	95.39 (15)	Na11^xxi—Al5—Na22^x	89.69 (10)
Ca21ⁱ—Ca12—Al6ⁱⁱⁱ	52.45 (9)	Na11^xxi—Al5—Al2^x	70.00 (9)
Ca21ⁱ—Ca12—Si7ⁱⁱ	49.90 (9)	Na11^xxi—Al5—Si5	0
Ca21ⁱ—Ca12—Al7ⁱⁱ	49.90 (9)	Na11^xxi—Al5—Al7	59.92 (9)
Ca21ⁱ—Ca12—O9ⁱⁱ	75.87 (19)	Na11^xxi—Al5—Al8^xxii	116.51 (10)
Ca21ⁱ—Ca12—O10ⁱⁱⁱ	164.1 (3)	Na11^xxi—Al5—O4^x	72.7 (3)
Ca21ⁱ—Ca12—O13	74.87 (17)	Na11^xxi—Al5—O7^xi	107.8 (3)
Ca21ⁱ—Ca12—O15^iv	32.56 (19)	Na11^xxi—Al5—O9	36.69 (19)
Na22ⁱ—Ca12—Si1^iv	62.88 (11)	Na11^xxi—Al5—O12	137.1 (3)
Na22ⁱ—Ca12—Al1^iv	62.88 (11)	Ca12^xvii—Al5—Na12^xvii	0.0 (5)
Na22ⁱ—Ca12—Al2^xi	94.86 (14)	Ca12^xvii—Al5—Ca21^x	88.80 (12)
Na22ⁱ—Ca12—Al3ⁱⁱⁱ	134.36 (15)	Ca12^xvii—Al5—Na22^x	78.47 (11)
Na22ⁱ—Ca12—Si4^xiv	165.57 (17)	Ca12^xvii—Al5—Al2^x	65.59 (10)
Na22ⁱ—Ca12—Al4^xiv	165.57 (17)	Ca12^xvii—Al5—Si5	0
Na22ⁱ—Ca12—Al5^iv	104.42 (15)	Ca12^xvii—Al5—Al7	126.95 (9)
Na22ⁱ—Ca12—Al6ⁱⁱⁱ	48.45 (9)	Ca12^xvii—Al5—Al8^xxii	107.52 (12)
Na22ⁱ—Ca12—Si7ⁱⁱ	51.63 (10)	Ca12^xvii—Al5—O4^x	72.3 (3)
Na22ⁱ—Ca12—Al7ⁱⁱ	51.63 (10)	Ca12^xvii—Al5—O7^xi	107.3 (3)
Na22ⁱ—Ca12—O9ⁱⁱ	72.48 (19)	Ca12^xvii—Al5—O9	139.0 (2)
Na22ⁱ—Ca12—O10ⁱⁱⁱ	153.2 (3)	Ca12^xvii—Al5—O12	38.6 (3)
Na22ⁱ—Ca12—O13	73.81 (17)	Na12^xvii—Al5—Ca21^x	88.80 (12)
Na22ⁱ—Ca12—O15^iv	41.12 (19)	Na12^xvii—Al5—Na22^x	78.47 (11)
Si1^iv—Ca12—Al1^iv	0.0 (5)	Na12^xvii—Al5—Al2^x	65.59 (10)
Si1^iv—Ca12—Al2^xi	89.12 (16)	Na12^xvii—Al5—Si5	0
Si1^iv—Ca12—Al3ⁱⁱⁱ	158.90 (16)	Na12^xvii—Al5—Al7	126.95 (9)
Si1^iv—Ca12—Si4^xiv	114.42 (15)	Na12^xvii—Al5—Al8^xxii	107.52 (12)
Si1^iv—Ca12—Al4^xiv	114.42 (15)	Na12^xvii—Al5—O4^x	72.3 (3)
Si1^iv—Ca12—Al5^iv	55.56 (11)	Na12^xvii—Al5—O7^xi	107.3 (3)
Si1^iv—Ca12—Al6ⁱⁱⁱ	86.03 (14)	Na12^xvii—Al5—O9	139.0 (2)
Si1^iv—Ca12—Si7ⁱⁱ	60.97 (10)	Na12^xvii—Al5—O12	38.6 (3)
Si1^iv—Ca12—Al7ⁱⁱ	60.97 (10)	Ca21^x—Al5—Na22^x	12.04 (10)
Si1^iv—Ca12—O9ⁱⁱ	93.3 (2)	Ca21^x—Al5—Al2^x	71.70 (9)
Si1^iv—Ca12—O10ⁱⁱⁱ	143.7 (2)	Ca21^x—Al5—Si5	0
Si1^iv—Ca12—O13	89.0 (2)	Ca21^x—Al5—Al7	142.03 (12)
Si1^iv—Ca12—O15^iv	32.2 (2)	Ca21^x—Al5—Al8^xxii	81.40 (9)
Al1^iv—Ca12—Al2^xi	89.12 (16)	Ca21^x—Al5—O4^x	45.3 (2)
Al1^iv—Ca12—Al3ⁱⁱⁱ	158.90 (16)	Ca21^x—Al5—O7^xi	56.9 (2)
Al1^iv—Ca12—Si4^xiv	114.42 (15)	Ca21^x—Al5—O9	120.5 (2)
Al1^iv—Ca12—Al4^xiv	114.42 (15)	Ca21^x—Al5—O12	125.1 (3)
Al1^iv—Ca12—Al5^iv	55.56 (11)	Na22^x—Al5—Al2^x	61.88 (10)
Al1^iv—Ca12—Al6ⁱⁱⁱ	86.03 (14)	Na22^x—Al5—Si5	0
Al1^iv—Ca12—Si7ⁱⁱ	60.97 (10)	Na22^x—Al5—Al7	148.82 (11)
Al1^iv—Ca12—Al7ⁱⁱ	60.97 (10)	Na22^x—Al5—Al8^xxii	90.48 (10)
Al1^iv—Ca12—O9ⁱⁱ	93.3 (2)	Na22^x—Al5—O4^x	36.0 (2)
Al1^iv—Ca12—O10ⁱⁱⁱ	143.7 (2)	Na22^x—Al5—O7^xi	66.6 (3)
Al1^iv—Ca12—O13	89.0 (2)	Na22^x—Al5—O9	125.7 (2)
Al1^iv—Ca12—O15^iv	32.2 (2)	Na22^x—Al5—O12	116.2 (3)
Al2^xi—Ca12—Al3ⁱⁱⁱ	78.28 (10)	Al2^x—Al5—Si5	0
Al2^xi—Ca12—Si4^xiv	99.32 (11)	Al2^x—Al5—Al7	108.74 (10)
Al2^xi—Ca12—Al4^xiv	99.32 (11)	Al2^x—Al5—Al8^xxii	152.11 (11)
Al2^xi—Ca12—Al5^iv	48.65 (9)	Al2^x—Al5—O4^x	26.43 (19)
Al2^xi—Ca12—Al6ⁱⁱⁱ	51.30 (9)	Al2^x—Al5—O7^xi	128.4 (3)
Al2^xi—Ca12—Si7ⁱⁱ	141.74 (18)	Al2^x—Al5—O9	95.1 (2)
Al2^xi—Ca12—Al7ⁱⁱ	141.74 (18)	Al2^x—Al5—O12	91.8 (2)
Al2^xi—Ca12—O9ⁱⁱ	164.1 (2)	Si5—Al5—Al7	0
Al2^xi—Ca12—O10ⁱⁱⁱ	89.9 (2)	Si5—Al5—Al8^xxii	0
Al2^xi—Ca12—O13	23.64 (13)	Si5—Al5—O4^x	0
Al2^xi—Ca12—O15^iv	111.3 (3)	Si5—Al5—O7^xi	0
Al3ⁱⁱⁱ—Ca12—Si4^xiv	52.47 (8)	Si5—Al5—O9	0
Al3ⁱⁱⁱ—Ca12—Al4^xiv	52.47 (8)	Si5—Al5—O12	0
Al3ⁱⁱⁱ—Ca12—Al5^iv	103.94 (11)	Al7—Al5—Al8^xxii	96.89 (9)
Al3ⁱⁱⁱ—Ca12—Al6ⁱⁱⁱ	98.75 (12)	Al7—Al5—O4^x	126.9 (3)
Al3ⁱⁱⁱ—Ca12—Si7ⁱⁱ	137.0 (2)	Al7—Al5—O7^xi	113.6 (3)
Al3ⁱⁱⁱ—Ca12—Al7ⁱⁱ	137.0 (2)	Al7—Al5—O9	23.33 (19)
Al3ⁱⁱⁱ—Ca12—O9ⁱⁱ	103.5 (3)	Al7—Al5—O12	92.8 (3)
Al3ⁱⁱⁱ—Ca12—O10ⁱⁱⁱ	22.38 (15)	Al8^xxii—Al5—O4^x	126.4 (2)
Al3ⁱⁱⁱ—Ca12—O13	86.10 (19)	Al8^xxii—Al5—O7^xi	24.8 (2)
Al3ⁱⁱⁱ—Ca12—O15^iv	168.4 (3)	Al8^xxii—Al5—O9	104.9 (2)
Si4^xiv—Ca12—Al4^xiv	0.0 (5)	Al8^xxii—Al5—O12	97.9 (2)
Si4^xiv—Ca12—Al5^iv	83.23 (11)	O4^x—Al5—O7^xi	102.1 (3)
Si4^xiv—Ca12—Al6ⁱⁱⁱ	145.47 (14)	O4^x—Al5—O9	106.9 (3)
Si4^xiv—Ca12—Si7ⁱⁱ	114.10 (16)	O4^x—Al5—O12	107.8 (3)
Si4^xiv—Ca12—Al7ⁱⁱ	114.10 (16)	O7^xi—Al5—O9	112.7 (4)
Si4^xiv—Ca12—O9ⁱⁱ	94.0 (2)	O7^xi—Al5—O12	113.7 (4)
Si4^xiv—Ca12—O10ⁱⁱⁱ	30.44 (15)	O9—Al5—O12	112.8 (4)
Si4^xiv—Ca12—O13	120.62 (18)	Ca11^ix—Si6—Na11^ix	0.0 (5)
Si4^xiv—Ca12—O15^iv	129.0 (2)	Ca11^ix—Si6—Ca21^xii	77.32 (10)
Al4^xiv—Ca12—Al5^iv	83.23 (11)	Ca11^ix—Si6—Na22^xii	77.41 (11)
Al4^xiv—Ca12—Al6ⁱⁱⁱ	145.47 (14)	Ca11^ix—Si6—Al6	0
Al4^xiv—Ca12—Si7ⁱⁱ	114.10 (16)	Ca11^ix—Si6—O2^xii	49.7 (2)
Al4^xiv—Ca12—Al7ⁱⁱ	114.10 (16)	Ca11^ix—Si6—O6	131.2 (3)
Al4^xiv—Ca12—O9ⁱⁱ	94.0 (2)	Ca11^ix—Si6—O8^vii	117.4 (2)
Al4^xiv—Ca12—O10ⁱⁱⁱ	30.44 (15)	Ca11^ix—Si6—O13^ix	52.7 (3)
Al4^xiv—Ca12—O13	120.62 (18)	Na11^ix—Si6—Ca21^xii	77.32 (10)
Al4^xiv—Ca12—O15^iv	129.0 (2)	Na11^ix—Si6—Na22^xii	77.41 (11)
Al5^iv—Ca12—Al6ⁱⁱⁱ	86.95 (14)	Na11^ix—Si6—Al6	0
Al5^iv—Ca12—Si7ⁱⁱ	115.40 (16)	Na11^ix—Si6—O2^xii	49.7 (2)
Al5^iv—Ca12—Al7ⁱⁱ	115.40 (16)	Na11^ix—Si6—O6	131.2 (3)
Al5^iv—Ca12—O9ⁱⁱ	142.7 (2)	Na11^ix—Si6—O8^vii	117.4 (2)
Al5^iv—Ca12—O10ⁱⁱⁱ	98.5 (2)	Na11^ix—Si6—O13^ix	52.7 (3)
Al5^iv—Ca12—O13	66.14 (19)	Ca21^xii—Si6—Na22^xii	13.18 (12)
Al5^iv—Ca12—O15^iv	87.5 (2)	Ca21^xii—Si6—Al6	0
Al6ⁱⁱⁱ—Ca12—Si7ⁱⁱ	100.02 (12)	Ca21^xii—Si6—O2^xii	59.4 (3)
Al6ⁱⁱⁱ—Ca12—Al7ⁱⁱ	100.02 (12)	Ca21^xii—Si6—O6	143.3 (2)
Al6ⁱⁱⁱ—Ca12—O9ⁱⁱ	113.19 (19)	Ca21^xii—Si6—O8^vii	46.4 (2)
Al6ⁱⁱⁱ—Ca12—O10ⁱⁱⁱ	120.5 (2)	Ca21^xii—Si6—O13^ix	106.9 (2)
Al6ⁱⁱⁱ—Ca12—O13	27.75 (13)	Na22^xii—Si6—Al6	0
Al6ⁱⁱⁱ—Ca12—O15^iv	83.3 (2)	Na22^xii—Si6—O2^xii	49.5 (3)
Si7ⁱⁱ—Ca12—Al7ⁱⁱ	0.0 (5)	Na22^xii—Si6—O6	134.9 (2)
Si7ⁱⁱ—Ca12—O9ⁱⁱ	33.53 (18)	Na22^xii—Si6—O8^vii	54.1 (2)
Si7ⁱⁱ—Ca12—O10ⁱⁱⁱ	128.4 (3)	Na22^xii—Si6—O13^ix	115.6 (2)
Si7ⁱⁱ—Ca12—O13	124.7 (2)	Al6—Si6—O2^xii	0
Si7ⁱⁱ—Ca12—O15^iv	32.0 (2)	Al6—Si6—O6	0
Al7ⁱⁱ—Ca12—O9ⁱⁱ	33.53 (18)	Al6—Si6—O8^vii	0
Al7ⁱⁱ—Ca12—O10ⁱⁱⁱ	128.4 (3)	Al6—Si6—O13^ix	0
Al7ⁱⁱ—Ca12—O13	124.7 (2)	O2^xii—Si6—O6	117.1 (4)
Al7ⁱⁱ—Ca12—O15^iv	32.0 (2)	O2^xii—Si6—O8^vii	103.4 (3)
O9ⁱⁱ—Ca12—O10ⁱⁱⁱ	97.3 (3)	O2^xii—Si6—O13^ix	102.3 (3)
O9ⁱⁱ—Ca12—O13	140.6 (2)	O6—Si6—O8^vii	111.3 (4)
O9ⁱⁱ—Ca12—O15^iv	65.5 (3)	O6—Si6—O13^ix	109.3 (3)
O10ⁱⁱⁱ—Ca12—O13	103.8 (3)	O8^vii—Si6—O13^ix	113.1 (3)
O10ⁱⁱⁱ—Ca12—O15^iv	155.5 (3)	Ca11^ix—Al6—Na11^ix	0.0 (5)
O13—Ca12—O15^iv	100.4 (3)	Ca11^ix—Al6—Ca12^ix	15.47 (12)
Ca11—Na12—Na11	0.0 (5)	Ca11^ix—Al6—Na12^ix	15.47 (12)
Ca11—Na12—Ca12	0	Ca11^ix—Al6—Ca21^xii	77.32 (10)
Ca11—Na12—Ca21ⁱ	83.9 (3)	Ca11^ix—Al6—Na22^xii	77.41 (11)
Ca11—Na12—Na22ⁱ	73.1 (3)	Ca11^ix—Al6—Al2^xxii	74.92 (9)
Ca11—Na12—Si1^iv	135.7 (4)	Ca11^ix—Al6—Al3^vii	131.48 (11)
Ca11—Na12—Al1^iv	135.7 (4)	Ca11^ix—Al6—Al4	107.79 (11)
Ca11—Na12—Al2^xi	90.2 (4)	Ca11^ix—Al6—Si6	0
Ca11—Na12—Al3ⁱⁱⁱ	62.0 (3)	Ca11^ix—Al6—O2^xii	49.7 (2)
Ca11—Na12—Si4^xiv	109.4 (4)	Ca11^ix—Al6—O6	131.2 (3)
Ca11—Na12—Al4^xiv	109.4 (4)	Ca11^ix—Al6—O8^vii	117.4 (2)
Ca11—Na12—Al5^iv	138.8 (5)	Ca11^ix—Al6—O13^ix	52.7 (3)
Ca11—Na12—Al6ⁱⁱⁱ	60.1 (4)	Na11^ix—Al6—Ca12^ix	15.47 (12)
Ca11—Na12—Si7ⁱⁱ	95.5 (3)	Na11^ix—Al6—Na12^ix	15.47 (12)
Ca11—Na12—Al7ⁱⁱ	95.5 (3)	Na11^ix—Al6—Ca21^xii	77.32 (10)
Ca11—Na12—O9ⁱⁱ	77.2 (4)	Na11^ix—Al6—Na22^xii	77.41 (11)
Ca11—Na12—O10ⁱⁱⁱ	80.6 (4)	Na11^ix—Al6—Al2^xxii	74.92 (9)
Ca11—Na12—O13	74.1 (4)	Na11^ix—Al6—Al3^vii	131.48 (11)
Ca11—Na12—O15^iv	110.3 (4)	Na11^ix—Al6—Al4	107.79 (11)
Na11—Na12—Ca12	0	Na11^ix—Al6—Si6	0
Na11—Na12—Ca21ⁱ	83.9 (3)	Na11^ix—Al6—O2^xii	49.7 (2)
Na11—Na12—Na22ⁱ	73.1 (3)	Na11^ix—Al6—O6	131.2 (3)
Na11—Na12—Si1^iv	135.7 (4)	Na11^ix—Al6—O8^vii	117.4 (2)
Na11—Na12—Al1^iv	135.7 (4)	Na11^ix—Al6—O13^ix	52.7 (3)
Na11—Na12—Al2^xi	90.2 (4)	Ca12^ix—Al6—Na12^ix	0.0 (5)
Na11—Na12—Al3ⁱⁱⁱ	62.0 (3)	Ca12^ix—Al6—Ca21^xii	72.33 (10)
Na11—Na12—Si4^xiv	109.4 (4)	Ca12^ix—Al6—Na22^xii	75.96 (11)
Na11—Na12—Al4^xiv	109.4 (4)	Ca12^ix—Al6—Al2^xxii	67.14 (9)
Na11—Na12—Al5^iv	138.8 (5)	Ca12^ix—Al6—Al3^vii	117.55 (12)
Na11—Na12—Al6ⁱⁱⁱ	60.1 (4)	Ca12^ix—Al6—Al4	117.58 (11)
Na11—Na12—Si7ⁱⁱ	95.5 (3)	Ca12^ix—Al6—Si6	0
Na11—Na12—Al7ⁱⁱ	95.5 (3)	Ca12^ix—Al6—O2^xii	60.4 (2)
Na11—Na12—O9ⁱⁱ	77.2 (4)	Ca12^ix—Al6—O6	141.4 (3)
Na11—Na12—O10ⁱⁱⁱ	80.6 (4)	Ca12^ix—Al6—O8^vii	106.1 (2)
Na11—Na12—O13	74.1 (4)	Ca12^ix—Al6—O13^ix	44.8 (2)
Na11—Na12—O15^iv	110.3 (4)	Na12^ix—Al6—Ca21^xii	72.33 (10)
Ca12—Na12—Ca21ⁱ	0	Na12^ix—Al6—Na22^xii	75.96 (11)
Ca12—Na12—Na22ⁱ	0	Na12^ix—Al6—Al2^xxii	67.14 (9)
Ca12—Na12—Si1^iv	0	Na12^ix—Al6—Al3^vii	117.55 (12)
Ca12—Na12—Al1^iv	0	Na12^ix—Al6—Al4	117.58 (11)
Ca12—Na12—Al2^xi	0	Na12^ix—Al6—Si6	0
Ca12—Na12—Al3ⁱⁱⁱ	0	Na12^ix—Al6—O2^xii	60.4 (2)
Ca12—Na12—Si4^xiv	0	Na12^ix—Al6—O6	141.4 (3)
Ca12—Na12—Al4^xiv	0	Na12^ix—Al6—O8^vii	106.1 (2)
Ca12—Na12—Al5^iv	0	Na12^ix—Al6—O13^ix	44.8 (2)
Ca12—Na12—Al6ⁱⁱⁱ	0	Ca21^xii—Al6—Na22^xii	13.18 (12)
Ca12—Na12—Si7ⁱⁱ	0	Ca21^xii—Al6—Al2^xxii	120.61 (10)
Ca12—Na12—Al7ⁱⁱ	0	Ca21^xii—Al6—Al3^vii	65.95 (10)
Ca12—Na12—O9ⁱⁱ	0	Ca21^xii—Al6—Al4	159.20 (11)
Ca12—Na12—O10ⁱⁱⁱ	0	Ca21^xii—Al6—Si6	0
Ca12—Na12—O13	0	Ca21^xii—Al6—O2^xii	59.4 (3)
Ca12—Na12—O15^iv	0	Ca21^xii—Al6—O6	143.3 (2)
Ca21ⁱ—Na12—Na22ⁱ	10.90 (10)	Ca21^xii—Al6—O8^vii	46.4 (2)
Ca21ⁱ—Na12—Si1^iv	52.00 (10)	Ca21^xii—Al6—O13^ix	106.9 (2)
Ca21ⁱ—Na12—Al1^iv	52.00 (10)	Na22^xii—Al6—Al2^xxii	132.07 (12)
Ca21ⁱ—Na12—Al2^xi	93.49 (14)	Na22^xii—Al6—Al3^vii	73.64 (10)
Ca21ⁱ—Na12—Al3ⁱⁱⁱ	144.57 (15)	Na22^xii—Al6—Al4	146.43 (13)
Ca21ⁱ—Na12—Si4^xiv	161.39 (16)	Na22^xii—Al6—Si6	0
Ca21ⁱ—Na12—Al4^xiv	161.39 (16)	Na22^xii—Al6—O2^xii	49.5 (3)
Ca21ⁱ—Na12—Al5^iv	95.39 (15)	Na22^xii—Al6—O6	134.9 (2)
Ca21ⁱ—Na12—Al6ⁱⁱⁱ	52.45 (9)	Na22^xii—Al6—O8^vii	54.1 (2)
Ca21ⁱ—Na12—Si7ⁱⁱ	49.90 (9)	Na22^xii—Al6—O13^ix	115.6 (2)
Ca21ⁱ—Na12—Al7ⁱⁱ	49.90 (9)	Al2^xxii—Al6—Al3^vii	97.06 (10)
Ca21ⁱ—Na12—O9ⁱⁱ	75.87 (19)	Al2^xxii—Al6—Al4	79.94 (7)
Ca21ⁱ—Na12—O10ⁱⁱⁱ	164.1 (3)	Al2^xxii—Al6—Si6	0
Ca21ⁱ—Na12—O13	74.87 (17)	Al2^xxii—Al6—O2^xii	124.2 (2)
Ca21ⁱ—Na12—O15^iv	32.56 (19)	Al2^xxii—Al6—O6	92.3 (2)
Na22ⁱ—Na12—Si1^iv	62.88 (11)	Al2^xxii—Al6—O8^vii	108.2 (2)
Na22ⁱ—Na12—Al1^iv	62.88 (11)	Al2^xxii—Al6—O13^ix	22.5 (2)
Na22ⁱ—Na12—Al2^xi	94.86 (14)	Al3^vii—Al6—Al4	117.92 (10)
Na22ⁱ—Na12—Al3ⁱⁱⁱ	134.36 (15)	Al3^vii—Al6—Si6	0
Na22ⁱ—Na12—Si4^xiv	165.57 (17)	Al3^vii—Al6—O2^xii	122.7 (3)
Na22ⁱ—Na12—Al4^xiv	165.57 (17)	Al3^vii—Al6—O6	96.3 (3)
Na22ⁱ—Na12—Al5^iv	104.42 (15)	Al3^vii—Al6—O8^vii	19.7 (2)
Na22ⁱ—Na12—Al6ⁱⁱⁱ	48.45 (9)	Al3^vii—Al6—O13^ix	108.8 (3)
Na22ⁱ—Na12—Si7ⁱⁱ	51.63 (10)	Al4—Al6—Si6	0
Na22ⁱ—Na12—Al7ⁱⁱ	51.63 (10)	Al4—Al6—O2^xii	107.9 (3)
Na22ⁱ—Na12—O9ⁱⁱ	72.48 (19)	Al4—Al6—O6	23.9 (3)
Na22ⁱ—Na12—O10ⁱⁱⁱ	153.2 (3)	Al4—Al6—O8^vii	134.7 (2)
Na22ⁱ—Na12—O13	73.81 (17)	Al4—Al6—O13^ix	91.4 (2)
Na22ⁱ—Na12—O15^iv	41.12 (19)	Si6—Al6—O2^xii	0
Si1^iv—Na12—Al1^iv	0.0 (5)	Si6—Al6—O6	0
Si1^iv—Na12—Al2^xi	89.12 (16)	Si6—Al6—O8^vii	0
Si1^iv—Na12—Al3ⁱⁱⁱ	158.90 (16)	Si6—Al6—O13^ix	0
Si1^iv—Na12—Si4^xiv	114.42 (15)	O2^xii—Al6—O6	117.1 (4)
Si1^iv—Na12—Al4^xiv	114.42 (15)	O2^xii—Al6—O8^vii	103.4 (3)
Si1^iv—Na12—Al5^iv	55.56 (11)	O2^xii—Al6—O13^ix	102.3 (3)
Si1^iv—Na12—Al6ⁱⁱⁱ	86.03 (14)	O6—Al6—O8^vii	111.3 (4)
Si1^iv—Na12—Si7ⁱⁱ	60.97 (10)	O6—Al6—O13^ix	109.3 (3)
Si1^iv—Na12—Al7ⁱⁱ	60.97 (10)	O8^vii—Al6—O13^ix	113.1 (3)
Si1^iv—Na12—O9ⁱⁱ	93.3 (2)	Ca11^xxi—Si7—Na11^xxi	0.0 (5)
Si1^iv—Na12—O10ⁱⁱⁱ	143.7 (2)	Ca11^xxi—Si7—Ca12^xxi	16.45 (11)
Si1^iv—Na12—O13	89.0 (2)	Ca11^xxi—Si7—Na12^xxi	16.45 (11)
Si1^iv—Na12—O15^iv	32.2 (2)	Ca11^xxi—Si7—Ca21^xvii	76.90 (11)
Al1^iv—Na12—Al2^xi	89.12 (16)	Ca11^xxi—Si7—Na22^xvii	72.47 (10)
Al1^iv—Na12—Al3ⁱⁱⁱ	158.90 (16)	Ca11^xxi—Si7—Al7	0
Al1^iv—Na12—Si4^xiv	114.42 (15)	Ca11^xxi—Si7—O5	106.6 (2)
Al1^iv—Na12—Al4^xiv	114.42 (15)	Ca11^xxi—Si7—O9	44.7 (3)
Al1^iv—Na12—Al5^iv	55.56 (11)	Ca11^xxi—Si7—O14	141.9 (2)
Al1^iv—Na12—Al6ⁱⁱⁱ	86.03 (14)	Ca11^xxi—Si7—O15^xiii	57.0 (3)
Al1^iv—Na12—Si7ⁱⁱ	60.97 (10)	Na11^xxi—Si7—Ca12^xxi	16.45 (11)
Al1^iv—Na12—Al7ⁱⁱ	60.97 (10)	Na11^xxi—Si7—Na12^xxi	16.45 (11)
Al1^iv—Na12—O9ⁱⁱ	93.3 (2)	Na11^xxi—Si7—Ca21^xvii	76.90 (11)
Al1^iv—Na12—O10ⁱⁱⁱ	143.7 (2)	Na11^xxi—Si7—Na22^xvii	72.47 (10)
Al1^iv—Na12—O13	89.0 (2)	Na11^xxi—Si7—Al7	0
Al1^iv—Na12—O15^iv	32.2 (2)	Na11^xxi—Si7—O5	106.6 (2)
Al2^xi—Na12—Al3ⁱⁱⁱ	78.28 (10)	Na11^xxi—Si7—O9	44.7 (3)
Al2^xi—Na12—Si4^xiv	99.32 (11)	Na11^xxi—Si7—O14	141.9 (2)
Al2^xi—Na12—Al4^xiv	99.32 (11)	Na11^xxi—Si7—O15^xiii	57.0 (3)
Al2^xi—Na12—Al5^iv	48.65 (9)	Ca12^xxi—Si7—Na12^xxi	0.0 (5)
Al2^xi—Na12—Al6ⁱⁱⁱ	51.30 (9)	Ca12^xxi—Si7—Ca21^xvii	80.09 (12)
Al2^xi—Na12—Si7ⁱⁱ	141.74 (18)	Ca12^xxi—Si7—Na22^xvii	79.41 (12)
Al2^xi—Na12—Al7ⁱⁱ	141.74 (18)	Ca12^xxi—Si7—Al7	0
Al2^xi—Na12—O9ⁱⁱ	164.1 (2)	Ca12^xxi—Si7—O5	119.4 (2)
Al2^xi—Na12—O10ⁱⁱⁱ	89.9 (2)	Ca12^xxi—Si7—O9	52.3 (3)
Al2^xi—Na12—O13	23.64 (13)	Ca12^xxi—Si7—O14	128.8 (2)
Al2^xi—Na12—O15^iv	111.3 (3)	Ca12^xxi—Si7—O15^xiii	47.4 (3)
Al3ⁱⁱⁱ—Na12—Si4^xiv	52.47 (8)	Na12^xxi—Si7—Ca21^xvii	80.09 (12)
Al3ⁱⁱⁱ—Na12—Al4^xiv	52.47 (8)	Na12^xxi—Si7—Na22^xvii	79.41 (12)
Al3ⁱⁱⁱ—Na12—Al5^iv	103.94 (11)	Na12^xxi—Si7—Al7	0
Al3ⁱⁱⁱ—Na12—Al6ⁱⁱⁱ	98.75 (12)	Na12^xxi—Si7—O5	119.4 (2)
Al3ⁱⁱⁱ—Na12—Si7ⁱⁱ	137.0 (2)	Na12^xxi—Si7—O9	52.3 (3)
Al3ⁱⁱⁱ—Na12—Al7ⁱⁱ	137.0 (2)	Na12^xxi—Si7—O14	128.8 (2)
Al3ⁱⁱⁱ—Na12—O9ⁱⁱ	103.5 (3)	Na12^xxi—Si7—O15^xiii	47.4 (3)
Al3ⁱⁱⁱ—Na12—O10ⁱⁱⁱ	22.38 (15)	Ca21^xvii—Si7—Na22^xvii	13.71 (12)
Al3ⁱⁱⁱ—Na12—O13	86.10 (19)	Ca21^xvii—Si7—Al7	0
Al3ⁱⁱⁱ—Na12—O15^iv	168.4 (3)	Ca21^xvii—Si7—O5	52.4 (3)
Si4^xiv—Na12—Al4^xiv	0.0 (5)	Ca21^xvii—Si7—O9	115.8 (2)
Si4^xiv—Na12—Al5^iv	83.23 (11)	Ca21^xvii—Si7—O14	130.9 (3)
Si4^xiv—Na12—Al6ⁱⁱⁱ	145.47 (14)	Ca21^xvii—Si7—O15^xiii	49.7 (2)
Si4^xiv—Na12—Si7ⁱⁱ	114.10 (16)	Na22^xvii—Si7—Al7	0
Si4^xiv—Na12—Al7ⁱⁱ	114.10 (16)	Na22^xvii—Si7—O5	45.3 (2)
Si4^xiv—Na12—O9ⁱⁱ	94.0 (2)	Na22^xvii—Si7—O9	106.0 (2)
Si4^xiv—Na12—O10ⁱⁱⁱ	30.44 (15)	Na22^xvii—Si7—O14	140.7 (3)
Si4^xiv—Na12—O13	120.62 (18)	Na22^xvii—Si7—O15^xiii	58.7 (2)
Si4^xiv—Na12—O15^iv	129.0 (2)	Al7—Si7—O5	0
Al4^xiv—Na12—Al5^iv	83.23 (11)	Al7—Si7—O9	0
Al4^xiv—Na12—Al6ⁱⁱⁱ	145.47 (14)	Al7—Si7—O14	0
Al4^xiv—Na12—Si7ⁱⁱ	114.10 (16)	Al7—Si7—O15^xiii	0
Al4^xiv—Na12—Al7ⁱⁱ	114.10 (16)	O5—Si7—O9	113.3 (3)
Al4^xiv—Na12—O9ⁱⁱ	94.0 (2)	O5—Si7—O14	111.3 (3)
Al4^xiv—Na12—O10ⁱⁱⁱ	30.44 (15)	O5—Si7—O15^xiii	102.1 (4)
Al4^xiv—Na12—O13	120.62 (18)	O9—Si7—O14	113.1 (4)
Al4^xiv—Na12—O15^iv	129.0 (2)	O9—Si7—O15^xiii	99.6 (4)
Al5^iv—Na12—Al6ⁱⁱⁱ	86.95 (14)	O14—Si7—O15^xiii	116.6 (4)
Al5^iv—Na12—Si7ⁱⁱ	115.40 (16)	Ca11^xxi—Al7—Na11^xxi	0.0 (5)
Al5^iv—Na12—Al7ⁱⁱ	115.40 (16)	Ca11^xxi—Al7—Ca12^xxi	16.45 (11)
Al5^iv—Na12—O9ⁱⁱ	142.7 (2)	Ca11^xxi—Al7—Na12^xxi	16.45 (11)
Al5^iv—Na12—O10ⁱⁱⁱ	98.5 (2)	Ca11^xxi—Al7—Ca21^xvii	76.90 (11)
Al5^iv—Na12—O13	66.14 (19)	Ca11^xxi—Al7—Na22^xvii	72.47 (10)
Al5^iv—Na12—O15^iv	87.5 (2)	Ca11^xxi—Al7—Al2^xxii	158.60 (11)
Al6ⁱⁱⁱ—Na12—Si7ⁱⁱ	100.02 (12)	Ca11^xxi—Al7—Al4	121.25 (10)
Al6ⁱⁱⁱ—Na12—Al7ⁱⁱ	100.02 (12)	Ca11^xxi—Al7—Al5	66.71 (10)
Al6ⁱⁱⁱ—Na12—O9ⁱⁱ	113.19 (19)	Ca11^xxi—Al7—Si7	0
Al6ⁱⁱⁱ—Na12—O10ⁱⁱⁱ	120.5 (2)	Ca11^xxi—Al7—O5	106.6 (2)
Al6ⁱⁱⁱ—Na12—O13	27.75 (13)	Ca11^xxi—Al7—O9	44.7 (3)
Al6ⁱⁱⁱ—Na12—O15^iv	83.3 (2)	Ca11^xxi—Al7—O14	141.9 (2)
Si7ⁱⁱ—Na12—Al7ⁱⁱ	0.0 (5)	Ca11^xxi—Al7—O15^xiii	57.0 (3)
Si7ⁱⁱ—Na12—O9ⁱⁱ	33.53 (18)	Na11^xxi—Al7—Ca12^xxi	16.45 (11)
Si7ⁱⁱ—Na12—O10ⁱⁱⁱ	128.4 (3)	Na11^xxi—Al7—Na12^xxi	16.45 (11)
Si7ⁱⁱ—Na12—O13	124.7 (2)	Na11^xxi—Al7—Ca21^xvii	76.90 (11)
Si7ⁱⁱ—Na12—O15^iv	32.0 (2)	Na11^xxi—Al7—Na22^xvii	72.47 (10)
Al7ⁱⁱ—Na12—O9ⁱⁱ	33.53 (18)	Na11^xxi—Al7—Al2^xxii	158.60 (11)
Al7ⁱⁱ—Na12—O10ⁱⁱⁱ	128.4 (3)	Na11^xxi—Al7—Al4	121.25 (10)
Al7ⁱⁱ—Na12—O13	124.7 (2)	Na11^xxi—Al7—Al5	66.71 (10)
Al7ⁱⁱ—Na12—O15^iv	32.0 (2)	Na11^xxi—Al7—Si7	0
O9ⁱⁱ—Na12—O10ⁱⁱⁱ	97.3 (3)	Na11^xxi—Al7—O5	106.6 (2)
O9ⁱⁱ—Na12—O13	140.6 (2)	Na11^xxi—Al7—O9	44.7 (3)
O9ⁱⁱ—Na12—O15^iv	65.5 (3)	Na11^xxi—Al7—O14	141.9 (2)
O10ⁱⁱⁱ—Na12—O13	103.8 (3)	Na11^xxi—Al7—O15^xiii	57.0 (3)
O10ⁱⁱⁱ—Na12—O15^iv	155.5 (3)	Ca12^xxi—Al7—Na12^xxi	0.0 (5)
O13—Na12—O15^iv	100.4 (3)	Ca12^xxi—Al7—Ca21^xvii	80.09 (12)
Ca11^xiii—Ca21—Na11^xiii	0.0 (5)	Ca12^xxi—Al7—Na22^xvii	79.41 (12)
Ca11^xiii—Ca21—Ca12^xiii	13.61 (9)	Ca12^xxi—Al7—Al2^xxii	142.19 (12)
Ca11^xiii—Ca21—Na12^xiii	13.61 (9)	Ca12^xxi—Al7—Al4	136.89 (12)
Ca11^xiii—Ca21—Na22	75.1 (4)	Ca12^xxi—Al7—Al5	73.81 (12)
Ca11^xiii—Ca21—Si1^vi	62.66 (9)	Ca12^xxi—Al7—Si7	0
Ca11^xiii—Ca21—Al1^vi	62.66 (9)	Ca12^xxi—Al7—O5	119.4 (2)
Ca11^xiii—Ca21—Al2	136.24 (13)	Ca12^xxi—Al7—O9	52.3 (3)
Ca11^xiii—Ca21—Al3^v	96.97 (10)	Ca12^xxi—Al7—O14	128.8 (2)
Ca11^xiii—Ca21—Al4^vi	104.74 (10)	Ca12^xxi—Al7—O15^xiii	47.4 (3)
Ca11^xiii—Ca21—Si5^xv	168.72 (15)	Na12^xxi—Al7—Ca21^xvii	80.09 (12)
Ca11^xiii—Ca21—Al5^xv	168.72 (15)	Na12^xxi—Al7—Na22^xvii	79.41 (12)
Ca11^xiii—Ca21—Si6^xvi	48.64 (8)	Na12^xxi—Al7—Al2^xxii	142.19 (12)
Ca11^xiii—Ca21—Al6^xvi	48.64 (8)	Na12^xxi—Al7—Al4	136.89 (12)
Ca11^xiii—Ca21—Si7^iv	54.15 (9)	Na12^xxi—Al7—Al5	73.81 (12)
Ca11^xiii—Ca21—Al7^iv	54.15 (9)	Na12^xxi—Al7—Si7	0
Ca11^xiii—Ca21—O4	157.0 (2)	Na12^xxi—Al7—O5	119.4 (2)
Ca11^xiii—Ca21—O5^iv	75.69 (18)	Na12^xxi—Al7—O9	52.3 (3)
Ca11^xiii—Ca21—O8^v	74.58 (18)	Na12^xxi—Al7—O14	128.8 (2)
Ca11^xiii—Ca21—O15^vi	43.39 (18)	Na12^xxi—Al7—O15^xiii	47.4 (3)
Na11^xiii—Ca21—Ca12^xiii	13.61 (9)	Ca21^xvii—Al7—Na22^xvii	13.71 (12)
Na11^xiii—Ca21—Na12^xiii	13.61 (9)	Ca21^xvii—Al7—Al2^xxii	107.62 (11)
Na11^xiii—Ca21—Na22	75.1 (4)	Ca21^xvii—Al7—Al4	75.95 (9)
Na11^xiii—Ca21—Si1^vi	62.66 (9)	Ca21^xvii—Al7—Al5	131.87 (11)
Na11^xiii—Ca21—Al1^vi	62.66 (9)	Ca21^xvii—Al7—Si7	0
Na11^xiii—Ca21—Al2	136.24 (13)	Ca21^xvii—Al7—O5	52.4 (3)
Na11^xiii—Ca21—Al3^v	96.97 (10)	Ca21^xvii—Al7—O9	115.8 (2)
Na11^xiii—Ca21—Al4^vi	104.74 (10)	Ca21^xvii—Al7—O14	130.9 (3)
Na11^xiii—Ca21—Si5^xv	168.72 (15)	Ca21^xvii—Al7—O15^xiii	49.7 (2)
Na11^xiii—Ca21—Al5^xv	168.72 (15)	Na22^xvii—Al7—Al2^xxii	116.48 (11)
Na11^xiii—Ca21—Si6^xvi	48.64 (8)	Na22^xvii—Al7—Al4	69.04 (9)
Na11^xiii—Ca21—Al6^xvi	48.64 (8)	Na22^xvii—Al7—Al5	119.55 (12)
Na11^xiii—Ca21—Si7^iv	54.15 (9)	Na22^xvii—Al7—Si7	0
Na11^xiii—Ca21—Al7^iv	54.15 (9)	Na22^xvii—Al7—O5	45.3 (2)
Na11^xiii—Ca21—O4	157.0 (2)	Na22^xvii—Al7—O9	106.0 (2)
Na11^xiii—Ca21—O5^iv	75.69 (18)	Na22^xvii—Al7—O14	140.7 (3)
Na11^xiii—Ca21—O8^v	74.58 (18)	Na22^xvii—Al7—O15^xiii	58.7 (2)
Na11^xiii—Ca21—O15^vi	43.39 (18)	Al2^xxii—Al7—Al4	79.84 (7)
Ca12^xiii—Ca21—Na12^xiii	0.0 (5)	Al2^xxii—Al7—Al5	117.88 (10)
Ca12^xiii—Ca21—Na22	88.6 (4)	Al2^xxii—Al7—Si7	0
Ca12^xiii—Ca21—Si1^vi	49.07 (10)	Al2^xxii—Al7—O5	91.9 (2)
Ca12^xiii—Ca21—Al1^vi	49.07 (10)	Al2^xxii—Al7—O9	136.6 (2)
Ca12^xiii—Ca21—Al2	149.23 (14)	Al2^xxii—Al7—O14	24.3 (2)
Ca12^xiii—Ca21—Al3^v	96.33 (11)	Al2^xxii—Al7—O15^xiii	109.3 (3)
Ca12^xiii—Ca21—Al4^vi	94.01 (11)	Al4—Al7—Al5	96.63 (10)
Ca12^xiii—Ca21—Si5^xv	159.26 (15)	Al4—Al7—Si7	0
Ca12^xiii—Ca21—Al5^xv	159.26 (15)	Al4—Al7—O5	23.8 (2)
Ca12^xiii—Ca21—Si6^xvi	55.22 (9)	Al4—Al7—O9	109.0 (2)
Ca12^xiii—Ca21—Al6^xvi	55.22 (9)	Al4—Al7—O14	93.6 (2)
Ca12^xiii—Ca21—Si7^iv	50.01 (9)	Al4—Al7—O15^xiii	125.4 (2)
Ca12^xiii—Ca21—Al7^iv	50.01 (9)	Al5—Al7—Si7	0
Ca12^xiii—Ca21—O4	170.4 (2)	Al5—Al7—O5	109.1 (3)
Ca12^xiii—Ca21—O5^iv	77.38 (18)	Al5—Al7—O9	22.1 (2)
Ca12^xiii—Ca21—O8^v	77.25 (18)	Al5—Al7—O14	96.7 (3)
Ca12^xiii—Ca21—O15^vi	31.64 (17)	Al5—Al7—O15^xiii	121.2 (3)
Na12^xiii—Ca21—Na22	88.6 (4)	Si7—Al7—O5	0
Na12^xiii—Ca21—Si1^vi	49.07 (10)	Si7—Al7—O9	0
Na12^xiii—Ca21—Al1^vi	49.07 (10)	Si7—Al7—O14	0
Na12^xiii—Ca21—Al2	149.23 (14)	Si7—Al7—O15^xiii	0
Na12^xiii—Ca21—Al3^v	96.33 (11)	O5—Al7—O9	113.3 (3)
Na12^xiii—Ca21—Al4^vi	94.01 (11)	O5—Al7—O14	111.3 (3)
Na12^xiii—Ca21—Si5^xv	159.26 (15)	O5—Al7—O15^xiii	102.1 (4)
Na12^xiii—Ca21—Al5^xv	159.26 (15)	O9—Al7—O14	113.1 (4)
Na12^xiii—Ca21—Si6^xvi	55.22 (9)	O9—Al7—O15^xiii	99.6 (4)
Na12^xiii—Ca21—Al6^xvi	55.22 (9)	O14—Al7—O15^xiii	116.6 (4)
Na12^xiii—Ca21—Si7^iv	50.01 (9)	Ca11^xiii—Si8—Na11^xiii	0.0 (5)
Na12^xiii—Ca21—Al7^iv	50.01 (9)	Ca11^xiii—Si8—Na22	73.99 (11)
Na12^xiii—Ca21—O4	170.4 (2)	Ca11^xiii—Si8—Al8	0
Na12^xiii—Ca21—O5^iv	77.38 (18)	Ca11^xiii—Si8—O1	61.1 (3)
Na12^xiii—Ca21—O8^v	77.25 (18)	Ca11^xiii—Si8—O2	43.7 (3)
Na12^xiii—Ca21—O15^vi	31.64 (17)	Ca11^xiii—Si8—O3^viii	119.0 (2)
Na22—Ca21—Si1^vi	137.6 (4)	Ca11^xiii—Si8—O7ⁱⁱⁱ	130.7 (2)
Na22—Ca21—Al1^vi	137.6 (4)	Na11^xiii—Si8—Na22	73.99 (11)
Na22—Ca21—Al2	64.5 (4)	Na11^xiii—Si8—Al8	0
Na22—Ca21—Al3^v	101.4 (5)	Na11^xiii—Si8—O1	61.1 (3)
Na22—Ca21—Al4^vi	150.3 (5)	Na11^xiii—Si8—O2	43.7 (3)
Na22—Ca21—Si5^xv	107.5 (3)	Na11^xiii—Si8—O3^viii	119.0 (2)
Na22—Ca21—Al5^xv	107.5 (3)	Na11^xiii—Si8—O7ⁱⁱⁱ	130.7 (2)
Na22—Ca21—Si6^xvi	68.4 (4)	Na22—Si8—Al8	0
Na22—Ca21—Al6^xvi	68.4 (4)	Na22—Si8—O1	120.5 (3)
Na22—Ca21—Si7^iv	92.7 (5)	Na22—Si8—O2	47.1 (2)
Na22—Ca21—Al7^iv	92.7 (5)	Na22—Si8—O3^viii	58.7 (3)
Na22—Ca21—O4	82.5 (4)	Na22—Si8—O7ⁱⁱⁱ	127.7 (3)
Na22—Ca21—O5^iv	73.6 (5)	Al8—Si8—O1	0
Na22—Ca21—O8^v	84.7 (5)	Al8—Si8—O2	0
Na22—Ca21—O15^vi	111.2 (5)	Al8—Si8—O3^viii	0
Si1^vi—Ca21—Al1^vi	0.0 (5)	Al8—Si8—O7ⁱⁱⁱ	0
Si1^vi—Ca21—Al2	156.17 (17)	O1—Si8—O2	104.8 (4)
Si1^vi—Ca21—Al3^v	88.48 (11)	O1—Si8—O3^viii	112.0 (4)
Si1^vi—Ca21—Al4^vi	54.31 (9)	O1—Si8—O7ⁱⁱⁱ	111.2 (4)
Si1^vi—Ca21—Si5^xv	113.11 (14)	O2—Si8—O3^viii	105.8 (4)
Si1^vi—Ca21—Al5^xv	113.11 (14)	O2—Si8—O7ⁱⁱⁱ	113.9 (4)
Si1^vi—Ca21—Si6^xvi	86.00 (9)	O3^viii—Si8—O7ⁱⁱⁱ	109.0 (3)
Si1^vi—Ca21—Al6^xvi	86.00 (9)	Ca11^xiii—Al8—Na11^xiii	0.0 (5)
Si1^vi—Ca21—Si7^iv	59.60 (9)	Ca11^xiii—Al8—Na22	73.99 (11)
Si1^vi—Ca21—Al7^iv	59.60 (9)	Ca11^xiii—Al8—Al5^viii	148.54 (11)
Si1^vi—Ca21—O4	139.9 (2)	Ca11^xiii—Al8—Si8	0
Si1^vi—Ca21—O5^iv	91.12 (18)	Ca11^xiii—Al8—O1	61.1 (3)
Si1^vi—Ca21—O8^v	88.24 (16)	Ca11^xiii—Al8—O2	43.7 (3)
Si1^vi—Ca21—O15^vi	30.2 (2)	Ca11^xiii—Al8—O3^viii	119.0 (2)
Al1^vi—Ca21—Al2	156.17 (17)	Ca11^xiii—Al8—O7ⁱⁱⁱ	130.7 (2)
Al1^vi—Ca21—Al3^v	88.48 (11)	Na11^xiii—Al8—Na22	73.99 (11)
Al1^vi—Ca21—Al4^vi	54.31 (9)	Na11^xiii—Al8—Al5^viii	148.54 (11)
Al1^vi—Ca21—Si5^xv	113.11 (14)	Na11^xiii—Al8—Si8	0
Al1^vi—Ca21—Al5^xv	113.11 (14)	Na11^xiii—Al8—O1	61.1 (3)
Al1^vi—Ca21—Si6^xvi	86.00 (9)	Na11^xiii—Al8—O2	43.7 (3)
Al1^vi—Ca21—Al6^xvi	86.00 (9)	Na11^xiii—Al8—O3^viii	119.0 (2)
Al1^vi—Ca21—Si7^iv	59.60 (9)	Na11^xiii—Al8—O7ⁱⁱⁱ	130.7 (2)
Al1^vi—Ca21—Al7^iv	59.60 (9)	Na22—Al8—Al5^viii	109.54 (12)
Al1^vi—Ca21—O4	139.9 (2)	Na22—Al8—Si8	0
Al1^vi—Ca21—O5^iv	91.12 (18)	Na22—Al8—O1	120.5 (3)
Al1^vi—Ca21—O8^v	88.24 (16)	Na22—Al8—O2	47.1 (2)
Al1^vi—Ca21—O15^vi	30.2 (2)	Na22—Al8—O3^viii	58.7 (3)
Al2—Ca21—Al3^v	75.97 (10)	Na22—Al8—O7ⁱⁱⁱ	127.7 (3)
Al2—Ca21—Al4^vi	102.20 (12)	Al5^viii—Al8—Si8	0
Al2—Ca21—Si5^xv	51.30 (7)	Al5^viii—Al8—O1	129.4 (3)
Al2—Ca21—Al5^xv	51.30 (7)	Al5^viii—Al8—O2	115.1 (3)
Al2—Ca21—Si6^xvi	98.69 (11)	Al5^viii—Al8—O3^viii	86.4 (2)
Al2—Ca21—Al6^xvi	98.69 (11)	Al5^viii—Al8—O7ⁱⁱⁱ	23.8 (2)
Al2—Ca21—Si7^iv	139.92 (14)	Si8—Al8—O1	0
Al2—Ca21—Al7^iv	139.92 (14)	Si8—Al8—O2	0
Al2—Ca21—O4	21.28 (14)	Si8—Al8—O3^viii	0
Al2—Ca21—O5^iv	106.80 (17)	Si8—Al8—O7ⁱⁱⁱ	0
Al2—Ca21—O8^v	85.15 (17)	O1—Al8—O2	104.8 (4)
Al2—Ca21—O15^vi	172.2 (3)	O1—Al8—O3^viii	112.0 (4)
Al3^v—Ca21—Al4^vi	48.87 (8)	O1—Al8—O7ⁱⁱⁱ	111.2 (4)
Al3^v—Ca21—Si5^xv	93.27 (13)	O2—Al8—O3^viii	105.8 (4)
Al3^v—Ca21—Al5^xv	93.27 (13)	O2—Al8—O7ⁱⁱⁱ	113.9 (4)
Al3^v—Ca21—Si6^xvi	53.84 (8)	O3^viii—Al8—O7ⁱⁱⁱ	109.0 (3)
Al3^v—Ca21—Al6^xvi	53.84 (8)	Si2^xi—O1—Al2^xi	0.0 (5)
Al3^v—Ca21—Si7^iv	143.39 (11)	Si2^xi—O1—Si8	158.0 (5)
Al3^v—Ca21—Al7^iv	143.39 (11)	Si2^xi—O1—Al8	158.0 (5)
Al3^v—Ca21—O4	82.0 (2)	Al2^xi—O1—Si8	158.0 (5)
Al3^v—Ca21—O5^iv	171.9 (2)	Al2^xi—O1—Al8	158.0 (5)
Al3^v—Ca21—O8^v	25.12 (18)	Si8—O1—Al8	0.0 (5)
Al3^v—Ca21—O15^vi	111.7 (2)	Ca11^xiii—O2—Na11^xiii	0.0 (5)
Al4^vi—Ca21—Si5^xv	78.61 (11)	Ca11^xiii—O2—Na22	109.1 (3)
Al4^vi—Ca21—Al5^xv	78.61 (11)	Ca11^xiii—O2—Si6^xvi	96.9 (3)
Al4^vi—Ca21—Si6^xvi	88.94 (11)	Ca11^xiii—O2—Al6^xvi	96.9 (3)
Al4^vi—Ca21—Al6^xvi	88.94 (11)	Ca11^xiii—O2—Si8	107.8 (4)
Al4^vi—Ca21—Si7^iv	111.55 (12)	Ca11^xiii—O2—Al8	107.8 (4)
Al4^vi—Ca21—Al7^iv	111.55 (12)	Na11^xiii—O2—Na22	109.1 (3)
Al4^vi—Ca21—O4	91.9 (2)	Na11^xiii—O2—Si6^xvi	96.9 (3)
Al4^vi—Ca21—O5^iv	135.8 (2)	Na11^xiii—O2—Al6^xvi	96.9 (3)
Al4^vi—Ca21—O8^v	67.15 (19)	Na11^xiii—O2—Si8	107.8 (4)
Al4^vi—Ca21—O15^vi	84.5 (2)	Na11^xiii—O2—Al8	107.8 (4)
Si5^xv—Ca21—Al5^xv	0.0 (5)	Na22—O2—Si6^xvi	97.6 (4)
Si5^xv—Ca21—Si6^xvi	142.63 (16)	Na22—O2—Al6^xvi	97.6 (4)
Si5^xv—Ca21—Al6^xvi	142.63 (16)	Na22—O2—Si8	103.0 (3)
Si5^xv—Ca21—Si7^iv	114.57 (13)	Na22—O2—Al8	103.0 (3)
Si5^xv—Ca21—Al7^iv	114.57 (13)	Si6^xvi—O2—Al6^xvi	0.0 (5)
Si5^xv—Ca21—O4	30.04 (14)	Si6^xvi—O2—Si8	140.1 (4)
Si5^xv—Ca21—O5^iv	94.34 (18)	Si6^xvi—O2—Al8	140.1 (4)
Si5^xv—Ca21—O8^v	116.4 (2)	Al6^xvi—O2—Si8	140.1 (4)
Si5^xv—Ca21—O15^vi	127.7 (2)	Al6^xvi—O2—Al8	140.1 (4)
Al5^xv—Ca21—Si6^xvi	142.63 (16)	Si8—O2—Al8	0.0 (5)
Al5^xv—Ca21—Al6^xvi	142.63 (16)	Si3—O3—Al3	0.0 (5)
Al5^xv—Ca21—Si7^iv	114.57 (13)	Si3—O3—Si8^xxii	150.7 (6)
Al5^xv—Ca21—Al7^iv	114.57 (13)	Si3—O3—Al8^xxii	150.7 (6)
Al5^xv—Ca21—O4	30.04 (14)	Al3—O3—Si8^xxii	150.7 (6)
Al5^xv—Ca21—O5^iv	94.34 (18)	Al3—O3—Al8^xxii	150.7 (6)
Al5^xv—Ca21—O8^v	116.4 (2)	Si8^xxii—O3—Al8^xxii	0.0 (5)
Al5^xv—Ca21—O15^vi	127.7 (2)	Ca21—O4—Na22	18.66 (17)
Si6^xvi—Ca21—Al6^xvi	0.0 (5)	Ca21—O4—Si2	127.9 (3)
Si6^xvi—Ca21—Si7^iv	102.79 (12)	Ca21—O4—Al2	127.9 (3)
Si6^xvi—Ca21—Al7^iv	102.79 (12)	Ca21—O4—Si5^xv	104.7 (3)
Si6^xvi—Ca21—O4	117.5 (2)	Ca21—O4—Al5^xv	104.7 (3)
Si6^xvi—Ca21—O5^iv	118.0 (2)	Na22—O4—Si2	111.5 (3)
Si6^xvi—Ca21—O8^v	28.77 (18)	Na22—O4—Al2	111.5 (3)
Si6^xvi—Ca21—O15^vi	85.18 (17)	Na22—O4—Si5^xv	119.8 (3)
Al6^xvi—Ca21—Si7^iv	102.79 (12)	Na22—O4—Al5^xv	119.8 (3)
Al6^xvi—Ca21—Al7^iv	102.79 (12)	Si2—O4—Al2	0.0 (5)
Al6^xvi—Ca21—O4	117.5 (2)	Si2—O4—Si5^xv	127.3 (4)
Al6^xvi—Ca21—O5^iv	118.0 (2)	Si2—O4—Al5^xv	127.3 (4)
Al6^xvi—Ca21—O8^v	28.77 (18)	Al2—O4—Si5^xv	127.3 (4)
Al6^xvi—Ca21—O15^vi	85.18 (17)	Al2—O4—Al5^xv	127.3 (4)
Si7^iv—Ca21—Al7^iv	0.0 (5)	Si5^xv—O4—Al5^xv	0.0 (5)
Si7^iv—Ca21—O4	133.7 (2)	Ca21^xvii—O5—Na22^xvii	18.09 (17)
Si7^iv—Ca21—O5^iv	33.13 (14)	Ca21^xvii—O5—Si4	132.9 (4)
Si7^iv—Ca21—O8^v	127.25 (19)	Ca21^xvii—O5—Al4	132.9 (4)
Si7^iv—Ca21—O15^vi	32.30 (19)	Ca21^xvii—O5—Si7	94.4 (3)
Al7^iv—Ca21—O4	133.7 (2)	Ca21^xvii—O5—Al7	94.4 (3)
Al7^iv—Ca21—O5^iv	33.13 (14)	Na22^xvii—O5—Si4	124.0 (3)
Al7^iv—Ca21—O8^v	127.25 (19)	Na22^xvii—O5—Al4	124.0 (3)
Al7^iv—Ca21—O15^vi	32.30 (19)	Na22^xvii—O5—Si7	104.0 (3)
O4—Ca21—O5^iv	103.4 (2)	Na22^xvii—O5—Al7	104.0 (3)
O4—Ca21—O8^v	98.3 (3)	Si4—O5—Al4	0.0 (5)
O4—Ca21—O15^vi	157.1 (3)	Si4—O5—Si7	131.8 (5)
O5^iv—Ca21—O8^v	146.8 (3)	Si4—O5—Al7	131.8 (5)
O5^iv—Ca21—O15^vi	65.4 (2)	Al4—O5—Si7	131.8 (5)
O8^v—Ca21—O15^vi	101.2 (2)	Al4—O5—Al7	131.8 (5)
Ca11^xiii—Na22—Na11^xiii	0.0 (5)	Si7—O5—Al7	0.0 (5)
Ca11^xiii—Na22—Ca12^xiii	13.52 (9)	Si4—O6—Al4	0.0 (5)
Ca11^xiii—Na22—Na12^xiii	13.52 (9)	Si4—O6—Si6	130.6 (5)
Ca11^xiii—Na22—Ca21	93.9 (4)	Si4—O6—Al6	130.6 (5)
Ca11^xiii—Na22—Si2	155.42 (17)	Al4—O6—Si6	130.6 (5)
Ca11^xiii—Na22—Al2	155.42 (17)	Al4—O6—Al6	130.6 (5)
Ca11^xiii—Na22—Al4^iv	96.88 (13)	Si6—O6—Al6	0.0 (5)
Ca11^xiii—Na22—Al5^xv	152.17 (16)	Si5^vii—O7—Al5^vii	0.0 (5)
Ca11^xiii—Na22—Si6^xvi	50.82 (9)	Si5^vii—O7—Si8^ix	131.4 (4)
Ca11^xiii—Na22—Al6^xvi	50.82 (9)	Si5^vii—O7—Al8^ix	131.4 (4)
Ca11^xiii—Na22—Si7^iv	55.01 (8)	Al5^vii—O7—Si8^ix	131.4 (4)
Ca11^xiii—Na22—Al7^iv	55.01 (8)	Al5^vii—O7—Al8^ix	131.4 (4)
Ca11^xiii—Na22—Si8	53.85 (9)	Si8^ix—O7—Al8^ix	0.0 (5)
Ca11^xiii—Na22—Al8	53.85 (9)	Ca21^xix—O8—Na22^xix	17.51 (16)
Ca11^xiii—Na22—O2	35.22 (18)	Ca21^xix—O8—Si3	114.5 (3)
Ca11^xiii—Na22—O4	170.9 (3)	Ca21^xix—O8—Al3	114.5 (3)
Ca11^xiii—Na22—O5^iv	79.28 (18)	Ca21^xix—O8—Si6^xi	104.9 (4)
Ca11^xiii—Na22—O8^v	76.63 (17)	Ca21^xix—O8—Al6^xi	104.9 (4)
Na11^xiii—Na22—Ca12^xiii	13.52 (9)	Na22^xix—O8—Si3	125.3 (3)
Na11^xiii—Na22—Na12^xiii	13.52 (9)	Na22^xix—O8—Al3	125.3 (3)
Na11^xiii—Na22—Ca21	93.9 (4)	Na22^xix—O8—Si6^xi	94.0 (4)
Na11^xiii—Na22—Si2	155.42 (17)	Na22^xix—O8—Al6^xi	94.0 (4)
Na11^xiii—Na22—Al2	155.42 (17)	Si3—O8—Al3	0.0 (5)
Na11^xiii—Na22—Al4^iv	96.88 (13)	Si3—O8—Si6^xi	140.3 (4)
Na11^xiii—Na22—Al5^xv	152.17 (16)	Si3—O8—Al6^xi	140.3 (4)
Na11^xiii—Na22—Si6^xvi	50.82 (9)	Al3—O8—Si6^xi	140.3 (4)
Na11^xiii—Na22—Al6^xvi	50.82 (9)	Al3—O8—Al6^xi	140.3 (4)
Na11^xiii—Na22—Si7^iv	55.01 (8)	Si6^xi—O8—Al6^xi	0.0 (5)
Na11^xiii—Na22—Al7^iv	55.01 (8)	Ca11^xxi—O9—Na11^xxi	0.0 (5)
Na11^xiii—Na22—Si8	53.85 (9)	Ca11^xxi—O9—Ca12^xxi	22.32 (16)
Na11^xiii—Na22—Al8	53.85 (9)	Ca11^xxi—O9—Na12^xxi	22.32 (16)
Na11^xiii—Na22—O2	35.22 (18)	Ca11^xxi—O9—Si5	119.7 (3)
Na11^xiii—Na22—O4	170.9 (3)	Ca11^xxi—O9—Al5	119.7 (3)
Na11^xiii—Na22—O5^iv	79.28 (18)	Ca11^xxi—O9—Si7	105.4 (4)
Na11^xiii—Na22—O8^v	76.63 (17)	Ca11^xxi—O9—Al7	105.4 (4)
Ca12^xiii—Na22—Na12^xiii	0.0 (5)	Na11^xxi—O9—Ca12^xxi	22.32 (16)
Ca12^xiii—Na22—Ca21	80.5 (4)	Na11^xxi—O9—Na12^xxi	22.32 (16)
Ca12^xiii—Na22—Si2	164.25 (16)	Na11^xxi—O9—Si5	119.7 (3)
Ca12^xiii—Na22—Al2	164.25 (16)	Na11^xxi—O9—Al5	119.7 (3)
Ca12^xiii—Na22—Al4^iv	97.60 (13)	Na11^xxi—O9—Si7	105.4 (4)
Ca12^xiii—Na22—Al5^xv	138.92 (16)	Na11^xxi—O9—Al7	105.4 (4)
Ca12^xiii—Na22—Si6^xvi	55.59 (9)	Ca12^xxi—O9—Na12^xxi	0.0 (5)
Ca12^xiii—Na22—Al6^xvi	55.59 (9)	Ca12^xxi—O9—Si5	129.7 (3)
Ca12^xiii—Na22—Si7^iv	48.95 (9)	Ca12^xxi—O9—Al5	129.7 (3)
Ca12^xiii—Na22—Al7^iv	48.95 (9)	Ca12^xxi—O9—Si7	94.2 (4)
Ca12^xiii—Na22—Si8	67.35 (10)	Ca12^xxi—O9—Al7	94.2 (4)
Ca12^xiii—Na22—Al8	67.35 (10)	Na12^xxi—O9—Si5	129.7 (3)
Ca12^xiii—Na22—O2	47.28 (18)	Na12^xxi—O9—Al5	129.7 (3)
Ca12^xiii—Na22—O4	159.0 (3)	Na12^xxi—O9—Si7	94.2 (4)
Ca12^xiii—Na22—O5^iv	77.14 (18)	Na12^xxi—O9—Al7	94.2 (4)
Ca12^xiii—Na22—O8^v	75.72 (17)	Si5—O9—Al5	0.0 (5)
Na12^xiii—Na22—Ca21	80.5 (4)	Si5—O9—Si7	134.6 (4)
Na12^xiii—Na22—Si2	164.25 (16)	Si5—O9—Al7	134.6 (4)
Na12^xiii—Na22—Al2	164.25 (16)	Al5—O9—Si7	134.6 (4)
Na12^xiii—Na22—Al4^iv	97.60 (13)	Al5—O9—Al7	134.6 (4)
Na12^xiii—Na22—Al5^xv	138.92 (16)	Si7—O9—Al7	0.0 (5)
Na12^xiii—Na22—Si6^xvi	55.59 (9)	Ca11^ix—O10—Na11^ix	0.0 (5)
Na12^xiii—Na22—Al6^xvi	55.59 (9)	Ca11^ix—O10—Ca12^ix	23.69 (16)
Na12^xiii—Na22—Si7^iv	48.95 (9)	Ca11^ix—O10—Na12^ix	23.69 (16)
Na12^xiii—Na22—Al7^iv	48.95 (9)	Ca11^ix—O10—Si3	105.2 (3)
Na12^xiii—Na22—Si8	67.35 (10)	Ca11^ix—O10—Al3	105.2 (3)
Na12^xiii—Na22—Al8	67.35 (10)	Ca11^ix—O10—Si4ⁱⁱⁱ	127.6 (3)
Na12^xiii—Na22—O2	47.28 (18)	Ca11^ix—O10—Al4ⁱⁱⁱ	127.6 (3)
Na12^xiii—Na22—O4	159.0 (3)	Na11^ix—O10—Ca12^ix	23.69 (16)
Na12^xiii—Na22—O5^iv	77.14 (18)	Na11^ix—O10—Na12^ix	23.69 (16)
Na12^xiii—Na22—O8^v	75.72 (17)	Na11^ix—O10—Si3	105.2 (3)
Ca21—Na22—Si2	103.6 (4)	Na11^ix—O10—Al3	105.2 (3)
Ca21—Na22—Al2	103.6 (4)	Na11^ix—O10—Si4ⁱⁱⁱ	127.6 (3)
Ca21—Na22—Al4^iv	101.3 (5)	Na11^ix—O10—Al4ⁱⁱⁱ	127.6 (3)
Ca21—Na22—Al5^xv	60.5 (3)	Ca12^ix—O10—Na12^ix	0.0 (5)
Ca21—Na22—Si6^xvi	98.4 (4)	Ca12^ix—O10—Si3	126.0 (3)
Ca21—Na22—Al6^xvi	98.4 (4)	Ca12^ix—O10—Al3	126.0 (3)
Ca21—Na22—Si7^iv	73.6 (5)	Ca12^ix—O10—Si4ⁱⁱⁱ	105.5 (3)
Ca21—Na22—Al7^iv	73.6 (5)	Ca12^ix—O10—Al4ⁱⁱⁱ	105.5 (3)
Ca21—Na22—Si8	147.4 (4)	Na12^ix—O10—Si3	126.0 (3)
Ca21—Na22—Al8	147.4 (4)	Na12^ix—O10—Al3	126.0 (3)
Ca21—Na22—O2	120.3 (4)	Na12^ix—O10—Si4ⁱⁱⁱ	105.5 (3)
Ca21—Na22—O4	78.8 (4)	Na12^ix—O10—Al4ⁱⁱⁱ	105.5 (3)
Ca21—Na22—O5^iv	88.3 (5)	Si3—O10—Al3	0.0 (5)
Ca21—Na22—O8^v	77.8 (4)	Si3—O10—Si4ⁱⁱⁱ	127.1 (3)
Si2—Na22—Al2	0.0 (5)	Si3—O10—Al4ⁱⁱⁱ	127.1 (3)
Si2—Na22—Al4^iv	96.50 (9)	Al3—O10—Si4ⁱⁱⁱ	127.1 (3)
Si2—Na22—Al5^xv	51.31 (7)	Al3—O10—Al4ⁱⁱⁱ	127.1 (3)
Si2—Na22—Si6^xvi	108.66 (15)	Si4ⁱⁱⁱ—O10—Al4ⁱⁱⁱ	0.0 (5)
Si2—Na22—Al6^xvi	108.66 (15)	Si1—O11—Al1	0.0 (5)
Si2—Na22—Si7^iv	146.77 (13)	Si1—O11—Si3	134.2 (4)
Si2—Na22—Al7^iv	146.77 (13)	Si1—O11—Al3	134.2 (4)
Si2—Na22—Si8	106.18 (15)	Al1—O11—Si3	134.2 (4)
Si2—Na22—Al8	106.18 (15)	Al1—O11—Al3	134.2 (4)
Si2—Na22—O2	120.3 (2)	Si3—O11—Al3	0.0 (5)
Si2—Na22—O4	27.45 (14)	Si1—O12—Al1	0.0 (5)
Si2—Na22—O5^iv	117.87 (17)	Si1—O12—Si5	150.6 (5)
Si2—Na22—O8^v	90.13 (19)	Si1—O12—Al5	150.6 (5)
Al2—Na22—Al4^iv	96.50 (9)	Al1—O12—Si5	150.6 (5)
Al2—Na22—Al5^xv	51.31 (7)	Al1—O12—Al5	150.6 (5)
Al2—Na22—Si6^xvi	108.66 (15)	Si5—O12—Al5	0.0 (5)
Al2—Na22—Al6^xvi	108.66 (15)	Ca11—O13—Na11	0.0 (5)
Al2—Na22—Si7^iv	146.77 (13)	Ca11—O13—Ca12	21.78 (16)
Al2—Na22—Al7^iv	146.77 (13)	Ca11—O13—Na12	21.78 (16)
Al2—Na22—Si8	106.18 (15)	Ca11—O13—Si2^xi	130.5 (4)
Al2—Na22—Al8	106.18 (15)	Ca11—O13—Al2^xi	130.5 (4)
Al2—Na22—O2	120.3 (2)	Ca11—O13—Si6ⁱⁱⁱ	94.4 (3)
Al2—Na22—O4	27.45 (14)	Ca11—O13—Al6ⁱⁱⁱ	94.4 (3)
Al2—Na22—O5^iv	117.87 (17)	Na11—O13—Ca12	21.78 (16)
Al2—Na22—O8^v	90.13 (19)	Na11—O13—Na12	21.78 (16)
Al4^iv—Na22—Al5^xv	79.35 (10)	Na11—O13—Si2^xi	130.5 (4)
Al4^iv—Na22—Si6^xvi	143.19 (16)	Na11—O13—Al2^xi	130.5 (4)
Al4^iv—Na22—Al6^xvi	143.19 (16)	Na11—O13—Si6ⁱⁱⁱ	94.4 (3)
Al4^iv—Na22—Si7^iv	53.33 (9)	Na11—O13—Al6ⁱⁱⁱ	94.4 (3)
Al4^iv—Na22—Al7^iv	53.33 (9)	Ca12—O13—Na12	0.0 (5)
Al4^iv—Na22—Si8	88.18 (13)	Ca12—O13—Si2^xi	117.8 (3)
Al4^iv—Na22—Al8	88.18 (13)	Ca12—O13—Al2^xi	117.8 (3)
Al4^iv—Na22—O2	110.9 (3)	Ca12—O13—Si6ⁱⁱⁱ	107.5 (3)
Al4^iv—Na22—O4	89.96 (19)	Ca12—O13—Al6ⁱⁱⁱ	107.5 (3)
Al4^iv—Na22—O5^iv	22.66 (14)	Na12—O13—Si2^xi	117.8 (3)
Al4^iv—Na22—O8^v	173.3 (2)	Na12—O13—Al2^xi	117.8 (3)
Al5^xv—Na22—Si6^xvi	137.43 (17)	Na12—O13—Si6ⁱⁱⁱ	107.5 (3)
Al5^xv—Na22—Al6^xvi	137.43 (17)	Na12—O13—Al6ⁱⁱⁱ	107.5 (3)
Al5^xv—Na22—Si7^iv	103.74 (14)	Si2^xi—O13—Al2^xi	0.0 (5)
Al5^xv—Na22—Al7^iv	103.74 (14)	Si2^xi—O13—Si6ⁱⁱⁱ	134.3 (4)
Al5^xv—Na22—Si8	151.87 (13)	Si2^xi—O13—Al6ⁱⁱⁱ	134.3 (4)
Al5^xv—Na22—Al8	151.87 (13)	Al2^xi—O13—Si6ⁱⁱⁱ	134.3 (4)
Al5^xv—Na22—O2	168.5 (3)	Al2^xi—O13—Al6ⁱⁱⁱ	134.3 (4)
Al5^xv—Na22—O4	24.18 (14)	Si6ⁱⁱⁱ—O13—Al6ⁱⁱⁱ	0.0 (5)
Al5^xv—Na22—O5^iv	88.7 (2)	Si2^xxii—O14—Al2^xxii	0.0 (5)
Al5^xv—Na22—O8^v	105.6 (2)	Si2^xxii—O14—Si7	131.4 (4)
Si6^xvi—Na22—Al6^xvi	0.0 (5)	Si2^xxii—O14—Al7	131.4 (4)
Si6^xvi—Na22—Si7^iv	104.47 (10)	Al2^xxii—O14—Si7	131.4 (4)
Si6^xvi—Na22—Al7^iv	104.47 (10)	Al2^xxii—O14—Al7	131.4 (4)
Si6^xvi—Na22—Si8	59.62 (10)	Si7—O14—Al7	0.0 (5)
Si6^xvi—Na22—Al8	59.62 (10)	Ca12^xvii—O15—Na12^xvii	0.0 (5)
Si6^xvi—Na22—O2	32.8 (2)	Ca12^xvii—O15—Ca21^xviii	115.8 (3)
Si6^xvi—Na22—O4	124.4 (2)	Ca12^xvii—O15—Si1	99.6 (3)
Si6^xvi—Na22—O5^iv	129.9 (2)	Ca12^xvii—O15—Al1	99.6 (3)
Si6^xvi—Na22—O8^v	31.90 (17)	Ca12^xvii—O15—Si7ⁱ	100.6 (4)
Al6^xvi—Na22—Si7^iv	104.47 (10)	Ca12^xvii—O15—Al7ⁱ	100.6 (4)
Al6^xvi—Na22—Al7^iv	104.47 (10)	Na12^xvii—O15—Ca21^xviii	115.8 (3)
Al6^xvi—Na22—Si8	59.62 (10)	Na12^xvii—O15—Si1	99.6 (3)
Al6^xvi—Na22—Al8	59.62 (10)	Na12^xvii—O15—Al1	99.6 (3)
Al6^xvi—Na22—O2	32.8 (2)	Na12^xvii—O15—Si7ⁱ	100.6 (4)
Al6^xvi—Na22—O4	124.4 (2)	Na12^xvii—O15—Al7ⁱ	100.6 (4)
Al6^xvi—Na22—O5^iv	129.9 (2)	Ca21^xviii—O15—Si1	103.3 (4)
Al6^xvi—Na22—O8^v	31.90 (17)	Ca21^xviii—O15—Al1	103.3 (4)
Si7^iv—Na22—Al7^iv	0.0 (5)	Ca21^xviii—O15—Si7ⁱ	98.0 (3)
Si7^iv—Na22—Si8	88.23 (12)	Ca21^xviii—O15—Al7ⁱ	98.0 (3)
Si7^iv—Na22—Al8	88.23 (12)	Si1—O15—Al1	0.0 (5)
Si7^iv—Na22—O2	87.0 (2)	Si1—O15—Si7ⁱ	140.3 (4)
Si7^iv—Na22—O4	126.6 (2)	Si1—O15—Al7ⁱ	140.3 (4)
Si7^iv—Na22—O5^iv	30.72 (14)	Al1—O15—Si7ⁱ	140.3 (4)
Si7^iv—Na22—O8^v	120.45 (17)	Al1—O15—Al7ⁱ	140.3 (4)
Al7^iv—Na22—Si8	88.23 (12)	Si7ⁱ—O15—Al7ⁱ	0.0 (5)
Al7^iv—Na22—Al8	88.23 (12)	Si1—O16—Al1	0.0 (5)
Al7^iv—Na22—O2	87.0 (2)	Si1—O16—Si4	155.7 (4)
Al7^iv—Na22—O4	126.6 (2)	Si1—O16—Al4	155.7 (4)
Al7^iv—Na22—O5^iv	30.72 (14)	Al1—O16—Si4	155.7 (4)
Al7^iv—Na22—O8^v	120.45 (17)	Al1—O16—Al4	155.7 (4)
Si8—Na22—Al8	0.0 (5)	Si4—O16—Al4	0.0 (5)
Si8—Na22—O2	29.88 (19)

Symmetry codes: (i) x, y, z+1; (ii) x, y+1, z+1; (iii) x−1/2, y+1/2, z; (iv) x, y+1, z; (v) x+1/2, y+1/2, z−1; (vi) x, y+1, z−1; (vii) x+1, y, z; (viii) x+1/2, y+1/2, z; (ix) x+1/2, y−1/2, z; (x) x−1, y−1, z; (xi) x−1, y, z; (xii) x+1/2, y−1/2, z+1; (xiii) x, y, z−1; (xiv) x−1, y+1, z; (xv) x+1, y+1, z; (xvi) x−1/2, y+1/2, z−1; (xvii) x, y−1, z; (xviii) x, y−1, z+1; (xix) x−1/2, y−1/2, z+1; (xx) x+1, y−1, z; (xxi) x, y−1, z−1; (xxii) x−1/2, y−1/2, z.

(II) top

Crystal data top

Al_1.543Ca_0.457Na_0.543O₈Si_2.457	Z = 4
M_r = 269.4	F(000) = 534
Triclinic, C1	D_x = 2.657 Mg m⁻³
Hall symbol: -C	Mo Kα radiation, λ = 0.71073 Å
a = 8.1846 (4) Å	Cell parameters from 3089 reflections
b = 12.9037 (6) Å	θ = 3.2–28.3°
c = 7.1202 (7) Å	µ = 1.20 mm⁻¹
α = 93.508 (6)°	T = 293 K
β = 116.170 (7)°	Irregular, colorless
γ = 89.708 (5)°	0.18 × 0.10 × 0.05 mm
V = 673.43 (9) Å³

Data collection top

Oxford Diffraction CCD diffractometer	2571 independent reflections
Radiation source: X-ray tube	2879 reflections with I > 3σ(I)
Graphite monochromator	R_int = 0.015
Detector resolution: 16.1500 pixels mm^-1	θ_max = 28.7°, θ_min = 3.2°
ω scans	h = −10→10
Absorption correction: analytical CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)	k = −17→17
T_min = 0.846, T_max = 0.949	l = −8→9
3089 measured reflections

Refinement top

Refinement on F²	0 restraints
R[F² > 2σ(F²)] = 0.033	60 constraints
wR(F²) = 0.092	Weighting scheme based on measured s.u.'s w = 1/(σ²(I) + 0.0004I²)
S = 2.47	(Δ/σ)_max = 0.043
1546 reflections	Δρ_max = 0.73 e Å⁻³
124 parameters	Δρ_min = −0.55 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ca11	0.76945 (19)	0.02630 (15)	0.1061 (3)	0.0268 (4)	0.351 (19)
Na11	0.76945 (19)	0.02630 (15)	0.1061 (3)	0.0268 (4)	0.17 (3)
Ca12	0.7685 (3)	0.9739 (2)	0.1715 (4)	0.0268 (4)	0.106 (19)
Na12	0.7685 (3)	0.9739 (2)	0.1715 (4)	0.0268 (4)	0.38 (4)
Si1	0.00325 (10)	0.31783 (6)	0.23194 (11)	0.0141 (3)	0.6776
Al1	0.00325 (10)	0.31783 (6)	0.23194 (11)	0.0141 (3)	0.3224
Si2	1.68204 (9)	0.37977 (6)	0.35698 (11)	0.0127 (3)	0.6793
Al2	1.68204 (9)	0.37977 (6)	0.35698 (11)	0.0127 (3)	0.3207
Si3	0.31341 (9)	0.39045 (5)	0.68298 (11)	0.0125 (3)	0.7237
Al3	0.31341 (9)	0.39045 (5)	0.68298 (11)	0.0125 (3)	0.2763
Si4	0.99349 (10)	0.33473 (6)	0.78632 (12)	0.0148 (3)	0.3766
Al4	0.99349 (10)	0.33473 (6)	0.78632 (12)	0.0148 (3)	0.6233
O1	0.4166 (2)	0.50644 (14)	0.7215 (3)	0.0173 (7)
O2	0.1890 (3)	0.36747 (15)	0.4311 (3)	0.0242 (8)
O3	0.1879 (2)	0.39322 (15)	0.8100 (3)	0.0220 (8)
O4	1.8011 (2)	0.39166 (15)	0.6154 (3)	0.0224 (7)
O5	0.9973 (3)	0.37035 (16)	0.0223 (3)	0.0253 (8)
O6	0.8168 (3)	0.35311 (16)	0.2457 (3)	0.0283 (9)
O7	1.9856 (3)	0.20624 (16)	0.7217 (3)	0.0240 (8)
O8	0.0159 (3)	0.18923 (17)	0.2181 (3)	0.0278 (8)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ca11	0.0130 (4)	0.0372 (7)	0.0248 (7)	−0.0001 (5)	0.0052 (4)	−0.0126 (5)
Na11	0.0130 (4)	0.0372 (7)	0.0248 (7)	−0.0001 (5)	0.0052 (4)	−0.0126 (5)
Ca12	0.0130 (4)	0.0372 (7)	0.0248 (7)	−0.0001 (5)	0.0052 (4)	−0.0126 (5)
Na12	0.0130 (4)	0.0372 (7)	0.0248 (7)	−0.0001 (5)	0.0052 (4)	−0.0126 (5)
Si1	0.0132 (4)	0.0197 (4)	0.0087 (4)	0.0052 (3)	0.0043 (3)	0.0002 (3)
Al1	0.0132 (4)	0.0197 (4)	0.0087 (4)	0.0052 (3)	0.0043 (3)	0.0002 (3)
Si2	0.0122 (4)	0.0145 (4)	0.0110 (4)	−0.0011 (3)	0.0046 (3)	0.0019 (3)
Al2	0.0122 (4)	0.0145 (4)	0.0110 (4)	−0.0011 (3)	0.0046 (3)	0.0019 (3)
Si3	0.0119 (4)	0.0126 (4)	0.0118 (4)	0.0007 (3)	0.0043 (3)	−0.0005 (3)
Al3	0.0119 (4)	0.0126 (4)	0.0118 (4)	0.0007 (3)	0.0043 (3)	−0.0005 (3)
Si4	0.0137 (4)	0.0204 (4)	0.0100 (4)	−0.0048 (3)	0.0048 (3)	0.0020 (3)
Al4	0.0137 (4)	0.0204 (4)	0.0100 (4)	−0.0048 (3)	0.0048 (3)	0.0020 (3)
O1	0.0172 (9)	0.0178 (9)	0.0153 (9)	−0.0018 (7)	0.0056 (8)	0.0025 (8)
O2	0.0209 (10)	0.0268 (11)	0.0162 (10)	0.0016 (8)	0.0008 (8)	−0.0028 (8)
O3	0.0220 (10)	0.0225 (10)	0.0238 (11)	−0.0029 (8)	0.0123 (9)	0.0002 (9)
O4	0.0214 (10)	0.0275 (11)	0.0135 (10)	−0.0021 (8)	0.0032 (8)	0.0015 (8)
O5	0.0292 (11)	0.0363 (12)	0.0136 (10)	0.0009 (9)	0.0119 (9)	0.0051 (9)
O6	0.0227 (11)	0.0279 (11)	0.0380 (13)	0.0025 (9)	0.0175 (10)	−0.0021 (10)
O7	0.0214 (10)	0.0284 (11)	0.0207 (11)	−0.0070 (8)	0.0077 (9)	0.0033 (9)
O8	0.0235 (10)	0.0309 (12)	0.0194 (11)	0.0117 (9)	0.0019 (9)	−0.0066 (9)

Geometric parameters (Å, º) top

Ca11—Ca11ⁱ	4.028 (2)	Ca12—O5^xiii	2.370 (3)
Ca11—Na11	0	Na12—Na12^xi	4.054 (3)
Ca11—Na11ⁱ	4.028 (2)	Na12—Si1^xii	3.151 (3)
Ca11—Ca12ⁱⁱ	0.846 (4)	Na12—Al1^xii	3.151 (3)
Ca11—Ca12ⁱⁱⁱ	3.952 (3)	Na12—Si2^xiii	3.300 (2)
Ca11—Na12ⁱⁱ	0.846 (4)	Na12—Al2^xiii	3.300 (2)
Ca11—Na12ⁱⁱⁱ	3.952 (3)	Na12—Al2^xiv	3.610 (3)
Ca11—Si1^iv	3.2602 (18)	Na12—Al3^xv	3.544 (3)
Ca11—Al1^iv	3.2602 (18)	Na12—Si4^xvi	3.131 (2)
Ca11—Al2^v	3.6327 (18)	Na12—Si4^xv	3.348 (3)
Ca11—Si3^vi	3.2222 (17)	Na12—Al4^xvi	3.131 (2)
Ca11—Al3^vii	3.547 (2)	Na12—Al4^xv	3.348 (3)
Ca11—Al3^vi	3.2222 (17)	Na12—O1^xv	2.353 (3)
Ca11—Si4^viii	3.3508 (18)	Na12—O3^xvii	2.515 (3)
Ca11—Si4^vi	3.111 (2)	Na12—O4^xiv	2.463 (4)
Ca11—Al4^viii	3.3508 (18)	Na12—O5^xiii	2.370 (3)
Ca11—Al4^vi	3.111 (2)	Si1—Al1	0
Ca11—O1^vi	2.357 (2)	Si1—O2	1.6521 (18)
Ca11—O3^vii	2.483 (3)	Si1—O5^xviii	1.658 (2)
Ca11—O4^ix	2.476 (3)	Si1—O6^xviii	1.632 (3)
Ca11—O5^x	2.396 (3)	Si1—O8	1.662 (2)
Na11—Na11ⁱ	4.028 (2)	Al1—Al3^xix	3.0328 (11)
Na11—Ca12ⁱⁱ	0.846 (4)	Al1—O2	1.6521 (18)
Na11—Ca12ⁱⁱⁱ	3.952 (3)	Al1—O5^xviii	1.658 (2)
Na11—Na12ⁱⁱ	0.846 (4)	Al1—O6^xviii	1.632 (3)
Na11—Na12ⁱⁱⁱ	3.952 (3)	Al1—O8	1.662 (2)
Na11—Si1^iv	3.2602 (18)	Si2—Al2	0
Na11—Al1^iv	3.2602 (18)	Si2—O1^xx	1.6765 (19)
Na11—Al2^v	3.6327 (18)	Si2—O4	1.6567 (19)
Na11—Si3^vi	3.2222 (17)	Si2—O6^xxi	1.642 (3)
Na11—Al3^vii	3.547 (2)	Si2—O7^xxii	1.640 (2)
Na11—Al3^vi	3.2222 (17)	Al2—Al3^xx	2.9979 (10)
Na11—Si4^viii	3.3508 (18)	Al2—Al4^xxi	3.0838 (12)
Na11—Si4^vi	3.111 (2)	Al2—Al4^ix	3.0279 (11)
Na11—Al4^viii	3.3508 (18)	Al2—O1^xx	1.6765 (19)
Na11—Al4^vi	3.111 (2)	Al2—O4	1.6567 (19)
Na11—O1^vi	2.357 (2)	Al2—O6^xxi	1.642 (3)
Na11—O3^vii	2.483 (3)	Al2—O7^xxii	1.640 (2)
Na11—O4^ix	2.476 (3)	Si3—Al3	0
Na11—O5^x	2.396 (3)	Si3—O1	1.6695 (19)
Ca12—Ca12^xi	4.054 (3)	Si3—O2	1.634 (2)
Ca12—Na12	0	Si3—O3	1.640 (3)
Ca12—Na12^xi	4.054 (3)	Si3—O8^xix	1.646 (2)
Ca12—Si1^xii	3.151 (3)	Al3—Al4^xviii	3.1141 (13)
Ca12—Al1^xii	3.151 (3)	Al3—O1	1.6695 (19)
Ca12—Si2^xiii	3.300 (2)	Al3—O2	1.634 (2)
Ca12—Al2^xiii	3.300 (2)	Al3—O3	1.640 (3)
Ca12—Al2^xiv	3.610 (3)	Al3—O8^xix	1.646 (2)
Ca12—Al3^xii	3.722 (3)	Si4—Al4	0
Ca12—Al3^xv	3.544 (3)	Si4—O3^xxi	1.700 (2)
Ca12—Si4^xvi	3.131 (2)	Si4—O4^xviii	1.7049 (18)
Ca12—Si4^xv	3.348 (3)	Si4—O5^xxiii	1.701 (2)
Ca12—Al4^xvi	3.131 (2)	Si4—O7^xviii	1.687 (2)
Ca12—Al4^xv	3.348 (3)	Al4—O3^xxi	1.700 (2)
Ca12—O1^xv	2.353 (3)	Al4—O4^xviii	1.7049 (18)
Ca12—O3^xvii	2.515 (3)	Al4—O5^xxiii	1.701 (2)
Ca12—O4^xiv	2.463 (4)	Al4—O7^xviii	1.687 (2)

Ca11ⁱ—Ca11—Na11	0	Na12^xi—Na12—Al1^xii	65.25 (6)
Ca11ⁱ—Ca11—Na11ⁱ	0.0 (5)	Na12^xi—Na12—Si2^xiii	164.82 (9)
Ca11ⁱ—Ca11—Ca12ⁱⁱ	78.79 (18)	Na12^xi—Na12—Al2^xiii	164.82 (9)
Ca11ⁱ—Ca11—Ca12ⁱⁱⁱ	12.12 (5)	Na12^xi—Na12—Al2^xiv	96.51 (8)
Ca11ⁱ—Ca11—Na12ⁱⁱ	78.79 (18)	Na12^xi—Na12—Al3^xv	136.99 (9)
Ca11ⁱ—Ca11—Na12ⁱⁱⁱ	12.12 (5)	Na12^xi—Na12—Si4^xvi	53.69 (5)
Ca11ⁱ—Ca11—Si1^iv	62.83 (4)	Na12^xi—Na12—Si4^xv	48.91 (5)
Ca11ⁱ—Ca11—Al1^iv	62.83 (4)	Na12^xi—Na12—Al4^xvi	53.69 (5)
Ca11ⁱ—Ca11—Al2^v	136.73 (6)	Na12^xi—Na12—Al4^xv	48.91 (5)
Ca11ⁱ—Ca11—Si3^vi	168.87 (7)	Na12^xi—Na12—O1^xv	156.57 (13)
Ca11ⁱ—Ca11—Al3^vii	96.89 (4)	Na12^xi—Na12—O3^xvii	74.32 (7)
Ca11ⁱ—Ca11—Al3^vi	168.87 (7)	Na12^xi—Na12—O4^xiv	75.79 (8)
Ca11ⁱ—Ca11—Si4^viii	48.82 (4)	Na12^xi—Na12—O5^xiii	44.39 (7)
Ca11ⁱ—Ca11—Si4^vi	54.16 (4)	Si1^xii—Na12—Al1^xii	0.0 (5)
Ca11ⁱ—Ca11—Al4^viii	48.82 (4)	Si1^xii—Na12—Si2^xiii	109.89 (8)
Ca11ⁱ—Ca11—Al4^vi	54.16 (4)	Si1^xii—Na12—Al2^xiii	109.89 (8)
Ca11ⁱ—Ca11—O1^vi	157.75 (9)	Si1^xii—Na12—Al2^xiv	88.79 (8)
Ca11ⁱ—Ca11—O3^vii	75.26 (6)	Si1^xii—Na12—Al3^xv	155.22 (8)
Ca11ⁱ—Ca11—O4^ix	75.70 (6)	Si1^xii—Na12—Si4^xvi	60.38 (5)
Ca11ⁱ—Ca11—O5^x	44.05 (6)	Si1^xii—Na12—Si4^xv	87.43 (7)
Na11—Ca11—Na11ⁱ	0	Si1^xii—Na12—Al4^xvi	60.38 (5)
Na11—Ca11—Ca12ⁱⁱ	0	Si1^xii—Na12—Al4^xv	87.43 (7)
Na11—Ca11—Ca12ⁱⁱⁱ	0	Si1^xii—Na12—O1^xv	137.65 (11)
Na11—Ca11—Na12ⁱⁱ	0	Si1^xii—Na12—O3^xvii	91.37 (9)
Na11—Ca11—Na12ⁱⁱⁱ	0	Si1^xii—Na12—O4^xiv	89.37 (10)
Na11—Ca11—Si1^iv	0	Si1^xii—Na12—O5^xiii	31.05 (7)
Na11—Ca11—Al1^iv	0	Al1^xii—Na12—Si2^xiii	109.89 (8)
Na11—Ca11—Al2^v	0	Al1^xii—Na12—Al2^xiii	109.89 (8)
Na11—Ca11—Si3^vi	0	Al1^xii—Na12—Al2^xiv	88.79 (8)
Na11—Ca11—Al3^vii	0	Al1^xii—Na12—Al3^xv	155.22 (8)
Na11—Ca11—Al3^vi	0	Al1^xii—Na12—Si4^xvi	60.38 (5)
Na11—Ca11—Si4^viii	0	Al1^xii—Na12—Si4^xv	87.43 (7)
Na11—Ca11—Si4^vi	0	Al1^xii—Na12—Al4^xvi	60.38 (5)
Na11—Ca11—Al4^viii	0	Al1^xii—Na12—Al4^xv	87.43 (7)
Na11—Ca11—Al4^vi	0	Al1^xii—Na12—O1^xv	137.65 (11)
Na11—Ca11—O1^vi	0	Al1^xii—Na12—O3^xvii	91.37 (9)
Na11—Ca11—O3^vii	0	Al1^xii—Na12—O4^xiv	89.37 (10)
Na11—Ca11—O4^ix	0	Al1^xii—Na12—O5^xiii	31.05 (7)
Na11—Ca11—O5^x	0	Si2^xiii—Na12—Al2^xiii	0.0 (5)
Na11ⁱ—Ca11—Ca12ⁱⁱ	78.79 (18)	Si2^xiii—Na12—Al2^xiv	97.76 (5)
Na11ⁱ—Ca11—Ca12ⁱⁱⁱ	12.12 (5)	Si2^xiii—Na12—Al3^xv	51.81 (4)
Na11ⁱ—Ca11—Na12ⁱⁱ	78.79 (18)	Si2^xiii—Na12—Si4^xvi	111.16 (8)
Na11ⁱ—Ca11—Na12ⁱⁱⁱ	12.12 (5)	Si2^xiii—Na12—Si4^xv	146.21 (8)
Na11ⁱ—Ca11—Si1^iv	62.83 (4)	Si2^xiii—Na12—Al4^xvi	111.16 (8)
Na11ⁱ—Ca11—Al1^iv	62.83 (4)	Si2^xiii—Na12—Al4^xv	146.21 (8)
Na11ⁱ—Ca11—Al2^v	136.73 (6)	Si2^xiii—Na12—O1^xv	28.76 (5)
Na11ⁱ—Ca11—Si3^vi	168.87 (7)	Si2^xiii—Na12—O3^xvii	91.81 (9)
Na11ⁱ—Ca11—Al3^vii	96.89 (4)	Si2^xiii—Na12—O4^xiv	119.15 (8)
Na11ⁱ—Ca11—Al3^vi	168.87 (7)	Si2^xiii—Na12—O5^xiii	124.19 (11)
Na11ⁱ—Ca11—Si4^viii	48.82 (4)	Al2^xiii—Na12—Al2^xiv	97.76 (5)
Na11ⁱ—Ca11—Si4^vi	54.16 (4)	Al2^xiii—Na12—Al3^xv	51.81 (4)
Na11ⁱ—Ca11—Al4^viii	48.82 (4)	Al2^xiii—Na12—Si4^xvi	111.16 (8)
Na11ⁱ—Ca11—Al4^vi	54.16 (4)	Al2^xiii—Na12—Si4^xv	146.21 (8)
Na11ⁱ—Ca11—O1^vi	157.75 (9)	Al2^xiii—Na12—Al4^xvi	111.16 (8)
Na11ⁱ—Ca11—O3^vii	75.26 (6)	Al2^xiii—Na12—Al4^xv	146.21 (8)
Na11ⁱ—Ca11—O4^ix	75.70 (6)	Al2^xiii—Na12—O1^xv	28.76 (5)
Na11ⁱ—Ca11—O5^x	44.05 (6)	Al2^xiii—Na12—O3^xvii	91.81 (9)
Ca12ⁱⁱ—Ca11—Ca12ⁱⁱⁱ	90.92 (18)	Al2^xiii—Na12—O4^xiv	119.15 (8)
Ca12ⁱⁱ—Ca11—Na12ⁱⁱ	0.0 (5)	Al2^xiii—Na12—O5^xiii	124.19 (11)
Ca12ⁱⁱ—Ca11—Na12ⁱⁱⁱ	90.92 (18)	Al2^xiv—Na12—Al3^xv	78.85 (5)
Ca12ⁱⁱ—Ca11—Si1^iv	141.63 (19)	Al2^xiv—Na12—Si4^xvi	142.98 (9)
Ca12ⁱⁱ—Ca11—Al1^iv	141.63 (19)	Al2^xiv—Na12—Si4^xv	52.45 (5)
Ca12ⁱⁱ—Ca11—Al2^v	60.51 (18)	Al2^xiv—Na12—Al4^xvi	142.98 (9)
Ca12ⁱⁱ—Ca11—Si3^vi	105.53 (16)	Al2^xiv—Na12—Al4^xv	52.45 (5)
Ca12ⁱⁱ—Ca11—Al3^vii	97.3 (2)	Al2^xiv—Na12—O1^xv	89.91 (8)
Ca12ⁱⁱ—Ca11—Al3^vi	105.53 (16)	Al2^xiv—Na12—O3^xvii	169.76 (10)
Ca12ⁱⁱ—Ca11—Si4^viii	67.84 (18)	Al2^xiv—Na12—O4^xiv	23.12 (5)
Ca12ⁱⁱ—Ca11—Si4^vi	98.9 (2)	Al2^xiv—Na12—O5^xiii	111.52 (12)
Ca12ⁱⁱ—Ca11—Al4^viii	67.84 (18)	Al3^xv—Na12—Si4^xvi	137.36 (10)
Ca12ⁱⁱ—Ca11—Al4^vi	98.9 (2)	Al3^xv—Na12—Si4^xv	101.39 (7)
Ca12ⁱⁱ—Ca11—O1^vi	79.38 (18)	Al3^xv—Na12—Al4^xvi	137.36 (10)
Ca12ⁱⁱ—Ca11—O3^vii	82.4 (2)	Al3^xv—Na12—Al4^xv	101.39 (7)
Ca12ⁱⁱ—Ca11—O4^ix	79.2 (2)	Al3^xv—Na12—O1^xv	23.38 (5)
Ca12ⁱⁱ—Ca11—O5^x	117.4 (2)	Al3^xv—Na12—O3^xvii	104.58 (11)
Ca12ⁱⁱⁱ—Ca11—Na12ⁱⁱ	90.92 (18)	Al3^xv—Na12—O4^xiv	87.49 (8)
Ca12ⁱⁱⁱ—Ca11—Na12ⁱⁱⁱ	0.0 (5)	Al3^xv—Na12—O5^xiii	169.63 (13)
Ca12ⁱⁱⁱ—Ca11—Si1^iv	50.71 (5)	Si4^xvi—Na12—Si4^xv	102.61 (6)
Ca12ⁱⁱⁱ—Ca11—Al1^iv	50.71 (5)	Si4^xvi—Na12—Al4^xvi	0.0 (5)
Ca12ⁱⁱⁱ—Ca11—Al2^v	147.95 (7)	Si4^xvi—Na12—Al4^xv	102.61 (6)
Ca12ⁱⁱⁱ—Ca11—Si3^vi	160.53 (7)	Si4^xvi—Na12—O1^xv	126.39 (12)
Ca12ⁱⁱⁱ—Ca11—Al3^vii	95.46 (5)	Si4^xvi—Na12—O3^xvii	32.79 (6)
Ca12ⁱⁱⁱ—Ca11—Al3^vi	160.53 (7)	Si4^xvi—Na12—O4^xiv	127.86 (9)
Ca12ⁱⁱⁱ—Ca11—Si4^viii	53.82 (5)	Si4^xvi—Na12—O5^xiii	32.43 (7)
Ca12ⁱⁱⁱ—Ca11—Si4^vi	50.95 (5)	Si4^xv—Na12—Al4^xvi	102.61 (6)
Ca12ⁱⁱⁱ—Ca11—Al4^viii	53.82 (5)	Si4^xv—Na12—Al4^xv	0.0 (5)
Ca12ⁱⁱⁱ—Ca11—Al4^vi	50.95 (5)	Si4^xv—Na12—O1^xv	123.79 (11)
Ca12ⁱⁱⁱ—Ca11—O1^vi	169.38 (10)	Si4^xv—Na12—O3^xvii	117.32 (8)
Ca12ⁱⁱⁱ—Ca11—O3^vii	76.65 (7)	Si4^xv—Na12—O4^xiv	29.40 (5)
Ca12ⁱⁱⁱ—Ca11—O4^ix	77.77 (7)	Si4^xv—Na12—O5^xiii	85.65 (9)
Ca12ⁱⁱⁱ—Ca11—O5^x	33.78 (7)	Al4^xvi—Na12—Al4^xv	102.61 (6)
Na12ⁱⁱ—Ca11—Na12ⁱⁱⁱ	90.92 (18)	Al4^xvi—Na12—O1^xv	126.39 (12)
Na12ⁱⁱ—Ca11—Si1^iv	141.63 (19)	Al4^xvi—Na12—O3^xvii	32.79 (6)
Na12ⁱⁱ—Ca11—Al1^iv	141.63 (19)	Al4^xvi—Na12—O4^xiv	127.86 (9)
Na12ⁱⁱ—Ca11—Al2^v	60.51 (18)	Al4^xvi—Na12—O5^xiii	32.43 (7)
Na12ⁱⁱ—Ca11—Si3^vi	105.53 (16)	Al4^xv—Na12—O1^xv	123.79 (11)
Na12ⁱⁱ—Ca11—Al3^vii	97.3 (2)	Al4^xv—Na12—O3^xvii	117.32 (8)
Na12ⁱⁱ—Ca11—Al3^vi	105.53 (16)	Al4^xv—Na12—O4^xiv	29.40 (5)
Na12ⁱⁱ—Ca11—Si4^viii	67.84 (18)	Al4^xv—Na12—O5^xiii	85.65 (9)
Na12ⁱⁱ—Ca11—Si4^vi	98.9 (2)	O1^xv—Na12—O3^xvii	96.83 (13)
Na12ⁱⁱ—Ca11—Al4^viii	67.84 (18)	O1^xv—Na12—O4^xiv	104.88 (10)
Na12ⁱⁱ—Ca11—Al4^vi	98.9 (2)	O1^xv—Na12—O5^xiii	150.56 (15)
Na12ⁱⁱ—Ca11—O1^vi	79.38 (18)	O3^xvii—Na12—O4^xiv	146.63 (11)
Na12ⁱⁱ—Ca11—O3^vii	82.4 (2)	O3^xvii—Na12—O5^xiii	65.21 (9)
Na12ⁱⁱ—Ca11—O4^ix	79.2 (2)	O4^xiv—Na12—O5^xiii	102.12 (12)
Na12ⁱⁱ—Ca11—O5^x	117.4 (2)	Ca11^iv—Si1—Na11^iv	0.0 (5)
Na12ⁱⁱⁱ—Ca11—Si1^iv	50.71 (5)	Ca11^iv—Si1—Ca12^v	76.08 (5)
Na12ⁱⁱⁱ—Ca11—Al1^iv	50.71 (5)	Ca11^iv—Si1—Na12^v	76.08 (5)
Na12ⁱⁱⁱ—Ca11—Al2^v	147.95 (7)	Ca11^iv—Si1—Al1	0
Na12ⁱⁱⁱ—Ca11—Si3^vi	160.53 (7)	Ca11^iv—Si1—O2	118.62 (8)
Na12ⁱⁱⁱ—Ca11—Al3^vii	95.46 (5)	Ca11^iv—Si1—O5^xviii	45.05 (9)
Na12ⁱⁱⁱ—Ca11—Al3^vi	160.53 (7)	Ca11^iv—Si1—O6^xviii	60.80 (9)
Na12ⁱⁱⁱ—Ca11—Si4^viii	53.82 (5)	Ca11^iv—Si1—O8	130.68 (7)
Na12ⁱⁱⁱ—Ca11—Si4^vi	50.95 (5)	Na11^iv—Si1—Ca12^v	76.08 (5)
Na12ⁱⁱⁱ—Ca11—Al4^viii	53.82 (5)	Na11^iv—Si1—Na12^v	76.08 (5)
Na12ⁱⁱⁱ—Ca11—Al4^vi	50.95 (5)	Na11^iv—Si1—Al1	0
Na12ⁱⁱⁱ—Ca11—O1^vi	169.38 (10)	Na11^iv—Si1—O2	118.62 (8)
Na12ⁱⁱⁱ—Ca11—O3^vii	76.65 (7)	Na11^iv—Si1—O5^xviii	45.05 (9)
Na12ⁱⁱⁱ—Ca11—O4^ix	77.77 (7)	Na11^iv—Si1—O6^xviii	60.80 (9)
Na12ⁱⁱⁱ—Ca11—O5^x	33.78 (7)	Na11^iv—Si1—O8	130.68 (7)
Si1^iv—Ca11—Al1^iv	0.0 (5)	Ca12^v—Si1—Na12^v	0.0 (5)
Si1^iv—Ca11—Al2^v	155.06 (7)	Ca12^v—Si1—Al1	0
Si1^iv—Ca11—Si3^vi	112.24 (6)	Ca12^v—Si1—O2	57.77 (10)
Si1^iv—Ca11—Al3^vii	87.64 (5)	Ca12^v—Si1—O5^xviii	47.49 (8)
Si1^iv—Ca11—Al3^vi	112.24 (6)	Ca12^v—Si1—O6^xviii	123.41 (10)
Si1^iv—Ca11—Si4^viii	85.63 (4)	Ca12^v—Si1—O8	125.08 (11)
Si1^iv—Ca11—Si4^vi	59.40 (4)	Na12^v—Si1—Al1	0
Si1^iv—Ca11—Al4^viii	85.63 (4)	Na12^v—Si1—O2	57.77 (10)
Si1^iv—Ca11—Al4^vi	59.40 (4)	Na12^v—Si1—O5^xviii	47.49 (8)
Si1^iv—Ca11—O1^vi	138.82 (10)	Na12^v—Si1—O6^xviii	123.41 (10)
Si1^iv—Ca11—O3^vii	87.55 (6)	Na12^v—Si1—O8	125.08 (11)
Si1^iv—Ca11—O4^ix	90.86 (7)	Al1—Si1—O2	0
Si1^iv—Ca11—O5^x	29.33 (6)	Al1—Si1—O5^xviii	0
Al1^iv—Ca11—Al2^v	155.06 (7)	Al1—Si1—O6^xviii	0
Al1^iv—Ca11—Si3^vi	112.24 (6)	Al1—Si1—O8	0
Al1^iv—Ca11—Al3^vii	87.64 (5)	O2—Si1—O5^xviii	105.24 (11)
Al1^iv—Ca11—Al3^vi	112.24 (6)	O2—Si1—O6^xviii	112.81 (12)
Al1^iv—Ca11—Si4^viii	85.63 (4)	O2—Si1—O8	109.32 (10)
Al1^iv—Ca11—Si4^vi	59.40 (4)	O5^xviii—Si1—O6^xviii	105.73 (12)
Al1^iv—Ca11—Al4^viii	85.63 (4)	O5^xviii—Si1—O8	112.70 (12)
Al1^iv—Ca11—Al4^vi	59.40 (4)	O6^xviii—Si1—O8	110.91 (12)
Al1^iv—Ca11—O1^vi	138.82 (10)	Ca11^iv—Al1—Na11^iv	0.0 (5)
Al1^iv—Ca11—O3^vii	87.55 (6)	Ca11^iv—Al1—Ca12^v	76.08 (5)
Al1^iv—Ca11—O4^ix	90.86 (7)	Ca11^iv—Al1—Na12^v	76.08 (5)
Al1^iv—Ca11—O5^x	29.33 (6)	Ca11^iv—Al1—Si1	0
Al2^v—Ca11—Si3^vi	51.44 (3)	Ca11^iv—Al1—Al3^xix	148.69 (4)
Al2^v—Ca11—Al3^vii	75.80 (4)	Ca11^iv—Al1—O2	118.62 (8)
Al2^v—Ca11—Al3^vi	51.44 (3)	Ca11^iv—Al1—O5^xviii	45.05 (9)
Al2^v—Ca11—Si4^viii	98.81 (5)	Ca11^iv—Al1—O6^xviii	60.80 (9)
Al2^v—Ca11—Si4^vi	141.06 (6)	Ca11^iv—Al1—O8	130.68 (7)
Al2^v—Ca11—Al4^viii	98.81 (5)	Na11^iv—Al1—Ca12^v	76.08 (5)
Al2^v—Ca11—Al4^vi	141.06 (6)	Na11^iv—Al1—Na12^v	76.08 (5)
Al2^v—Ca11—O1^vi	21.43 (5)	Na11^iv—Al1—Si1	0
Al2^v—Ca11—O3^vii	84.83 (6)	Na11^iv—Al1—Al3^xix	148.69 (4)
Al2^v—Ca11—O4^ix	107.94 (6)	Na11^iv—Al1—O2	118.62 (8)
Al2^v—Ca11—O5^x	173.85 (9)	Na11^iv—Al1—O5^xviii	45.05 (9)
Si3^vi—Ca11—Al3^vii	92.76 (5)	Na11^iv—Al1—O6^xviii	60.80 (9)
Si3^vi—Ca11—Al3^vi	0.0 (5)	Na11^iv—Al1—O8	130.68 (7)
Si3^vi—Ca11—Si4^viii	142.27 (7)	Ca12^v—Al1—Na12^v	0.0 (5)
Si3^vi—Ca11—Si4^vi	114.74 (6)	Ca12^v—Al1—Si1	0
Si3^vi—Ca11—Al4^viii	142.27 (7)	Ca12^v—Al1—Al3^xix	107.48 (5)
Si3^vi—Ca11—Al4^vi	114.74 (6)	Ca12^v—Al1—O2	57.77 (10)
Si3^vi—Ca11—O1^vi	30.03 (5)	Ca12^v—Al1—O5^xviii	47.49 (8)
Si3^vi—Ca11—O3^vii	115.23 (8)	Ca12^v—Al1—O6^xviii	123.41 (10)
Si3^vi—Ca11—O4^ix	94.84 (6)	Ca12^v—Al1—O8	125.08 (11)
Si3^vi—Ca11—O5^x	126.79 (9)	Na12^v—Al1—Si1	0
Al3^vii—Ca11—Al3^vi	92.76 (5)	Na12^v—Al1—Al3^xix	107.48 (5)
Al3^vii—Ca11—Si4^viii	53.58 (3)	Na12^v—Al1—O2	57.77 (10)
Al3^vii—Ca11—Si4^vi	142.63 (5)	Na12^v—Al1—O5^xviii	47.49 (8)
Al3^vii—Ca11—Al4^viii	53.58 (3)	Na12^v—Al1—O6^xviii	123.41 (10)
Al3^vii—Ca11—Al4^vi	142.63 (5)	Na12^v—Al1—O8	125.08 (11)
Al3^vii—Ca11—O1^vi	81.63 (7)	Si1—Al1—Al3^xix	0
Al3^vii—Ca11—O3^vii	24.28 (6)	Si1—Al1—O2	0
Al3^vii—Ca11—O4^ix	172.26 (8)	Si1—Al1—O5^xviii	0
Al3^vii—Ca11—O5^x	110.35 (7)	Si1—Al1—O6^xviii	0
Al3^vi—Ca11—Si4^viii	142.27 (7)	Si1—Al1—O8	0
Al3^vi—Ca11—Si4^vi	114.74 (6)	Al3^xix—Al1—O2	86.94 (7)
Al3^vi—Ca11—Al4^viii	142.27 (7)	Al3^xix—Al1—O5^xviii	114.21 (9)
Al3^vi—Ca11—Al4^vi	114.74 (6)	Al3^xix—Al1—O6^xviii	128.59 (9)
Al3^vi—Ca11—O1^vi	30.03 (5)	Al3^xix—Al1—O8	23.42 (6)
Al3^vi—Ca11—O3^vii	115.23 (8)	O2—Al1—O5^xviii	105.24 (11)
Al3^vi—Ca11—O4^ix	94.84 (6)	O2—Al1—O6^xviii	112.81 (12)
Al3^vi—Ca11—O5^x	126.79 (9)	O2—Al1—O8	109.32 (10)
Si4^viii—Ca11—Si4^vi	102.98 (5)	O5^xviii—Al1—O6^xviii	105.73 (12)
Si4^viii—Ca11—Al4^viii	0.0 (5)	O5^xviii—Al1—O8	112.70 (12)
Si4^viii—Ca11—Al4^vi	102.98 (5)	O6^xviii—Al1—O8	110.91 (12)
Si4^viii—Ca11—O1^vi	117.53 (8)	Ca12^xxv—Si2—Na12^xxv	0.0 (5)
Si4^viii—Ca11—O3^vii	29.35 (6)	Ca12^xxv—Si2—Al2	0
Si4^viii—Ca11—O4^ix	118.73 (8)	Ca12^xxv—Si2—O1^xx	42.48 (8)
Si4^viii—Ca11—O5^x	85.19 (6)	Ca12^xxv—Si2—O4	115.46 (10)
Si4^vi—Ca11—Al4^viii	102.98 (5)	Ca12^xxv—Si2—O6^xxi	131.65 (9)
Si4^vi—Ca11—Al4^vi	0.0 (5)	Ca12^xxv—Si2—O7^xxii	64.12 (9)
Si4^vi—Ca11—O1^vi	134.46 (8)	Na12^xxv—Si2—Al2	0
Si4^vi—Ca11—O3^vii	127.55 (7)	Na12^xxv—Si2—O1^xx	42.48 (8)
Si4^vi—Ca11—O4^ix	33.12 (5)	Na12^xxv—Si2—O4	115.46 (10)
Si4^vi—Ca11—O5^x	32.84 (6)	Na12^xxv—Si2—O6^xxi	131.65 (9)
Al4^viii—Ca11—Al4^vi	102.98 (5)	Na12^xxv—Si2—O7^xxii	64.12 (9)
Al4^viii—Ca11—O1^vi	117.53 (8)	Al2—Si2—O1^xx	0
Al4^viii—Ca11—O3^vii	29.35 (6)	Al2—Si2—O4	0
Al4^viii—Ca11—O4^ix	118.73 (8)	Al2—Si2—O6^xxi	0
Al4^viii—Ca11—O5^x	85.19 (6)	Al2—Si2—O7^xxii	0
Al4^vi—Ca11—O1^vi	134.46 (8)	O1^xx—Si2—O4	107.79 (10)
Al4^vi—Ca11—O3^vii	127.55 (7)	O1^xx—Si2—O6^xxi	108.95 (12)
Al4^vi—Ca11—O4^ix	33.12 (5)	O1^xx—Si2—O7^xxii	105.61 (10)
Al4^vi—Ca11—O5^x	32.84 (6)	O4—Si2—O6^xxi	110.32 (11)
O1^vi—Ca11—O3^vii	97.59 (9)	O4—Si2—O7^xxii	112.98 (12)
O1^vi—Ca11—O4^ix	104.34 (8)	O6^xxi—Si2—O7^xxii	110.97 (11)
O1^vi—Ca11—O5^x	156.49 (11)	Ca11^xii—Al2—Na11^xii	0.0 (5)
O3^vii—Ca11—O4^ix	148.07 (11)	Ca11^xii—Al2—Ca12^xxv	12.90 (6)
O3^vii—Ca11—O5^x	100.79 (8)	Ca11^xii—Al2—Ca12^xiv	84.25 (5)
O4^ix—Ca11—O5^x	65.95 (8)	Ca11^xii—Al2—Na12^xxv	12.90 (6)
Ca11—Na11—Ca11ⁱ	0	Ca11^xii—Al2—Na12^xiv	84.25 (5)
Ca11—Na11—Na11ⁱ	0	Ca11^xii—Al2—Si2	0
Ca11—Na11—Ca12ⁱⁱ	0	Ca11^xii—Al2—Al3^xx	57.19 (3)
Ca11—Na11—Ca12ⁱⁱⁱ	0	Ca11^xii—Al2—Al4^xxi	143.36 (4)
Ca11—Na11—Na12ⁱⁱ	0	Ca11^xii—Al2—Al4^ix	97.11 (4)
Ca11—Na11—Na12ⁱⁱⁱ	0	Ca11^xii—Al2—O1^xx	30.92 (7)
Ca11—Na11—Si1^iv	0	Ca11^xii—Al2—O4	119.56 (9)
Ca11—Na11—Al1^iv	0	Ca11^xii—Al2—O6^xxi	122.45 (8)
Ca11—Na11—Al2^v	0	Ca11^xii—Al2—O7^xxii	74.73 (8)
Ca11—Na11—Si3^vi	0	Na11^xii—Al2—Ca12^xxv	12.90 (6)
Ca11—Na11—Al3^vii	0	Na11^xii—Al2—Ca12^xiv	84.25 (5)
Ca11—Na11—Al3^vi	0	Na11^xii—Al2—Na12^xxv	12.90 (6)
Ca11—Na11—Si4^viii	0	Na11^xii—Al2—Na12^xiv	84.25 (5)
Ca11—Na11—Si4^vi	0	Na11^xii—Al2—Si2	0
Ca11—Na11—Al4^viii	0	Na11^xii—Al2—Al3^xx	57.19 (3)
Ca11—Na11—Al4^vi	0	Na11^xii—Al2—Al4^xxi	143.36 (4)
Ca11—Na11—O1^vi	0	Na11^xii—Al2—Al4^ix	97.11 (4)
Ca11—Na11—O3^vii	0	Na11^xii—Al2—O1^xx	30.92 (7)
Ca11—Na11—O4^ix	0	Na11^xii—Al2—O4	119.56 (9)
Ca11—Na11—O5^x	0	Na11^xii—Al2—O6^xxi	122.45 (8)
Ca11ⁱ—Na11—Na11ⁱ	0.0 (5)	Na11^xii—Al2—O7^xxii	74.73 (8)
Ca11ⁱ—Na11—Ca12ⁱⁱ	78.79 (18)	Ca12^xxv—Al2—Ca12^xiv	82.24 (6)
Ca11ⁱ—Na11—Ca12ⁱⁱⁱ	12.12 (5)	Ca12^xxv—Al2—Na12^xxv	0.0 (5)
Ca11ⁱ—Na11—Na12ⁱⁱ	78.79 (18)	Ca12^xxv—Al2—Na12^xiv	82.24 (6)
Ca11ⁱ—Na11—Na12ⁱⁱⁱ	12.12 (5)	Ca12^xxv—Al2—Si2	0
Ca11ⁱ—Na11—Si1^iv	62.83 (4)	Ca12^xxv—Al2—Al3^xx	68.30 (5)
Ca11ⁱ—Na11—Al1^iv	62.83 (4)	Ca12^xxv—Al2—Al4^xxi	138.09 (6)
Ca11ⁱ—Na11—Al2^v	136.73 (6)	Ca12^xxv—Al2—Al4^ix	87.82 (5)
Ca11ⁱ—Na11—Si3^vi	168.87 (7)	Ca12^xxv—Al2—O1^xx	42.48 (8)
Ca11ⁱ—Na11—Al3^vii	96.89 (4)	Ca12^xxv—Al2—O4	115.46 (10)
Ca11ⁱ—Na11—Al3^vi	168.87 (7)	Ca12^xxv—Al2—O6^xxi	131.65 (9)
Ca11ⁱ—Na11—Si4^viii	48.82 (4)	Ca12^xxv—Al2—O7^xxii	64.12 (9)
Ca11ⁱ—Na11—Si4^vi	54.16 (4)	Ca12^xiv—Al2—Na12^xxv	82.24 (6)
Ca11ⁱ—Na11—Al4^viii	48.82 (4)	Ca12^xiv—Al2—Na12^xiv	0.0 (5)
Ca11ⁱ—Na11—Al4^vi	54.16 (4)	Ca12^xiv—Al2—Si2	0
Ca11ⁱ—Na11—O1^vi	157.75 (9)	Ca12^xiv—Al2—Al3^xx	67.83 (5)
Ca11ⁱ—Na11—O3^vii	75.26 (6)	Ca12^xiv—Al2—Al4^xxi	59.40 (4)
Ca11ⁱ—Na11—O4^ix	75.70 (6)	Ca12^xiv—Al2—Al4^ix	124.92 (6)
Ca11ⁱ—Na11—O5^x	44.05 (6)	Ca12^xiv—Al2—O1^xx	74.45 (8)
Na11ⁱ—Na11—Ca12ⁱⁱ	78.79 (18)	Ca12^xiv—Al2—O4	35.72 (8)
Na11ⁱ—Na11—Ca12ⁱⁱⁱ	12.12 (5)	Ca12^xiv—Al2—O6^xxi	134.87 (8)
Na11ⁱ—Na11—Na12ⁱⁱ	78.79 (18)	Ca12^xiv—Al2—O7^xxii	111.02 (10)
Na11ⁱ—Na11—Na12ⁱⁱⁱ	12.12 (5)	Na12^xxv—Al2—Na12^xiv	82.24 (6)
Na11ⁱ—Na11—Si1^iv	62.83 (4)	Na12^xxv—Al2—Si2	0
Na11ⁱ—Na11—Al1^iv	62.83 (4)	Na12^xxv—Al2—Al3^xx	68.30 (5)
Na11ⁱ—Na11—Al2^v	136.73 (6)	Na12^xxv—Al2—Al4^xxi	138.09 (6)
Na11ⁱ—Na11—Si3^vi	168.87 (7)	Na12^xxv—Al2—Al4^ix	87.82 (5)
Na11ⁱ—Na11—Al3^vii	96.89 (4)	Na12^xxv—Al2—O1^xx	42.48 (8)
Na11ⁱ—Na11—Al3^vi	168.87 (7)	Na12^xxv—Al2—O4	115.46 (10)
Na11ⁱ—Na11—Si4^viii	48.82 (4)	Na12^xxv—Al2—O6^xxi	131.65 (9)
Na11ⁱ—Na11—Si4^vi	54.16 (4)	Na12^xxv—Al2—O7^xxii	64.12 (9)
Na11ⁱ—Na11—Al4^viii	48.82 (4)	Na12^xiv—Al2—Si2	0
Na11ⁱ—Na11—Al4^vi	54.16 (4)	Na12^xiv—Al2—Al3^xx	67.83 (5)
Na11ⁱ—Na11—O1^vi	157.75 (9)	Na12^xiv—Al2—Al4^xxi	59.40 (4)
Na11ⁱ—Na11—O3^vii	75.26 (6)	Na12^xiv—Al2—Al4^ix	124.92 (6)
Na11ⁱ—Na11—O4^ix	75.70 (6)	Na12^xiv—Al2—O1^xx	74.45 (8)
Na11ⁱ—Na11—O5^x	44.05 (6)	Na12^xiv—Al2—O4	35.72 (8)
Ca12ⁱⁱ—Na11—Ca12ⁱⁱⁱ	90.92 (18)	Na12^xiv—Al2—O6^xxi	134.87 (8)
Ca12ⁱⁱ—Na11—Na12ⁱⁱ	0.0 (5)	Na12^xiv—Al2—O7^xxii	111.02 (10)
Ca12ⁱⁱ—Na11—Na12ⁱⁱⁱ	90.92 (18)	Si2—Al2—Al3^xx	0
Ca12ⁱⁱ—Na11—Si1^iv	141.63 (19)	Si2—Al2—Al4^xxi	0
Ca12ⁱⁱ—Na11—Al1^iv	141.63 (19)	Si2—Al2—Al4^ix	0
Ca12ⁱⁱ—Na11—Al2^v	60.51 (18)	Si2—Al2—O1^xx	0
Ca12ⁱⁱ—Na11—Si3^vi	105.53 (16)	Si2—Al2—O4	0
Ca12ⁱⁱ—Na11—Al3^vii	97.3 (2)	Si2—Al2—O6^xxi	0
Ca12ⁱⁱ—Na11—Al3^vi	105.53 (16)	Si2—Al2—O7^xxii	0
Ca12ⁱⁱ—Na11—Si4^viii	67.84 (18)	Al3^xx—Al2—Al4^xxi	107.34 (3)
Ca12ⁱⁱ—Na11—Si4^vi	98.9 (2)	Al3^xx—Al2—Al4^ix	152.06 (3)
Ca12ⁱⁱ—Na11—Al4^viii	67.84 (18)	Al3^xx—Al2—O1^xx	26.31 (6)
Ca12ⁱⁱ—Na11—Al4^vi	98.9 (2)	Al3^xx—Al2—O4	92.96 (8)
Ca12ⁱⁱ—Na11—O1^vi	79.38 (18)	Al3^xx—Al2—O6^xxi	95.22 (8)
Ca12ⁱⁱ—Na11—O3^vii	82.4 (2)	Al3^xx—Al2—O7^xxii	131.92 (8)
Ca12ⁱⁱ—Na11—O4^ix	79.2 (2)	Al4^xxi—Al2—Al4^ix	100.11 (3)
Ca12ⁱⁱ—Na11—O5^x	117.4 (2)	Al4^xxi—Al2—O1^xx	127.91 (6)
Ca12ⁱⁱⁱ—Na11—Na12ⁱⁱ	90.92 (18)	Al4^xxi—Al2—O4	23.82 (7)
Ca12ⁱⁱⁱ—Na11—Na12ⁱⁱⁱ	0.0 (5)	Al4^xxi—Al2—O6^xxi	89.76 (7)
Ca12ⁱⁱⁱ—Na11—Si1^iv	50.71 (5)	Al4^xxi—Al2—O7^xxii	112.17 (8)
Ca12ⁱⁱⁱ—Na11—Al1^iv	50.71 (5)	Al4^ix—Al2—O1^xx	126.98 (6)
Ca12ⁱⁱⁱ—Na11—Al2^v	147.95 (7)	Al4^ix—Al2—O4	110.93 (8)
Ca12ⁱⁱⁱ—Na11—Si3^vi	160.53 (7)	Al4^ix—Al2—O6^xxi	89.98 (8)
Ca12ⁱⁱⁱ—Na11—Al3^vii	95.46 (5)	Al4^ix—Al2—O7^xxii	24.85 (8)
Ca12ⁱⁱⁱ—Na11—Al3^vi	160.53 (7)	O1^xx—Al2—O4	107.79 (10)
Ca12ⁱⁱⁱ—Na11—Si4^viii	53.82 (5)	O1^xx—Al2—O6^xxi	108.95 (12)
Ca12ⁱⁱⁱ—Na11—Si4^vi	50.95 (5)	O1^xx—Al2—O7^xxii	105.61 (10)
Ca12ⁱⁱⁱ—Na11—Al4^viii	53.82 (5)	O4—Al2—O6^xxi	110.32 (11)
Ca12ⁱⁱⁱ—Na11—Al4^vi	50.95 (5)	O4—Al2—O7^xxii	112.98 (12)
Ca12ⁱⁱⁱ—Na11—O1^vi	169.38 (10)	O6^xxi—Al2—O7^xxii	110.97 (11)
Ca12ⁱⁱⁱ—Na11—O3^vii	76.65 (7)	Ca11^vi—Si3—Na11^vi	0.0 (5)
Ca12ⁱⁱⁱ—Na11—O4^ix	77.77 (7)	Ca11^vi—Si3—Al3	0
Ca12ⁱⁱⁱ—Na11—O5^x	33.78 (7)	Ca11^vi—Si3—O1	44.96 (7)
Na12ⁱⁱ—Na11—Na12ⁱⁱⁱ	90.92 (18)	Ca11^vi—Si3—O2	124.46 (10)
Na12ⁱⁱ—Na11—Si1^iv	141.63 (19)	Ca11^vi—Si3—O3	122.76 (7)
Na12ⁱⁱ—Na11—Al1^iv	141.63 (19)	Ca11^vi—Si3—O8^xix	58.47 (8)
Na12ⁱⁱ—Na11—Al2^v	60.51 (18)	Na11^vi—Si3—Al3	0
Na12ⁱⁱ—Na11—Si3^vi	105.53 (16)	Na11^vi—Si3—O1	44.96 (7)
Na12ⁱⁱ—Na11—Al3^vii	97.3 (2)	Na11^vi—Si3—O2	124.46 (10)
Na12ⁱⁱ—Na11—Al3^vi	105.53 (16)	Na11^vi—Si3—O3	122.76 (7)
Na12ⁱⁱ—Na11—Si4^viii	67.84 (18)	Na11^vi—Si3—O8^xix	58.47 (8)
Na12ⁱⁱ—Na11—Si4^vi	98.9 (2)	Al3—Si3—O1	0
Na12ⁱⁱ—Na11—Al4^viii	67.84 (18)	Al3—Si3—O2	0
Na12ⁱⁱ—Na11—Al4^vi	98.9 (2)	Al3—Si3—O3	0
Na12ⁱⁱ—Na11—O1^vi	79.38 (18)	Al3—Si3—O8^xix	0
Na12ⁱⁱ—Na11—O3^vii	82.4 (2)	O1—Si3—O2	108.04 (11)
Na12ⁱⁱ—Na11—O4^ix	79.2 (2)	O1—Si3—O3	108.52 (11)
Na12ⁱⁱ—Na11—O5^x	117.4 (2)	O1—Si3—O8^xix	103.42 (10)
Na12ⁱⁱⁱ—Na11—Si1^iv	50.71 (5)	O2—Si3—O3	111.26 (11)
Na12ⁱⁱⁱ—Na11—Al1^iv	50.71 (5)	O2—Si3—O8^xix	113.12 (11)
Na12ⁱⁱⁱ—Na11—Al2^v	147.95 (7)	O3—Si3—O8^xix	112.02 (12)
Na12ⁱⁱⁱ—Na11—Si3^vi	160.53 (7)	Ca11^xxvi—Al3—Ca11^vi	87.24 (5)
Na12ⁱⁱⁱ—Na11—Al3^vii	95.46 (5)	Ca11^xxvi—Al3—Na11^xxvi	0.0 (5)
Na12ⁱⁱⁱ—Na11—Al3^vi	160.53 (7)	Ca11^xxvi—Al3—Na11^vi	87.24 (5)
Na12ⁱⁱⁱ—Na11—Si4^viii	53.82 (5)	Ca11^xxvi—Al3—Ca12^v	132.12 (6)
Na12ⁱⁱⁱ—Na11—Si4^vi	50.95 (5)	Ca11^xxvi—Al3—Ca12^xv	89.22 (6)
Na12ⁱⁱⁱ—Na11—Al4^viii	53.82 (5)	Ca11^xxvi—Al3—Na12^xv	89.22 (6)
Na12ⁱⁱⁱ—Na11—Al4^vi	50.95 (5)	Ca11^xxvi—Al3—Al1^xix	116.95 (4)
Na12ⁱⁱⁱ—Na11—O1^vi	169.38 (10)	Ca11^xxvi—Al3—Al2^xx	69.58 (4)
Na12ⁱⁱⁱ—Na11—O3^vii	76.65 (7)	Ca11^xxvi—Al3—Si3	0
Na12ⁱⁱⁱ—Na11—O4^ix	77.77 (7)	Ca11^xxvi—Al3—Al4^xviii	59.98 (4)
Na12ⁱⁱⁱ—Na11—O5^x	33.78 (7)	Ca11^xxvi—Al3—O1	72.64 (9)
Si1^iv—Na11—Al1^iv	0.0 (5)	Ca11^xxvi—Al3—O2	137.18 (9)
Si1^iv—Na11—Al2^v	155.06 (7)	Ca11^xxvi—Al3—O3	38.50 (7)
Si1^iv—Na11—Si3^vi	112.24 (6)	Ca11^xxvi—Al3—O8^xix	107.95 (9)
Si1^iv—Na11—Al3^vii	87.64 (5)	Ca11^vi—Al3—Na11^xxvi	87.24 (5)
Si1^iv—Na11—Al3^vi	112.24 (6)	Ca11^vi—Al3—Na11^vi	0.0 (5)
Si1^iv—Na11—Si4^viii	85.63 (4)	Ca11^vi—Al3—Ca12^v	88.48 (5)
Si1^iv—Na11—Si4^vi	59.40 (4)	Ca11^vi—Al3—Ca12^xv	13.30 (5)
Si1^iv—Na11—Al4^viii	85.63 (4)	Ca11^vi—Al3—Na12^xv	13.30 (5)
Si1^iv—Na11—Al4^vi	59.40 (4)	Ca11^vi—Al3—Al1^xix	81.71 (4)
Si1^iv—Na11—O1^vi	138.82 (10)	Ca11^vi—Al3—Al2^xx	71.36 (4)
Si1^iv—Na11—O3^vii	87.55 (6)	Ca11^vi—Al3—Si3	0
Si1^iv—Na11—O4^ix	90.86 (7)	Ca11^vi—Al3—Al4^xviii	142.77 (5)
Si1^iv—Na11—O5^x	29.33 (6)	Ca11^vi—Al3—O1	44.96 (7)
Al1^iv—Na11—Al2^v	155.06 (7)	Ca11^vi—Al3—O2	124.46 (10)
Al1^iv—Na11—Si3^vi	112.24 (6)	Ca11^vi—Al3—O3	122.76 (7)
Al1^iv—Na11—Al3^vii	87.64 (5)	Ca11^vi—Al3—O8^xix	58.47 (8)
Al1^iv—Na11—Al3^vi	112.24 (6)	Na11^xxvi—Al3—Na11^vi	87.24 (5)
Al1^iv—Na11—Si4^viii	85.63 (4)	Na11^xxvi—Al3—Ca12^v	132.12 (6)
Al1^iv—Na11—Si4^vi	59.40 (4)	Na11^xxvi—Al3—Ca12^xv	89.22 (6)
Al1^iv—Na11—Al4^viii	85.63 (4)	Na11^xxvi—Al3—Na12^xv	89.22 (6)
Al1^iv—Na11—Al4^vi	59.40 (4)	Na11^xxvi—Al3—Al1^xix	116.95 (4)
Al1^iv—Na11—O1^vi	138.82 (10)	Na11^xxvi—Al3—Al2^xx	69.58 (4)
Al1^iv—Na11—O3^vii	87.55 (6)	Na11^xxvi—Al3—Si3	0
Al1^iv—Na11—O4^ix	90.86 (7)	Na11^xxvi—Al3—Al4^xviii	59.98 (4)
Al1^iv—Na11—O5^x	29.33 (6)	Na11^xxvi—Al3—O1	72.64 (9)
Al2^v—Na11—Si3^vi	51.44 (3)	Na11^xxvi—Al3—O2	137.18 (9)
Al2^v—Na11—Al3^vii	75.80 (4)	Na11^xxvi—Al3—O3	38.50 (7)
Al2^v—Na11—Al3^vi	51.44 (3)	Na11^xxvi—Al3—O8^xix	107.95 (9)
Al2^v—Na11—Si4^viii	98.81 (5)	Na11^vi—Al3—Ca12^v	88.48 (5)
Al2^v—Na11—Si4^vi	141.06 (6)	Na11^vi—Al3—Ca12^xv	13.30 (5)
Al2^v—Na11—Al4^viii	98.81 (5)	Na11^vi—Al3—Na12^xv	13.30 (5)
Al2^v—Na11—Al4^vi	141.06 (6)	Na11^vi—Al3—Al1^xix	81.71 (4)
Al2^v—Na11—O1^vi	21.43 (5)	Na11^vi—Al3—Al2^xx	71.36 (4)
Al2^v—Na11—O3^vii	84.83 (6)	Na11^vi—Al3—Si3	0
Al2^v—Na11—O4^ix	107.94 (6)	Na11^vi—Al3—Al4^xviii	142.77 (5)
Al2^v—Na11—O5^x	173.85 (9)	Na11^vi—Al3—O1	44.96 (7)
Si3^vi—Na11—Al3^vii	92.76 (5)	Na11^vi—Al3—O2	124.46 (10)
Si3^vi—Na11—Al3^vi	0.0 (5)	Na11^vi—Al3—O3	122.76 (7)
Si3^vi—Na11—Si4^viii	142.27 (7)	Na11^vi—Al3—O8^xix	58.47 (8)
Si3^vi—Na11—Si4^vi	114.74 (6)	Ca12^v—Al3—Ca12^xv	77.50 (6)
Si3^vi—Na11—Al4^viii	142.27 (7)	Ca12^v—Al3—Na12^xv	77.50 (6)
Si3^vi—Na11—Al4^vi	114.74 (6)	Ca12^v—Al3—Al1^xix	109.50 (5)
Si3^vi—Na11—O1^vi	30.03 (5)	Ca12^v—Al3—Al2^xx	63.93 (5)
Si3^vi—Na11—O3^vii	115.23 (8)	Ca12^v—Al3—Si3	0
Si3^vi—Na11—O4^ix	94.84 (6)	Ca12^v—Al3—Al4^xviii	125.92 (4)
Si3^vi—Na11—O5^x	126.79 (9)	Ca12^v—Al3—O1	71.03 (8)
Al3^vii—Na11—Al3^vi	92.76 (5)	Ca12^v—Al3—O2	39.26 (9)
Al3^vii—Na11—Si4^viii	53.58 (3)	Ca12^v—Al3—O3	136.65 (8)
Al3^vii—Na11—Si4^vi	142.63 (5)	Ca12^v—Al3—O8^xix	109.97 (10)
Al3^vii—Na11—Al4^viii	53.58 (3)	Ca12^xv—Al3—Na12^xv	0.0 (5)
Al3^vii—Na11—Al4^vi	142.63 (5)	Ca12^xv—Al3—Al1^xix	92.50 (5)
Al3^vii—Na11—O1^vi	81.63 (7)	Ca12^xv—Al3—Al2^xx	59.89 (5)
Al3^vii—Na11—O3^vii	24.28 (6)	Ca12^xv—Al3—Si3	0
Al3^vii—Na11—O4^ix	172.26 (8)	Ca12^xv—Al3—Al4^xviii	148.79 (6)
Al3^vii—Na11—O5^x	110.35 (7)	Ca12^xv—Al3—O1	34.01 (8)
Al3^vi—Na11—Si4^viii	142.27 (7)	Ca12^xv—Al3—O2	115.51 (10)
Al3^vi—Na11—Si4^vi	114.74 (6)	Ca12^xv—Al3—O3	127.26 (8)
Al3^vi—Na11—Al4^viii	142.27 (7)	Ca12^xv—Al3—O8^xix	70.02 (9)
Al3^vi—Na11—Al4^vi	114.74 (6)	Na12^xv—Al3—Al1^xix	92.50 (5)
Al3^vi—Na11—O1^vi	30.03 (5)	Na12^xv—Al3—Al2^xx	59.89 (5)
Al3^vi—Na11—O3^vii	115.23 (8)	Na12^xv—Al3—Si3	0
Al3^vi—Na11—O4^ix	94.84 (6)	Na12^xv—Al3—Al4^xviii	148.79 (6)
Al3^vi—Na11—O5^x	126.79 (9)	Na12^xv—Al3—O1	34.01 (8)
Si4^viii—Na11—Si4^vi	102.98 (5)	Na12^xv—Al3—O2	115.51 (10)
Si4^viii—Na11—Al4^viii	0.0 (5)	Na12^xv—Al3—O3	127.26 (8)
Si4^viii—Na11—Al4^vi	102.98 (5)	Na12^xv—Al3—O8^xix	70.02 (9)
Si4^viii—Na11—O1^vi	117.53 (8)	Al1^xix—Al3—Al2^xx	152.18 (4)
Si4^viii—Na11—O3^vii	29.35 (6)	Al1^xix—Al3—Si3	0
Si4^viii—Na11—O4^ix	118.73 (8)	Al1^xix—Al3—Al4^xviii	97.06 (3)
Si4^viii—Na11—O5^x	85.19 (6)	Al1^xix—Al3—O1	126.42 (7)
Si4^vi—Na11—Al4^viii	102.98 (5)	Al1^xix—Al3—O2	97.31 (8)
Si4^vi—Na11—Al4^vi	0.0 (5)	Al1^xix—Al3—O3	104.58 (8)
Si4^vi—Na11—O1^vi	134.46 (8)	Al1^xix—Al3—O8^xix	23.65 (7)
Si4^vi—Na11—O3^vii	127.55 (7)	Al2^xx—Al3—Si3	0
Si4^vi—Na11—O4^ix	33.12 (5)	Al2^xx—Al3—Al4^xviii	108.52 (3)
Si4^vi—Na11—O5^x	32.84 (6)	Al2^xx—Al3—O1	26.43 (6)
Al4^viii—Na11—Al4^vi	102.98 (5)	Al2^xx—Al3—O2	92.34 (8)
Al4^viii—Na11—O1^vi	117.53 (8)	Al2^xx—Al3—O3	95.99 (8)
Al4^viii—Na11—O3^vii	29.35 (6)	Al2^xx—Al3—O8^xix	129.78 (8)
Al4^viii—Na11—O4^ix	118.73 (8)	Si3—Al3—Al4^xviii	0
Al4^viii—Na11—O5^x	85.19 (6)	Si3—Al3—O1	0
Al4^vi—Na11—O1^vi	134.46 (8)	Si3—Al3—O2	0
Al4^vi—Na11—O3^vii	127.55 (7)	Si3—Al3—O3	0
Al4^vi—Na11—O4^ix	33.12 (5)	Si3—Al3—O8^xix	0
Al4^vi—Na11—O5^x	32.84 (6)	Al4^xviii—Al3—O1	126.90 (9)
O1^vi—Na11—O3^vii	97.59 (9)	Al4^xviii—Al3—O2	92.69 (9)
O1^vi—Na11—O4^ix	104.34 (8)	Al4^xviii—Al3—O3	21.59 (6)
O1^vi—Na11—O5^x	156.49 (11)	Al4^xviii—Al3—O8^xix	112.41 (10)
O3^vii—Na11—O4^ix	148.07 (11)	O1—Al3—O2	108.04 (11)
O3^vii—Na11—O5^x	100.79 (8)	O1—Al3—O3	108.52 (11)
O4^ix—Na11—O5^x	65.95 (8)	O1—Al3—O8^xix	103.42 (10)
Ca11^xxiv—Ca12—Ca11ⁱⁱⁱ	89.08 (17)	O2—Al3—O3	111.26 (11)
Ca11^xxiv—Ca12—Na11^xxiv	0.0 (5)	O2—Al3—O8^xix	113.12 (11)
Ca11^xxiv—Ca12—Na11ⁱⁱⁱ	89.08 (17)	O3—Al3—O8^xix	112.02 (12)
Ca11^xxiv—Ca12—Ca12^xi	77.04 (17)	Ca11^xxvii—Si4—Ca11^vi	77.02 (5)
Ca11^xxiv—Ca12—Na12	0	Ca11^xxvii—Si4—Na11^xxvii	0.0 (5)
Ca11^xxiv—Ca12—Na12^xi	77.04 (17)	Ca11^xxvii—Si4—Na11^vi	77.02 (5)
Ca11^xxiv—Ca12—Si1^xii	142.29 (19)	Ca11^xxvii—Si4—Ca12^xxviii	14.49 (6)
Ca11^xxiv—Ca12—Al1^xii	142.29 (19)	Ca11^xxvii—Si4—Ca12^xv	72.30 (5)
Ca11^xxiv—Ca12—Si2^xiii	106.6 (2)	Ca11^xxvii—Si4—Na12^xxviii	14.49 (6)
Ca11^xxiv—Ca12—Al2^xiii	106.6 (2)	Ca11^xxvii—Si4—Na12^xv	72.30 (5)
Ca11^xxiv—Ca12—Al2^xiv	95.5 (2)	Ca11^xxvii—Si4—Al4	0
Ca11^xxiv—Ca12—Al3^xii	143.7 (2)	Ca11^xxvii—Si4—O3^xxi	45.74 (8)
Ca11^xxiv—Ca12—Al3^xv	61.17 (16)	Ca11^xxvii—Si4—O4^xviii	106.76 (8)
Ca11^xxiv—Ca12—Si4^xvi	97.67 (19)	Ca11^xxvii—Si4—O5^xxiii	58.07 (8)
Ca11^xxiv—Ca12—Si4^xv	66.7 (2)	Ca11^xxvii—Si4—O7^xviii	142.56 (7)
Ca11^xxiv—Ca12—Al4^xvi	97.67 (19)	Ca11^vi—Si4—Na11^xxvii	77.02 (5)
Ca11^xxiv—Ca12—Al4^xv	66.7 (2)	Ca11^vi—Si4—Na11^vi	0.0 (5)
Ca11^xxiv—Ca12—O1^xv	79.9 (2)	Ca11^vi—Si4—Ca12^xxviii	78.54 (6)
Ca11^xxiv—Ca12—O3^xvii	78.2 (2)	Ca11^vi—Si4—Ca12^xv	14.46 (6)
Ca11^xxiv—Ca12—O4^xiv	81.0 (2)	Ca11^vi—Si4—Na12^xxviii	78.54 (6)
Ca11^xxiv—Ca12—O5^xiii	116.04 (18)	Ca11^vi—Si4—Na12^xv	14.46 (6)
Ca11ⁱⁱⁱ—Ca12—Na11^xxiv	89.08 (17)	Ca11^vi—Si4—Al4	0
Ca11ⁱⁱⁱ—Ca12—Na11ⁱⁱⁱ	0.0 (5)	Ca11^vi—Si4—O3^xxi	116.58 (8)
Ca11ⁱⁱⁱ—Ca12—Ca12^xi	12.04 (5)	Ca11^vi—Si4—O4^xviii	52.53 (9)
Ca11ⁱⁱⁱ—Ca12—Na12	0	Ca11^vi—Si4—O5^xxiii	49.79 (7)
Ca11ⁱⁱⁱ—Ca12—Na12^xi	12.04 (5)	Ca11^vi—Si4—O7^xviii	131.16 (10)
Ca11ⁱⁱⁱ—Ca12—Si1^xii	53.21 (5)	Na11^xxvii—Si4—Na11^vi	77.02 (5)
Ca11ⁱⁱⁱ—Ca12—Al1^xii	53.21 (5)	Na11^xxvii—Si4—Ca12^xxviii	14.49 (6)
Ca11ⁱⁱⁱ—Ca12—Si2^xiii	158.29 (9)	Na11^xxvii—Si4—Ca12^xv	72.30 (5)
Ca11ⁱⁱⁱ—Ca12—Al2^xiii	158.29 (9)	Na11^xxvii—Si4—Na12^xxviii	14.49 (6)
Ca11ⁱⁱⁱ—Ca12—Al2^xiv	95.49 (7)	Na11^xxvii—Si4—Na12^xv	72.30 (5)
Ca11ⁱⁱⁱ—Ca12—Al3^xii	95.96 (7)	Na11^xxvii—Si4—Al4	0
Ca11ⁱⁱⁱ—Ca12—Al3^xv	148.59 (9)	Na11^xxvii—Si4—O3^xxi	45.74 (8)
Ca11ⁱⁱⁱ—Ca12—Si4^xvi	50.50 (4)	Na11^xxvii—Si4—O4^xviii	106.76 (8)
Ca11ⁱⁱⁱ—Ca12—Si4^xv	53.88 (4)	Na11^xxvii—Si4—O5^xxiii	58.07 (8)
Ca11ⁱⁱⁱ—Ca12—Al4^xvi	50.50 (4)	Na11^xxvii—Si4—O7^xviii	142.56 (7)
Ca11ⁱⁱⁱ—Ca12—Al4^xv	53.88 (4)	Na11^vi—Si4—Ca12^xxviii	78.54 (6)
Ca11ⁱⁱⁱ—Ca12—O1^xv	168.19 (13)	Na11^vi—Si4—Ca12^xv	14.46 (6)
Ca11ⁱⁱⁱ—Ca12—O3^xvii	76.50 (7)	Na11^vi—Si4—Na12^xxviii	78.54 (6)
Ca11ⁱⁱⁱ—Ca12—O4^xiv	77.38 (8)	Na11^vi—Si4—Na12^xv	14.46 (6)
Ca11ⁱⁱⁱ—Ca12—O5^xiii	34.20 (7)	Na11^vi—Si4—Al4	0
Na11^xxiv—Ca12—Na11ⁱⁱⁱ	89.08 (17)	Na11^vi—Si4—O3^xxi	116.58 (8)
Na11^xxiv—Ca12—Ca12^xi	77.04 (17)	Na11^vi—Si4—O4^xviii	52.53 (9)
Na11^xxiv—Ca12—Na12	0	Na11^vi—Si4—O5^xxiii	49.79 (7)
Na11^xxiv—Ca12—Na12^xi	77.04 (17)	Na11^vi—Si4—O7^xviii	131.16 (10)
Na11^xxiv—Ca12—Si1^xii	142.29 (19)	Ca12^xxviii—Si4—Ca12^xv	77.39 (6)
Na11^xxiv—Ca12—Al1^xii	142.29 (19)	Ca12^xxviii—Si4—Na12^xxviii	0.0 (5)
Na11^xxiv—Ca12—Si2^xiii	106.6 (2)	Ca12^xxviii—Si4—Na12^xv	77.39 (6)
Na11^xxiv—Ca12—Al2^xiii	106.6 (2)	Ca12^xxviii—Si4—Al4	0
Na11^xxiv—Ca12—Al2^xiv	95.5 (2)	Ca12^xxviii—Si4—O3^xxi	53.24 (9)
Na11^xxiv—Ca12—Al3^xii	143.7 (2)	Ca12^xxviii—Si4—O4^xviii	117.26 (9)
Na11^xxiv—Ca12—Al3^xv	61.17 (16)	Ca12^xxviii—Si4—O5^xxiii	48.34 (9)
Na11^xxiv—Ca12—Si4^xvi	97.67 (19)	Ca12^xxviii—Si4—O7^xviii	132.08 (8)
Na11^xxiv—Ca12—Si4^xv	66.7 (2)	Ca12^xv—Si4—Na12^xxviii	77.39 (6)
Na11^xxiv—Ca12—Al4^xvi	97.67 (19)	Ca12^xv—Si4—Na12^xv	0.0 (5)
Na11^xxiv—Ca12—Al4^xv	66.7 (2)	Ca12^xv—Si4—Al4	0
Na11^xxiv—Ca12—O1^xv	79.9 (2)	Ca12^xv—Si4—O3^xxi	106.08 (9)
Na11^xxiv—Ca12—O3^xvii	78.2 (2)	Ca12^xv—Si4—O4^xviii	45.16 (8)
Na11^xxiv—Ca12—O4^xiv	81.0 (2)	Ca12^xv—Si4—O5^xxiii	59.51 (8)
Na11^xxiv—Ca12—O5^xiii	116.04 (18)	Ca12^xv—Si4—O7^xviii	141.20 (9)
Na11ⁱⁱⁱ—Ca12—Ca12^xi	12.04 (5)	Na12^xxviii—Si4—Na12^xv	77.39 (6)
Na11ⁱⁱⁱ—Ca12—Na12	0	Na12^xxviii—Si4—Al4	0
Na11ⁱⁱⁱ—Ca12—Na12^xi	12.04 (5)	Na12^xxviii—Si4—O3^xxi	53.24 (9)
Na11ⁱⁱⁱ—Ca12—Si1^xii	53.21 (5)	Na12^xxviii—Si4—O4^xviii	117.26 (9)
Na11ⁱⁱⁱ—Ca12—Al1^xii	53.21 (5)	Na12^xxviii—Si4—O5^xxiii	48.34 (9)
Na11ⁱⁱⁱ—Ca12—Si2^xiii	158.29 (9)	Na12^xxviii—Si4—O7^xviii	132.08 (8)
Na11ⁱⁱⁱ—Ca12—Al2^xiii	158.29 (9)	Na12^xv—Si4—Al4	0
Na11ⁱⁱⁱ—Ca12—Al2^xiv	95.49 (7)	Na12^xv—Si4—O3^xxi	106.08 (9)
Na11ⁱⁱⁱ—Ca12—Al3^xii	95.96 (7)	Na12^xv—Si4—O4^xviii	45.16 (8)
Na11ⁱⁱⁱ—Ca12—Al3^xv	148.59 (9)	Na12^xv—Si4—O5^xxiii	59.51 (8)
Na11ⁱⁱⁱ—Ca12—Si4^xvi	50.50 (4)	Na12^xv—Si4—O7^xviii	141.20 (9)
Na11ⁱⁱⁱ—Ca12—Si4^xv	53.88 (4)	Al4—Si4—O3^xxi	0
Na11ⁱⁱⁱ—Ca12—Al4^xvi	50.50 (4)	Al4—Si4—O4^xviii	0
Na11ⁱⁱⁱ—Ca12—Al4^xv	53.88 (4)	Al4—Si4—O5^xxiii	0
Na11ⁱⁱⁱ—Ca12—O1^xv	168.19 (13)	Al4—Si4—O7^xviii	0
Na11ⁱⁱⁱ—Ca12—O3^xvii	76.50 (7)	O3^xxi—Si4—O4^xviii	113.09 (11)
Na11ⁱⁱⁱ—Ca12—O4^xiv	77.38 (8)	O3^xxi—Si4—O5^xxiii	101.57 (11)
Na11ⁱⁱⁱ—Ca12—O5^xiii	34.20 (7)	O3^xxi—Si4—O7^xviii	112.12 (11)
Ca12^xi—Ca12—Na12	0	O4^xviii—Si4—O5^xxiii	102.29 (11)
Ca12^xi—Ca12—Na12^xi	0.0 (5)	O4^xviii—Si4—O7^xviii	110.34 (9)
Ca12^xi—Ca12—Si1^xii	65.25 (6)	O5^xxiii—Si4—O7^xviii	116.92 (12)
Ca12^xi—Ca12—Al1^xii	65.25 (6)	Ca11^xxvii—Al4—Ca11^vi	77.02 (5)
Ca12^xi—Ca12—Si2^xiii	164.82 (9)	Ca11^xxvii—Al4—Na11^xxvii	0.0 (5)
Ca12^xi—Ca12—Al2^xiii	164.82 (9)	Ca11^xxvii—Al4—Na11^vi	77.02 (5)
Ca12^xi—Ca12—Al2^xiv	96.51 (8)	Ca11^xxvii—Al4—Ca12^xxviii	14.49 (6)
Ca12^xi—Ca12—Al3^xii	105.63 (8)	Ca11^xxvii—Al4—Ca12^xv	72.30 (5)
Ca12^xi—Ca12—Al3^xv	136.99 (9)	Ca11^xxvii—Al4—Na12^xxviii	14.49 (6)
Ca12^xi—Ca12—Si4^xvi	53.69 (5)	Ca11^xxvii—Al4—Na12^xv	72.30 (5)
Ca12^xi—Ca12—Si4^xv	48.91 (5)	Ca11^xxvii—Al4—Al2^xviii	120.99 (4)
Ca12^xi—Ca12—Al4^xvi	53.69 (5)	Ca11^xxvii—Al4—Al2^ix	158.82 (4)
Ca12^xi—Ca12—Al4^xv	48.91 (5)	Ca11^xxvii—Al4—Al3^xxi	66.44 (4)
Ca12^xi—Ca12—O1^xv	156.57 (13)	Ca11^xxvii—Al4—Si4	0
Ca12^xi—Ca12—O3^xvii	74.32 (7)	Ca11^xxvii—Al4—O3^xxi	45.74 (8)
Ca12^xi—Ca12—O4^xiv	75.79 (8)	Ca11^xxvii—Al4—O4^xviii	106.76 (8)
Ca12^xi—Ca12—O5^xiii	44.39 (7)	Ca11^xxvii—Al4—O5^xxiii	58.07 (8)
Na12—Ca12—Na12^xi	0	Ca11^xxvii—Al4—O7^xviii	142.56 (7)
Na12—Ca12—Si1^xii	0	Ca11^vi—Al4—Na11^xxvii	77.02 (5)
Na12—Ca12—Al1^xii	0	Ca11^vi—Al4—Na11^vi	0.0 (5)
Na12—Ca12—Si2^xiii	0	Ca11^vi—Al4—Ca12^xxviii	78.54 (6)
Na12—Ca12—Al2^xiii	0	Ca11^vi—Al4—Ca12^xv	14.46 (6)
Na12—Ca12—Al2^xiv	0	Ca11^vi—Al4—Na12^xxviii	78.54 (6)
Na12—Ca12—Al3^xii	0	Ca11^vi—Al4—Na12^xv	14.46 (6)
Na12—Ca12—Al3^xv	0	Ca11^vi—Al4—Al2^xviii	75.36 (4)
Na12—Ca12—Si4^xvi	0	Ca11^vi—Al4—Al2^ix	107.78 (4)
Na12—Ca12—Si4^xv	0	Ca11^vi—Al4—Al3^xxi	131.57 (5)
Na12—Ca12—Al4^xvi	0	Ca11^vi—Al4—Si4	0
Na12—Ca12—Al4^xv	0	Ca11^vi—Al4—O3^xxi	116.58 (8)
Na12—Ca12—O1^xv	0	Ca11^vi—Al4—O4^xviii	52.53 (9)
Na12—Ca12—O3^xvii	0	Ca11^vi—Al4—O5^xxiii	49.79 (7)
Na12—Ca12—O4^xiv	0	Ca11^vi—Al4—O7^xviii	131.16 (10)
Na12—Ca12—O5^xiii	0	Na11^xxvii—Al4—Na11^vi	77.02 (5)
Na12^xi—Ca12—Si1^xii	65.25 (6)	Na11^xxvii—Al4—Ca12^xxviii	14.49 (6)
Na12^xi—Ca12—Al1^xii	65.25 (6)	Na11^xxvii—Al4—Ca12^xv	72.30 (5)
Na12^xi—Ca12—Si2^xiii	164.82 (9)	Na11^xxvii—Al4—Na12^xxviii	14.49 (6)
Na12^xi—Ca12—Al2^xiii	164.82 (9)	Na11^xxvii—Al4—Na12^xv	72.30 (5)
Na12^xi—Ca12—Al2^xiv	96.51 (8)	Na11^xxvii—Al4—Al2^xviii	120.99 (4)
Na12^xi—Ca12—Al3^xii	105.63 (8)	Na11^xxvii—Al4—Al2^ix	158.82 (4)
Na12^xi—Ca12—Al3^xv	136.99 (9)	Na11^xxvii—Al4—Al3^xxi	66.44 (4)
Na12^xi—Ca12—Si4^xvi	53.69 (5)	Na11^xxvii—Al4—Si4	0
Na12^xi—Ca12—Si4^xv	48.91 (5)	Na11^xxvii—Al4—O3^xxi	45.74 (8)
Na12^xi—Ca12—Al4^xvi	53.69 (5)	Na11^xxvii—Al4—O4^xviii	106.76 (8)
Na12^xi—Ca12—Al4^xv	48.91 (5)	Na11^xxvii—Al4—O5^xxiii	58.07 (8)
Na12^xi—Ca12—O1^xv	156.57 (13)	Na11^xxvii—Al4—O7^xviii	142.56 (7)
Na12^xi—Ca12—O3^xvii	74.32 (7)	Na11^vi—Al4—Ca12^xxviii	78.54 (6)
Na12^xi—Ca12—O4^xiv	75.79 (8)	Na11^vi—Al4—Ca12^xv	14.46 (6)
Na12^xi—Ca12—O5^xiii	44.39 (7)	Na11^vi—Al4—Na12^xxviii	78.54 (6)
Si1^xii—Ca12—Al1^xii	0.0 (5)	Na11^vi—Al4—Na12^xv	14.46 (6)
Si1^xii—Ca12—Si2^xiii	109.89 (8)	Na11^vi—Al4—Al2^xviii	75.36 (4)
Si1^xii—Ca12—Al2^xiii	109.89 (8)	Na11^vi—Al4—Al2^ix	107.78 (4)
Si1^xii—Ca12—Al2^xiv	88.79 (8)	Na11^vi—Al4—Al3^xxi	131.57 (5)
Si1^xii—Ca12—Al3^xii	54.32 (5)	Na11^vi—Al4—Si4	0
Si1^xii—Ca12—Al3^xv	155.22 (8)	Na11^vi—Al4—O3^xxi	116.58 (8)
Si1^xii—Ca12—Si4^xvi	60.38 (5)	Na11^vi—Al4—O4^xviii	52.53 (9)
Si1^xii—Ca12—Si4^xv	87.43 (7)	Na11^vi—Al4—O5^xxiii	49.79 (7)
Si1^xii—Ca12—Al4^xvi	60.38 (5)	Na11^vi—Al4—O7^xviii	131.16 (10)
Si1^xii—Ca12—Al4^xv	87.43 (7)	Ca12^xxviii—Al4—Ca12^xv	77.39 (6)
Si1^xii—Ca12—O1^xv	137.65 (11)	Ca12^xxviii—Al4—Na12^xxviii	0.0 (5)
Si1^xii—Ca12—O3^xvii	91.37 (9)	Ca12^xxviii—Al4—Na12^xv	77.39 (6)
Si1^xii—Ca12—O4^xiv	89.37 (10)	Ca12^xxviii—Al4—Al2^xviii	134.25 (6)
Si1^xii—Ca12—O5^xiii	31.05 (7)	Ca12^xxviii—Al4—Al2^ix	144.51 (6)
Al1^xii—Ca12—Si2^xiii	109.89 (8)	Ca12^xxviii—Al4—Al3^xxi	73.79 (6)
Al1^xii—Ca12—Al2^xiii	109.89 (8)	Ca12^xxviii—Al4—Si4	0
Al1^xii—Ca12—Al2^xiv	88.79 (8)	Ca12^xxviii—Al4—O3^xxi	53.24 (9)
Al1^xii—Ca12—Al3^xii	54.32 (5)	Ca12^xxviii—Al4—O4^xviii	117.26 (9)
Al1^xii—Ca12—Al3^xv	155.22 (8)	Ca12^xxviii—Al4—O5^xxiii	48.34 (9)
Al1^xii—Ca12—Si4^xvi	60.38 (5)	Ca12^xxviii—Al4—O7^xviii	132.08 (8)
Al1^xii—Ca12—Si4^xv	87.43 (7)	Ca12^xv—Al4—Na12^xxviii	77.39 (6)
Al1^xii—Ca12—Al4^xvi	60.38 (5)	Ca12^xv—Al4—Na12^xv	0.0 (5)
Al1^xii—Ca12—Al4^xv	87.43 (7)	Ca12^xv—Al4—Al2^xviii	68.15 (5)
Al1^xii—Ca12—O1^xv	137.65 (11)	Ca12^xv—Al4—Al2^ix	117.10 (5)
Al1^xii—Ca12—O3^xvii	91.37 (9)	Ca12^xv—Al4—Al3^xxi	118.53 (6)
Al1^xii—Ca12—O4^xiv	89.37 (10)	Ca12^xv—Al4—Si4	0
Al1^xii—Ca12—O5^xiii	31.05 (7)	Ca12^xv—Al4—O3^xxi	106.08 (9)
Si2^xiii—Ca12—Al2^xiii	0.0 (5)	Ca12^xv—Al4—O4^xviii	45.16 (8)
Si2^xiii—Ca12—Al2^xiv	97.76 (5)	Ca12^xv—Al4—O5^xxiii	59.51 (8)
Si2^xiii—Ca12—Al3^xii	80.40 (5)	Ca12^xv—Al4—O7^xviii	141.20 (9)
Si2^xiii—Ca12—Al3^xv	51.81 (4)	Na12^xxviii—Al4—Na12^xv	77.39 (6)
Si2^xiii—Ca12—Si4^xvi	111.16 (8)	Na12^xxviii—Al4—Al2^xviii	134.25 (6)
Si2^xiii—Ca12—Si4^xv	146.21 (8)	Na12^xxviii—Al4—Al2^ix	144.51 (6)
Si2^xiii—Ca12—Al4^xvi	111.16 (8)	Na12^xxviii—Al4—Al3^xxi	73.79 (6)
Si2^xiii—Ca12—Al4^xv	146.21 (8)	Na12^xxviii—Al4—Si4	0
Si2^xiii—Ca12—O1^xv	28.76 (5)	Na12^xxviii—Al4—O3^xxi	53.24 (9)
Si2^xiii—Ca12—O3^xvii	91.81 (9)	Na12^xxviii—Al4—O4^xviii	117.26 (9)
Si2^xiii—Ca12—O4^xiv	119.15 (8)	Na12^xxviii—Al4—O5^xxiii	48.34 (9)
Si2^xiii—Ca12—O5^xiii	124.19 (11)	Na12^xxviii—Al4—O7^xviii	132.08 (8)
Al2^xiii—Ca12—Al2^xiv	97.76 (5)	Na12^xv—Al4—Al2^xviii	68.15 (5)
Al2^xiii—Ca12—Al3^xii	80.40 (5)	Na12^xv—Al4—Al2^ix	117.10 (5)
Al2^xiii—Ca12—Al3^xv	51.81 (4)	Na12^xv—Al4—Al3^xxi	118.53 (6)
Al2^xiii—Ca12—Si4^xvi	111.16 (8)	Na12^xv—Al4—Si4	0
Al2^xiii—Ca12—Si4^xv	146.21 (8)	Na12^xv—Al4—O3^xxi	106.08 (9)
Al2^xiii—Ca12—Al4^xvi	111.16 (8)	Na12^xv—Al4—O4^xviii	45.16 (8)
Al2^xiii—Ca12—Al4^xv	146.21 (8)	Na12^xv—Al4—O5^xxiii	59.51 (8)
Al2^xiii—Ca12—O1^xv	28.76 (5)	Na12^xv—Al4—O7^xviii	141.20 (9)
Al2^xiii—Ca12—O3^xvii	91.81 (9)	Al2^xviii—Al4—Al2^ix	79.89 (2)
Al2^xiii—Ca12—O4^xiv	119.15 (8)	Al2^xviii—Al4—Al3^xxi	96.85 (3)
Al2^xiii—Ca12—O5^xiii	124.19 (11)	Al2^xviii—Al4—Si4	0
Al2^xiv—Ca12—Al3^xii	48.24 (4)	Al2^xviii—Al4—O3^xxi	108.56 (8)
Al2^xiv—Ca12—Al3^xv	78.85 (5)	Al2^xviii—Al4—O4^xviii	23.11 (8)
Al2^xiv—Ca12—Si4^xvi	142.98 (9)	Al2^xviii—Al4—O5^xxiii	124.84 (8)
Al2^xiv—Ca12—Si4^xv	52.45 (5)	Al2^xviii—Al4—O7^xviii	92.96 (6)
Al2^xiv—Ca12—Al4^xvi	142.98 (9)	Al2^ix—Al4—Al3^xxi	117.89 (4)
Al2^xiv—Ca12—Al4^xv	52.45 (5)	Al2^ix—Al4—Si4	0
Al2^xiv—Ca12—O1^xv	89.91 (8)	Al2^ix—Al4—O3^xxi	135.58 (8)
Al2^xiv—Ca12—O3^xvii	169.76 (10)	Al2^ix—Al4—O4^xviii	91.70 (7)
Al2^xiv—Ca12—O4^xiv	23.12 (5)	Al2^ix—Al4—O5^xxiii	108.60 (9)
Al2^xiv—Ca12—O5^xiii	111.52 (12)	Al2^ix—Al4—O7^xviii	24.11 (7)
Al3^xii—Ca12—Al3^xv	102.50 (5)	Al3^xxi—Al4—Si4	0
Al3^xii—Ca12—Si4^xvi	113.21 (8)	Al3^xxi—Al4—O3^xxi	20.80 (8)
Al3^xii—Ca12—Si4^xv	87.57 (7)	Al3^xxi—Al4—O4^xviii	108.83 (9)
Al3^xii—Ca12—Al4^xvi	113.21 (8)	Al3^xxi—Al4—O5^xxiii	121.92 (8)
Al3^xii—Ca12—Al4^xv	87.57 (7)	Al3^xxi—Al4—O7^xviii	96.45 (9)
Al3^xii—Ca12—O1^xv	95.47 (8)	Si4—Al4—O3^xxi	0
Al3^xii—Ca12—O3^xvii	137.98 (11)	Si4—Al4—O4^xviii	0
Al3^xii—Ca12—O4^xiv	65.26 (8)	Si4—Al4—O5^xxiii	0
Al3^xii—Ca12—O5^xiii	85.26 (10)	Si4—Al4—O7^xviii	0
Al3^xv—Ca12—Si4^xvi	137.36 (10)	O3^xxi—Al4—O4^xviii	113.09 (11)
Al3^xv—Ca12—Si4^xv	101.39 (7)	O3^xxi—Al4—O5^xxiii	101.57 (11)
Al3^xv—Ca12—Al4^xvi	137.36 (10)	O3^xxi—Al4—O7^xviii	112.12 (11)
Al3^xv—Ca12—Al4^xv	101.39 (7)	O4^xviii—Al4—O5^xxiii	102.29 (11)
Al3^xv—Ca12—O1^xv	23.38 (5)	O4^xviii—Al4—O7^xviii	110.34 (9)
Al3^xv—Ca12—O3^xvii	104.58 (11)	O5^xxiii—Al4—O7^xviii	116.92 (12)
Al3^xv—Ca12—O4^xiv	87.49 (8)	Ca11^vi—O1—Na11^vi	0.0 (5)
Al3^xv—Ca12—O5^xiii	169.63 (13)	Ca11^vi—O1—Ca12^xv	20.69 (9)
Si4^xvi—Ca12—Si4^xv	102.61 (6)	Ca11^vi—O1—Na12^xv	20.69 (9)
Si4^xvi—Ca12—Al4^xvi	0.0 (5)	Ca11^vi—O1—Si2^xx	127.65 (11)
Si4^xvi—Ca12—Al4^xv	102.61 (6)	Ca11^vi—O1—Al2^xx	127.65 (11)
Si4^xvi—Ca12—O1^xv	126.39 (12)	Ca11^vi—O1—Si3	105.01 (10)
Si4^xvi—Ca12—O3^xvii	32.79 (6)	Ca11^vi—O1—Al3	105.01 (10)
Si4^xvi—Ca12—O4^xiv	127.86 (9)	Na11^vi—O1—Ca12^xv	20.69 (9)
Si4^xvi—Ca12—O5^xiii	32.43 (7)	Na11^vi—O1—Na12^xv	20.69 (9)
Si4^xv—Ca12—Al4^xvi	102.61 (6)	Na11^vi—O1—Si2^xx	127.65 (11)
Si4^xv—Ca12—Al4^xv	0.0 (5)	Na11^vi—O1—Al2^xx	127.65 (11)
Si4^xv—Ca12—O1^xv	123.79 (11)	Na11^vi—O1—Si3	105.01 (10)
Si4^xv—Ca12—O3^xvii	117.32 (8)	Na11^vi—O1—Al3	105.01 (10)
Si4^xv—Ca12—O4^xiv	29.40 (5)	Ca12^xv—O1—Na12^xv	0.0 (5)
Si4^xv—Ca12—O5^xiii	85.65 (9)	Ca12^xv—O1—Si2^xx	108.77 (12)
Al4^xvi—Ca12—Al4^xv	102.61 (6)	Ca12^xv—O1—Al2^xx	108.77 (12)
Al4^xvi—Ca12—O1^xv	126.39 (12)	Ca12^xv—O1—Si3	122.60 (12)
Al4^xvi—Ca12—O3^xvii	32.79 (6)	Ca12^xv—O1—Al3	122.60 (12)
Al4^xvi—Ca12—O4^xiv	127.86 (9)	Na12^xv—O1—Si2^xx	108.77 (12)
Al4^xvi—Ca12—O5^xiii	32.43 (7)	Na12^xv—O1—Al2^xx	108.77 (12)
Al4^xv—Ca12—O1^xv	123.79 (11)	Na12^xv—O1—Si3	122.60 (12)
Al4^xv—Ca12—O3^xvii	117.32 (8)	Na12^xv—O1—Al3	122.60 (12)
Al4^xv—Ca12—O4^xiv	29.40 (5)	Si2^xx—O1—Al2^xx	0.0 (5)
Al4^xv—Ca12—O5^xiii	85.65 (9)	Si2^xx—O1—Si3	127.26 (11)
O1^xv—Ca12—O3^xvii	96.83 (13)	Si2^xx—O1—Al3	127.26 (11)
O1^xv—Ca12—O4^xiv	104.88 (10)	Al2^xx—O1—Si3	127.26 (11)
O1^xv—Ca12—O5^xiii	150.56 (15)	Al2^xx—O1—Al3	127.26 (11)
O3^xvii—Ca12—O4^xiv	146.63 (11)	Si3—O1—Al3	0.0 (5)
O3^xvii—Ca12—O5^xiii	65.21 (9)	Si1—O2—Al1	0.0 (5)
O4^xiv—Ca12—O5^xiii	102.12 (12)	Si1—O2—Si3	150.60 (17)
Ca11^xxiv—Na12—Ca11ⁱⁱⁱ	89.08 (17)	Si1—O2—Al3	150.60 (17)
Ca11^xxiv—Na12—Na11^xxiv	0.0 (5)	Al1—O2—Si3	150.60 (17)
Ca11^xxiv—Na12—Na11ⁱⁱⁱ	89.08 (17)	Al1—O2—Al3	150.60 (17)
Ca11^xxiv—Na12—Ca12	0	Si3—O2—Al3	0.0 (5)
Ca11^xxiv—Na12—Ca12^xi	77.04 (17)	Ca11^xxvi—O3—Na11^xxvi	0.0 (5)
Ca11^xxiv—Na12—Na12^xi	77.04 (17)	Ca11^xxvi—O3—Ca12^xxix	19.48 (8)
Ca11^xxiv—Na12—Si1^xii	142.29 (19)	Ca11^xxvi—O3—Na12^xxix	19.48 (8)
Ca11^xxiv—Na12—Al1^xii	142.29 (19)	Ca11^xxvi—O3—Si3	117.22 (10)
Ca11^xxiv—Na12—Si2^xiii	106.6 (2)	Ca11^xxvi—O3—Al3	117.22 (10)
Ca11^xxiv—Na12—Al2^xiii	106.6 (2)	Ca11^xxvi—O3—Si4^xviii	104.91 (12)
Ca11^xxiv—Na12—Al2^xiv	95.5 (2)	Ca11^xxvi—O3—Al4^xviii	104.91 (12)
Ca11^xxiv—Na12—Al3^xv	61.17 (16)	Na11^xxvi—O3—Ca12^xxix	19.48 (8)
Ca11^xxiv—Na12—Si4^xvi	97.67 (19)	Na11^xxvi—O3—Na12^xxix	19.48 (8)
Ca11^xxiv—Na12—Si4^xv	66.7 (2)	Na11^xxvi—O3—Si3	117.22 (10)
Ca11^xxiv—Na12—Al4^xvi	97.67 (19)	Na11^xxvi—O3—Al3	117.22 (10)
Ca11^xxiv—Na12—Al4^xv	66.7 (2)	Na11^xxvi—O3—Si4^xviii	104.91 (12)
Ca11^xxiv—Na12—O1^xv	79.9 (2)	Na11^xxvi—O3—Al4^xviii	104.91 (12)
Ca11^xxiv—Na12—O3^xvii	78.2 (2)	Ca12^xxix—O3—Na12^xxix	0.0 (5)
Ca11^xxiv—Na12—O4^xiv	81.0 (2)	Ca12^xxix—O3—Si3	127.69 (11)
Ca11^xxiv—Na12—O5^xiii	116.04 (18)	Ca12^xxix—O3—Al3	127.69 (11)
Ca11ⁱⁱⁱ—Na12—Na11^xxiv	89.08 (17)	Ca12^xxix—O3—Si4^xviii	93.97 (12)
Ca11ⁱⁱⁱ—Na12—Na11ⁱⁱⁱ	0.0 (5)	Ca12^xxix—O3—Al4^xviii	93.97 (12)
Ca11ⁱⁱⁱ—Na12—Ca12	0	Na12^xxix—O3—Si3	127.69 (11)
Ca11ⁱⁱⁱ—Na12—Ca12^xi	12.04 (5)	Na12^xxix—O3—Al3	127.69 (11)
Ca11ⁱⁱⁱ—Na12—Na12^xi	12.04 (5)	Na12^xxix—O3—Si4^xviii	93.97 (12)
Ca11ⁱⁱⁱ—Na12—Si1^xii	53.21 (5)	Na12^xxix—O3—Al4^xviii	93.97 (12)
Ca11ⁱⁱⁱ—Na12—Al1^xii	53.21 (5)	Si3—O3—Al3	0.0 (5)
Ca11ⁱⁱⁱ—Na12—Si2^xiii	158.29 (9)	Si3—O3—Si4^xviii	137.61 (12)
Ca11ⁱⁱⁱ—Na12—Al2^xiii	158.29 (9)	Si3—O3—Al4^xviii	137.61 (12)
Ca11ⁱⁱⁱ—Na12—Al2^xiv	95.49 (7)	Al3—O3—Si4^xviii	137.61 (12)
Ca11ⁱⁱⁱ—Na12—Al3^xv	148.59 (9)	Al3—O3—Al4^xviii	137.61 (12)
Ca11ⁱⁱⁱ—Na12—Si4^xvi	50.50 (4)	Si4^xviii—O3—Al4^xviii	0.0 (5)
Ca11ⁱⁱⁱ—Na12—Si4^xv	53.88 (4)	Ca11^ix—O4—Na11^ix	0.0 (5)
Ca11ⁱⁱⁱ—Na12—Al4^xvi	50.50 (4)	Ca11^ix—O4—Ca12^xiv	19.72 (8)
Ca11ⁱⁱⁱ—Na12—Al4^xv	53.88 (4)	Ca11^ix—O4—Na12^xiv	19.72 (8)
Ca11ⁱⁱⁱ—Na12—O1^xv	168.19 (13)	Ca11^ix—O4—Si2	131.73 (11)
Ca11ⁱⁱⁱ—Na12—O3^xvii	76.50 (7)	Ca11^ix—O4—Al2	131.73 (11)
Ca11ⁱⁱⁱ—Na12—O4^xiv	77.38 (8)	Ca11^ix—O4—Si4^xxi	94.35 (10)
Ca11ⁱⁱⁱ—Na12—O5^xiii	34.20 (7)	Ca11^ix—O4—Al4^xxi	94.35 (10)
Na11^xxiv—Na12—Na11ⁱⁱⁱ	89.08 (17)	Na11^ix—O4—Ca12^xiv	19.72 (8)
Na11^xxiv—Na12—Ca12	0	Na11^ix—O4—Na12^xiv	19.72 (8)
Na11^xxiv—Na12—Ca12^xi	77.04 (17)	Na11^ix—O4—Si2	131.73 (11)
Na11^xxiv—Na12—Na12^xi	77.04 (17)	Na11^ix—O4—Al2	131.73 (11)
Na11^xxiv—Na12—Si1^xii	142.29 (19)	Na11^ix—O4—Si4^xxi	94.35 (10)
Na11^xxiv—Na12—Al1^xii	142.29 (19)	Na11^ix—O4—Al4^xxi	94.35 (10)
Na11^xxiv—Na12—Si2^xiii	106.6 (2)	Ca12^xiv—O4—Na12^xiv	0.0 (5)
Na11^xxiv—Na12—Al2^xiii	106.6 (2)	Ca12^xiv—O4—Si2	121.16 (11)
Na11^xxiv—Na12—Al2^xiv	95.5 (2)	Ca12^xiv—O4—Al2	121.16 (11)
Na11^xxiv—Na12—Al3^xv	61.17 (16)	Ca12^xiv—O4—Si4^xxi	105.44 (10)
Na11^xxiv—Na12—Si4^xvi	97.67 (19)	Ca12^xiv—O4—Al4^xxi	105.44 (10)
Na11^xxiv—Na12—Si4^xv	66.7 (2)	Na12^xiv—O4—Si2	121.16 (11)
Na11^xxiv—Na12—Al4^xvi	97.67 (19)	Na12^xiv—O4—Al2	121.16 (11)
Na11^xxiv—Na12—Al4^xv	66.7 (2)	Na12^xiv—O4—Si4^xxi	105.44 (10)
Na11^xxiv—Na12—O1^xv	79.9 (2)	Na12^xiv—O4—Al4^xxi	105.44 (10)
Na11^xxiv—Na12—O3^xvii	78.2 (2)	Si2—O4—Al2	0.0 (5)
Na11^xxiv—Na12—O4^xiv	81.0 (2)	Si2—O4—Si4^xxi	133.08 (14)
Na11^xxiv—Na12—O5^xiii	116.04 (18)	Si2—O4—Al4^xxi	133.08 (14)
Na11ⁱⁱⁱ—Na12—Ca12	0	Al2—O4—Si4^xxi	133.08 (14)
Na11ⁱⁱⁱ—Na12—Ca12^xi	12.04 (5)	Al2—O4—Al4^xxi	133.08 (14)
Na11ⁱⁱⁱ—Na12—Na12^xi	12.04 (5)	Si4^xxi—O4—Al4^xxi	0.0 (5)
Na11ⁱⁱⁱ—Na12—Si1^xii	53.21 (5)	Ca11^x—O5—Na11^x	0.0 (5)
Na11ⁱⁱⁱ—Na12—Al1^xii	53.21 (5)	Ca11^x—O5—Ca12^xxv	112.02 (11)
Na11ⁱⁱⁱ—Na12—Si2^xiii	158.29 (9)	Ca11^x—O5—Na12^xxv	112.02 (11)
Na11ⁱⁱⁱ—Na12—Al2^xiii	158.29 (9)	Ca11^x—O5—Si1^xxi	105.62 (13)
Na11ⁱⁱⁱ—Na12—Al2^xiv	95.49 (7)	Ca11^x—O5—Al1^xxi	105.62 (13)
Na11ⁱⁱⁱ—Na12—Al3^xv	148.59 (9)	Ca11^x—O5—Si4^xxx	97.37 (9)
Na11ⁱⁱⁱ—Na12—Si4^xvi	50.50 (4)	Ca11^x—O5—Al4^xxx	97.37 (9)
Na11ⁱⁱⁱ—Na12—Si4^xv	53.88 (4)	Na11^x—O5—Ca12^xxv	112.02 (11)
Na11ⁱⁱⁱ—Na12—Al4^xvi	50.50 (4)	Na11^x—O5—Na12^xxv	112.02 (11)
Na11ⁱⁱⁱ—Na12—Al4^xv	53.88 (4)	Na11^x—O5—Si1^xxi	105.62 (13)
Na11ⁱⁱⁱ—Na12—O1^xv	168.19 (13)	Na11^x—O5—Al1^xxi	105.62 (13)
Na11ⁱⁱⁱ—Na12—O3^xvii	76.50 (7)	Na11^x—O5—Si4^xxx	97.37 (9)
Na11ⁱⁱⁱ—Na12—O4^xiv	77.38 (8)	Na11^x—O5—Al4^xxx	97.37 (9)
Na11ⁱⁱⁱ—Na12—O5^xiii	34.20 (7)	Ca12^xxv—O5—Na12^xxv	0.0 (5)
Ca12—Na12—Ca12^xi	0	Ca12^xxv—O5—Si1^xxi	101.46 (10)
Ca12—Na12—Na12^xi	0	Ca12^xxv—O5—Al1^xxi	101.46 (10)
Ca12—Na12—Si1^xii	0	Ca12^xxv—O5—Si4^xxx	99.23 (13)
Ca12—Na12—Al1^xii	0	Ca12^xxv—O5—Al4^xxx	99.23 (13)
Ca12—Na12—Si2^xiii	0	Na12^xxv—O5—Si1^xxi	101.46 (10)
Ca12—Na12—Al2^xiii	0	Na12^xxv—O5—Al1^xxi	101.46 (10)
Ca12—Na12—Al2^xiv	0	Na12^xxv—O5—Si4^xxx	99.23 (13)
Ca12—Na12—Al3^xv	0	Na12^xxv—O5—Al4^xxx	99.23 (13)
Ca12—Na12—Si4^xvi	0	Si1^xxi—O5—Al1^xxi	0.0 (5)
Ca12—Na12—Si4^xv	0	Si1^xxi—O5—Si4^xxx	140.26 (14)
Ca12—Na12—Al4^xvi	0	Si1^xxi—O5—Al4^xxx	140.26 (14)
Ca12—Na12—Al4^xv	0	Al1^xxi—O5—Si4^xxx	140.26 (14)
Ca12—Na12—O1^xv	0	Al1^xxi—O5—Al4^xxx	140.26 (14)
Ca12—Na12—O3^xvii	0	Si4^xxx—O5—Al4^xxx	0.0 (5)
Ca12—Na12—O4^xiv	0	Si1^xxi—O6—Al1^xxi	0.0 (5)
Ca12—Na12—O5^xiii	0	Si1^xxi—O6—Si2^xviii	157.08 (14)
Ca12^xi—Na12—Na12^xi	0.0 (5)	Si1^xxi—O6—Al2^xviii	157.08 (14)
Ca12^xi—Na12—Si1^xii	65.25 (6)	Al1^xxi—O6—Si2^xviii	157.08 (14)
Ca12^xi—Na12—Al1^xii	65.25 (6)	Al1^xxi—O6—Al2^xviii	157.08 (14)
Ca12^xi—Na12—Si2^xiii	164.82 (9)	Si2^xviii—O6—Al2^xviii	0.0 (5)
Ca12^xi—Na12—Al2^xiii	164.82 (9)	Si2^xxii—O7—Al2^xxii	0.0 (5)
Ca12^xi—Na12—Al2^xiv	96.51 (8)	Si2^xxii—O7—Si4^xxi	131.05 (14)
Ca12^xi—Na12—Al3^xv	136.99 (9)	Si2^xxii—O7—Al4^xxi	131.05 (14)
Ca12^xi—Na12—Si4^xvi	53.69 (5)	Al2^xxii—O7—Si4^xxi	131.05 (14)
Ca12^xi—Na12—Si4^xv	48.91 (5)	Al2^xxii—O7—Al4^xxi	131.05 (14)
Ca12^xi—Na12—Al4^xvi	53.69 (5)	Si4^xxi—O7—Al4^xxi	0.0 (5)
Ca12^xi—Na12—Al4^xv	48.91 (5)	Si1—O8—Al1	0.0 (5)
Ca12^xi—Na12—O1^xv	156.57 (13)	Si1—O8—Si3^xix	132.92 (12)
Ca12^xi—Na12—O3^xvii	74.32 (7)	Si1—O8—Al3^xix	132.92 (12)
Ca12^xi—Na12—O4^xiv	75.79 (8)	Al1—O8—Si3^xix	132.92 (12)
Ca12^xi—Na12—O5^xiii	44.39 (7)	Al1—O8—Al3^xix	132.92 (12)
Na12^xi—Na12—Si1^xii	65.25 (6)	Si3^xix—O8—Al3^xix	0.0 (5)

Symmetry codes: (i) −x+1, −y, −z; (ii) x, y−1, z; (iii) −x+1, −y+1, −z; (iv) −x+1/2, −y+1/2, −z; (v) x−1/2, y−1/2, z; (vi) −x+3/2, −y+1/2, −z+1; (vii) x+1/2, y−1/2, z−1; (viii) x−1/2, y−1/2, z−1; (ix) −x+5/2, −y+1/2, −z+1; (x) −x+3/2, −y+1/2, −z; (xi) −x+1, −y+2, −z; (xii) x+1/2, y+1/2, z; (xiii) x−1/2, y+1/2, z; (xiv) −x+5/2, −y+3/2, −z+1; (xv) −x+3/2, −y+3/2, −z+1; (xvi) x−1/2, y+1/2, z−1; (xvii) x+1/2, y+1/2, z−1; (xviii) x−1, y, z; (xix) −x+1/2, −y+1/2, −z+1; (xx) −x+2, −y+1, −z+1; (xxi) x+1, y, z; (xxii) −x+7/2, −y+1/2, −z+1; (xxiii) x, y, z+1; (xxiv) x, y+1, z; (xxv) x+1/2, y−1/2, z; (xxvi) x−1/2, y+1/2, z+1; (xxvii) x+1/2, y+1/2, z+1; (xxviii) x+1/2, y−1/2, z+1; (xxix) x−1/2, y−1/2, z+1; (xxx) x, y, z−1.

(III) top

Crystal data top

Al_1.403Ca_0.433Na_0.567O₈Si_2.597	Z = 8
M_r = 269.2	F(000) = 1068
Triclinic, X1(αβγ)0†	D_x = 2.683 Mg m⁻³
q = 0.070000a* + 0.044000b* + -0.241000c*	Mo Kα radiation, λ = 0.71073 Å
a = 8.1590 (9) Å	Cell parameters from 4618 reflections
b = 12.8579 (12) Å	θ = 3.2–28.4°
c = 14.1875 (19) Å	µ = 1.21 mm⁻¹
α = 93.369 (9)°	T = 293 K
β = 116.229 (12)°	Irregular, colourless
γ = 89.691 (8)°	0.18 × 0.10 × 0.05 mm
V = 1332.5 (3) Å³

† Symmetry operations: (1) x₁, x₂, x₃, x₄; (2) x₁, x₂, x₃+1/2, x₄+1/2; (3) x₁+1/2, x₂+1/2, x₃, x₄+1/2; (4) x₁+1/2, x₂+1/2, x₃+1/2, x₄.

Data collection top

Oxford Diffraction CCD diffractometer	8560 independent reflections
Radiation source: X-ray tube	4756 reflections with I > 3σ(I)
Graphite monochromator	R_int = 0.017
Detector resolution: 16.1500 pixels mm^-1	θ_max = 28.9°, θ_min = 3.2°
ω scans	h = −10→10
Absorption correction: analytical CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)	k = −17→17
T_min = 0.837, T_max = 0.948	l = −17→19
13172 measured reflections

Refinement top

Refinement on F²	149 constraints
R[F² > 2σ(F²)] = 0.048	Weighting scheme based on measured s.u.'s w = 1/(σ²(I) + 0.0004I²)
wR(F²) = 0.130	(Δ/σ)_max = 0.027
S = 1.55	Δρ_max = 1.57 e Å⁻³
8560 reflections	Δρ_min = −1.03 e Å⁻³
404 parameters	Absolute structure: 3932 of Friedel pairs used in the refinement
0 restraints	Absolute structure parameter: 0.20 (14)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ca1	0.5376 (3)	0.9930 (2)	0.0619 (2)	0.0624 (11)	0.4241
Na1	0.5376 (3)	0.9930 (2)	0.0619 (2)	0.0624 (11)	0.5759
Ca2	1.0037 (5)	1.0002 (3)	0.9179 (3)	0.0100 (8)	0.4424
Na2	0.9920 (6)	0.9616 (3)	0.9440 (4)	0.0100 (8)	0.5576
Si1	0.7731 (2)	0.31288 (13)	0.10703 (13)	0.0101 (7)	0.6299
Al1	0.7731 (2)	0.31288 (13)	0.10703 (13)	0.0101 (7)	0.3701
Si2	0.0875 (3)	0.61571 (13)	0.31275 (15)	0.0115 (7)	0.722
Al2	0.0875 (3)	0.61571 (13)	0.31275 (15)	0.0115 (7)	0.278
Si3	0.9569 (3)	0.10483 (12)	0.14978 (14)	0.0114 (7)	0.8668
Al3	0.9569 (3)	0.10483 (12)	0.14978 (14)	0.0114 (7)	0.1332
Si4	0.0836 (3)	0.38568 (12)	0.33274 (14)	0.0107 (6)	0.6711
Al4	0.0836 (3)	0.38568 (12)	0.33274 (14)	0.0107 (6)	0.3289
Si5	0.7757 (3)	0.66142 (12)	0.09795 (14)	0.0125 (7)	0.4671
Al5	0.7757 (3)	0.66142 (12)	0.09795 (14)	0.0125 (7)	0.5329
Si6	0.7626 (2)	0.33084 (12)	0.88407 (14)	0.0117 (7)	0.3438
Al6	0.7626 (2)	0.33084 (12)	0.88407 (14)	0.0117 (7)	0.6562
Si7	0.9515 (3)	0.87509 (13)	0.16975 (14)	0.0114 (7)	0.6859
Al7	0.9515 (3)	0.87509 (13)	0.16975 (14)	0.0114 (7)	0.3142
Si8	0.2668 (3)	0.17695 (13)	0.37516 (15)	0.0138 (7)	0.8076
Al8	0.2668 (3)	0.17695 (13)	0.37516 (15)	0.0138 (7)	0.1924
O1	0.9708 (7)	0.6033 (4)	0.1846 (4)	0.0172 (19)
O2	0.2530 (7)	0.3054 (4)	0.3816 (4)	0.023 (2)
O3	0.4538 (8)	0.1437 (4)	0.3696 (5)	0.026 (2)
O4	0.8512 (7)	0.9885 (3)	0.1310 (4)	0.0155 (18)
O5	0.7649 (8)	0.3671 (4)	0.0014 (4)	0.023 (2)
O6	0.0799 (8)	0.1270 (4)	0.2756 (4)	0.021 (2)
O7	0.7818 (7)	0.7874 (3)	0.1295 (4)	0.0167 (19)
O8	0.0786 (7)	0.1010 (3)	0.0836 (4)	0.018 (2)
O9	0.9539 (7)	0.3875 (4)	0.3935 (4)	0.021 (2)
O10	0.7525 (7)	0.1990 (4)	0.8508 (4)	0.022 (2)
O11	0.1848 (7)	0.5013 (3)	0.3528 (4)	0.0149 (18)
O12	0.9584 (7)	0.3620 (4)	0.2067 (4)	0.024 (2)
O13	0.2710 (8)	0.1258 (4)	0.4787 (4)	0.0193 (18)
O14	0.5884 (8)	0.3499 (4)	0.1154 (5)	0.025 (2)
O15	0.0737 (8)	0.8858 (4)	0.2998 (4)	0.022 (2)
O16	0.7860 (7)	0.1842 (4)	0.1000 (4)	0.0186 (19)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ca1	0.0095 (11)	0.1024 (19)	0.0571 (15)	−0.0032 (11)	0.0060 (10)	−0.0613 (14)
Na1	0.0095 (11)	0.1024 (19)	0.0571 (15)	−0.0032 (11)	0.0060 (10)	−0.0613 (14)
Ca2	0.0109 (12)	0.0039 (9)	0.0164 (11)	−0.0013 (7)	0.0071 (8)	0.0013 (8)
Na2	0.0109 (12)	0.0039 (9)	0.0164 (11)	−0.0013 (7)	0.0071 (8)	0.0013 (8)
Si1	0.0090 (10)	0.0135 (8)	0.0071 (8)	0.0051 (6)	0.0028 (8)	0.0017 (7)
Al1	0.0090 (10)	0.0135 (8)	0.0071 (8)	0.0051 (6)	0.0028 (8)	0.0017 (7)
Si2	0.0099 (9)	0.0115 (7)	0.0122 (9)	0.0016 (6)	0.0038 (8)	0.0022 (7)
Al2	0.0099 (9)	0.0115 (7)	0.0122 (9)	0.0016 (6)	0.0038 (8)	0.0022 (7)
Si3	0.0117 (9)	0.0101 (7)	0.0125 (9)	0.0015 (6)	0.0053 (7)	0.0009 (7)
Al3	0.0117 (9)	0.0101 (7)	0.0125 (9)	0.0015 (6)	0.0053 (7)	0.0009 (7)
Si4	0.0117 (10)	0.0102 (7)	0.0092 (8)	−0.0005 (6)	0.0037 (7)	0.0001 (7)
Al4	0.0117 (10)	0.0102 (7)	0.0092 (8)	−0.0005 (6)	0.0037 (7)	0.0001 (7)
Si5	0.0160 (11)	0.0126 (8)	0.0092 (8)	−0.0021 (7)	0.0061 (8)	−0.0003 (7)
Al5	0.0160 (11)	0.0126 (8)	0.0092 (8)	−0.0021 (7)	0.0061 (8)	−0.0003 (7)
Si6	0.0089 (10)	0.0153 (8)	0.0109 (9)	−0.0018 (7)	0.0044 (8)	0.0016 (7)
Al6	0.0089 (10)	0.0153 (8)	0.0109 (9)	−0.0018 (7)	0.0044 (8)	0.0016 (7)
Si7	0.0140 (10)	0.0122 (8)	0.0090 (9)	−0.0016 (7)	0.0060 (8)	0.0006 (7)
Al7	0.0140 (10)	0.0122 (8)	0.0090 (9)	−0.0016 (7)	0.0060 (8)	0.0006 (7)
Si8	0.0150 (11)	0.0155 (8)	0.0116 (9)	0.0018 (7)	0.0068 (8)	−0.0014 (7)
Al8	0.0150 (11)	0.0155 (8)	0.0116 (9)	0.0018 (7)	0.0068 (8)	−0.0014 (7)
O1	0.019 (3)	0.015 (2)	0.013 (2)	0.0043 (19)	0.004 (2)	0.001 (2)
O2	0.023 (3)	0.015 (2)	0.025 (3)	0.010 (2)	0.007 (3)	0.001 (2)
O3	0.021 (3)	0.027 (2)	0.029 (3)	0.002 (2)	0.012 (3)	−0.003 (2)
O4	0.024 (3)	0.016 (2)	0.010 (2)	0.0043 (18)	0.011 (2)	0.0070 (18)
O5	0.037 (3)	0.018 (2)	0.021 (3)	0.003 (2)	0.019 (3)	0.002 (2)
O6	0.021 (3)	0.016 (2)	0.016 (2)	0.009 (2)	0.000 (2)	0.0000 (19)
O7	0.018 (3)	0.013 (2)	0.019 (2)	−0.0097 (18)	0.008 (2)	−0.005 (2)
O8	0.024 (3)	0.019 (2)	0.015 (2)	−0.0058 (19)	0.012 (2)	−0.0045 (19)
O9	0.015 (3)	0.022 (2)	0.029 (3)	−0.0015 (19)	0.012 (2)	0.001 (2)
O10	0.018 (3)	0.028 (3)	0.019 (3)	0.002 (2)	0.006 (2)	0.006 (2)
O11	0.010 (2)	0.0094 (18)	0.020 (3)	−0.0071 (17)	0.002 (2)	−0.0007 (19)
O12	0.015 (3)	0.031 (3)	0.016 (2)	−0.008 (2)	0.000 (2)	−0.007 (2)
O13	0.019 (3)	0.028 (3)	0.009 (2)	−0.001 (2)	0.005 (2)	0.002 (2)
O14	0.019 (3)	0.028 (2)	0.036 (4)	0.003 (2)	0.021 (3)	−0.001 (2)
O15	0.018 (3)	0.027 (2)	0.015 (3)	−0.003 (2)	0.001 (2)	0.002 (2)
O16	0.015 (3)	0.024 (2)	0.012 (2)	0.0033 (19)	0.002 (2)	−0.003 (2)

Geometric parameters (Å, º) top

	Average	Minimum	Maximum
Ca1—O1ⁱ	2.43 (2)	2.41 (2)	2.46 (2)
Ca1—O4	2.320 (11)	2.277 (10)	2.381 (11)
Ca1—O5ⁱ	2.55 (2)	2.45 (2)	2.66 (2)
Ca1—O9ⁱⁱ	2.50 (2)	2.469 (19)	2.53 (2)
Ca1—O13ⁱⁱⁱ	2.65 (2)	2.53 (2)	2.77 (2)
Ca2—O2^iv	3.13 (3)	2.571 (16)	3.732 (16)
Ca2—O5^v	2.63 (3)	2.361 (15)	2.929 (16)
Ca2—O6^vi	2.95 (3)	2.512 (15)	3.381 (15)
Ca2—O8^vii	2.47 (3)	2.44 (5)	2.529 (11)
Ca2—O11^iv	2.391 (13)	2.321 (13)	2.483 (12)
Ca2—O13^vi	2.53 (3)	2.321 (16)	2.774 (16)
Ca2—O15^viii	2.44 (3)	2.41 (5)	2.474 (16)
Na2—O2^iv	2.632 (15)	2.455 (12)	2.815 (13)
Na2—O5^v	2.365 (15)	2.230 (14)	2.499 (14)
Na2—O8^vii	2.450 (11)	2.400 (10)	2.499 (10)
Na2—O11^iv	2.328 (11)	2.300 (11)	2.357 (11)
Na2—O15^viii	2.560 (14)	2.487 (14)	2.634 (14)
Si1—O5	1.665 (14)	1.619 (15)	1.711 (14)
Si1—O12	1.644 (10)	1.598 (10)	1.690 (10)
Si1—O14	1.633 (14)	1.598 (15)	1.663 (15)
Si1—O16	1.7 (4)	1.6 (11)	1.70 (3)
Si2—O1^ix	1.635 (8)	1.595 (8)	1.676 (8)
Si2—O3ⁱ	1.647 (15)	1.605 (15)	1.690 (15)
Si2—O10ⁱⁱ	1.599 (13)	1.551 (17)	1.646 (17)
Si2—O11	1.674 (12)	1.642 (15)	1.708 (15)
Si3—O4^x	1.679 (12)	1.644 (13)	1.712 (13)
Si3—O6^xi	1.623 (8)	1.594 (8)	1.652 (8)
Si3—O8^xi	1.643 (13)	1.597 (11)	1.683 (11)
Si3—O16	1.6 (10)	1.6 (16)	2(2)
Si4—O2	1.639 (14)	1.598 (15)	1.675 (14)
Si4—O9^ix	1.635 (12)	1.595 (13)	1.671 (13)
Si4—O11	1.653 (12)	1.628 (13)	1.676 (13)
Si4—O12^ix	1.631 (9)	1.605 (9)	1.655 (8)
Si5—O1	1.724 (11)	1.684 (11)	1.764 (12)
Si5—O7	1.650 (16)	1.616 (15)	1.684 (15)
Si5—O8^xii	1.714 (13)	1.644 (13)	1.784 (13)
Si5—O13^xiii	1.712 (11)	1.674 (11)	1.749 (11)
Si6—O5^xiv	1.696 (12)	1.637 (12)	1.754 (12)
Si6—O9^xv	1.675 (12)	1.644 (13)	1.704 (13)
Si6—O10	1.726 (16)	1.674 (19)	1.778 (19)
Si6—O15^xvi	1.663 (11)	1.613 (12)	1.714 (12)
Si7—O4	1.668 (12)	1.621 (12)	1.717 (12)
Si7—O7	1.660 (13)	1.613 (13)	1.707 (13)
Si7—O14^xii	1.637 (15)	1.592 (15)	1.682 (16)
Si7—O15^xi	1.662 (8)	1.625 (8)	1.699 (8)
Si8—O2	1.656 (16)	1.600 (14)	1.711 (13)
Si8—O3	1.619 (15)	1.568 (13)	1.666 (13)
Si8—O6	1.654 (9)	1.619 (9)	1.689 (9)
Si8—O13	1.632 (12)	1.588 (11)	1.674 (11)

Na1—Ca1—Ca2^xvii	0	0	0
Na1—Ca1—Na2^xvii	0	0	0
Na1—Ca1—Si1ⁱ	0	0	0
Na1—Ca1—Al1ⁱ	0	0	0
Na1—Ca1—Al2^xii	0	0	0
Na1—Ca1—Si3^xviii	0	0	0
Na1—Ca1—Al3^xviii	0	0	0
Na1—Ca1—Al4^xiii	0	0	0
Na1—Ca1—Si5ⁱ	0	0	0
Na1—Ca1—Al5ⁱ	0	0	0
Na1—Ca1—Si6^xix	0	0	0
Na1—Ca1—Al6^xix	0	0	0
Na1—Ca1—Si7	0	0	0
Na1—Ca1—Al7	0	0	0
Na1—Ca1—Si8ⁱⁱⁱ	0	0	0
Na1—Ca1—Al8ⁱⁱⁱ	0	0	0
Na1—Ca1—O1ⁱ	0	0	0
Na1—Ca1—O4	0	0	0
Na1—Ca1—O5ⁱ	0	0	0
Na1—Ca1—O9ⁱⁱ	0	0	0
Na1—Ca1—O13ⁱⁱⁱ	0	0	0
Ca2^xvii—Ca1—Na2^xvii	9.7 (5)	1.80 (17)	17.9 (2)
Ca2^xvii—Ca1—Si1ⁱ	59.0 (6)	52.0 (2)	65.8 (2)
Ca2^xvii—Ca1—Al1ⁱ	59.0 (6)	52.0 (2)	65.8 (2)
Ca2^xvii—Ca1—Al2^xii	96.2 (5)	95.2 (6)	97.1 (4)
Ca2^xvii—Ca1—Si3^xviii	152.3 (11)	145.9 (12)	158.7 (13)
Ca2^xvii—Ca1—Al3^xviii	152.3 (11)	145.9 (12)	158.7 (13)
Ca2^xvii—Ca1—Al4^xiii	94.8 (5)	92.5 (6)	97.0 (5)
Ca2^xvii—Ca1—Si5ⁱ	52.2 (5)	49.8 (3)	55.2 (2)
Ca2^xvii—Ca1—Al5ⁱ	52.2 (5)	49.8 (3)	55.2 (2)
Ca2^xvii—Ca1—Si6^xix	52.3 (5)	50.8 (6)	54.3 (3)
Ca2^xvii—Ca1—Al6^xix	52.3 (5)	50.8 (6)	54.3 (3)
Ca2^xvii—Ca1—Si7	155.1 (11)	149.7 (13)	160.3 (13)
Ca2^xvii—Ca1—Al7	155.1 (11)	149.7 (13)	160.3 (13)
Ca2^xvii—Ca1—Si8ⁱⁱⁱ	53.4 (6)	47.9 (2)	59.1 (3)
Ca2^xvii—Ca1—Al8ⁱⁱⁱ	53.4 (6)	47.9 (2)	59.1 (3)
Ca2^xvii—Ca1—O1ⁱ	78.3 (5)	77.1 (6)	79.6 (3)
Ca2^xvii—Ca1—O4	171.8 (11)	166.8 (11)	177.7 (8)
Ca2^xvii—Ca1—O5ⁱ	41.4 (7)	35.7 (4)	47.3 (3)
Ca2^xvii—Ca1—O9ⁱⁱ	75.9 (5)	73.6 (7)	77.7 (6)
Ca2^xvii—Ca1—O13ⁱⁱⁱ	39.5 (6)	33.6 (3)	45.8 (3)
Na2^xvii—Ca1—Si1ⁱ	49.48 (19)	47.6 (2)	51.20 (18)
Na2^xvii—Ca1—Al1ⁱ	49.48 (19)	47.6 (2)	51.20 (18)
Na2^xvii—Ca1—Al2^xii	93.3 (3)	92.0 (3)	94.3 (3)
Na2^xvii—Ca1—Si3^xviii	160.3 (8)	150.5 (8)	169.7 (8)
Na2^xvii—Ca1—Al3^xviii	160.3 (8)	150.5 (8)	169.7 (8)
Na2^xvii—Ca1—Al4^xiii	97.5 (3)	96.7 (4)	98.8 (3)
Na2^xvii—Ca1—Si5ⁱ	54.96 (18)	54.01 (18)	55.75 (17)
Na2^xvii—Ca1—Al5ⁱ	54.96 (18)	54.01 (18)	55.75 (17)
Na2^xvii—Ca1—Si6^xix	50.02 (16)	47.67 (18)	52.38 (17)
Na2^xvii—Ca1—Al6^xix	50.02 (16)	47.67 (18)	52.38 (17)
Na2^xvii—Ca1—Si7	147.4 (8)	137.5 (8)	157.5 (9)
Na2^xvii—Ca1—Al7	147.4 (8)	137.5 (8)	157.5 (9)
Na2^xvii—Ca1—Si8ⁱⁱⁱ	62.90 (19)	59.9 (2)	65.92 (19)
Na2^xvii—Ca1—Al8ⁱⁱⁱ	62.90 (19)	59.9 (2)	65.92 (19)
Na2^xvii—Ca1—O1ⁱ	77.3 (3)	76.4 (3)	78.5 (3)
Na2^xvii—Ca1—O4	169.1 (10)	158.4 (11)	179.1 (9)
Na2^xvii—Ca1—O5ⁱ	33.6 (3)	31.3 (3)	35.8 (4)
Na2^xvii—Ca1—O9ⁱⁱ	76.9 (3)	75.3 (3)	78.9 (3)
Na2^xvii—Ca1—O13ⁱⁱⁱ	47.6 (3)	46.0 (3)	49.3 (3)
Si1ⁱ—Ca1—Al1ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si1ⁱ—Ca1—Al2^xii	83.5 (4)	79.5 (3)	87.4 (4)
Si1ⁱ—Ca1—Si3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Si1ⁱ—Ca1—Al3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Si1ⁱ—Ca1—Al4^xiii	105.1 (6)	100.0 (6)	109.9 (6)
Si1ⁱ—Ca1—Si5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Si1ⁱ—Ca1—Al5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Si1ⁱ—Ca1—Si6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Si1ⁱ—Ca1—Al6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Si1ⁱ—Ca1—Si7	100.3 (7)	91.9 (6)	109.1 (8)
Si1ⁱ—Ca1—Al7	100.3 (7)	91.9 (6)	109.1 (8)
Si1ⁱ—Ca1—Si8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Si1ⁱ—Ca1—Al8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Si1ⁱ—Ca1—O1ⁱ	83.1 (5)	78.6 (5)	87.5 (5)
Si1ⁱ—Ca1—O4	124.2 (9)	111.5 (9)	137.2 (9)
Si1ⁱ—Ca1—O5ⁱ	27.4 (3)	24.6 (3)	30.2 (4)
Si1ⁱ—Ca1—O9ⁱⁱ	84.9 (7)	80.0 (7)	89.7 (7)
Si1ⁱ—Ca1—O13ⁱⁱⁱ	94.5 (4)	92.4 (4)	96.4 (3)
Al1ⁱ—Ca1—Al2^xii	83.5 (4)	79.5 (3)	87.4 (4)
Al1ⁱ—Ca1—Si3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Al1ⁱ—Ca1—Al3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Al1ⁱ—Ca1—Al4^xiii	105.1 (6)	100.0 (6)	109.9 (6)
Al1ⁱ—Ca1—Si5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Al1ⁱ—Ca1—Al5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Al1ⁱ—Ca1—Si6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Al1ⁱ—Ca1—Al6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Al1ⁱ—Ca1—Si7	100.3 (7)	91.9 (6)	109.1 (8)
Al1ⁱ—Ca1—Al7	100.3 (7)	91.9 (6)	109.1 (8)
Al1ⁱ—Ca1—Si8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Al1ⁱ—Ca1—Al8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Al1ⁱ—Ca1—O1ⁱ	83.1 (5)	78.6 (5)	87.5 (5)
Al1ⁱ—Ca1—O4	124.2 (9)	111.5 (9)	137.2 (9)
Al1ⁱ—Ca1—O5ⁱ	27.4 (3)	24.6 (3)	30.2 (4)
Al1ⁱ—Ca1—O9ⁱⁱ	84.9 (7)	80.0 (7)	89.7 (7)
Al1ⁱ—Ca1—O13ⁱⁱⁱ	94.5 (4)	92.4 (4)	96.4 (3)
Al2^xii—Ca1—Si3^xviii	80.0 (4)	78.4 (4)	81.4 (4)
Al2^xii—Ca1—Al3^xviii	80.0 (4)	78.4 (4)	81.4 (4)
Al2^xii—Ca1—Al4^xiii	166.7 (4)	162.7 (7)	170.01 (14)
Al2^xii—Ca1—Si5ⁱ	52.6 (3)	51.9 (3)	53.2 (3)
Al2^xii—Ca1—Al5ⁱ	52.6 (3)	51.9 (3)	53.2 (3)
Al2^xii—Ca1—Si6^xix	136.9 (4)	131.0 (5)	142.5 (4)
Al2^xii—Ca1—Al6^xix	136.9 (4)	131.0 (5)	142.5 (4)
Al2^xii—Ca1—Si7	94.2 (3)	92.5 (3)	95.6 (2)
Al2^xii—Ca1—Al7	94.2 (3)	92.5 (3)	95.6 (2)
Al2^xii—Ca1—Si8ⁱⁱⁱ	102.6 (6)	99.1 (6)	106.0 (6)
Al2^xii—Ca1—Al8ⁱⁱⁱ	102.6 (6)	99.1 (6)	106.0 (6)
Al2^xii—Ca1—O1ⁱ	20.8 (2)	19.2 (2)	22.3 (2)
Al2^xii—Ca1—O4	88.4 (5)	86.9 (5)	90.5 (5)
Al2^xii—Ca1—O5ⁱ	105.3 (5)	99.2 (5)	111.2 (5)
Al2^xii—Ca1—O9ⁱⁱ	166.8 (7)	159.4 (9)	172.8 (3)
Al2^xii—Ca1—O13ⁱⁱⁱ	84.0 (6)	83.7 (6)	84.4 (6)
Si3^xviii—Ca1—Al3^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xviii—Ca1—Al4^xiii	88.3 (3)	85.1 (3)	90.9 (3)
Si3^xviii—Ca1—Si5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Si3^xviii—Ca1—Al5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Si3^xviii—Ca1—Si6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Si3^xviii—Ca1—Al6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Si3^xviii—Ca1—Si7	51.80 (18)	51.14 (19)	52.22 (17)
Si3^xviii—Ca1—Al7	51.80 (18)	51.14 (19)	52.22 (17)
Si3^xviii—Ca1—Si8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Si3^xviii—Ca1—Al8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Si3^xviii—Ca1—O1ⁱ	91.2 (6)	87.1 (6)	95.0 (6)
Si3^xviii—Ca1—O4	26.5 (3)	22.4 (4)	30.2 (3)
Si3^xviii—Ca1—O5ⁱ	164.6 (9)	156.8 (10)	169.9 (9)
Si3^xviii—Ca1—O9ⁱⁱ	110.5 (5)	107.1 (5)	113.1 (5)
Si3^xviii—Ca1—O13ⁱⁱⁱ	113.1 (9)	103.7 (8)	122.9 (10)
Al3^xviii—Ca1—Al4^xiii	88.3 (3)	85.1 (3)	90.9 (3)
Al3^xviii—Ca1—Si5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Al3^xviii—Ca1—Al5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Al3^xviii—Ca1—Si6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Al3^xviii—Ca1—Al6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Al3^xviii—Ca1—Si7	51.80 (18)	51.14 (19)	52.22 (17)
Al3^xviii—Ca1—Al7	51.80 (18)	51.14 (19)	52.22 (17)
Al3^xviii—Ca1—Si8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Al3^xviii—Ca1—Al8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Al3^xviii—Ca1—O1ⁱ	91.2 (6)	87.1 (6)	95.0 (6)
Al3^xviii—Ca1—O4	26.5 (3)	22.4 (4)	30.2 (3)
Al3^xviii—Ca1—O5ⁱ	164.6 (9)	156.8 (10)	169.9 (9)
Al3^xviii—Ca1—O9ⁱⁱ	110.5 (5)	107.1 (5)	113.1 (5)
Al3^xviii—Ca1—O13ⁱⁱⁱ	113.1 (9)	103.7 (8)	122.9 (10)
Al4^xiii—Ca1—Si5ⁱ	134.0 (5)	126.5 (6)	141.0 (4)
Al4^xiii—Ca1—Al5ⁱ	134.0 (5)	126.5 (6)	141.0 (4)
Al4^xiii—Ca1—Si6^xix	53.6 (3)	53.3 (3)	54.2 (3)
Al4^xiii—Ca1—Al6^xix	53.6 (3)	53.3 (3)	54.2 (3)
Al4^xiii—Ca1—Si7	76.8 (4)	74.4 (4)	78.6 (3)
Al4^xiii—Ca1—Al7	76.8 (4)	74.4 (4)	78.6 (3)
Al4^xiii—Ca1—Si8ⁱⁱⁱ	81.0 (3)	75.9 (3)	86.1 (4)
Al4^xiii—Ca1—Al8ⁱⁱⁱ	81.0 (3)	75.9 (3)	86.1 (4)
Al4^xiii—Ca1—O1ⁱ	163.8 (8)	153.2 (10)	173.5 (5)
Al4^xiii—Ca1—O4	79.8 (5)	79.2 (4)	80.9 (4)
Al4^xiii—Ca1—O5ⁱ	85.0 (6)	83.8 (6)	86.6 (6)
Al4^xiii—Ca1—O9ⁱⁱ	22.4 (3)	22.0 (3)	22.7 (3)
Al4^xiii—Ca1—O13ⁱⁱⁱ	102.0 (5)	94.9 (5)	109.1 (5)
Si5ⁱ—Ca1—Al5ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si5ⁱ—Ca1—Si6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Si5ⁱ—Ca1—Al6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Si5ⁱ—Ca1—Si7	145.5 (5)	144.4 (4)	147.3 (5)
Si5ⁱ—Ca1—Al7	145.5 (5)	144.4 (4)	147.3 (5)
Si5ⁱ—Ca1—Si8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Si5ⁱ—Ca1—Al8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Si5ⁱ—Ca1—O1ⁱ	31.8 (3)	30.9 (3)	32.7 (3)
Si5ⁱ—Ca1—O4	130.0 (9)	122.1 (10)	136.7 (8)
Si5ⁱ—Ca1—O5ⁱ	85.2 (4)	82.7 (4)	87.6 (4)
Si5ⁱ—Ca1—O9ⁱⁱ	123.3 (4)	118.3 (5)	128.0 (3)
Si5ⁱ—Ca1—O13ⁱⁱⁱ	32.1 (3)	31.5 (3)	32.7 (3)
Al5ⁱ—Ca1—Si6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Al5ⁱ—Ca1—Al6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Al5ⁱ—Ca1—Si7	145.5 (5)	144.4 (4)	147.3 (5)
Al5ⁱ—Ca1—Al7	145.5 (5)	144.4 (4)	147.3 (5)
Al5ⁱ—Ca1—Si8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Al5ⁱ—Ca1—Al8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Al5ⁱ—Ca1—O1ⁱ	31.8 (3)	30.9 (3)	32.7 (3)
Al5ⁱ—Ca1—O4	130.0 (9)	122.1 (10)	136.7 (8)
Al5ⁱ—Ca1—O5ⁱ	85.2 (4)	82.7 (4)	87.6 (4)
Al5ⁱ—Ca1—O9ⁱⁱ	123.3 (4)	118.3 (5)	128.0 (3)
Al5ⁱ—Ca1—O13ⁱⁱⁱ	32.1 (3)	31.5 (3)	32.7 (3)
Si6^xix—Ca1—Al6^xix	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xix—Ca1—Si7	106.2 (7)	100.5 (7)	111.6 (8)
Si6^xix—Ca1—Al7	106.2 (7)	100.5 (7)	111.6 (8)
Si6^xix—Ca1—Si8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Si6^xix—Ca1—Al8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Si6^xix—Ca1—O1ⁱ	126.0 (4)	121.9 (4)	130.1 (3)
Si6^xix—Ca1—O4	124.1 (9)	118.3 (9)	128.5 (8)
Si6^xix—Ca1—O5ⁱ	31.9 (4)	31.1 (3)	32.8 (4)
Si6^xix—Ca1—O9ⁱⁱ	31.3 (3)	30.6 (3)	31.9 (3)
Si6^xix—Ca1—O13ⁱⁱⁱ	84.2 (3)	82.4 (3)	85.7 (3)
Al6^xix—Ca1—Si7	106.2 (7)	100.5 (7)	111.6 (8)
Al6^xix—Ca1—Al7	106.2 (7)	100.5 (7)	111.6 (8)
Al6^xix—Ca1—Si8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Al6^xix—Ca1—Al8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Al6^xix—Ca1—O1ⁱ	126.0 (4)	121.9 (4)	130.1 (3)
Al6^xix—Ca1—O4	124.1 (9)	118.3 (9)	128.5 (8)
Al6^xix—Ca1—O5ⁱ	31.9 (4)	31.1 (3)	32.8 (4)
Al6^xix—Ca1—O9ⁱⁱ	31.3 (3)	30.6 (3)	31.9 (3)
Al6^xix—Ca1—O13ⁱⁱⁱ	84.2 (3)	82.4 (3)	85.7 (3)
Si7—Ca1—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Si7—Ca1—Si8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Si7—Ca1—Al8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Si7—Ca1—O1ⁱ	114.5 (4)	111.8 (4)	117.2 (4)
Si7—Ca1—O4	25.4 (4)	21.1 (4)	29.6 (3)
Si7—Ca1—O5ⁱ	114.0 (10)	105.9 (9)	122.3 (11)
Si7—Ca1—O9ⁱⁱ	89.7 (6)	85.3 (6)	93.7 (6)
Si7—Ca1—O13ⁱⁱⁱ	164.6 (9)	154.7 (9)	173.7 (9)
Al7—Ca1—Si8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Al7—Ca1—Al8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Al7—Ca1—O1ⁱ	114.5 (4)	111.8 (4)	117.2 (4)
Al7—Ca1—O4	25.4 (4)	21.1 (4)	29.6 (3)
Al7—Ca1—O5ⁱ	114.0 (10)	105.9 (9)	122.3 (11)
Al7—Ca1—O9ⁱⁱ	89.7 (6)	85.3 (6)	93.7 (6)
Al7—Ca1—O13ⁱⁱⁱ	164.6 (9)	154.7 (9)	173.7 (9)
Si8ⁱⁱⁱ—Ca1—Al8ⁱⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si8ⁱⁱⁱ—Ca1—O1ⁱ	83.6 (7)	78.7 (7)	88.3 (7)
Si8ⁱⁱⁱ—Ca1—O4	123.1 (9)	111.6 (9)	134.7 (8)
Si8ⁱⁱⁱ—Ca1—O5ⁱ	91.2 (4)	88.8 (4)	93.4 (3)
Si8ⁱⁱⁱ—Ca1—O9ⁱⁱ	79.5 (4)	74.1 (4)	84.7 (4)
Si8ⁱⁱⁱ—Ca1—O13ⁱⁱⁱ	24.6 (3)	21.2 (3)	28.2 (4)
Al8ⁱⁱⁱ—Ca1—O1ⁱ	83.6 (7)	78.7 (7)	88.3 (7)
Al8ⁱⁱⁱ—Ca1—O4	123.1 (9)	111.6 (9)	134.7 (8)
Al8ⁱⁱⁱ—Ca1—O5ⁱ	91.2 (4)	88.8 (4)	93.4 (3)
Al8ⁱⁱⁱ—Ca1—O9ⁱⁱ	79.5 (4)	74.1 (4)	84.7 (4)
Al8ⁱⁱⁱ—Ca1—O13ⁱⁱⁱ	24.6 (3)	21.2 (3)	28.2 (4)
O1ⁱ—Ca1—O4	105.5 (7)	101.7 (8)	109.5 (6)
O1ⁱ—Ca1—O5ⁱ	97.7 (5)	92.2 (5)	103.0 (5)
O1ⁱ—Ca1—O9ⁱⁱ	152.5 (5)	149.1 (6)	156.9 (3)
O1ⁱ—Ca1—O13ⁱⁱⁱ	63.4 (6)	61.7 (6)	65.2 (6)
O4—Ca1—O5ⁱ	138.9 (13)	127.1 (12)	150.2 (13)
O4—Ca1—O9ⁱⁱ	99.0 (7)	96.6 (7)	100.3 (7)
O4—Ca1—O13ⁱⁱⁱ	139.3 (12)	125.5 (11)	152.9 (12)
O5ⁱ—Ca1—O9ⁱⁱ	62.8 (6)	61.4 (6)	64.4 (6)
O5ⁱ—Ca1—O13ⁱⁱⁱ	80.6 (4)	79.9 (4)	81.0 (4)
O9ⁱⁱ—Ca1—O13ⁱⁱⁱ	94.2 (5)	88.2 (5)	99.8 (4)
Ca1—Na1—Ca2^xvii	0	0	0
Ca1—Na1—Na2^xvii	0	0	0
Ca1—Na1—Si1ⁱ	0	0	0
Ca1—Na1—Al1ⁱ	0	0	0
Ca1—Na1—Al2^xii	0	0	0
Ca1—Na1—Si3^xviii	0	0	0
Ca1—Na1—Al3^xviii	0	0	0
Ca1—Na1—Al4^xiii	0	0	0
Ca1—Na1—Si5ⁱ	0	0	0
Ca1—Na1—Al5ⁱ	0	0	0
Ca1—Na1—Si6^xix	0	0	0
Ca1—Na1—Al6^xix	0	0	0
Ca1—Na1—Si7	0	0	0
Ca1—Na1—Al7	0	0	0
Ca1—Na1—Si8ⁱⁱⁱ	0	0	0
Ca1—Na1—Al8ⁱⁱⁱ	0	0	0
Ca1—Na1—O1ⁱ	0	0	0
Ca1—Na1—O4	0	0	0
Ca1—Na1—O5ⁱ	0	0	0
Ca1—Na1—O9ⁱⁱ	0	0	0
Ca1—Na1—O13ⁱⁱⁱ	0	0	0
Ca2^xvii—Na1—Na2^xvii	9.7 (5)	1.80 (17)	17.9 (2)
Ca2^xvii—Na1—Si1ⁱ	59.0 (6)	52.0 (2)	65.8 (2)
Ca2^xvii—Na1—Al1ⁱ	59.0 (6)	52.0 (2)	65.8 (2)
Ca2^xvii—Na1—Al2^xii	96.2 (5)	95.2 (6)	97.1 (4)
Ca2^xvii—Na1—Si3^xviii	152.3 (11)	145.9 (12)	158.7 (13)
Ca2^xvii—Na1—Al3^xviii	152.3 (11)	145.9 (12)	158.7 (13)
Ca2^xvii—Na1—Al4^xiii	94.8 (5)	92.5 (6)	97.0 (5)
Ca2^xvii—Na1—Si5ⁱ	52.2 (5)	49.8 (3)	55.2 (2)
Ca2^xvii—Na1—Al5ⁱ	52.2 (5)	49.8 (3)	55.2 (2)
Ca2^xvii—Na1—Si6^xix	52.3 (5)	50.8 (6)	54.3 (3)
Ca2^xvii—Na1—Al6^xix	52.3 (5)	50.8 (6)	54.3 (3)
Ca2^xvii—Na1—Si7	155.1 (11)	149.7 (13)	160.3 (13)
Ca2^xvii—Na1—Al7	155.1 (11)	149.7 (13)	160.3 (13)
Ca2^xvii—Na1—Si8ⁱⁱⁱ	53.4 (6)	47.9 (2)	59.1 (3)
Ca2^xvii—Na1—Al8ⁱⁱⁱ	53.4 (6)	47.9 (2)	59.1 (3)
Ca2^xvii—Na1—O1ⁱ	78.3 (5)	77.1 (6)	79.6 (3)
Ca2^xvii—Na1—O4	171.8 (11)	166.8 (11)	177.7 (8)
Ca2^xvii—Na1—O5ⁱ	41.4 (7)	35.7 (4)	47.3 (3)
Ca2^xvii—Na1—O9ⁱⁱ	75.9 (5)	73.6 (7)	77.7 (6)
Ca2^xvii—Na1—O13ⁱⁱⁱ	39.5 (6)	33.6 (3)	45.8 (3)
Na2^xvii—Na1—Si1ⁱ	49.48 (19)	47.6 (2)	51.20 (18)
Na2^xvii—Na1—Al1ⁱ	49.48 (19)	47.6 (2)	51.20 (18)
Na2^xvii—Na1—Al2^xii	93.3 (3)	92.0 (3)	94.3 (3)
Na2^xvii—Na1—Si3^xviii	160.3 (8)	150.5 (8)	169.7 (8)
Na2^xvii—Na1—Al3^xviii	160.3 (8)	150.5 (8)	169.7 (8)
Na2^xvii—Na1—Al4^xiii	97.5 (3)	96.7 (4)	98.8 (3)
Na2^xvii—Na1—Si5ⁱ	54.96 (18)	54.01 (18)	55.75 (17)
Na2^xvii—Na1—Al5ⁱ	54.96 (18)	54.01 (18)	55.75 (17)
Na2^xvii—Na1—Si6^xix	50.02 (16)	47.67 (18)	52.38 (17)
Na2^xvii—Na1—Al6^xix	50.02 (16)	47.67 (18)	52.38 (17)
Na2^xvii—Na1—Si7	147.4 (8)	137.5 (8)	157.5 (9)
Na2^xvii—Na1—Al7	147.4 (8)	137.5 (8)	157.5 (9)
Na2^xvii—Na1—Si8ⁱⁱⁱ	62.90 (19)	59.9 (2)	65.92 (19)
Na2^xvii—Na1—Al8ⁱⁱⁱ	62.90 (19)	59.9 (2)	65.92 (19)
Na2^xvii—Na1—O1ⁱ	77.3 (3)	76.4 (3)	78.5 (3)
Na2^xvii—Na1—O4	169.1 (10)	158.4 (11)	179.1 (9)
Na2^xvii—Na1—O5ⁱ	33.6 (3)	31.3 (3)	35.8 (4)
Na2^xvii—Na1—O9ⁱⁱ	76.9 (3)	75.3 (3)	78.9 (3)
Na2^xvii—Na1—O13ⁱⁱⁱ	47.6 (3)	46.0 (3)	49.3 (3)
Si1ⁱ—Na1—Al1ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si1ⁱ—Na1—Al2^xii	83.5 (4)	79.5 (3)	87.4 (4)
Si1ⁱ—Na1—Si3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Si1ⁱ—Na1—Al3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Si1ⁱ—Na1—Al4^xiii	105.1 (6)	100.0 (6)	109.9 (6)
Si1ⁱ—Na1—Si5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Si1ⁱ—Na1—Al5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Si1ⁱ—Na1—Si6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Si1ⁱ—Na1—Al6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Si1ⁱ—Na1—Si7	100.3 (7)	91.9 (6)	109.1 (8)
Si1ⁱ—Na1—Al7	100.3 (7)	91.9 (6)	109.1 (8)
Si1ⁱ—Na1—Si8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Si1ⁱ—Na1—Al8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Si1ⁱ—Na1—O1ⁱ	83.1 (5)	78.6 (5)	87.5 (5)
Si1ⁱ—Na1—O4	124.2 (9)	111.5 (9)	137.2 (9)
Si1ⁱ—Na1—O5ⁱ	27.4 (3)	24.6 (3)	30.2 (4)
Si1ⁱ—Na1—O9ⁱⁱ	84.9 (7)	80.0 (7)	89.7 (7)
Si1ⁱ—Na1—O13ⁱⁱⁱ	94.5 (4)	92.4 (4)	96.4 (3)
Al1ⁱ—Na1—Al2^xii	83.5 (4)	79.5 (3)	87.4 (4)
Al1ⁱ—Na1—Si3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Al1ⁱ—Na1—Al3^xviii	145.8 (6)	137.0 (6)	154.2 (5)
Al1ⁱ—Na1—Al4^xiii	105.1 (6)	100.0 (6)	109.9 (6)
Al1ⁱ—Na1—Si5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Al1ⁱ—Na1—Al5ⁱ	84.7 (3)	82.3 (3)	86.9 (3)
Al1ⁱ—Na1—Si6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Al1ⁱ—Na1—Al6^xix	56.5 (4)	53.3 (4)	59.6 (4)
Al1ⁱ—Na1—Si7	100.3 (7)	91.9 (6)	109.1 (8)
Al1ⁱ—Na1—Al7	100.3 (7)	91.9 (6)	109.1 (8)
Al1ⁱ—Na1—Si8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Al1ⁱ—Na1—Al8ⁱⁱⁱ	112.37 (15)	111.05 (17)	113.70 (16)
Al1ⁱ—Na1—O1ⁱ	83.1 (5)	78.6 (5)	87.5 (5)
Al1ⁱ—Na1—O4	124.2 (9)	111.5 (9)	137.2 (9)
Al1ⁱ—Na1—O5ⁱ	27.4 (3)	24.6 (3)	30.2 (4)
Al1ⁱ—Na1—O9ⁱⁱ	84.9 (7)	80.0 (7)	89.7 (7)
Al1ⁱ—Na1—O13ⁱⁱⁱ	94.5 (4)	92.4 (4)	96.4 (3)
Al2^xii—Na1—Si3^xviii	80.0 (4)	78.4 (4)	81.4 (4)
Al2^xii—Na1—Al3^xviii	80.0 (4)	78.4 (4)	81.4 (4)
Al2^xii—Na1—Al4^xiii	166.7 (4)	162.7 (7)	170.01 (14)
Al2^xii—Na1—Si5ⁱ	52.6 (3)	51.9 (3)	53.2 (3)
Al2^xii—Na1—Al5ⁱ	52.6 (3)	51.9 (3)	53.2 (3)
Al2^xii—Na1—Si6^xix	136.9 (4)	131.0 (5)	142.5 (4)
Al2^xii—Na1—Al6^xix	136.9 (4)	131.0 (5)	142.5 (4)
Al2^xii—Na1—Si7	94.2 (3)	92.5 (3)	95.6 (2)
Al2^xii—Na1—Al7	94.2 (3)	92.5 (3)	95.6 (2)
Al2^xii—Na1—Si8ⁱⁱⁱ	102.6 (6)	99.1 (6)	106.0 (6)
Al2^xii—Na1—Al8ⁱⁱⁱ	102.6 (6)	99.1 (6)	106.0 (6)
Al2^xii—Na1—O1ⁱ	20.8 (2)	19.2 (2)	22.3 (2)
Al2^xii—Na1—O4	88.4 (5)	86.9 (5)	90.5 (5)
Al2^xii—Na1—O5ⁱ	105.3 (5)	99.2 (5)	111.2 (5)
Al2^xii—Na1—O9ⁱⁱ	166.8 (7)	159.4 (9)	172.8 (3)
Al2^xii—Na1—O13ⁱⁱⁱ	84.0 (6)	83.7 (6)	84.4 (6)
Si3^xviii—Na1—Al3^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xviii—Na1—Al4^xiii	88.3 (3)	85.1 (3)	90.9 (3)
Si3^xviii—Na1—Si5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Si3^xviii—Na1—Al5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Si3^xviii—Na1—Si6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Si3^xviii—Na1—Al6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Si3^xviii—Na1—Si7	51.80 (18)	51.14 (19)	52.22 (17)
Si3^xviii—Na1—Al7	51.80 (18)	51.14 (19)	52.22 (17)
Si3^xviii—Na1—Si8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Si3^xviii—Na1—Al8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Si3^xviii—Na1—O1ⁱ	91.2 (6)	87.1 (6)	95.0 (6)
Si3^xviii—Na1—O4	26.5 (3)	22.4 (4)	30.2 (3)
Si3^xviii—Na1—O5ⁱ	164.6 (9)	156.8 (10)	169.9 (9)
Si3^xviii—Na1—O9ⁱⁱ	110.5 (5)	107.1 (5)	113.1 (5)
Si3^xviii—Na1—O13ⁱⁱⁱ	113.1 (9)	103.7 (8)	122.9 (10)
Al3^xviii—Na1—Al4^xiii	88.3 (3)	85.1 (3)	90.9 (3)
Al3^xviii—Na1—Si5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Al3^xviii—Na1—Al5ⁱ	107.7 (8)	101.3 (7)	114.0 (8)
Al3^xviii—Na1—Si6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Al3^xviii—Na1—Al6^xix	141.0 (5)	138.8 (5)	142.5 (6)
Al3^xviii—Na1—Si7	51.80 (18)	51.14 (19)	52.22 (17)
Al3^xviii—Na1—Al7	51.80 (18)	51.14 (19)	52.22 (17)
Al3^xviii—Na1—Si8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Al3^xviii—Na1—Al8ⁱⁱⁱ	100.4 (7)	92.5 (6)	108.9 (7)
Al3^xviii—Na1—O1ⁱ	91.2 (6)	87.1 (6)	95.0 (6)
Al3^xviii—Na1—O4	26.5 (3)	22.4 (4)	30.2 (3)
Al3^xviii—Na1—O5ⁱ	164.6 (9)	156.8 (10)	169.9 (9)
Al3^xviii—Na1—O9ⁱⁱ	110.5 (5)	107.1 (5)	113.1 (5)
Al3^xviii—Na1—O13ⁱⁱⁱ	113.1 (9)	103.7 (8)	122.9 (10)
Al4^xiii—Na1—Si5ⁱ	134.0 (5)	126.5 (6)	141.0 (4)
Al4^xiii—Na1—Al5ⁱ	134.0 (5)	126.5 (6)	141.0 (4)
Al4^xiii—Na1—Si6^xix	53.6 (3)	53.3 (3)	54.2 (3)
Al4^xiii—Na1—Al6^xix	53.6 (3)	53.3 (3)	54.2 (3)
Al4^xiii—Na1—Si7	76.8 (4)	74.4 (4)	78.6 (3)
Al4^xiii—Na1—Al7	76.8 (4)	74.4 (4)	78.6 (3)
Al4^xiii—Na1—Si8ⁱⁱⁱ	81.0 (3)	75.9 (3)	86.1 (4)
Al4^xiii—Na1—Al8ⁱⁱⁱ	81.0 (3)	75.9 (3)	86.1 (4)
Al4^xiii—Na1—O1ⁱ	163.8 (8)	153.2 (10)	173.5 (5)
Al4^xiii—Na1—O4	79.8 (5)	79.2 (4)	80.9 (4)
Al4^xiii—Na1—O5ⁱ	85.0 (6)	83.8 (6)	86.6 (6)
Al4^xiii—Na1—O9ⁱⁱ	22.4 (3)	22.0 (3)	22.7 (3)
Al4^xiii—Na1—O13ⁱⁱⁱ	102.0 (5)	94.9 (5)	109.1 (5)
Si5ⁱ—Na1—Al5ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si5ⁱ—Na1—Si6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Si5ⁱ—Na1—Al6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Si5ⁱ—Na1—Si7	145.5 (5)	144.4 (4)	147.3 (5)
Si5ⁱ—Na1—Al7	145.5 (5)	144.4 (4)	147.3 (5)
Si5ⁱ—Na1—Si8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Si5ⁱ—Na1—Al8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Si5ⁱ—Na1—O1ⁱ	31.8 (3)	30.9 (3)	32.7 (3)
Si5ⁱ—Na1—O4	130.0 (9)	122.1 (10)	136.7 (8)
Si5ⁱ—Na1—O5ⁱ	85.2 (4)	82.7 (4)	87.6 (4)
Si5ⁱ—Na1—O9ⁱⁱ	123.3 (4)	118.3 (5)	128.0 (3)
Si5ⁱ—Na1—O13ⁱⁱⁱ	32.1 (3)	31.5 (3)	32.7 (3)
Al5ⁱ—Na1—Si6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Al5ⁱ—Na1—Al6^xix	103.88 (17)	102.46 (16)	105.85 (15)
Al5ⁱ—Na1—Si7	145.5 (5)	144.4 (4)	147.3 (5)
Al5ⁱ—Na1—Al7	145.5 (5)	144.4 (4)	147.3 (5)
Al5ⁱ—Na1—Si8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Al5ⁱ—Na1—Al8ⁱⁱⁱ	54.6 (4)	51.0 (3)	58.2 (4)
Al5ⁱ—Na1—O1ⁱ	31.8 (3)	30.9 (3)	32.7 (3)
Al5ⁱ—Na1—O4	130.0 (9)	122.1 (10)	136.7 (8)
Al5ⁱ—Na1—O5ⁱ	85.2 (4)	82.7 (4)	87.6 (4)
Al5ⁱ—Na1—O9ⁱⁱ	123.3 (4)	118.3 (5)	128.0 (3)
Al5ⁱ—Na1—O13ⁱⁱⁱ	32.1 (3)	31.5 (3)	32.7 (3)
Si6^xix—Na1—Al6^xix	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xix—Na1—Si7	106.2 (7)	100.5 (7)	111.6 (8)
Si6^xix—Na1—Al7	106.2 (7)	100.5 (7)	111.6 (8)
Si6^xix—Na1—Si8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Si6^xix—Na1—Al8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Si6^xix—Na1—O1ⁱ	126.0 (4)	121.9 (4)	130.1 (3)
Si6^xix—Na1—O4	124.1 (9)	118.3 (9)	128.5 (8)
Si6^xix—Na1—O5ⁱ	31.9 (4)	31.1 (3)	32.8 (4)
Si6^xix—Na1—O9ⁱⁱ	31.3 (3)	30.6 (3)	31.9 (3)
Si6^xix—Na1—O13ⁱⁱⁱ	84.2 (3)	82.4 (3)	85.7 (3)
Al6^xix—Na1—Si7	106.2 (7)	100.5 (7)	111.6 (8)
Al6^xix—Na1—Al7	106.2 (7)	100.5 (7)	111.6 (8)
Al6^xix—Na1—Si8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Al6^xix—Na1—Al8ⁱⁱⁱ	81.7 (3)	78.8 (3)	84.3 (3)
Al6^xix—Na1—O1ⁱ	126.0 (4)	121.9 (4)	130.1 (3)
Al6^xix—Na1—O4	124.1 (9)	118.3 (9)	128.5 (8)
Al6^xix—Na1—O5ⁱ	31.9 (4)	31.1 (3)	32.8 (4)
Al6^xix—Na1—O9ⁱⁱ	31.3 (3)	30.6 (3)	31.9 (3)
Al6^xix—Na1—O13ⁱⁱⁱ	84.2 (3)	82.4 (3)	85.7 (3)
Si7—Na1—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Si7—Na1—Si8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Si7—Na1—Al8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Si7—Na1—O1ⁱ	114.5 (4)	111.8 (4)	117.2 (4)
Si7—Na1—O4	25.4 (4)	21.1 (4)	29.6 (3)
Si7—Na1—O5ⁱ	114.0 (10)	105.9 (9)	122.3 (11)
Si7—Na1—O9ⁱⁱ	89.7 (6)	85.3 (6)	93.7 (6)
Si7—Na1—O13ⁱⁱⁱ	164.6 (9)	154.7 (9)	173.7 (9)
Al7—Na1—Si8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Al7—Na1—Al8ⁱⁱⁱ	144.3 (5)	137.5 (6)	150.8 (5)
Al7—Na1—O1ⁱ	114.5 (4)	111.8 (4)	117.2 (4)
Al7—Na1—O4	25.4 (4)	21.1 (4)	29.6 (3)
Al7—Na1—O5ⁱ	114.0 (10)	105.9 (9)	122.3 (11)
Al7—Na1—O9ⁱⁱ	89.7 (6)	85.3 (6)	93.7 (6)
Al7—Na1—O13ⁱⁱⁱ	164.6 (9)	154.7 (9)	173.7 (9)
Si8ⁱⁱⁱ—Na1—Al8ⁱⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si8ⁱⁱⁱ—Na1—O1ⁱ	83.6 (7)	78.7 (7)	88.3 (7)
Si8ⁱⁱⁱ—Na1—O4	123.1 (9)	111.6 (9)	134.7 (8)
Si8ⁱⁱⁱ—Na1—O5ⁱ	91.2 (4)	88.8 (4)	93.4 (3)
Si8ⁱⁱⁱ—Na1—O9ⁱⁱ	79.5 (4)	74.1 (4)	84.7 (4)
Si8ⁱⁱⁱ—Na1—O13ⁱⁱⁱ	24.6 (3)	21.2 (3)	28.2 (4)
Al8ⁱⁱⁱ—Na1—O1ⁱ	83.6 (7)	78.7 (7)	88.3 (7)
Al8ⁱⁱⁱ—Na1—O4	123.1 (9)	111.6 (9)	134.7 (8)
Al8ⁱⁱⁱ—Na1—O5ⁱ	91.2 (4)	88.8 (4)	93.4 (3)
Al8ⁱⁱⁱ—Na1—O9ⁱⁱ	79.5 (4)	74.1 (4)	84.7 (4)
Al8ⁱⁱⁱ—Na1—O13ⁱⁱⁱ	24.6 (3)	21.2 (3)	28.2 (4)
O1ⁱ—Na1—O4	105.5 (7)	101.7 (8)	109.5 (6)
O1ⁱ—Na1—O5ⁱ	97.7 (5)	92.2 (5)	103.0 (5)
O1ⁱ—Na1—O9ⁱⁱ	152.5 (5)	149.1 (6)	156.9 (3)
O1ⁱ—Na1—O13ⁱⁱⁱ	63.4 (6)	61.7 (6)	65.2 (6)
O4—Na1—O5ⁱ	138.9 (13)	127.1 (12)	150.2 (13)
O4—Na1—O9ⁱⁱ	99.0 (7)	96.6 (7)	100.3 (7)
O4—Na1—O13ⁱⁱⁱ	139.3 (12)	125.5 (11)	152.9 (12)
O5ⁱ—Na1—O9ⁱⁱ	62.8 (6)	61.4 (6)	64.4 (6)
O5ⁱ—Na1—O13ⁱⁱⁱ	80.6 (4)	79.9 (4)	81.0 (4)
O9ⁱⁱ—Na1—O13ⁱⁱⁱ	94.2 (5)	88.2 (5)	99.8 (4)
Ca1^xx—Ca2—Na1^xx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xx—Ca2—Na2	102.6 (19)	82.3 (6)	142 (3)
Ca1^xx—Ca2—Si1^v	53.9 (5)	51.5 (5)	56.5 (5)
Ca1^xx—Ca2—Al1^v	53.9 (5)	51.5 (5)	56.5 (5)
Ca1^xx—Ca2—Si2^iv	155.2 (12)	143.8 (6)	165.6 (5)
Ca1^xx—Ca2—Al2^iv	155.2 (12)	143.8 (6)	165.6 (5)
Ca1^xx—Ca2—Al3^xxi	94.4 (5)	90.9 (3)	97.2 (5)
Ca1^xx—Ca2—Al3^xxii	97.4 (5)	92.7 (4)	101.8 (5)
Ca1^xx—Ca2—Si4^iv	151.9 (12)	137.8 (5)	166.0 (6)
Ca1^xx—Ca2—Al4^iv	151.9 (12)	137.8 (5)	166.0 (6)
Ca1^xx—Ca2—Si5^v	52.4 (4)	51.2 (4)	53.1 (4)
Ca1^xx—Ca2—Al5^v	52.4 (4)	51.2 (4)	53.1 (4)
Ca1^xx—Ca2—Si6^xii	52.1 (4)	50.6 (4)	53.5 (5)
Ca1^xx—Ca2—Al6^xii	52.1 (4)	50.6 (4)	53.5 (5)
Ca1^xx—Ca2—Al7^xiv	92.6 (5)	86.6 (4)	98.5 (4)
Ca1^xx—Ca2—Al7^xv	96.1 (6)	95.2 (4)	96.8 (8)
Ca1^xx—Ca2—Si8^vi	58.3 (4)	55.4 (4)	61.6 (5)
Ca1^xx—Ca2—Al8^vi	58.3 (4)	55.4 (4)	61.6 (5)
Ca1^xx—Ca2—O2^iv	123.7 (11)	112.0 (5)	136.0 (6)
Ca1^xx—Ca2—O5^v	39.8 (5)	37.3 (5)	42.4 (5)
Ca1^xx—Ca2—O6^vi	81.8 (5)	78.1 (6)	85.7 (6)
Ca1^xx—Ca2—O8^vii	76.7 (5)	73.2 (4)	79.9 (6)
Ca1^xx—Ca2—O11^iv	165.0 (13)	154.2 (6)	176.4 (17)
Ca1^xx—Ca2—O13^vi	41.5 (5)	37.4 (5)	45.2 (5)
Ca1^xx—Ca2—O15^viii	77.2 (5)	75.2 (5)	78.8 (6)
Na1^xx—Ca2—Na2	102.6 (19)	82.3 (6)	142 (3)
Na1^xx—Ca2—Si1^v	53.9 (5)	51.5 (5)	56.5 (5)
Na1^xx—Ca2—Al1^v	53.9 (5)	51.5 (5)	56.5 (5)
Na1^xx—Ca2—Si2^iv	155.2 (12)	143.8 (6)	165.6 (5)
Na1^xx—Ca2—Al2^iv	155.2 (12)	143.8 (6)	165.6 (5)
Na1^xx—Ca2—Al3^xxi	94.4 (5)	90.9 (3)	97.2 (5)
Na1^xx—Ca2—Al3^xxii	97.4 (5)	92.7 (4)	101.8 (5)
Na1^xx—Ca2—Si4^iv	151.9 (12)	137.8 (5)	166.0 (6)
Na1^xx—Ca2—Al4^iv	151.9 (12)	137.8 (5)	166.0 (6)
Na1^xx—Ca2—Si5^v	52.4 (4)	51.2 (4)	53.1 (4)
Na1^xx—Ca2—Al5^v	52.4 (4)	51.2 (4)	53.1 (4)
Na1^xx—Ca2—Si6^xii	52.1 (4)	50.6 (4)	53.5 (5)
Na1^xx—Ca2—Al6^xii	52.1 (4)	50.6 (4)	53.5 (5)
Na1^xx—Ca2—Al7^xiv	92.6 (5)	86.6 (4)	98.5 (4)
Na1^xx—Ca2—Al7^xv	96.1 (6)	95.2 (4)	96.8 (8)
Na1^xx—Ca2—Si8^vi	58.3 (4)	55.4 (4)	61.6 (5)
Na1^xx—Ca2—Al8^vi	58.3 (4)	55.4 (4)	61.6 (5)
Na1^xx—Ca2—O2^iv	123.7 (11)	112.0 (5)	136.0 (6)
Na1^xx—Ca2—O5^v	39.8 (5)	37.3 (5)	42.4 (5)
Na1^xx—Ca2—O6^vi	81.8 (5)	78.1 (6)	85.7 (6)
Na1^xx—Ca2—O8^vii	76.7 (5)	73.2 (4)	79.9 (6)
Na1^xx—Ca2—O11^iv	165.0 (13)	154.2 (6)	176.4 (17)
Na1^xx—Ca2—O13^vi	41.5 (5)	37.4 (5)	45.2 (5)
Na1^xx—Ca2—O15^viii	77.2 (5)	75.2 (5)	78.8 (6)
Na2—Ca2—Si1^v	51 (2)	30.2 (4)	99 (3)
Na2—Ca2—Al1^v	51 (2)	30.2 (4)	99 (3)
Na2—Ca2—Si2^iv	92 (2)	54 (3)	104.5 (12)
Na2—Ca2—Al2^iv	92 (2)	54 (3)	104.5 (12)
Na2—Ca2—Al3^xxi	64 (3)	50 (4)	71 (4)
Na2—Ca2—Al3^xxii	142 (3)	120 (3)	154 (4)
Na2—Ca2—Si4^iv	54.7 (15)	40 (3)	61.0 (13)
Na2—Ca2—Al4^iv	54.7 (15)	40 (3)	61.0 (13)
Na2—Ca2—Si5^v	103 (3)	94.3 (5)	114 (5)
Na2—Ca2—Al5^v	103 (3)	94.3 (5)	114 (5)
Na2—Ca2—Si6^xii	91 (4)	63.6 (6)	145 (4)
Na2—Ca2—Al6^xii	91 (4)	63.6 (6)	145 (4)
Na2—Ca2—Al7^xiv	28 (3)	21 (5)	46 (3)
Na2—Ca2—Al7^xv	107 (4)	92.3 (8)	126 (5)
Na2—Ca2—Si8^vi	148 (3)	134 (4)	167 (5)
Na2—Ca2—Al8^vi	148 (3)	134 (4)	167 (5)
Na2—Ca2—O2^iv	41 (3)	34.9 (4)	56 (4)
Na2—Ca2—O5^v	72 (3)	45.1 (6)	129 (4)
Na2—Ca2—O6^vi	156 (4)	128 (4)	174 (4)
Na2—Ca2—O8^vii	79 (3)	72 (4)	87 (5)
Na2—Ca2—O11^iv	70.3 (17)	43 (3)	80.6 (12)
Na2—Ca2—O13^vi	127 (3)	112.8 (5)	145 (5)
Na2—Ca2—O15^viii	101 (4)	76.7 (8)	137 (4)
Si1^v—Ca2—Al1^v	0.0 (5)	0.0 (5)	0.0 (5)
Si1^v—Ca2—Si2^iv	142.5 (8)	130.6 (3)	153.5 (3)
Si1^v—Ca2—Al2^iv	142.5 (8)	130.6 (3)	153.5 (3)
Si1^v—Ca2—Al3^xxi	80.3 (5)	71.41 (19)	89.0 (2)
Si1^v—Ca2—Al3^xxii	138.2 (7)	136.0 (5)	140.3 (9)
Si1^v—Ca2—Si4^iv	99.5 (9)	86.4 (3)	113.6 (4)
Si1^v—Ca2—Al4^iv	99.5 (9)	86.4 (3)	113.6 (4)
Si1^v—Ca2—Si5^v	81.5 (4)	75.3 (2)	86.9 (2)
Si1^v—Ca2—Al5^v	81.5 (4)	75.3 (2)	86.9 (2)
Si1^v—Ca2—Si6^xii	54.4 (5)	47.76 (18)	61.0 (2)
Si1^v—Ca2—Al6^xii	54.4 (5)	47.76 (18)	61.0 (2)
Si1^v—Ca2—Al7^xiv	48.1 (4)	41.99 (15)	54.7 (2)
Si1^v—Ca2—Al7^xv	102.2 (9)	94.9 (3)	108.9 (4)
Si1^v—Ca2—Si8^vi	112.2 (2)	109.4 (2)	114.4 (2)
Si1^v—Ca2—Al8^vi	112.2 (2)	109.4 (2)	114.4 (2)
Si1^v—Ca2—O2^iv	73.7 (8)	62.4 (2)	86.8 (4)
Si1^v—Ca2—O5^v	24.7 (4)	19.3 (3)	30.5 (3)
Si1^v—Ca2—O6^vi	132.3 (5)	130.6 (5)	134.4 (6)
Si1^v—Ca2—O8^vii	79.3 (6)	69.2 (3)	89.0 (3)
Si1^v—Ca2—O11^iv	120.7 (12)	102.0 (4)	139.1 (5)
Si1^v—Ca2—O13^vi	91.6 (5)	84.8 (3)	97.0 (3)
Si1^v—Ca2—O15^viii	81.9 (9)	71.9 (3)	91.5 (4)
Al1^v—Ca2—Si2^iv	142.5 (8)	130.6 (3)	153.5 (3)
Al1^v—Ca2—Al2^iv	142.5 (8)	130.6 (3)	153.5 (3)
Al1^v—Ca2—Al3^xxi	80.3 (5)	71.41 (19)	89.0 (2)
Al1^v—Ca2—Al3^xxii	138.2 (7)	136.0 (5)	140.3 (9)
Al1^v—Ca2—Si4^iv	99.5 (9)	86.4 (3)	113.6 (4)
Al1^v—Ca2—Al4^iv	99.5 (9)	86.4 (3)	113.6 (4)
Al1^v—Ca2—Si5^v	81.5 (4)	75.3 (2)	86.9 (2)
Al1^v—Ca2—Al5^v	81.5 (4)	75.3 (2)	86.9 (2)
Al1^v—Ca2—Si6^xii	54.4 (5)	47.76 (18)	61.0 (2)
Al1^v—Ca2—Al6^xii	54.4 (5)	47.76 (18)	61.0 (2)
Al1^v—Ca2—Al7^xiv	48.1 (4)	41.99 (15)	54.7 (2)
Al1^v—Ca2—Al7^xv	102.2 (9)	94.9 (3)	108.9 (4)
Al1^v—Ca2—Si8^vi	112.2 (2)	109.4 (2)	114.4 (2)
Al1^v—Ca2—Al8^vi	112.2 (2)	109.4 (2)	114.4 (2)
Al1^v—Ca2—O2^iv	73.7 (8)	62.4 (2)	86.8 (4)
Al1^v—Ca2—O5^v	24.7 (4)	19.3 (3)	30.5 (3)
Al1^v—Ca2—O6^vi	132.3 (5)	130.6 (5)	134.4 (6)
Al1^v—Ca2—O8^vii	79.3 (6)	69.2 (3)	89.0 (3)
Al1^v—Ca2—O11^iv	120.7 (12)	102.0 (4)	139.1 (5)
Al1^v—Ca2—O13^vi	91.6 (5)	84.8 (3)	97.0 (3)
Al1^v—Ca2—O15^viii	81.9 (9)	71.9 (3)	91.5 (4)
Si2^iv—Ca2—Al2^iv	0.0 (5)	0.0 (5)	0.0 (5)
Si2^iv—Ca2—Al3^xxi	76.0 (5)	72.5 (2)	78.2 (2)
Si2^iv—Ca2—Al3^xxii	75.5 (5)	67.10 (18)	84.6 (2)
Si2^iv—Ca2—Si4^iv	51.18 (19)	49.92 (12)	52.3 (2)
Si2^iv—Ca2—Al4^iv	51.18 (19)	49.92 (12)	52.3 (2)
Si2^iv—Ca2—Si5^v	105.7 (10)	96.3 (3)	114.3 (4)
Si2^iv—Ca2—Al5^v	105.7 (10)	96.3 (3)	114.3 (4)
Si2^iv—Ca2—Si6^xii	144.4 (8)	141.6 (2)	147.8 (13)
Si2^iv—Ca2—Al6^xii	144.4 (8)	141.6 (2)	147.8 (13)
Si2^iv—Ca2—Al7^xiv	95.7 (5)	90.9 (2)	99.3 (3)
Si2^iv—Ca2—Al7^xv	94.3 (4)	89.94 (17)	97.7 (2)
Si2^iv—Ca2—Si8^vi	102.0 (10)	87.7 (3)	117.9 (4)
Si2^iv—Ca2—Al8^vi	102.0 (10)	87.7 (3)	117.9 (4)
Si2^iv—Ca2—O2^iv	79.5 (3)	76.4 (3)	81.9 (3)
Si2^iv—Ca2—O5^v	162.3 (12)	146.1 (5)	175.1 (6)
Si2^iv—Ca2—O6^vi	84.8 (8)	73.3 (3)	97.8 (4)
Si2^iv—Ca2—O8^vii	88.0 (8)	80.9 (4)	93.9 (5)
Si2^iv—Ca2—O11^iv	25.9 (4)	19.6 (3)	31.8 (2)
Si2^iv—Ca2—O13^vi	114.3 (13)	99.3 (4)	130.2 (6)
Si2^iv—Ca2—O15^viii	115.2 (7)	109.1 (3)	120.2 (7)
Al2^iv—Ca2—Al3^xxi	76.0 (5)	72.5 (2)	78.2 (2)
Al2^iv—Ca2—Al3^xxii	75.5 (5)	67.10 (18)	84.6 (2)
Al2^iv—Ca2—Si4^iv	51.18 (19)	49.92 (12)	52.3 (2)
Al2^iv—Ca2—Al4^iv	51.18 (19)	49.92 (12)	52.3 (2)
Al2^iv—Ca2—Si5^v	105.7 (10)	96.3 (3)	114.3 (4)
Al2^iv—Ca2—Al5^v	105.7 (10)	96.3 (3)	114.3 (4)
Al2^iv—Ca2—Si6^xii	144.4 (8)	141.6 (2)	147.8 (13)
Al2^iv—Ca2—Al6^xii	144.4 (8)	141.6 (2)	147.8 (13)
Al2^iv—Ca2—Al7^xiv	95.7 (5)	90.9 (2)	99.3 (3)
Al2^iv—Ca2—Al7^xv	94.3 (4)	89.94 (17)	97.7 (2)
Al2^iv—Ca2—Si8^vi	102.0 (10)	87.7 (3)	117.9 (4)
Al2^iv—Ca2—Al8^vi	102.0 (10)	87.7 (3)	117.9 (4)
Al2^iv—Ca2—O2^iv	79.5 (3)	76.4 (3)	81.9 (3)
Al2^iv—Ca2—O5^v	162.3 (12)	146.1 (5)	175.1 (6)
Al2^iv—Ca2—O6^vi	84.8 (8)	73.3 (3)	97.8 (4)
Al2^iv—Ca2—O8^vii	88.0 (8)	80.9 (4)	93.9 (5)
Al2^iv—Ca2—O11^iv	25.9 (4)	19.6 (3)	31.8 (2)
Al2^iv—Ca2—O13^vi	114.3 (13)	99.3 (4)	130.2 (6)
Al2^iv—Ca2—O15^viii	115.2 (7)	109.1 (3)	120.2 (7)
Al3^xxi—Ca2—Al3^xxii	137.0 (11)	123.3 (4)	151.1 (4)
Al3^xxi—Ca2—Si4^iv	87.1 (4)	81.7 (2)	91.2 (3)
Al3^xxi—Ca2—Al4^iv	87.1 (4)	81.7 (2)	91.2 (3)
Al3^xxi—Ca2—Si5^v	52.9 (4)	52.11 (19)	53.8 (7)
Al3^xxi—Ca2—Al5^v	52.9 (4)	52.11 (19)	53.8 (7)
Al3^xxi—Ca2—Si6^xii	132.8 (7)	119.0 (3)	145.1 (2)
Al3^xxi—Ca2—Al6^xii	132.8 (7)	119.0 (3)	145.1 (2)
Al3^xxi—Ca2—Al7^xiv	43.9 (3)	39.45 (16)	48.00 (18)
Al3^xxi—Ca2—Al7^xv	163.0 (7)	155.6 (4)	169.6 (3)
Al3^xxi—Ca2—Si8^vi	105.2 (9)	97.4 (4)	112.2 (4)
Al3^xxi—Ca2—Al8^vi	105.2 (9)	97.4 (4)	112.2 (4)
Al3^xxi—Ca2—O2^iv	94.5 (6)	83.6 (3)	105.0 (4)
Al3^xxi—Ca2—O5^v	101.2 (7)	89.1 (3)	112.8 (3)
Al3^xxi—Ca2—O6^vi	124.5 (12)	112.0 (4)	137.2 (6)
Al3^xxi—Ca2—O8^vii	21.2 (4)	19.7 (4)	22.5 (4)
Al3^xxi—Ca2—O11^iv	77.8 (6)	76.0 (3)	79.8 (9)
Al3^xxi—Ca2—O13^vi	84.3 (8)	82.5 (4)	86.2 (13)
Al3^xxi—Ca2—O15^viii	160.1 (12)	141.4 (5)	175.6 (3)
Al3^xxii—Ca2—Si4^iv	99.1 (4)	91.95 (16)	105.04 (17)
Al3^xxii—Ca2—Al4^iv	99.1 (4)	91.95 (16)	105.04 (17)
Al3^xxii—Ca2—Si5^v	105.5 (9)	93.8 (3)	117.7 (4)
Al3^xxii—Ca2—Al5^v	105.5 (9)	93.8 (3)	117.7 (4)
Al3^xxii—Ca2—Si6^xii	84.4 (5)	79.4 (2)	88.8 (3)
Al3^xxii—Ca2—Al6^xii	84.4 (5)	79.4 (2)	88.8 (3)
Al3^xxii—Ca2—Al7^xiv	167.4 (5)	165.0 (4)	169.6 (3)
Al3^xxii—Ca2—Al7^xv	45.9 (3)	42.22 (16)	49.33 (18)
Al3^xxii—Ca2—Si8^vi	50.4 (4)	44.54 (13)	56.80 (19)
Al3^xxii—Ca2—Al8^vi	50.4 (4)	44.54 (13)	56.80 (19)
Al3^xxii—Ca2—O2^iv	111.2 (6)	105.4 (3)	114.9 (3)
Al3^xxii—Ca2—O5^v	113.7 (7)	108.6 (4)	117.4 (4)
Al3^xxii—Ca2—O6^vi	21.3 (3)	18.85 (16)	23.9 (2)
Al3^xxii—Ca2—O8^vii	127.5 (13)	111.7 (5)	143.8 (5)
Al3^xxii—Ca2—O11^iv	89.3 (7)	77.3 (3)	100.9 (3)
Al3^xxii—Ca2—O13^vi	77.7 (8)	67.0 (3)	89.3 (4)
Al3^xxii—Ca2—O15^viii	60.6 (6)	53.2 (3)	67.6 (3)
Si4^iv—Ca2—Al4^iv	0.0 (5)	0.0 (5)	0.0 (5)
Si4^iv—Ca2—Si5^v	138.6 (8)	133.6 (3)	141.7 (13)
Si4^iv—Ca2—Al5^v	138.6 (8)	133.6 (3)	141.7 (13)
Si4^iv—Ca2—Si6^xii	106.9 (10)	96.5 (3)	116.3 (4)
Si4^iv—Ca2—Al6^xii	106.9 (10)	96.5 (3)	116.3 (4)
Si4^iv—Ca2—Al7^xiv	70.0 (5)	61.66 (17)	78.4 (2)
Si4^iv—Ca2—Al7^xv	79.4 (5)	77.1 (3)	81.3 (8)
Si4^iv—Ca2—Si8^vi	146.8 (8)	131.7 (3)	161.4 (2)
Si4^iv—Ca2—Al8^vi	146.8 (8)	131.7 (3)	161.4 (2)
Si4^iv—Ca2—O2^iv	28.4 (3)	25.75 (18)	30.5 (3)
Si4^iv—Ca2—O5^v	112.2 (13)	96.6 (4)	128.5 (6)
Si4^iv—Ca2—O6^vi	118.8 (6)	108.2 (3)	128.5 (3)
Si4^iv—Ca2—O8^vii	107.7 (7)	101.2 (4)	112.4 (9)
Si4^iv—Ca2—O11^iv	25.5 (4)	19.5 (3)	30.5 (2)
Si4^iv—Ca2—O13^vi	161.3 (12)	148.7 (5)	169.7 (14)
Si4^iv—Ca2—O15^viii	90.7 (9)	84.1 (5)	95.9 (8)
Al4^iv—Ca2—Si5^v	138.6 (8)	133.6 (3)	141.7 (13)
Al4^iv—Ca2—Al5^v	138.6 (8)	133.6 (3)	141.7 (13)
Al4^iv—Ca2—Si6^xii	106.9 (10)	96.5 (3)	116.3 (4)
Al4^iv—Ca2—Al6^xii	106.9 (10)	96.5 (3)	116.3 (4)
Al4^iv—Ca2—Al7^xiv	70.0 (5)	61.66 (17)	78.4 (2)
Al4^iv—Ca2—Al7^xv	79.4 (5)	77.1 (3)	81.3 (8)
Al4^iv—Ca2—Si8^vi	146.8 (8)	131.7 (3)	161.4 (2)
Al4^iv—Ca2—Al8^vi	146.8 (8)	131.7 (3)	161.4 (2)
Al4^iv—Ca2—O2^iv	28.4 (3)	25.75 (18)	30.5 (3)
Al4^iv—Ca2—O5^v	112.2 (13)	96.6 (4)	128.5 (6)
Al4^iv—Ca2—O6^vi	118.8 (6)	108.2 (3)	128.5 (3)
Al4^iv—Ca2—O8^vii	107.7 (7)	101.2 (4)	112.4 (9)
Al4^iv—Ca2—O11^iv	25.5 (4)	19.5 (3)	30.5 (2)
Al4^iv—Ca2—O13^vi	161.3 (12)	148.7 (5)	169.7 (14)
Al4^iv—Ca2—O15^viii	90.7 (9)	84.1 (5)	95.9 (8)
Si5^v—Ca2—Al5^v	0.0 (5)	0.0 (5)	0.0 (5)
Si5^v—Ca2—Si6^xii	103.8 (3)	101.1 (2)	106.6 (3)
Si5^v—Ca2—Al6^xii	103.8 (3)	101.1 (2)	106.6 (3)
Si5^v—Ca2—Al7^xiv	82.7 (5)	77.0 (2)	87.5 (2)
Si5^v—Ca2—Al7^xv	137.5 (7)	127.7 (3)	145.7 (4)
Si5^v—Ca2—Si8^vi	56.9 (5)	51.4 (2)	62.4 (2)
Si5^v—Ca2—Al8^vi	56.9 (5)	51.4 (2)	62.4 (2)
Si5^v—Ca2—O2^iv	142.3 (9)	127.0 (3)	157.0 (4)
Si5^v—Ca2—O5^v	84.2 (4)	79.8 (3)	87.2 (4)
Si5^v—Ca2—O6^vi	84.5 (9)	75.3 (3)	94.1 (4)
Si5^v—Ca2—O8^vii	31.8 (5)	30.4 (5)	33.4 (6)
Si5^v—Ca2—O11^iv	121.9 (12)	113.2 (5)	127.3 (12)
Si5^v—Ca2—O13^vi	32.0 (4)	31.2 (3)	32.8 (6)
Si5^v—Ca2—O15^viii	125.3 (5)	119.9 (4)	130.4 (5)
Al5^v—Ca2—Si6^xii	103.8 (3)	101.1 (2)	106.6 (3)
Al5^v—Ca2—Al6^xii	103.8 (3)	101.1 (2)	106.6 (3)
Al5^v—Ca2—Al7^xiv	82.7 (5)	77.0 (2)	87.5 (2)
Al5^v—Ca2—Al7^xv	137.5 (7)	127.7 (3)	145.7 (4)
Al5^v—Ca2—Si8^vi	56.9 (5)	51.4 (2)	62.4 (2)
Al5^v—Ca2—Al8^vi	56.9 (5)	51.4 (2)	62.4 (2)
Al5^v—Ca2—O2^iv	142.3 (9)	127.0 (3)	157.0 (4)
Al5^v—Ca2—O5^v	84.2 (4)	79.8 (3)	87.2 (4)
Al5^v—Ca2—O6^vi	84.5 (9)	75.3 (3)	94.1 (4)
Al5^v—Ca2—O8^vii	31.8 (5)	30.4 (5)	33.4 (6)
Al5^v—Ca2—O11^iv	121.9 (12)	113.2 (5)	127.3 (12)
Al5^v—Ca2—O13^vi	32.0 (4)	31.2 (3)	32.8 (6)
Al5^v—Ca2—O15^viii	125.3 (5)	119.9 (4)	130.4 (5)
Si6^xii—Ca2—Al6^xii	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xii—Ca2—Al7^xiv	99.7 (9)	86.5 (3)	113.7 (4)
Si6^xii—Ca2—Al7^xv	52.5 (5)	51.78 (17)	53.4 (7)
Si6^xii—Ca2—Si8^vi	84.8 (4)	80.8 (2)	87.7 (2)
Si6^xii—Ca2—Al8^vi	84.8 (4)	80.8 (2)	87.7 (2)
Si6^xii—Ca2—O2^iv	82.6 (10)	73.3 (3)	91.7 (4)
Si6^xii—Ca2—O5^v	31.8 (4)	29.9 (3)	33.5 (4)
Si6^xii—Ca2—O6^vi	86.1 (6)	81.1 (3)	90.4 (4)
Si6^xii—Ca2—O8^vii	123.0 (6)	112.5 (3)	131.6 (4)
Si6^xii—Ca2—O11^iv	128.4 (12)	115.7 (5)	137.7 (10)
Si6^xii—Ca2—O13^vi	85.7 (5)	83.5 (3)	88.0 (7)
Si6^xii—Ca2—O15^viii	30.6 (4)	28.1 (2)	32.7 (3)
Al6^xii—Ca2—Al7^xiv	99.7 (9)	86.5 (3)	113.7 (4)
Al6^xii—Ca2—Al7^xv	52.5 (5)	51.78 (17)	53.4 (7)
Al6^xii—Ca2—Si8^vi	84.8 (4)	80.8 (2)	87.7 (2)
Al6^xii—Ca2—Al8^vi	84.8 (4)	80.8 (2)	87.7 (2)
Al6^xii—Ca2—O2^iv	82.6 (10)	73.3 (3)	91.7 (4)
Al6^xii—Ca2—O5^v	31.8 (4)	29.9 (3)	33.5 (4)
Al6^xii—Ca2—O6^vi	86.1 (6)	81.1 (3)	90.4 (4)
Al6^xii—Ca2—O8^vii	123.0 (6)	112.5 (3)	131.6 (4)
Al6^xii—Ca2—O11^iv	128.4 (12)	115.7 (5)	137.7 (10)
Al6^xii—Ca2—O13^vi	85.7 (5)	83.5 (3)	88.0 (7)
Al6^xii—Ca2—O15^viii	30.6 (4)	28.1 (2)	32.7 (3)
Al7^xiv—Ca2—Al7^xv	130.2 (10)	117.6 (4)	142.8 (4)
Al7^xiv—Ca2—Si8^vi	138.6 (6)	136.86 (18)	140.5 (9)
Al7^xiv—Ca2—Al8^vi	138.6 (6)	136.86 (18)	140.5 (9)
Al7^xiv—Ca2—O2^iv	60.0 (5)	50.2 (2)	71.0 (3)
Al7^xiv—Ca2—O5^v	72.7 (7)	61.1 (3)	85.2 (4)
Al7^xiv—Ca2—O6^vi	165.9 (9)	159.6 (5)	170.0 (7)
Al7^xiv—Ca2—O8^vii	57.5 (6)	50.5 (3)	63.9 (3)
Al7^xiv—Ca2—O11^iv	79.8 (7)	68.9 (3)	89.6 (3)
Al7^xiv—Ca2—O13^vi	111.6 (7)	104.3 (3)	117.5 (3)
Al7^xiv—Ca2—O15^viii	119.6 (13)	102.8 (5)	136.8 (6)
Al7^xv—Ca2—Si8^vi	84.3 (5)	77.3 (2)	91.3 (3)
Al7^xv—Ca2—Al8^vi	84.3 (5)	77.3 (2)	91.3 (3)
Al7^xv—Ca2—O2^iv	74.4 (7)	72.1 (3)	75.8 (10)
Al7^xv—Ca2—O5^v	83.6 (8)	81.2 (3)	85.3 (10)
Al7^xv—Ca2—O6^vi	62.2 (5)	57.1 (2)	67.0 (3)
Al7^xv—Ca2—O8^vii	164.2 (11)	153.3 (5)	175.2 (5)
Al7^xv—Ca2—O11^iv	88.5 (7)	86.8 (3)	91.6 (10)
Al7^xv—Ca2—O13^vi	106.2 (7)	96.5 (3)	115.2 (4)
Al7^xv—Ca2—O15^viii	22.0 (3)	19.2 (2)	24.7 (2)
Si8^vi—Ca2—Al8^vi	0.0 (5)	0.0 (5)	0.0 (5)
Si8^vi—Ca2—O2^iv	157.2 (9)	149.8 (3)	161.2 (14)
Si8^vi—Ca2—O5^v	94.4 (5)	91.1 (4)	96.8 (4)
Si8^vi—Ca2—O6^vi	29.3 (3)	25.82 (16)	33.0 (2)
Si8^vi—Ca2—O8^vii	85.9 (9)	77.2 (5)	93.9 (5)
Si8^vi—Ca2—O11^iv	126.7 (13)	106.0 (4)	148.6 (5)
Si8^vi—Ca2—O13^vi	27.3 (4)	22.44 (19)	32.6 (3)
Si8^vi—Ca2—O15^viii	83.9 (7)	75.8 (4)	91.3 (4)
Al8^vi—Ca2—O2^iv	157.2 (9)	149.8 (3)	161.2 (14)
Al8^vi—Ca2—O5^v	94.4 (5)	91.1 (4)	96.8 (4)
Al8^vi—Ca2—O6^vi	29.3 (3)	25.82 (16)	33.0 (2)
Al8^vi—Ca2—O8^vii	85.9 (9)	77.2 (5)	93.9 (5)
Al8^vi—Ca2—O11^iv	126.7 (13)	106.0 (4)	148.6 (5)
Al8^vi—Ca2—O13^vi	27.3 (4)	22.44 (19)	32.6 (3)
Al8^vi—Ca2—O15^viii	83.9 (7)	75.8 (4)	91.3 (4)
O2^iv—Ca2—O5^v	83.9 (11)	70.7 (4)	98.5 (6)
O2^iv—Ca2—O6^vi	132.0 (8)	124.2 (3)	137.6 (4)
O2^iv—Ca2—O8^vii	113.7 (10)	99.6 (4)	127.2 (6)
O2^iv—Ca2—O11^iv	53.7 (6)	44.8 (4)	60.9 (4)
O2^iv—Ca2—O13^vi	162.6 (12)	147.1 (4)	174.5 (11)
O2^iv—Ca2—O15^viii	76.2 (10)	68.9 (5)	82.2 (5)
O5^v—Ca2—O6^vi	108.9 (7)	103.6 (5)	112.9 (5)
O5^v—Ca2—O8^vii	94.2 (7)	83.3 (4)	104.0 (4)
O5^v—Ca2—O11^iv	137.2 (16)	114.8 (5)	158.8 (7)
O5^v—Ca2—O13^vi	81.0 (5)	78.6 (4)	82.4 (5)
O5^v—Ca2—O15^viii	61.8 (8)	56.7 (4)	66.1 (6)
O6^vi—Ca2—O8^vii	109.5 (13)	96.1 (5)	122.8 (6)
O6^vi—Ca2—O11^iv	104.5 (9)	88.0 (4)	121.3 (4)
O6^vi—Ca2—O13^vi	56.6 (7)	48.2 (3)	65.6 (4)
O6^vi—Ca2—O15^viii	70.8 (7)	62.7 (4)	78.2 (4)
O8^vii—Ca2—O11^iv	95.6 (9)	92.0 (5)	98.3 (12)
O8^vii—Ca2—O13^vi	63.3 (8)	60.5 (5)	66.2 (11)
O8^vii—Ca2—O15^viii	149.7 (8)	140.1 (5)	158.7 (5)
O11^iv—Ca2—O13^vi	138.5 (17)	118.9 (6)	155.7 (7)
O11^iv—Ca2—O15^viii	105.4 (10)	99.9 (7)	111.0 (14)
O13^vi—Ca2—O15^viii	98.0 (7)	90.2 (5)	104.7 (6)
Ca1^xx—Na2—Na1^xx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xx—Na2—Ca2	67.9 (12)	36 (2)	81.2 (6)
Ca1^xx—Na2—Si1^v	55.8 (4)	52.3 (4)	59.3 (4)
Ca1^xx—Na2—Al1^v	55.8 (4)	52.3 (4)	59.3 (4)
Ca1^xx—Na2—Al2^iv	139.0 (5)	135.5 (4)	142.4 (5)
Ca1^xx—Na2—Al3^xxi	95.7 (3)	94.9 (3)	96.6 (3)
Ca1^xx—Na2—Si4^iv	166.3 (4)	163.8 (5)	168.7 (4)
Ca1^xx—Na2—Al4^iv	166.3 (4)	163.8 (5)	168.7 (4)
Ca1^xx—Na2—Si5^v	50.4 (4)	49.7 (4)	51.1 (4)
Ca1^xx—Na2—Al5^v	50.4 (4)	49.7 (4)	51.1 (4)
Ca1^xx—Na2—Si6^xii	51.2 (4)	49.6 (3)	52.9 (4)
Ca1^xx—Na2—Al6^xii	51.2 (4)	49.6 (3)	52.9 (4)
Ca1^xx—Na2—Al7^xiv	100.4 (3)	96.9 (3)	104.0 (3)
Ca1^xx—Na2—O2^iv	136.1 (5)	131.9 (5)	140.5 (5)
Ca1^xx—Na2—O5^v	36.7 (5)	34.9 (5)	38.4 (6)
Ca1^xx—Na2—O8^vii	74.7 (5)	72.9 (5)	76.7 (5)
Ca1^xx—Na2—O11^iv	159.1 (5)	156.4 (5)	161.7 (5)
Ca1^xx—Na2—O15^viii	74.1 (4)	73.0 (4)	75.2 (4)
Na1^xx—Na2—Ca2	67.9 (12)	36 (2)	81.2 (6)
Na1^xx—Na2—Si1^v	55.8 (4)	52.3 (4)	59.3 (4)
Na1^xx—Na2—Al1^v	55.8 (4)	52.3 (4)	59.3 (4)
Na1^xx—Na2—Al2^iv	139.0 (5)	135.5 (4)	142.4 (5)
Na1^xx—Na2—Al3^xxi	95.7 (3)	94.9 (3)	96.6 (3)
Na1^xx—Na2—Si4^iv	166.3 (4)	163.8 (5)	168.7 (4)
Na1^xx—Na2—Al4^iv	166.3 (4)	163.8 (5)	168.7 (4)
Na1^xx—Na2—Si5^v	50.4 (4)	49.7 (4)	51.1 (4)
Na1^xx—Na2—Al5^v	50.4 (4)	49.7 (4)	51.1 (4)
Na1^xx—Na2—Si6^xii	51.2 (4)	49.6 (3)	52.9 (4)
Na1^xx—Na2—Al6^xii	51.2 (4)	49.6 (3)	52.9 (4)
Na1^xx—Na2—Al7^xiv	100.4 (3)	96.9 (3)	104.0 (3)
Na1^xx—Na2—O2^iv	136.1 (5)	131.9 (5)	140.5 (5)
Na1^xx—Na2—O5^v	36.7 (5)	34.9 (5)	38.4 (6)
Na1^xx—Na2—O8^vii	74.7 (5)	72.9 (5)	76.7 (5)
Na1^xx—Na2—O11^iv	159.1 (5)	156.4 (5)	161.7 (5)
Na1^xx—Na2—O15^viii	74.1 (4)	73.0 (4)	75.2 (4)
Ca2—Na2—Si1^v	121 (2)	77 (3)	138.3 (6)
Ca2—Na2—Al1^v	121 (2)	77 (3)	138.3 (6)
Ca2—Na2—Al2^iv	77 (2)	58.7 (4)	123 (4)
Ca2—Na2—Al3^xxi	105 (4)	95.5 (6)	127 (4)
Ca2—Na2—Si4^iv	114.8 (16)	104.3 (4)	137 (3)
Ca2—Na2—Al4^iv	114.8 (16)	104.3 (4)	137 (3)
Ca2—Na2—Si5^v	66 (3)	62 (5)	74 (4)
Ca2—Na2—Al5^v	66 (3)	62 (5)	74 (4)
Ca2—Na2—Si6^xii	77 (4)	33 (4)	95.0 (9)
Ca2—Na2—Al6^xii	77 (4)	33 (4)	95.0 (9)
Ca2—Na2—Al7^xiv	147 (3)	131 (3)	157 (5)
Ca2—Na2—O2^iv	130 (3)	119 (4)	137 (4)
Ca2—Na2—O5^v	94 (3)	48 (4)	111.7 (7)
Ca2—Na2—O8^vii	85 (3)	77.2 (7)	103 (4)
Ca2—Na2—O11^iv	93.1 (18)	77.5 (5)	133 (3)
Ca2—Na2—O15^viii	64 (4)	40 (4)	74.9 (19)
Si1^v—Na2—Al1^v	0.0 (5)	0.0 (5)	0.0 (5)
Si1^v—Na2—Al2^iv	159.9 (3)	159.7 (3)	160.1 (4)
Si1^v—Na2—Al3^xxi	90.0 (2)	89.0 (2)	90.9 (2)
Si1^v—Na2—Si4^iv	116.7 (3)	116.3 (3)	117.0 (3)
Si1^v—Na2—Al4^iv	116.7 (3)	116.3 (3)	117.0 (3)
Si1^v—Na2—Si5^v	85.9 (2)	85.4 (2)	86.4 (2)
Si1^v—Na2—Al5^v	85.9 (2)	85.4 (2)	86.4 (2)
Si1^v—Na2—Si6^xii	59.85 (19)	58.81 (19)	60.9 (2)
Si1^v—Na2—Al6^xii	59.85 (19)	58.81 (19)	60.9 (2)
Si1^v—Na2—Al7^xiv	56.10 (19)	55.68 (18)	56.50 (18)
Si1^v—Na2—O2^iv	87.4 (3)	86.6 (3)	88.1 (3)
Si1^v—Na2—O5^v	30.8 (3)	30.0 (3)	31.7 (3)
Si1^v—Na2—O8^vii	89.7 (3)	88.9 (3)	90.4 (3)
Si1^v—Na2—O11^iv	144.8 (4)	144.1 (5)	145.5 (5)
Si1^v—Na2—O15^viii	90.5 (3)	87.8 (3)	93.3 (4)
Al1^v—Na2—Al2^iv	159.9 (3)	159.7 (3)	160.1 (4)
Al1^v—Na2—Al3^xxi	90.0 (2)	89.0 (2)	90.9 (2)
Al1^v—Na2—Si4^iv	116.7 (3)	116.3 (3)	117.0 (3)
Al1^v—Na2—Al4^iv	116.7 (3)	116.3 (3)	117.0 (3)
Al1^v—Na2—Si5^v	85.9 (2)	85.4 (2)	86.4 (2)
Al1^v—Na2—Al5^v	85.9 (2)	85.4 (2)	86.4 (2)
Al1^v—Na2—Si6^xii	59.85 (19)	58.81 (19)	60.9 (2)
Al1^v—Na2—Al6^xii	59.85 (19)	58.81 (19)	60.9 (2)
Al1^v—Na2—Al7^xiv	56.10 (19)	55.68 (18)	56.50 (18)
Al1^v—Na2—O2^iv	87.4 (3)	86.6 (3)	88.1 (3)
Al1^v—Na2—O5^v	30.8 (3)	30.0 (3)	31.7 (3)
Al1^v—Na2—O8^vii	89.7 (3)	88.9 (3)	90.4 (3)
Al1^v—Na2—O11^iv	144.8 (4)	144.1 (5)	145.5 (5)
Al1^v—Na2—O15^viii	90.5 (3)	87.8 (3)	93.3 (4)
Al2^iv—Na2—Al3^xxi	76.23 (19)	75.4 (2)	77.1 (2)
Al2^iv—Na2—Si4^iv	51.82 (16)	51.62 (15)	51.99 (15)
Al2^iv—Na2—Al4^iv	51.82 (16)	51.62 (15)	51.99 (15)
Al2^iv—Na2—Si5^v	97.0 (2)	96.2 (2)	97.9 (2)
Al2^iv—Na2—Al5^v	97.0 (2)	96.2 (2)	97.9 (2)
Al2^iv—Na2—Si6^xii	138.0 (3)	136.7 (3)	139.3 (3)
Al2^iv—Na2—Al6^xii	138.0 (3)	136.7 (3)	139.3 (3)
Al2^iv—Na2—Al7^xiv	103.9 (3)	103.8 (3)	104.1 (3)
Al2^iv—Na2—O2^iv	83.4 (3)	82.4 (3)	84.2 (3)
Al2^iv—Na2—O5^v	169.1 (5)	167.9 (4)	170.3 (5)
Al2^iv—Na2—O8^vii	83.9 (3)	82.5 (3)	85.4 (3)
Al2^iv—Na2—O11^iv	20.7 (2)	19.6 (2)	21.8 (2)
Al2^iv—Na2—O15^viii	106.2 (3)	103.4 (3)	109.0 (3)
Al3^xxi—Na2—Si4^iv	95.5 (3)	94.1 (2)	96.9 (3)
Al3^xxi—Na2—Al4^iv	95.5 (3)	94.1 (2)	96.9 (3)
Al3^xxi—Na2—Si5^v	53.46 (17)	53.26 (18)	53.65 (18)
Al3^xxi—Na2—Al5^v	53.46 (17)	53.26 (18)	53.65 (18)
Al3^xxi—Na2—Si6^xii	143.3 (2)	142.6 (2)	143.9 (2)
Al3^xxi—Na2—Al6^xii	143.3 (2)	142.6 (2)	143.9 (2)
Al3^xxi—Na2—Al7^xiv	49.9 (2)	49.66 (19)	50.06 (19)
Al3^xxi—Na2—O2^iv	108.5 (4)	104.7 (4)	112.4 (4)
Al3^xxi—Na2—O5^v	112.3 (3)	110.6 (3)	114.0 (3)
Al3^xxi—Na2—O8^vii	25.3 (3)	23.8 (3)	26.7 (3)
Al3^xxi—Na2—O11^iv	83.0 (3)	82.1 (3)	84.0 (3)
Al3^xxi—Na2—O15^viii	167.2 (4)	165.1 (4)	169.6 (4)
Si4^iv—Na2—Al4^iv	0.0 (5)	0.0 (5)	0.0 (5)
Si4^iv—Na2—Si5^v	143.1 (3)	141.4 (3)	144.9 (3)
Si4^iv—Na2—Al5^v	143.1 (3)	141.4 (3)	144.9 (3)
Si4^iv—Na2—Si6^xii	115.8 (2)	115.4 (2)	116.2 (2)
Si4^iv—Na2—Al6^xii	115.8 (2)	115.4 (2)	116.2 (2)
Si4^iv—Na2—Al7^xiv	81.2 (2)	79.7 (2)	82.7 (2)
Si4^iv—Na2—O2^iv	31.6 (2)	30.8 (2)	32.5 (3)
Si4^iv—Na2—O5^v	130.8 (4)	129.1 (4)	132.7 (4)
Si4^iv—Na2—O8^vii	117.9 (5)	115.4 (5)	120.4 (5)
Si4^iv—Na2—O11^iv	31.2 (3)	29.8 (2)	32.5 (2)
Si4^iv—Na2—O15^viii	95.6 (3)	94.6 (3)	96.6 (3)
Al4^iv—Na2—Si5^v	143.1 (3)	141.4 (3)	144.9 (3)
Al4^iv—Na2—Al5^v	143.1 (3)	141.4 (3)	144.9 (3)
Al4^iv—Na2—Si6^xii	115.8 (2)	115.4 (2)	116.2 (2)
Al4^iv—Na2—Al6^xii	115.8 (2)	115.4 (2)	116.2 (2)
Al4^iv—Na2—Al7^xiv	81.2 (2)	79.7 (2)	82.7 (2)
Al4^iv—Na2—O2^iv	31.6 (2)	30.8 (2)	32.5 (3)
Al4^iv—Na2—O5^v	130.8 (4)	129.1 (4)	132.7 (4)
Al4^iv—Na2—O8^vii	117.9 (5)	115.4 (5)	120.4 (5)
Al4^iv—Na2—O11^iv	31.2 (3)	29.8 (2)	32.5 (2)
Al4^iv—Na2—O15^viii	95.6 (3)	94.6 (3)	96.6 (3)
Si5^v—Na2—Al5^v	0.0 (5)	0.0 (5)	0.0 (5)
Si5^v—Na2—Si6^xii	100.6 (3)	98.6 (2)	102.5 (3)
Si5^v—Na2—Al6^xii	100.6 (3)	98.6 (2)	102.5 (3)
Si5^v—Na2—Al7^xiv	89.7 (2)	88.9 (2)	90.6 (2)
Si5^v—Na2—O2^iv	160.7 (4)	157.3 (4)	164.1 (4)
Si5^v—Na2—O5^v	83.7 (4)	83.1 (4)	84.3 (4)
Si5^v—Na2—O8^vii	28.3 (4)	26.7 (4)	29.9 (4)
Si5^v—Na2—O11^iv	115.9 (3)	115.7 (3)	116.2 (3)
Si5^v—Na2—O15^viii	113.9 (4)	111.7 (4)	116.2 (4)
Al5^v—Na2—Si6^xii	100.6 (3)	98.6 (2)	102.5 (3)
Al5^v—Na2—Al6^xii	100.6 (3)	98.6 (2)	102.5 (3)
Al5^v—Na2—Al7^xiv	89.7 (2)	88.9 (2)	90.6 (2)
Al5^v—Na2—O2^iv	160.7 (4)	157.3 (4)	164.1 (4)
Al5^v—Na2—O5^v	83.7 (4)	83.1 (4)	84.3 (4)
Al5^v—Na2—O8^vii	28.3 (4)	26.7 (4)	29.9 (4)
Al5^v—Na2—O11^iv	115.9 (3)	115.7 (3)	116.2 (3)
Al5^v—Na2—O15^viii	113.9 (4)	111.7 (4)	116.2 (4)
Si6^xii—Na2—Al6^xii	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xii—Na2—Al7^xiv	113.9 (3)	112.5 (2)	115.3 (2)
Si6^xii—Na2—O2^iv	91.6 (4)	89.6 (4)	93.6 (3)
Si6^xii—Na2—O5^v	32.1 (3)	30.4 (3)	33.9 (3)
Si6^xii—Na2—O8^vii	125.8 (4)	123.2 (4)	128.4 (4)
Si6^xii—Na2—O11^iv	133.6 (4)	132.0 (4)	135.2 (4)
Si6^xii—Na2—O15^viii	31.9 (2)	30.1 (2)	33.7 (3)
Al6^xii—Na2—Al7^xiv	113.9 (3)	112.5 (2)	115.3 (2)
Al6^xii—Na2—O2^iv	91.6 (4)	89.6 (4)	93.6 (3)
Al6^xii—Na2—O5^v	32.1 (3)	30.4 (3)	33.9 (3)
Al6^xii—Na2—O8^vii	125.8 (4)	123.2 (4)	128.4 (4)
Al6^xii—Na2—O11^iv	133.6 (4)	132.0 (4)	135.2 (4)
Al6^xii—Na2—O15^viii	31.9 (2)	30.1 (2)	33.7 (3)
Al7^xiv—Na2—O2^iv	71.6 (3)	68.1 (3)	75.2 (3)
Al7^xiv—Na2—O5^v	86.9 (4)	85.6 (4)	88.1 (4)
Al7^xiv—Na2—O8^vii	68.8 (3)	66.8 (3)	70.7 (3)
Al7^xiv—Na2—O11^iv	94.7 (4)	93.9 (4)	95.5 (4)
Al7^xiv—Na2—O15^viii	138.4 (4)	136.3 (4)	140.5 (4)
O2^iv—Na2—O5^v	99.5 (5)	96.9 (5)	102.3 (5)
O2^iv—Na2—O8^vii	133.8 (6)	129.8 (6)	137.7 (6)
O2^iv—Na2—O11^iv	62.7 (4)	60.6 (4)	64.8 (4)
O2^iv—Na2—O15^viii	84.2 (4)	81.3 (4)	87.1 (4)
O5^v—Na2—O8^vii	101.1 (4)	100.5 (5)	101.6 (4)
O5^v—Na2—O11^iv	160.3 (5)	159.7 (5)	160.8 (5)
O5^v—Na2—O15^viii	63.9 (4)	60.5 (4)	67.5 (4)
O8^vii—Na2—O11^iv	97.7 (4)	96.6 (4)	98.8 (4)
O8^vii—Na2—O15^viii	142.0 (5)	138.7 (5)	145.5 (5)
O11^iv—Na2—O15^viii	103.7 (4)	100.7 (4)	106.5 (4)
Ca1^xxiii—Si1—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Si1—Ca2^xxiv	67.1 (3)	61.7 (3)	73.0 (3)
Ca1^xxiii—Si1—Na2^xxiv	74.7 (3)	73.0 (3)	76.5 (4)
Ca1^xxiii—Si1—Al1	0	0	0
Ca1^xxiii—Si1—O5	44.7 (5)	42.4 (5)	47.0 (4)
Ca1^xxiii—Si1—O12	60.9 (5)	58.0 (5)	63.7 (5)
Ca1^xxiii—Si1—O14	119.7 (7)	117.2 (6)	122.3 (6)
Ca1^xxiii—Si1—O16	127.5 (6)	126.5 (6)	128.5 (6)
Na1^xxiii—Si1—Ca2^xxiv	67.1 (3)	61.7 (3)	73.0 (3)
Na1^xxiii—Si1—Na2^xxiv	74.7 (3)	73.0 (3)	76.5 (4)
Na1^xxiii—Si1—Al1	0	0	0
Na1^xxiii—Si1—O5	44.7 (5)	42.4 (5)	47.0 (4)
Na1^xxiii—Si1—O12	60.9 (5)	58.0 (5)	63.7 (5)
Na1^xxiii—Si1—O14	119.7 (7)	117.2 (6)	122.3 (6)
Na1^xxiii—Si1—O16	127.5 (6)	126.5 (6)	128.5 (6)
Ca2^xxiv—Si1—Na2^xxiv	7.7 (4)	3.6 (2)	11.6 (2)
Ca2^xxiv—Si1—Al1	0	0	0
Ca2^xxiv—Si1—O5	40.6 (6)	35.5 (5)	46.0 (5)
Ca2^xxiv—Si1—O12	115.0 (7)	111.8 (5)	118.4 (5)
Ca2^xxiv—Si1—O14	65.0 (6)	57.6 (5)	72.2 (4)
Ca2^xxiv—Si1—O16	133.0 (6)	131.5 (4)	134.2 (4)
Na2^xxiv—Si1—Al1	0	0	0
Na2^xxiv—Si1—O5	46.7 (5)	43.9 (5)	49.5 (5)
Na2^xxiv—Si1—O12	120.2 (6)	119.1 (6)	121.2 (6)
Na2^xxiv—Si1—O14	58.5 (5)	54.0 (5)	62.9 (5)
Na2^xxiv—Si1—O16	129.7 (4)	128.2 (4)	131.2 (3)
Al1—Si1—O5	0	0	0
Al1—Si1—O12	0	0	0
Al1—Si1—O14	0	0	0
Al1—Si1—O16	0	0	0
O5—Si1—O12	105.6 (7)	105.0 (7)	106.1 (8)
O5—Si1—O14	105.2 (7)	103.5 (7)	106.8 (6)
O5—Si1—O16	113.2 (8)	112.6 (8)	113.7 (8)
O12—Si1—O14	111.7 (7)	111.2 (7)	112.1 (7)
O12—Si1—O16	109.2 (6)	109.1 (5)	109.4 (6)
O14—Si1—O16	111.8 (7)	110.0 (7)	113.6 (6)
Ca1^xxiii—Al1—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Al1—Ca2^xxiv	67.1 (3)	61.7 (3)	73.0 (3)
Ca1^xxiii—Al1—Na2^xxiv	74.7 (3)	73.0 (3)	76.5 (4)
Ca1^xxiii—Al1—Si1	0	0	0
Ca1^xxiii—Al1—Al3	110.7 (4)	107.2 (4)	114.1 (4)
Ca1^xxiii—Al1—Al4^xi	74.7 (3)	71.9 (3)	77.4 (2)
Ca1^xxiii—Al1—Al6^xxv	57.7 (3)	57.1 (3)	58.1 (3)
Ca1^xxiii—Al1—Al7^xxvi	123.5 (5)	122.3 (5)	124.8 (5)
Ca1^xxiii—Al1—O5	44.7 (5)	42.4 (5)	47.0 (4)
Ca1^xxiii—Al1—O12	60.9 (5)	58.0 (5)	63.7 (5)
Ca1^xxiii—Al1—O14	119.7 (7)	117.2 (6)	122.3 (6)
Ca1^xxiii—Al1—O16	127.5 (6)	126.5 (6)	128.5 (6)
Na1^xxiii—Al1—Ca2^xxiv	67.1 (3)	61.7 (3)	73.0 (3)
Na1^xxiii—Al1—Na2^xxiv	74.7 (3)	73.0 (3)	76.5 (4)
Na1^xxiii—Al1—Si1	0	0	0
Na1^xxiii—Al1—Al3	110.7 (4)	107.2 (4)	114.1 (4)
Na1^xxiii—Al1—Al4^xi	74.7 (3)	71.9 (3)	77.4 (2)
Na1^xxiii—Al1—Al6^xxv	57.7 (3)	57.1 (3)	58.1 (3)
Na1^xxiii—Al1—Al7^xxvi	123.5 (5)	122.3 (5)	124.8 (5)
Na1^xxiii—Al1—O5	44.7 (5)	42.4 (5)	47.0 (4)
Na1^xxiii—Al1—O12	60.9 (5)	58.0 (5)	63.7 (5)
Na1^xxiii—Al1—O14	119.7 (7)	117.2 (6)	122.3 (6)
Na1^xxiii—Al1—O16	127.5 (6)	126.5 (6)	128.5 (6)
Ca2^xxiv—Al1—Na2^xxiv	7.7 (4)	3.6 (2)	11.6 (2)
Ca2^xxiv—Al1—Si1	0	0	0
Ca2^xxiv—Al1—Al3	149.0 (5)	148.3 (8)	149.9 (8)
Ca2^xxiv—Al1—Al4^xi	121.8 (6)	119.6 (3)	124.0 (3)
Ca2^xxiv—Al1—Al6^xxv	55.5 (4)	52.8 (2)	58.3 (2)
Ca2^xxiv—Al1—Al7^xxvi	75.0 (4)	71.0 (2)	78.9 (2)
Ca2^xxiv—Al1—O5	40.6 (6)	35.5 (5)	46.0 (5)
Ca2^xxiv—Al1—O12	115.0 (7)	111.8 (5)	118.4 (5)
Ca2^xxiv—Al1—O14	65.0 (6)	57.6 (5)	72.2 (4)
Ca2^xxiv—Al1—O16	133.0 (6)	131.5 (4)	134.2 (4)
Na2^xxiv—Al1—Si1	0	0	0
Na2^xxiv—Al1—Al3	148.8 (2)	147.3 (3)	150.3 (2)
Na2^xxiv—Al1—Al4^xi	125.3 (3)	123.7 (3)	127.0 (3)
Na2^xxiv—Al1—Al6^xxv	59.6 (2)	58.0 (2)	61.3 (2)
Na2^xxiv—Al1—Al7^xxvi	68.8 (2)	67.0 (2)	70.5 (2)
Na2^xxiv—Al1—O5	46.7 (5)	43.9 (5)	49.5 (5)
Na2^xxiv—Al1—O12	120.2 (6)	119.1 (6)	121.2 (6)
Na2^xxiv—Al1—O14	58.5 (5)	54.0 (5)	62.9 (5)
Na2^xxiv—Al1—O16	129.7 (4)	128.2 (4)	131.2 (3)
Si1—Al1—Al3	0	0	0
Si1—Al1—Al4^xi	0	0	0
Si1—Al1—Al6^xxv	0	0	0
Si1—Al1—Al7^xxvi	0	0	0
Si1—Al1—O5	0	0	0
Si1—Al1—O12	0	0	0
Si1—Al1—O14	0	0	0
Si1—Al1—O16	0	0	0
Al3—Al1—Al4^xi	84.73 (16)	84.08 (16)	85.39 (17)
Al3—Al1—Al6^xxv	96.3 (2)	95.3 (2)	97.4 (2)
Al3—Al1—Al7^xxvi	122.9 (3)	119.1 (3)	126.8 (3)
Al3—Al1—O5	114.9 (6)	111.4 (6)	118.5 (6)
Al3—Al1—O12	86.8 (4)	85.7 (4)	87.9 (4)
Al3—Al1—O14	129.2 (6)	123.5 (5)	134.8 (5)
Al3—Al1—O16	23.6 (3)	21.7 (3)	25.6 (3)
Al4^xi—Al1—Al6^xxv	129.4 (3)	127.3 (3)	131.5 (3)
Al4^xi—Al1—Al7^xxvi	92.98 (19)	91.96 (19)	94.08 (19)
Al4^xi—Al1—O5	119.3 (5)	118.8 (5)	119.7 (5)
Al4^xi—Al1—O12	14.4 (4)	13.8 (5)	14.9 (4)
Al4^xi—Al1—O14	102.2 (4)	101.2 (4)	103.1 (4)
Al4^xi—Al1—O16	104.8 (4)	104.4 (4)	105.3 (4)
Al6^xxv—Al1—Al7^xxvi	125.8 (2)	124.7 (2)	127.0 (2)
Al6^xxv—Al1—O5	20.6 (5)	17.7 (5)	23.6 (6)
Al6^xxv—Al1—O12	115.1 (5)	112.6 (5)	117.6 (6)
Al6^xxv—Al1—O14	114.8 (5)	112.3 (5)	117.3 (4)
Al6^xxv—Al1—O16	92.6 (5)	90.1 (5)	95.0 (5)
Al7^xxvi—Al1—O5	115.4 (5)	113.7 (5)	117.2 (5)
Al7^xxvi—Al1—O12	103.8 (5)	102.3 (5)	105.3 (5)
Al7^xxvi—Al1—O14	11.0 (4)	8.0 (4)	14.2 (4)
Al7^xxvi—Al1—O16	109.0 (5)	107.7 (6)	110.3 (5)
O5—Al1—O12	105.6 (7)	105.0 (7)	106.1 (8)
O5—Al1—O14	105.2 (7)	103.5 (7)	106.8 (6)
O5—Al1—O16	113.2 (8)	112.6 (8)	113.7 (8)
O12—Al1—O14	111.7 (7)	111.2 (7)	112.1 (7)
O12—Al1—O16	109.2 (6)	109.1 (5)	109.4 (6)
O14—Al1—O16	111.8 (7)	110.0 (7)	113.6 (6)
Ca2^xxvii—Si2—Al2	0	0	0
Ca2^xxvii—Si2—O1^ix	116.3 (6)	114.0 (4)	118.2 (4)
Ca2^xxvii—Si2—O3ⁱ	127.9 (6)	122.0 (4)	133.4 (4)
Ca2^xxvii—Si2—O10ⁱⁱ	67.6 (7)	57.0 (4)	77.1 (4)
Ca2^xxvii—Si2—O11	38.7 (7)	29.8 (4)	48.7 (4)
Al2—Si2—O1^ix	0	0	0
Al2—Si2—O3ⁱ	0	0	0
Al2—Si2—O10ⁱⁱ	0	0	0
Al2—Si2—O11	0	0	0
O1^ix—Si2—O3ⁱ	111.3 (6)	110.0 (6)	112.6 (6)
O1^ix—Si2—O10ⁱⁱ	112.8 (6)	111.6 (6)	113.9 (6)
O1^ix—Si2—O11	107.5 (6)	106.2 (7)	108.8 (8)
O3ⁱ—Si2—O10ⁱⁱ	110.8 (6)	110.4 (6)	111.1 (7)
O3ⁱ—Si2—O11	108.5 (6)	107.1 (6)	110.0 (6)
O10ⁱⁱ—Si2—O11	105.7 (6)	104.4 (5)	106.9 (5)
Ca1^xxvi—Al2—Na1^xxvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxvi—Al2—Ca2^xxvii	85.5 (3)	83.8 (2)	87.7 (3)
Ca1^xxvi—Al2—Na2^xxvii	88.2 (3)	86.4 (3)	90.1 (3)
Ca1^xxvi—Al2—Si2	0	0	0
Ca1^xxvi—Al2—Al4	73.6 (5)	70.0 (4)	77.1 (5)
Ca1^xxvi—Al2—Al5^ix	56.2 (3)	54.7 (3)	57.8 (3)
Ca1^xxvi—Al2—Al6ⁱⁱ	119.6 (4)	115.9 (4)	123.4 (4)
Ca1^xxvi—Al2—Al8ⁱ	126.96 (14)	126.53 (15)	127.34 (16)
Ca1^xxvi—Al2—O1^ix	31.8 (4)	30.1 (4)	33.6 (5)
Ca1^xxvi—Al2—O3ⁱ	137.0 (4)	135.8 (4)	137.9 (4)
Ca1^xxvi—Al2—O10ⁱⁱ	106.7 (5)	105.4 (6)	108.0 (5)
Ca1^xxvi—Al2—O11	80.0 (5)	75.8 (5)	84.0 (5)
Na1^xxvi—Al2—Ca2^xxvii	85.5 (3)	83.8 (2)	87.7 (3)
Na1^xxvi—Al2—Na2^xxvii	88.2 (3)	86.4 (3)	90.1 (3)
Na1^xxvi—Al2—Si2	0	0	0
Na1^xxvi—Al2—Al4	73.6 (5)	70.0 (4)	77.1 (5)
Na1^xxvi—Al2—Al5^ix	56.2 (3)	54.7 (3)	57.8 (3)
Na1^xxvi—Al2—Al6ⁱⁱ	119.6 (4)	115.9 (4)	123.4 (4)
Na1^xxvi—Al2—Al8ⁱ	126.96 (14)	126.53 (15)	127.34 (16)
Na1^xxvi—Al2—O1^ix	31.8 (4)	30.1 (4)	33.6 (5)
Na1^xxvi—Al2—O3ⁱ	137.0 (4)	135.8 (4)	137.9 (4)
Na1^xxvi—Al2—O10ⁱⁱ	106.7 (5)	105.4 (6)	108.0 (5)
Na1^xxvi—Al2—O11	80.0 (5)	75.8 (5)	84.0 (5)
Ca2^xxvii—Al2—Na2^xxvii	10.7 (6)	2.6 (2)	19.8 (3)
Ca2^xxvii—Al2—Si2	0	0	0
Ca2^xxvii—Al2—Al4	64.1 (6)	54.7 (2)	74.6 (3)
Ca2^xxvii—Al2—Al5^ix	139.9 (5)	136.3 (3)	142.6 (5)
Ca2^xxvii—Al2—Al6ⁱⁱ	91.4 (6)	83.0 (3)	99.0 (2)
Ca2^xxvii—Al2—Al8ⁱ	139.1 (5)	131.8 (2)	145.8 (2)
Ca2^xxvii—Al2—O1^ix	116.3 (6)	114.0 (4)	118.2 (4)
Ca2^xxvii—Al2—O3ⁱ	127.9 (6)	122.0 (4)	133.4 (4)
Ca2^xxvii—Al2—O10ⁱⁱ	67.6 (7)	57.0 (4)	77.1 (4)
Ca2^xxvii—Al2—O11	38.7 (7)	29.8 (4)	48.7 (4)
Na2^xxvii—Al2—Si2	0	0	0
Na2^xxvii—Al2—Al4	55.21 (17)	53.10 (15)	57.35 (15)
Na2^xxvii—Al2—Al5^ix	144.4 (3)	142.5 (3)	146.1 (3)
Na2^xxvii—Al2—Al6ⁱⁱ	98.81 (16)	97.35 (16)	100.23 (15)
Na2^xxvii—Al2—Al8ⁱ	131.0 (2)	128.8 (2)	133.1 (2)
Na2^xxvii—Al2—O1^ix	119.9 (5)	119.6 (4)	120.2 (4)
Na2^xxvii—Al2—O3ⁱ	120.2 (4)	119.3 (4)	121.3 (5)
Na2^xxvii—Al2—O10ⁱⁱ	76.3 (4)	73.8 (3)	78.7 (4)
Na2^xxvii—Al2—O11	29.4 (3)	28.1 (3)	30.8 (3)
Si2—Al2—Al4	0	0	0
Si2—Al2—Al5^ix	0	0	0
Si2—Al2—Al6ⁱⁱ	0	0	0
Si2—Al2—Al8ⁱ	0	0	0
Si2—Al2—O1^ix	0	0	0
Si2—Al2—O3ⁱ	0	0	0
Si2—Al2—O10ⁱⁱ	0	0	0
Si2—Al2—O11	0	0	0
Al4—Al2—Al5^ix	107.4 (2)	106.7 (3)	108.1 (3)
Al4—Al2—Al6ⁱⁱ	152.16 (16)	151.71 (14)	152.58 (14)
Al4—Al2—Al8ⁱ	98.8 (2)	96.9 (2)	100.8 (2)
Al4—Al2—O1^ix	92.6 (4)	91.9 (5)	93.2 (5)
Al4—Al2—O3ⁱ	95.8 (4)	94.7 (4)	97.0 (4)
Al4—Al2—O10ⁱⁱ	131.5 (4)	131.0 (4)	131.9 (4)
Al4—Al2—O11	25.8 (3)	25.0 (3)	26.6 (3)
Al5^ix—Al2—Al6ⁱⁱ	99.9 (3)	99.3 (4)	100.5 (4)
Al5^ix—Al2—Al8ⁱ	78.34 (17)	77.08 (17)	79.57 (17)
Al5^ix—Al2—O1^ix	24.5 (4)	22.9 (4)	26.0 (4)
Al5^ix—Al2—O3ⁱ	90.0 (4)	87.3 (4)	92.8 (4)
Al5^ix—Al2—O10ⁱⁱ	112.2 (5)	112.1 (5)	112.4 (5)
Al5^ix—Al2—O11	128.0 (4)	126.3 (5)	129.6 (5)
Al6ⁱⁱ—Al2—Al8ⁱ	91.7 (2)	89.24 (18)	94.08 (19)
Al6ⁱⁱ—Al2—O1^ix	111.1 (5)	110.2 (5)	111.9 (5)
Al6ⁱⁱ—Al2—O3ⁱ	89.3 (4)	86.8 (3)	91.7 (3)
Al6ⁱⁱ—Al2—O10ⁱⁱ	25.5 (4)	23.7 (4)	27.3 (4)
Al6ⁱⁱ—Al2—O11	127.4 (3)	127.2 (4)	127.6 (4)
Al8ⁱ—Al2—O1^ix	99.7 (4)	99.2 (4)	100.3 (4)
Al8ⁱ—Al2—O3ⁱ	11.7 (4)	9.8 (4)	13.7 (4)
Al8ⁱ—Al2—O10ⁱⁱ	115.5 (5)	114.6 (6)	116.3 (6)
Al8ⁱ—Al2—O11	115.6 (5)	112.4 (5)	118.8 (5)
O1^ix—Al2—O3ⁱ	111.3 (6)	110.0 (6)	112.6 (6)
O1^ix—Al2—O10ⁱⁱ	112.8 (6)	111.6 (6)	113.9 (6)
O1^ix—Al2—O11	107.5 (6)	106.2 (7)	108.8 (8)
O3ⁱ—Al2—O10ⁱⁱ	110.8 (6)	110.4 (6)	111.1 (7)
O3ⁱ—Al2—O11	108.5 (6)	107.1 (6)	110.0 (6)
O10ⁱⁱ—Al2—O11	105.7 (6)	104.4 (5)	106.9 (5)
Ca1^x—Si3—Na1^x	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^x—Si3—Al3	0	0	0
Ca1^x—Si3—O4^x	38.2 (5)	31.2 (5)	45.6 (6)
Ca1^x—Si3—O6^xi	119.1 (5)	115.9 (5)	122.5 (5)
Ca1^x—Si3—O8^xi	123.8 (4)	122.1 (5)	126.3 (4)
Ca1^x—Si3—O16	64.7 (6)	54.8 (7)	74.4 (6)
Na1^x—Si3—Al3	0	0	0
Na1^x—Si3—O4^x	38.2 (5)	31.2 (5)	45.6 (6)
Na1^x—Si3—O6^xi	119.1 (5)	115.9 (5)	122.5 (5)
Na1^x—Si3—O8^xi	123.8 (4)	122.1 (5)	126.3 (4)
Na1^x—Si3—O16	64.7 (6)	54.8 (7)	74.4 (6)
Al3—Si3—O4^x	0	0	0
Al3—Si3—O6^xi	0	0	0
Al3—Si3—O8^xi	0	0	0
Al3—Si3—O16	0	0	0
O4^x—Si3—O6^xi	107.4 (5)	106.5 (5)	108.3 (5)
O4^x—Si3—O8^xi	108.4 (5)	105.8 (5)	110.9 (5)
O4^x—Si3—O16	102.8 (6)	100.4 (6)	105.2 (6)
O6^xi—Si3—O8^xi	112.9 (5)	112.3 (5)	113.6 (5)
O6^xi—Si3—O16	113.1 (6)	112.6 (6)	113.6 (6)
O8^xi—Si3—O16	111.5 (6)	111.2 (6)	111.7 (6)
Ca1^x—Al3—Na1^x	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^x—Al3—Ca2^xxviii	91.5 (3)	87.9 (4)	94.6 (3)
Ca1^x—Al3—Ca2^xxix	81.4 (3)	77.9 (3)	85.3 (3)
Ca1^x—Al3—Na2^xxviii	86.5 (4)	84.9 (4)	88.1 (4)
Ca1^x—Al3—Al1	87.6 (5)	81.0 (5)	93.9 (4)
Ca1^x—Al3—Si3	0	0	0
Ca1^x—Al3—Al5^xxiii	146.1 (3)	144.5 (3)	147.4 (3)
Ca1^x—Al3—Al7^x	64.8 (5)	58.1 (4)	71.9 (5)
Ca1^x—Al3—Al8^xi	134.1 (3)	130.6 (3)	137.7 (3)
Ca1^x—Al3—O4^x	38.2 (5)	31.2 (5)	45.6 (6)
Ca1^x—Al3—O6^xi	119.1 (5)	115.9 (5)	122.5 (5)
Ca1^x—Al3—O8^xi	123.8 (4)	122.1 (5)	126.3 (4)
Ca1^x—Al3—O16	64.7 (6)	54.8 (7)	74.4 (6)
Na1^x—Al3—Ca2^xxviii	91.5 (3)	87.9 (4)	94.6 (3)
Na1^x—Al3—Ca2^xxix	81.4 (3)	77.9 (3)	85.3 (3)
Na1^x—Al3—Na2^xxviii	86.5 (4)	84.9 (4)	88.1 (4)
Na1^x—Al3—Al1	87.6 (5)	81.0 (5)	93.9 (4)
Na1^x—Al3—Si3	0	0	0
Na1^x—Al3—Al5^xxiii	146.1 (3)	144.5 (3)	147.4 (3)
Na1^x—Al3—Al7^x	64.8 (5)	58.1 (4)	71.9 (5)
Na1^x—Al3—Al8^xi	134.1 (3)	130.6 (3)	137.7 (3)
Na1^x—Al3—O4^x	38.2 (5)	31.2 (5)	45.6 (6)
Na1^x—Al3—O6^xi	119.1 (5)	115.9 (5)	122.5 (5)
Na1^x—Al3—O8^xi	123.8 (4)	122.1 (5)	126.3 (4)
Na1^x—Al3—O16	64.7 (6)	54.8 (7)	74.4 (6)
Ca2^xxviii—Al3—Ca2^xxix	137.2 (6)	130.1 (3)	143.8 (3)
Ca2^xxviii—Al3—Na2^xxviii	10.6 (6)	2.64 (18)	19.0 (2)
Ca2^xxviii—Al3—Al1	110.0 (6)	101.2 (3)	119.2 (2)
Ca2^xxviii—Al3—Si3	0	0	0
Ca2^xxviii—Al3—Al5^xxiii	55.6 (4)	52.47 (18)	59.1 (2)
Ca2^xxviii—Al3—Al7^x	77.5 (6)	67.9 (2)	86.7 (3)
Ca2^xxviii—Al3—Al8^xi	128.6 (2)	126.47 (19)	130.55 (19)
Ca2^xxviii—Al3—O4^x	80.2 (7)	73.4 (4)	87.1 (4)
Ca2^xxviii—Al3—O6^xi	139.3 (5)	136.2 (5)	141.9 (5)
Ca2^xxviii—Al3—O8^xi	32.9 (5)	31.1 (4)	34.7 (3)
Ca2^xxviii—Al3—O16	103.1 (6)	97.8 (4)	108.8 (4)
Ca2^xxix—Al3—Na2^xxviii	127.4 (6)	124.4 (3)	130.8 (3)
Ca2^xxix—Al3—Al1	111.7 (5)	107.6 (3)	115.4 (2)
Ca2^xxix—Al3—Si3	0	0	0
Ca2^xxix—Al3—Al5^xxiii	126.29 (17)	125.19 (18)	127.42 (17)
Ca2^xxix—Al3—Al7^x	61.3 (6)	57.62 (19)	65.4 (2)
Ca2^xxix—Al3—Al8^xi	55.3 (4)	53.3 (3)	57.3 (3)
Ca2^xxix—Al3—O4^x	68.3 (6)	65.2 (3)	71.7 (4)
Ca2^xxix—Al3—O6^xi	40.7 (6)	38.6 (4)	42.6 (4)
Ca2^xxix—Al3—O8^xi	136.5 (5)	135.7 (4)	137.6 (4)
Ca2^xxix—Al3—O16	111.4 (6)	110.4 (5)	112.4 (7)
Na2^xxviii—Al3—Al1	118.6 (2)	117.71 (19)	119.56 (19)
Na2^xxviii—Al3—Si3	0	0	0
Na2^xxviii—Al3—Al5^xxiii	62.2 (2)	61.6 (2)	62.8 (2)
Na2^xxviii—Al3—Al7^x	67.19 (19)	66.50 (19)	67.89 (19)
Na2^xxviii—Al3—Al8^xi	129.4 (2)	128.36 (18)	130.31 (19)
Na2^xxviii—Al3—O4^x	70.7 (4)	69.8 (4)	71.6 (4)
Na2^xxviii—Al3—O6^xi	137.3 (5)	136.5 (5)	138.0 (5)
Na2^xxviii—Al3—O8^xi	39.6 (3)	37.3 (3)	41.9 (3)
Na2^xxviii—Al3—O16	108.6 (4)	107.7 (4)	109.5 (4)
Al1—Al3—Si3	0	0	0
Al1—Al3—Al5^xxiii	96.9 (3)	94.7 (3)	99.1 (3)
Al1—Al3—Al7^x	151.9 (2)	150.7 (2)	153.2 (2)
Al1—Al3—Al8^xi	95.4 (2)	94.5 (2)	96.3 (2)
Al1—Al3—O4^x	125.8 (4)	125.1 (4)	126.6 (4)
Al1—Al3—O6^xi	97.4 (5)	95.9 (5)	98.9 (5)
Al1—Al3—O8^xi	104.6 (4)	100.6 (4)	108.6 (4)
Al1—Al3—O16	23.9 (5)	21.5 (4)	26.4 (5)
Si3—Al3—Al5^xxiii	0	0	0
Si3—Al3—Al7^x	0	0	0
Si3—Al3—Al8^xi	0	0	0
Si3—Al3—O4^x	0	0	0
Si3—Al3—O6^xi	0	0	0
Si3—Al3—O8^xi	0	0	0
Si3—Al3—O16	0	0	0
Al5^xxiii—Al3—Al7^x	108.9 (3)	106.5 (3)	111.2 (3)
Al5^xxiii—Al3—Al8^xi	78.43 (15)	76.86 (14)	79.93 (15)
Al5^xxiii—Al3—O4^x	127.8 (5)	126.6 (5)	128.9 (5)
Al5^xxiii—Al3—O6^xi	93.2 (5)	92.6 (5)	93.7 (5)
Al5^xxiii—Al3—O8^xi	22.9 (3)	21.4 (3)	24.5 (3)
Al5^xxiii—Al3—O16	112.3 (5)	110.4 (5)	114.2 (6)
Al7^x—Al3—Al8^xi	100.35 (18)	99.77 (18)	100.96 (18)
Al7^x—Al3—O4^x	26.7 (3)	25.5 (3)	28.0 (3)
Al7^x—Al3—O6^xi	92.2 (4)	91.2 (4)	93.2 (4)
Al7^x—Al3—O8^xi	95.7 (4)	91.5 (4)	99.8 (4)
Al7^x—Al3—O16	129.4 (5)	125.9 (5)	133.0 (5)
Al8^xi—Al3—O4^x	119.7 (3)	118.6 (3)	120.9 (3)
Al8^xi—Al3—O6^xi	15.2 (4)	14.3 (4)	16.1 (5)
Al8^xi—Al3—O8^xi	99.2 (3)	98.9 (4)	99.5 (3)
Al8^xi—Al3—O16	115.3 (5)	114.3 (5)	116.3 (5)
O4^x—Al3—O6^xi	107.4 (5)	106.5 (5)	108.3 (5)
O4^x—Al3—O8^xi	108.4 (5)	105.8 (5)	110.9 (5)
O4^x—Al3—O16	102.8 (6)	100.4 (6)	105.2 (6)
O6^xi—Al3—O8^xi	112.9 (5)	112.3 (5)	113.6 (5)
O6^xi—Al3—O16	113.1 (6)	112.6 (6)	113.6 (6)
O8^xi—Al3—O16	111.5 (6)	111.2 (6)	111.7 (6)
Ca2^xxvii—Si4—Na2^xxvii	10.6 (5)	2.5 (2)	18.9 (2)
Ca2^xxvii—Si4—Al4	0	0	0
Ca2^xxvii—Si4—O2	65.6 (7)	53.0 (4)	77.9 (4)
Ca2^xxvii—Si4—O9^ix	126.6 (5)	125.4 (3)	127.9 (8)
Ca2^xxvii—Si4—O11	39.0 (7)	28.6 (4)	50.0 (4)
Ca2^xxvii—Si4—O12^ix	119.3 (6)	113.6 (5)	125.2 (5)
Na2^xxvii—Si4—Al4	0	0	0
Na2^xxvii—Si4—O2	57.4 (4)	53.4 (3)	61.6 (4)
Na2^xxvii—Si4—O9^ix	122.3 (3)	121.5 (3)	123.2 (4)
Na2^xxvii—Si4—O11	46.8 (3)	44.0 (3)	49.7 (3)
Na2^xxvii—Si4—O12^ix	126.9 (5)	126.1 (5)	127.7 (5)
Al4—Si4—O2	0	0	0
Al4—Si4—O9^ix	0	0	0
Al4—Si4—O11	0	0	0
Al4—Si4—O12^ix	0	0	0
O2—Si4—O9^ix	112.8 (6)	112.2 (6)	113.5 (6)
O2—Si4—O11	104.2 (6)	102.8 (5)	105.6 (5)
O2—Si4—O12^ix	112.5 (6)	111.9 (7)	113.2 (7)
O9^ix—Si4—O11	108.6 (6)	107.0 (5)	110.1 (5)
O9^ix—Si4—O12^ix	109.6 (5)	109.0 (5)	110.3 (5)
O11—Si4—O12^ix	108.8 (5)	108.3 (5)	109.4 (5)
Ca1^xxx—Al4—Na1^xxx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxx—Al4—Ca2^xxvii	91.5 (3)	89.4 (3)	93.9 (3)
Ca1^xxx—Al4—Na2^xxvii	87.9 (2)	86.6 (2)	89.0 (2)
Ca1^xxx—Al4—Al1^ix	128.8 (2)	127.4 (2)	130.4 (2)
Ca1^xxx—Al4—Al2	76.7 (5)	70.9 (5)	82.2 (5)
Ca1^xxx—Al4—Si4	0	0	0
Ca1^xxx—Al4—Al6^xxxi	55.9 (3)	54.1 (3)	57.7 (3)
Ca1^xxx—Al4—Al8	110.7 (4)	105.2 (4)	116.3 (4)
Ca1^xxx—Al4—O2	103.8 (5)	101.0 (5)	106.6 (5)
Ca1^xxx—Al4—O9^ix	35.7 (4)	34.0 (3)	37.6 (4)
Ca1^xxx—Al4—O11	78.3 (5)	75.0 (5)	81.5 (6)
Ca1^xxx—Al4—O12^ix	139.2 (5)	138.0 (5)	140.3 (5)
Na1^xxx—Al4—Ca2^xxvii	91.5 (3)	89.4 (3)	93.9 (3)
Na1^xxx—Al4—Na2^xxvii	87.9 (2)	86.6 (2)	89.0 (2)
Na1^xxx—Al4—Al1^ix	128.8 (2)	127.4 (2)	130.4 (2)
Na1^xxx—Al4—Al2	76.7 (5)	70.9 (5)	82.2 (5)
Na1^xxx—Al4—Si4	0	0	0
Na1^xxx—Al4—Al6^xxxi	55.9 (3)	54.1 (3)	57.7 (3)
Na1^xxx—Al4—Al8	110.7 (4)	105.2 (4)	116.3 (4)
Na1^xxx—Al4—O2	103.8 (5)	101.0 (5)	106.6 (5)
Na1^xxx—Al4—O9^ix	35.7 (4)	34.0 (3)	37.6 (4)
Na1^xxx—Al4—O11	78.3 (5)	75.0 (5)	81.5 (6)
Na1^xxx—Al4—O12^ix	139.2 (5)	138.0 (5)	140.3 (5)
Ca2^xxvii—Al4—Na2^xxvii	10.6 (5)	2.5 (2)	18.9 (2)
Ca2^xxvii—Al4—Al1^ix	133.5 (5)	127.7 (2)	139.3 (2)
Ca2^xxvii—Al4—Al2	64.7 (6)	54.58 (19)	75.4 (2)
Ca2^xxvii—Al4—Si4	0	0	0
Ca2^xxvii—Al4—Al6^xxxi	146.1 (5)	142.87 (19)	148.3 (6)
Ca2^xxvii—Al4—Al8	88.0 (6)	78.5 (3)	97.0 (2)
Ca2^xxvii—Al4—O2	65.6 (7)	53.0 (4)	77.9 (4)
Ca2^xxvii—Al4—O9^ix	126.6 (5)	125.4 (3)	127.9 (8)
Ca2^xxvii—Al4—O11	39.0 (7)	28.6 (4)	50.0 (4)
Ca2^xxvii—Al4—O12^ix	119.3 (6)	113.6 (5)	125.2 (5)
Na2^xxvii—Al4—Al1^ix	140.9 (3)	139.9 (3)	141.9 (3)
Na2^xxvii—Al4—Al2	72.97 (18)	71.00 (16)	74.93 (17)
Na2^xxvii—Al4—Si4	0	0	0
Na2^xxvii—Al4—Al6^xxxi	140.6 (2)	140.1 (2)	141.3 (2)
Na2^xxvii—Al4—Al8	80.50 (18)	78.91 (18)	82.11 (17)
Na2^xxvii—Al4—O2	57.4 (4)	53.4 (3)	61.6 (4)
Na2^xxvii—Al4—O9^ix	122.3 (3)	121.5 (3)	123.2 (4)
Na2^xxvii—Al4—O11	46.8 (3)	44.0 (3)	49.7 (3)
Na2^xxvii—Al4—O12^ix	126.9 (5)	126.1 (5)	127.7 (5)
Al1^ix—Al4—Al2	100.4 (2)	99.4 (3)	101.4 (3)
Al1^ix—Al4—Si4	0	0	0
Al1^ix—Al4—Al6^xxxi	78.30 (17)	76.76 (17)	79.77 (17)
Al1^ix—Al4—Al8	95.1 (2)	93.9 (3)	96.3 (3)
Al1^ix—Al4—O2	114.7 (4)	113.9 (4)	115.4 (4)
Al1^ix—Al4—O9^ix	96.4 (3)	94.7 (3)	98.1 (3)
Al1^ix—Al4—O11	120.2 (4)	119.1 (4)	121.3 (4)
Al1^ix—Al4—O12^ix	14.5 (4)	13.4 (4)	15.6 (4)
Al2—Al4—Si4	0	0	0
Al2—Al4—Al6^xxxi	108.2 (2)	106.1 (2)	110.2 (2)
Al2—Al4—Al8	152.3 (2)	150.9 (2)	153.7 (2)
Al2—Al4—O2	130.2 (4)	127.5 (4)	132.9 (4)
Al2—Al4—O9^ix	96.1 (4)	93.2 (4)	99.0 (4)
Al2—Al4—O11	26.2 (3)	25.0 (3)	27.5 (3)
Al2—Al4—O12^ix	92.8 (4)	91.6 (4)	94.0 (4)
Si4—Al4—Al6^xxxi	0	0	0
Si4—Al4—Al8	0	0	0
Si4—Al4—O2	0	0	0
Si4—Al4—O9^ix	0	0	0
Si4—Al4—O11	0	0	0
Si4—Al4—O12^ix	0	0	0
Al6^xxxi—Al4—Al8	97.3 (3)	94.87 (17)	99.81 (17)
Al6^xxxi—Al4—O2	112.5 (5)	110.9 (5)	114.2 (4)
Al6^xxxi—Al4—O9^ix	20.3 (3)	19.7 (3)	20.8 (3)
Al6^xxxi—Al4—O11	126.0 (5)	125.3 (4)	126.6 (5)
Al6^xxxi—Al4—O12^ix	92.4 (5)	91.8 (5)	92.9 (4)
Al8—Al4—O2	23.5 (3)	21.5 (3)	25.6 (3)
Al8—Al4—O9^ix	104.8 (4)	101.2 (3)	108.5 (3)
Al8—Al4—O11	126.9 (4)	125.4 (4)	128.4 (4)
Al8—Al4—O12^ix	96.9 (4)	95.0 (4)	98.8 (4)
O2—Al4—O9^ix	112.8 (6)	112.2 (6)	113.5 (6)
O2—Al4—O11	104.2 (6)	102.8 (5)	105.6 (5)
O2—Al4—O12^ix	112.5 (6)	111.9 (7)	113.2 (7)
O9^ix—Al4—O11	108.6 (6)	107.0 (5)	110.1 (5)
O9^ix—Al4—O12^ix	109.6 (5)	109.0 (5)	110.3 (5)
O11—Al4—O12^ix	108.8 (5)	108.3 (5)	109.4 (5)
Ca1^xxiii—Si5—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Si5—Ca2^xxiv	75.3 (4)	71.8 (4)	78.9 (3)
Ca1^xxiii—Si5—Na2^xxiv	74.6 (4)	74.0 (4)	75.1 (4)
Ca1^xxiii—Si5—Al5	0	0	0
Ca1^xxiii—Si5—O1	48.1 (4)	46.3 (4)	50.0 (4)
Ca1^xxiii—Si5—O7	137.6 (6)	134.4 (6)	140.7 (6)
Ca1^xxiii—Si5—O8^xii	109.8 (6)	107.4 (6)	112.2 (6)
Ca1^xxiii—Si5—O13^xiii	55.2 (5)	52.1 (5)	58.5 (5)
Na1^xxiii—Si5—Ca2^xxiv	75.3 (4)	71.8 (4)	78.9 (3)
Na1^xxiii—Si5—Na2^xxiv	74.6 (4)	74.0 (4)	75.1 (4)
Na1^xxiii—Si5—Al5	0	0	0
Na1^xxiii—Si5—O1	48.1 (4)	46.3 (4)	50.0 (4)
Na1^xxiii—Si5—O7	137.6 (6)	134.4 (6)	140.7 (6)
Na1^xxiii—Si5—O8^xii	109.8 (6)	107.4 (6)	112.2 (6)
Na1^xxiii—Si5—O13^xiii	55.2 (5)	52.1 (5)	58.5 (5)
Ca2^xxiv—Si5—Na2^xxiv	11.4 (6)	3.3 (2)	21.1 (3)
Ca2^xxiv—Si5—Al5	0	0	0
Ca2^xxiv—Si5—O1	112.4 (8)	105.6 (5)	119.5 (5)
Ca2^xxiv—Si5—O7	136.7 (7)	129.1 (4)	143.8 (4)
Ca2^xxiv—Si5—O8^xii	49.6 (5)	45.6 (4)	54.2 (4)
Ca2^xxiv—Si5—O13^xiii	51.7 (6)	47.1 (5)	56.1 (5)
Na2^xxiv—Si5—Al5	0	0	0
Na2^xxiv—Si5—O1	105.5 (5)	103.8 (5)	107.3 (5)
Na2^xxiv—Si5—O7	142.9 (4)	141.1 (4)	144.6 (4)
Na2^xxiv—Si5—O8^xii	42.7 (4)	41.9 (4)	43.5 (4)
Na2^xxiv—Si5—O13^xiii	60.4 (5)	58.0 (5)	62.9 (5)
Al5—Si5—O1	0	0	0
Al5—Si5—O7	0	0	0
Al5—Si5—O8^xii	0	0	0
Al5—Si5—O13^xiii	0	0	0
O1—Si5—O7	110.7 (5)	110.4 (5)	111.0 (5)
O1—Si5—O8^xii	113.2 (7)	112.1 (7)	114.3 (7)
O1—Si5—O13^xiii	102.4 (6)	100.8 (6)	104.1 (7)
O7—Si5—O8^xii	112.5 (6)	110.9 (7)	114.0 (7)
O7—Si5—O13^xiii	117.0 (7)	116.1 (7)	118.0 (7)
O8^xii—Si5—O13^xiii	100.3 (6)	98.5 (6)	102.2 (6)
Ca1^xxiii—Al5—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Al5—Ca2^xxiv	75.3 (4)	71.8 (4)	78.9 (3)
Ca1^xxiii—Al5—Na2^xxiv	74.6 (4)	74.0 (4)	75.1 (4)
Ca1^xxiii—Al5—Al2^xi	71.2 (3)	69.4 (3)	73.1 (3)
Ca1^xxiii—Al5—Al3ⁱ	123.9 (5)	122.6 (5)	125.3 (5)
Ca1^xxiii—Al5—Si5	0	0	0
Ca1^xxiii—Al5—Al7	113.2 (4)	109.5 (4)	116.8 (4)
Ca1^xxiii—Al5—Al8^xiii	69.0 (4)	63.5 (3)	74.6 (3)
Ca1^xxiii—Al5—O1	48.1 (4)	46.3 (4)	50.0 (4)
Ca1^xxiii—Al5—O7	137.6 (6)	134.4 (6)	140.7 (6)
Ca1^xxiii—Al5—O8^xii	109.8 (6)	107.4 (6)	112.2 (6)
Ca1^xxiii—Al5—O13^xiii	55.2 (5)	52.1 (5)	58.5 (5)
Na1^xxiii—Al5—Ca2^xxiv	75.3 (4)	71.8 (4)	78.9 (3)
Na1^xxiii—Al5—Na2^xxiv	74.6 (4)	74.0 (4)	75.1 (4)
Na1^xxiii—Al5—Al2^xi	71.2 (3)	69.4 (3)	73.1 (3)
Na1^xxiii—Al5—Al3ⁱ	123.9 (5)	122.6 (5)	125.3 (5)
Na1^xxiii—Al5—Si5	0	0	0
Na1^xxiii—Al5—Al7	113.2 (4)	109.5 (4)	116.8 (4)
Na1^xxiii—Al5—Al8^xiii	69.0 (4)	63.5 (3)	74.6 (3)
Na1^xxiii—Al5—O1	48.1 (4)	46.3 (4)	50.0 (4)
Na1^xxiii—Al5—O7	137.6 (6)	134.4 (6)	140.7 (6)
Na1^xxiii—Al5—O8^xii	109.8 (6)	107.4 (6)	112.2 (6)
Na1^xxiii—Al5—O13^xiii	55.2 (5)	52.1 (5)	58.5 (5)
Ca2^xxiv—Al5—Na2^xxiv	11.4 (6)	3.3 (2)	21.1 (3)
Ca2^xxiv—Al5—Al2^xi	128.5 (7)	120.3 (3)	137.0 (4)
Ca2^xxiv—Al5—Al3ⁱ	71.4 (4)	67.9 (2)	75.4 (2)
Ca2^xxiv—Al5—Si5	0	0	0
Ca2^xxiv—Al5—Al7	150.6 (7)	141.5 (3)	159.3 (3)
Ca2^xxiv—Al5—Al8^xiii	64.7 (5)	58.0 (2)	71.3 (2)
Ca2^xxiv—Al5—O1	112.4 (8)	105.6 (5)	119.5 (5)
Ca2^xxiv—Al5—O7	136.7 (7)	129.1 (4)	143.8 (4)
Ca2^xxiv—Al5—O8^xii	49.6 (5)	45.6 (4)	54.2 (4)
Ca2^xxiv—Al5—O13^xiii	51.7 (6)	47.1 (5)	56.1 (5)
Na2^xxiv—Al5—Al2^xi	119.1 (3)	117.5 (3)	120.7 (3)
Na2^xxiv—Al5—Al3ⁱ	64.3 (2)	63.8 (2)	64.7 (2)
Na2^xxiv—Al5—Si5	0	0	0
Na2^xxiv—Al5—Al7	160.9 (3)	159.5 (3)	162.5 (3)
Na2^xxiv—Al5—Al8^xiii	74.8 (2)	73.0 (2)	76.8 (2)
Na2^xxiv—Al5—O1	105.5 (5)	103.8 (5)	107.3 (5)
Na2^xxiv—Al5—O7	142.9 (4)	141.1 (4)	144.6 (4)
Na2^xxiv—Al5—O8^xii	42.7 (4)	41.9 (4)	43.5 (4)
Na2^xxiv—Al5—O13^xiii	60.4 (5)	58.0 (5)	62.9 (5)
Al2^xi—Al5—Al3ⁱ	96.7 (2)	95.4 (2)	98.1 (2)
Al2^xi—Al5—Si5	0	0	0
Al2^xi—Al5—Al7	79.8 (2)	79.2 (3)	80.4 (3)
Al2^xi—Al5—Al8^xiii	131.6 (2)	129.6 (2)	133.6 (2)
Al2^xi—Al5—O1	23.1 (3)	22.8 (4)	23.4 (3)
Al2^xi—Al5—O7	93.2 (3)	92.5 (4)	93.9 (4)
Al2^xi—Al5—O8^xii	109.2 (4)	108.5 (4)	110.0 (4)
Al2^xi—Al5—O13^xiii	124.9 (5)	123.9 (5)	126.0 (5)
Al3ⁱ—Al5—Si5	0	0	0
Al3ⁱ—Al5—Al7	118.1 (3)	114.8 (3)	121.3 (3)
Al3ⁱ—Al5—Al8^xiii	128.14 (16)	126.45 (16)	129.90 (17)
Al3ⁱ—Al5—O1	108.6 (5)	106.7 (5)	110.6 (5)
Al3ⁱ—Al5—O7	96.3 (5)	93.2 (5)	99.2 (5)
Al3ⁱ—Al5—O8^xii	21.9 (3)	21.0 (3)	22.9 (3)
Al3ⁱ—Al5—O13^xiii	121.7 (5)	119.7 (5)	123.8 (5)
Si5—Al5—Al7	0	0	0
Si5—Al5—Al8^xiii	0	0	0
Si5—Al5—O1	0	0	0
Si5—Al5—O7	0	0	0
Si5—Al5—O8^xii	0	0	0
Si5—Al5—O13^xiii	0	0	0
Al7—Al5—Al8^xiii	91.5 (3)	90.5 (2)	92.4 (3)
Al7—Al5—O1	91.6 (4)	91.2 (4)	92.1 (4)
Al7—Al5—O7	24.6 (3)	23.1 (3)	26.2 (4)
Al7—Al5—O8^xii	136.6 (5)	135.0 (5)	138.2 (5)
Al7—Al5—O13^xiii	108.7 (5)	106.6 (5)	110.7 (5)
Al8^xiii—Al5—O1	112.1 (5)	109.3 (4)	114.9 (5)
Al8^xiii—Al5—O7	97.9 (5)	97.1 (5)	98.7 (5)
Al8^xiii—Al5—O8^xii	109.4 (3)	108.0 (3)	110.7 (3)
Al8^xiii—Al5—O13^xiii	19.1 (4)	17.6 (4)	20.6 (4)
O1—Al5—O7	110.7 (5)	110.4 (5)	111.0 (5)
O1—Al5—O8^xii	113.2 (7)	112.1 (7)	114.3 (7)
O1—Al5—O13^xiii	102.4 (6)	100.8 (6)	104.1 (7)
O7—Al5—O8^xii	112.5 (6)	110.9 (7)	114.0 (7)
O7—Al5—O13^xiii	117.0 (7)	116.1 (7)	118.0 (7)
O8^xii—Al5—O13^xiii	100.3 (6)	98.5 (6)	102.2 (6)
Ca1^xxxii—Si6—Na1^xxxii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxii—Si6—Ca2^xxvi	75.5 (4)	73.2 (4)	77.8 (4)
Ca1^xxxii—Si6—Na2^xxvi	78.8 (3)	77.2 (3)	80.3 (3)
Ca1^xxxii—Si6—Al6	0	0	0
Ca1^xxxii—Si6—O5^xiv	52.7 (5)	50.5 (5)	54.9 (5)
Ca1^xxxii—Si6—O9^xv	50.7 (4)	49.6 (4)	52.1 (5)
Ca1^xxxii—Si6—O10	137.6 (5)	133.2 (6)	141.8 (6)
Ca1^xxxii—Si6—O15^xvi	112.9 (7)	109.3 (8)	116.7 (9)
Na1^xxxii—Si6—Ca2^xxvi	75.5 (4)	73.2 (4)	77.8 (4)
Na1^xxxii—Si6—Na2^xxvi	78.8 (3)	77.2 (3)	80.3 (3)
Na1^xxxii—Si6—Al6	0	0	0
Na1^xxxii—Si6—O5^xiv	52.7 (5)	50.5 (5)	54.9 (5)
Na1^xxxii—Si6—O9^xv	50.7 (4)	49.6 (4)	52.1 (5)
Na1^xxxii—Si6—O10	137.6 (5)	133.2 (6)	141.8 (6)
Na1^xxxii—Si6—O15^xvi	112.9 (7)	109.3 (8)	116.7 (9)
Ca2^xxvi—Si6—Na2^xxvi	12.1 (6)	2.1 (3)	21.7 (2)
Ca2^xxvi—Si6—Al6	0	0	0
Ca2^xxvi—Si6—O5^xiv	55.0 (6)	48.9 (4)	61.0 (5)
Ca2^xxvi—Si6—O9^xv	110.6 (8)	106.4 (4)	115.0 (4)
Ca2^xxvi—Si6—O10	137.1 (7)	132.2 (5)	141.2 (4)
Ca2^xxvi—Si6—O15^xvi	48.4 (6)	44.7 (4)	52.5 (4)
Na2^xxvi—Si6—Al6	0	0	0
Na2^xxvi—Si6—O5^xiv	47.7 (4)	46.7 (4)	48.8 (4)
Na2^xxvi—Si6—O9^xv	119.8 (6)	116.9 (5)	122.6 (5)
Na2^xxvi—Si6—O10	128.1 (5)	125.7 (5)	130.5 (5)
Na2^xxvi—Si6—O15^xvi	54.3 (4)	52.2 (4)	56.5 (4)
Al6—Si6—O5^xiv	0	0	0
Al6—Si6—O9^xv	0	0	0
Al6—Si6—O10	0	0	0
Al6—Si6—O15^xvi	0	0	0
O5^xiv—Si6—O9^xv	102.9 (6)	101.6 (6)	104.2 (7)
O5^xiv—Si6—O10	117.1 (8)	115.4 (10)	118.8 (9)
O5^xiv—Si6—O15^xvi	102.0 (7)	100.0 (7)	104.1 (7)
O9^xv—Si6—O10	111.9 (6)	111.1 (6)	112.7 (6)
O9^xv—Si6—O15^xvi	113.0 (7)	111.9 (9)	114.1 (9)
O10—Si6—O15^xvi	109.5 (6)	108.7 (5)	110.3 (5)
Ca1^xxxii—Al6—Na1^xxxii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxii—Al6—Ca2^xxvi	75.5 (4)	73.2 (4)	77.8 (4)
Ca1^xxxii—Al6—Na2^xxvi	78.8 (3)	77.2 (3)	80.3 (3)
Ca1^xxxii—Al6—Al1^xiv	65.9 (4)	62.5 (4)	69.2 (4)
Ca1^xxxii—Al6—Al2^xvi	151.0 (5)	146.5 (5)	155.4 (5)
Ca1^xxxii—Al6—Al4^viii	70.5 (3)	68.7 (3)	72.3 (3)
Ca1^xxxii—Al6—Si6	0	0	0
Ca1^xxxii—Al6—Al7^xxx	128.4 (6)	124.5 (6)	132.4 (7)
Ca1^xxxii—Al6—O5^xiv	52.7 (5)	50.5 (5)	54.9 (5)
Ca1^xxxii—Al6—O9^xv	50.7 (4)	49.6 (4)	52.1 (5)
Ca1^xxxii—Al6—O10	137.6 (5)	133.2 (6)	141.8 (6)
Ca1^xxxii—Al6—O15^xvi	112.9 (7)	109.3 (8)	116.7 (9)
Na1^xxxii—Al6—Ca2^xxvi	75.5 (4)	73.2 (4)	77.8 (4)
Na1^xxxii—Al6—Na2^xxvi	78.8 (3)	77.2 (3)	80.3 (3)
Na1^xxxii—Al6—Al1^xiv	65.9 (4)	62.5 (4)	69.2 (4)
Na1^xxxii—Al6—Al2^xvi	151.0 (5)	146.5 (5)	155.4 (5)
Na1^xxxii—Al6—Al4^viii	70.5 (3)	68.7 (3)	72.3 (3)
Na1^xxxii—Al6—Si6	0	0	0
Na1^xxxii—Al6—Al7^xxx	128.4 (6)	124.5 (6)	132.4 (7)
Na1^xxxii—Al6—O5^xiv	52.7 (5)	50.5 (5)	54.9 (5)
Na1^xxxii—Al6—O9^xv	50.7 (4)	49.6 (4)	52.1 (5)
Na1^xxxii—Al6—O10	137.6 (5)	133.2 (6)	141.8 (6)
Na1^xxxii—Al6—O15^xvi	112.9 (7)	109.3 (8)	116.7 (9)
Ca2^xxvi—Al6—Na2^xxvi	12.1 (6)	2.1 (3)	21.7 (2)
Ca2^xxvi—Al6—Al1^xiv	70.3 (5)	60.9 (2)	79.2 (2)
Ca2^xxvi—Al6—Al2^xvi	113.8 (5)	107.9 (3)	119.1 (2)
Ca2^xxvi—Al6—Al4^viii	123.7 (7)	119.2 (3)	128.5 (3)
Ca2^xxvi—Al6—Si6	0	0	0
Ca2^xxvi—Al6—Al7^xxx	71.2 (4)	67.41 (18)	75.35 (19)
Ca2^xxvi—Al6—O5^xiv	55.0 (6)	48.9 (4)	61.0 (5)
Ca2^xxvi—Al6—O9^xv	110.6 (8)	106.4 (4)	115.0 (4)
Ca2^xxvi—Al6—O10	137.1 (7)	132.2 (5)	141.2 (4)
Ca2^xxvi—Al6—O15^xvi	48.4 (6)	44.7 (4)	52.5 (4)
Na2^xxvi—Al6—Al1^xiv	60.5 (2)	59.9 (2)	61.1 (2)
Na2^xxvi—Al6—Al2^xvi	105.5 (2)	105.1 (2)	105.9 (2)
Na2^xxvi—Al6—Al4^viii	134.7 (4)	130.6 (2)	138.7 (3)
Na2^xxvi—Al6—Si6	0	0	0
Na2^xxvi—Al6—Al7^xxx	76.8 (2)	75.25 (19)	78.25 (19)
Na2^xxvi—Al6—O5^xiv	47.7 (4)	46.7 (4)	48.8 (4)
Na2^xxvi—Al6—O9^xv	119.8 (6)	116.9 (5)	122.6 (5)
Na2^xxvi—Al6—O10	128.1 (5)	125.7 (5)	130.5 (5)
Na2^xxvi—Al6—O15^xvi	54.3 (4)	52.2 (4)	56.5 (4)
Al1^xiv—Al6—Al2^xvi	90.9 (3)	90.0 (4)	91.8 (4)
Al1^xiv—Al6—Al4^viii	127.90 (17)	126.42 (17)	129.46 (18)
Al1^xiv—Al6—Si6	0	0	0
Al1^xiv—Al6—Al7^xxx	132.0 (2)	129.91 (19)	133.96 (19)
Al1^xiv—Al6—O5^xiv	20.2 (5)	18.1 (6)	22.2 (5)
Al1^xiv—Al6—O9^xv	111.5 (4)	111.2 (4)	111.9 (4)
Al1^xiv—Al6—O10	97.0 (5)	95.4 (5)	98.7 (4)
Al1^xiv—Al6—O15^xvi	112.8 (5)	109.8 (5)	115.7 (5)
Al2^xvi—Al6—Al4^viii	117.6 (3)	114.39 (19)	120.91 (19)
Al2^xvi—Al6—Si6	0	0	0
Al2^xvi—Al6—Al7^xxx	79.7 (2)	79.20 (18)	80.30 (18)
Al2^xvi—Al6—O5^xiv	108.7 (6)	106.2 (7)	111.1 (6)
Al2^xvi—Al6—O9^xv	134.7 (5)	132.2 (4)	137.2 (5)
Al2^xvi—Al6—O10	23.5 (4)	21.5 (4)	25.6 (4)
Al2^xvi—Al6—O15^xvi	91.4 (5)	91.0 (6)	91.8 (5)
Al4^viii—Al6—Si6	0	0	0
Al4^viii—Al6—Al7^xxx	97.1 (2)	95.7 (2)	98.5 (2)
Al4^viii—Al6—O5^xiv	122.1 (5)	119.9 (5)	124.4 (5)
Al4^viii—Al6—O9^xv	19.8 (4)	18.5 (4)	21.0 (4)
Al4^viii—Al6—O10	96.7 (5)	94.5 (5)	98.9 (5)
Al4^viii—Al6—O15^xvi	109.1 (6)	107.4 (6)	111.0 (6)
Si6—Al6—Al7^xxx	0	0	0
Si6—Al6—O5^xiv	0	0	0
Si6—Al6—O9^xv	0	0	0
Si6—Al6—O10	0	0	0
Si6—Al6—O15^xvi	0	0	0
Al7^xxx—Al6—O5^xiv	124.4 (5)	123.1 (5)	125.6 (5)
Al7^xxx—Al6—O9^xv	108.0 (4)	107.4 (5)	108.7 (5)
Al7^xxx—Al6—O10	92.4 (4)	91.7 (3)	93.2 (3)
Al7^xxx—Al6—O15^xvi	22.9 (4)	22.2 (4)	23.5 (4)
O5^xiv—Al6—O9^xv	102.9 (6)	101.6 (6)	104.2 (7)
O5^xiv—Al6—O10	117.1 (8)	115.4 (10)	118.8 (9)
O5^xiv—Al6—O15^xvi	102.0 (7)	100.0 (7)	104.1 (7)
O9^xv—Al6—O10	111.9 (6)	111.1 (6)	112.7 (6)
O9^xv—Al6—O15^xvi	113.0 (7)	111.9 (9)	114.1 (9)
O10—Al6—O15^xvi	109.5 (6)	108.7 (5)	110.3 (5)
Ca1—Si7—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—Si7—Al7	0	0	0
Ca1—Si7—O4	36.7 (5)	30.9 (5)	42.8 (6)
Ca1—Si7—O7	69.1 (6)	62.2 (7)	75.6 (6)
Ca1—Si7—O14^xii	127.7 (5)	123.1 (4)	132.1 (4)
Ca1—Si7—O15^xi	118.3 (6)	116.9 (6)	119.7 (6)
Na1—Si7—Al7	0	0	0
Na1—Si7—O4	36.7 (5)	30.9 (5)	42.8 (6)
Na1—Si7—O7	69.1 (6)	62.2 (7)	75.6 (6)
Na1—Si7—O14^xii	127.7 (5)	123.1 (4)	132.1 (4)
Na1—Si7—O15^xi	118.3 (6)	116.9 (6)	119.7 (6)
Al7—Si7—O4	0	0	0
Al7—Si7—O7	0	0	0
Al7—Si7—O14^xii	0	0	0
Al7—Si7—O15^xi	0	0	0
O4—Si7—O7	105.4 (6)	104.3 (6)	106.4 (6)
O4—Si7—O14^xii	109.4 (6)	107.8 (6)	111.0 (6)
O4—Si7—O15^xi	108.2 (6)	107.5 (6)	108.9 (6)
O7—Si7—O14^xii	111.5 (6)	110.6 (6)	112.4 (6)
O7—Si7—O15^xi	113.2 (6)	113.0 (6)	113.4 (6)
O14^xii—Si7—O15^xi	109.0 (6)	107.1 (6)	110.8 (6)
Ca1—Al7—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—Al7—Ca2^xxv	82.8 (3)	75.9 (3)	89.7 (4)
Ca1—Al7—Ca2^xxxiii	85.9 (3)	82.9 (4)	89.4 (3)
Ca1—Al7—Na2^xxv	84.1 (3)	79.6 (3)	88.8 (3)
Ca1—Al7—Al1^xii	138.4 (3)	133.4 (3)	142.9 (3)
Ca1—Al7—Al3^xviii	63.4 (5)	57.0 (4)	70.1 (5)
Ca1—Al7—Al5	91.9 (5)	86.3 (5)	97.1 (4)
Ca1—Al7—Al6^xiii	140.7 (3)	138.9 (4)	142.4 (4)
Ca1—Al7—Si7	0	0	0
Ca1—Al7—O4	36.7 (5)	30.9 (5)	42.8 (6)
Ca1—Al7—O7	69.1 (6)	62.2 (7)	75.6 (6)
Ca1—Al7—O14^xii	127.7 (5)	123.1 (4)	132.1 (4)
Ca1—Al7—O15^xi	118.3 (6)	116.9 (6)	119.7 (6)
Na1—Al7—Ca2^xxv	82.8 (3)	75.9 (3)	89.7 (4)
Na1—Al7—Ca2^xxxiii	85.9 (3)	82.9 (4)	89.4 (3)
Na1—Al7—Na2^xxv	84.1 (3)	79.6 (3)	88.8 (3)
Na1—Al7—Al1^xii	138.4 (3)	133.4 (3)	142.9 (3)
Na1—Al7—Al3^xviii	63.4 (5)	57.0 (4)	70.1 (5)
Na1—Al7—Al5	91.9 (5)	86.3 (5)	97.1 (4)
Na1—Al7—Al6^xiii	140.7 (3)	138.9 (4)	142.4 (4)
Na1—Al7—Si7	0	0	0
Na1—Al7—O4	36.7 (5)	30.9 (5)	42.8 (6)
Na1—Al7—O7	69.1 (6)	62.2 (7)	75.6 (6)
Na1—Al7—O14^xii	127.7 (5)	123.1 (4)	132.1 (4)
Na1—Al7—O15^xi	118.3 (6)	116.9 (6)	119.7 (6)
Ca2^xxv—Al7—Ca2^xxxiii	130.2 (6)	125.7 (9)	134.2 (8)
Ca2^xxv—Al7—Na2^xxv	5.0 (5)	1.9 (3)	8.68 (19)
Ca2^xxv—Al7—Al1^xii	57.1 (3)	54.22 (19)	59.6 (2)
Ca2^xxv—Al7—Al3^xviii	58.7 (5)	53.82 (19)	64.2 (2)
Ca2^xxv—Al7—Al5	108.1 (5)	103.6 (3)	112.0 (2)
Ca2^xxv—Al7—Al6^xiii	126.5 (2)	125.9 (2)	127.1 (2)
Ca2^xxv—Al7—Si7	0	0	0
Ca2^xxv—Al7—O4	63.7 (6)	58.1 (4)	69.9 (4)
Ca2^xxv—Al7—O7	112.2 (5)	110.2 (4)	113.8 (4)
Ca2^xxv—Al7—O14^xii	47.3 (5)	41.2 (4)	52.9 (4)
Ca2^xxv—Al7—O15^xi	134.1 (6)	132.9 (5)	135.3 (5)
Ca2^xxxiii—Al7—Na2^xxv	134.5 (6)	127.8 (3)	141.0 (3)
Ca2^xxxiii—Al7—Al1^xii	126.67 (19)	125.90 (18)	127.4 (2)
Ca2^xxxiii—Al7—Al3^xviii	72.8 (6)	65.3 (2)	80.2 (2)
Ca2^xxxiii—Al7—Al5	120.5 (6)	113.7 (3)	127.5 (3)
Ca2^xxxiii—Al7—Al6^xiii	56.3 (4)	52.76 (19)	60.14 (19)
Ca2^xxxiii—Al7—Si7	0	0	0
Ca2^xxxiii—Al7—O4	78.6 (7)	71.5 (4)	85.6 (4)
Ca2^xxxiii—Al7—O7	108.2 (6)	104.3 (4)	112.0 (5)
Ca2^xxxiii—Al7—O14^xii	134.9 (4)	133.3 (4)	136.5 (5)
Ca2^xxxiii—Al7—O15^xi	33.4 (6)	29.5 (5)	37.9 (5)
Na2^xxv—Al7—Al1^xii	55.13 (18)	53.54 (18)	56.73 (18)
Na2^xxv—Al7—Al3^xviii	62.94 (18)	62.42 (18)	63.48 (19)
Na2^xxv—Al7—Al5	103.94 (19)	102.97 (19)	104.91 (19)
Na2^xxv—Al7—Al6^xiii	127.2 (2)	125.8 (2)	128.7 (2)
Na2^xxv—Al7—Si7	0	0	0
Na2^xxv—Al7—O4	67.0 (4)	66.0 (4)	68.1 (4)
Na2^xxv—Al7—O7	109.0 (4)	108.8 (4)	109.1 (4)
Na2^xxv—Al7—O14^xii	45.0 (4)	43.1 (4)	47.0 (4)
Na2^xxv—Al7—O15^xi	136.9 (5)	136.8 (5)	137.1 (5)
Al1^xii—Al7—Al3^xviii	98.8 (3)	96.4 (3)	101.2 (3)
Al1^xii—Al7—Al5	91.6 (3)	89.2 (3)	94.0 (3)
Al1^xii—Al7—Al6^xiii	78.39 (16)	77.05 (15)	79.71 (15)
Al1^xii—Al7—Si7	0	0	0
Al1^xii—Al7—O4	117.1 (5)	114.1 (5)	120.0 (5)
Al1^xii—Al7—O7	114.4 (5)	113.4 (5)	115.4 (5)
Al1^xii—Al7—O14^xii	10.9 (3)	8.2 (3)	13.7 (3)
Al1^xii—Al7—O15^xi	98.6 (5)	98.1 (5)	99.1 (5)
Al3^xviii—Al7—Al5	152.04 (18)	151.55 (17)	152.50 (17)
Al3^xviii—Al7—Al6^xiii	107.0 (2)	106.3 (2)	107.7 (2)
Al3^xviii—Al7—Si7	0	0	0
Al3^xviii—Al7—O4	26.9 (3)	26.2 (3)	27.6 (3)
Al3^xviii—Al7—O7	132.3 (5)	131.6 (5)	132.9 (5)
Al3^xviii—Al7—O14^xii	94.6 (4)	93.2 (4)	96.1 (4)
Al3^xviii—Al7—O15^xi	93.3 (5)	92.4 (5)	94.2 (5)
Al5—Al7—Al6^xiii	100.5 (3)	99.8 (3)	101.2 (3)
Al5—Al7—Si7	0	0	0
Al5—Al7—O4	126.5 (3)	126.3 (3)	126.8 (3)
Al5—Al7—O7	24.5 (5)	23.3 (5)	25.6 (5)
Al5—Al7—O14^xii	90.8 (4)	88.6 (4)	93.0 (4)
Al5—Al7—O15^xi	110.8 (6)	109.9 (6)	111.8 (6)
Al6^xiii—Al7—Si7	0	0	0
Al6^xiii—Al7—O4	127.6 (4)	126.1 (4)	129.1 (4)
Al6^xiii—Al7—O7	112.4 (5)	111.8 (5)	113.0 (5)
Al6^xiii—Al7—O14^xii	89.2 (4)	85.5 (4)	92.8 (4)
Al6^xiii—Al7—O15^xi	23.0 (5)	21.0 (5)	24.8 (5)
Si7—Al7—O4	0	0	0
Si7—Al7—O7	0	0	0
Si7—Al7—O14^xii	0	0	0
Si7—Al7—O15^xi	0	0	0
O4—Al7—O7	105.4 (6)	104.3 (6)	106.4 (6)
O4—Al7—O14^xii	109.4 (6)	107.8 (6)	111.0 (6)
O4—Al7—O15^xi	108.2 (6)	107.5 (6)	108.9 (6)
O7—Al7—O14^xii	111.5 (6)	110.6 (6)	112.4 (6)
O7—Al7—O15^xi	113.2 (6)	113.0 (6)	113.4 (6)
O14^xii—Al7—O15^xi	109.0 (6)	107.1 (6)	110.8 (6)
Ca1^xxxiv—Si8—Na1^xxxiv	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—Si8—Ca2^xxxv	68.3 (3)	61.7 (3)	75.4 (3)
Ca1^xxxiv—Si8—Al8	0	0	0
Ca1^xxxiv—Si8—O2	133.2 (5)	132.4 (5)	134.1 (4)
Ca1^xxxiv—Si8—O3	64.6 (5)	59.2 (6)	70.0 (5)
Ca1^xxxiv—Si8—O6	115.0 (6)	113.2 (7)	116.9 (7)
Ca1^xxxiv—Si8—O13	42.4 (5)	38.2 (5)	46.7 (5)
Na1^xxxiv—Si8—Ca2^xxxv	68.3 (3)	61.7 (3)	75.4 (3)
Na1^xxxiv—Si8—Al8	0	0	0
Na1^xxxiv—Si8—O2	133.2 (5)	132.4 (5)	134.1 (4)
Na1^xxxiv—Si8—O3	64.6 (5)	59.2 (6)	70.0 (5)
Na1^xxxiv—Si8—O6	115.0 (6)	113.2 (7)	116.9 (7)
Na1^xxxiv—Si8—O13	42.4 (5)	38.2 (5)	46.7 (5)
Ca2^xxxv—Si8—Al8	0	0	0
Ca2^xxxv—Si8—O2	127.0 (8)	125.2 (5)	128.6 (8)
Ca2^xxxv—Si8—O3	121.5 (7)	119.7 (9)	123.1 (5)
Ca2^xxxv—Si8—O6	59.8 (6)	55.0 (4)	64.4 (4)
Ca2^xxxv—Si8—O13	45.0 (5)	41.5 (4)	48.8 (4)
Al8—Si8—O2	0	0	0
Al8—Si8—O3	0	0	0
Al8—Si8—O6	0	0	0
Al8—Si8—O13	0	0	0
O2—Si8—O3	110.3 (7)	109.1 (6)	111.5 (6)
O2—Si8—O6	109.2 (6)	108.4 (5)	110.0 (5)
O2—Si8—O13	112.3 (7)	111.6 (6)	112.9 (6)
O3—Si8—O6	113.8 (6)	112.9 (6)	114.7 (6)
O3—Si8—O13	106.4 (7)	105.4 (6)	107.4 (6)
O6—Si8—O13	104.8 (7)	103.7 (6)	105.8 (6)
Ca1^xxxiv—Al8—Na1^xxxiv	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—Al8—Ca2^xxxv	68.3 (3)	61.7 (3)	75.4 (3)
Ca1^xxxiv—Al8—Al2^xxiii	74.6 (3)	71.8 (3)	77.4 (2)
Ca1^xxxiv—Al8—Al3^ix	122.1 (5)	121.0 (5)	123.3 (5)
Ca1^xxxiv—Al8—Al4	149.1 (4)	148.2 (4)	149.9 (4)
Ca1^xxxiv—Al8—Al5^xxx	56.3 (3)	54.1 (3)	58.6 (3)
Ca1^xxxiv—Al8—Si8	0	0	0
Ca1^xxxiv—Al8—O2	133.2 (5)	132.4 (5)	134.1 (4)
Ca1^xxxiv—Al8—O3	64.6 (5)	59.2 (6)	70.0 (5)
Ca1^xxxiv—Al8—O6	115.0 (6)	113.2 (7)	116.9 (7)
Ca1^xxxiv—Al8—O13	42.4 (5)	38.2 (5)	46.7 (5)
Na1^xxxiv—Al8—Ca2^xxxv	68.3 (3)	61.7 (3)	75.4 (3)
Na1^xxxiv—Al8—Al2^xxiii	74.6 (3)	71.8 (3)	77.4 (2)
Na1^xxxiv—Al8—Al3^ix	122.1 (5)	121.0 (5)	123.3 (5)
Na1^xxxiv—Al8—Al4	149.1 (4)	148.2 (4)	149.9 (4)
Na1^xxxiv—Al8—Al5^xxx	56.3 (3)	54.1 (3)	58.6 (3)
Na1^xxxiv—Al8—Si8	0	0	0
Na1^xxxiv—Al8—O2	133.2 (5)	132.4 (5)	134.1 (4)
Na1^xxxiv—Al8—O3	64.6 (5)	59.2 (6)	70.0 (5)
Na1^xxxiv—Al8—O6	115.0 (6)	113.2 (7)	116.9 (7)
Na1^xxxiv—Al8—O13	42.4 (5)	38.2 (5)	46.7 (5)
Ca2^xxxv—Al8—Al2^xxiii	124.0 (6)	123.0 (6)	125.1 (4)
Ca2^xxxv—Al8—Al3^ix	74.2 (4)	69.60 (18)	78.58 (17)
Ca2^xxxv—Al8—Al4	110.3 (5)	104.4 (3)	115.8 (2)
Ca2^xxxv—Al8—Al5^xxx	58.4 (4)	57.2 (4)	59.6 (2)
Ca2^xxxv—Al8—Si8	0	0	0
Ca2^xxxv—Al8—O2	127.0 (8)	125.2 (5)	128.6 (8)
Ca2^xxxv—Al8—O3	121.5 (7)	119.7 (9)	123.1 (5)
Ca2^xxxv—Al8—O6	59.8 (6)	55.0 (4)	64.4 (4)
Ca2^xxxv—Al8—O13	45.0 (5)	41.5 (4)	48.8 (4)
Al2^xxiii—Al8—Al3^ix	93.07 (19)	92.2 (2)	94.0 (2)
Al2^xxiii—Al8—Al4	122.7 (3)	119.2 (2)	126.2 (2)
Al2^xxiii—Al8—Al5^xxx	126.2 (2)	125.3 (2)	127.3 (2)
Al2^xxiii—Al8—Si8	0	0	0
Al2^xxiii—Al8—O2	108.9 (6)	107.5 (6)	110.3 (5)
Al2^xxiii—Al8—O3	12.0 (5)	9.9 (4)	14.2 (5)
Al2^xxiii—Al8—O6	104.2 (5)	102.9 (5)	105.5 (5)
Al2^xxiii—Al8—O13	116.9 (5)	114.9 (6)	118.9 (6)
Al3^ix—Al8—Al4	84.76 (18)	84.2 (2)	85.3 (2)
Al3^ix—Al8—Al5^xxx	129.5 (3)	127.3 (2)	131.8 (2)
Al3^ix—Al8—Si8	0	0	0
Al3^ix—Al8—O2	104.4 (3)	104.0 (3)	104.9 (3)
Al3^ix—Al8—O3	103.9 (5)	103.1 (5)	104.6 (5)
Al3^ix—Al8—O6	14.9 (4)	14.5 (4)	15.2 (4)
Al3^ix—Al8—O13	119.2 (5)	118.3 (4)	120.1 (4)
Al4—Al8—Al5^xxx	95.7 (3)	94.7 (3)	96.6 (3)
Al4—Al8—Si8	0	0	0
Al4—Al8—O2	23.2 (4)	21.4 (3)	25.1 (4)
Al4—Al8—O3	127.9 (5)	123.0 (5)	132.8 (5)
Al4—Al8—O6	87.1 (4)	86.0 (4)	88.2 (4)
Al4—Al8—O13	113.5 (5)	110.4 (5)	116.7 (5)
Al5^xxx—Al8—Si8	0	0	0
Al5^xxx—Al8—O2	92.2 (4)	89.3 (4)	95.0 (4)
Al5^xxx—Al8—O3	114.4 (5)	112.7 (5)	116.0 (5)
Al5^xxx—Al8—O6	114.7 (5)	112.1 (5)	117.3 (5)
Al5^xxx—Al8—O13	20.1 (4)	17.9 (4)	22.4 (4)
Si8—Al8—O2	0	0	0
Si8—Al8—O3	0	0	0
Si8—Al8—O6	0	0	0
Si8—Al8—O13	0	0	0
O2—Al8—O3	110.3 (7)	109.1 (6)	111.5 (6)
O2—Al8—O6	109.2 (6)	108.4 (5)	110.0 (5)
O2—Al8—O13	112.3 (7)	111.6 (6)	112.9 (6)
O3—Al8—O6	113.8 (6)	112.9 (6)	114.7 (6)
O3—Al8—O13	106.4 (7)	105.4 (6)	107.4 (6)
O6—Al8—O13	104.8 (7)	103.7 (6)	105.8 (6)
Ca1^xxiii—O1—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—O1—Si2^xi	127.5 (6)	124.2 (7)	130.7 (7)
Ca1^xxiii—O1—Al2^xi	127.5 (6)	124.2 (7)	130.7 (7)
Ca1^xxiii—O1—Si5	100.0 (5)	97.6 (5)	102.5 (5)
Ca1^xxiii—O1—Al5	100.0 (5)	97.6 (5)	102.5 (5)
Na1^xxiii—O1—Si2^xi	127.5 (6)	124.2 (7)	130.7 (7)
Na1^xxiii—O1—Al2^xi	127.5 (6)	124.2 (7)	130.7 (7)
Na1^xxiii—O1—Si5	100.0 (5)	97.6 (5)	102.5 (5)
Na1^xxiii—O1—Al5	100.0 (5)	97.6 (5)	102.5 (5)
Si2^xi—O1—Al2^xi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xi—O1—Si5	132.4 (8)	130.6 (8)	134.3 (9)
Si2^xi—O1—Al5	132.4 (8)	130.6 (8)	134.3 (9)
Al2^xi—O1—Si5	132.4 (8)	130.6 (8)	134.3 (9)
Al2^xi—O1—Al5	132.4 (8)	130.6 (8)	134.3 (9)
Si5—O1—Al5	0.0 (5)	0.0 (5)	0.0 (5)
Ca2^xxvii—O2—Na2^xxvii	9.2 (5)	3.6 (4)	14.75 (19)
Ca2^xxvii—O2—Si4	86.0 (7)	76.3 (4)	96.8 (4)
Ca2^xxvii—O2—Al4	86.0 (7)	76.3 (4)	96.8 (4)
Ca2^xxvii—O2—Si8	137.4 (8)	132.7 (6)	141.3 (8)
Ca2^xxvii—O2—Al8	137.4 (8)	132.7 (6)	141.3 (8)
Na2^xxvii—O2—Si4	90.9 (6)	87.4 (4)	94.3 (4)
Na2^xxvii—O2—Al4	90.9 (6)	87.4 (4)	94.3 (4)
Na2^xxvii—O2—Si8	134.6 (7)	132.5 (7)	136.6 (7)
Na2^xxvii—O2—Al8	134.6 (7)	132.5 (7)	136.6 (7)
Si4—O2—Al4	0.0 (5)	0.0 (5)	0.0 (5)
Si4—O2—Si8	133.3 (7)	129.5 (7)	136.9 (7)
Si4—O2—Al8	133.3 (7)	129.5 (7)	136.9 (7)
Al4—O2—Si8	133.3 (7)	129.5 (7)	136.9 (7)
Al4—O2—Al8	133.3 (7)	129.5 (7)	136.9 (7)
Si8—O2—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xxiii—O3—Al2^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xxiii—O3—Si8	156.2 (7)	152.1 (6)	160.3 (6)
Si2^xxiii—O3—Al8	156.2 (7)	152.1 (6)	160.3 (6)
Al2^xxiii—O3—Si8	156.2 (7)	152.1 (6)	160.3 (6)
Al2^xxiii—O3—Al8	156.2 (7)	152.1 (6)	160.3 (6)
Si8—O3—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—O4—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—O4—Si3^xviii	115.3 (9)	104.2 (8)	126.4 (9)
Ca1—O4—Al3^xviii	115.3 (9)	104.2 (8)	126.4 (9)
Ca1—O4—Si7	117.9 (9)	107.6 (9)	128.0 (9)
Ca1—O4—Al7	117.9 (9)	107.6 (9)	128.0 (9)
Na1—O4—Si3^xviii	115.3 (9)	104.2 (8)	126.4 (9)
Na1—O4—Al3^xviii	115.3 (9)	104.2 (8)	126.4 (9)
Na1—O4—Si7	117.9 (9)	107.6 (9)	128.0 (9)
Na1—O4—Al7	117.9 (9)	107.6 (9)	128.0 (9)
Si3^xviii—O4—Al3^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xviii—O4—Si7	126.4 (6)	124.9 (5)	127.9 (5)
Si3^xviii—O4—Al7	126.4 (6)	124.9 (5)	127.9 (5)
Al3^xviii—O4—Si7	126.4 (6)	124.9 (5)	127.9 (5)
Al3^xviii—O4—Al7	126.4 (6)	124.9 (5)	127.9 (5)
Si7—O4—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—O5—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—O5—Ca2^xxiv	98.7 (8)	90.8 (7)	106.9 (8)
Ca1^xxiii—O5—Na2^xxiv	109.7 (8)	108.6 (8)	110.8 (8)
Ca1^xxiii—O5—Si1	107.9 (6)	102.9 (5)	112.9 (5)
Ca1^xxiii—O5—Al1	107.9 (6)	102.9 (5)	112.9 (5)
Ca1^xxiii—O5—Si6^xxv	95.4 (7)	93.8 (7)	97.2 (7)
Ca1^xxiii—O5—Al6^xxv	95.4 (7)	93.8 (7)	97.2 (7)
Na1^xxiii—O5—Ca2^xxiv	98.7 (8)	90.8 (7)	106.9 (8)
Na1^xxiii—O5—Na2^xxiv	109.7 (8)	108.6 (8)	110.8 (8)
Na1^xxiii—O5—Si1	107.9 (6)	102.9 (5)	112.9 (5)
Na1^xxiii—O5—Al1	107.9 (6)	102.9 (5)	112.9 (5)
Na1^xxiii—O5—Si6^xxv	95.4 (7)	93.8 (7)	97.2 (7)
Na1^xxiii—O5—Al6^xxv	95.4 (7)	93.8 (7)	97.2 (7)
Ca2^xxiv—O5—Na2^xxiv	13.8 (7)	3.7 (3)	23.2 (3)
Ca2^xxiv—O5—Si1	114.8 (9)	103.6 (7)	125.2 (7)
Ca2^xxiv—O5—Al1	114.8 (9)	103.6 (7)	125.2 (7)
Ca2^xxiv—O5—Si6^xxv	93.2 (7)	89.1 (5)	97.9 (5)
Ca2^xxiv—O5—Al6^xxv	93.2 (7)	89.1 (5)	97.9 (5)
Na2^xxiv—O5—Si1	102.4 (6)	99.8 (6)	105.1 (7)
Na2^xxiv—O5—Al1	102.4 (6)	99.8 (6)	105.1 (7)
Na2^xxiv—O5—Si6^xxv	100.2 (5)	99.3 (4)	101.0 (5)
Na2^xxiv—O5—Al6^xxv	100.2 (5)	99.3 (4)	101.0 (5)
Si1—O5—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O5—Si6^xxv	139.2 (11)	134.4 (11)	144.1 (12)
Si1—O5—Al6^xxv	139.2 (11)	134.4 (11)	144.1 (12)
Al1—O5—Si6^xxv	139.2 (11)	134.4 (11)	144.1 (12)
Al1—O5—Al6^xxv	139.2 (11)	134.4 (11)	144.1 (12)
Si6^xxv—O5—Al6^xxv	0.0 (5)	0.0 (5)	0.0 (5)
Ca2^xxxv—O6—Si3^ix	118.0 (7)	117.5 (6)	118.5 (5)
Ca2^xxxv—O6—Al3^ix	118.0 (7)	117.5 (6)	118.5 (5)
Ca2^xxxv—O6—Si8	90.9 (6)	89.5 (5)	92.2 (5)
Ca2^xxxv—O6—Al8	90.9 (6)	89.5 (5)	92.2 (5)
Si3^ix—O6—Al3^ix	0.0 (5)	0.0 (5)	0.0 (5)
Si3^ix—O6—Si8	149.9 (8)	148.6 (8)	151.2 (8)
Si3^ix—O6—Al8	149.9 (8)	148.6 (8)	151.2 (8)
Al3^ix—O6—Si8	149.9 (8)	148.6 (8)	151.2 (8)
Al3^ix—O6—Al8	149.9 (8)	148.6 (8)	151.2 (8)
Si8—O6—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Si5—O7—Al5	0.0 (5)	0.0 (5)	0.0 (5)
Si5—O7—Si7	130.9 (8)	128.5 (7)	133.4 (7)
Si5—O7—Al7	130.9 (8)	128.5 (7)	133.4 (7)
Al5—O7—Si7	130.9 (8)	128.5 (7)	133.4 (7)
Al5—O7—Al7	130.9 (8)	128.5 (7)	133.4 (7)
Si7—O7—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Ca2^xxxvi—O8—Na2^xxxvi	16.1 (8)	4.7 (3)	28.6 (4)
Ca2^xxxvi—O8—Si3^ix	126.0 (7)	123.0 (6)	129.3 (6)
Ca2^xxxvi—O8—Al3^ix	126.0 (7)	123.0 (6)	129.3 (6)
Ca2^xxxvi—O8—Si5^xxvi	98.6 (7)	93.3 (6)	103.8 (6)
Ca2^xxxvi—O8—Al5^xxvi	98.6 (7)	93.3 (6)	103.8 (6)
Na2^xxxvi—O8—Si3^ix	115.1 (6)	111.6 (6)	118.7 (6)
Na2^xxxvi—O8—Al3^ix	115.1 (6)	111.6 (6)	118.7 (6)
Na2^xxxvi—O8—Si5^xxvi	109.0 (6)	107.0 (6)	111.0 (6)
Na2^xxxvi—O8—Al5^xxvi	109.0 (6)	107.0 (6)	111.0 (6)
Si3^ix—O8—Al3^ix	0.0 (5)	0.0 (5)	0.0 (5)
Si3^ix—O8—Si5^xxvi	135.1 (6)	133.1 (5)	137.1 (5)
Si3^ix—O8—Al5^xxvi	135.1 (6)	133.1 (5)	137.1 (5)
Al3^ix—O8—Si5^xxvi	135.1 (6)	133.1 (5)	137.1 (5)
Al3^ix—O8—Al5^xxvi	135.1 (6)	133.1 (5)	137.1 (5)
Si5^xxvi—O8—Al5^xxvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xvi—O9—Na1^xvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xvi—O9—Si4^xi	121.9 (5)	119.8 (5)	124.0 (5)
Ca1^xvi—O9—Al4^xi	121.9 (5)	119.8 (5)	124.0 (5)
Ca1^xvi—O9—Si6^xxxiii	98.0 (6)	96.1 (6)	99.8 (6)
Ca1^xvi—O9—Al6^xxxiii	98.0 (6)	96.1 (6)	99.8 (6)
Na1^xvi—O9—Si4^xi	121.9 (5)	119.8 (5)	124.0 (5)
Na1^xvi—O9—Al4^xi	121.9 (5)	119.8 (5)	124.0 (5)
Na1^xvi—O9—Si6^xxxiii	98.0 (6)	96.1 (6)	99.8 (6)
Na1^xvi—O9—Al6^xxxiii	98.0 (6)	96.1 (6)	99.8 (6)
Si4^xi—O9—Al4^xi	0.0 (5)	0.0 (5)	0.0 (5)
Si4^xi—O9—Si6^xxxiii	139.9 (6)	138.2 (6)	141.7 (6)
Si4^xi—O9—Al6^xxxiii	139.9 (6)	138.2 (6)	141.7 (6)
Al4^xi—O9—Si6^xxxiii	139.9 (6)	138.2 (6)	141.7 (6)
Al4^xi—O9—Al6^xxxiii	139.9 (6)	138.2 (6)	141.7 (6)
Si6^xxxiii—O9—Al6^xxxiii	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xvi—O10—Al2^xvi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xvi—O10—Si6	131.0 (8)	127.5 (8)	134.5 (8)
Si2^xvi—O10—Al6	131.0 (8)	127.5 (8)	134.5 (8)
Al2^xvi—O10—Si6	131.0 (8)	127.5 (8)	134.5 (8)
Al2^xvi—O10—Al6	131.0 (8)	127.5 (8)	134.5 (8)
Si6—O10—Al6	0.0 (5)	0.0 (5)	0.0 (5)
Ca2^xxvii—O11—Na2^xxvii	16.6 (9)	3.5 (3)	30.5 (4)
Ca2^xxvii—O11—Si2	115.4 (11)	99.6 (5)	130.6 (6)
Ca2^xxvii—O11—Al2	115.4 (11)	99.6 (5)	130.6 (6)
Ca2^xxvii—O11—Si4	115.5 (11)	99.5 (5)	131.9 (6)
Ca2^xxvii—O11—Al4	115.5 (11)	99.5 (5)	131.9 (6)
Na2^xxvii—O11—Si2	129.9 (5)	127.5 (5)	132.2 (5)
Na2^xxvii—O11—Al2	129.9 (5)	127.5 (5)	132.2 (5)
Na2^xxvii—O11—Si4	102.0 (5)	97.9 (5)	106.3 (5)
Na2^xxvii—O11—Al4	102.0 (5)	97.9 (5)	106.3 (5)
Si2—O11—Al2	0.0 (5)	0.0 (5)	0.0 (5)
Si2—O11—Si4	128.0 (5)	126.0 (5)	129.8 (5)
Si2—O11—Al4	128.0 (5)	126.0 (5)	129.8 (5)
Al2—O11—Si4	128.0 (5)	126.0 (5)	129.8 (5)
Al2—O11—Al4	128.0 (5)	126.0 (5)	129.8 (5)
Si4—O11—Al4	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O12—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O12—Si4^xi	151.2 (9)	149.6 (9)	152.8 (9)
Si1—O12—Al4^xi	151.2 (9)	149.6 (9)	152.8 (9)
Al1—O12—Si4^xi	151.2 (9)	149.6 (9)	152.8 (9)
Al1—O12—Al4^xi	151.2 (9)	149.6 (9)	152.8 (9)
Si4^xi—O12—Al4^xi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—O13—Na1^xxxiv	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—O13—Ca2^xxxv	99.1 (7)	89.3 (6)	109.0 (7)
Ca1^xxxiv—O13—Si5^xxx	92.7 (6)	89.9 (6)	95.6 (5)
Ca1^xxxiv—O13—Al5^xxx	92.7 (6)	89.9 (6)	95.6 (5)
Ca1^xxxiv—O13—Si8	112.9 (7)	105.2 (7)	120.6 (7)
Ca1^xxxiv—O13—Al8	112.9 (7)	105.2 (7)	120.6 (7)
Na1^xxxiv—O13—Ca2^xxxv	99.1 (7)	89.3 (6)	109.0 (7)
Na1^xxxiv—O13—Si5^xxx	92.7 (6)	89.9 (6)	95.6 (5)
Na1^xxxiv—O13—Al5^xxx	92.7 (6)	89.9 (6)	95.6 (5)
Na1^xxxiv—O13—Si8	112.9 (7)	105.2 (7)	120.6 (7)
Na1^xxxiv—O13—Al8	112.9 (7)	105.2 (7)	120.6 (7)
Ca2^xxxv—O13—Si5^xxx	96.4 (8)	92.7 (6)	100.5 (6)
Ca2^xxxv—O13—Al5^xxx	96.4 (8)	92.7 (6)	100.5 (6)
Ca2^xxxv—O13—Si8	107.6 (7)	98.6 (4)	116.1 (4)
Ca2^xxxv—O13—Al8	107.6 (7)	98.6 (4)	116.1 (4)
Si5^xxx—O13—Al5^xxx	0.0 (5)	0.0 (5)	0.0 (5)
Si5^xxx—O13—Si8	140.8 (10)	137.0 (8)	144.5 (8)
Si5^xxx—O13—Al8	140.8 (10)	137.0 (8)	144.5 (8)
Al5^xxx—O13—Si8	140.8 (10)	137.0 (8)	144.5 (8)
Al5^xxx—O13—Al8	140.8 (10)	137.0 (8)	144.5 (8)
Si8—O13—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O14—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O14—Si7^xxvi	158.0 (8)	152.1 (7)	163.9 (7)
Si1—O14—Al7^xxvi	158.0 (8)	152.1 (7)	163.9 (7)
Al1—O14—Si7^xxvi	158.0 (8)	152.1 (7)	163.9 (7)
Al1—O14—Al7^xxvi	158.0 (8)	152.1 (7)	163.9 (7)
Si7^xxvi—O14—Al7^xxvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca2^xxxi—O15—Na2^xxxi	15.5 (8)	3.1 (2)	28.9 (3)
Ca2^xxxi—O15—Si6ⁱⁱ	101.1 (6)	95.1 (4)	107.0 (4)
Ca2^xxxi—O15—Al6ⁱⁱ	101.1 (6)	95.1 (4)	107.0 (4)
Ca2^xxxi—O15—Si7^ix	124.5 (8)	117.5 (6)	131.3 (7)
Ca2^xxxi—O15—Al7^ix	124.5 (8)	117.5 (6)	131.3 (7)
Na2^xxxi—O15—Si6ⁱⁱ	93.8 (4)	90.7 (4)	96.9 (4)
Na2^xxxi—O15—Al6ⁱⁱ	93.8 (4)	90.7 (4)	96.9 (4)
Na2^xxxi—O15—Si7^ix	130.7 (6)	127.7 (6)	133.6 (6)
Na2^xxxi—O15—Al7^ix	130.7 (6)	127.7 (6)	133.6 (6)
Si6ⁱⁱ—O15—Al6ⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si6ⁱⁱ—O15—Si7^ix	134.2 (8)	131.7 (8)	136.7 (8)
Si6ⁱⁱ—O15—Al7^ix	134.2 (8)	131.7 (8)	136.7 (8)
Al6ⁱⁱ—O15—Si7^ix	134.2 (8)	131.7 (8)	136.7 (8)
Al6ⁱⁱ—O15—Al7^ix	134.2 (8)	131.7 (8)	136.7 (8)
Si7^ix—O15—Al7^ix	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O16—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O16—Si3	130 (110)	128 (6)	140 (40)
Si1—O16—Al3	130 (110)	128 (6)	140 (40)
Al1—O16—Si3	130 (110)	128 (6)	140 (40)
Al1—O16—Al3	130 (110)	128 (6)	140 (40)
Si3—O16—Al3	0.0 (5)	0.0 (5)	0.0 (5)

Symmetry codes: (i) x₁−1/2, x₂+1/2, x₃, x₄+1/2; (ii) x₁−1/2, x₂+1/2, x₃−1/2, x₄; (iii) x₁, x₂+1, x₃−1/2, x₄+1/2; (iv) x₁+1/2, x₂+1/2, x₃+1/2, x₄; (v) x₁+1/2, x₂+1/2, x₃+1, x₄+1/2; (vi) x₁+1, x₂+1, x₃+1/2, x₄+1/2; (vii) x₁+1, x₂+1, x₃+1, x₄; (viii) x₁+1, x₂, x₃+1/2, x₄+1/2; (ix) x₁−1, x₂, x₃, x₄; (x) x₁, x₂−1, x₃, x₄; (xi) x₁+1, x₂, x₃, x₄; (xii) x₁+1/2, x₂+1/2, x₃, x₄+1/2; (xiii) x₁+1/2, x₂+1/2, x₃−1/2, x₄; (xiv) x₁, x₂, x₃+1, x₄; (xv) x₁, x₂, x₃+1/2, x₄+1/2; (xvi) x₁+1/2, x₂−1/2, x₃+1/2, x₄; (xvii) x₁−1, x₂, x₃−1, x₄; (xviii) x₁, x₂+1, x₃, x₄; (xix) x₁−1/2, x₂+1/2, x₃−1, x₄+1/2; (xx) x₁+1, x₂, x₃+1, x₄; (xxi) x₁, x₂+1, x₃+1, x₄; (xxii) x₁, x₂+1, x₃+1/2, x₄+1/2; (xxiii) x₁+1/2, x₂−1/2, x₃, x₄+1/2; (xxiv) x₁−1/2, x₂−1/2, x₃−1, x₄+1/2; (xxv) x₁, x₂, x₃−1, x₄; (xxvi) x₁−1/2, x₂−1/2, x₃, x₄+1/2; (xxvii) x₁−1/2, x₂−1/2, x₃−1/2, x₄; (xxviii) x₁, x₂−1, x₃−1, x₄; (xxix) x₁, x₂−1, x₃−1/2, x₄+1/2; (xxx) x₁−1/2, x₂−1/2, x₃+1/2, x₄; (xxxi) x₁−1, x₂, x₃−1/2, x₄+1/2; (xxxii) x₁+1/2, x₂−1/2, x₃+1, x₄+1/2; (xxxiii) x₁, x₂, x₃−1/2, x₄+1/2; (xxxiv) x₁, x₂−1, x₃+1/2, x₄+1/2; (xxxv) x₁−1, x₂−1, x₃−1/2, x₄+1/2; (xxxvi) x₁−1, x₂−1, x₃−1, x₄.

(IV) top

Crystal data top

Al_1.372Ca_0.476Na_0.524O₈Si_2.628	Z = 8
M_r = 269.9	F(000) = 1068
Triclinic, X1(αβγ)0†	D_x = 2.690 Mg m⁻³
q = 0.070000a* + 0.044000b* + -0.241000c*	Mo Kα radiation, λ = 0.71073 Å
a = 8.1590 (9) Å	Cell parameters from 4618 reflections
b = 12.8579 (12) Å	θ = 3.2–28.4°
c = 14.1875 (19) Å	µ = 1.24 mm⁻¹
α = 93.369 (9)°	T = 293 K
β = 116.229 (12)°	Irregular, colourless
γ = 89.691 (8)°	0.18 × 0.10 × 0.05 mm
V = 1332.5 (3) Å³

† Symmetry operations: (1) x₁, x₂, x₃, x₄; (2) −x₁, −x₂+1/2, −x₃, −x₄; (3) x₁, x₂, x₃+1/2, x₄+1/2; (4) −x₁, −x₂+1/2, −x₃+1/2, −x₄+1/2; (5) x₁+1/2, x₂+1/2, x₃, x₄+1/2; (6) −x₁+1/2, −x₂, −x₃, −x₄+1/2; (7) x₁+1/2, x₂+1/2, x₃+1/2, x₄; (8) −x₁+1/2, −x₂, −x₃+1/2, −x₄.

Data collection top

Oxford Diffraction CCD diffractometer	4628 independent reflections
Radiation source: X-ray tube	2951 reflections with I > 3σ(I)
Graphite monochromator	R_int = 0.022
Detector resolution: 16.1500 pixels mm^-1	θ_max = 28.9°, θ_min = 3.2°
ω scans	h = −10→10
Absorption correction: analytical CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)	k = −17→17
T_min = 0.837, T_max = 0.948	l = −17→19
13172 measured reflections

Refinement top

Refinement on F²	0 restraints
R[F² > 2σ(F²)] = 0.061	116 constraints
wR(F²) = 0.156	Weighting scheme based on measured s.u.'s w = 1/(σ²(I) + 0.0004I²)
S = 2.22	(Δ/σ)_max = 0.039
4628 reflections	Δρ_max = 3.39 e Å⁻³
351 parameters	Δρ_min = −2.00 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ca	0.5196 (3)	0.02526 (16)	0.05231 (16)	0.0200 (6)	0.4327
Na	0.5177 (4)	0.9812 (2)	0.0833 (2)	0.0200 (6)	0.5673
Si1	0.25320 (11)	0.81789 (6)	0.11597 (6)	0.0110 (3)	0.7286
Na1	0.25320 (11)	0.81789 (6)	0.11597 (6)	0.0110 (3)	0.2714
Si2	0.93210 (11)	0.87972 (6)	0.17847 (6)	0.0106 (3)	0.7155
Na2	0.93210 (11)	0.87972 (6)	0.17847 (6)	0.0106 (3)	0.2845
Si3	0.56340 (11)	0.89036 (6)	0.34148 (7)	0.0107 (3)	0.778
Na3	0.56340 (11)	0.89036 (6)	0.34148 (7)	0.0107 (3)	0.222
Si4	0.24353 (11)	0.83471 (7)	0.89314 (7)	0.0112 (3)	0.4062
Na4	0.24353 (11)	0.83471 (7)	0.89314 (7)	0.0112 (3)	0.5938
O1	0.6664 (3)	0.00642 (15)	0.36062 (16)	0.0145 (8)
O2	0.4394 (3)	0.86730 (17)	0.21580 (17)	0.0208 (8)
O3	0.2472 (3)	0.87066 (17)	0.01120 (16)	0.0200 (9)
O4	0.0512 (3)	0.89142 (16)	0.30762 (16)	0.0190 (8)
O5	0.4377 (3)	0.89321 (17)	0.40501 (17)	0.0191 (9)
O6	0.2356 (3)	0.70602 (17)	0.86072 (17)	0.0188 (8)
O7	0.2665 (3)	0.68959 (17)	0.10897 (17)	0.0195 (8)
O8	0.0669 (3)	0.85319 (18)	0.12290 (19)	0.0249 (10)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ca	0.0118 (5)	0.0242 (9)	0.0200 (9)	0.0008 (6)	0.0045 (6)	−0.0073 (6)
Na	0.0118 (5)	0.0242 (9)	0.0200 (9)	0.0008 (6)	0.0045 (6)	−0.0073 (6)
Si1	0.0117 (4)	0.0131 (4)	0.0082 (4)	0.0034 (3)	0.0045 (3)	0.0007 (3)
Na1	0.0117 (4)	0.0131 (4)	0.0082 (4)	0.0034 (3)	0.0045 (3)	0.0007 (3)
Si2	0.0111 (4)	0.0100 (4)	0.0105 (4)	0.0005 (3)	0.0044 (3)	0.0016 (3)
Na2	0.0111 (4)	0.0100 (4)	0.0105 (4)	0.0005 (3)	0.0044 (3)	0.0016 (3)
Si3	0.0110 (4)	0.0093 (4)	0.0107 (4)	0.0003 (3)	0.0039 (3)	0.0004 (3)
Na3	0.0110 (4)	0.0093 (4)	0.0107 (4)	0.0003 (3)	0.0039 (3)	0.0004 (3)
Si4	0.0121 (4)	0.0132 (4)	0.0090 (4)	−0.0021 (3)	0.0051 (3)	0.0011 (3)
Na4	0.0121 (4)	0.0132 (4)	0.0090 (4)	−0.0021 (3)	0.0051 (3)	0.0011 (3)
O1	0.0154 (11)	0.0117 (10)	0.0149 (11)	−0.0003 (8)	0.0050 (9)	0.0027 (9)
O2	0.0188 (11)	0.0211 (12)	0.0141 (11)	0.0011 (9)	0.0001 (9)	−0.0019 (9)
O3	0.0271 (12)	0.0238 (12)	0.0120 (11)	0.0018 (10)	0.0111 (10)	0.0024 (10)
O4	0.0186 (11)	0.0203 (12)	0.0133 (11)	0.0016 (9)	0.0026 (9)	0.0022 (9)
O5	0.0202 (11)	0.0190 (11)	0.0210 (12)	−0.0025 (9)	0.0119 (10)	−0.0005 (10)
O6	0.0177 (11)	0.0197 (11)	0.0184 (12)	−0.0032 (9)	0.0074 (10)	0.0014 (10)
O7	0.0191 (11)	0.0180 (11)	0.0165 (12)	0.0057 (9)	0.0040 (10)	−0.0024 (9)
O8	0.0202 (12)	0.0259 (13)	0.0331 (14)	0.0034 (10)	0.0164 (11)	−0.0019 (11)

Geometric parameters (Å, º) top

	Average	Minimum	Maximum
Ca—O1ⁱ	2.350 (5)	2.289 (5)	2.415 (6)
Ca—O3ⁱⁱ	2.392 (5)	2.330 (5)	2.454 (5)
Ca—O4ⁱⁱⁱ	2.488 (6)	2.459 (6)	2.517 (6)
Ca—O5^iv	2.462 (5)	2.437 (5)	2.488 (5)
Ca—O7^v	2.753 (5)	2.528 (5)	2.986 (5)
Na—O1^vi	2.350 (7)	2.322 (7)	2.378 (7)
Na—O3	2.411 (6)	2.354 (6)	2.465 (6)
Na—O4^vii	2.422 (7)	2.405 (7)	2.441 (7)
Na—O5^viii	2.517 (6)	2.494 (6)	2.537 (6)
Si1—O2	1.649 (4)	1.613 (3)	1.686 (4)
Si1—O3	1.652 (4)	1.608 (4)	1.696 (4)
Si1—O7	1.654 (4)	1.603 (4)	1.703 (4)
Si1—O8	1.629 (5)	1.587 (5)	1.667 (5)
Si2—O1^vi	1.669 (3)	1.627 (3)	1.712 (3)
Si2—O4^ix	1.650 (4)	1.606 (4)	1.693 (4)
Si2—O6^x	1.634 (4)	1.592 (4)	1.676 (4)
Si2—O8^ix	1.638 (5)	1.594 (5)	1.682 (5)
Si3—O1^xi	1.665 (3)	1.636 (3)	1.693 (3)
Si3—O2	1.624 (4)	1.593 (4)	1.655 (4)
Si3—O5	1.639 (5)	1.595 (5)	1.678 (5)
Si3—O7^xii	1.641 (4)	1.608 (4)	1.670 (4)
Si4—O3^xiii	1.699 (4)	1.649 (4)	1.749 (4)
Si4—O4^xiv	1.696 (4)	1.646 (4)	1.746 (4)
Si4—O5^xiv	1.693 (4)	1.644 (4)	1.743 (5)
Si4—O6	1.685 (4)	1.646 (4)	1.724 (4)

Ca^xv—Ca—Na^xvi	78.1 (4)	76.8 (5)	79.3 (4)
Ca^xv—Ca—Naⁱⁱ	10.66 (9)	8.54 (10)	12.74 (9)
Ca^xv—Ca—Si1ⁱⁱ	62.76 (7)	61.74 (7)	63.77 (7)
Ca^xv—Ca—Na1^xvi	48.78 (7)	48.37 (7)	49.19 (7)
Ca^xv—Ca—Na1ⁱⁱ	62.76 (7)	61.74 (7)	63.77 (7)
Ca^xv—Ca—Si2^xvi	137.12 (11)	135.32 (11)	139.00 (12)
Ca^xv—Ca—Na2^xvi	137.12 (11)	135.32 (11)	139.00 (12)
Ca^xv—Ca—Na2^xvii	104.75 (9)	104.38 (9)	105.10 (9)
Ca^xv—Ca—Na2^vi	91.09 (10)	90.35 (10)	91.84 (11)
Ca^xv—Ca—Si3^iv	97.35 (9)	96.38 (8)	98.32 (9)
Ca^xv—Ca—Si3^vi	168.03 (12)	166.28 (13)	169.62 (14)
Ca^xv—Ca—Na3^iv	97.35 (9)	96.38 (8)	98.32 (9)
Ca^xv—Ca—Na3^vi	168.03 (12)	166.28 (13)	169.62 (14)
Ca^xv—Ca—Si4^xviii	49.12 (7)	47.74 (7)	50.52 (7)
Ca^xv—Ca—Si4^xix	53.90 (7)	53.40 (7)	54.40 (7)
Ca^xv—Ca—Na4^xviii	49.12 (7)	47.74 (7)	50.52 (7)
Ca^xv—Ca—Na4^xix	53.90 (7)	53.40 (7)	54.40 (7)
Ca^xv—Ca—O1ⁱ	158.12 (17)	154.48 (17)	161.86 (18)
Ca^xv—Ca—O3ⁱⁱ	43.86 (11)	42.77 (11)	44.93 (11)
Ca^xv—Ca—O4ⁱⁱⁱ	75.36 (12)	73.88 (12)	76.86 (12)
Ca^xv—Ca—O5^iv	75.60 (12)	73.47 (12)	77.71 (12)
Ca^xv—Ca—O7^v	139.36 (14)	137.83 (13)	140.94 (15)
Na^xvi—Ca—Naⁱⁱ	88.7 (4)	87.7 (4)	90.0 (4)
Na^xvi—Ca—Si1ⁱⁱ	140.7 (5)	139.4 (6)	141.7 (4)
Na^xvi—Ca—Na1^xvi	29.6 (4)	28.3 (5)	30.8 (3)
Na^xvi—Ca—Na1ⁱⁱ	140.7 (5)	139.4 (6)	141.7 (4)
Na^xvi—Ca—Si2^xvi	62.4 (4)	61.3 (4)	63.6 (6)
Na^xvi—Ca—Na2^xvi	62.4 (4)	61.3 (4)	63.6 (6)
Na^xvi—Ca—Na2^xvii	149.3 (6)	148.0 (5)	150.8 (7)
Na^xvi—Ca—Na2^vi	68.4 (5)	65.3 (6)	71.1 (4)
Na^xvi—Ca—Si3^iv	100.9 (5)	99.6 (4)	102.3 (6)
Na^xvi—Ca—Si3^vi	105.7 (4)	104.1 (5)	107.4 (3)
Na^xvi—Ca—Na3^iv	100.9 (5)	99.6 (4)	102.3 (6)
Na^xvi—Ca—Na3^vi	105.7 (4)	104.1 (5)	107.4 (3)
Na^xvi—Ca—Si4^xviii	70.0 (4)	68.9 (3)	71.4 (5)
Na^xvi—Ca—Si4^xix	95.7 (6)	92.2 (7)	98.7 (5)
Na^xvi—Ca—Na4^xviii	70.0 (4)	68.9 (3)	71.4 (5)
Na^xvi—Ca—Na4^xix	95.7 (6)	92.2 (7)	98.7 (5)
Na^xvi—Ca—O1ⁱ	80.7 (4)	78.9 (5)	82.6 (4)
Na^xvi—Ca—O3ⁱⁱ	115.2 (5)	112.7 (6)	117.3 (5)
Na^xvi—Ca—O4ⁱⁱⁱ	75.9 (5)	73.2 (7)	78.2 (5)
Na^xvi—Ca—O5^iv	85.6 (5)	83.6 (4)	88.1 (6)
Na^xvi—Ca—O7^v	129.1 (4)	125.5 (5)	132.4 (3)
Naⁱⁱ—Ca—Si1ⁱⁱ	52.13 (9)	50.92 (10)	53.38 (10)
Naⁱⁱ—Ca—Na1^xvi	59.42 (10)	57.16 (10)	61.63 (10)
Naⁱⁱ—Ca—Na1ⁱⁱ	52.13 (9)	50.92 (10)	53.38 (10)
Naⁱⁱ—Ca—Si2^xvi	146.79 (13)	146.35 (12)	147.19 (12)
Naⁱⁱ—Ca—Na2^xvi	146.79 (13)	146.35 (12)	147.19 (12)
Naⁱⁱ—Ca—Na2^xvii	95.67 (11)	94.66 (11)	96.76 (11)
Naⁱⁱ—Ca—Na2^vi	95.06 (12)	94.72 (13)	95.42 (13)
Naⁱⁱ—Ca—Si3^iv	95.55 (11)	94.71 (10)	96.33 (10)
Naⁱⁱ—Ca—Si3^vi	161.54 (13)	160.62 (13)	162.45 (13)
Naⁱⁱ—Ca—Na3^iv	95.55 (11)	94.71 (10)	96.33 (10)
Naⁱⁱ—Ca—Na3^vi	161.54 (13)	160.62 (13)	162.45 (13)
Naⁱⁱ—Ca—Si4^xviii	52.90 (9)	52.16 (9)	53.60 (9)
Naⁱⁱ—Ca—Si4^xix	51.60 (9)	50.48 (9)	52.77 (10)
Naⁱⁱ—Ca—Na4^xviii	52.90 (9)	52.16 (9)	53.60 (9)
Naⁱⁱ—Ca—Na4^xix	51.60 (9)	50.48 (9)	52.77 (10)
Naⁱⁱ—Ca—O1ⁱ	168.30 (17)	166.36 (17)	170.32 (18)
Naⁱⁱ—Ca—O3ⁱⁱ	35.17 (12)	34.29 (12)	36.07 (12)
Naⁱⁱ—Ca—O4ⁱⁱⁱ	77.69 (14)	76.36 (13)	79.07 (14)
Naⁱⁱ—Ca—O5^iv	76.21 (13)	74.36 (13)	78.01 (13)
Naⁱⁱ—Ca—O7^v	130.99 (14)	129.76 (14)	132.07 (14)
Si1ⁱⁱ—Ca—Na1^xvi	111.55 (9)	110.51 (9)	112.56 (9)
Si1ⁱⁱ—Ca—Na1ⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si1ⁱⁱ—Ca—Si2^xvi	155.18 (14)	155.11 (15)	155.24 (14)
Si1ⁱⁱ—Ca—Na2^xvi	155.18 (14)	155.11 (15)	155.24 (14)
Si1ⁱⁱ—Ca—Na2^xvii	53.97 (7)	53.17 (7)	54.79 (7)
Si1ⁱⁱ—Ca—Na2^vi	107.26 (10)	106.80 (10)	107.72 (10)
Si1ⁱⁱ—Ca—Si3^iv	87.92 (9)	86.62 (9)	89.19 (9)
Si1ⁱⁱ—Ca—Si3^vi	112.05 (11)	110.13 (11)	113.96 (12)
Si1ⁱⁱ—Ca—Na3^iv	87.92 (9)	86.62 (9)	89.19 (9)
Si1ⁱⁱ—Ca—Na3^vi	112.05 (11)	110.13 (11)	113.96 (12)
Si1ⁱⁱ—Ca—Si4^xviii	85.80 (7)	85.73 (7)	85.88 (7)
Si1ⁱⁱ—Ca—Si4^xix	59.26 (7)	58.57 (7)	59.95 (7)
Si1ⁱⁱ—Ca—Na4^xviii	85.80 (7)	85.73 (7)	85.88 (7)
Si1ⁱⁱ—Ca—Na4^xix	59.26 (7)	58.57 (7)	59.95 (7)
Si1ⁱⁱ—Ca—O1ⁱ	138.66 (18)	136.10 (18)	141.03 (18)
Si1ⁱⁱ—Ca—O3ⁱⁱ	29.37 (12)	28.25 (12)	30.48 (11)
Si1ⁱⁱ—Ca—O4ⁱⁱⁱ	90.42 (12)	89.93 (12)	90.93 (13)
Si1ⁱⁱ—Ca—O5^iv	87.77 (12)	87.40 (11)	88.13 (11)
Si1ⁱⁱ—Ca—O7^v	83.89 (11)	81.66 (11)	86.27 (12)
Na1^xvi—Ca—Na1ⁱⁱ	111.55 (9)	110.51 (9)	112.56 (9)
Na1^xvi—Ca—Si2^xvi	89.92 (8)	88.13 (8)	91.78 (9)
Na1^xvi—Ca—Na2^xvi	89.92 (8)	88.13 (8)	91.78 (9)
Na1^xvi—Ca—Na2^xvii	139.82 (9)	138.45 (9)	141.14 (9)
Na1^xvi—Ca—Na2^vi	76.65 (8)	75.86 (8)	77.44 (8)
Na1^xvi—Ca—Si3^iv	99.48 (8)	97.15 (8)	101.88 (9)
Na1^xvi—Ca—Si3^vi	134.90 (10)	132.48 (10)	137.30 (10)
Na1^xvi—Ca—Na3^iv	99.48 (8)	97.15 (8)	101.88 (9)
Na1^xvi—Ca—Na3^vi	134.90 (10)	132.48 (10)	137.30 (10)
Na1^xvi—Ca—Si4^xviii	51.50 (6)	50.69 (6)	52.33 (6)
Na1^xvi—Ca—Si4^xix	79.41 (9)	78.88 (9)	79.93 (9)
Na1^xvi—Ca—Na4^xviii	51.50 (6)	50.69 (6)	52.33 (6)
Na1^xvi—Ca—Na4^xix	79.41 (9)	78.88 (9)	79.93 (9)
Na1^xvi—Ca—O1ⁱ	109.59 (14)	106.00 (14)	113.31 (15)
Na1^xvi—Ca—O3ⁱⁱ	89.03 (14)	88.26 (14)	89.76 (14)
Na1^xvi—Ca—O4ⁱⁱⁱ	74.32 (13)	73.19 (12)	75.44 (13)
Na1^xvi—Ca—O5^iv	76.88 (13)	74.98 (13)	78.77 (13)
Na1^xvi—Ca—O7^v	152.14 (15)	149.46 (16)	154.61 (15)
Na1ⁱⁱ—Ca—Si2^xvi	155.18 (14)	155.11 (15)	155.24 (14)
Na1ⁱⁱ—Ca—Na2^xvi	155.18 (14)	155.11 (15)	155.24 (14)
Na1ⁱⁱ—Ca—Na2^xvii	53.97 (7)	53.17 (7)	54.79 (7)
Na1ⁱⁱ—Ca—Na2^vi	107.26 (10)	106.80 (10)	107.72 (10)
Na1ⁱⁱ—Ca—Si3^iv	87.92 (9)	86.62 (9)	89.19 (9)
Na1ⁱⁱ—Ca—Si3^vi	112.05 (11)	110.13 (11)	113.96 (12)
Na1ⁱⁱ—Ca—Na3^iv	87.92 (9)	86.62 (9)	89.19 (9)
Na1ⁱⁱ—Ca—Na3^vi	112.05 (11)	110.13 (11)	113.96 (12)
Na1ⁱⁱ—Ca—Si4^xviii	85.80 (7)	85.73 (7)	85.88 (7)
Na1ⁱⁱ—Ca—Si4^xix	59.26 (7)	58.57 (7)	59.95 (7)
Na1ⁱⁱ—Ca—Na4^xviii	85.80 (7)	85.73 (7)	85.88 (7)
Na1ⁱⁱ—Ca—Na4^xix	59.26 (7)	58.57 (7)	59.95 (7)
Na1ⁱⁱ—Ca—O1ⁱ	138.66 (18)	136.10 (18)	141.03 (18)
Na1ⁱⁱ—Ca—O3ⁱⁱ	29.37 (12)	28.25 (12)	30.48 (11)
Na1ⁱⁱ—Ca—O4ⁱⁱⁱ	90.42 (12)	89.93 (12)	90.93 (13)
Na1ⁱⁱ—Ca—O5^iv	87.77 (12)	87.40 (11)	88.13 (11)
Na1ⁱⁱ—Ca—O7^v	83.89 (11)	81.66 (11)	86.27 (12)
Si2^xvi—Ca—Na2^xvi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xvi—Ca—Na2^xvii	101.62 (10)	100.67 (10)	102.48 (11)
Si2^xvi—Ca—Na2^vi	89.18 (7)	87.84 (8)	90.46 (7)
Si2^xvi—Ca—Si3^iv	75.96 (8)	73.92 (8)	78.07 (9)
Si2^xvi—Ca—Si3^vi	51.47 (5)	50.77 (5)	52.11 (5)
Si2^xvi—Ca—Na3^iv	75.96 (8)	73.92 (8)	78.07 (9)
Si2^xvi—Ca—Na3^vi	51.47 (5)	50.77 (5)	52.11 (5)
Si2^xvi—Ca—Si4^xviii	99.14 (9)	97.74 (9)	100.63 (9)
Si2^xvi—Ca—Si4^xix	140.71 (12)	139.94 (12)	141.43 (12)
Si2^xvi—Ca—Na4^xviii	99.14 (9)	97.74 (9)	100.63 (9)
Si2^xvi—Ca—Na4^xix	140.71 (12)	139.94 (12)	141.43 (12)
Si2^xvi—Ca—O1ⁱ	21.60 (9)	19.50 (9)	23.78 (9)
Si2^xvi—Ca—O3ⁱⁱ	173.29 (17)	172.51 (17)	174.16 (17)
Si2^xvi—Ca—O4ⁱⁱⁱ	107.88 (12)	106.13 (12)	109.56 (12)
Si2^xvi—Ca—O5^iv	85.15 (12)	83.17 (12)	87.23 (12)
Si2^xvi—Ca—O7^v	82.04 (10)	81.38 (10)	82.87 (10)
Na2^xvi—Ca—Na2^xvii	101.62 (10)	100.67 (10)	102.48 (11)
Na2^xvi—Ca—Na2^vi	89.18 (7)	87.84 (8)	90.46 (7)
Na2^xvi—Ca—Si3^iv	75.96 (8)	73.92 (8)	78.07 (9)
Na2^xvi—Ca—Si3^vi	51.47 (5)	50.77 (5)	52.11 (5)
Na2^xvi—Ca—Na3^iv	75.96 (8)	73.92 (8)	78.07 (9)
Na2^xvi—Ca—Na3^vi	51.47 (5)	50.77 (5)	52.11 (5)
Na2^xvi—Ca—Si4^xviii	99.14 (9)	97.74 (9)	100.63 (9)
Na2^xvi—Ca—Si4^xix	140.71 (12)	139.94 (12)	141.43 (12)
Na2^xvi—Ca—Na4^xviii	99.14 (9)	97.74 (9)	100.63 (9)
Na2^xvi—Ca—Na4^xix	140.71 (12)	139.94 (12)	141.43 (12)
Na2^xvi—Ca—O1ⁱ	21.60 (9)	19.50 (9)	23.78 (9)
Na2^xvi—Ca—O3ⁱⁱ	173.29 (17)	172.51 (17)	174.16 (17)
Na2^xvi—Ca—O4ⁱⁱⁱ	107.88 (12)	106.13 (12)	109.56 (12)
Na2^xvi—Ca—O5^iv	85.15 (12)	83.17 (12)	87.23 (12)
Na2^xvi—Ca—O7^v	82.04 (10)	81.38 (10)	82.87 (10)
Na2^xvii—Ca—Na2^vi	140.86 (10)	138.28 (10)	143.42 (10)
Na2^xvii—Ca—Si3^iv	48.46 (6)	48.29 (6)	48.62 (6)
Na2^xvii—Ca—Si3^vi	77.91 (9)	76.21 (9)	79.54 (10)
Na2^xvii—Ca—Na3^iv	48.46 (6)	48.29 (6)	48.62 (6)
Na2^xvii—Ca—Na3^vi	77.91 (9)	76.21 (9)	79.54 (10)
Na2^xvii—Ca—Si4^xviii	88.54 (9)	87.62 (9)	89.47 (9)
Na2^xvii—Ca—Si4^xix	110.84 (10)	108.65 (10)	113.00 (10)
Na2^xvii—Ca—Na4^xviii	88.54 (9)	87.62 (9)	89.47 (9)
Na2^xvii—Ca—Na4^xix	110.84 (10)	108.65 (10)	113.00 (10)
Na2^xvii—Ca—O1ⁱ	91.16 (16)	90.28 (16)	91.90 (16)
Na2^xvii—Ca—O3ⁱⁱ	83.34 (14)	81.43 (15)	85.26 (14)
Na2^xvii—Ca—O4ⁱⁱⁱ	134.74 (14)	132.78 (14)	136.68 (14)
Na2^xvii—Ca—O5^iv	66.17 (13)	64.73 (13)	67.60 (13)
Na2^xvii—Ca—O7^v	67.98 (12)	64.12 (11)	71.96 (13)
Na2^vi—Ca—Si3^iv	164.64 (10)	163.31 (10)	165.84 (10)
Na2^vi—Ca—Si3^vi	80.13 (7)	79.43 (7)	80.81 (7)
Na2^vi—Ca—Na3^iv	164.64 (10)	163.31 (10)	165.84 (10)
Na2^vi—Ca—Na3^vi	80.13 (7)	79.43 (7)	80.81 (7)
Na2^vi—Ca—Si4^xviii	127.13 (12)	125.28 (12)	128.98 (12)
Na2^vi—Ca—Si4^xix	51.65 (7)	51.16 (7)	52.15 (7)
Na2^vi—Ca—Na4^xviii	127.13 (12)	125.28 (12)	128.98 (12)
Na2^vi—Ca—Na4^xix	51.65 (7)	51.16 (7)	52.15 (7)
Na2^vi—Ca—O1ⁱ	85.41 (13)	83.65 (13)	87.10 (13)
Na2^vi—Ca—O3ⁱⁱ	84.18 (14)	82.85 (14)	85.56 (15)
Na2^vi—Ca—O4ⁱⁱⁱ	18.97 (7)	17.95 (7)	19.96 (7)
Na2^vi—Ca—O5^iv	152.88 (17)	150.50 (17)	155.22 (17)
Na2^vi—Ca—O7^v	76.66 (12)	74.96 (13)	78.26 (11)
Si3^iv—Ca—Si3^vi	92.97 (10)	92.07 (10)	93.97 (10)
Si3^iv—Ca—Na3^iv	0.0 (5)	0.0 (5)	0.0 (5)
Si3^iv—Ca—Na3^vi	92.97 (10)	92.07 (10)	93.97 (10)
Si3^iv—Ca—Si4^xviii	53.79 (6)	53.29 (7)	54.35 (7)
Si3^iv—Ca—Si4^xix	142.76 (9)	141.83 (10)	143.75 (9)
Si3^iv—Ca—Na4^xviii	53.79 (6)	53.29 (7)	54.35 (7)
Si3^iv—Ca—Na4^xix	142.76 (9)	141.83 (10)	143.75 (9)
Si3^iv—Ca—O1ⁱ	81.96 (14)	79.91 (14)	84.01 (15)
Si3^iv—Ca—O3ⁱⁱ	110.68 (14)	108.58 (15)	112.71 (14)
Si3^iv—Ca—O4ⁱⁱⁱ	172.40 (14)	169.64 (14)	175.17 (13)
Si3^iv—Ca—O5^iv	24.44 (11)	23.12 (11)	25.73 (11)
Si3^iv—Ca—O7^v	104.21 (15)	100.77 (15)	107.62 (17)
Si3^vi—Ca—Na3^iv	92.97 (10)	92.07 (10)	93.97 (10)
Si3^vi—Ca—Na3^vi	0.0 (5)	0.0 (5)	0.0 (5)
Si3^vi—Ca—Si4^xviii	142.72 (13)	141.54 (13)	143.96 (13)
Si3^vi—Ca—Si4^xix	114.22 (10)	112.32 (10)	116.07 (11)
Si3^vi—Ca—Na4^xviii	142.72 (13)	141.54 (13)	143.96 (13)
Si3^vi—Ca—Na4^xix	114.22 (10)	112.32 (10)	116.07 (11)
Si3^vi—Ca—O1ⁱ	29.89 (9)	28.20 (9)	31.44 (9)
Si3^vi—Ca—O3ⁱⁱ	126.39 (15)	124.69 (15)	128.09 (15)
Si3^vi—Ca—O4ⁱⁱⁱ	94.44 (11)	92.72 (11)	96.13 (11)
Si3^vi—Ca—O5^iv	115.63 (16)	113.54 (16)	117.83 (16)
Si3^vi—Ca—O7^v	30.60 (8)	29.89 (7)	31.35 (8)
Na3^iv—Ca—Na3^vi	92.97 (10)	92.07 (10)	93.97 (10)
Na3^iv—Ca—Si4^xviii	53.79 (6)	53.29 (7)	54.35 (7)
Na3^iv—Ca—Si4^xix	142.76 (9)	141.83 (10)	143.75 (9)
Na3^iv—Ca—Na4^xviii	53.79 (6)	53.29 (7)	54.35 (7)
Na3^iv—Ca—Na4^xix	142.76 (9)	141.83 (10)	143.75 (9)
Na3^iv—Ca—O1ⁱ	81.96 (14)	79.91 (14)	84.01 (15)
Na3^iv—Ca—O3ⁱⁱ	110.68 (14)	108.58 (15)	112.71 (14)
Na3^iv—Ca—O4ⁱⁱⁱ	172.40 (14)	169.64 (14)	175.17 (13)
Na3^iv—Ca—O5^iv	24.44 (11)	23.12 (11)	25.73 (11)
Na3^iv—Ca—O7^v	104.21 (15)	100.77 (15)	107.62 (17)
Na3^vi—Ca—Si4^xviii	142.72 (13)	141.54 (13)	143.96 (13)
Na3^vi—Ca—Si4^xix	114.22 (10)	112.32 (10)	116.07 (11)
Na3^vi—Ca—Na4^xviii	142.72 (13)	141.54 (13)	143.96 (13)
Na3^vi—Ca—Na4^xix	114.22 (10)	112.32 (10)	116.07 (11)
Na3^vi—Ca—O1ⁱ	29.89 (9)	28.20 (9)	31.44 (9)
Na3^vi—Ca—O3ⁱⁱ	126.39 (15)	124.69 (15)	128.09 (15)
Na3^vi—Ca—O4ⁱⁱⁱ	94.44 (11)	92.72 (11)	96.13 (11)
Na3^vi—Ca—O5^iv	115.63 (16)	113.54 (16)	117.83 (16)
Na3^vi—Ca—O7^v	30.60 (8)	29.89 (7)	31.35 (8)
Si4^xviii—Ca—Si4^xix	103.02 (9)	101.15 (9)	104.90 (9)
Si4^xviii—Ca—Na4^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si4^xviii—Ca—Na4^xix	103.02 (9)	101.15 (9)	104.90 (9)
Si4^xviii—Ca—O1ⁱ	118.11 (14)	115.22 (14)	121.12 (15)
Si4^xviii—Ca—O3ⁱⁱ	85.31 (11)	84.92 (11)	85.68 (11)
Si4^xviii—Ca—O4ⁱⁱⁱ	118.76 (15)	116.22 (15)	121.33 (15)
Si4^xviii—Ca—O5^iv	29.41 (11)	28.21 (11)	30.57 (10)
Si4^xviii—Ca—O7^v	156.06 (18)	153.09 (17)	159.16 (19)
Si4^xix—Ca—Na4^xviii	103.02 (9)	101.15 (9)	104.90 (9)
Si4^xix—Ca—Na4^xix	0.0 (5)	0.0 (5)	0.0 (5)
Si4^xix—Ca—O1ⁱ	133.76 (15)	130.98 (16)	136.32 (16)
Si4^xix—Ca—O3ⁱⁱ	32.69 (11)	31.69 (11)	33.74 (11)
Si4^xix—Ca—O4ⁱⁱⁱ	32.86 (8)	31.78 (8)	33.96 (9)
Si4^xix—Ca—O5^iv	127.61 (13)	125.25 (13)	129.94 (12)
Si4^xix—Ca—O7^v	90.08 (13)	89.54 (12)	90.63 (14)
Na4^xviii—Ca—Na4^xix	103.02 (9)	101.15 (9)	104.90 (9)
Na4^xviii—Ca—O1ⁱ	118.11 (14)	115.22 (14)	121.12 (15)
Na4^xviii—Ca—O3ⁱⁱ	85.31 (11)	84.92 (11)	85.68 (11)
Na4^xviii—Ca—O4ⁱⁱⁱ	118.76 (15)	116.22 (15)	121.33 (15)
Na4^xviii—Ca—O5^iv	29.41 (11)	28.21 (11)	30.57 (10)
Na4^xviii—Ca—O7^v	156.06 (18)	153.09 (17)	159.16 (19)
Na4^xix—Ca—O1ⁱ	133.76 (15)	130.98 (16)	136.32 (16)
Na4^xix—Ca—O3ⁱⁱ	32.69 (11)	31.69 (11)	33.74 (11)
Na4^xix—Ca—O4ⁱⁱⁱ	32.86 (8)	31.78 (8)	33.96 (9)
Na4^xix—Ca—O5^iv	127.61 (13)	125.25 (13)	129.94 (12)
Na4^xix—Ca—O7^v	90.08 (13)	89.54 (12)	90.63 (14)
O1ⁱ—Ca—O3ⁱⁱ	155.87 (18)	152.77 (19)	158.81 (18)
O1ⁱ—Ca—O4ⁱⁱⁱ	103.96 (16)	101.22 (16)	106.58 (16)
O1ⁱ—Ca—O5^iv	98.14 (17)	95.40 (17)	101.00 (18)
O1ⁱ—Ca—O7^v	60.48 (12)	58.12 (12)	62.71 (13)
O3ⁱⁱ—Ca—O4ⁱⁱⁱ	65.52 (15)	63.41 (15)	67.70 (15)
O3ⁱⁱ—Ca—O5^iv	100.99 (14)	99.77 (15)	102.18 (14)
O3ⁱⁱ—Ca—O7^v	95.90 (15)	94.38 (15)	97.41 (15)
O4ⁱⁱⁱ—Ca—O5^iv	148.2 (2)	144.63 (19)	151.69 (19)
O4ⁱⁱⁱ—Ca—O7^v	82.89 (15)	81.55 (16)	84.26 (15)
O5^iv—Ca—O7^v	128.4 (2)	125.1 (2)	131.7 (2)
Ca^xi—Na—Caⁱⁱ	91.3 (4)	88.1 (3)	94.6 (5)
Ca^xi—Na—Na^xx	80.6 (4)	78.3 (3)	82.9 (5)
Ca^xi—Na—Si1	143.9 (4)	141.0 (4)	146.7 (5)
Ca^xi—Na—Na1	143.9 (4)	141.0 (4)	146.7 (5)
Ca^xi—Na—Na1^xx	32.3 (4)	30.4 (3)	34.6 (5)
Ca^xi—Na—Si2	106.2 (5)	104.1 (4)	107.6 (6)
Ca^xi—Na—Na2	106.2 (5)	104.1 (4)	107.6 (6)
Ca^xi—Na—Na2^xxi	100.5 (5)	95.7 (4)	105.8 (6)
Ca^xi—Na—Si3^xxi	62.6 (4)	59.3 (3)	65.8 (5)
Ca^xi—Na—Na3	148.1 (5)	144.0 (5)	152.5 (6)
Ca^xi—Na—Na3^viii	67.9 (5)	66.3 (4)	68.9 (6)
Ca^xi—Na—Na3^xxi	62.6 (4)	59.3 (3)	65.8 (5)
Ca^xi—Na—Si4^xxii	97.2 (4)	95.5 (4)	98.7 (5)
Ca^xi—Na—Si4^xxiii	71.4 (5)	66.1 (4)	77.1 (6)
Ca^xi—Na—Na4^xxii	97.2 (4)	95.5 (4)	98.7 (5)
Ca^xi—Na—Na4^xxiii	71.4 (5)	66.1 (4)	77.1 (6)
Ca^xi—Na—O1^vi	81.2 (5)	75.8 (4)	86.1 (6)
Ca^xi—Na—O3	117.4 (4)	114.6 (4)	120.0 (5)
Ca^xi—Na—O4^vii	86.8 (5)	81.3 (4)	92.9 (7)
Ca^xi—Na—O5^viii	77.3 (5)	75.7 (4)	78.5 (6)
Caⁱⁱ—Na—Na^xx	10.73 (10)	8.65 (10)	12.80 (10)
Caⁱⁱ—Na—Si1	52.87 (9)	52.78 (9)	52.95 (9)
Caⁱⁱ—Na—Na1	52.87 (9)	52.78 (9)	52.95 (9)
Caⁱⁱ—Na—Na1^xx	59.09 (8)	57.44 (8)	60.73 (9)
Caⁱⁱ—Na—Si2	155.74 (16)	149.91 (16)	161.78 (17)
Caⁱⁱ—Na—Na2	155.74 (16)	149.91 (16)	161.78 (17)
Caⁱⁱ—Na—Na2^xxi	95.54 (15)	95.29 (15)	95.84 (14)
Caⁱⁱ—Na—Si3^xxi	151.57 (16)	145.36 (16)	157.84 (17)
Caⁱⁱ—Na—Na3	94.82 (15)	93.68 (15)	95.93 (15)
Caⁱⁱ—Na—Na3^viii	95.35 (11)	94.37 (11)	96.42 (11)
Caⁱⁱ—Na—Na3^xxi	151.57 (16)	145.36 (16)	157.84 (17)
Caⁱⁱ—Na—Si4^xxii	50.72 (8)	49.34 (8)	52.15 (8)
Caⁱⁱ—Na—Si4^xxiii	54.09 (9)	53.54 (9)	54.64 (9)
Caⁱⁱ—Na—Na4^xxii	50.72 (8)	49.34 (8)	52.15 (8)
Caⁱⁱ—Na—Na4^xxiii	54.09 (9)	53.54 (9)	54.64 (9)
Caⁱⁱ—Na—O1^vi	169.4 (2)	163.8 (2)	173.7 (2)
Caⁱⁱ—Na—O3	34.86 (11)	33.73 (11)	36.02 (12)
Caⁱⁱ—Na—O4^vii	77.67 (15)	76.36 (15)	79.03 (15)
Caⁱⁱ—Na—O5^viii	76.77 (14)	74.80 (13)	78.81 (13)
Na^xx—Na—Si1	63.59 (12)	61.55 (12)	65.59 (12)
Na^xx—Na—Na1	63.59 (12)	61.55 (12)	65.59 (12)
Na^xx—Na—Na1^xx	48.38 (10)	47.61 (10)	49.17 (10)
Na^xx—Na—Si2	162.08 (17)	158.59 (17)	165.51 (18)
Na^xx—Na—Na2	162.08 (17)	158.59 (17)	165.51 (18)
Na^xx—Na—Na2^xxi	97.41 (15)	97.18 (15)	97.57 (15)
Na^xx—Na—Si3^xxi	141.43 (17)	136.57 (17)	146.33 (18)
Na^xx—Na—Na3	103.94 (17)	102.44 (16)	105.47 (16)
Na^xx—Na—Na3^viii	91.38 (13)	89.75 (13)	92.90 (13)
Na^xx—Na—Na3^xxi	141.43 (17)	136.57 (17)	146.33 (18)
Na^xx—Na—Si4^xxii	53.12 (10)	52.07 (10)	54.06 (10)
Na^xx—Na—Si4^xxiii	50.31 (10)	49.28 (10)	51.34 (10)
Na^xx—Na—Na4^xxii	53.12 (10)	52.07 (10)	54.06 (10)
Na^xx—Na—Na4^xxiii	50.31 (10)	49.28 (10)	51.34 (10)
Na^xx—Na—O1^vi	160.9 (3)	154.5 (2)	166.8 (3)
Na^xx—Na—O3	43.65 (13)	42.43 (13)	44.86 (13)
Na^xx—Na—O4^vii	77.21 (16)	75.61 (15)	78.79 (16)
Na^xx—Na—O5^viii	74.64 (15)	72.25 (14)	76.91 (14)
Si1—Na—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—Na—Na1^xx	111.96 (12)	110.37 (12)	113.49 (12)
Si1—Na—Si2	107.22 (15)	101.18 (14)	113.61 (16)
Si1—Na—Na2	107.22 (15)	101.18 (14)	113.61 (16)
Si1—Na—Na2^xxi	87.92 (15)	86.25 (15)	89.57 (16)
Si1—Na—Si3^xxi	152.89 (16)	147.54 (16)	158.00 (16)
Si1—Na—Na3	53.19 (10)	51.60 (9)	54.81 (10)
Si1—Na—Na3^viii	107.74 (13)	104.03 (13)	111.42 (13)
Si1—Na—Na3^xxi	152.89 (16)	147.54 (16)	158.00 (16)
Si1—Na—Si4^xxii	59.22 (9)	57.23 (9)	61.27 (10)
Si1—Na—Si4^xxiii	87.17 (15)	86.71 (15)	87.57 (15)
Si1—Na—Na4^xxii	59.22 (9)	57.23 (9)	61.27 (10)
Si1—Na—Na4^xxiii	87.17 (15)	86.71 (15)	87.57 (15)
Si1—Na—O1^vi	134.0 (2)	125.0 (2)	143.2 (2)
Si1—Na—O3	30.04 (12)	28.50 (11)	31.62 (12)
Si1—Na—O4^vii	88.4 (2)	87.0 (2)	89.7 (2)
Si1—Na—O5^viii	89.42 (16)	86.39 (16)	92.50 (16)
Na1—Na—Na1^xx	111.96 (12)	110.37 (12)	113.49 (12)
Na1—Na—Si2	107.22 (15)	101.18 (14)	113.61 (16)
Na1—Na—Na2	107.22 (15)	101.18 (14)	113.61 (16)
Na1—Na—Na2^xxi	87.92 (15)	86.25 (15)	89.57 (16)
Na1—Na—Si3^xxi	152.89 (16)	147.54 (16)	158.00 (16)
Na1—Na—Na3	53.19 (10)	51.60 (9)	54.81 (10)
Na1—Na—Na3^viii	107.74 (13)	104.03 (13)	111.42 (13)
Na1—Na—Na3^xxi	152.89 (16)	147.54 (16)	158.00 (16)
Na1—Na—Si4^xxii	59.22 (9)	57.23 (9)	61.27 (10)
Na1—Na—Si4^xxiii	87.17 (15)	86.71 (15)	87.57 (15)
Na1—Na—Na4^xxii	59.22 (9)	57.23 (9)	61.27 (10)
Na1—Na—Na4^xxiii	87.17 (15)	86.71 (15)	87.57 (15)
Na1—Na—O1^vi	134.0 (2)	125.0 (2)	143.2 (2)
Na1—Na—O3	30.04 (12)	28.50 (11)	31.62 (12)
Na1—Na—O4^vii	88.4 (2)	87.0 (2)	89.7 (2)
Na1—Na—O5^viii	89.42 (16)	86.39 (16)	92.50 (16)
Na1^xx—Na—Si2	137.58 (19)	133.77 (19)	141.08 (19)
Na1^xx—Na—Na2	137.58 (19)	133.77 (19)	141.08 (19)
Na1^xx—Na—Na2^xxi	99.43 (13)	96.88 (12)	101.94 (13)
Na1^xx—Na—Si3^xxi	93.77 (13)	89.07 (12)	98.57 (14)
Na1^xx—Na—Na3	138.55 (17)	136.46 (17)	140.63 (17)
Na1^xx—Na—Na3^viii	76.68 (11)	73.50 (10)	79.75 (11)
Na1^xx—Na—Na3^xxi	93.77 (13)	89.07 (12)	98.57 (14)
Na1^xx—Na—Si4^xxii	78.77 (10)	76.99 (10)	80.43 (10)
Na1^xx—Na—Si4^xxiii	51.68 (8)	49.22 (8)	54.11 (8)
Na1^xx—Na—Na4^xxii	78.77 (10)	76.99 (10)	80.43 (10)
Na1^xx—Na—Na4^xxiii	51.68 (8)	49.22 (8)	54.11 (8)
Na1^xx—Na—O1^vi	113.5 (2)	106.3 (2)	120.6 (2)
Na1^xx—Na—O3	88.47 (14)	86.87 (14)	89.97 (14)
Na1^xx—Na—O4^vii	78.16 (15)	75.20 (14)	81.06 (15)
Na1^xx—Na—O5^viii	74.53 (14)	71.48 (14)	77.44 (14)
Si2—Na—Na2	0.0 (5)	0.0 (5)	0.0 (5)
Si2—Na—Na2^xxi	97.26 (11)	96.39 (11)	98.07 (11)
Si2—Na—Si3^xxi	51.74 (8)	51.33 (8)	52.07 (7)
Si2—Na—Na3	79.04 (10)	75.98 (10)	82.21 (11)
Si2—Na—Na3^viii	76.56 (12)	74.51 (12)	78.46 (14)
Si2—Na—Na3^xxi	51.74 (8)	51.33 (8)	52.07 (7)
Si2—Na—Si4^xxii	109.19 (16)	105.24 (15)	113.19 (17)
Si2—Na—Si4^xxiii	146.95 (15)	143.73 (15)	149.66 (15)
Si2—Na—Na4^xxii	109.19 (16)	105.24 (15)	113.19 (17)
Si2—Na—Na4^xxiii	146.95 (15)	143.73 (15)	149.66 (15)
Si2—Na—O1^vi	27.78 (10)	24.60 (10)	30.89 (10)
Si2—Na—O3	120.9 (2)	115.66 (19)	126.4 (2)
Si2—Na—O4^vii	118.78 (16)	116.71 (16)	121.00 (16)
Si2—Na—O5^viii	90.55 (18)	87.32 (17)	93.82 (19)
Na2—Na—Na2^xxi	97.26 (11)	96.39 (11)	98.07 (11)
Na2—Na—Si3^xxi	51.74 (8)	51.33 (8)	52.07 (7)
Na2—Na—Na3	79.04 (10)	75.98 (10)	82.21 (11)
Na2—Na—Na3^viii	76.56 (12)	74.51 (12)	78.46 (14)
Na2—Na—Na3^xxi	51.74 (8)	51.33 (8)	52.07 (7)
Na2—Na—Si4^xxii	109.19 (16)	105.24 (15)	113.19 (17)
Na2—Na—Si4^xxiii	146.95 (15)	143.73 (15)	149.66 (15)
Na2—Na—Na4^xxii	109.19 (16)	105.24 (15)	113.19 (17)
Na2—Na—Na4^xxiii	146.95 (15)	143.73 (15)	149.66 (15)
Na2—Na—O1^vi	27.78 (10)	24.60 (10)	30.89 (10)
Na2—Na—O3	120.9 (2)	115.66 (19)	126.4 (2)
Na2—Na—O4^vii	118.78 (16)	116.71 (16)	121.00 (16)
Na2—Na—O5^viii	90.55 (18)	87.32 (17)	93.82 (19)
Na2^xxi—Na—Si3^xxi	79.57 (10)	77.70 (10)	81.36 (10)
Na2^xxi—Na—Na3	47.84 (8)	47.21 (8)	48.43 (8)
Na2^xxi—Na—Na3^viii	163.82 (16)	158.83 (17)	168.19 (16)
Na2^xxi—Na—Na3^xxi	79.57 (10)	77.70 (10)	81.36 (10)
Na2^xxi—Na—Si4^xxii	142.08 (19)	139.4 (2)	144.80 (19)
Na2^xxi—Na—Si4^xxiii	52.86 (9)	52.39 (9)	53.38 (9)
Na2^xxi—Na—Na4^xxii	142.08 (19)	139.4 (2)	144.80 (19)
Na2^xxi—Na—Na4^xxiii	52.86 (9)	52.39 (9)	53.38 (9)
Na2^xxi—Na—O1^vi	90.23 (16)	87.34 (16)	92.92 (16)
Na2^xxi—Na—O3	110.6 (2)	107.5 (2)	113.8 (2)
Na2^xxi—Na—O4^vii	22.79 (9)	21.56 (9)	24.06 (9)
Na2^xxi—Na—O5^viii	171.0 (2)	168.09 (19)	174.45 (19)
Si3^xxi—Na—Na3	101.94 (11)	99.57 (11)	104.10 (11)
Si3^xxi—Na—Na3^viii	85.15 (14)	83.19 (14)	86.84 (15)
Si3^xxi—Na—Na3^xxi	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xxi—Na—Si4^xxii	137.8 (2)	136.1 (2)	139.1 (2)
Si3^xxi—Na—Si4^xxiii	103.58 (13)	98.63 (13)	108.49 (14)
Si3^xxi—Na—Na4^xxii	137.8 (2)	136.1 (2)	139.1 (2)
Si3^xxi—Na—Na4^xxiii	103.58 (13)	98.63 (13)	108.49 (14)
Si3^xxi—Na—O1^vi	24.25 (10)	20.73 (10)	27.50 (10)
Si3^xxi—Na—O3	168.1 (2)	166.4 (2)	169.2 (3)
Si3^xxi—Na—O4^vii	89.07 (15)	85.45 (15)	92.65 (16)
Si3^xxi—Na—O5^viii	105.6 (2)	103.5 (2)	107.6 (2)
Na3—Na—Na3^viii	141.99 (15)	136.11 (15)	148.00 (15)
Na3—Na—Na3^xxi	101.94 (11)	99.57 (11)	104.10 (11)
Na3—Na—Si4^xxii	110.77 (16)	107.14 (15)	114.50 (17)
Na3—Na—Si4^xxiii	87.21 (14)	86.08 (14)	88.40 (14)
Na3—Na—Na4^xxii	110.77 (16)	107.14 (15)	114.50 (17)
Na3—Na—Na4^xxiii	87.21 (14)	86.08 (14)	88.40 (14)
Na3—Na—O1^vi	93.82 (16)	89.36 (16)	98.18 (16)
Na3—Na—O3	83.17 (19)	80.02 (18)	86.4 (2)
Na3—Na—O4^vii	64.22 (16)	62.76 (15)	65.69 (16)
Na3—Na—O5^viii	134.5 (2)	129.2 (2)	139.9 (2)
Na3^viii—Na—Na3^xxi	85.15 (14)	83.19 (14)	86.84 (15)
Na3^viii—Na—Si4^xxii	52.75 (9)	52.40 (9)	53.16 (9)
Na3^viii—Na—Si4^xxiii	127.63 (14)	122.48 (15)	132.59 (14)
Na3^viii—Na—Na4^xxii	52.75 (9)	52.40 (9)	53.16 (9)
Na3^viii—Na—Na4^xxiii	127.63 (14)	122.48 (15)	132.59 (14)
Na3^viii—Na—O1^vi	77.29 (18)	76.60 (18)	77.76 (19)
Na3^viii—Na—O3	84.68 (17)	83.68 (16)	85.81 (17)
Na3^viii—Na—O4^vii	153.7 (2)	147.0 (2)	160.3 (2)
Na3^viii—Na—O5^viii	20.54 (11)	19.85 (11)	21.30 (11)
Na3^xxi—Na—Si4^xxii	137.8 (2)	136.1 (2)	139.1 (2)
Na3^xxi—Na—Si4^xxiii	103.58 (13)	98.63 (13)	108.49 (14)
Na3^xxi—Na—Na4^xxii	137.8 (2)	136.1 (2)	139.1 (2)
Na3^xxi—Na—Na4^xxiii	103.58 (13)	98.63 (13)	108.49 (14)
Na3^xxi—Na—O1^vi	24.25 (10)	20.73 (10)	27.50 (10)
Na3^xxi—Na—O3	168.1 (2)	166.4 (2)	169.2 (3)
Na3^xxi—Na—O4^vii	89.07 (15)	85.45 (15)	92.65 (16)
Na3^xxi—Na—O5^viii	105.6 (2)	103.5 (2)	107.6 (2)
Si4^xxii—Na—Si4^xxiii	103.34 (12)	101.55 (12)	105.21 (12)
Si4^xxii—Na—Na4^xxii	0.0 (5)	0.0 (5)	0.0 (5)
Si4^xxii—Na—Na4^xxiii	103.34 (12)	101.55 (12)	105.21 (12)
Si4^xxii—Na—O1^vi	125.0 (2)	121.6 (2)	127.8 (3)
Si4^xxii—Na—O3	32.14 (12)	31.44 (12)	32.85 (12)
Si4^xxii—Na—O4^vii	128.1 (2)	125.68 (19)	130.9 (2)
Si4^xxii—Na—O5^viii	32.31 (11)	31.41 (11)	33.22 (11)
Si4^xxiii—Na—Na4^xxii	103.34 (12)	101.55 (12)	105.21 (12)
Si4^xxiii—Na—Na4^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Si4^xxiii—Na—O1^vi	126.39 (19)	118.6 (2)	133.7 (2)
Si4^xxiii—Na—O3	86.17 (17)	84.70 (17)	87.71 (18)
Si4^xxiii—Na—O4^vii	30.10 (9)	29.29 (9)	30.95 (9)
Si4^xxiii—Na—O5^viii	119.30 (16)	115.19 (16)	123.30 (16)
Na4^xxii—Na—Na4^xxiii	103.34 (12)	101.55 (12)	105.21 (12)
Na4^xxii—Na—O1^vi	125.0 (2)	121.6 (2)	127.8 (3)
Na4^xxii—Na—O3	32.14 (12)	31.44 (12)	32.85 (12)
Na4^xxii—Na—O4^vii	128.1 (2)	125.68 (19)	130.9 (2)
Na4^xxii—Na—O5^viii	32.31 (11)	31.41 (11)	33.22 (11)
Na4^xxiii—Na—O1^vi	126.39 (19)	118.6 (2)	133.7 (2)
Na4^xxiii—Na—O3	86.17 (17)	84.70 (17)	87.71 (18)
Na4^xxiii—Na—O4^vii	30.10 (9)	29.29 (9)	30.95 (9)
Na4^xxiii—Na—O5^viii	119.30 (16)	115.19 (16)	123.30 (16)
O1^vi—Na—O3	146.8 (3)	139.6 (3)	153.7 (3)
O1^vi—Na—O4^vii	106.1 (2)	100.8 (2)	111.2 (2)
O1^vi—Na—O5^viii	96.6 (2)	94.9 (2)	98.2 (3)
O3—Na—O4^vii	101.8 (2)	99.1 (2)	104.6 (3)
O3—Na—O5^viii	64.39 (17)	62.83 (17)	66.00 (17)
O4^vii—Na—O5^viii	149.3 (2)	144.5 (2)	154.0 (2)
Caⁱⁱ—Si1—Na	74.97 (10)	73.83 (10)	76.16 (11)
Caⁱⁱ—Si1—Na1	0	0	0
Caⁱⁱ—Si1—O2	118.48 (14)	118.12 (14)	118.80 (14)
Caⁱⁱ—Si1—O3	45.22 (15)	42.59 (16)	47.88 (15)
Caⁱⁱ—Si1—O7	130.86 (13)	129.97 (13)	131.75 (12)
Caⁱⁱ—Si1—O8	60.71 (17)	57.13 (17)	64.23 (16)
Na—Si1—Na1	0	0	0
Na—Si1—O2	58.35 (17)	56.34 (17)	60.32 (17)
Na—Si1—O3	46.89 (14)	45.73 (14)	48.03 (14)
Na—Si1—O7	125.88 (19)	124.62 (19)	127.14 (19)
Na—Si1—O8	122.31 (17)	119.91 (18)	124.69 (17)
Na1—Si1—O2	0	0	0
Na1—Si1—O3	0	0	0
Na1—Si1—O7	0	0	0
Na1—Si1—O8	0	0	0
O2—Si1—O3	105.2 (2)	104.3 (2)	106.1 (2)
O2—Si1—O7	109.24 (17)	108.86 (16)	109.69 (17)
O2—Si1—O8	112.7 (2)	112.3 (2)	113.2 (2)
O3—Si1—O7	112.6 (2)	112.4 (2)	112.7 (2)
O3—Si1—O8	105.8 (2)	104.9 (2)	106.7 (2)
O7—Si1—O8	111.1 (2)	109.9 (2)	112.4 (2)
Ca^xi—Na1—Caⁱⁱ	68.47 (8)	67.85 (8)	69.07 (8)
Ca^xi—Na1—Na	6.56 (8)	4.97 (8)	8.24 (9)
Ca^xi—Na1—Na^xx	61.52 (9)	60.54 (9)	62.54 (9)
Ca^xi—Na1—Si1	0	0	0
Ca^xi—Na1—Na2^xxiv	121.44 (7)	118.65 (7)	124.20 (7)
Ca^xi—Na1—Na3	77.52 (6)	76.54 (6)	78.49 (6)
Ca^xi—Na1—Na3^xii	113.72 (8)	112.66 (8)	114.77 (8)
Ca^xi—Na1—Na4^xxii	55.91 (6)	54.62 (6)	57.20 (6)
Ca^xi—Na1—O2	63.73 (16)	62.67 (15)	64.80 (16)
Ca^xi—Na1—O3	41.75 (12)	41.18 (12)	42.24 (12)
Ca^xi—Na1—O7	129.34 (18)	126.61 (18)	132.07 (18)
Ca^xi—Na1—O8	117.64 (16)	113.63 (16)	121.59 (16)
Caⁱⁱ—Na1—Na	74.97 (10)	73.83 (10)	76.16 (11)
Caⁱⁱ—Na1—Na^xx	6.98 (10)	6.00 (11)	7.95 (10)
Caⁱⁱ—Na1—Si1	0	0	0
Caⁱⁱ—Na1—Na2^xxiv	70.95 (8)	69.57 (8)	72.31 (9)
Caⁱⁱ—Na1—Na3	124.38 (7)	123.73 (7)	125.02 (7)
Caⁱⁱ—Na1—Na3^xii	148.90 (8)	148.24 (8)	149.60 (8)
Caⁱⁱ—Na1—Na4^xxii	58.30 (8)	57.03 (8)	59.59 (8)
Caⁱⁱ—Na1—O2	118.48 (14)	118.12 (14)	118.80 (14)
Caⁱⁱ—Na1—O3	45.22 (15)	42.59 (16)	47.88 (15)
Caⁱⁱ—Na1—O7	130.86 (13)	129.97 (13)	131.75 (12)
Caⁱⁱ—Na1—O8	60.71 (17)	57.13 (17)	64.23 (16)
Na—Na1—Na^xx	68.03 (11)	66.00 (11)	70.12 (12)
Na—Na1—Si1	0	0	0
Na—Na1—Na2^xxiv	124.98 (11)	123.61 (11)	126.35 (11)
Na—Na1—Na3	72.44 (9)	70.66 (9)	74.20 (9)
Na—Na1—Na3^xii	108.65 (11)	105.85 (11)	111.36 (11)
Na—Na1—Na4^xxii	59.44 (10)	58.61 (10)	60.29 (10)
Na—Na1—O2	58.35 (17)	56.34 (17)	60.32 (17)
Na—Na1—O3	46.89 (14)	45.73 (14)	48.03 (14)
Na—Na1—O7	125.88 (19)	124.62 (19)	127.14 (19)
Na—Na1—O8	122.31 (17)	119.91 (18)	124.69 (17)
Na^xx—Na1—Si1	0	0	0
Na^xx—Na1—Na2^xxiv	76.50 (10)	74.67 (10)	78.35 (10)
Na^xx—Na1—Na3	120.84 (8)	120.03 (8)	121.64 (8)
Na^xx—Na1—Na3^xii	148.88 (10)	148.06 (10)	149.69 (10)
Na^xx—Na1—Na4^xxii	54.74 (10)	53.26 (9)	56.25 (10)
Na^xx—Na1—O2	113.52 (15)	112.51 (15)	114.59 (15)
Na^xx—Na1—O3	39.85 (16)	36.72 (17)	43.00 (16)
Na^xx—Na1—O7	133.93 (14)	133.32 (14)	134.57 (13)
Na^xx—Na1—O8	66.67 (18)	62.39 (18)	70.87 (17)
Si1—Na1—Na2^xxiv	0	0	0
Si1—Na1—Na3	0	0	0
Si1—Na1—Na3^xii	0	0	0
Si1—Na1—Na4^xxii	0	0	0
Si1—Na1—O2	0	0	0
Si1—Na1—O3	0	0	0
Si1—Na1—O7	0	0	0
Si1—Na1—O8	0	0	0
Na2^xxiv—Na1—Na3	93.04 (6)	92.09 (6)	94.05 (6)
Na2^xxiv—Na1—Na3^xii	122.84 (7)	119.26 (7)	126.47 (7)
Na2^xxiv—Na1—Na4^xxii	125.97 (5)	124.98 (5)	127.04 (5)
Na2^xxiv—Na1—O2	103.96 (17)	102.77 (17)	105.17 (16)
Na2^xxiv—Na1—O3	116.16 (14)	114.32 (15)	118.06 (14)
Na2^xxiv—Na1—O7	109.07 (17)	107.84 (17)	110.26 (16)
Na2^xxiv—Na1—O8	11.48 (14)	9.17 (14)	13.93 (15)
Na3—Na1—Na3^xii	84.75 (5)	84.19 (5)	85.33 (5)
Na3—Na1—Na4^xxii	129.45 (7)	127.35 (7)	131.53 (7)
Na3—Na1—O2	14.54 (16)	14.19 (16)	14.91 (16)
Na3—Na1—O3	119.20 (13)	118.54 (12)	119.82 (13)
Na3—Na1—O7	104.72 (12)	104.35 (12)	105.02 (12)
Na3—Na1—O8	103.02 (14)	102.50 (14)	103.54 (15)
Na3^xii—Na1—Na4^xxii	96.02 (6)	95.00 (6)	97.03 (6)
Na3^xii—Na1—O2	86.92 (13)	85.84 (13)	87.97 (13)
Na3^xii—Na1—O3	114.22 (15)	110.76 (15)	117.66 (16)
Na3^xii—Na1—O7	23.40 (11)	21.58 (10)	25.40 (11)
Na3^xii—Na1—O8	128.55 (16)	123.52 (16)	133.64 (16)
Na4^xxii—Na1—O2	114.96 (17)	112.45 (17)	117.47 (18)
Na4^xxii—Na1—O3	20.35 (13)	17.67 (12)	23.04 (13)
Na4^xxii—Na1—O7	92.26 (16)	89.42 (16)	95.07 (16)
Na4^xxii—Na1—O8	114.57 (15)	112.79 (16)	116.33 (15)
O2—Na1—O3	105.2 (2)	104.3 (2)	106.1 (2)
O2—Na1—O7	109.24 (17)	108.86 (16)	109.69 (17)
O2—Na1—O8	112.7 (2)	112.3 (2)	113.2 (2)
O3—Na1—O7	112.6 (2)	112.4 (2)	112.7 (2)
O3—Na1—O8	105.8 (2)	104.9 (2)	106.7 (2)
O7—Na1—O8	111.1 (2)	109.9 (2)	112.4 (2)
Ca^xi—Si2—Na	11.41 (12)	8.78 (11)	14.24 (12)
Ca^xi—Si2—Na2	0	0	0
Ca^xi—Si2—O1^vi	31.16 (12)	29.10 (12)	33.30 (12)
Ca^xi—Si2—O4^ix	119.74 (16)	119.09 (16)	120.42 (16)
Ca^xi—Si2—O6^x	74.47 (13)	71.24 (13)	77.61 (13)
Ca^xi—Si2—O8^ix	122.31 (15)	120.80 (15)	123.94 (16)
Na—Si2—Na2	0	0	0
Na—Si2—O1^vi	41.05 (15)	36.39 (15)	45.98 (15)
Na—Si2—O4^ix	115.57 (18)	114.79 (18)	116.31 (18)
Na—Si2—O6^x	65.42 (15)	59.45 (15)	71.06 (15)
Na—Si2—O8^ix	130.81 (17)	128.24 (17)	133.43 (17)
Na2—Si2—O1^vi	0	0	0
Na2—Si2—O4^ix	0	0	0
Na2—Si2—O6^x	0	0	0
Na2—Si2—O8^ix	0	0	0
O1^vi—Si2—O4^ix	107.63 (18)	106.99 (18)	108.27 (18)
O1^vi—Si2—O6^x	105.60 (17)	104.51 (17)	106.68 (17)
O1^vi—Si2—O8^ix	109.0 (2)	107.6 (2)	110.5 (2)
O4^ix—Si2—O6^x	112.9 (2)	112.7 (2)	113.2 (2)
O4^ix—Si2—O8^ix	110.31 (19)	109.27 (19)	111.30 (19)
O6^x—Si2—O8^ix	111.1 (2)	110.6 (2)	111.6 (2)
Ca^xi—Na2—Ca^xvii	78.30 (8)	76.38 (8)	80.26 (9)
Ca^xi—Na2—Ca^vi	90.82 (8)	89.47 (8)	92.23 (9)
Ca^xi—Na2—Na	11.41 (12)	8.78 (11)	14.24 (12)
Ca^xi—Na2—Na^xxi	85.35 (10)	84.48 (9)	86.14 (9)
Ca^xi—Na2—Na1^ix	133.12 (9)	130.89 (9)	135.21 (9)
Ca^xi—Na2—Si2	0	0	0
Ca^xi—Na2—Na3^xxi	57.40 (6)	54.71 (6)	60.20 (7)
Ca^xi—Na2—Na4^xxv	143.49 (9)	141.89 (8)	145.12 (8)
Ca^xi—Na2—Na4^x	96.87 (6)	94.57 (7)	99.06 (6)
Ca^xi—Na2—O1^vi	31.16 (12)	29.10 (12)	33.30 (12)
Ca^xi—Na2—O4^ix	119.74 (16)	119.09 (16)	120.42 (16)
Ca^xi—Na2—O6^x	74.47 (13)	71.24 (13)	77.61 (13)
Ca^xi—Na2—O8^ix	122.31 (15)	120.80 (15)	123.94 (16)
Ca^xvii—Na2—Ca^vi	140.81 (8)	138.87 (8)	142.80 (8)
Ca^xvii—Na2—Na	88.35 (12)	84.81 (11)	91.95 (12)
Ca^xvii—Na2—Na^xxi	129.94 (11)	129.63 (11)	130.26 (11)
Ca^xvii—Na2—Na1^ix	55.10 (6)	54.47 (6)	55.69 (6)
Ca^xvii—Na2—Si2	0	0	0
Ca^xvii—Na2—Na3^xxi	61.98 (7)	60.47 (7)	63.52 (7)
Ca^xvii—Na2—Na4^xxv	126.61 (7)	125.79 (7)	127.43 (7)
Ca^xvii—Na2—Na4^x	105.29 (7)	103.58 (7)	106.95 (7)
Ca^xvii—Na2—O1^vi	65.98 (16)	63.70 (16)	68.28 (16)
Ca^xvii—Na2—O4^ix	136.07 (16)	135.84 (15)	136.30 (16)
Ca^xvii—Na2—O6^x	110.45 (16)	110.20 (16)	110.70 (16)
Ca^xvii—Na2—O8^ix	45.04 (14)	42.77 (14)	47.37 (15)
Ca^vi—Na2—Na	86.24 (11)	85.40 (11)	87.17 (12)
Ca^vi—Na2—Na^xxi	11.08 (10)	8.70 (10)	13.52 (10)
Ca^vi—Na2—Na1^ix	127.21 (6)	126.72 (6)	127.76 (6)
Ca^vi—Na2—Si2	0	0	0
Ca^vi—Na2—Na3^xxi	80.35 (7)	79.50 (7)	81.21 (7)
Ca^vi—Na2—Na4^xxv	52.79 (6)	51.42 (6)	54.15 (6)
Ca^vi—Na2—Na4^x	113.39 (8)	113.17 (8)	113.61 (8)
Ca^vi—Na2—O1^vi	85.32 (15)	84.14 (14)	86.52 (15)
Ca^vi—Na2—O4^ix	29.35 (14)	28.17 (15)	30.48 (14)
Ca^vi—Na2—O6^x	102.39 (17)	101.26 (17)	103.52 (18)
Ca^vi—Na2—O8^ix	137.47 (13)	135.79 (13)	139.17 (12)
Na—Na2—Na^xxi	82.74 (12)	81.94 (12)	83.63 (12)
Na—Na2—Na1^ix	141.98 (12)	138.98 (12)	144.49 (12)
Na—Na2—Si2	0	0	0
Na—Na2—Na3^xxi	66.87 (10)	61.62 (9)	72.44 (10)
Na—Na2—Na4^xxv	138.35 (12)	137.08 (12)	139.71 (12)
Na—Na2—Na4^x	89.11 (9)	84.48 (10)	93.45 (9)
Na—Na2—O1^vi	41.05 (15)	36.39 (15)	45.98 (15)
Na—Na2—O4^ix	115.57 (18)	114.79 (18)	116.31 (18)
Na—Na2—O6^x	65.42 (15)	59.45 (15)	71.06 (15)
Na—Na2—O8^ix	130.81 (17)	128.24 (17)	133.43 (17)
Na^xxi—Na2—Na1^ix	126.53 (9)	125.83 (9)	127.25 (9)
Na^xxi—Na2—Si2	0	0	0
Na^xxi—Na2—Na3^xxi	69.29 (10)	67.50 (10)	71.06 (10)
Na^xxi—Na2—Na4^xxv	58.39 (8)	57.50 (8)	59.28 (8)
Na^xxi—Na2—Na4^x	123.58 (11)	121.58 (11)	125.60 (11)
Na^xxi—Na2—O1^vi	75.71 (15)	73.51 (15)	77.90 (16)
Na^xxi—Na2—O4^ix	34.67 (15)	33.31 (15)	36.02 (14)
Na^xxi—Na2—O6^x	109.98 (19)	109.83 (19)	110.15 (19)
Na^xxi—Na2—O8^ix	135.17 (14)	133.87 (14)	136.39 (14)
Na1^ix—Na2—Si2	0	0	0
Na1^ix—Na2—Na3^xxi	98.88 (6)	96.77 (6)	101.00 (6)
Na1^ix—Na2—Na4^xxv	78.40 (5)	77.11 (5)	79.62 (5)
Na1^ix—Na2—Na4^x	91.64 (6)	89.21 (6)	94.03 (6)
Na1^ix—Na2—O1^vi	116.39 (16)	113.55 (17)	119.29 (16)
Na1^ix—Na2—O4^ix	99.29 (15)	98.62 (15)	99.93 (15)
Na1^ix—Na2—O6^x	114.93 (16)	114.05 (15)	115.75 (16)
Na1^ix—Na2—O8^ix	11.39 (12)	9.40 (12)	13.45 (12)
Si2—Na2—Na3^xxi	0	0	0
Si2—Na2—Na4^xxv	0	0	0
Si2—Na2—Na4^x	0	0	0
Si2—Na2—O1^vi	0	0	0
Si2—Na2—O4^ix	0	0	0
Si2—Na2—O6^x	0	0	0
Si2—Na2—O8^ix	0	0	0
Na3^xxi—Na2—Na4^xxv	107.18 (5)	106.58 (5)	107.81 (5)
Na3^xxi—Na2—Na4^x	152.07 (5)	151.71 (5)	152.43 (5)
Na3^xxi—Na2—O1^vi	26.27 (11)	25.65 (11)	26.92 (11)
Na3^xxi—Na2—O4^ix	92.87 (13)	92.15 (13)	93.56 (13)
Na3^xxi—Na2—O6^x	131.87 (13)	131.40 (13)	132.36 (13)
Na3^xxi—Na2—O8^ix	95.24 (15)	94.00 (14)	96.54 (15)
Na4^xxv—Na2—Na4^x	100.22 (5)	99.60 (5)	100.83 (5)
Na4^xxv—Na2—O1^vi	127.68 (12)	126.41 (12)	128.94 (12)
Na4^xxv—Na2—O4^ix	23.80 (13)	21.97 (13)	25.66 (14)
Na4^xxv—Na2—O6^x	112.23 (14)	111.72 (14)	112.80 (14)
Na4^xxv—Na2—O8^ix	89.73 (13)	86.75 (13)	92.65 (12)
Na4^x—Na2—O1^vi	127.04 (11)	126.73 (11)	127.34 (11)
Na4^x—Na2—O4^ix	110.96 (14)	109.99 (14)	111.96 (14)
Na4^x—Na2—O6^x	24.94 (13)	23.52 (13)	26.39 (14)
Na4^x—Na2—O8^ix	90.03 (14)	87.81 (14)	92.20 (14)
O1^vi—Na2—O4^ix	107.63 (18)	106.99 (18)	108.27 (18)
O1^vi—Na2—O6^x	105.60 (17)	104.51 (17)	106.68 (17)
O1^vi—Na2—O8^ix	109.0 (2)	107.6 (2)	110.5 (2)
O4^ix—Na2—O6^x	112.9 (2)	112.7 (2)	113.2 (2)
O4^ix—Na2—O8^ix	110.31 (19)	109.27 (19)	111.30 (19)
O6^x—Na2—O8^ix	111.1 (2)	110.6 (2)	111.6 (2)
Ca^xxvi—Si3—Ca^vi	86.95 (9)	85.19 (9)	88.62 (9)
Ca^xxvi—Si3—Na^xxi	89.44 (11)	87.11 (11)	91.62 (11)
Ca^xxvi—Si3—Na3	0	0	0
Ca^xxvi—Si3—O1^xi	72.70 (16)	71.94 (16)	73.42 (16)
Ca^xxvi—Si3—O2	137.29 (16)	136.69 (16)	137.85 (15)
Ca^xxvi—Si3—O5	38.44 (12)	37.34 (12)	39.44 (12)
Ca^xxvi—Si3—O7^xii	107.97 (15)	107.39 (15)	108.64 (16)
Ca^vi—Si3—Na^xxi	11.74 (10)	9.89 (11)	13.52 (10)
Ca^vi—Si3—Na3	0	0	0
Ca^vi—Si3—O1^xi	44.80 (12)	40.62 (12)	48.95 (12)
Ca^vi—Si3—O2	124.66 (18)	123.81 (18)	125.50 (19)
Ca^vi—Si3—O5	122.35 (14)	121.40 (14)	122.95 (14)
Ca^vi—Si3—O7^xii	58.85 (14)	52.81 (14)	65.02 (14)
Na^xxi—Si3—Na3	0	0	0
Na^xxi—Si3—O1^xi	35.52 (14)	29.79 (14)	41.30 (14)
Na^xxi—Si3—O2	116.28 (19)	114.37 (18)	118.2 (2)
Na^xxi—Si3—O5	127.01 (15)	124.66 (15)	128.92 (15)
Na^xxi—Si3—O7^xii	68.64 (15)	60.68 (15)	76.61 (15)
Na3—Si3—O1^xi	0	0	0
Na3—Si3—O2	0	0	0
Na3—Si3—O5	0	0	0
Na3—Si3—O7^xii	0	0	0
O1^xi—Si3—O2	108.11 (19)	107.21 (19)	109.0 (2)
O1^xi—Si3—O5	108.5 (2)	106.6 (2)	110.3 (2)
O1^xi—Si3—O7^xii	103.62 (17)	101.68 (17)	105.64 (17)
O2—Si3—O5	111.29 (19)	111.0 (2)	111.54 (19)
O2—Si3—O7^xii	112.9 (2)	112.5 (2)	113.2 (2)
O5—Si3—O7^xii	112.0 (2)	111.5 (2)	112.5 (2)
Ca^xxvi—Na3—Ca^vi	86.95 (9)	85.19 (9)	88.62 (9)
Ca^xxvi—Na3—Na	131.07 (10)	130.64 (10)	131.55 (10)
Ca^xxvi—Na3—Na^xiv	11.27 (10)	8.96 (10)	13.53 (10)
Ca^xxvi—Na3—Na^xxi	89.44 (11)	87.11 (11)	91.62 (11)
Ca^xxvi—Na3—Na1	128.68 (7)	127.30 (7)	130.06 (7)
Ca^xxvi—Na3—Na1^xii	116.96 (8)	114.98 (8)	118.98 (8)
Ca^xxvi—Na3—Na2^xxi	69.57 (7)	67.94 (7)	71.20 (8)
Ca^xxvi—Na3—Si3	0	0	0
Ca^xxvi—Na3—Na4^viii	59.91 (7)	59.52 (7)	60.26 (7)
Ca^xxvi—Na3—O1^xi	72.70 (16)	71.94 (16)	73.42 (16)
Ca^xxvi—Na3—O2	137.29 (16)	136.69 (16)	137.85 (15)
Ca^xxvi—Na3—O5	38.44 (12)	37.34 (12)	39.44 (12)
Ca^xxvi—Na3—O7^xii	107.97 (15)	107.39 (15)	108.64 (16)
Ca^vi—Na3—Na	88.24 (10)	86.98 (10)	89.58 (11)
Ca^vi—Na3—Na^xiv	90.15 (10)	88.68 (10)	91.44 (10)
Ca^vi—Na3—Na^xxi	11.74 (10)	9.89 (11)	13.52 (10)
Ca^vi—Na3—Na1	139.05 (10)	137.87 (10)	140.26 (10)
Ca^vi—Na3—Na1^xii	81.95 (7)	78.78 (7)	85.15 (7)
Ca^vi—Na3—Na2^xxi	71.12 (7)	67.71 (7)	74.51 (7)
Ca^vi—Na3—Si3	0	0	0
Ca^vi—Na3—Na4^viii	142.38 (9)	142.03 (9)	142.91 (9)
Ca^vi—Na3—O1^xi	44.80 (12)	40.62 (12)	48.95 (12)
Ca^vi—Na3—O2	124.66 (18)	123.81 (18)	125.50 (19)
Ca^vi—Na3—O5	122.35 (14)	121.40 (14)	122.95 (14)
Ca^vi—Na3—O7^xii	58.85 (14)	52.81 (14)	65.02 (14)
Na—Na3—Na^xiv	142.06 (12)	139.35 (12)	144.74 (11)
Na—Na3—Na^xxi	78.06 (12)	75.77 (11)	80.51 (12)
Na—Na3—Na1	54.36 (8)	53.40 (8)	55.34 (8)
Na—Na3—Na1^xii	110.43 (10)	108.74 (10)	112.04 (10)
Na—Na3—Na2^xxi	62.87 (9)	61.72 (9)	64.07 (9)
Na—Na3—Si3	0	0	0
Na—Na3—Na4^viii	126.00 (8)	125.07 (8)	126.90 (8)
Na—Na3—O1^xi	70.01 (15)	69.25 (15)	70.78 (15)
Na—Na3—O2	40.09 (16)	39.61 (16)	40.56 (16)
Na—Na3—O5	136.19 (14)	134.38 (14)	137.99 (14)
Na—Na3—O7^xii	110.66 (19)	108.36 (19)	112.90 (19)
Na^xiv—Na3—Na^xxi	94.66 (12)	92.42 (12)	96.61 (12)
Na^xiv—Na3—Na1	128.85 (9)	127.34 (9)	130.41 (9)
Na^xiv—Na3—Na1^xii	106.84 (9)	103.03 (9)	110.74 (9)
Na^xiv—Na3—Na2^xxi	80.82 (9)	77.01 (9)	84.58 (9)
Na^xiv—Na3—Si3	0	0	0
Na^xiv—Na3—Na4^viii	53.96 (8)	53.17 (8)	54.76 (8)
Na^xiv—Na3—O1^xi	82.52 (17)	80.28 (17)	84.80 (17)
Na^xiv—Na3—O2	140.35 (17)	139.32 (17)	141.44 (17)
Na^xiv—Na3—O5	32.59 (13)	32.31 (13)	32.76 (12)
Na^xiv—Na3—O7^xii	100.69 (17)	99.05 (17)	102.17 (17)
Na^xxi—Na3—Na1	130.99 (11)	128.72 (11)	133.29 (12)
Na^xxi—Na3—Na1^xii	91.00 (9)	86.29 (10)	95.64 (9)
Na^xxi—Na3—Na2^xxi	61.39 (9)	56.21 (9)	66.63 (9)
Na^xxi—Na3—Si3	0	0	0
Na^xxi—Na3—Na4^viii	148.37 (11)	146.68 (11)	149.53 (11)
Na^xxi—Na3—O1^xi	35.52 (14)	29.79 (14)	41.30 (14)
Na^xxi—Na3—O2	116.28 (19)	114.37 (18)	118.2 (2)
Na^xxi—Na3—O5	127.01 (15)	124.66 (15)	128.92 (15)
Na^xxi—Na3—O7^xii	68.64 (15)	60.68 (15)	76.61 (15)
Na1—Na3—Na1^xii	95.25 (5)	94.25 (5)	96.23 (5)
Na1—Na3—Na2^xxi	100.38 (5)	99.69 (5)	101.09 (5)
Na1—Na3—Si3	0	0	0
Na1—Na3—Na4^viii	78.37 (5)	76.85 (5)	79.85 (5)
Na1—Na3—O1^xi	119.83 (13)	118.51 (12)	121.20 (13)
Na1—Na3—O2	14.78 (15)	13.92 (15)	15.64 (15)
Na1—Na3—O5	97.82 (12)	96.73 (12)	98.89 (11)
Na1—Na3—O7^xii	115.06 (13)	114.26 (13)	115.72 (13)
Na1^xii—Na3—Na2^xxi	152.15 (7)	150.85 (7)	153.46 (7)
Na1^xii—Na3—Si3	0	0	0
Na1^xii—Na3—Na4^viii	97.11 (6)	94.74 (6)	99.55 (6)
Na1^xii—Na3—O1^xi	126.47 (13)	125.37 (13)	127.54 (13)
Na1^xii—Na3—O2	97.11 (13)	95.48 (13)	98.70 (14)
Na1^xii—Na3—O5	104.67 (14)	100.90 (14)	108.50 (14)
Na1^xii—Na3—O7^xii	23.65 (11)	21.46 (11)	26.00 (12)
Na2^xxi—Na3—Si3	0	0	0
Na2^xxi—Na3—Na4^viii	108.48 (6)	106.28 (6)	110.65 (6)
Na2^xxi—Na3—O1^xi	26.35 (11)	25.02 (10)	27.75 (11)
Na2^xxi—Na3—O2	92.56 (13)	91.59 (13)	93.56 (14)
Na2^xxi—Na3—O5	95.91 (13)	92.47 (13)	99.24 (13)
Na2^xxi—Na3—O7^xii	129.88 (14)	126.73 (14)	133.10 (14)
Si3—Na3—Na4^viii	0	0	0
Si3—Na3—O1^xi	0	0	0
Si3—Na3—O2	0	0	0
Si3—Na3—O5	0	0	0
Si3—Na3—O7^xii	0	0	0
Na4^viii—Na3—O1^xi	126.86 (16)	125.88 (16)	127.77 (16)
Na4^viii—Na3—O2	92.72 (16)	91.96 (16)	93.43 (16)
Na4^viii—Na3—O5	21.59 (11)	21.04 (11)	22.22 (11)
Na4^viii—Na3—O7^xii	112.30 (17)	110.38 (17)	114.19 (16)
O1^xi—Na3—O2	108.11 (19)	107.21 (19)	109.0 (2)
O1^xi—Na3—O5	108.5 (2)	106.6 (2)	110.3 (2)
O1^xi—Na3—O7^xii	103.62 (17)	101.68 (17)	105.64 (17)
O2—Na3—O5	111.29 (19)	111.0 (2)	111.54 (19)
O2—Na3—O7^xii	112.9 (2)	112.5 (2)	113.2 (2)
O5—Na3—O7^xii	112.0 (2)	111.5 (2)	112.5 (2)
Ca^xxvii—Si4—Ca^xix	76.99 (9)	75.32 (8)	78.64 (9)
Ca^xxvii—Si4—Na^xiii	12.79 (12)	10.17 (12)	15.45 (12)
Ca^xxvii—Si4—Na^xxiii	73.03 (10)	71.96 (9)	74.07 (10)
Ca^xxvii—Si4—Na4	0	0	0
Ca^xxvii—Si4—O3^xiii	58.15 (15)	55.65 (14)	60.64 (15)
Ca^xxvii—Si4—O4^xiv	106.95 (13)	105.95 (13)	107.88 (13)
Ca^xxvii—Si4—O5^xiv	45.53 (15)	44.48 (15)	46.58 (15)
Ca^xxvii—Si4—O6	142.46 (13)	141.37 (13)	143.50 (12)
Ca^xix—Si4—Na^xiii	77.68 (11)	75.98 (11)	79.38 (11)
Ca^xix—Si4—Na^xxiii	13.02 (12)	10.50 (12)	15.48 (13)
Ca^xix—Si4—Na4	0	0	0
Ca^xix—Si4—O3^xiii	49.49 (13)	48.73 (13)	50.27 (13)
Ca^xix—Si4—O4^xiv	52.77 (16)	51.23 (15)	54.32 (16)
Ca^xix—Si4—O5^xiv	116.39 (15)	114.94 (15)	117.84 (15)
Ca^xix—Si4—O6	131.36 (17)	130.29 (17)	132.44 (17)
Na^xiii—Si4—Na^xxiii	76.59 (12)	74.60 (12)	78.65 (12)
Na^xiii—Si4—Na4	0	0	0
Na^xiii—Si4—O3^xiii	49.04 (17)	47.39 (17)	50.68 (17)
Na^xiii—Si4—O4^xiv	115.82 (15)	113.28 (15)	118.45 (16)
Na^xiii—Si4—O5^xiv	52.58 (18)	51.88 (18)	53.34 (18)
Na^xiii—Si4—O6	133.77 (14)	131.11 (14)	136.43 (14)
Na^xxiii—Si4—Na4	0	0	0
Na^xxiii—Si4—O3^xiii	58.44 (15)	56.57 (14)	60.32 (15)
Na^xxiii—Si4—O4^xiv	45.73 (16)	45.13 (15)	46.35 (16)
Na^xxiii—Si4—O5^xiv	107.21 (16)	106.77 (16)	107.70 (16)
Na^xxiii—Si4—O6	140.19 (17)	138.81 (17)	141.51 (17)
Na4—Si4—O3^xiii	0	0	0
Na4—Si4—O4^xiv	0	0	0
Na4—Si4—O5^xiv	0	0	0
Na4—Si4—O6	0	0	0
O3^xiii—Si4—O4^xiv	102.2 (2)	100.31 (19)	104.2 (2)
O3^xiii—Si4—O5^xiv	101.51 (19)	100.18 (18)	102.84 (19)
O3^xiii—Si4—O6	117.2 (2)	116.1 (2)	118.3 (2)
O4^xiv—Si4—O5^xiv	113.14 (19)	112.3 (2)	114.03 (19)
O4^xiv—Si4—O6	110.15 (16)	109.60 (16)	110.77 (16)
O5^xiv—Si4—O6	112.1 (2)	110.9 (2)	113.3 (2)
Ca^xxvii—Na4—Ca^xix	76.99 (9)	75.32 (8)	78.64 (9)
Ca^xxvii—Na4—Na^xiii	12.79 (12)	10.17 (12)	15.45 (12)
Ca^xxvii—Na4—Na^xxiii	73.03 (10)	71.96 (9)	74.07 (10)
Ca^xxvii—Na4—Na1^xiii	72.61 (8)	70.95 (8)	74.25 (8)
Ca^xxvii—Na4—Na2^xxviii	121.09 (7)	120.35 (7)	121.79 (8)
Ca^xxvii—Na4—Na2^x	158.81 (8)	158.45 (8)	159.22 (8)
Ca^xxvii—Na4—Na3^xiv	66.31 (8)	65.43 (8)	67.19 (8)
Ca^xxvii—Na4—Si4	0	0	0
Ca^xxvii—Na4—O3^xiii	58.15 (15)	55.65 (14)	60.64 (15)
Ca^xxvii—Na4—O4^xiv	106.95 (13)	105.95 (13)	107.88 (13)
Ca^xxvii—Na4—O5^xiv	45.53 (15)	44.48 (15)	46.58 (15)
Ca^xxvii—Na4—O6	142.46 (13)	141.37 (13)	143.50 (12)
Ca^xix—Na4—Na^xiii	77.68 (11)	75.98 (11)	79.38 (11)
Ca^xix—Na4—Na^xxiii	13.02 (12)	10.50 (12)	15.48 (13)
Ca^xix—Na4—Na1^xiii	62.46 (8)	60.97 (8)	63.94 (8)
Ca^xix—Na4—Na2^xxviii	75.57 (7)	74.64 (7)	76.47 (7)
Ca^xix—Na4—Na2^x	107.93 (8)	107.23 (8)	108.65 (8)
Ca^xix—Na4—Na3^xiv	131.51 (8)	128.46 (8)	134.54 (9)
Ca^xix—Na4—Si4	0	0	0
Ca^xix—Na4—O3^xiii	49.49 (13)	48.73 (13)	50.27 (13)
Ca^xix—Na4—O4^xiv	52.77 (16)	51.23 (15)	54.32 (16)
Ca^xix—Na4—O5^xiv	116.39 (15)	114.94 (15)	117.84 (15)
Ca^xix—Na4—O6	131.36 (17)	130.29 (17)	132.44 (17)
Na^xiii—Na4—Na^xxiii	76.59 (12)	74.60 (12)	78.65 (12)
Na^xiii—Na4—Na1^xiii	61.34 (12)	59.80 (12)	62.86 (12)
Na^xiii—Na4—Na2^xxviii	132.55 (10)	130.12 (10)	135.04 (11)
Na^xiii—Na4—Na2^x	146.32 (11)	143.84 (12)	148.79 (11)
Na^xiii—Na4—Na3^xiv	73.29 (12)	72.55 (12)	74.00 (12)
Na^xiii—Na4—Si4	0	0	0
Na^xiii—Na4—O3^xiii	49.04 (17)	47.39 (17)	50.68 (17)
Na^xiii—Na4—O4^xiv	115.82 (15)	113.28 (15)	118.45 (16)
Na^xiii—Na4—O5^xiv	52.58 (18)	51.88 (18)	53.34 (18)
Na^xiii—Na4—O6	133.77 (14)	131.11 (14)	136.43 (14)
Na^xxiii—Na4—Na1^xiii	73.64 (11)	70.05 (11)	77.17 (11)
Na^xxiii—Na4—Na2^xxviii	68.74 (9)	68.25 (9)	69.28 (9)
Na^xxiii—Na4—Na2^x	116.06 (10)	113.95 (10)	118.11 (10)
Na^xxiii—Na4—Na3^xiv	119.95 (11)	119.23 (11)	120.69 (11)
Na^xxiii—Na4—Si4	0	0	0
Na^xxiii—Na4—O3^xiii	58.44 (15)	56.57 (14)	60.32 (15)
Na^xxiii—Na4—O4^xiv	45.73 (16)	45.13 (15)	46.35 (16)
Na^xxiii—Na4—O5^xiv	107.21 (16)	106.77 (16)	107.70 (16)
Na^xxiii—Na4—O6	140.19 (17)	138.81 (17)	141.51 (17)
Na1^xiii—Na4—Na2^xxviii	131.83 (7)	129.82 (7)	133.81 (7)
Na1^xiii—Na4—Na2^x	91.15 (6)	90.33 (6)	92.00 (6)
Na1^xiii—Na4—Na3^xiv	128.05 (5)	126.52 (5)	129.64 (5)
Na1^xiii—Na4—Si4	0	0	0
Na1^xiii—Na4—O3^xiii	19.71 (12)	17.87 (12)	21.53 (12)
Na1^xiii—Na4—O4^xiv	112.42 (17)	109.38 (16)	115.43 (17)
Na1^xiii—Na4—O5^xiv	110.45 (14)	109.72 (14)	111.17 (14)
Na1^xiii—Na4—O6	97.54 (16)	96.55 (16)	98.50 (16)
Na2^xxviii—Na4—Na2^x	79.77 (5)	79.26 (5)	80.28 (5)
Na2^xxviii—Na4—Na3^xiv	96.87 (6)	95.51 (6)	98.29 (6)
Na2^xxviii—Na4—Si4	0	0	0
Na2^xxviii—Na4—O3^xiii	124.73 (13)	123.48 (13)	125.95 (14)
Na2^xxviii—Na4—O4^xiv	23.07 (14)	22.56 (14)	23.54 (13)
Na2^xxviii—Na4—O5^xiv	108.60 (14)	108.00 (14)	109.23 (14)
Na2^xxviii—Na4—O6	92.81 (11)	91.97 (12)	93.67 (11)
Na2^x—Na4—Na3^xiv	117.84 (7)	114.55 (7)	121.16 (7)
Na2^x—Na4—Si4	0	0	0
Na2^x—Na4—O3^xiii	108.75 (15)	106.57 (15)	110.89 (15)
Na2^x—Na4—O4^xiv	91.53 (12)	91.07 (12)	92.00 (12)
Na2^x—Na4—O5^xiv	135.63 (15)	133.63 (15)	137.66 (15)
Na2^x—Na4—O6	24.16 (13)	22.50 (13)	25.84 (13)
Na3^xiv—Na4—Si4	0	0	0
Na3^xiv—Na4—O3^xiii	121.92 (13)	119.84 (13)	123.94 (14)
Na3^xiv—Na4—O4^xiv	108.88 (16)	107.30 (17)	110.54 (16)
Na3^xiv—Na4—O5^xiv	20.89 (14)	19.85 (13)	21.88 (14)
Na3^xiv—Na4—O6	96.33 (16)	93.60 (17)	99.12 (16)
Si4—Na4—O3^xiii	0	0	0
Si4—Na4—O4^xiv	0	0	0
Si4—Na4—O5^xiv	0	0	0
Si4—Na4—O6	0	0	0
O3^xiii—Na4—O4^xiv	102.2 (2)	100.31 (19)	104.2 (2)
O3^xiii—Na4—O5^xiv	101.51 (19)	100.18 (18)	102.84 (19)
O3^xiii—Na4—O6	117.2 (2)	116.1 (2)	118.3 (2)
O4^xiv—Na4—O5^xiv	113.14 (19)	112.3 (2)	114.03 (19)
O4^xiv—Na4—O6	110.15 (16)	109.60 (16)	110.77 (16)
O5^xiv—Na4—O6	112.1 (2)	110.9 (2)	113.3 (2)
Caⁱ—O1—Na^vi	18.15 (16)	14.34 (16)	22.02 (16)
Caⁱ—O1—Si2^vi	127.24 (19)	123.01 (19)	131.32 (19)
Caⁱ—O1—Na2^vi	127.24 (19)	123.01 (19)	131.32 (19)
Caⁱ—O1—Si3^xvi	105.31 (17)	99.68 (16)	111.15 (18)
Caⁱ—O1—Na3^xvi	105.31 (17)	99.68 (16)	111.15 (18)
Na^vi—O1—Si2^vi	111.2 (2)	103.3 (2)	118.9 (2)
Na^vi—O1—Na2^vi	111.2 (2)	103.3 (2)	118.9 (2)
Na^vi—O1—Si3^xvi	120.2 (2)	111.2 (2)	129.5 (2)
Na^vi—O1—Na3^xvi	120.2 (2)	111.2 (2)	129.5 (2)
Si2^vi—O1—Na2^vi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^vi—O1—Si3^xvi	127.38 (19)	125.57 (19)	129.11 (19)
Si2^vi—O1—Na3^xvi	127.38 (19)	125.57 (19)	129.11 (19)
Na2^vi—O1—Si3^xvi	127.38 (19)	125.57 (19)	129.11 (19)
Na2^vi—O1—Na3^xvi	127.38 (19)	125.57 (19)	129.11 (19)
Si3^xvi—O1—Na3^xvi	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O2—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O2—Si3	150.7 (3)	149.5 (3)	151.9 (3)
Si1—O2—Na3	150.7 (3)	149.5 (3)	151.9 (3)
Na1—O2—Si3	150.7 (3)	149.5 (3)	151.9 (3)
Na1—O2—Na3	150.7 (3)	149.5 (3)	151.9 (3)
Si3—O2—Na3	0.0 (5)	0.0 (5)	0.0 (5)
Caⁱⁱ—O3—Na	109.95 (19)	109.23 (19)	110.65 (19)
Caⁱⁱ—O3—Si1	105.4 (2)	101.9 (2)	109.0 (2)
Caⁱⁱ—O3—Na1	105.4 (2)	101.9 (2)	109.0 (2)
Caⁱⁱ—O3—Si4^xxii	97.81 (17)	97.50 (17)	98.09 (17)
Caⁱⁱ—O3—Na4^xxii	97.81 (17)	97.50 (17)	98.09 (17)
Na—O3—Si1	103.07 (19)	100.50 (19)	105.67 (19)
Na—O3—Na1	103.07 (19)	100.50 (19)	105.67 (19)
Na—O3—Si4^xxii	98.8 (2)	97.8 (2)	99.8 (2)
Na—O3—Na4^xxii	98.8 (2)	97.8 (2)	99.8 (2)
Si1—O3—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O3—Si4^xxii	139.9 (2)	135.5 (2)	144.4 (2)
Si1—O3—Na4^xxii	139.9 (2)	135.5 (2)	144.4 (2)
Na1—O3—Si4^xxii	139.9 (2)	135.5 (2)	144.4 (2)
Na1—O3—Na4^xxii	139.9 (2)	135.5 (2)	144.4 (2)
Si4^xxii—O3—Na4^xxii	0.0 (5)	0.0 (5)	0.0 (5)
Caⁱⁱⁱ—O4—Na^vii	17.27 (16)	13.73 (16)	20.87 (16)
Caⁱⁱⁱ—O4—Si2^xxiv	131.7 (2)	129.59 (19)	133.9 (2)
Caⁱⁱⁱ—O4—Na2^xxiv	131.7 (2)	129.59 (19)	133.9 (2)
Caⁱⁱⁱ—O4—Si4^viii	94.40 (18)	92.61 (18)	96.18 (18)
Caⁱⁱⁱ—O4—Na4^viii	94.40 (18)	92.61 (18)	96.18 (18)
Na^vii—O4—Si2^xxiv	122.5 (2)	119.98 (19)	125.1 (2)
Na^vii—O4—Na2^xxiv	122.5 (2)	119.98 (19)	125.1 (2)
Na^vii—O4—Si4^viii	104.16 (19)	103.62 (19)	104.76 (19)
Na^vii—O4—Na4^viii	104.16 (19)	103.62 (19)	104.76 (19)
Si2^xxiv—O4—Na2^xxiv	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xxiv—O4—Si4^viii	133.1 (3)	130.9 (3)	135.4 (3)
Si2^xxiv—O4—Na4^viii	133.1 (3)	130.9 (3)	135.4 (3)
Na2^xxiv—O4—Si4^viii	133.1 (3)	130.9 (3)	135.4 (3)
Na2^xxiv—O4—Na4^viii	133.1 (3)	130.9 (3)	135.4 (3)
Si4^viii—O4—Na4^viii	0.0 (5)	0.0 (5)	0.0 (5)
Ca^xxvi—O5—Na^xiv	17.14 (15)	13.59 (15)	20.69 (15)
Ca^xxvi—O5—Si3	117.11 (19)	114.96 (19)	119.39 (19)
Ca^xxvi—O5—Na3	117.11 (19)	114.96 (19)	119.39 (19)
Ca^xxvi—O5—Si4^viii	105.1 (2)	102.9 (2)	107.3 (2)
Ca^xxvi—O5—Na4^viii	105.1 (2)	102.9 (2)	107.3 (2)
Na^xiv—O5—Si3	126.9 (2)	126.0 (2)	127.5 (2)
Na^xiv—O5—Na3	126.9 (2)	126.0 (2)	127.5 (2)
Na^xiv—O5—Si4^viii	95.1 (2)	93.7 (2)	96.6 (2)
Na^xiv—O5—Na4^viii	95.1 (2)	93.7 (2)	96.6 (2)
Si3—O5—Na3	0.0 (5)	0.0 (5)	0.0 (5)
Si3—O5—Si4^viii	137.5 (2)	136.4 (2)	138.7 (2)
Si3—O5—Na4^viii	137.5 (2)	136.4 (2)	138.7 (2)
Na3—O5—Si4^viii	137.5 (2)	136.4 (2)	138.7 (2)
Na3—O5—Na4^viii	137.5 (2)	136.4 (2)	138.7 (2)
Si4^viii—O5—Na4^viii	0.0 (5)	0.0 (5)	0.0 (5)
Si2^x—O6—Na2^x	0.0 (5)	0.0 (5)	0.0 (5)
Si2^x—O6—Si4	130.9 (2)	128.1 (2)	133.8 (2)
Si2^x—O6—Na4	130.9 (2)	128.1 (2)	133.8 (2)
Na2^x—O6—Si4	130.9 (2)	128.1 (2)	133.8 (2)
Na2^x—O6—Na4	130.9 (2)	128.1 (2)	133.8 (2)
Si4—O6—Na4	0.0 (5)	0.0 (5)	0.0 (5)
Ca^xxix—O7—Si1	134.9 (2)	133.8 (2)	136.4 (2)
Ca^xxix—O7—Na1	134.9 (2)	133.8 (2)	136.4 (2)
Ca^xxix—O7—Si3^xii	90.43 (16)	84.96 (15)	96.10 (17)
Ca^xxix—O7—Na3^xii	90.43 (16)	84.96 (15)	96.10 (17)
Si1—O7—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O7—Si3^xii	133.0 (2)	128.8 (2)	136.8 (2)
Si1—O7—Na3^xii	133.0 (2)	128.8 (2)	136.8 (2)
Na1—O7—Si3^xii	133.0 (2)	128.8 (2)	136.8 (2)
Na1—O7—Na3^xii	133.0 (2)	128.8 (2)	136.8 (2)
Si3^xii—O7—Na3^xii	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O8—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O8—Si2^xxiv	157.1 (3)	152.7 (3)	161.4 (2)
Si1—O8—Na2^xxiv	157.1 (3)	152.7 (3)	161.4 (2)
Na1—O8—Si2^xxiv	157.1 (3)	152.7 (3)	161.4 (2)
Na1—O8—Na2^xxiv	157.1 (3)	152.7 (3)	161.4 (2)
Si2^xxiv—O8—Na2^xxiv	0.0 (5)	0.0 (5)	0.0 (5)

Symmetry codes: (i) −x₁+3/2, −x₂, −x₃+1/2, −x₄; (ii) −x₁+1/2, −x₂+1, −x₃, −x₄+1/2; (iii) −x₁+1/2, −x₂+1, −x₃+1/2, −x₄; (iv) x₁, x₂−1, x₃−1/2, x₄+1/2; (v) x₁+1/2, x₂−1/2, x₃, x₄+1/2; (vi) −x₁+3/2, −x₂+1, −x₃+1/2, −x₄; (vii) −x₁+1/2, −x₂+2, −x₃+1/2, −x₄; (viii) x₁, x₂, x₃−1/2, x₄+1/2; (ix) x₁+1, x₂, x₃, x₄; (x) −x₁+1, −x₂+3/2, −x₃+1, −x₄; (xi) x₁, x₂+1, x₃, x₄; (xii) −x₁+1, −x₂+3/2, −x₃+1/2, −x₄+1/2; (xiii) x₁, x₂, x₃+1, x₄; (xiv) x₁, x₂, x₃+1/2, x₄+1/2; (xv) −x₁+1/2, −x₂, −x₃, −x₄+1/2; (xvi) x₁, x₂−1, x₃, x₄; (xvii) −x₁+3/2, −x₂+1, −x₃, −x₄+1/2; (xviii) x₁, x₂−1, x₃−1, x₄; (xix) −x₁+1/2, −x₂+1, −x₃+1, −x₄+1/2; (xx) −x₁+1/2, −x₂+2, −x₃, −x₄+1/2; (xxi) −x₁+3/2, −x₂+2, −x₃+1/2, −x₄; (xxii) x₁, x₂, x₃−1, x₄; (xxiii) −x₁+1/2, −x₂+2, −x₃+1, −x₄+1/2; (xxiv) x₁−1, x₂, x₃, x₄; (xxv) x₁+1, x₂, x₃−1/2, x₄+1/2; (xxvi) x₁, x₂+1, x₃+1/2, x₄+1/2; (xxvii) x₁, x₂+1, x₃+1, x₄; (xxviii) x₁−1, x₂, x₃+1/2, x₄+1/2; (xxix) x₁−1/2, x₂+1/2, x₃, x₄+1/2.

(V) top

Crystal data top

Al_1.403Ca_0.433Na_0.567O₈Si_2.597	γ = 89.691 (8)°
M_r = 269.2	V = 1332.5 (3) Å³
Triclinic, X1(αβγ)0†	Z = 8
q = 0.070000a* + 0.044000b* + -0.241000c*	Mo Kα radiation, λ = 0.71073 Å
a = 8.1590 (9) Å	µ = 1.21 mm⁻¹
b = 12.8579 (12) Å	T = 293 K
c = 14.1875 (19) Å	Irregular, colourless
α = 93.369 (9)°	0.18 × 0.10 × 0.05 mm
β = 116.229 (12)°

† Symmetry operations: (1) x₁, x₂, x₃, x₄; (2) x₁, x₂, x₃+1/2, x₄+1/2; (3) x₁+1/2, x₂+1/2, x₃, x₄+1/2; (4) x₁+1/2, x₂+1/2, x₃+1/2, x₄.

Data collection top

Oxford Diffraction CCD diffractometer	8560 independent reflections
Radiation source: X-ray tube	4756 reflections with I > 3σ(I)
Graphite monochromator	R_int = 0.017
Detector resolution: 16.1500 pixels mm^-1	θ_max = 28.9°, θ_min = 3.2°
ω scans	h = −10→10
Absorption correction: analytical CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)	k = −17→17
T_min = 0.837, T_max = 0.948	l = −17→19
13172 measured reflections

Refinement top

Refinement on F²	155 constraints
R[F² > 2σ(F²)] = 0.049	Weighting scheme based on measured s.u.'s w = 1/(σ²(I) + 0.0004I²)
wR(F²) = 0.131	(Δ/σ)_max = 0.046
S = 1.55	Δρ_max = 1.77 e Å⁻³
8560 reflections	Δρ_min = −1.06 e Å⁻³
400 parameters	Absolute structure: 3932 of Friedel pairs used in the refinement
0 restraints	Absolute structure parameter: 0.40 (13)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ca1	0.5370 (2)	0.99007 (19)	0.06202 (18)	0.0608 (11)	0.4241
Na1	0.5370 (2)	0.99007 (19)	0.06202 (18)	0.0608 (11)	0.5759
Ca21	0.9989 (4)	1.0253 (3)	0.9030 (3)	0.0180 (8)	0.2295 (18)
Ca22	1.0057 (9)	0.9669 (5)	0.9337 (6)	0.0180 (8)	0.2295 (18)
Na2	0.9916 (9)	0.9610 (5)	0.9436 (5)	0.0180 (8)	0.541 (4)
Si1	0.7736 (2)	0.31027 (13)	0.10719 (14)	0.0101 (7)	0.6299
Al1	0.7736 (2)	0.31027 (13)	0.10719 (14)	0.0101 (7)	0.3701
Si2	0.0875 (2)	0.61317 (13)	0.31240 (15)	0.0119 (6)	0.722
Al2	0.0875 (2)	0.61317 (13)	0.31240 (15)	0.0119 (6)	0.278
Si3	0.9570 (3)	0.10232 (13)	0.14972 (15)	0.0115 (6)	0.8668
Al3	0.9570 (3)	0.10232 (13)	0.14972 (15)	0.0115 (6)	0.1332
Si4	0.0838 (3)	0.38321 (13)	0.33272 (15)	0.0111 (6)	0.6711
Al4	0.0838 (3)	0.38321 (13)	0.33272 (15)	0.0111 (6)	0.3289
Si5	0.7764 (3)	0.65875 (13)	0.09785 (14)	0.0123 (7)	0.4671
Al5	0.7764 (3)	0.65875 (13)	0.09785 (14)	0.0123 (7)	0.5329
Si6	0.7633 (2)	0.32819 (13)	0.88396 (15)	0.0122 (7)	0.3438
Al6	0.7633 (2)	0.32819 (13)	0.88396 (15)	0.0122 (7)	0.6562
Si7	0.9514 (3)	0.87256 (13)	0.16942 (14)	0.0113 (7)	0.6859
Al7	0.9514 (3)	0.87256 (13)	0.16942 (14)	0.0113 (7)	0.3142
Si8	0.2674 (3)	0.17442 (13)	0.37532 (15)	0.0142 (7)	0.8076
Al8	0.2674 (3)	0.17442 (13)	0.37532 (15)	0.0142 (7)	0.1924
O1	0.9716 (7)	0.6005 (4)	0.1847 (4)	0.0168 (18)
O2	0.2531 (7)	0.3017 (3)	0.3815 (4)	0.023 (2)
O3	0.4532 (8)	0.1407 (4)	0.3692 (5)	0.026 (2)
O4	0.8524 (7)	0.9857 (3)	0.1312 (4)	0.0151 (18)
O5	0.7662 (8)	0.3641 (4)	0.0010 (4)	0.023 (2)
O6	0.0800 (7)	0.1248 (4)	0.2758 (4)	0.0207 (19)
O7	0.7828 (7)	0.7843 (3)	0.1296 (4)	0.0172 (19)
O8	0.0785 (7)	0.0979 (3)	0.0833 (4)	0.019 (2)
O9	0.9541 (7)	0.3844 (3)	0.3932 (4)	0.0201 (19)
O10	0.7536 (7)	0.1960 (4)	0.8509 (4)	0.021 (2)
O11	0.1860 (7)	0.4985 (3)	0.3528 (4)	0.0160 (18)
O12	0.9584 (7)	0.3600 (4)	0.2069 (4)	0.024 (2)
O13	0.2720 (7)	0.1227 (4)	0.4782 (4)	0.0199 (19)
O14	0.5879 (8)	0.3469 (4)	0.1150 (5)	0.025 (2)
O15	0.0745 (7)	0.8830 (4)	0.2999 (4)	0.023 (2)
O16	0.7859 (7)	0.1804 (4)	0.0999 (4)	0.0181 (18)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ca1	0.0103 (11)	0.0975 (19)	0.0563 (15)	−0.0027 (10)	0.0057 (10)	−0.0589 (14)
Na1	0.0103 (11)	0.0975 (19)	0.0563 (15)	−0.0027 (10)	0.0057 (10)	−0.0589 (14)
Ca21	0.0103 (13)	0.0214 (9)	0.0211 (12)	−0.0005 (8)	0.0071 (8)	−0.0086 (8)
Ca22	0.0103 (13)	0.0214 (9)	0.0211 (12)	−0.0005 (8)	0.0071 (8)	−0.0086 (8)
Na2	0.0103 (13)	0.0214 (9)	0.0211 (12)	−0.0005 (8)	0.0071 (8)	−0.0086 (8)
Si1	0.0085 (10)	0.0142 (8)	0.0071 (8)	0.0048 (6)	0.0029 (8)	0.0017 (7)
Al1	0.0085 (10)	0.0142 (8)	0.0071 (8)	0.0048 (6)	0.0029 (8)	0.0017 (7)
Si2	0.0094 (9)	0.0125 (8)	0.0129 (9)	0.0020 (6)	0.0042 (7)	0.0015 (7)
Al2	0.0094 (9)	0.0125 (8)	0.0129 (9)	0.0020 (6)	0.0042 (7)	0.0015 (7)
Si3	0.0109 (9)	0.0100 (7)	0.0127 (9)	0.0007 (6)	0.0046 (7)	0.0000 (7)
Al3	0.0109 (9)	0.0100 (7)	0.0127 (9)	0.0007 (6)	0.0046 (7)	0.0000 (7)
Si4	0.0129 (9)	0.0107 (7)	0.0096 (8)	0.0004 (6)	0.0047 (7)	0.0007 (7)
Al4	0.0129 (9)	0.0107 (7)	0.0096 (8)	0.0004 (6)	0.0047 (7)	0.0007 (7)
Si5	0.0153 (10)	0.0127 (8)	0.0093 (8)	−0.0023 (6)	0.0059 (8)	−0.0007 (7)
Al5	0.0153 (10)	0.0127 (8)	0.0093 (8)	−0.0023 (6)	0.0059 (8)	−0.0007 (7)
Si6	0.0097 (10)	0.0162 (8)	0.0109 (8)	−0.0019 (7)	0.0048 (7)	0.0018 (7)
Al6	0.0097 (10)	0.0162 (8)	0.0109 (8)	−0.0019 (7)	0.0048 (7)	0.0018 (7)
Si7	0.0146 (10)	0.0114 (8)	0.0086 (9)	−0.0016 (6)	0.0056 (8)	0.0014 (7)
Al7	0.0146 (10)	0.0114 (8)	0.0086 (9)	−0.0016 (6)	0.0056 (8)	0.0014 (7)
Si8	0.0157 (11)	0.0154 (8)	0.0120 (9)	0.0021 (7)	0.0069 (8)	−0.0013 (7)
Al8	0.0157 (11)	0.0154 (8)	0.0120 (9)	0.0021 (7)	0.0069 (8)	−0.0013 (7)
O1	0.019 (3)	0.014 (2)	0.013 (2)	0.0015 (18)	0.003 (2)	0.0013 (19)
O2	0.026 (3)	0.014 (2)	0.024 (3)	0.0110 (19)	0.006 (2)	0.000 (2)
O3	0.020 (3)	0.029 (2)	0.028 (3)	0.002 (2)	0.011 (3)	−0.003 (2)
O4	0.023 (3)	0.0144 (19)	0.012 (2)	0.0026 (17)	0.011 (2)	0.0058 (19)
O5	0.034 (3)	0.020 (2)	0.019 (2)	0.005 (2)	0.016 (2)	0.002 (2)
O6	0.023 (3)	0.016 (2)	0.014 (2)	0.0104 (19)	0.000 (2)	0.000 (2)
O7	0.020 (3)	0.015 (2)	0.017 (2)	−0.0086 (18)	0.008 (2)	−0.0046 (19)
O8	0.028 (3)	0.019 (2)	0.015 (2)	−0.0053 (19)	0.014 (2)	−0.0055 (19)
O9	0.012 (2)	0.021 (2)	0.027 (3)	−0.0023 (18)	0.010 (2)	0.002 (2)
O10	0.016 (3)	0.026 (2)	0.021 (3)	0.0010 (19)	0.007 (2)	0.006 (2)
O11	0.012 (2)	0.0125 (19)	0.018 (3)	−0.0061 (17)	0.002 (2)	−0.0003 (19)
O12	0.014 (3)	0.031 (2)	0.018 (3)	−0.009 (2)	−0.001 (2)	−0.007 (2)
O13	0.022 (3)	0.027 (2)	0.011 (2)	−0.0026 (19)	0.007 (2)	0.002 (2)
O14	0.021 (3)	0.026 (2)	0.038 (4)	0.0019 (19)	0.023 (3)	−0.001 (2)
O15	0.017 (3)	0.029 (2)	0.015 (3)	0.000 (2)	0.001 (2)	0.002 (2)
O16	0.013 (3)	0.024 (2)	0.013 (2)	0.0026 (18)	0.002 (2)	−0.002 (2)

Geometric parameters (Å, º) top

	Average	Minimum	Maximum
Ca1—O1ⁱ	2.425 (9)	2.393 (9)	2.469 (10)
Ca1—O4	2.334 (9)	2.292 (9)	2.393 (9)
Ca1—O5ⁱ	2.542 (9)	2.441 (9)	2.646 (9)
Ca1—O9ⁱⁱ	2.506 (9)	2.495 (9)	2.520 (8)
Ca1—O13ⁱⁱⁱ	2.637 (9)	2.535 (9)	2.746 (8)
Ca21—O6^iv	2.620 (10)	2.571 (10)	2.643 (10)
Ca21—O8^v	2.482 (8)	2.432 (8)	2.512 (9)
Ca21—O11^vi	2.344 (9)	2.323 (9)	2.375 (9)
Ca21—O13^iv	2.377 (9)	2.311 (9)	2.406 (9)
Ca21—O15^vii	2.468 (10)	2.429 (10)	2.558 (10)
Ca22—O5^viii	2.410 (11)	2.335 (11)	2.447 (11)
Ca22—O8^v	2.456 (10)	2.429 (10)	2.516 (10)
Ca22—O11^vi	2.408 (10)	2.352 (10)	2.435 (10)
Ca22—O15^vii	2.440 (12)	2.379 (12)	2.467 (12)
Na2—O2^vi	2.659 (12)	2.476 (11)	2.847 (12)
Na2—O5^viii	2.391 (12)	2.266 (13)	2.516 (13)
Na2—O8^v	2.429 (11)	2.383 (12)	2.473 (12)
Na2—O11^vi	2.310 (11)	2.287 (11)	2.334 (11)
Na2—O15^vii	2.569 (15)	2.501 (14)	2.637 (14)
Si1—O5	1.672 (10)	1.627 (10)	1.718 (10)
Si1—O12	1.644 (7)	1.602 (7)	1.686 (7)
Si1—O14	1.636 (11)	1.598 (11)	1.668 (11)
Si1—O16	1.672 (8)	1.625 (8)	1.719 (8)
Si2—O1^ix	1.630 (7)	1.588 (7)	1.671 (7)
Si2—O3ⁱ	1.650 (11)	1.611 (11)	1.689 (11)
Si2—O10ⁱⁱ	1.601 (8)	1.562 (8)	1.639 (8)
Si2—O11	1.682 (7)	1.641 (7)	1.724 (7)
Si3—O4^x	1.679 (8)	1.652 (8)	1.704 (8)
Si3—O6^xi	1.627 (7)	1.604 (7)	1.651 (7)
Si3—O8^xi	1.645 (10)	1.596 (10)	1.688 (10)
Si3—O16	1.631 (8)	1.603 (8)	1.655 (8)
Si4—O2	1.649 (8)	1.605 (8)	1.688 (8)
Si4—O9^ix	1.632 (10)	1.594 (10)	1.666 (10)
Si4—O11	1.652 (7)	1.618 (8)	1.684 (7)
Si4—O12^ix	1.628 (8)	1.597 (8)	1.657 (8)
Si5—O1	1.726 (7)	1.685 (7)	1.767 (7)
Si5—O7	1.645 (7)	1.608 (7)	1.683 (7)
Si5—O8^xii	1.722 (9)	1.656 (9)	1.786 (9)
Si5—O13^xiii	1.719 (9)	1.682 (9)	1.756 (9)
Si6—O5^xiv	1.688 (10)	1.630 (10)	1.747 (10)
Si6—O9^xv	1.669 (9)	1.632 (9)	1.705 (9)
Si6—O10	1.730 (8)	1.682 (8)	1.777 (8)
Si6—O15^xvi	1.661 (8)	1.610 (7)	1.712 (8)
Si7—O4	1.660 (7)	1.621 (7)	1.700 (7)
Si7—O7	1.660 (8)	1.607 (8)	1.713 (8)
Si7—O14^xii	1.635 (12)	1.588 (12)	1.683 (12)
Si7—O15^xi	1.668 (7)	1.631 (7)	1.705 (7)
Si8—O2	1.642 (8)	1.591 (8)	1.692 (8)
Si8—O3	1.615 (11)	1.568 (11)	1.659 (11)
Si8—O6	1.654 (7)	1.614 (7)	1.696 (7)
Si8—O13	1.626 (9)	1.582 (9)	1.668 (9)

Na1—Ca1—Ca21^xvii	0	0	0
Na1—Ca1—Ca22^xvii	0	0	0
Na1—Ca1—Na2^xvii	0	0	0
Na1—Ca1—Si1ⁱ	0	0	0
Na1—Ca1—Al1ⁱ	0	0	0
Na1—Ca1—Al2^xii	0	0	0
Na1—Ca1—Si3^xviii	0	0	0
Na1—Ca1—Al3^xviii	0	0	0
Na1—Ca1—Al4^xii	0	0	0
Na1—Ca1—Al4^xiii	0	0	0
Na1—Ca1—Si5ⁱ	0	0	0
Na1—Ca1—Al5ⁱ	0	0	0
Na1—Ca1—Si6^xix	0	0	0
Na1—Ca1—Al6^xix	0	0	0
Na1—Ca1—Si7	0	0	0
Na1—Ca1—Al7	0	0	0
Na1—Ca1—Si8ⁱⁱⁱ	0	0	0
Na1—Ca1—Al8ⁱⁱⁱ	0	0	0
Na1—Ca1—O1ⁱ	0	0	0
Na1—Ca1—O4	0	0	0
Na1—Ca1—O5ⁱ	0	0	0
Na1—Ca1—O9ⁱⁱ	0	0	0
Na1—Ca1—O13ⁱⁱⁱ	0	0	0
Ca21^xvii—Ca1—Ca22^xvii	12.54 (12)	12.54 (12)	12.54 (12)
Ca21^xvii—Ca1—Na2^xvii	15.22 (17)	14.65 (17)	15.59 (17)
Ca21^xvii—Ca1—Si1ⁱ	64.08 (8)	63.05 (8)	66.07 (8)
Ca21^xvii—Ca1—Al1ⁱ	64.08 (8)	63.05 (8)	66.07 (8)
Ca21^xvii—Ca1—Al2^xii	96.60 (11)	96.33 (11)	96.87 (11)
Ca21^xvii—Ca1—Si3^xviii	151.73 (14)	140.18 (14)	157.40 (15)
Ca21^xvii—Ca1—Al3^xviii	151.73 (14)	140.18 (14)	157.40 (15)
Ca21^xvii—Ca1—Al4^xiii	93.97 (10)	91.65 (10)	95.73 (10)
Ca21^xvii—Ca1—Si5ⁱ	50.38 (8)	48.52 (7)	51.28 (8)
Ca21^xvii—Ca1—Al5ⁱ	50.38 (8)	48.52 (7)	51.28 (8)
Ca21^xvii—Ca1—Si6^xix	53.78 (8)	53.03 (8)	55.48 (8)
Ca21^xvii—Ca1—Al6^xix	53.78 (8)	53.03 (8)	55.48 (8)
Ca21^xvii—Ca1—Si7	155.54 (13)	151.25 (13)	164.10 (14)
Ca21^xvii—Ca1—Al7	155.54 (13)	151.25 (13)	164.10 (14)
Ca21^xvii—Ca1—Si8ⁱⁱⁱ	49.29 (9)	46.65 (8)	50.53 (9)
Ca21^xvii—Ca1—Al8ⁱⁱⁱ	49.29 (9)	46.65 (8)	50.53 (9)
Ca21^xvii—Ca1—O1ⁱ	77.92 (18)	76.25 (18)	79.36 (18)
Ca21^xvii—Ca1—O4	170.8 (2)	161.6 (3)	176.4 (3)
Ca21^xvii—Ca1—O5ⁱ	46.03 (18)	45.39 (18)	47.20 (18)
Ca21^xvii—Ca1—O9ⁱⁱ	75.78 (19)	74.15 (19)	78.22 (19)
Ca21^xvii—Ca1—O13ⁱⁱⁱ	35.10 (18)	33.85 (18)	35.77 (18)
Ca22^xvii—Ca1—Na2^xvii	2.9 (2)	2.4 (2)	3.4 (2)
Ca22^xvii—Ca1—Si1ⁱ	53.53 (13)	51.36 (12)	54.43 (13)
Ca22^xvii—Ca1—Al1ⁱ	53.53 (13)	51.36 (12)	54.43 (13)
Ca22^xvii—Ca1—Al2^xii	95.99 (15)	94.77 (15)	96.40 (15)
Ca22^xvii—Ca1—Si3^xviii	152.97 (17)	148.13 (17)	163.90 (17)
Ca22^xvii—Ca1—Al3^xviii	152.97 (17)	148.13 (17)	163.90 (17)
Ca22^xvii—Ca1—Al4^xii	93.98 (16)	89.67 (15)	95.99 (16)
Ca22^xvii—Ca1—Al4^xiii	95.73 (15)	94.18 (15)	97.28 (15)
Ca22^xvii—Ca1—Si5ⁱ	54.60 (12)	53.91 (12)	55.93 (12)
Ca22^xvii—Ca1—Al5ⁱ	54.60 (12)	53.91 (12)	55.93 (12)
Ca22^xvii—Ca1—Si6^xix	50.99 (13)	49.24 (13)	51.89 (13)
Ca22^xvii—Ca1—Al6^xix	50.99 (13)	49.24 (13)	51.89 (13)
Ca22^xvii—Ca1—Si7	154.66 (17)	144.23 (17)	159.24 (17)
Ca22^xvii—Ca1—Al7	154.66 (17)	144.23 (17)	159.24 (17)
Ca22^xvii—Ca1—Si8ⁱⁱⁱ	58.32 (13)	57.06 (13)	61.08 (13)
Ca22^xvii—Ca1—Al8ⁱⁱⁱ	58.32 (13)	57.06 (13)	61.08 (13)
Ca22^xvii—Ca1—O1ⁱ	79.2 (2)	78.1 (2)	80.1 (2)
Ca22^xvii—Ca1—O4	171.6 (3)	167.9 (3)	177.8 (3)
Ca22^xvii—Ca1—O5ⁱ	36.7 (2)	35.4 (2)	37.4 (2)
Ca22^xvii—Ca1—O9ⁱⁱ	76.3 (2)	74.1 (2)	77.6 (2)
Ca22^xvii—Ca1—O13ⁱⁱⁱ	44.7 (2)	44.2 (2)	46.1 (2)
Na2^xvii—Ca1—Si1ⁱ	49.97 (15)	48.03 (15)	51.79 (16)
Na2^xvii—Ca1—Al1ⁱ	49.97 (15)	48.03 (15)	51.79 (16)
Na2^xvii—Ca1—Al2^xii	93.40 (18)	91.96 (17)	94.48 (17)
Na2^xvii—Ca1—Si3^xviii	159.79 (18)	150.14 (18)	169.17 (19)
Na2^xvii—Ca1—Al3^xviii	159.79 (18)	150.14 (18)	169.17 (19)
Na2^xvii—Ca1—Al4^xii	89.32 (18)	85.70 (17)	92.77 (17)
Na2^xvii—Ca1—Al4^xiii	97.66 (17)	96.59 (16)	99.27 (17)
Na2^xvii—Ca1—Si5ⁱ	54.80 (15)	53.81 (14)	55.65 (15)
Na2^xvii—Ca1—Al5ⁱ	54.80 (15)	53.81 (14)	55.65 (15)
Na2^xvii—Ca1—Si6^xix	50.43 (16)	47.96 (17)	52.93 (17)
Na2^xvii—Ca1—Al6^xix	50.43 (16)	47.96 (17)	52.93 (17)
Na2^xvii—Ca1—Si7	147.99 (18)	138.08 (18)	158.01 (19)
Na2^xvii—Ca1—Al7	147.99 (18)	138.08 (18)	158.01 (19)
Na2^xvii—Ca1—Si8ⁱⁱⁱ	62.65 (15)	59.63 (17)	65.69 (16)
Na2^xvii—Ca1—Al8ⁱⁱⁱ	62.65 (15)	59.63 (17)	65.69 (16)
Na2^xvii—Ca1—O1ⁱ	77.4 (2)	76.7 (2)	78.5 (2)
Na2^xvii—Ca1—O4	169.2 (3)	159.1 (3)	179.6 (3)
Na2^xvii—Ca1—O5ⁱ	34.2 (2)	32.0 (2)	36.4 (2)
Na2^xvii—Ca1—O9ⁱⁱ	77.3 (2)	75.4 (3)	79.4 (2)
Na2^xvii—Ca1—O13ⁱⁱⁱ	47.4 (2)	45.6 (2)	49.3 (2)
Si1ⁱ—Ca1—Al1ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si1ⁱ—Ca1—Al2^xii	83.68 (12)	79.60 (11)	87.71 (12)
Si1ⁱ—Ca1—Si3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Si1ⁱ—Ca1—Al3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Si1ⁱ—Ca1—Al4^xii	49.68 (8)	46.50 (7)	52.94 (9)
Si1ⁱ—Ca1—Al4^xiii	105.24 (12)	100.38 (12)	109.86 (12)
Si1ⁱ—Ca1—Si5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Si1ⁱ—Ca1—Al5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Si1ⁱ—Ca1—Si6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Si1ⁱ—Ca1—Al6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Si1ⁱ—Ca1—Si7	100.41 (13)	92.09 (12)	109.12 (14)
Si1ⁱ—Ca1—Al7	100.41 (13)	92.09 (12)	109.12 (14)
Si1ⁱ—Ca1—Si8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Si1ⁱ—Ca1—Al8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Si1ⁱ—Ca1—O1ⁱ	83.4 (2)	79.1 (2)	87.6 (2)
Si1ⁱ—Ca1—O4	124.3 (2)	111.7 (2)	137.1 (2)
Si1ⁱ—Ca1—O5ⁱ	27.7 (2)	24.81 (18)	30.5 (2)
Si1ⁱ—Ca1—O9ⁱⁱ	85.1 (2)	80.4 (2)	89.6 (2)
Si1ⁱ—Ca1—O13ⁱⁱⁱ	94.9 (2)	92.7 (2)	96.9 (2)
Al1ⁱ—Ca1—Al2^xii	83.68 (12)	79.60 (11)	87.71 (12)
Al1ⁱ—Ca1—Si3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Al1ⁱ—Ca1—Al3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Al1ⁱ—Ca1—Al4^xii	49.68 (8)	46.50 (7)	52.94 (9)
Al1ⁱ—Ca1—Al4^xiii	105.24 (12)	100.38 (12)	109.86 (12)
Al1ⁱ—Ca1—Si5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Al1ⁱ—Ca1—Al5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Al1ⁱ—Ca1—Si6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Al1ⁱ—Ca1—Al6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Al1ⁱ—Ca1—Si7	100.41 (13)	92.09 (12)	109.12 (14)
Al1ⁱ—Ca1—Al7	100.41 (13)	92.09 (12)	109.12 (14)
Al1ⁱ—Ca1—Si8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Al1ⁱ—Ca1—Al8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Al1ⁱ—Ca1—O1ⁱ	83.4 (2)	79.1 (2)	87.6 (2)
Al1ⁱ—Ca1—O4	124.3 (2)	111.7 (2)	137.1 (2)
Al1ⁱ—Ca1—O5ⁱ	27.7 (2)	24.81 (18)	30.5 (2)
Al1ⁱ—Ca1—O9ⁱⁱ	85.1 (2)	80.4 (2)	89.6 (2)
Al1ⁱ—Ca1—O13ⁱⁱⁱ	94.9 (2)	92.7 (2)	96.9 (2)
Al2^xii—Ca1—Si3^xviii	79.89 (10)	78.21 (10)	81.61 (10)
Al2^xii—Ca1—Al3^xviii	79.89 (10)	78.21 (10)	81.61 (10)
Al2^xii—Ca1—Al4^xii	45.60 (8)	43.79 (8)	47.33 (8)
Al2^xii—Ca1—Al4^xiii	166.55 (11)	162.51 (13)	170.01 (10)
Al2^xii—Ca1—Si5ⁱ	52.60 (9)	51.78 (9)	53.40 (9)
Al2^xii—Ca1—Al5ⁱ	52.60 (9)	51.78 (9)	53.40 (9)
Al2^xii—Ca1—Si6^xix	137.30 (14)	131.26 (14)	142.99 (14)
Al2^xii—Ca1—Al6^xix	137.30 (14)	131.26 (14)	142.99 (14)
Al2^xii—Ca1—Si7	94.27 (10)	92.50 (10)	95.95 (10)
Al2^xii—Ca1—Al7	94.27 (10)	92.50 (10)	95.95 (10)
Al2^xii—Ca1—Si8ⁱⁱⁱ	102.57 (12)	99.11 (11)	105.93 (12)
Al2^xii—Ca1—Al8ⁱⁱⁱ	102.57 (12)	99.11 (11)	105.93 (12)
Al2^xii—Ca1—O1ⁱ	20.63 (16)	18.99 (16)	22.27 (16)
Al2^xii—Ca1—O4	88.4 (2)	86.4 (2)	91.0 (2)
Al2^xii—Ca1—O5ⁱ	105.8 (3)	99.6 (2)	111.8 (3)
Al2^xii—Ca1—O9ⁱⁱ	167.2 (2)	159.9 (3)	173.2 (2)
Al2^xii—Ca1—O13ⁱⁱⁱ	84.2 (2)	84.0 (2)	84.5 (2)
Si3^xviii—Ca1—Al3^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xviii—Ca1—Al4^xii	98.97 (10)	94.61 (10)	102.81 (10)
Si3^xviii—Ca1—Al4^xiii	88.11 (11)	85.02 (11)	90.73 (11)
Si3^xviii—Ca1—Si5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Si3^xviii—Ca1—Al5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Si3^xviii—Ca1—Si6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Si3^xviii—Ca1—Al6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Si3^xviii—Ca1—Si7	51.73 (8)	51.17 (7)	52.13 (8)
Si3^xviii—Ca1—Al7	51.73 (8)	51.17 (7)	52.13 (8)
Si3^xviii—Ca1—Si8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Si3^xviii—Ca1—Al8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Si3^xviii—Ca1—O1ⁱ	91.0 (2)	87.1 (2)	94.8 (2)
Si3^xviii—Ca1—O4	26.48 (18)	22.40 (18)	30.12 (17)
Si3^xviii—Ca1—O5ⁱ	164.3 (2)	156.8 (2)	169.6 (3)
Si3^xviii—Ca1—O9ⁱⁱ	110.2 (2)	106.9 (2)	112.8 (2)
Si3^xviii—Ca1—O13ⁱⁱⁱ	112.8 (2)	103.5 (2)	122.5 (2)
Al3^xviii—Ca1—Al4^xii	98.97 (10)	94.61 (10)	102.81 (10)
Al3^xviii—Ca1—Al4^xiii	88.11 (11)	85.02 (11)	90.73 (11)
Al3^xviii—Ca1—Si5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Al3^xviii—Ca1—Al5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Al3^xviii—Ca1—Si6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Al3^xviii—Ca1—Al6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Al3^xviii—Ca1—Si7	51.73 (8)	51.17 (7)	52.13 (8)
Al3^xviii—Ca1—Al7	51.73 (8)	51.17 (7)	52.13 (8)
Al3^xviii—Ca1—Si8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Al3^xviii—Ca1—Al8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Al3^xviii—Ca1—O1ⁱ	91.0 (2)	87.1 (2)	94.8 (2)
Al3^xviii—Ca1—O4	26.48 (18)	22.40 (18)	30.12 (17)
Al3^xviii—Ca1—O5ⁱ	164.3 (2)	156.8 (2)	169.6 (3)
Al3^xviii—Ca1—O9ⁱⁱ	110.2 (2)	106.9 (2)	112.8 (2)
Al3^xviii—Ca1—O13ⁱⁱⁱ	112.8 (2)	103.5 (2)	122.5 (2)
Al4^xii—Ca1—Al4^xiii	136.25 (13)	128.17 (12)	144.29 (13)
Al4^xii—Ca1—Si5ⁱ	84.34 (12)	81.53 (11)	87.01 (12)
Al4^xii—Ca1—Al5ⁱ	84.34 (12)	81.53 (11)	87.01 (12)
Al4^xii—Ca1—Si6^xix	104.62 (13)	98.17 (12)	111.14 (13)
Al4^xii—Ca1—Al6^xix	104.62 (13)	98.17 (12)	111.14 (13)
Al4^xii—Ca1—Si7	74.65 (10)	69.74 (9)	79.68 (11)
Al4^xii—Ca1—Al7	74.65 (10)	69.74 (9)	79.68 (11)
Al4^xii—Ca1—Si8ⁱⁱⁱ	138.24 (13)	136.75 (13)	139.97 (13)
Al4^xii—Ca1—Al8ⁱⁱⁱ	138.24 (13)	136.75 (13)	139.97 (13)
Al4^xii—Ca1—O1ⁱ	59.2 (2)	55.75 (19)	62.6 (2)
Al4^xii—Ca1—O4	87.7 (2)	80.1 (2)	95.0 (2)
Al4^xii—Ca1—O5ⁱ	77.3 (2)	71.3 (2)	83.4 (2)
Al4^xii—Ca1—O9ⁱⁱ	126.3 (2)	117.8 (2)	134.9 (2)
Al4^xii—Ca1—O13ⁱⁱⁱ	114.0 (2)	110.8 (3)	116.9 (2)
Al4^xiii—Ca1—Si5ⁱ	133.92 (12)	126.46 (13)	141.06 (11)
Al4^xiii—Ca1—Al5ⁱ	133.92 (12)	126.46 (13)	141.06 (11)
Al4^xiii—Ca1—Si6^xix	53.56 (10)	53.09 (10)	54.25 (10)
Al4^xiii—Ca1—Al6^xix	53.56 (10)	53.09 (10)	54.25 (10)
Al4^xiii—Ca1—Si7	76.64 (10)	74.40 (9)	78.38 (10)
Al4^xiii—Ca1—Al7	76.64 (10)	74.40 (9)	78.38 (10)
Al4^xiii—Ca1—Si8ⁱⁱⁱ	80.91 (11)	75.87 (10)	86.00 (12)
Al4^xiii—Ca1—Al8ⁱⁱⁱ	80.91 (11)	75.87 (10)	86.00 (12)
Al4^xiii—Ca1—O1ⁱ	163.8 (2)	153.4 (2)	173.69 (19)
Al4^xiii—Ca1—O4	79.6 (2)	78.8 (2)	81.1 (2)
Al4^xiii—Ca1—O5ⁱ	84.8 (2)	83.4 (2)	86.7 (2)
Al4^xiii—Ca1—O9ⁱⁱ	22.4 (2)	21.9 (2)	22.7 (2)
Al4^xiii—Ca1—O13ⁱⁱⁱ	101.7 (2)	94.6 (2)	108.8 (2)
Si5ⁱ—Ca1—Al5ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si5ⁱ—Ca1—Si6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Si5ⁱ—Ca1—Al6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Si5ⁱ—Ca1—Si7	145.50 (13)	144.28 (14)	147.75 (13)
Si5ⁱ—Ca1—Al7	145.50 (13)	144.28 (14)	147.75 (13)
Si5ⁱ—Ca1—Si8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Si5ⁱ—Ca1—Al8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Si5ⁱ—Ca1—O1ⁱ	31.97 (16)	31.09 (16)	32.84 (16)
Si5ⁱ—Ca1—O4	129.9 (2)	122.2 (2)	136.7 (2)
Si5ⁱ—Ca1—O5ⁱ	85.7 (2)	83.4 (2)	87.9 (2)
Si5ⁱ—Ca1—O9ⁱⁱ	123.54 (19)	118.46 (19)	128.26 (18)
Si5ⁱ—Ca1—O13ⁱⁱⁱ	32.3 (2)	31.78 (19)	32.9 (2)
Al5ⁱ—Ca1—Si6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Al5ⁱ—Ca1—Al6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Al5ⁱ—Ca1—Si7	145.50 (13)	144.28 (14)	147.75 (13)
Al5ⁱ—Ca1—Al7	145.50 (13)	144.28 (14)	147.75 (13)
Al5ⁱ—Ca1—Si8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Al5ⁱ—Ca1—Al8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Al5ⁱ—Ca1—O1ⁱ	31.97 (16)	31.09 (16)	32.84 (16)
Al5ⁱ—Ca1—O4	129.9 (2)	122.2 (2)	136.7 (2)
Al5ⁱ—Ca1—O5ⁱ	85.7 (2)	83.4 (2)	87.9 (2)
Al5ⁱ—Ca1—O9ⁱⁱ	123.54 (19)	118.46 (19)	128.26 (18)
Al5ⁱ—Ca1—O13ⁱⁱⁱ	32.3 (2)	31.78 (19)	32.9 (2)
Si6^xix—Ca1—Al6^xix	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xix—Ca1—Si7	106.10 (13)	100.61 (12)	111.30 (14)
Si6^xix—Ca1—Al7	106.10 (13)	100.61 (12)	111.30 (14)
Si6^xix—Ca1—Si8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Si6^xix—Ca1—Al8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Si6^xix—Ca1—O1ⁱ	126.5 (2)	122.5 (2)	130.5 (2)
Si6^xix—Ca1—O4	123.9 (2)	118.4 (2)	128.1 (3)
Si6^xix—Ca1—O5ⁱ	31.7 (2)	30.8 (2)	32.8 (2)
Si6^xix—Ca1—O9ⁱⁱ	31.2 (2)	30.7 (2)	31.8 (2)
Si6^xix—Ca1—O13ⁱⁱⁱ	84.27 (17)	82.32 (16)	85.90 (18)
Al6^xix—Ca1—Si7	106.10 (13)	100.61 (12)	111.30 (14)
Al6^xix—Ca1—Al7	106.10 (13)	100.61 (12)	111.30 (14)
Al6^xix—Ca1—Si8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Al6^xix—Ca1—Al8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Al6^xix—Ca1—O1ⁱ	126.5 (2)	122.5 (2)	130.5 (2)
Al6^xix—Ca1—O4	123.9 (2)	118.4 (2)	128.1 (3)
Al6^xix—Ca1—O5ⁱ	31.7 (2)	30.8 (2)	32.8 (2)
Al6^xix—Ca1—O9ⁱⁱ	31.2 (2)	30.7 (2)	31.8 (2)
Al6^xix—Ca1—O13ⁱⁱⁱ	84.27 (17)	82.32 (16)	85.90 (18)
Si7—Ca1—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Si7—Ca1—Si8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Si7—Ca1—Al8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Si7—Ca1—O1ⁱ	114.50 (19)	111.54 (19)	117.59 (19)
Si7—Ca1—O4	25.37 (18)	21.13 (18)	29.40 (18)
Si7—Ca1—O5ⁱ	114.0 (2)	105.8 (2)	122.3 (2)
Si7—Ca1—O9ⁱⁱ	89.5 (2)	85.37 (19)	93.2 (2)
Si7—Ca1—O13ⁱⁱⁱ	164.2 (2)	154.3 (2)	173.4 (2)
Al7—Ca1—Si8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Al7—Ca1—Al8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Al7—Ca1—O1ⁱ	114.50 (19)	111.54 (19)	117.59 (19)
Al7—Ca1—O4	25.37 (18)	21.13 (18)	29.40 (18)
Al7—Ca1—O5ⁱ	114.0 (2)	105.8 (2)	122.3 (2)
Al7—Ca1—O9ⁱⁱ	89.5 (2)	85.37 (19)	93.2 (2)
Al7—Ca1—O13ⁱⁱⁱ	164.2 (2)	154.3 (2)	173.4 (2)
Si8ⁱⁱⁱ—Ca1—Al8ⁱⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si8ⁱⁱⁱ—Ca1—O1ⁱ	83.6 (2)	78.9 (2)	88.2 (2)
Si8ⁱⁱⁱ—Ca1—O4	122.8 (2)	111.2 (2)	134.5 (3)
Si8ⁱⁱⁱ—Ca1—O5ⁱ	91.43 (18)	88.91 (19)	93.66 (17)
Si8ⁱⁱⁱ—Ca1—O9ⁱⁱ	79.56 (19)	74.39 (19)	84.66 (19)
Si8ⁱⁱⁱ—Ca1—O13ⁱⁱⁱ	24.4 (2)	21.0 (2)	27.9 (2)
Al8ⁱⁱⁱ—Ca1—O1ⁱ	83.6 (2)	78.9 (2)	88.2 (2)
Al8ⁱⁱⁱ—Ca1—O4	122.8 (2)	111.2 (2)	134.5 (3)
Al8ⁱⁱⁱ—Ca1—O5ⁱ	91.43 (18)	88.91 (19)	93.66 (17)
Al8ⁱⁱⁱ—Ca1—O9ⁱⁱ	79.56 (19)	74.39 (19)	84.66 (19)
Al8ⁱⁱⁱ—Ca1—O13ⁱⁱⁱ	24.4 (2)	21.0 (2)	27.9 (2)
O1ⁱ—Ca1—O4	105.4 (3)	101.5 (3)	109.8 (3)
O1ⁱ—Ca1—O5ⁱ	98.3 (3)	93.1 (3)	103.4 (3)
O1ⁱ—Ca1—O9ⁱⁱ	153.0 (3)	149.4 (2)	157.5 (3)
O1ⁱ—Ca1—O13ⁱⁱⁱ	63.8 (3)	62.1 (2)	65.4 (3)
O4—Ca1—O5ⁱ	138.7 (3)	127.0 (3)	149.8 (3)
O4—Ca1—O9ⁱⁱ	98.8 (3)	96.5 (3)	100.3 (3)
O4—Ca1—O13ⁱⁱⁱ	139.0 (3)	125.4 (3)	152.5 (3)
O5ⁱ—Ca1—O9ⁱⁱ	62.7 (3)	61.2 (3)	64.4 (3)
O5ⁱ—Ca1—O13ⁱⁱⁱ	80.9 (3)	80.4 (3)	81.2 (3)
O9ⁱⁱ—Ca1—O13ⁱⁱⁱ	94.1 (2)	88.2 (2)	99.7 (2)
Ca1—Na1—Ca21^xvii	0	0	0
Ca1—Na1—Ca22^xvii	0	0	0
Ca1—Na1—Na2^xvii	0	0	0
Ca1—Na1—Si1ⁱ	0	0	0
Ca1—Na1—Al1ⁱ	0	0	0
Ca1—Na1—Al2^xii	0	0	0
Ca1—Na1—Si3^xviii	0	0	0
Ca1—Na1—Al3^xviii	0	0	0
Ca1—Na1—Al4^xiii	0	0	0
Ca1—Na1—Si5ⁱ	0	0	0
Ca1—Na1—Al5ⁱ	0	0	0
Ca1—Na1—Si6^xix	0	0	0
Ca1—Na1—Al6^xix	0	0	0
Ca1—Na1—Si7	0	0	0
Ca1—Na1—Al7	0	0	0
Ca1—Na1—Si8ⁱⁱⁱ	0	0	0
Ca1—Na1—Al8ⁱⁱⁱ	0	0	0
Ca1—Na1—O1ⁱ	0	0	0
Ca1—Na1—O4	0	0	0
Ca1—Na1—O5ⁱ	0	0	0
Ca1—Na1—O9ⁱⁱ	0	0	0
Ca1—Na1—O13ⁱⁱⁱ	0	0	0
Ca21^xvii—Na1—Ca22^xvii	12.54 (12)	12.54 (12)	12.54 (12)
Ca21^xvii—Na1—Na2^xvii	15.22 (17)	14.65 (17)	15.59 (17)
Ca21^xvii—Na1—Si1ⁱ	64.08 (8)	63.05 (8)	66.07 (8)
Ca21^xvii—Na1—Al1ⁱ	64.08 (8)	63.05 (8)	66.07 (8)
Ca21^xvii—Na1—Al2^xii	96.60 (11)	96.33 (11)	96.87 (11)
Ca21^xvii—Na1—Si3^xviii	151.73 (14)	140.18 (14)	157.40 (15)
Ca21^xvii—Na1—Al3^xviii	151.73 (14)	140.18 (14)	157.40 (15)
Ca21^xvii—Na1—Al4^xiii	93.97 (10)	91.65 (10)	95.73 (10)
Ca21^xvii—Na1—Si5ⁱ	50.38 (8)	48.52 (7)	51.28 (8)
Ca21^xvii—Na1—Al5ⁱ	50.38 (8)	48.52 (7)	51.28 (8)
Ca21^xvii—Na1—Si6^xix	53.78 (8)	53.03 (8)	55.48 (8)
Ca21^xvii—Na1—Al6^xix	53.78 (8)	53.03 (8)	55.48 (8)
Ca21^xvii—Na1—Si7	155.54 (13)	151.25 (13)	164.10 (14)
Ca21^xvii—Na1—Al7	155.54 (13)	151.25 (13)	164.10 (14)
Ca21^xvii—Na1—Si8ⁱⁱⁱ	49.29 (9)	46.65 (8)	50.53 (9)
Ca21^xvii—Na1—Al8ⁱⁱⁱ	49.29 (9)	46.65 (8)	50.53 (9)
Ca21^xvii—Na1—O1ⁱ	77.92 (18)	76.25 (18)	79.36 (18)
Ca21^xvii—Na1—O4	170.8 (2)	161.6 (3)	176.4 (3)
Ca21^xvii—Na1—O5ⁱ	46.03 (18)	45.39 (18)	47.20 (18)
Ca21^xvii—Na1—O9ⁱⁱ	75.78 (19)	74.15 (19)	78.22 (19)
Ca21^xvii—Na1—O13ⁱⁱⁱ	35.10 (18)	33.85 (18)	35.77 (18)
Ca22^xvii—Na1—Na2^xvii	2.9 (2)	2.4 (2)	3.4 (2)
Ca22^xvii—Na1—Si1ⁱ	53.53 (13)	51.36 (12)	54.43 (13)
Ca22^xvii—Na1—Al1ⁱ	53.53 (13)	51.36 (12)	54.43 (13)
Ca22^xvii—Na1—Al2^xii	95.99 (15)	94.77 (15)	96.40 (15)
Ca22^xvii—Na1—Si3^xviii	152.97 (17)	148.13 (17)	163.90 (17)
Ca22^xvii—Na1—Al3^xviii	152.97 (17)	148.13 (17)	163.90 (17)
Ca22^xvii—Na1—Al4^xiii	95.73 (15)	94.18 (15)	97.28 (15)
Ca22^xvii—Na1—Si5ⁱ	54.60 (12)	53.91 (12)	55.93 (12)
Ca22^xvii—Na1—Al5ⁱ	54.60 (12)	53.91 (12)	55.93 (12)
Ca22^xvii—Na1—Si6^xix	50.99 (13)	49.24 (13)	51.89 (13)
Ca22^xvii—Na1—Al6^xix	50.99 (13)	49.24 (13)	51.89 (13)
Ca22^xvii—Na1—Si7	154.66 (17)	144.23 (17)	159.24 (17)
Ca22^xvii—Na1—Al7	154.66 (17)	144.23 (17)	159.24 (17)
Ca22^xvii—Na1—Si8ⁱⁱⁱ	58.32 (13)	57.06 (13)	61.08 (13)
Ca22^xvii—Na1—Al8ⁱⁱⁱ	58.32 (13)	57.06 (13)	61.08 (13)
Ca22^xvii—Na1—O1ⁱ	79.2 (2)	78.1 (2)	80.1 (2)
Ca22^xvii—Na1—O4	171.6 (3)	167.9 (3)	177.8 (3)
Ca22^xvii—Na1—O5ⁱ	36.7 (2)	35.4 (2)	37.4 (2)
Ca22^xvii—Na1—O9ⁱⁱ	76.3 (2)	74.1 (2)	77.6 (2)
Ca22^xvii—Na1—O13ⁱⁱⁱ	44.7 (2)	44.2 (2)	46.1 (2)
Na2^xvii—Na1—Si1ⁱ	49.97 (15)	48.03 (15)	51.79 (16)
Na2^xvii—Na1—Al1ⁱ	49.97 (15)	48.03 (15)	51.79 (16)
Na2^xvii—Na1—Al2^xii	93.40 (18)	91.96 (17)	94.48 (17)
Na2^xvii—Na1—Si3^xviii	159.79 (18)	150.14 (18)	169.17 (19)
Na2^xvii—Na1—Al3^xviii	159.79 (18)	150.14 (18)	169.17 (19)
Na2^xvii—Na1—Al4^xiii	97.66 (17)	96.59 (16)	99.27 (17)
Na2^xvii—Na1—Si5ⁱ	54.80 (15)	53.81 (14)	55.65 (15)
Na2^xvii—Na1—Al5ⁱ	54.80 (15)	53.81 (14)	55.65 (15)
Na2^xvii—Na1—Si6^xix	50.43 (16)	47.96 (17)	52.93 (17)
Na2^xvii—Na1—Al6^xix	50.43 (16)	47.96 (17)	52.93 (17)
Na2^xvii—Na1—Si7	147.99 (18)	138.08 (18)	158.01 (19)
Na2^xvii—Na1—Al7	147.99 (18)	138.08 (18)	158.01 (19)
Na2^xvii—Na1—Si8ⁱⁱⁱ	62.65 (15)	59.63 (17)	65.69 (16)
Na2^xvii—Na1—Al8ⁱⁱⁱ	62.65 (15)	59.63 (17)	65.69 (16)
Na2^xvii—Na1—O1ⁱ	77.4 (2)	76.7 (2)	78.5 (2)
Na2^xvii—Na1—O4	169.2 (3)	159.1 (3)	179.6 (3)
Na2^xvii—Na1—O5ⁱ	34.2 (2)	32.0 (2)	36.4 (2)
Na2^xvii—Na1—O9ⁱⁱ	77.3 (2)	75.4 (3)	79.4 (2)
Na2^xvii—Na1—O13ⁱⁱⁱ	47.4 (2)	45.6 (2)	49.3 (2)
Si1ⁱ—Na1—Al1ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si1ⁱ—Na1—Al2^xii	83.68 (12)	79.60 (11)	87.71 (12)
Si1ⁱ—Na1—Si3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Si1ⁱ—Na1—Al3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Si1ⁱ—Na1—Al4^xiii	105.24 (12)	100.38 (12)	109.86 (12)
Si1ⁱ—Na1—Si5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Si1ⁱ—Na1—Al5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Si1ⁱ—Na1—Si6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Si1ⁱ—Na1—Al6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Si1ⁱ—Na1—Si7	100.41 (13)	92.09 (12)	109.12 (14)
Si1ⁱ—Na1—Al7	100.41 (13)	92.09 (12)	109.12 (14)
Si1ⁱ—Na1—Si8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Si1ⁱ—Na1—Al8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Si1ⁱ—Na1—O1ⁱ	83.4 (2)	79.1 (2)	87.6 (2)
Si1ⁱ—Na1—O4	124.3 (2)	111.7 (2)	137.1 (2)
Si1ⁱ—Na1—O5ⁱ	27.7 (2)	24.81 (18)	30.5 (2)
Si1ⁱ—Na1—O9ⁱⁱ	85.1 (2)	80.4 (2)	89.6 (2)
Si1ⁱ—Na1—O13ⁱⁱⁱ	94.9 (2)	92.7 (2)	96.9 (2)
Al1ⁱ—Na1—Al2^xii	83.68 (12)	79.60 (11)	87.71 (12)
Al1ⁱ—Na1—Si3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Al1ⁱ—Na1—Al3^xviii	145.83 (13)	137.06 (13)	154.20 (13)
Al1ⁱ—Na1—Al4^xiii	105.24 (12)	100.38 (12)	109.86 (12)
Al1ⁱ—Na1—Si5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Al1ⁱ—Na1—Al5ⁱ	84.95 (11)	82.52 (11)	87.15 (11)
Al1ⁱ—Na1—Si6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Al1ⁱ—Na1—Al6^xix	56.71 (10)	53.52 (9)	59.87 (10)
Al1ⁱ—Na1—Si7	100.41 (13)	92.09 (12)	109.12 (14)
Al1ⁱ—Na1—Al7	100.41 (13)	92.09 (12)	109.12 (14)
Al1ⁱ—Na1—Si8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Al1ⁱ—Na1—Al8ⁱⁱⁱ	112.61 (9)	111.41 (9)	113.88 (10)
Al1ⁱ—Na1—O1ⁱ	83.4 (2)	79.1 (2)	87.6 (2)
Al1ⁱ—Na1—O4	124.3 (2)	111.7 (2)	137.1 (2)
Al1ⁱ—Na1—O5ⁱ	27.7 (2)	24.81 (18)	30.5 (2)
Al1ⁱ—Na1—O9ⁱⁱ	85.1 (2)	80.4 (2)	89.6 (2)
Al1ⁱ—Na1—O13ⁱⁱⁱ	94.9 (2)	92.7 (2)	96.9 (2)
Al2^xii—Na1—Si3^xviii	79.89 (10)	78.21 (10)	81.61 (10)
Al2^xii—Na1—Al3^xviii	79.89 (10)	78.21 (10)	81.61 (10)
Al2^xii—Na1—Al4^xiii	166.55 (11)	162.51 (13)	170.01 (10)
Al2^xii—Na1—Si5ⁱ	52.60 (9)	51.78 (9)	53.40 (9)
Al2^xii—Na1—Al5ⁱ	52.60 (9)	51.78 (9)	53.40 (9)
Al2^xii—Na1—Si6^xix	137.30 (14)	131.26 (14)	142.99 (14)
Al2^xii—Na1—Al6^xix	137.30 (14)	131.26 (14)	142.99 (14)
Al2^xii—Na1—Si7	94.27 (10)	92.50 (10)	95.95 (10)
Al2^xii—Na1—Al7	94.27 (10)	92.50 (10)	95.95 (10)
Al2^xii—Na1—Si8ⁱⁱⁱ	102.57 (12)	99.11 (11)	105.93 (12)
Al2^xii—Na1—Al8ⁱⁱⁱ	102.57 (12)	99.11 (11)	105.93 (12)
Al2^xii—Na1—O1ⁱ	20.63 (16)	18.99 (16)	22.27 (16)
Al2^xii—Na1—O4	88.4 (2)	86.4 (2)	91.0 (2)
Al2^xii—Na1—O5ⁱ	105.8 (3)	99.6 (2)	111.8 (3)
Al2^xii—Na1—O9ⁱⁱ	167.2 (2)	159.9 (3)	173.2 (2)
Al2^xii—Na1—O13ⁱⁱⁱ	84.2 (2)	84.0 (2)	84.5 (2)
Si3^xviii—Na1—Al3^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xviii—Na1—Al4^xiii	88.11 (11)	85.02 (11)	90.73 (11)
Si3^xviii—Na1—Si5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Si3^xviii—Na1—Al5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Si3^xviii—Na1—Si6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Si3^xviii—Na1—Al6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Si3^xviii—Na1—Si7	51.73 (8)	51.17 (7)	52.13 (8)
Si3^xviii—Na1—Al7	51.73 (8)	51.17 (7)	52.13 (8)
Si3^xviii—Na1—Si8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Si3^xviii—Na1—Al8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Si3^xviii—Na1—O1ⁱ	91.0 (2)	87.1 (2)	94.8 (2)
Si3^xviii—Na1—O4	26.48 (18)	22.40 (18)	30.12 (17)
Si3^xviii—Na1—O5ⁱ	164.3 (2)	156.8 (2)	169.6 (3)
Si3^xviii—Na1—O9ⁱⁱ	110.2 (2)	106.9 (2)	112.8 (2)
Si3^xviii—Na1—O13ⁱⁱⁱ	112.8 (2)	103.5 (2)	122.5 (2)
Al3^xviii—Na1—Al4^xiii	88.11 (11)	85.02 (11)	90.73 (11)
Al3^xviii—Na1—Si5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Al3^xviii—Na1—Al5ⁱ	107.56 (13)	101.29 (13)	113.68 (14)
Al3^xviii—Na1—Si6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Al3^xviii—Na1—Al6^xix	140.78 (16)	138.37 (16)	142.15 (16)
Al3^xviii—Na1—Si7	51.73 (8)	51.17 (7)	52.13 (8)
Al3^xviii—Na1—Al7	51.73 (8)	51.17 (7)	52.13 (8)
Al3^xviii—Na1—Si8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Al3^xviii—Na1—Al8ⁱⁱⁱ	100.15 (13)	92.20 (11)	108.66 (14)
Al3^xviii—Na1—O1ⁱ	91.0 (2)	87.1 (2)	94.8 (2)
Al3^xviii—Na1—O4	26.48 (18)	22.40 (18)	30.12 (17)
Al3^xviii—Na1—O5ⁱ	164.3 (2)	156.8 (2)	169.6 (3)
Al3^xviii—Na1—O9ⁱⁱ	110.2 (2)	106.9 (2)	112.8 (2)
Al3^xviii—Na1—O13ⁱⁱⁱ	112.8 (2)	103.5 (2)	122.5 (2)
Al4^xiii—Na1—Si5ⁱ	133.92 (12)	126.46 (13)	141.06 (11)
Al4^xiii—Na1—Al5ⁱ	133.92 (12)	126.46 (13)	141.06 (11)
Al4^xiii—Na1—Si6^xix	53.56 (10)	53.09 (10)	54.25 (10)
Al4^xiii—Na1—Al6^xix	53.56 (10)	53.09 (10)	54.25 (10)
Al4^xiii—Na1—Si7	76.64 (10)	74.40 (9)	78.38 (10)
Al4^xiii—Na1—Al7	76.64 (10)	74.40 (9)	78.38 (10)
Al4^xiii—Na1—Si8ⁱⁱⁱ	80.91 (11)	75.87 (10)	86.00 (12)
Al4^xiii—Na1—Al8ⁱⁱⁱ	80.91 (11)	75.87 (10)	86.00 (12)
Al4^xiii—Na1—O1ⁱ	163.8 (2)	153.4 (2)	173.69 (19)
Al4^xiii—Na1—O4	79.6 (2)	78.8 (2)	81.1 (2)
Al4^xiii—Na1—O5ⁱ	84.8 (2)	83.4 (2)	86.7 (2)
Al4^xiii—Na1—O9ⁱⁱ	22.4 (2)	21.9 (2)	22.7 (2)
Al4^xiii—Na1—O13ⁱⁱⁱ	101.7 (2)	94.6 (2)	108.8 (2)
Si5ⁱ—Na1—Al5ⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si5ⁱ—Na1—Si6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Si5ⁱ—Na1—Al6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Si5ⁱ—Na1—Si7	145.50 (13)	144.28 (14)	147.75 (13)
Si5ⁱ—Na1—Al7	145.50 (13)	144.28 (14)	147.75 (13)
Si5ⁱ—Na1—Si8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Si5ⁱ—Na1—Al8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Si5ⁱ—Na1—O1ⁱ	31.97 (16)	31.09 (16)	32.84 (16)
Si5ⁱ—Na1—O4	129.9 (2)	122.2 (2)	136.7 (2)
Si5ⁱ—Na1—O5ⁱ	85.7 (2)	83.4 (2)	87.9 (2)
Si5ⁱ—Na1—O9ⁱⁱ	123.54 (19)	118.46 (19)	128.26 (18)
Si5ⁱ—Na1—O13ⁱⁱⁱ	32.3 (2)	31.78 (19)	32.9 (2)
Al5ⁱ—Na1—Si6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Al5ⁱ—Na1—Al6^xix	104.14 (10)	102.62 (10)	106.21 (10)
Al5ⁱ—Na1—Si7	145.50 (13)	144.28 (14)	147.75 (13)
Al5ⁱ—Na1—Al7	145.50 (13)	144.28 (14)	147.75 (13)
Al5ⁱ—Na1—Si8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Al5ⁱ—Na1—Al8ⁱⁱⁱ	54.56 (10)	51.02 (9)	58.10 (10)
Al5ⁱ—Na1—O1ⁱ	31.97 (16)	31.09 (16)	32.84 (16)
Al5ⁱ—Na1—O4	129.9 (2)	122.2 (2)	136.7 (2)
Al5ⁱ—Na1—O5ⁱ	85.7 (2)	83.4 (2)	87.9 (2)
Al5ⁱ—Na1—O9ⁱⁱ	123.54 (19)	118.46 (19)	128.26 (18)
Al5ⁱ—Na1—O13ⁱⁱⁱ	32.3 (2)	31.78 (19)	32.9 (2)
Si6^xix—Na1—Al6^xix	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xix—Na1—Si7	106.10 (13)	100.61 (12)	111.30 (14)
Si6^xix—Na1—Al7	106.10 (13)	100.61 (12)	111.30 (14)
Si6^xix—Na1—Si8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Si6^xix—Na1—Al8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Si6^xix—Na1—O1ⁱ	126.5 (2)	122.5 (2)	130.5 (2)
Si6^xix—Na1—O4	123.9 (2)	118.4 (2)	128.1 (3)
Si6^xix—Na1—O5ⁱ	31.7 (2)	30.8 (2)	32.8 (2)
Si6^xix—Na1—O9ⁱⁱ	31.2 (2)	30.7 (2)	31.8 (2)
Si6^xix—Na1—O13ⁱⁱⁱ	84.27 (17)	82.32 (16)	85.90 (18)
Al6^xix—Na1—Si7	106.10 (13)	100.61 (12)	111.30 (14)
Al6^xix—Na1—Al7	106.10 (13)	100.61 (12)	111.30 (14)
Al6^xix—Na1—Si8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Al6^xix—Na1—Al8ⁱⁱⁱ	81.75 (9)	78.91 (9)	84.39 (9)
Al6^xix—Na1—O1ⁱ	126.5 (2)	122.5 (2)	130.5 (2)
Al6^xix—Na1—O4	123.9 (2)	118.4 (2)	128.1 (3)
Al6^xix—Na1—O5ⁱ	31.7 (2)	30.8 (2)	32.8 (2)
Al6^xix—Na1—O9ⁱⁱ	31.2 (2)	30.7 (2)	31.8 (2)
Al6^xix—Na1—O13ⁱⁱⁱ	84.27 (17)	82.32 (16)	85.90 (18)
Si7—Na1—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Si7—Na1—Si8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Si7—Na1—Al8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Si7—Na1—O1ⁱ	114.50 (19)	111.54 (19)	117.59 (19)
Si7—Na1—O4	25.37 (18)	21.13 (18)	29.40 (18)
Si7—Na1—O5ⁱ	114.0 (2)	105.8 (2)	122.3 (2)
Si7—Na1—O9ⁱⁱ	89.5 (2)	85.37 (19)	93.2 (2)
Si7—Na1—O13ⁱⁱⁱ	164.2 (2)	154.3 (2)	173.4 (2)
Al7—Na1—Si8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Al7—Na1—Al8ⁱⁱⁱ	143.94 (15)	137.02 (15)	150.64 (15)
Al7—Na1—O1ⁱ	114.50 (19)	111.54 (19)	117.59 (19)
Al7—Na1—O4	25.37 (18)	21.13 (18)	29.40 (18)
Al7—Na1—O5ⁱ	114.0 (2)	105.8 (2)	122.3 (2)
Al7—Na1—O9ⁱⁱ	89.5 (2)	85.37 (19)	93.2 (2)
Al7—Na1—O13ⁱⁱⁱ	164.2 (2)	154.3 (2)	173.4 (2)
Si8ⁱⁱⁱ—Na1—Al8ⁱⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si8ⁱⁱⁱ—Na1—O1ⁱ	83.6 (2)	78.9 (2)	88.2 (2)
Si8ⁱⁱⁱ—Na1—O4	122.8 (2)	111.2 (2)	134.5 (3)
Si8ⁱⁱⁱ—Na1—O5ⁱ	91.43 (18)	88.91 (19)	93.66 (17)
Si8ⁱⁱⁱ—Na1—O9ⁱⁱ	79.56 (19)	74.39 (19)	84.66 (19)
Si8ⁱⁱⁱ—Na1—O13ⁱⁱⁱ	24.4 (2)	21.0 (2)	27.9 (2)
Al8ⁱⁱⁱ—Na1—O1ⁱ	83.6 (2)	78.9 (2)	88.2 (2)
Al8ⁱⁱⁱ—Na1—O4	122.8 (2)	111.2 (2)	134.5 (3)
Al8ⁱⁱⁱ—Na1—O5ⁱ	91.43 (18)	88.91 (19)	93.66 (17)
Al8ⁱⁱⁱ—Na1—O9ⁱⁱ	79.56 (19)	74.39 (19)	84.66 (19)
Al8ⁱⁱⁱ—Na1—O13ⁱⁱⁱ	24.4 (2)	21.0 (2)	27.9 (2)
O1ⁱ—Na1—O4	105.4 (3)	101.5 (3)	109.8 (3)
O1ⁱ—Na1—O5ⁱ	98.3 (3)	93.1 (3)	103.4 (3)
O1ⁱ—Na1—O9ⁱⁱ	153.0 (3)	149.4 (2)	157.5 (3)
O1ⁱ—Na1—O13ⁱⁱⁱ	63.8 (3)	62.1 (2)	65.4 (3)
O4—Na1—O5ⁱ	138.7 (3)	127.0 (3)	149.8 (3)
O4—Na1—O9ⁱⁱ	98.8 (3)	96.5 (3)	100.3 (3)
O4—Na1—O13ⁱⁱⁱ	139.0 (3)	125.4 (3)	152.5 (3)
O5ⁱ—Na1—O9ⁱⁱ	62.7 (3)	61.2 (3)	64.4 (3)
O5ⁱ—Na1—O13ⁱⁱⁱ	80.9 (3)	80.4 (3)	81.2 (3)
O9ⁱⁱ—Na1—O13ⁱⁱⁱ	94.1 (2)	88.2 (2)	99.7 (2)
Ca1^xx—Ca21—Na1^xx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xx—Ca21—Ca22	74.6 (5)	74.6 (5)	74.6 (5)
Ca1^xx—Ca21—Na2	85.0 (5)	81.9 (5)	86.5 (5)
Ca1^xx—Ca21—Si2^vi	163.45 (13)	162.18 (13)	165.55 (14)
Ca1^xx—Ca21—Al2^vi	163.45 (13)	162.18 (13)	165.55 (14)
Ca1^xx—Ca21—Al3^xxi	92.29 (10)	90.62 (10)	93.56 (10)
Ca1^xx—Ca21—Al3^xxii	100.02 (12)	97.80 (12)	104.38 (13)
Ca1^xx—Ca21—Al4^vi	141.40 (12)	136.84 (12)	143.61 (13)
Ca1^xx—Ca21—Si5^viii	51.64 (9)	51.20 (9)	52.44 (10)
Ca1^xx—Ca21—Al5^viii	51.64 (9)	51.20 (9)	52.44 (10)
Ca1^xx—Ca21—Si6^xii	51.47 (8)	49.15 (8)	52.56 (9)
Ca1^xx—Ca21—Al6^xii	51.47 (8)	49.15 (8)	52.56 (9)
Ca1^xx—Ca21—Al7^xv	96.11 (12)	95.37 (11)	96.54 (12)
Ca1^xx—Ca21—Si8^iv	57.74 (9)	55.33 (9)	62.61 (9)
Ca1^xx—Ca21—Al8^iv	57.74 (9)	55.33 (9)	62.61 (9)
Ca1^xx—Ca21—O6^iv	83.11 (19)	80.31 (19)	88.4 (2)
Ca1^xx—Ca21—O8^v	75.0 (2)	72.4 (2)	77.6 (2)
Ca1^xx—Ca21—O11^vi	159.7 (2)	156.0 (2)	161.5 (2)
Ca1^xx—Ca21—O13^iv	38.9 (2)	37.9 (2)	40.4 (2)
Ca1^xx—Ca21—O15^vii	76.05 (19)	73.53 (18)	77.21 (19)
Na1^xx—Ca21—Ca22	74.6 (5)	74.6 (5)	74.6 (5)
Na1^xx—Ca21—Na2	85.0 (5)	81.9 (5)	86.5 (5)
Na1^xx—Ca21—Si2^vi	163.45 (13)	162.18 (13)	165.55 (14)
Na1^xx—Ca21—Al2^vi	163.45 (13)	162.18 (13)	165.55 (14)
Na1^xx—Ca21—Al3^xxi	92.29 (10)	90.62 (10)	93.56 (10)
Na1^xx—Ca21—Al3^xxii	100.02 (12)	97.80 (12)	104.38 (13)
Na1^xx—Ca21—Al4^vi	141.40 (12)	136.84 (12)	143.61 (13)
Na1^xx—Ca21—Si5^viii	51.64 (9)	51.20 (9)	52.44 (10)
Na1^xx—Ca21—Al5^viii	51.64 (9)	51.20 (9)	52.44 (10)
Na1^xx—Ca21—Si6^xii	51.47 (8)	49.15 (8)	52.56 (9)
Na1^xx—Ca21—Al6^xii	51.47 (8)	49.15 (8)	52.56 (9)
Na1^xx—Ca21—Al7^xv	96.11 (12)	95.37 (11)	96.54 (12)
Na1^xx—Ca21—Si8^iv	57.74 (9)	55.33 (9)	62.61 (9)
Na1^xx—Ca21—Al8^iv	57.74 (9)	55.33 (9)	62.61 (9)
Na1^xx—Ca21—O6^iv	83.11 (19)	80.31 (19)	88.4 (2)
Na1^xx—Ca21—O8^v	75.0 (2)	72.4 (2)	77.6 (2)
Na1^xx—Ca21—O11^vi	159.7 (2)	156.0 (2)	161.5 (2)
Na1^xx—Ca21—O13^iv	38.9 (2)	37.9 (2)	40.4 (2)
Na1^xx—Ca21—O15^vii	76.05 (19)	73.53 (18)	77.21 (19)
Ca22—Ca21—Na2	10.1 (8)	10.1 (8)	10.1 (8)
Ca22—Ca21—Si2^vi	110.5 (5)	110.5 (5)	110.5 (5)
Ca22—Ca21—Al2^vi	110.5 (5)	110.5 (5)	110.5 (5)
Ca22—Ca21—Al3^xxi	75.5 (6)	75.5 (6)	75.5 (6)
Ca22—Ca21—Al3^xxii	137.1 (6)	137.1 (6)	137.1 (6)
Ca22—Ca21—Al4^vi	62.7 (4)	62.7 (4)	62.7 (4)
Ca22—Ca21—Si5^viii	97.8 (5)	97.8 (5)	97.8 (5)
Ca22—Ca21—Al5^viii	97.8 (5)	97.8 (5)	97.8 (5)
Ca22—Ca21—Si6^xii	58.5 (6)	58.5 (6)	58.5 (6)
Ca22—Ca21—Al6^xii	58.5 (6)	58.5 (6)	58.5 (6)
Ca22—Ca21—Al7^xv	88.6 (6)	88.6 (6)	88.6 (6)
Ca22—Ca21—Si8^iv	136.7 (5)	136.7 (5)	136.7 (5)
Ca22—Ca21—Al8^iv	136.7 (5)	136.7 (5)	136.7 (5)
Ca22—Ca21—O6^iv	147.4 (7)	147.4 (7)	147.4 (7)
Ca22—Ca21—O8^v	80.8 (6)	80.8 (6)	80.8 (6)
Ca22—Ca21—O11^vi	82.3 (5)	82.3 (5)	82.3 (5)
Ca22—Ca21—O13^iv	112.1 (5)	112.1 (5)	112.1 (5)
Ca22—Ca21—O15^vii	71.9 (6)	71.9 (6)	71.9 (6)
Na2—Ca21—Si2^vi	103.1 (5)	101.8 (5)	103.8 (5)
Na2—Ca21—Al2^vi	103.1 (5)	101.8 (5)	103.8 (5)
Na2—Ca21—Al3^xxi	66.8 (6)	66.0 (6)	68.0 (5)
Na2—Ca21—Al3^xxii	144.1 (6)	142.9 (5)	144.6 (6)
Na2—Ca21—Al4^vi	58.1 (4)	56.6 (4)	59.0 (4)
Na2—Ca21—Si5^viii	97.1 (5)	96.5 (5)	97.5 (4)
Na2—Ca21—Al5^viii	97.1 (5)	96.5 (5)	97.5 (4)
Na2—Ca21—Si6^xii	67.8 (6)	67.6 (6)	68.5 (5)
Na2—Ca21—Al6^xii	67.8 (6)	67.6 (6)	68.5 (5)
Na2—Ca21—Al7^xv	95.9 (6)	94.9 (5)	96.3 (6)
Na2—Ca21—Si8^iv	142.7 (5)	141.7 (5)	144.5 (4)
Na2—Ca21—Al8^iv	142.7 (5)	141.7 (5)	144.5 (4)
Na2—Ca21—O6^iv	156.6 (7)	155.6 (7)	157.2 (7)
Na2—Ca21—O8^v	76.2 (6)	74.8 (6)	76.8 (6)
Na2—Ca21—O11^vi	74.9 (5)	74.4 (5)	75.3 (5)
Na2—Ca21—O13^iv	116.8 (5)	116.0 (5)	117.1 (5)
Na2—Ca21—O15^vii	81.3 (6)	80.4 (6)	81.8 (7)
Si2^vi—Ca21—Al2^vi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^vi—Ca21—Al3^xxi	78.25 (11)	77.30 (11)	78.67 (12)
Si2^vi—Ca21—Al3^xxii	81.88 (11)	81.21 (11)	82.69 (11)
Si2^vi—Ca21—Al4^vi	51.67 (8)	51.53 (8)	51.90 (8)
Si2^vi—Ca21—Si5^viii	112.56 (14)	111.23 (14)	114.23 (14)
Si2^vi—Ca21—Al5^viii	112.56 (14)	111.23 (14)	114.23 (14)
Si2^vi—Ca21—Si6^xii	144.88 (12)	144.64 (12)	145.33 (12)
Si2^vi—Ca21—Al6^xii	144.88 (12)	144.64 (12)	145.33 (12)
Si2^vi—Ca21—Al7^xv	97.23 (10)	96.62 (10)	98.28 (10)
Si2^vi—Ca21—Si8^iv	112.82 (13)	112.57 (13)	112.96 (13)
Si2^vi—Ca21—Al8^iv	112.82 (13)	112.57 (13)	112.96 (13)
Si2^vi—Ca21—O6^iv	93.7 (2)	92.8 (2)	94.9 (2)
Si2^vi—Ca21—O8^v	92.9 (2)	90.5 (2)	94.8 (2)
Si2^vi—Ca21—O11^vi	30.53 (18)	29.16 (18)	31.18 (18)
Si2^vi—Ca21—O13^iv	126.0 (2)	124.8 (2)	128.5 (2)
Si2^vi—Ca21—O15^vii	118.98 (19)	118.19 (19)	120.75 (19)
Al2^vi—Ca21—Al3^xxi	78.25 (11)	77.30 (11)	78.67 (12)
Al2^vi—Ca21—Al3^xxii	81.88 (11)	81.21 (11)	82.69 (11)
Al2^vi—Ca21—Al4^vi	51.67 (8)	51.53 (8)	51.90 (8)
Al2^vi—Ca21—Si5^viii	112.56 (14)	111.23 (14)	114.23 (14)
Al2^vi—Ca21—Al5^viii	112.56 (14)	111.23 (14)	114.23 (14)
Al2^vi—Ca21—Si6^xii	144.88 (12)	144.64 (12)	145.33 (12)
Al2^vi—Ca21—Al6^xii	144.88 (12)	144.64 (12)	145.33 (12)
Al2^vi—Ca21—Al7^xv	97.23 (10)	96.62 (10)	98.28 (10)
Al2^vi—Ca21—Si8^iv	112.82 (13)	112.57 (13)	112.96 (13)
Al2^vi—Ca21—Al8^iv	112.82 (13)	112.57 (13)	112.96 (13)
Al2^vi—Ca21—O6^iv	93.7 (2)	92.8 (2)	94.9 (2)
Al2^vi—Ca21—O8^v	92.9 (2)	90.5 (2)	94.8 (2)
Al2^vi—Ca21—O11^vi	30.53 (18)	29.16 (18)	31.18 (18)
Al2^vi—Ca21—O13^iv	126.0 (2)	124.8 (2)	128.5 (2)
Al2^vi—Ca21—O15^vii	118.98 (19)	118.19 (19)	120.75 (19)
Al3^xxi—Ca21—Al3^xxii	147.16 (12)	146.42 (12)	148.04 (12)
Al3^xxi—Ca21—Al4^vi	83.80 (12)	83.13 (11)	84.94 (12)
Al3^xxi—Ca21—Si5^viii	52.89 (10)	52.86 (10)	52.99 (11)
Al3^xxi—Ca21—Al5^viii	52.89 (10)	52.86 (10)	52.99 (11)
Al3^xxi—Ca21—Si6^xii	123.15 (12)	122.92 (12)	123.53 (12)
Al3^xxi—Ca21—Al6^xii	123.15 (12)	122.92 (12)	123.53 (12)
Al3^xxi—Ca21—Al7^xv	159.99 (13)	158.89 (13)	160.94 (13)
Al3^xxi—Ca21—Si8^iv	110.52 (11)	109.88 (11)	111.03 (12)
Al3^xxi—Ca21—Al8^iv	110.52 (11)	109.88 (11)	111.03 (12)
Al3^xxi—Ca21—O6^iv	133.7 (2)	133.1 (2)	134.9 (2)
Al3^xxi—Ca21—O8^v	20.3 (2)	18.6 (2)	21.0 (2)
Al3^xxi—Ca21—O11^vi	77.4 (2)	76.9 (2)	77.6 (2)
Al3^xxi—Ca21—O13^iv	85.4 (2)	85.0 (2)	85.9 (3)
Al3^xxi—Ca21—O15^vii	146.9 (2)	146.5 (2)	147.2 (2)
Al3^xxii—Ca21—Al4^vi	103.86 (10)	102.62 (10)	104.40 (10)
Al3^xxii—Ca21—Si5^viii	113.97 (13)	113.40 (13)	115.14 (14)
Al3^xxii—Ca21—Al5^viii	113.97 (13)	113.40 (13)	115.14 (14)
Al3^xxii—Ca21—Si6^xii	87.54 (13)	86.59 (12)	88.05 (13)
Al3^xxii—Ca21—Al6^xii	87.54 (13)	86.59 (12)	88.05 (13)
Al3^xxii—Ca21—Al7^xv	48.42 (9)	48.36 (9)	48.50 (9)
Al3^xxii—Ca21—Si8^iv	54.78 (9)	54.48 (9)	55.37 (10)
Al3^xxii—Ca21—Al8^iv	54.78 (9)	54.48 (9)	55.37 (10)
Al3^xxii—Ca21—O6^iv	23.01 (15)	22.68 (15)	23.35 (15)
Al3^xxii—Ca21—O8^v	139.5 (2)	138.6 (2)	141.2 (2)
Al3^xxii—Ca21—O11^vi	98.0 (2)	97.0 (2)	98.5 (2)
Al3^xxii—Ca21—O13^iv	85.5 (2)	85.0 (2)	86.6 (2)
Al3^xxii—Ca21—O15^vii	65.9 (2)	65.3 (2)	67.1 (2)
Al4^vi—Ca21—Si5^viii	136.61 (17)	136.00 (17)	137.65 (17)
Al4^vi—Ca21—Al5^viii	136.61 (17)	136.00 (17)	137.65 (17)
Al4^vi—Ca21—Si6^xii	99.63 (11)	99.49 (11)	99.71 (11)
Al4^vi—Ca21—Al6^xii	99.63 (11)	99.49 (11)	99.71 (11)
Al4^vi—Ca21—Al7^xv	78.32 (10)	78.04 (10)	78.43 (10)
Al4^vi—Ca21—Si8^iv	157.62 (13)	157.08 (13)	157.87 (13)
Al4^vi—Ca21—Al8^iv	157.62 (13)	157.08 (13)	157.87 (13)
Al4^vi—Ca21—O6^iv	126.20 (18)	124.67 (18)	126.90 (18)
Al4^vi—Ca21—O8^v	103.9 (3)	101.8 (2)	105.2 (3)
Al4^vi—Ca21—O11^vi	21.53 (17)	20.71 (18)	23.33 (17)
Al4^vi—Ca21—O13^iv	169.1 (3)	168.4 (3)	170.4 (3)
Al4^vi—Ca21—O15^vii	86.6 (2)	85.9 (2)	87.0 (2)
Si5^viii—Ca21—Al5^viii	0.0 (5)	0.0 (5)	0.0 (5)
Si5^viii—Ca21—Si6^xii	102.36 (11)	100.33 (11)	103.46 (11)
Si5^viii—Ca21—Al6^xii	102.36 (11)	100.33 (11)	103.46 (11)
Si5^viii—Ca21—Al7^xv	143.63 (15)	141.80 (15)	144.60 (15)
Si5^viii—Ca21—Si8^iv	60.73 (10)	60.58 (10)	60.99 (10)
Si5^viii—Ca21—Al8^iv	60.73 (10)	60.58 (10)	60.99 (10)
Si5^viii—Ca21—O6^iv	91.21 (18)	90.60 (18)	92.61 (18)
Si5^viii—Ca21—O8^v	32.8 (2)	32.0 (2)	34.3 (2)
Si5^viii—Ca21—O11^vi	127.4 (3)	126.7 (3)	127.6 (3)
Si5^viii—Ca21—O13^iv	32.5 (2)	32.3 (2)	33.1 (2)
Si5^viii—Ca21—O15^vii	127.4 (2)	124.2 (2)	129.2 (2)
Al5^viii—Ca21—Si6^xii	102.36 (11)	100.33 (11)	103.46 (11)
Al5^viii—Ca21—Al6^xii	102.36 (11)	100.33 (11)	103.46 (11)
Al5^viii—Ca21—Al7^xv	143.63 (15)	141.80 (15)	144.60 (15)
Al5^viii—Ca21—Si8^iv	60.73 (10)	60.58 (10)	60.99 (10)
Al5^viii—Ca21—Al8^iv	60.73 (10)	60.58 (10)	60.99 (10)
Al5^viii—Ca21—O6^iv	91.21 (18)	90.60 (18)	92.61 (18)
Al5^viii—Ca21—O8^v	32.8 (2)	32.0 (2)	34.3 (2)
Al5^viii—Ca21—O11^vi	127.4 (3)	126.7 (3)	127.6 (3)
Al5^viii—Ca21—O13^iv	32.5 (2)	32.3 (2)	33.1 (2)
Al5^viii—Ca21—O15^vii	127.4 (2)	124.2 (2)	129.2 (2)
Si6^xii—Ca21—Al6^xii	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xii—Ca21—Al7^xv	52.57 (9)	51.69 (8)	53.04 (9)
Si6^xii—Ca21—Si8^iv	87.02 (13)	86.80 (13)	87.13 (13)
Si6^xii—Ca21—Al8^iv	87.02 (13)	86.80 (13)	87.13 (13)
Si6^xii—Ca21—O6^iv	89.1 (2)	87.7 (2)	89.7 (2)
Si6^xii—Ca21—O8^v	116.0 (2)	113.7 (2)	117.5 (2)
Si6^xii—Ca21—O11^vi	120.5 (2)	119.7 (2)	122.2 (2)
Si6^xii—Ca21—O13^iv	86.1 (2)	83.2 (2)	87.3 (2)
Si6^xii—Ca21—O15^vii	28.73 (16)	27.17 (16)	29.43 (16)
Al6^xii—Ca21—Al7^xv	52.57 (9)	51.69 (8)	53.04 (9)
Al6^xii—Ca21—Si8^iv	87.02 (13)	86.80 (13)	87.13 (13)
Al6^xii—Ca21—Al8^iv	87.02 (13)	86.80 (13)	87.13 (13)
Al6^xii—Ca21—O6^iv	89.1 (2)	87.7 (2)	89.7 (2)
Al6^xii—Ca21—O8^v	116.0 (2)	113.7 (2)	117.5 (2)
Al6^xii—Ca21—O11^vi	120.5 (2)	119.7 (2)	122.2 (2)
Al6^xii—Ca21—O13^iv	86.1 (2)	83.2 (2)	87.3 (2)
Al6^xii—Ca21—O15^vii	28.73 (16)	27.17 (16)	29.43 (16)
Al7^xv—Ca21—Si8^iv	89.27 (13)	88.88 (13)	89.80 (14)
Al7^xv—Ca21—Al8^iv	89.27 (13)	88.88 (13)	89.80 (14)
Al7^xv—Ca21—O6^iv	65.61 (19)	65.04 (19)	65.85 (19)
Al7^xv—Ca21—O8^v	168.3 (2)	165.5 (2)	169.6 (2)
Al7^xv—Ca21—O11^vi	88.8 (2)	88.1 (2)	90.6 (2)
Al7^xv—Ca21—O13^iv	112.3 (3)	110.2 (3)	113.3 (3)
Al7^xv—Ca21—O15^vii	23.91 (16)	23.06 (16)	24.80 (16)
Si8^iv—Ca21—Al8^iv	0.0 (5)	0.0 (5)	0.0 (5)
Si8^iv—Ca21—O6^iv	31.92 (15)	31.52 (15)	32.85 (16)
Si8^iv—Ca21—O8^v	92.1 (2)	91.3 (2)	93.9 (2)
Si8^iv—Ca21—O11^vi	142.3 (2)	140.9 (2)	142.9 (2)
Si8^iv—Ca21—O13^iv	30.8 (2)	30.5 (2)	31.5 (2)
Si8^iv—Ca21—O15^vii	89.5 (3)	89.1 (3)	90.1 (3)
Al8^iv—Ca21—O6^iv	31.92 (15)	31.52 (15)	32.85 (16)
Al8^iv—Ca21—O8^v	92.1 (2)	91.3 (2)	93.9 (2)
Al8^iv—Ca21—O11^vi	142.3 (2)	140.9 (2)	142.9 (2)
Al8^iv—Ca21—O13^iv	30.8 (2)	30.5 (2)	31.5 (2)
Al8^iv—Ca21—O15^vii	89.5 (3)	89.1 (3)	90.1 (3)
O6^iv—Ca21—O8^v	119.6 (3)	118.6 (3)	121.5 (3)
O6^iv—Ca21—O11^vi	116.7 (3)	115.0 (3)	117.6 (3)
O6^iv—Ca21—O13^iv	62.7 (3)	62.0 (3)	64.3 (3)
O6^iv—Ca21—O15^vii	76.3 (3)	75.9 (3)	76.7 (3)
O8^v—Ca21—O11^vi	97.1 (3)	95.0 (3)	98.1 (3)
O8^v—Ca21—O13^iv	65.3 (3)	64.4 (3)	67.4 (3)
O8^v—Ca21—O15^vii	144.5 (3)	140.8 (3)	146.4 (3)
O11^vi—Ca21—O13^iv	153.2 (3)	152.8 (3)	154.3 (3)
O11^vi—Ca21—O15^vii	103.1 (3)	101.8 (3)	105.8 (3)
O13^iv—Ca21—O15^vii	102.5 (3)	99.1 (3)	104.0 (3)
Ca1^xx—Ca22—Na1^xx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xx—Ca22—Ca21	92.8 (5)	92.8 (5)	92.8 (5)
Ca1^xx—Ca22—Na2	121 (2)	117 (2)	124 (3)
Ca1^xx—Ca22—Si1^viii	54.87 (12)	53.38 (12)	58.28 (13)
Ca1^xx—Ca22—Al1^viii	54.87 (12)	53.38 (12)	58.28 (13)
Ca1^xx—Ca22—Al2^vi	145.9 (2)	141.4 (2)	147.9 (2)
Ca1^xx—Ca22—Al3^xxi	95.87 (15)	94.69 (15)	96.70 (16)
Ca1^xx—Ca22—Si4^vi	163.1 (2)	161.2 (2)	167.2 (2)
Ca1^xx—Ca22—Al4^vi	163.1 (2)	161.2 (2)	167.2 (2)
Ca1^xx—Ca22—Si5^viii	52.57 (12)	51.86 (12)	52.96 (12)
Ca1^xx—Ca22—Al5^viii	52.57 (12)	51.86 (12)	52.96 (12)
Ca1^xx—Ca22—Si6^xii	52.25 (13)	51.63 (13)	53.77 (13)
Ca1^xx—Ca22—Al6^xii	52.25 (13)	51.63 (13)	53.77 (13)
Ca1^xx—Ca22—Al7^xiv	96.88 (16)	95.25 (16)	100.56 (16)
Ca1^xx—Ca22—Al7^xv	95.5 (2)	94.7 (2)	96.4 (2)
Ca1^xx—Ca22—Al8^iv	58.45 (13)	53.25 (13)	60.77 (13)
Ca1^xx—Ca22—O5^viii	37.9 (2)	37.2 (2)	39.4 (2)
Ca1^xx—Ca22—O8^v	77.5 (2)	75.1 (2)	78.9 (2)
Ca1^xx—Ca22—O11^vi	166.9 (3)	163.8 (3)	168.2 (3)
Ca1^xx—Ca22—O15^vii	77.4 (3)	77.1 (3)	78.2 (3)
Na1^xx—Ca22—Ca21	92.8 (5)	92.8 (5)	92.8 (5)
Na1^xx—Ca22—Na2	121 (2)	117 (2)	124 (3)
Na1^xx—Ca22—Si1^viii	54.87 (12)	53.38 (12)	58.28 (13)
Na1^xx—Ca22—Al1^viii	54.87 (12)	53.38 (12)	58.28 (13)
Na1^xx—Ca22—Al2^vi	145.9 (2)	141.4 (2)	147.9 (2)
Na1^xx—Ca22—Al3^xxi	95.87 (15)	94.69 (15)	96.70 (16)
Na1^xx—Ca22—Si4^vi	163.1 (2)	161.2 (2)	167.2 (2)
Na1^xx—Ca22—Al4^vi	163.1 (2)	161.2 (2)	167.2 (2)
Na1^xx—Ca22—Si5^viii	52.57 (12)	51.86 (12)	52.96 (12)
Na1^xx—Ca22—Al5^viii	52.57 (12)	51.86 (12)	52.96 (12)
Na1^xx—Ca22—Si6^xii	52.25 (13)	51.63 (13)	53.77 (13)
Na1^xx—Ca22—Al6^xii	52.25 (13)	51.63 (13)	53.77 (13)
Na1^xx—Ca22—Al7^xiv	96.88 (16)	95.25 (16)	100.56 (16)
Na1^xx—Ca22—Al7^xv	95.5 (2)	94.7 (2)	96.4 (2)
Na1^xx—Ca22—Al8^iv	58.45 (13)	53.25 (13)	60.77 (13)
Na1^xx—Ca22—O5^viii	37.9 (2)	37.2 (2)	39.4 (2)
Na1^xx—Ca22—O8^v	77.5 (2)	75.1 (2)	78.9 (2)
Na1^xx—Ca22—O11^vi	166.9 (3)	163.8 (3)	168.2 (3)
Na1^xx—Ca22—O15^vii	77.4 (3)	77.1 (3)	78.2 (3)
Ca21—Ca22—Na2	136 (3)	136 (3)	136 (3)
Ca21—Ca22—Si1^viii	146.9 (5)	146.9 (5)	146.9 (5)
Ca21—Ca22—Al1^viii	146.9 (5)	146.9 (5)	146.9 (5)
Ca21—Ca22—Al2^vi	56.4 (5)	56.4 (5)	56.4 (5)
Ca21—Ca22—Al3^xxi	90.8 (6)	90.8 (6)	90.8 (6)
Ca21—Ca22—Si4^vi	103.5 (5)	103.5 (5)	103.5 (5)
Ca21—Ca22—Al4^vi	103.5 (5)	103.5 (5)	103.5 (5)
Ca21—Ca22—Si5^viii	67.0 (4)	67.0 (4)	67.0 (4)
Ca21—Ca22—Al5^viii	67.0 (4)	67.0 (4)	67.0 (4)
Ca21—Ca22—Si6^xii	107.1 (7)	107.1 (7)	107.1 (7)
Ca21—Ca22—Al6^xii	107.1 (7)	107.1 (7)	107.1 (7)
Ca21—Ca22—Al7^xv	77.7 (6)	77.7 (6)	77.7 (6)
Ca21—Ca22—Al8^iv	34.2 (4)	34.2 (4)	34.2 (4)
Ca21—Ca22—O5^viii	125.7 (7)	125.7 (7)	125.7 (7)
Ca21—Ca22—O8^v	78.5 (5)	78.5 (5)	78.5 (5)
Ca21—Ca22—O11^vi	76.6 (5)	76.6 (5)	76.6 (5)
Ca21—Ca22—O15^vii	88.0 (7)	88.0 (7)	88.0 (7)
Na2—Ca22—Si1^viii	74 (2)	68 (2)	77 (3)
Na2—Ca22—Al1^viii	74 (2)	68 (2)	77 (3)
Na2—Ca22—Al2^vi	78 (3)	75 (3)	84 (2)
Na2—Ca22—Al3^xxi	52 (3)	45 (3)	57 (2)
Na2—Ca22—Si4^vi	53 (2)	50 (2)	59 (3)
Na2—Ca22—Al4^vi	53 (2)	50 (2)	59 (3)
Na2—Ca22—Si5^viii	103 (3)	95 (3)	107 (2)
Na2—Ca22—Al5^viii	103 (3)	95 (3)	107 (2)
Na2—Ca22—Si6^xii	123 (3)	117 (2)	127 (3)
Na2—Ca22—Al6^xii	123 (3)	117 (2)	127 (3)
Na2—Ca22—Al7^xiv	25 (2)	20 (3)	27 (2)
Na2—Ca22—Al7^xv	128 (3)	124 (2)	135 (3)
Na2—Ca22—Al8^iv	151 (3)	144 (3)	156 (2)
Na2—Ca22—O5^viii	102 (3)	96 (2)	105 (3)
Na2—Ca22—O8^v	74 (3)	66 (3)	79 (2)
Na2—Ca22—O11^vi	64 (2)	62 (3)	69 (3)
Na2—Ca22—O15^vii	132 (3)	127 (2)	139 (3)
Si1^viii—Ca22—Al1^viii	0.0 (5)	0.0 (5)	0.0 (5)
Si1^viii—Ca22—Al2^vi	151.8 (3)	151.2 (3)	152.9 (3)
Si1^viii—Ca22—Al3^xxi	86.97 (19)	86.11 (19)	87.38 (19)
Si1^viii—Ca22—Si4^vi	110.4 (2)	109.5 (2)	111.8 (2)
Si1^viii—Ca22—Al4^vi	110.4 (2)	109.5 (2)	111.8 (2)
Si1^viii—Ca22—Si5^viii	85.59 (15)	85.40 (15)	85.65 (15)
Si1^viii—Ca22—Al5^viii	85.59 (15)	85.40 (15)	85.65 (15)
Si1^viii—Ca22—Si6^xii	59.55 (15)	59.34 (14)	60.03 (15)
Si1^viii—Ca22—Al6^xii	59.55 (15)	59.34 (14)	60.03 (15)
Si1^viii—Ca22—Al7^xiv	53.11 (14)	53.05 (14)	53.16 (14)
Si1^viii—Ca22—Al7^xv	107.8 (2)	107.1 (2)	108.9 (2)
Si1^viii—Ca22—Al8^iv	113.32 (19)	111.52 (19)	114.17 (19)
Si1^viii—Ca22—O5^viii	29.3 (3)	28.7 (3)	29.7 (3)
Si1^viii—Ca22—O8^v	86.8 (2)	86.3 (2)	87.4 (2)
Si1^viii—Ca22—O11^vi	135.5 (4)	134.7 (4)	136.4 (4)
Si1^viii—Ca22—O15^vii	89.6 (3)	88.7 (3)	91.8 (3)
Al1^viii—Ca22—Al2^vi	151.8 (3)	151.2 (3)	152.9 (3)
Al1^viii—Ca22—Al3^xxi	86.97 (19)	86.11 (19)	87.38 (19)
Al1^viii—Ca22—Si4^vi	110.4 (2)	109.5 (2)	111.8 (2)
Al1^viii—Ca22—Al4^vi	110.4 (2)	109.5 (2)	111.8 (2)
Al1^viii—Ca22—Si5^viii	85.59 (15)	85.40 (15)	85.65 (15)
Al1^viii—Ca22—Al5^viii	85.59 (15)	85.40 (15)	85.65 (15)
Al1^viii—Ca22—Si6^xii	59.55 (15)	59.34 (14)	60.03 (15)
Al1^viii—Ca22—Al6^xii	59.55 (15)	59.34 (14)	60.03 (15)
Al1^viii—Ca22—Al7^xiv	53.11 (14)	53.05 (14)	53.16 (14)
Al1^viii—Ca22—Al7^xv	107.8 (2)	107.1 (2)	108.9 (2)
Al1^viii—Ca22—Al8^iv	113.32 (19)	111.52 (19)	114.17 (19)
Al1^viii—Ca22—O5^viii	29.3 (3)	28.7 (3)	29.7 (3)
Al1^viii—Ca22—O8^v	86.8 (2)	86.3 (2)	87.4 (2)
Al1^viii—Ca22—O11^vi	135.5 (4)	134.7 (4)	136.4 (4)
Al1^viii—Ca22—O15^vii	89.6 (3)	88.7 (3)	91.8 (3)
Al2^vi—Ca22—Al3^xxi	73.96 (16)	73.55 (16)	74.82 (16)
Al2^vi—Ca22—Si4^vi	50.87 (11)	50.76 (11)	51.09 (11)
Al2^vi—Ca22—Al4^vi	50.87 (11)	50.76 (11)	51.09 (11)
Al2^vi—Ca22—Si5^viii	98.58 (19)	97.18 (19)	99.43 (19)
Al2^vi—Ca22—Al5^viii	98.58 (19)	97.18 (19)	99.43 (19)
Al2^vi—Ca22—Si6^xii	143.4 (2)	142.9 (3)	143.6 (2)
Al2^vi—Ca22—Al6^xii	143.4 (2)	142.9 (3)	143.6 (2)
Al2^vi—Ca22—Al7^xiv	99.1 (2)	98.6 (2)	100.0 (2)
Al2^vi—Ca22—Al7^xv	91.06 (15)	89.95 (15)	91.66 (15)
Al2^vi—Ca22—Al8^iv	90.48 (17)	90.39 (17)	90.66 (17)
Al2^vi—Ca22—O5^viii	175.0 (3)	173.6 (3)	177.4 (4)
Al2^vi—Ca22—O8^v	83.2 (3)	81.7 (3)	85.0 (3)
Al2^vi—Ca22—O11^vi	21.18 (19)	20.68 (19)	22.38 (19)
Al2^vi—Ca22—O15^vii	111.3 (3)	109.1 (3)	112.2 (3)
Al3^xxi—Ca22—Si4^vi	91.0 (2)	90.2 (2)	91.6 (2)
Al3^xxi—Ca22—Al4^vi	91.0 (2)	90.2 (2)	91.6 (2)
Al3^xxi—Ca22—Si5^viii	52.98 (14)	52.83 (14)	53.05 (14)
Al3^xxi—Ca22—Al5^viii	52.98 (14)	52.83 (14)	53.05 (14)
Al3^xxi—Ca22—Si6^xii	142.5 (2)	141.9 (2)	142.7 (2)
Al3^xxi—Ca22—Al6^xii	142.5 (2)	141.9 (2)	142.7 (2)
Al3^xxi—Ca22—Al7^xiv	47.31 (13)	47.19 (13)	47.36 (13)
Al3^xxi—Ca22—Al7^xv	164.9 (2)	164.4 (2)	165.1 (2)
Al3^xxi—Ca22—Al8^iv	98.99 (17)	98.35 (17)	99.89 (17)
Al3^xxi—Ca22—O5^viii	110.2 (3)	108.1 (3)	111.1 (3)
Al3^xxi—Ca22—O8^v	22.3 (2)	21.6 (2)	23.9 (2)
Al3^xxi—Ca22—O11^vi	78.7 (3)	78.2 (3)	79.7 (3)
Al3^xxi—Ca22—O15^vii	173.3 (3)	172.0 (3)	174.9 (3)
Si4^vi—Ca22—Al4^vi	0.0 (5)	0.0 (5)	0.0 (5)
Si4^vi—Ca22—Si5^viii	140.6 (3)	139.1 (3)	141.5 (3)
Si4^vi—Ca22—Al5^viii	140.6 (3)	139.1 (3)	141.5 (3)
Si4^vi—Ca22—Si6^xii	115.1 (2)	115.0 (2)	115.3 (2)
Si4^vi—Ca22—Al6^xii	115.1 (2)	115.0 (2)	115.3 (2)
Si4^vi—Ca22—Al7^xiv	76.63 (19)	76.03 (19)	76.93 (19)
Si4^vi—Ca22—Al7^xv	80.75 (15)	80.61 (15)	81.06 (15)
Si4^vi—Ca22—Al8^iv	135.5 (2)	135.2 (2)	136.1 (2)
Si4^vi—Ca22—O5^viii	125.3 (3)	123.9 (3)	128.0 (3)
Si4^vi—Ca22—O8^v	112.0 (4)	110.3 (4)	114.2 (4)
Si4^vi—Ca22—O11^vi	29.81 (19)	28.60 (19)	30.34 (19)
Si4^vi—Ca22—O15^vii	95.6 (3)	94.9 (3)	96.5 (3)
Al4^vi—Ca22—Si5^viii	140.6 (3)	139.1 (3)	141.5 (3)
Al4^vi—Ca22—Al5^viii	140.6 (3)	139.1 (3)	141.5 (3)
Al4^vi—Ca22—Si6^xii	115.1 (2)	115.0 (2)	115.3 (2)
Al4^vi—Ca22—Al6^xii	115.1 (2)	115.0 (2)	115.3 (2)
Al4^vi—Ca22—Al7^xiv	76.63 (19)	76.03 (19)	76.93 (19)
Al4^vi—Ca22—Al7^xv	80.75 (15)	80.61 (15)	81.06 (15)
Al4^vi—Ca22—Al8^iv	135.5 (2)	135.2 (2)	136.1 (2)
Al4^vi—Ca22—O5^viii	125.3 (3)	123.9 (3)	128.0 (3)
Al4^vi—Ca22—O8^v	112.0 (4)	110.3 (4)	114.2 (4)
Al4^vi—Ca22—O11^vi	29.81 (19)	28.60 (19)	30.34 (19)
Al4^vi—Ca22—O15^vii	95.6 (3)	94.9 (3)	96.5 (3)
Si5^viii—Ca22—Al5^viii	0.0 (5)	0.0 (5)	0.0 (5)
Si5^viii—Ca22—Si6^xii	104.1 (2)	103.1 (2)	105.5 (2)
Si5^viii—Ca22—Al6^xii	104.1 (2)	103.1 (2)	105.5 (2)
Si5^viii—Ca22—Al7^xiv	86.60 (18)	86.32 (18)	87.24 (18)
Si5^viii—Ca22—Al7^xv	129.8 (3)	128.9 (3)	130.3 (3)
Si5^viii—Ca22—Al8^iv	52.25 (13)	51.82 (13)	52.44 (13)
Si5^viii—Ca22—O5^viii	86.3 (2)	84.8 (2)	86.9 (2)
Si5^viii—Ca22—O8^v	30.7 (2)	28.9 (2)	31.5 (2)
Si5^viii—Ca22—O11^vi	116.1 (3)	115.9 (3)	116.6 (3)
Si5^viii—Ca22—O15^vii	121.0 (3)	119.7 (3)	122.3 (4)
Al5^viii—Ca22—Si6^xii	104.1 (2)	103.1 (2)	105.5 (2)
Al5^viii—Ca22—Al6^xii	104.1 (2)	103.1 (2)	105.5 (2)
Al5^viii—Ca22—Al7^xiv	86.60 (18)	86.32 (18)	87.24 (18)
Al5^viii—Ca22—Al7^xv	129.8 (3)	128.9 (3)	130.3 (3)
Al5^viii—Ca22—Al8^iv	52.25 (13)	51.82 (13)	52.44 (13)
Al5^viii—Ca22—O5^viii	86.3 (2)	84.8 (2)	86.9 (2)
Al5^viii—Ca22—O8^v	30.7 (2)	28.9 (2)	31.5 (2)
Al5^viii—Ca22—O11^vi	116.1 (3)	115.9 (3)	116.6 (3)
Al5^viii—Ca22—O15^vii	121.0 (3)	119.7 (3)	122.3 (4)
Si6^xii—Ca22—Al6^xii	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xii—Ca22—Al7^xiv	110.5 (2)	109.9 (2)	111.1 (2)
Si6^xii—Ca22—Al7^xv	52.38 (14)	52.02 (14)	53.13 (15)
Si6^xii—Ca22—Al8^iv	81.4 (2)	81.0 (2)	81.6 (2)
Si6^xii—Ca22—O5^viii	32.8 (2)	32.0 (2)	34.6 (2)
Si6^xii—Ca22—O8^v	129.0 (3)	126.9 (3)	130.9 (3)
Si6^xii—Ca22—O11^vi	136.7 (3)	135.2 (3)	137.4 (3)
Si6^xii—Ca22—O15^vii	32.13 (19)	31.41 (19)	33.8 (2)
Al6^xii—Ca22—Al7^xiv	110.5 (2)	109.9 (2)	111.1 (2)
Al6^xii—Ca22—Al7^xv	52.38 (14)	52.02 (14)	53.13 (15)
Al6^xii—Ca22—Al8^iv	81.4 (2)	81.0 (2)	81.6 (2)
Al6^xii—Ca22—O5^viii	32.8 (2)	32.0 (2)	34.6 (2)
Al6^xii—Ca22—O8^v	129.0 (3)	126.9 (3)	130.9 (3)
Al6^xii—Ca22—O11^vi	136.7 (3)	135.2 (3)	137.4 (3)
Al6^xii—Ca22—O15^vii	32.13 (19)	31.41 (19)	33.8 (2)
Al7^xiv—Ca22—Al7^xv	140.4 (2)	139.8 (2)	141.5 (2)
Al7^xiv—Ca22—Al8^iv	138.76 (19)	138.55 (19)	139.09 (19)
Al7^xiv—Ca22—O5^viii	82.4 (3)	81.7 (3)	82.8 (3)
Al7^xiv—Ca22—O8^v	63.1 (3)	62.4 (3)	64.3 (3)
Al7^xiv—Ca22—O11^vi	88.1 (3)	87.4 (3)	88.7 (3)
Al7^xiv—Ca22—O15^vii	133.4 (3)	132.9 (3)	134.4 (3)
Al7^xv—Ca22—Al8^iv	78.69 (19)	78.17 (18)	78.93 (19)
Al7^xv—Ca22—O5^viii	84.8 (3)	83.8 (3)	87.3 (3)
Al7^xv—Ca22—O8^v	156.5 (4)	154.3 (4)	157.5 (4)
Al7^xv—Ca22—O11^vi	88.1 (3)	86.4 (3)	88.8 (3)
Al7^xv—Ca22—O15^vii	20.35 (18)	19.11 (18)	21.17 (18)
Al8^iv—Ca22—O5^viii	91.5 (3)	89.3 (3)	92.6 (3)
Al8^iv—Ca22—O8^v	78.6 (3)	76.7 (3)	79.5 (3)
Al8^iv—Ca22—O11^vi	110.4 (3)	109.9 (3)	111.5 (3)
Al8^iv—Ca22—O15^vii	77.1 (3)	76.4 (3)	77.5 (3)
O5^viii—Ca22—O8^v	101.7 (3)	100.9 (3)	102.1 (3)
O5^viii—Ca22—O11^vi	155.1 (4)	154.2 (4)	156.6 (4)
O5^viii—Ca22—O15^vii	64.8 (3)	63.2 (3)	68.4 (3)
O8^v—Ca22—O11^vi	94.3 (4)	93.4 (4)	96.0 (4)
O8^v—Ca22—O15^vii	151.6 (4)	148.6 (4)	153.5 (4)
O11^vi—Ca22—O15^vii	107.8 (3)	104.9 (3)	109.1 (3)
Ca1^xx—Na2—Na1^xx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xx—Na2—Ca21	79.8 (5)	78.6 (5)	82.5 (5)
Ca1^xx—Na2—Ca22	56 (2)	54 (2)	59.1 (18)
Ca1^xx—Na2—Si1^viii	55.56 (15)	52.17 (14)	59.00 (16)
Ca1^xx—Na2—Al1^viii	55.56 (15)	52.17 (14)	59.00 (16)
Ca1^xx—Na2—Al2^vi	139.7 (3)	136.1 (3)	143.2 (3)
Ca1^xx—Na2—Si3^xxi	95.83 (19)	94.55 (17)	97.15 (18)
Ca1^xx—Na2—Al3^xxi	95.83 (19)	94.55 (17)	97.15 (18)
Ca1^xx—Na2—Si4^vi	165.6 (3)	163.0 (3)	168.1 (3)
Ca1^xx—Na2—Al4^vi	165.6 (3)	163.0 (3)	168.1 (3)
Ca1^xx—Na2—Si5^viii	50.41 (14)	49.49 (14)	51.23 (15)
Ca1^xx—Na2—Al5^viii	50.41 (14)	49.49 (14)	51.23 (15)
Ca1^xx—Na2—Si6^xii	51.07 (15)	49.46 (14)	52.80 (16)
Ca1^xx—Na2—Al6^xii	51.07 (15)	49.46 (14)	52.80 (16)
Ca1^xx—Na2—Al7^xiv	100.1 (2)	96.59 (19)	103.77 (19)
Ca1^xx—Na2—O2^vi	135.1 (3)	131.1 (4)	139.3 (3)
Ca1^xx—Na2—O5^viii	36.7 (2)	35.0 (2)	38.5 (3)
Ca1^xx—Na2—O8^v	74.8 (3)	72.5 (3)	77.3 (3)
Ca1^xx—Na2—O11^vi	160.0 (4)	157.3 (4)	162.7 (4)
Ca1^xx—Na2—O15^vii	74.0 (3)	72.8 (3)	75.1 (3)
Na1^xx—Na2—Ca21	79.8 (5)	78.6 (5)	82.5 (5)
Na1^xx—Na2—Ca22	56 (2)	54 (2)	59.1 (18)
Na1^xx—Na2—Si1^viii	55.56 (15)	52.17 (14)	59.00 (16)
Na1^xx—Na2—Al1^viii	55.56 (15)	52.17 (14)	59.00 (16)
Na1^xx—Na2—Al2^vi	139.7 (3)	136.1 (3)	143.2 (3)
Na1^xx—Na2—Si3^xxi	95.83 (19)	94.55 (17)	97.15 (18)
Na1^xx—Na2—Al3^xxi	95.83 (19)	94.55 (17)	97.15 (18)
Na1^xx—Na2—Si4^vi	165.6 (3)	163.0 (3)	168.1 (3)
Na1^xx—Na2—Al4^vi	165.6 (3)	163.0 (3)	168.1 (3)
Na1^xx—Na2—Si5^viii	50.41 (14)	49.49 (14)	51.23 (15)
Na1^xx—Na2—Al5^viii	50.41 (14)	49.49 (14)	51.23 (15)
Na1^xx—Na2—Si6^xii	51.07 (15)	49.46 (14)	52.80 (16)
Na1^xx—Na2—Al6^xii	51.07 (15)	49.46 (14)	52.80 (16)
Na1^xx—Na2—Al7^xiv	100.1 (2)	96.59 (19)	103.77 (19)
Na1^xx—Na2—O2^vi	135.1 (3)	131.1 (4)	139.3 (3)
Na1^xx—Na2—O5^viii	36.7 (2)	35.0 (2)	38.5 (3)
Na1^xx—Na2—O8^v	74.8 (3)	72.5 (3)	77.3 (3)
Na1^xx—Na2—O11^vi	160.0 (4)	157.3 (4)	162.7 (4)
Na1^xx—Na2—O15^vii	74.0 (3)	72.8 (3)	75.1 (3)
Ca21—Na2—Ca22	34 (2)	34 (2)	34 (2)
Ca21—Na2—Si1^viii	137.1 (6)	136.2 (6)	137.6 (6)
Ca21—Na2—Al1^viii	137.1 (6)	136.2 (6)	137.6 (6)
Ca21—Na2—Al2^vi	60.2 (4)	59.8 (5)	61.1 (4)
Ca21—Na2—Si3^xxi	96.9 (6)	95.0 (5)	98.5 (6)
Ca21—Na2—Al3^xxi	96.9 (6)	95.0 (5)	98.5 (6)
Ca21—Na2—Si4^vi	105.4 (5)	104.9 (5)	106.3 (4)
Ca21—Na2—Al4^vi	105.4 (5)	104.9 (5)	106.3 (4)
Ca21—Na2—Si5^viii	65.0 (4)	63.9 (4)	66.4 (4)
Ca21—Na2—Al5^viii	65.0 (4)	63.9 (4)	66.4 (4)
Ca21—Na2—Si6^xii	93.6 (7)	92.7 (6)	94.7 (7)
Ca21—Na2—Al6^xii	93.6 (7)	92.7 (6)	94.7 (7)
Ca21—Na2—Al7^xiv	146.7 (7)	145.1 (6)	148.1 (7)
Ca21—Na2—O2^vi	130.7 (6)	129.8 (5)	131.1 (6)
Ca21—Na2—O5^viii	110.7 (8)	110.0 (7)	111.5 (7)
Ca21—Na2—O8^v	79.0 (6)	77.6 (5)	81.6 (5)
Ca21—Na2—O11^vi	78.8 (5)	78.6 (5)	79.3 (5)
Ca21—Na2—O15^vii	74.3 (7)	73.6 (7)	75.5 (6)
Ca22—Na2—Si1^viii	102 (3)	99 (3)	108 (2)
Ca22—Na2—Al1^viii	102 (3)	99 (3)	108 (2)
Ca22—Na2—Al2^vi	98 (3)	92 (2)	101 (3)
Ca22—Na2—Al3^xxi	125 (3)	119 (2)	133 (3)
Ca22—Na2—Si4^vi	124 (2)	117 (3)	126 (2)
Ca22—Na2—Al4^vi	124 (2)	117 (3)	126 (2)
Ca22—Na2—Si5^viii	73 (2)	69 (2)	82 (3)
Ca22—Na2—Al5^viii	73 (2)	69 (2)	82 (3)
Ca22—Na2—Si6^xii	53 (3)	50 (3)	59 (2)
Ca22—Na2—Al6^xii	53 (3)	50 (3)	59 (2)
Ca22—Na2—Al7^xiv	153 (2)	151 (2)	159 (3)
Ca22—Na2—O2^vi	124 (3)	119 (3)	127 (2)
Ca22—Na2—O5^viii	73 (3)	70 (3)	78 (2)
Ca22—Na2—O8^v	101 (3)	94 (2)	110 (3)
Ca22—Na2—O11^vi	110 (2)	105 (2)	113 (3)
Ca22—Na2—O15^vii	44 (3)	38 (3)	48 (2)
Si1^viii—Na2—Al1^viii	0.0 (5)	0.0 (5)	0.0 (5)
Si1^viii—Na2—Al2^vi	159.8 (4)	159.1 (4)	160.5 (4)
Si1^viii—Na2—Si3^xxi	89.8 (2)	88.9 (2)	90.7 (2)
Si1^viii—Na2—Al3^xxi	89.8 (2)	88.9 (2)	90.7 (2)
Si1^viii—Na2—Si4^vi	116.0 (3)	115.6 (3)	116.5 (4)
Si1^viii—Na2—Al4^vi	116.0 (3)	115.6 (3)	116.5 (4)
Si1^viii—Na2—Si5^viii	85.76 (19)	85.35 (19)	86.13 (19)
Si1^viii—Na2—Al5^viii	85.76 (19)	85.35 (19)	86.13 (19)
Si1^viii—Na2—Si6^xii	59.51 (18)	58.47 (19)	60.6 (2)
Si1^viii—Na2—Al6^xii	59.51 (18)	58.47 (19)	60.6 (2)
Si1^viii—Na2—Al7^xiv	55.86 (18)	55.34 (18)	56.34 (17)
Si1^viii—Na2—O2^vi	86.6 (3)	86.3 (3)	86.9 (3)
Si1^viii—Na2—O5^viii	30.8 (3)	29.9 (3)	31.6 (3)
Si1^viii—Na2—O8^v	89.4 (3)	88.7 (3)	90.1 (3)
Si1^viii—Na2—O11^vi	144.1 (5)	143.2 (4)	145.0 (4)
Si1^viii—Na2—O15^vii	89.8 (3)	87.1 (3)	92.6 (3)
Al1^viii—Na2—Al2^vi	159.8 (4)	159.1 (4)	160.5 (4)
Al1^viii—Na2—Si3^xxi	89.8 (2)	88.9 (2)	90.7 (2)
Al1^viii—Na2—Al3^xxi	89.8 (2)	88.9 (2)	90.7 (2)
Al1^viii—Na2—Si4^vi	116.0 (3)	115.6 (3)	116.5 (4)
Al1^viii—Na2—Al4^vi	116.0 (3)	115.6 (3)	116.5 (4)
Al1^viii—Na2—Si5^viii	85.76 (19)	85.35 (19)	86.13 (19)
Al1^viii—Na2—Al5^viii	85.76 (19)	85.35 (19)	86.13 (19)
Al1^viii—Na2—Si6^xii	59.51 (18)	58.47 (19)	60.6 (2)
Al1^viii—Na2—Al6^xii	59.51 (18)	58.47 (19)	60.6 (2)
Al1^viii—Na2—Al7^xiv	55.86 (18)	55.34 (18)	56.34 (17)
Al1^viii—Na2—O2^vi	86.6 (3)	86.3 (3)	86.9 (3)
Al1^viii—Na2—O5^viii	30.8 (3)	29.9 (3)	31.6 (3)
Al1^viii—Na2—O8^v	89.4 (3)	88.7 (3)	90.1 (3)
Al1^viii—Na2—O11^vi	144.1 (5)	143.2 (4)	145.0 (4)
Al1^viii—Na2—O15^vii	89.8 (3)	87.1 (3)	92.6 (3)
Al2^vi—Na2—Si3^xxi	76.6 (2)	75.8 (2)	77.5 (2)
Al2^vi—Na2—Al3^xxi	76.6 (2)	75.8 (2)	77.5 (2)
Al2^vi—Na2—Si4^vi	51.98 (14)	51.72 (13)	52.22 (13)
Al2^vi—Na2—Al4^vi	51.98 (14)	51.72 (13)	52.22 (13)
Al2^vi—Na2—Si5^viii	97.7 (2)	96.8 (2)	98.6 (2)
Al2^vi—Na2—Al5^viii	97.7 (2)	96.8 (2)	98.6 (2)
Al2^vi—Na2—Si6^xii	138.1 (3)	136.7 (4)	139.5 (4)
Al2^vi—Na2—Al6^xii	138.1 (3)	136.7 (4)	139.5 (4)
Al2^vi—Na2—Al7^xiv	104.1 (3)	103.8 (3)	104.4 (3)
Al2^vi—Na2—O2^vi	83.7 (3)	82.7 (2)	84.6 (3)
Al2^vi—Na2—O5^viii	169.1 (5)	167.7 (5)	170.6 (5)
Al2^vi—Na2—O8^v	84.6 (3)	83.1 (3)	86.0 (3)
Al2^vi—Na2—O11^vi	21.0 (2)	19.7 (2)	22.3 (2)
Al2^vi—Na2—O15^vii	106.6 (3)	103.7 (3)	109.4 (3)
Si3^xxi—Na2—Al3^xxi	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xxi—Na2—Si4^vi	95.6 (3)	94.1 (3)	97.1 (3)
Si3^xxi—Na2—Al4^vi	95.6 (3)	94.1 (3)	97.1 (3)
Si3^xxi—Na2—Si5^viii	53.73 (16)	53.43 (16)	53.98 (16)
Si3^xxi—Na2—Al5^viii	53.73 (16)	53.43 (16)	53.98 (16)
Si3^xxi—Na2—Si6^xii	143.0 (2)	142.2 (2)	143.9 (2)
Si3^xxi—Na2—Al6^xii	143.0 (2)	142.2 (2)	143.9 (2)
Si3^xxi—Na2—Al7^xiv	49.85 (17)	49.62 (15)	50.08 (16)
Si3^xxi—Na2—O2^vi	108.5 (4)	104.7 (4)	112.4 (4)
Si3^xxi—Na2—O5^viii	112.4 (3)	110.8 (3)	113.9 (3)
Si3^xxi—Na2—O8^v	25.3 (3)	23.7 (3)	26.8 (3)
Si3^xxi—Na2—O11^vi	83.5 (4)	82.5 (4)	84.4 (4)
Si3^xxi—Na2—O15^vii	167.7 (4)	165.0 (4)	170.6 (4)
Al3^xxi—Na2—Si4^vi	95.6 (3)	94.1 (3)	97.1 (3)
Al3^xxi—Na2—Al4^vi	95.6 (3)	94.1 (3)	97.1 (3)
Al3^xxi—Na2—Si5^viii	53.73 (16)	53.43 (16)	53.98 (16)
Al3^xxi—Na2—Al5^viii	53.73 (16)	53.43 (16)	53.98 (16)
Al3^xxi—Na2—Si6^xii	143.0 (2)	142.2 (2)	143.9 (2)
Al3^xxi—Na2—Al6^xii	143.0 (2)	142.2 (2)	143.9 (2)
Al3^xxi—Na2—Al7^xiv	49.85 (17)	49.62 (15)	50.08 (16)
Al3^xxi—Na2—O2^vi	108.5 (4)	104.7 (4)	112.4 (4)
Al3^xxi—Na2—O5^viii	112.4 (3)	110.8 (3)	113.9 (3)
Al3^xxi—Na2—O8^v	25.3 (3)	23.7 (3)	26.8 (3)
Al3^xxi—Na2—O11^vi	83.5 (4)	82.5 (4)	84.4 (4)
Al3^xxi—Na2—O15^vii	167.7 (4)	165.0 (4)	170.6 (4)
Si4^vi—Na2—Al4^vi	0.0 (5)	0.0 (5)	0.0 (5)
Si4^vi—Na2—Si5^viii	143.8 (3)	142.0 (3)	145.5 (3)
Si4^vi—Na2—Al5^viii	143.8 (3)	142.0 (3)	145.5 (3)
Si4^vi—Na2—Si6^xii	115.4 (3)	114.6 (3)	116.1 (3)
Si4^vi—Na2—Al6^xii	115.4 (3)	114.6 (3)	116.1 (3)
Si4^vi—Na2—Al7^xiv	81.0 (3)	79.6 (2)	82.3 (3)
Si4^vi—Na2—O2^vi	31.80 (19)	31.02 (18)	32.6 (2)
Si4^vi—Na2—O5^viii	130.0 (4)	128.3 (4)	131.8 (4)
Si4^vi—Na2—O8^v	118.2 (4)	115.5 (4)	120.9 (4)
Si4^vi—Na2—O11^vi	31.0 (2)	29.4 (2)	32.5 (2)
Si4^vi—Na2—O15^vii	95.5 (3)	94.2 (3)	96.7 (3)
Al4^vi—Na2—Si5^viii	143.8 (3)	142.0 (3)	145.5 (3)
Al4^vi—Na2—Al5^viii	143.8 (3)	142.0 (3)	145.5 (3)
Al4^vi—Na2—Si6^xii	115.4 (3)	114.6 (3)	116.1 (3)
Al4^vi—Na2—Al6^xii	115.4 (3)	114.6 (3)	116.1 (3)
Al4^vi—Na2—Al7^xiv	81.0 (3)	79.6 (2)	82.3 (3)
Al4^vi—Na2—O2^vi	31.80 (19)	31.02 (18)	32.6 (2)
Al4^vi—Na2—O5^viii	130.0 (4)	128.3 (4)	131.8 (4)
Al4^vi—Na2—O8^v	118.2 (4)	115.5 (4)	120.9 (4)
Al4^vi—Na2—O11^vi	31.0 (2)	29.4 (2)	32.5 (2)
Al4^vi—Na2—O15^vii	95.5 (3)	94.2 (3)	96.7 (3)
Si5^viii—Na2—Al5^viii	0.0 (5)	0.0 (5)	0.0 (5)
Si5^viii—Na2—Si6^xii	100.5 (3)	98.3 (2)	102.7 (2)
Si5^viii—Na2—Al6^xii	100.5 (3)	98.3 (2)	102.7 (2)
Si5^viii—Na2—Al7^xiv	89.8 (2)	88.9 (2)	90.8 (2)
Si5^viii—Na2—O2^vi	160.6 (5)	157.5 (4)	163.7 (5)
Si5^viii—Na2—O5^viii	83.8 (3)	83.3 (3)	84.1 (3)
Si5^viii—Na2—O8^v	28.6 (3)	26.8 (3)	30.4 (3)
Si5^viii—Na2—O11^vi	116.9 (4)	116.3 (3)	117.3 (3)
Si5^viii—Na2—O15^vii	114.0 (4)	111.6 (4)	116.7 (4)
Al5^viii—Na2—Si6^xii	100.5 (3)	98.3 (2)	102.7 (2)
Al5^viii—Na2—Al6^xii	100.5 (3)	98.3 (2)	102.7 (2)
Al5^viii—Na2—Al7^xiv	89.8 (2)	88.9 (2)	90.8 (2)
Al5^viii—Na2—O2^vi	160.6 (5)	157.5 (4)	163.7 (5)
Al5^viii—Na2—O5^viii	83.8 (3)	83.3 (3)	84.1 (3)
Al5^viii—Na2—O8^v	28.6 (3)	26.8 (3)	30.4 (3)
Al5^viii—Na2—O11^vi	116.9 (4)	116.3 (3)	117.3 (3)
Al5^viii—Na2—O15^vii	114.0 (4)	111.6 (4)	116.7 (4)
Si6^xii—Na2—Al6^xii	0.0 (5)	0.0 (5)	0.0 (5)
Si6^xii—Na2—Al7^xiv	113.3 (3)	111.7 (3)	114.8 (3)
Si6^xii—Na2—O2^vi	90.9 (3)	89.1 (4)	92.7 (3)
Si6^xii—Na2—O5^viii	31.7 (3)	30.1 (2)	33.5 (3)
Si6^xii—Na2—O8^v	125.7 (4)	122.7 (3)	128.8 (3)
Si6^xii—Na2—O11^vi	133.4 (4)	131.5 (4)	135.1 (4)
Si6^xii—Na2—O15^vii	31.6 (2)	29.90 (19)	33.3 (2)
Al6^xii—Na2—Al7^xiv	113.3 (3)	111.7 (3)	114.8 (3)
Al6^xii—Na2—O2^vi	90.9 (3)	89.1 (4)	92.7 (3)
Al6^xii—Na2—O5^viii	31.7 (3)	30.1 (2)	33.5 (3)
Al6^xii—Na2—O8^v	125.7 (4)	122.7 (3)	128.8 (3)
Al6^xii—Na2—O11^vi	133.4 (4)	131.5 (4)	135.1 (4)
Al6^xii—Na2—O15^vii	31.6 (2)	29.90 (19)	33.3 (2)
Al7^xiv—Na2—O2^vi	71.2 (3)	67.8 (3)	74.7 (3)
Al7^xiv—Na2—O5^viii	86.6 (4)	85.3 (3)	88.0 (4)
Al7^xiv—Na2—O8^v	68.6 (3)	66.6 (4)	70.6 (4)
Al7^xiv—Na2—O11^vi	94.6 (4)	94.0 (4)	95.1 (4)
Al7^xiv—Na2—O15^vii	137.4 (4)	135.2 (4)	139.7 (4)
O2^vi—Na2—O5^viii	98.5 (4)	96.1 (4)	100.9 (4)
O2^vi—Na2—O8^v	133.7 (6)	129.5 (5)	137.8 (6)
O2^vi—Na2—O11^vi	62.8 (3)	60.5 (3)	65.0 (3)
O2^vi—Na2—O15^vii	83.7 (4)	81.0 (4)	86.3 (4)
O5^viii—Na2—O8^v	101.2 (4)	100.4 (4)	102.0 (4)
O5^viii—Na2—O11^vi	159.3 (5)	158.8 (5)	159.7 (5)
O5^viii—Na2—O15^vii	63.3 (4)	60.0 (3)	66.8 (4)
O8^v—Na2—O11^vi	98.5 (4)	97.4 (4)	99.5 (4)
O8^v—Na2—O15^vii	142.5 (5)	138.5 (5)	146.6 (5)
O11^vi—Na2—O15^vii	103.8 (4)	100.7 (4)	106.7 (4)
Ca1^xxiii—Si1—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Si1—Ca22^xxiv	71.53 (15)	70.34 (16)	72.19 (15)
Ca1^xxiii—Si1—Na2^xxiv	74.4 (2)	72.8 (2)	76.2 (2)
Ca1^xxiii—Si1—Al1	0	0	0
Ca1^xxiii—Si1—O5	44.7 (3)	42.3 (3)	47.1 (3)
Ca1^xxiii—Si1—O12	60.9 (3)	58.3 (3)	63.3 (4)
Ca1^xxiii—Si1—O14	119.8 (3)	117.0 (3)	122.6 (3)
Ca1^xxiii—Si1—O16	127.7 (4)	126.8 (4)	128.5 (4)
Na1^xxiii—Si1—Ca22^xxiv	71.53 (15)	70.34 (16)	72.19 (15)
Na1^xxiii—Si1—Na2^xxiv	74.4 (2)	72.8 (2)	76.2 (2)
Na1^xxiii—Si1—Al1	0	0	0
Na1^xxiii—Si1—O5	44.7 (3)	42.3 (3)	47.1 (3)
Na1^xxiii—Si1—O12	60.9 (3)	58.3 (3)	63.3 (4)
Na1^xxiii—Si1—O14	119.8 (3)	117.0 (3)	122.6 (3)
Na1^xxiii—Si1—O16	127.7 (4)	126.8 (4)	128.5 (4)
Ca22^xxiv—Si1—Na2^xxiv	4.0 (3)	3.4 (3)	4.5 (3)
Ca22^xxiv—Si1—Al1	0	0	0
Ca22^xxiv—Si1—O5	44.6 (4)	43.0 (3)	45.5 (3)
Ca22^xxiv—Si1—O12	117.9 (3)	117.2 (3)	119.1 (3)
Ca22^xxiv—Si1—O14	59.6 (4)	58.0 (4)	62.5 (4)
Ca22^xxiv—Si1—O16	131.5 (3)	129.6 (3)	132.5 (3)
Na2^xxiv—Si1—Al1	0	0	0
Na2^xxiv—Si1—O5	47.0 (4)	44.6 (4)	49.4 (4)
Na2^xxiv—Si1—O12	119.6 (3)	119.0 (3)	120.4 (3)
Na2^xxiv—Si1—O14	58.4 (4)	54.0 (4)	62.8 (4)
Na2^xxiv—Si1—O16	129.8 (3)	127.9 (3)	131.7 (3)
Al1—Si1—O5	0	0	0
Al1—Si1—O12	0	0	0
Al1—Si1—O14	0	0	0
Al1—Si1—O16	0	0	0
O5—Si1—O12	105.5 (5)	105.3 (4)	105.7 (5)
O5—Si1—O14	105.4 (5)	103.4 (5)	107.4 (5)
O5—Si1—O16	112.9 (4)	112.3 (4)	113.4 (4)
O12—Si1—O14	111.8 (5)	110.8 (5)	112.8 (4)
O12—Si1—O16	109.7 (4)	108.9 (4)	110.4 (4)
O14—Si1—O16	111.4 (5)	109.4 (5)	113.5 (5)
Ca1^xxiii—Al1—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Al1—Ca22^xxiv	71.53 (15)	70.34 (16)	72.19 (15)
Ca1^xxiii—Al1—Na2^xxiv	74.4 (2)	72.8 (2)	76.2 (2)
Ca1^xxiii—Al1—Si1	0	0	0
Ca1^xxiii—Al1—Al3	110.84 (13)	107.53 (13)	114.00 (13)
Ca1^xxiii—Al1—Al4^xi	74.68 (10)	71.75 (10)	77.52 (10)
Ca1^xxiii—Al1—Al6^xxv	57.65 (10)	57.42 (10)	57.81 (10)
Ca1^xxiii—Al1—Al7^xxvi	123.40 (12)	122.04 (12)	124.83 (12)
Ca1^xxiii—Al1—O5	44.7 (3)	42.3 (3)	47.1 (3)
Ca1^xxiii—Al1—O12	60.9 (3)	58.3 (3)	63.3 (4)
Ca1^xxiii—Al1—O14	119.8 (3)	117.0 (3)	122.6 (3)
Ca1^xxiii—Al1—O16	127.7 (4)	126.8 (4)	128.5 (4)
Na1^xxiii—Al1—Ca22^xxiv	71.53 (15)	70.34 (16)	72.19 (15)
Na1^xxiii—Al1—Na2^xxiv	74.4 (2)	72.8 (2)	76.2 (2)
Na1^xxiii—Al1—Si1	0	0	0
Na1^xxiii—Al1—Al3	110.84 (13)	107.53 (13)	114.00 (13)
Na1^xxiii—Al1—Al4^xi	74.68 (10)	71.75 (10)	77.52 (10)
Na1^xxiii—Al1—Al6^xxv	57.65 (10)	57.42 (10)	57.81 (10)
Na1^xxiii—Al1—Al7^xxvi	123.40 (12)	122.04 (12)	124.83 (12)
Na1^xxiii—Al1—O5	44.7 (3)	42.3 (3)	47.1 (3)
Na1^xxiii—Al1—O12	60.9 (3)	58.3 (3)	63.3 (4)
Na1^xxiii—Al1—O14	119.8 (3)	117.0 (3)	122.6 (3)
Na1^xxiii—Al1—O16	127.7 (4)	126.8 (4)	128.5 (4)
Ca22^xxiv—Al1—Na2^xxiv	4.0 (3)	3.4 (3)	4.5 (3)
Ca22^xxiv—Al1—Si1	0	0	0
Ca22^xxiv—Al1—Al3	148.72 (17)	147.56 (17)	149.30 (17)
Ca22^xxiv—Al1—Al4^xi	123.65 (15)	122.61 (15)	125.88 (16)
Ca22^xxiv—Al1—Al6^xxv	57.27 (17)	55.47 (17)	58.08 (17)
Ca22^xxiv—Al1—Al7^xxvi	71.78 (17)	71.10 (17)	73.18 (18)
Ca22^xxiv—Al1—O5	44.6 (4)	43.0 (3)	45.5 (3)
Ca22^xxiv—Al1—O12	117.9 (3)	117.2 (3)	119.1 (3)
Ca22^xxiv—Al1—O14	59.6 (4)	58.0 (4)	62.5 (4)
Ca22^xxiv—Al1—O16	131.5 (3)	129.6 (3)	132.5 (3)
Na2^xxiv—Al1—Si1	0	0	0
Na2^xxiv—Al1—Al3	149.0 (2)	147.3 (2)	150.7 (2)
Na2^xxiv—Al1—Al4^xi	125.02 (18)	123.23 (18)	126.85 (19)
Na2^xxiv—Al1—Al6^xxv	59.7 (2)	58.2 (2)	61.3 (2)
Na2^xxiv—Al1—Al7^xxvi	68.7 (2)	66.9 (2)	70.3 (2)
Na2^xxiv—Al1—O5	47.0 (4)	44.6 (4)	49.4 (4)
Na2^xxiv—Al1—O12	119.6 (3)	119.0 (3)	120.4 (3)
Na2^xxiv—Al1—O14	58.4 (4)	54.0 (4)	62.8 (4)
Na2^xxiv—Al1—O16	129.8 (3)	127.9 (3)	131.7 (3)
Si1—Al1—Al3	0	0	0
Si1—Al1—Al4^xi	0	0	0
Si1—Al1—Al6^xxv	0	0	0
Si1—Al1—Al7^xxvi	0	0	0
Si1—Al1—O5	0	0	0
Si1—Al1—O12	0	0	0
Si1—Al1—O14	0	0	0
Si1—Al1—O16	0	0	0
Al3—Al1—Al4^xi	84.83 (9)	84.14 (9)	85.54 (9)
Al3—Al1—Al6^xxv	96.27 (12)	95.34 (12)	97.21 (13)
Al3—Al1—Al7^xxvi	122.98 (14)	119.18 (14)	126.81 (14)
Al3—Al1—O5	114.6 (3)	111.4 (3)	117.7 (4)
Al3—Al1—O12	87.2 (3)	85.7 (3)	88.6 (3)
Al3—Al1—O14	129.0 (3)	123.4 (3)	134.6 (4)
Al3—Al1—O16	23.7 (2)	22.1 (2)	25.5 (3)
Al4^xi—Al1—Al6^xxv	129.39 (14)	127.19 (13)	131.57 (14)
Al4^xi—Al1—Al7^xxvi	93.07 (11)	91.96 (11)	94.26 (12)
Al4^xi—Al1—O5	119.3 (3)	118.6 (3)	119.9 (3)
Al4^xi—Al1—O12	14.3 (4)	13.7 (4)	15.0 (4)
Al4^xi—Al1—O14	102.4 (3)	101.3 (3)	103.3 (3)
Al4^xi—Al1—O16	105.0 (2)	104.4 (2)	105.6 (2)
Al6^xxv—Al1—Al7^xxvi	125.68 (11)	124.51 (11)	126.93 (11)
Al6^xxv—Al1—O5	20.3 (3)	17.5 (3)	23.1 (3)
Al6^xxv—Al1—O12	115.1 (4)	113.0 (4)	117.3 (4)
Al6^xxv—Al1—O14	114.6 (3)	112.2 (3)	117.1 (3)
Al6^xxv—Al1—O16	92.6 (3)	89.9 (3)	95.2 (3)
Al7^xxvi—Al1—O5	115.6 (3)	114.1 (3)	117.2 (3)
Al7^xxvi—Al1—O12	103.7 (4)	102.2 (4)	105.2 (4)
Al7^xxvi—Al1—O14	11.1 (3)	8.1 (3)	14.2 (3)
Al7^xxvi—Al1—O16	108.9 (4)	107.9 (4)	109.9 (3)
O5—Al1—O12	105.5 (5)	105.3 (4)	105.7 (5)
O5—Al1—O14	105.4 (5)	103.4 (5)	107.4 (5)
O5—Al1—O16	112.9 (4)	112.3 (4)	113.4 (4)
O12—Al1—O14	111.8 (5)	110.8 (5)	112.8 (4)
O12—Al1—O16	109.7 (4)	108.9 (4)	110.4 (4)
O14—Al1—O16	111.4 (5)	109.4 (5)	113.5 (5)
Ca21^xxvii—Si2—Al2	0	0	0
Ca21^xxvii—Si2—O1^ix	114.8 (4)	114.5 (3)	114.9 (4)
Ca21^xxvii—Si2—O3ⁱ	131.9 (3)	130.8 (3)	133.2 (3)
Ca21^xxvii—Si2—O10ⁱⁱ	60.3 (3)	59.3 (3)	61.9 (3)
Ca21^xxvii—Si2—O11	45.2 (3)	43.7 (3)	45.9 (3)
Al2—Si2—O1^ix	0	0	0
Al2—Si2—O3ⁱ	0	0	0
Al2—Si2—O10ⁱⁱ	0	0	0
Al2—Si2—O11	0	0	0
O1^ix—Si2—O3ⁱ	111.3 (4)	110.1 (4)	112.5 (4)
O1^ix—Si2—O10ⁱⁱ	113.0 (5)	112.1 (5)	113.9 (5)
O1^ix—Si2—O11	107.4 (4)	105.9 (4)	109.0 (4)
O3ⁱ—Si2—O10ⁱⁱ	111.1 (5)	110.4 (4)	111.9 (5)
O3ⁱ—Si2—O11	108.5 (5)	107.4 (5)	109.6 (5)
O10ⁱⁱ—Si2—O11	105.1 (4)	104.2 (4)	105.9 (4)
Ca1^xxvi—Al2—Na1^xxvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxvi—Al2—Ca21^xxvii	84.34 (11)	83.05 (11)	85.33 (11)
Ca1^xxvi—Al2—Ca22^xxvii	86.81 (15)	84.87 (15)	87.88 (15)
Ca1^xxvi—Al2—Na2^xxvii	88.4 (2)	86.6 (2)	90.2 (2)
Ca1^xxvi—Al2—Si2	0	0	0
Ca1^xxvi—Al2—Al4	73.55 (11)	69.98 (11)	76.99 (11)
Ca1^xxvi—Al2—Al5^ix	56.15 (9)	54.74 (9)	57.62 (9)
Ca1^xxvi—Al2—Al6ⁱⁱ	119.74 (14)	116.06 (14)	123.54 (15)
Ca1^xxvi—Al2—Al8ⁱ	126.97 (9)	126.56 (9)	127.32 (9)
Ca1^xxvi—Al2—O1^ix	31.6 (3)	30.0 (3)	33.1 (3)
Ca1^xxvi—Al2—O3ⁱ	136.7 (3)	135.6 (3)	137.7 (3)
Ca1^xxvi—Al2—O10ⁱⁱ	106.9 (4)	105.6 (4)	108.3 (4)
Ca1^xxvi—Al2—O11	80.0 (3)	75.9 (3)	83.9 (3)
Na1^xxvi—Al2—Ca21^xxvii	84.34 (11)	83.05 (11)	85.33 (11)
Na1^xxvi—Al2—Ca22^xxvii	86.81 (15)	84.87 (15)	87.88 (15)
Na1^xxvi—Al2—Na2^xxvii	88.4 (2)	86.6 (2)	90.2 (2)
Na1^xxvi—Al2—Si2	0	0	0
Na1^xxvi—Al2—Al4	73.55 (11)	69.98 (11)	76.99 (11)
Na1^xxvi—Al2—Al5^ix	56.15 (9)	54.74 (9)	57.62 (9)
Na1^xxvi—Al2—Al6ⁱⁱ	119.74 (14)	116.06 (14)	123.54 (15)
Na1^xxvi—Al2—Al8ⁱ	126.97 (9)	126.56 (9)	127.32 (9)
Na1^xxvi—Al2—O1^ix	31.6 (3)	30.0 (3)	33.1 (3)
Na1^xxvi—Al2—O3ⁱ	136.7 (3)	135.6 (3)	137.7 (3)
Na1^xxvi—Al2—O10ⁱⁱ	106.9 (4)	105.6 (4)	108.3 (4)
Na1^xxvi—Al2—O11	80.0 (3)	75.9 (3)	83.9 (3)
Ca21^xxvii—Al2—Ca22^xxvii	13.05 (15)	13.05 (15)	13.05 (15)
Ca21^xxvii—Al2—Na2^xxvii	16.7 (2)	15.8 (2)	17.2 (2)
Ca21^xxvii—Al2—Si2	0	0	0
Ca21^xxvii—Al2—Al4	70.98 (11)	69.37 (10)	71.83 (11)
Ca21^xxvii—Al2—Al5^ix	137.99 (16)	136.07 (16)	139.40 (16)
Ca21^xxvii—Al2—Al6ⁱⁱ	85.73 (11)	85.18 (11)	86.82 (11)
Ca21^xxvii—Al2—Al8ⁱ	143.91 (14)	142.77 (14)	144.46 (13)
Ca21^xxvii—Al2—O1^ix	114.8 (4)	114.5 (3)	114.9 (4)
Ca21^xxvii—Al2—O3ⁱ	131.9 (3)	130.8 (3)	133.2 (3)
Ca21^xxvii—Al2—O10ⁱⁱ	60.3 (3)	59.3 (3)	61.9 (3)
Ca21^xxvii—Al2—O11	45.2 (3)	43.7 (3)	45.9 (3)
Ca22^xxvii—Al2—Na2^xxvii	3.7 (2)	3.1 (3)	4.3 (2)
Ca22^xxvii—Al2—Si2	0	0	0
Ca22^xxvii—Al2—Al4	56.54 (13)	55.84 (13)	57.97 (13)
Ca22^xxvii—Al2—Al5^ix	142.03 (18)	140.64 (18)	143.88 (18)
Ca22^xxvii—Al2—Al6ⁱⁱ	97.53 (13)	96.73 (14)	97.92 (13)
Ca22^xxvii—Al2—Al8ⁱ	133.45 (18)	132.65 (18)	135.28 (18)
Ca22^xxvii—Al2—O1^ix	117.8 (3)	117.6 (3)	117.9 (4)
Ca22^xxvii—Al2—O3ⁱ	123.4 (3)	122.4 (3)	124.9 (3)
Ca22^xxvii—Al2—O10ⁱⁱ	74.7 (3)	73.3 (3)	75.5 (3)
Ca22^xxvii—Al2—O11	31.1 (3)	30.6 (3)	32.3 (3)
Na2^xxvii—Al2—Si2	0	0	0
Na2^xxvii—Al2—Al4	55.45 (16)	53.59 (17)	57.36 (17)
Na2^xxvii—Al2—Al5^ix	144.5 (2)	142.7 (2)	146.2 (2)
Na2^xxvii—Al2—Al6ⁱⁱ	98.43 (16)	97.03 (16)	99.79 (16)
Na2^xxvii—Al2—Al8ⁱ	130.9 (2)	128.9 (2)	133.0 (2)
Na2^xxvii—Al2—O1^ix	119.9 (4)	119.5 (4)	120.2 (4)
Na2^xxvii—Al2—O3ⁱ	120.2 (3)	119.4 (3)	121.1 (4)
Na2^xxvii—Al2—O10ⁱⁱ	75.6 (3)	73.5 (3)	77.8 (3)
Na2^xxvii—Al2—O11	29.5 (3)	28.2 (3)	30.8 (3)
Si2—Al2—Al4	0	0	0
Si2—Al2—Al5^ix	0	0	0
Si2—Al2—Al6ⁱⁱ	0	0	0
Si2—Al2—Al8ⁱ	0	0	0
Si2—Al2—O1^ix	0	0	0
Si2—Al2—O3ⁱ	0	0	0
Si2—Al2—O10ⁱⁱ	0	0	0
Si2—Al2—O11	0	0	0
Al4—Al2—Al5^ix	107.43 (10)	106.79 (10)	108.11 (10)
Al4—Al2—Al6ⁱⁱ	152.01 (11)	151.54 (11)	152.46 (11)
Al4—Al2—Al8ⁱ	98.80 (13)	96.88 (13)	100.74 (13)
Al4—Al2—O1^ix	92.5 (3)	91.4 (3)	93.5 (3)
Al4—Al2—O3ⁱ	95.6 (3)	94.9 (3)	96.3 (3)
Al4—Al2—O10ⁱⁱ	131.1 (3)	130.7 (3)	131.4 (3)
Al4—Al2—O11	26.0 (2)	25.4 (2)	26.5 (3)
Al5^ix—Al2—Al6ⁱⁱ	100.01 (11)	99.35 (11)	100.68 (11)
Al5^ix—Al2—Al8ⁱ	78.51 (11)	77.22 (11)	79.77 (11)
Al5^ix—Al2—O1^ix	24.6 (3)	23.2 (3)	26.1 (3)
Al5^ix—Al2—O3ⁱ	90.0 (3)	87.2 (3)	92.8 (3)
Al5^ix—Al2—O10ⁱⁱ	112.5 (3)	112.4 (3)	112.7 (3)
Al5^ix—Al2—O11	128.1 (2)	126.6 (2)	129.7 (3)
Al6ⁱⁱ—Al2—Al8ⁱ	91.69 (12)	89.31 (12)	94.05 (12)
Al6ⁱⁱ—Al2—O1^ix	111.2 (3)	109.9 (3)	112.5 (3)
Al6ⁱⁱ—Al2—O3ⁱ	89.5 (3)	87.6 (3)	91.5 (3)
Al6ⁱⁱ—Al2—O10ⁱⁱ	25.7 (3)	24.0 (3)	27.5 (3)
Al6ⁱⁱ—Al2—O11	127.1 (3)	126.9 (2)	127.4 (3)
Al8ⁱ—Al2—O1^ix	100.0 (3)	99.6 (3)	100.5 (4)
Al8ⁱ—Al2—O3ⁱ	11.6 (3)	9.7 (3)	13.6 (3)
Al8ⁱ—Al2—O10ⁱⁱ	115.6 (4)	114.7 (4)	116.5 (4)
Al8ⁱ—Al2—O11	115.6 (4)	112.7 (4)	118.6 (4)
O1^ix—Al2—O3ⁱ	111.3 (4)	110.1 (4)	112.5 (4)
O1^ix—Al2—O10ⁱⁱ	113.0 (5)	112.1 (5)	113.9 (5)
O1^ix—Al2—O11	107.4 (4)	105.9 (4)	109.0 (4)
O3ⁱ—Al2—O10ⁱⁱ	111.1 (5)	110.4 (4)	111.9 (5)
O3ⁱ—Al2—O11	108.5 (5)	107.4 (5)	109.6 (5)
O10ⁱⁱ—Al2—O11	105.1 (4)	104.2 (4)	105.9 (4)
Ca1^x—Si3—Na1^x	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^x—Si3—Na2^xxviii	86.66 (19)	84.97 (19)	88.35 (18)
Ca1^x—Si3—Al3	0	0	0
Ca1^x—Si3—O4^x	38.5 (3)	31.4 (3)	46.0 (3)
Ca1^x—Si3—O6^xi	118.9 (4)	115.2 (4)	122.8 (4)
Ca1^x—Si3—O8^xi	123.7 (3)	121.9 (3)	126.2 (2)
Ca1^x—Si3—O16	64.4 (3)	54.9 (3)	73.5 (3)
Na1^x—Si3—Na2^xxviii	86.66 (19)	84.97 (19)	88.35 (18)
Na1^x—Si3—Al3	0	0	0
Na1^x—Si3—O4^x	38.5 (3)	31.4 (3)	46.0 (3)
Na1^x—Si3—O6^xi	118.9 (4)	115.2 (4)	122.8 (4)
Na1^x—Si3—O8^xi	123.7 (3)	121.9 (3)	126.2 (2)
Na1^x—Si3—O16	64.4 (3)	54.9 (3)	73.5 (3)
Na2^xxviii—Si3—Al3	0	0	0
Na2^xxviii—Si3—O4^x	70.9 (4)	69.6 (4)	72.2 (4)
Na2^xxviii—Si3—O6^xi	137.6 (4)	136.9 (4)	138.3 (4)
Na2^xxviii—Si3—O8^xi	39.1 (3)	36.8 (3)	41.4 (3)
Na2^xxviii—Si3—O16	108.1 (3)	106.9 (3)	109.4 (3)
Al3—Si3—O4^x	0	0	0
Al3—Si3—O6^xi	0	0	0
Al3—Si3—O8^xi	0	0	0
Al3—Si3—O16	0	0	0
O4^x—Si3—O6^xi	107.4 (4)	107.1 (4)	107.6 (4)
O4^x—Si3—O8^xi	107.9 (4)	105.5 (4)	110.2 (4)
O4^x—Si3—O16	102.7 (4)	100.9 (4)	104.5 (4)
O6^xi—Si3—O8^xi	113.2 (4)	112.6 (4)	113.8 (4)
O6^xi—Si3—O16	113.3 (4)	113.0 (4)	113.6 (4)
O8^xi—Si3—O16	111.7 (4)	111.6 (4)	111.8 (4)
Ca1^x—Al3—Na1^x	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^x—Al3—Ca21^xxviii	93.92 (10)	92.74 (11)	94.73 (10)
Ca1^x—Al3—Ca21^xxix	79.42 (11)	77.17 (11)	84.84 (12)
Ca1^x—Al3—Ca22^xxviii	88.56 (14)	88.21 (14)	89.32 (14)
Ca1^x—Al3—Na2^xxviii	86.66 (19)	84.97 (19)	88.35 (18)
Ca1^x—Al3—Al1	87.72 (11)	81.32 (11)	93.78 (11)
Ca1^x—Al3—Si3	0	0	0
Ca1^x—Al3—Al5^xxiii	146.18 (13)	144.62 (13)	147.81 (13)
Ca1^x—Al3—Al7^x	64.70 (10)	58.09 (10)	71.70 (11)
Ca1^x—Al3—Al8^xi	134.05 (15)	130.29 (15)	137.93 (16)
Ca1^x—Al3—O4^x	38.5 (3)	31.4 (3)	46.0 (3)
Ca1^x—Al3—O6^xi	118.9 (4)	115.2 (4)	122.8 (4)
Ca1^x—Al3—O8^xi	123.7 (3)	121.9 (3)	126.2 (2)
Ca1^x—Al3—O16	64.4 (3)	54.9 (3)	73.5 (3)
Na1^x—Al3—Ca21^xxviii	93.92 (10)	92.74 (11)	94.73 (10)
Na1^x—Al3—Ca21^xxix	79.42 (11)	77.17 (11)	84.84 (12)
Na1^x—Al3—Ca22^xxviii	88.56 (14)	88.21 (14)	89.32 (14)
Na1^x—Al3—Na2^xxviii	86.66 (19)	84.97 (19)	88.35 (18)
Na1^x—Al3—Al1	87.72 (11)	81.32 (11)	93.78 (11)
Na1^x—Al3—Si3	0	0	0
Na1^x—Al3—Al5^xxiii	146.18 (13)	144.62 (13)	147.81 (13)
Na1^x—Al3—Al7^x	64.70 (10)	58.09 (10)	71.70 (11)
Na1^x—Al3—Al8^xi	134.05 (15)	130.29 (15)	137.93 (16)
Na1^x—Al3—O4^x	38.5 (3)	31.4 (3)	46.0 (3)
Na1^x—Al3—O6^xi	118.9 (4)	115.2 (4)	122.8 (4)
Na1^x—Al3—O8^xi	123.7 (3)	121.9 (3)	126.2 (2)
Na1^x—Al3—O16	64.4 (3)	54.9 (3)	73.5 (3)
Ca21^xxviii—Al3—Ca21^xxix	146.35 (11)	145.86 (11)	146.93 (11)
Ca21^xxviii—Al3—Ca22^xxviii	13.65 (13)	13.65 (13)	13.65 (13)
Ca21^xxviii—Al3—Na2^xxviii	16.34 (19)	15.45 (19)	17.0 (2)
Ca21^xxviii—Al3—Al1	103.61 (11)	103.25 (11)	104.42 (12)
Ca21^xxviii—Al3—Si3	0	0	0
Ca21^xxviii—Al3—Al5^xxiii	53.39 (9)	52.68 (9)	53.71 (9)
Ca21^xxviii—Al3—Al7^x	84.08 (11)	83.57 (11)	84.31 (11)
Ca21^xxviii—Al3—Al8^xi	129.72 (13)	128.08 (13)	130.46 (13)
Ca21^xxviii—Al3—O4^x	84.9 (3)	84.7 (3)	85.6 (3)
Ca21^xxviii—Al3—O6^xi	141.4 (4)	140.9 (4)	142.0 (4)
Ca21^xxviii—Al3—O8^xi	31.3 (2)	30.1 (2)	31.8 (2)
Ca21^xxviii—Al3—O16	99.0 (3)	97.1 (3)	100.1 (3)
Ca21^xxix—Al3—Ca22^xxviii	132.60 (15)	131.95 (15)	134.17 (15)
Ca21^xxix—Al3—Na2^xxviii	130.2 (2)	129.2 (2)	132.5 (2)
Ca21^xxix—Al3—Al1	108.80 (13)	108.00 (13)	109.16 (13)
Ca21^xxix—Al3—Si3	0	0	0
Ca21^xxix—Al3—Al5^xxiii	125.84 (10)	125.22 (10)	127.07 (10)
Ca21^xxix—Al3—Al7^x	64.18 (10)	63.39 (10)	66.01 (10)
Ca21^xxix—Al3—Al8^xi	54.08 (9)	52.65 (9)	54.73 (9)
Ca21^xxix—Al3—O4^x	70.6 (3)	70.0 (3)	71.6 (3)
Ca21^xxix—Al3—O6^xi	38.9 (3)	38.1 (3)	39.2 (3)
Ca21^xxix—Al3—O8^xi	136.3 (3)	135.1 (3)	138.3 (3)
Ca21^xxix—Al3—O16	111.3 (4)	108.8 (4)	112.7 (4)
Ca22^xxviii—Al3—Na2^xxviii	3.1 (2)	2.3 (2)	3.8 (2)
Ca22^xxviii—Al3—Al1	117.18 (15)	116.28 (15)	117.58 (15)
Ca22^xxviii—Al3—Si3	0	0	0
Ca22^xxviii—Al3—Al5^xxiii	58.60 (14)	58.06 (14)	59.82 (14)
Ca22^xxviii—Al3—Al7^x	69.85 (15)	69.62 (15)	70.32 (15)
Ca22^xxviii—Al3—Al8^xi	127.63 (15)	127.00 (15)	128.99 (15)
Ca22^xxviii—Al3—O4^x	74.4 (3)	73.6 (3)	74.7 (3)
Ca22^xxviii—Al3—O6^xi	137.4 (4)	137.0 (4)	137.6 (4)
Ca22^xxviii—Al3—O8^xi	34.8 (3)	33.9 (3)	36.5 (3)
Ca22^xxviii—Al3—O16	107.1 (3)	106.5 (3)	108.4 (3)
Na2^xxviii—Al3—Al1	118.31 (18)	117.35 (17)	119.27 (17)
Na2^xxviii—Al3—Si3	0	0	0
Na2^xxviii—Al3—Al5^xxiii	62.03 (18)	61.20 (19)	62.9 (2)
Na2^xxviii—Al3—Al7^x	67.49 (18)	66.75 (17)	68.24 (17)
Na2^xxviii—Al3—Al8^xi	129.42 (18)	128.27 (17)	130.50 (17)
Na2^xxviii—Al3—O4^x	70.9 (4)	69.6 (4)	72.2 (4)
Na2^xxviii—Al3—O6^xi	137.6 (4)	136.9 (4)	138.3 (4)
Na2^xxviii—Al3—O8^xi	39.1 (3)	36.8 (3)	41.4 (3)
Na2^xxviii—Al3—O16	108.1 (3)	106.9 (3)	109.4 (3)
Al1—Al3—Si3	0	0	0
Al1—Al3—Al5^xxiii	96.97 (12)	94.61 (12)	99.34 (12)
Al1—Al3—Al7^x	151.97 (15)	150.64 (15)	153.34 (15)
Al1—Al3—Al8^xi	95.35 (10)	94.34 (10)	96.35 (10)
Al1—Al3—O4^x	126.2 (3)	125.2 (3)	127.3 (3)
Al1—Al3—O6^xi	97.2 (3)	96.0 (3)	98.5 (3)
Al1—Al3—O8^xi	104.8 (3)	100.8 (3)	108.8 (3)
Al1—Al3—O16	24.3 (3)	22.3 (2)	26.5 (3)
Si3—Al3—Al5^xxiii	0	0	0
Si3—Al3—Al7^x	0	0	0
Si3—Al3—Al8^xi	0	0	0
Si3—Al3—O4^x	0	0	0
Si3—Al3—O6^xi	0	0	0
Si3—Al3—O8^xi	0	0	0
Si3—Al3—O16	0	0	0
Al5^xxiii—Al3—Al7^x	108.77 (13)	106.38 (13)	111.17 (13)
Al5^xxiii—Al3—Al8^xi	78.40 (11)	76.85 (10)	79.90 (11)
Al5^xxiii—Al3—O4^x	127.5 (4)	126.4 (3)	128.6 (4)
Al5^xxiii—Al3—O6^xi	93.2 (4)	92.5 (4)	93.9 (4)
Al5^xxiii—Al3—O8^xi	23.1 (2)	21.9 (2)	24.4 (2)
Al5^xxiii—Al3—O16	112.6 (4)	111.0 (4)	114.3 (4)
Al7^x—Al3—Al8^xi	100.39 (10)	99.71 (10)	101.08 (10)
Al7^x—Al3—O4^x	26.4 (2)	25.2 (2)	27.6 (3)
Al7^x—Al3—O6^xi	92.3 (3)	91.7 (3)	92.9 (3)
Al7^x—Al3—O8^xi	95.4 (3)	91.4 (3)	99.3 (3)
Al7^x—Al3—O16	129.0 (3)	126.1 (3)	131.9 (3)
Al8^xi—Al3—O4^x	119.5 (3)	118.4 (3)	120.6 (3)
Al8^xi—Al3—O6^xi	15.3 (3)	14.0 (3)	16.5 (3)
Al8^xi—Al3—O8^xi	99.3 (2)	98.9 (3)	99.8 (2)
Al8^xi—Al3—O16	115.7 (3)	115.1 (3)	116.3 (3)
O4^x—Al3—O6^xi	107.4 (4)	107.1 (4)	107.6 (4)
O4^x—Al3—O8^xi	107.9 (4)	105.5 (4)	110.2 (4)
O4^x—Al3—O16	102.7 (4)	100.9 (4)	104.5 (4)
O6^xi—Al3—O8^xi	113.2 (4)	112.6 (4)	113.8 (4)
O6^xi—Al3—O16	113.3 (4)	113.0 (4)	113.6 (4)
O8^xi—Al3—O16	111.7 (4)	111.6 (4)	111.8 (4)
Ca22^xxvii—Si4—Na2^xxvii	3.5 (3)	3.1 (3)	4.1 (3)
Ca22^xxvii—Si4—Al4	0	0	0
Ca22^xxvii—Si4—O2	56.7 (3)	54.6 (3)	61.6 (3)
Ca22^xxvii—Si4—O9^ix	126.1 (3)	125.5 (3)	126.4 (3)
Ca22^xxvii—Si4—O11	46.5 (3)	44.0 (3)	47.6 (3)
Ca22^xxvii—Si4—O12^ix	123.5 (4)	123.2 (4)	123.7 (4)
Na2^xxvii—Si4—Al4	0	0	0
Na2^xxvii—Si4—O2	58.3 (3)	53.7 (3)	63.0 (3)
Na2^xxvii—Si4—O9^ix	122.5 (3)	121.7 (3)	123.3 (3)
Na2^xxvii—Si4—O11	46.1 (3)	43.5 (3)	48.6 (3)
Na2^xxvii—Si4—O12^ix	126.9 (4)	126.6 (4)	127.2 (4)
Al4—Si4—O2	0	0	0
Al4—Si4—O9^ix	0	0	0
Al4—Si4—O11	0	0	0
Al4—Si4—O12^ix	0	0	0
O2—Si4—O9^ix	112.5 (5)	111.7 (5)	113.4 (5)
O2—Si4—O11	104.3 (4)	102.2 (4)	106.4 (4)
O2—Si4—O12^ix	112.5 (4)	111.2 (4)	113.5 (4)
O9^ix—Si4—O11	109.1 (4)	107.7 (4)	110.6 (4)
O9^ix—Si4—O12^ix	109.4 (4)	108.8 (4)	109.9 (4)
O11—Si4—O12^ix	108.8 (4)	107.6 (4)	110.0 (4)
Ca1^xxvi—Al4—Ca1^xxx	136.27 (11)	132.15 (12)	140.20 (11)
Ca1^xxvi—Al4—Na1^xxx	136.27 (11)	132.15 (12)	140.20 (11)
Ca1^xxvi—Al4—Ca21^xxvii	75.33 (10)	74.79 (10)	75.66 (10)
Ca1^xxvi—Al4—Ca22^xxvii	86.34 (17)	85.73 (17)	86.61 (17)
Ca1^xxvi—Al4—Na2^xxvii	89.6 (2)	89.4 (2)	89.9 (2)
Ca1^xxvi—Al4—Al1^ix	55.69 (9)	54.66 (9)	56.76 (9)
Ca1^xxvi—Al4—Al2	60.88 (10)	59.20 (10)	62.70 (11)
Ca1^xxvi—Al4—Si4	0	0	0
Ca1^xxvi—Al4—Al6^xxxi	126.03 (9)	124.93 (9)	127.12 (9)
Ca1^xxvi—Al4—Al8	112.08 (13)	109.96 (13)	114.03 (13)
Ca1^xxvi—Al4—O2	111.6 (4)	109.4 (4)	113.6 (4)
Ca1^xxvi—Al4—O9^ix	134.7 (3)	133.0 (3)	136.4 (3)
Ca1^xxvi—Al4—O11	68.8 (3)	67.8 (3)	69.9 (3)
Ca1^xxvi—Al4—O12^ix	41.8 (3)	41.6 (3)	41.9 (3)
Ca1^xxx—Al4—Na1^xxx	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxx—Al4—Ca21^xxvii	91.59 (10)	89.98 (10)	94.79 (10)
Ca1^xxx—Al4—Ca22^xxvii	91.71 (17)	90.07 (16)	92.36 (17)
Ca1^xxx—Al4—Na2^xxvii	87.9 (2)	86.6 (2)	89.1 (2)
Ca1^xxx—Al4—Al1^ix	128.76 (13)	127.21 (13)	130.34 (13)
Ca1^xxx—Al4—Al2	76.84 (11)	71.25 (11)	82.26 (12)
Ca1^xxx—Al4—Si4	0	0	0
Ca1^xxx—Al4—Al6^xxxi	55.77 (9)	53.97 (9)	57.66 (9)
Ca1^xxx—Al4—Al8	110.57 (12)	105.31 (12)	116.02 (12)
Ca1^xxx—Al4—O2	103.9 (3)	101.1 (3)	106.8 (3)
Ca1^xxx—Al4—O9^ix	35.8 (2)	34.2 (2)	37.5 (2)
Ca1^xxx—Al4—O11	78.6 (3)	75.3 (3)	81.9 (3)
Ca1^xxx—Al4—O12^ix	139.0 (4)	137.5 (4)	140.3 (4)
Na1^xxx—Al4—Ca21^xxvii	91.59 (10)	89.98 (10)	94.79 (10)
Na1^xxx—Al4—Ca22^xxvii	91.71 (17)	90.07 (16)	92.36 (17)
Na1^xxx—Al4—Na2^xxvii	87.9 (2)	86.6 (2)	89.1 (2)
Na1^xxx—Al4—Al1^ix	128.76 (13)	127.21 (13)	130.34 (13)
Na1^xxx—Al4—Al2	76.84 (11)	71.25 (11)	82.26 (12)
Na1^xxx—Al4—Si4	0	0	0
Na1^xxx—Al4—Al6^xxxi	55.77 (9)	53.97 (9)	57.66 (9)
Na1^xxx—Al4—Al8	110.57 (12)	105.31 (12)	116.02 (12)
Na1^xxx—Al4—O2	103.9 (3)	101.1 (3)	106.8 (3)
Na1^xxx—Al4—O9^ix	35.8 (2)	34.2 (2)	37.5 (2)
Na1^xxx—Al4—O11	78.6 (3)	75.3 (3)	81.9 (3)
Na1^xxx—Al4—O12^ix	139.0 (4)	137.5 (4)	140.3 (4)
Ca21^xxvii—Al4—Ca22^xxvii	13.83 (14)	13.83 (14)	13.83 (14)
Ca21^xxvii—Al4—Na2^xxvii	16.5 (2)	16.0 (2)	17.0 (2)
Ca21^xxvii—Al4—Al1^ix	129.58 (14)	128.58 (14)	130.91 (14)
Ca21^xxvii—Al4—Al2	57.35 (9)	56.63 (9)	58.78 (10)
Ca21^xxvii—Al4—Si4	0	0	0
Ca21^xxvii—Al4—Al6^xxxi	147.62 (13)	146.98 (13)	148.83 (13)
Ca21^xxvii—Al4—Al8	94.69 (11)	93.24 (11)	95.32 (11)
Ca21^xxvii—Al4—O2	74.8 (3)	69.7 (3)	77.1 (3)
Ca21^xxvii—Al4—O9^ix	127.3 (3)	126.5 (3)	128.9 (3)
Ca21^xxvii—Al4—O11	31.3 (3)	30.1 (3)	34.0 (3)
Ca21^xxvii—Al4—O12^ix	115.5 (4)	115.0 (4)	115.7 (4)
Ca22^xxvii—Al4—Na2^xxvii	3.5 (3)	3.1 (3)	4.1 (3)
Ca22^xxvii—Al4—Al1^ix	137.7 (2)	136.3 (2)	138.7 (2)
Ca22^xxvii—Al4—Al2	72.59 (15)	70.95 (15)	73.40 (15)
Ca22^xxvii—Al4—Si4	0	0	0
Ca22^xxvii—Al4—Al6^xxxi	144.22 (19)	143.97 (19)	144.57 (19)
Ca22^xxvii—Al4—Al8	80.80 (15)	80.14 (15)	82.32 (15)
Ca22^xxvii—Al4—O2	56.7 (3)	54.6 (3)	61.6 (3)
Ca22^xxvii—Al4—O9^ix	126.1 (3)	125.5 (3)	126.4 (3)
Ca22^xxvii—Al4—O11	46.5 (3)	44.0 (3)	47.6 (3)
Ca22^xxvii—Al4—O12^ix	123.5 (4)	123.2 (4)	123.7 (4)
Na2^xxvii—Al4—Al1^ix	140.9 (3)	140.0 (2)	141.8 (3)
Na2^xxvii—Al4—Al2	72.56 (18)	70.82 (19)	74.3 (2)
Na2^xxvii—Al4—Si4	0	0	0
Na2^xxvii—Al4—Al6^xxxi	140.7 (2)	140.1 (2)	141.5 (2)
Na2^xxvii—Al4—Al8	80.90 (19)	79.32 (18)	82.48 (17)
Na2^xxvii—Al4—O2	58.3 (3)	53.7 (3)	63.0 (3)
Na2^xxvii—Al4—O9^ix	122.5 (3)	121.7 (3)	123.3 (3)
Na2^xxvii—Al4—O11	46.1 (3)	43.5 (3)	48.6 (3)
Na2^xxvii—Al4—O12^ix	126.9 (4)	126.6 (4)	127.2 (4)
Al1^ix—Al4—Al2	100.37 (10)	99.46 (10)	101.32 (10)
Al1^ix—Al4—Si4	0	0	0
Al1^ix—Al4—Al6^xxxi	78.29 (10)	76.72 (10)	79.78 (11)
Al1^ix—Al4—Al8	95.13 (10)	93.92 (10)	96.31 (10)
Al1^ix—Al4—O2	114.3 (3)	112.9 (3)	115.5 (3)
Al1^ix—Al4—O9^ix	96.3 (2)	94.6 (3)	97.8 (2)
Al1^ix—Al4—O11	120.3 (3)	119.2 (3)	121.6 (3)
Al1^ix—Al4—O12^ix	14.5 (3)	13.4 (3)	15.5 (4)
Al2—Al4—Si4	0	0	0
Al2—Al4—Al6^xxxi	108.25 (13)	106.27 (13)	110.21 (13)
Al2—Al4—Al8	152.28 (15)	151.03 (15)	153.56 (15)
Al2—Al4—O2	130.6 (3)	127.1 (3)	134.2 (3)
Al2—Al4—O9^ix	96.5 (3)	93.4 (3)	99.4 (3)
Al2—Al4—O11	26.5 (2)	25.2 (2)	27.9 (3)
Al2—Al4—O12^ix	92.6 (3)	90.8 (3)	94.3 (3)
Si4—Al4—Al6^xxxi	0	0	0
Si4—Al4—Al8	0	0	0
Si4—Al4—O2	0	0	0
Si4—Al4—O9^ix	0	0	0
Si4—Al4—O11	0	0	0
Si4—Al4—O12^ix	0	0	0
Al6^xxxi—Al4—Al8	97.26 (13)	95.06 (12)	99.52 (13)
Al6^xxxi—Al4—O2	112.2 (4)	110.0 (4)	114.4 (4)
Al6^xxxi—Al4—O9^ix	20.0 (2)	19.6 (2)	20.5 (2)
Al6^xxxi—Al4—O11	126.3 (4)	125.6 (3)	126.9 (4)
Al6^xxxi—Al4—O12^ix	92.3 (4)	91.7 (4)	92.7 (4)
Al8—Al4—O2	23.0 (3)	20.5 (2)	25.6 (3)
Al8—Al4—O9^ix	104.5 (3)	101.1 (3)	108.1 (3)
Al8—Al4—O11	126.6 (3)	125.4 (3)	127.7 (3)
Al8—Al4—O12^ix	97.2 (3)	94.9 (3)	99.4 (3)
O2—Al4—O9^ix	112.5 (5)	111.7 (5)	113.4 (5)
O2—Al4—O11	104.3 (4)	102.2 (4)	106.4 (4)
O2—Al4—O12^ix	112.5 (4)	111.2 (4)	113.5 (4)
O9^ix—Al4—O11	109.1 (4)	107.7 (4)	110.6 (4)
O9^ix—Al4—O12^ix	109.4 (4)	108.8 (4)	109.9 (4)
O11—Al4—O12^ix	108.8 (4)	107.6 (4)	110.0 (4)
Ca1^xxiii—Si5—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Si5—Ca21^xxiv	77.99 (11)	76.52 (11)	80.20 (11)
Ca1^xxiii—Si5—Ca22^xxiv	72.81 (15)	72.16 (15)	73.63 (15)
Ca1^xxiii—Si5—Na2^xxiv	74.8 (2)	74.1 (2)	75.4 (2)
Ca1^xxiii—Si5—Al5	0	0	0
Ca1^xxiii—Si5—O1	48.1 (3)	46.2 (3)	50.2 (3)
Ca1^xxiii—Si5—O7	137.8 (4)	134.8 (4)	140.7 (3)
Ca1^xxiii—Si5—O8^xii	109.5 (3)	107.3 (3)	111.6 (3)
Ca1^xxiii—Si5—O13^xiii	55.1 (3)	52.1 (3)	58.2 (3)
Na1^xxiii—Si5—Ca21^xxiv	77.99 (11)	76.52 (11)	80.20 (11)
Na1^xxiii—Si5—Ca22^xxiv	72.81 (15)	72.16 (15)	73.63 (15)
Na1^xxiii—Si5—Na2^xxiv	74.8 (2)	74.1 (2)	75.4 (2)
Na1^xxiii—Si5—Al5	0	0	0
Na1^xxiii—Si5—O1	48.1 (3)	46.2 (3)	50.2 (3)
Na1^xxiii—Si5—O7	137.8 (4)	134.8 (4)	140.7 (3)
Na1^xxiii—Si5—O8^xii	109.5 (3)	107.3 (3)	111.6 (3)
Na1^xxiii—Si5—O13^xiii	55.1 (3)	52.1 (3)	58.2 (3)
Ca21^xxiv—Si5—Ca22^xxiv	15.26 (15)	15.26 (15)	15.26 (15)
Ca21^xxiv—Si5—Na2^xxiv	17.9 (2)	17.2 (2)	18.6 (2)
Ca21^xxiv—Si5—Al5	0	0	0
Ca21^xxiv—Si5—O1	117.7 (3)	116.5 (3)	119.8 (3)
Ca21^xxiv—Si5—O7	131.0 (3)	129.2 (3)	132.1 (3)
Ca21^xxiv—Si5—O8^xii	52.1 (3)	51.8 (3)	52.7 (3)
Ca21^xxiv—Si5—O13^xiii	48.7 (3)	46.2 (3)	49.9 (3)
Ca22^xxiv—Si5—Na2^xxiv	3.9 (3)	3.3 (3)	4.5 (3)
Ca22^xxiv—Si5—Al5	0	0	0
Ca22^xxiv—Si5—O1	107.0 (3)	105.6 (3)	107.7 (3)
Ca22^xxiv—Si5—O7	142.6 (3)	141.3 (3)	144.1 (3)
Ca22^xxiv—Si5—O8^xii	46.1 (3)	45.5 (3)	46.5 (3)
Ca22^xxiv—Si5—O13^xiii	55.5 (3)	54.3 (3)	58.1 (3)
Na2^xxiv—Si5—Al5	0	0	0
Na2^xxiv—Si5—O1	105.9 (3)	104.4 (3)	107.5 (3)
Na2^xxiv—Si5—O7	142.6 (3)	141.0 (3)	144.1 (3)
Na2^xxiv—Si5—O8^xii	42.4 (3)	41.5 (3)	43.4 (3)
Na2^xxiv—Si5—O13^xiii	60.4 (4)	57.7 (4)	63.0 (4)
Al5—Si5—O1	0	0	0
Al5—Si5—O7	0	0	0
Al5—Si5—O8^xii	0	0	0
Al5—Si5—O13^xiii	0	0	0
O1—Si5—O7	110.6 (3)	109.9 (3)	111.4 (3)
O1—Si5—O8^xii	113.2 (4)	111.9 (4)	114.4 (4)
O1—Si5—O13^xiii	102.3 (4)	101.0 (4)	103.7 (4)
O7—Si5—O8^xii	112.6 (4)	111.0 (5)	114.2 (4)
O7—Si5—O13^xiii	117.3 (4)	116.3 (5)	118.2 (4)
O8^xii—Si5—O13^xiii	100.2 (4)	98.6 (4)	101.8 (4)
Ca1^xxiii—Al5—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—Al5—Ca21^xxiv	77.99 (11)	76.52 (11)	80.20 (11)
Ca1^xxiii—Al5—Ca22^xxiv	72.81 (15)	72.16 (15)	73.63 (15)
Ca1^xxiii—Al5—Na2^xxiv	74.8 (2)	74.1 (2)	75.4 (2)
Ca1^xxiii—Al5—Al2^xi	71.26 (11)	69.43 (10)	73.17 (11)
Ca1^xxiii—Al5—Al3ⁱ	123.76 (13)	122.59 (13)	124.94 (13)
Ca1^xxiii—Al5—Si5	0	0	0
Ca1^xxiii—Al5—Al7	113.46 (14)	109.97 (14)	116.90 (13)
Ca1^xxiii—Al5—Al8^xiii	69.20 (12)	63.62 (11)	74.86 (12)
Ca1^xxiii—Al5—O1	48.1 (3)	46.2 (3)	50.2 (3)
Ca1^xxiii—Al5—O7	137.8 (4)	134.8 (4)	140.7 (3)
Ca1^xxiii—Al5—O8^xii	109.5 (3)	107.3 (3)	111.6 (3)
Ca1^xxiii—Al5—O13^xiii	55.1 (3)	52.1 (3)	58.2 (3)
Na1^xxiii—Al5—Ca21^xxiv	77.99 (11)	76.52 (11)	80.20 (11)
Na1^xxiii—Al5—Ca22^xxiv	72.81 (15)	72.16 (15)	73.63 (15)
Na1^xxiii—Al5—Na2^xxiv	74.8 (2)	74.1 (2)	75.4 (2)
Na1^xxiii—Al5—Al2^xi	71.26 (11)	69.43 (10)	73.17 (11)
Na1^xxiii—Al5—Al3ⁱ	123.76 (13)	122.59 (13)	124.94 (13)
Na1^xxiii—Al5—Si5	0	0	0
Na1^xxiii—Al5—Al7	113.46 (14)	109.97 (14)	116.90 (13)
Na1^xxiii—Al5—Al8^xiii	69.20 (12)	63.62 (11)	74.86 (12)
Na1^xxiii—Al5—O1	48.1 (3)	46.2 (3)	50.2 (3)
Na1^xxiii—Al5—O7	137.8 (4)	134.8 (4)	140.7 (3)
Na1^xxiii—Al5—O8^xii	109.5 (3)	107.3 (3)	111.6 (3)
Na1^xxiii—Al5—O13^xiii	55.1 (3)	52.1 (3)	58.2 (3)
Ca21^xxiv—Al5—Ca22^xxiv	15.26 (15)	15.26 (15)	15.26 (15)
Ca21^xxiv—Al5—Na2^xxiv	17.9 (2)	17.2 (2)	18.6 (2)
Ca21^xxiv—Al5—Al2^xi	134.55 (13)	133.33 (13)	137.07 (13)
Ca21^xxiv—Al5—Al3ⁱ	73.71 (12)	73.41 (11)	74.33 (12)
Ca21^xxiv—Al5—Si5	0	0	0
Ca21^xxiv—Al5—Al7	144.04 (13)	142.88 (13)	144.56 (14)
Ca21^xxiv—Al5—Al8^xiii	60.00 (11)	58.28 (11)	60.78 (11)
Ca21^xxiv—Al5—O1	117.7 (3)	116.5 (3)	119.8 (3)
Ca21^xxiv—Al5—O7	131.0 (3)	129.2 (3)	132.1 (3)
Ca21^xxiv—Al5—O8^xii	52.1 (3)	51.8 (3)	52.7 (3)
Ca21^xxiv—Al5—O13^xiii	48.7 (3)	46.2 (3)	49.9 (3)
Ca22^xxiv—Al5—Na2^xxiv	3.9 (3)	3.3 (3)	4.5 (3)
Ca22^xxiv—Al5—Al2^xi	122.11 (16)	120.18 (15)	123.04 (16)
Ca22^xxiv—Al5—Al3ⁱ	68.39 (17)	67.27 (17)	68.90 (18)
Ca22^xxiv—Al5—Si5	0	0	0
Ca22^xxiv—Al5—Al7	157.53 (17)	157.11 (17)	158.24 (17)
Ca22^xxiv—Al5—Al8^xiii	70.27 (17)	69.38 (17)	72.14 (17)
Ca22^xxiv—Al5—O1	107.0 (3)	105.6 (3)	107.7 (3)
Ca22^xxiv—Al5—O7	142.6 (3)	141.3 (3)	144.1 (3)
Ca22^xxiv—Al5—O8^xii	46.1 (3)	45.5 (3)	46.5 (3)
Ca22^xxiv—Al5—O13^xiii	55.5 (3)	54.3 (3)	58.1 (3)
Na2^xxiv—Al5—Al2^xi	119.46 (18)	117.61 (18)	121.36 (19)
Na2^xxiv—Al5—Al3ⁱ	64.2 (2)	63.5 (2)	64.9 (2)
Na2^xxiv—Al5—Si5	0	0	0
Na2^xxiv—Al5—Al7	160.50 (18)	158.9 (2)	162.1 (2)
Na2^xxiv—Al5—Al8^xiii	74.7 (2)	72.7 (2)	76.9 (2)
Na2^xxiv—Al5—O1	105.9 (3)	104.4 (3)	107.5 (3)
Na2^xxiv—Al5—O7	142.6 (3)	141.0 (3)	144.1 (3)
Na2^xxiv—Al5—O8^xii	42.4 (3)	41.5 (3)	43.4 (3)
Na2^xxiv—Al5—O13^xiii	60.4 (4)	57.7 (4)	63.0 (4)
Al2^xi—Al5—Al3ⁱ	96.72 (13)	95.23 (13)	98.25 (13)
Al2^xi—Al5—Si5	0	0	0
Al2^xi—Al5—Al7	79.90 (9)	79.32 (9)	80.45 (9)
Al2^xi—Al5—Al8^xiii	131.66 (15)	129.81 (15)	133.53 (15)
Al2^xi—Al5—O1	23.1 (3)	22.9 (3)	23.3 (3)
Al2^xi—Al5—O7	93.1 (2)	92.1 (2)	94.0 (2)
Al2^xi—Al5—O8^xii	109.2 (3)	108.3 (3)	110.1 (3)
Al2^xi—Al5—O13^xiii	124.9 (3)	123.9 (3)	125.8 (3)
Al3ⁱ—Al5—Si5	0	0	0
Al3ⁱ—Al5—Al7	117.99 (14)	114.62 (14)	121.29 (14)
Al3ⁱ—Al5—Al8^xiii	128.12 (11)	126.60 (11)	129.72 (11)
Al3ⁱ—Al5—O1	108.6 (3)	106.7 (4)	110.5 (3)
Al3ⁱ—Al5—O7	96.2 (4)	93.1 (4)	99.2 (4)
Al3ⁱ—Al5—O8^xii	22.1 (3)	21.0 (3)	23.1 (3)
Al3ⁱ—Al5—O13^xiii	121.8 (3)	119.7 (3)	123.9 (3)
Si5—Al5—Al7	0	0	0
Si5—Al5—Al8^xiii	0	0	0
Si5—Al5—O1	0	0	0
Si5—Al5—O7	0	0	0
Si5—Al5—O8^xii	0	0	0
Si5—Al5—O13^xiii	0	0	0
Al7—Al5—Al8^xiii	91.41 (12)	90.52 (12)	92.31 (12)
Al7—Al5—O1	91.8 (3)	91.1 (3)	92.4 (3)
Al7—Al5—O7	24.5 (3)	22.4 (3)	26.7 (3)
Al7—Al5—O8^xii	136.6 (3)	134.9 (3)	138.3 (3)
Al7—Al5—O13^xiii	108.8 (3)	106.7 (3)	110.8 (3)
Al8^xiii—Al5—O1	112.2 (4)	109.6 (3)	114.8 (4)
Al8^xiii—Al5—O7	98.0 (3)	97.1 (3)	98.9 (3)
Al8^xiii—Al5—O8^xii	109.3 (3)	108.2 (3)	110.4 (3)
Al8^xiii—Al5—O13^xiii	19.3 (3)	17.5 (3)	21.1 (3)
O1—Al5—O7	110.6 (3)	109.9 (3)	111.4 (3)
O1—Al5—O8^xii	113.2 (4)	111.9 (4)	114.4 (4)
O1—Al5—O13^xiii	102.3 (4)	101.0 (4)	103.7 (4)
O7—Al5—O8^xii	112.6 (4)	111.0 (5)	114.2 (4)
O7—Al5—O13^xiii	117.3 (4)	116.3 (5)	118.2 (4)
O8^xii—Al5—O13^xiii	100.2 (4)	98.6 (4)	101.8 (4)
Ca1^xxxii—Si6—Na1^xxxii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxii—Si6—Ca21^xxvi	74.81 (10)	72.86 (10)	76.44 (10)
Ca1^xxxii—Si6—Ca22^xxvi	76.72 (14)	75.83 (14)	78.52 (14)
Ca1^xxxii—Si6—Na2^xxvi	78.49 (18)	76.69 (18)	80.20 (19)
Ca1^xxxii—Si6—Al6	0	0	0
Ca1^xxxii—Si6—O5^xiv	52.4 (3)	50.4 (3)	54.4 (3)
Ca1^xxxii—Si6—O9^xv	51.1 (3)	49.7 (3)	52.7 (3)
Ca1^xxxii—Si6—O10	137.4 (3)	133.6 (3)	141.2 (2)
Ca1^xxxii—Si6—O15^xvi	112.9 (3)	109.1 (3)	116.8 (3)
Na1^xxxii—Si6—Ca21^xxvi	74.81 (10)	72.86 (10)	76.44 (10)
Na1^xxxii—Si6—Ca22^xxvi	76.72 (14)	75.83 (14)	78.52 (14)
Na1^xxxii—Si6—Na2^xxvi	78.49 (18)	76.69 (18)	80.20 (19)
Na1^xxxii—Si6—Al6	0	0	0
Na1^xxxii—Si6—O5^xiv	52.4 (3)	50.4 (3)	54.4 (3)
Na1^xxxii—Si6—O9^xv	51.1 (3)	49.7 (3)	52.7 (3)
Na1^xxxii—Si6—O10	137.4 (3)	133.6 (3)	141.2 (2)
Na1^xxxii—Si6—O15^xvi	112.9 (3)	109.1 (3)	116.8 (3)
Ca21^xxvi—Si6—Ca22^xxvi	14.35 (17)	14.35 (17)	14.35 (17)
Ca21^xxvi—Si6—Na2^xxvi	18.6 (2)	17.3 (2)	19.2 (2)
Ca21^xxvi—Si6—Al6	0	0	0
Ca21^xxvi—Si6—O5^xiv	59.6 (3)	58.3 (3)	61.2 (3)
Ca21^xxvi—Si6—O9^xv	107.6 (3)	105.5 (3)	108.5 (3)
Ca21^xxvi—Si6—O10	140.5 (3)	139.7 (3)	142.3 (3)
Ca21^xxvi—Si6—O15^xvi	45.8 (3)	44.0 (3)	46.8 (3)
Ca22^xxvi—Si6—Na2^xxvi	3.5 (3)	2.9 (3)	4.4 (3)
Ca22^xxvi—Si6—Al6	0	0	0
Ca22^xxvi—Si6—O5^xiv	50.4 (3)	49.3 (3)	51.2 (3)
Ca22^xxvi—Si6—O9^xv	115.1 (3)	114.1 (3)	117.4 (3)
Ca22^xxvi—Si6—O10	132.6 (4)	130.5 (4)	133.5 (4)
Ca22^xxvi—Si6—O15^xvi	51.3 (3)	50.3 (3)	53.4 (4)
Na2^xxvi—Si6—Al6	0	0	0
Na2^xxvi—Si6—O5^xiv	48.1 (3)	47.2 (3)	49.0 (3)
Na2^xxvi—Si6—O9^xv	119.6 (3)	116.9 (3)	122.3 (4)
Na2^xxvi—Si6—O10	128.5 (4)	126.4 (4)	130.4 (4)
Na2^xxvi—Si6—O15^xvi	54.1 (4)	51.8 (4)	56.5 (4)
Al6—Si6—O5^xiv	0	0	0
Al6—Si6—O9^xv	0	0	0
Al6—Si6—O10	0	0	0
Al6—Si6—O15^xvi	0	0	0
O5^xiv—Si6—O9^xv	102.9 (4)	101.5 (4)	104.4 (4)
O5^xiv—Si6—O10	117.0 (5)	115.1 (5)	118.8 (4)
O5^xiv—Si6—O15^xvi	102.2 (5)	99.8 (4)	104.6 (5)
O9^xv—Si6—O10	111.7 (4)	110.8 (4)	112.6 (4)
O9^xv—Si6—O15^xvi	113.1 (4)	112.3 (4)	114.0 (4)
O10—Si6—O15^xvi	109.6 (4)	108.9 (4)	110.4 (4)
Ca1^xxxii—Al6—Na1^xxxii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxii—Al6—Ca21^xxvi	74.81 (10)	72.86 (10)	76.44 (10)
Ca1^xxxii—Al6—Ca22^xxvi	76.72 (14)	75.83 (14)	78.52 (14)
Ca1^xxxii—Al6—Na2^xxvi	78.49 (18)	76.69 (18)	80.20 (19)
Ca1^xxxii—Al6—Al1^xiv	65.68 (11)	62.40 (11)	68.87 (11)
Ca1^xxxii—Al6—Al2^xvi	151.00 (14)	146.42 (14)	155.41 (13)
Ca1^xxxii—Al6—Al4^vii	70.63 (11)	68.59 (10)	72.81 (11)
Ca1^xxxii—Al6—Si6	0	0	0
Ca1^xxxii—Al6—Al7^xxx	128.41 (13)	124.33 (13)	132.68 (14)
Ca1^xxxii—Al6—O5^xiv	52.4 (3)	50.4 (3)	54.4 (3)
Ca1^xxxii—Al6—O9^xv	51.1 (3)	49.7 (3)	52.7 (3)
Ca1^xxxii—Al6—O10	137.4 (3)	133.6 (3)	141.2 (2)
Ca1^xxxii—Al6—O15^xvi	112.9 (3)	109.1 (3)	116.8 (3)
Na1^xxxii—Al6—Ca21^xxvi	74.81 (10)	72.86 (10)	76.44 (10)
Na1^xxxii—Al6—Ca22^xxvi	76.72 (14)	75.83 (14)	78.52 (14)
Na1^xxxii—Al6—Na2^xxvi	78.49 (18)	76.69 (18)	80.20 (19)
Na1^xxxii—Al6—Al1^xiv	65.68 (11)	62.40 (11)	68.87 (11)
Na1^xxxii—Al6—Al2^xvi	151.00 (14)	146.42 (14)	155.41 (13)
Na1^xxxii—Al6—Al4^vii	70.63 (11)	68.59 (10)	72.81 (11)
Na1^xxxii—Al6—Si6	0	0	0
Na1^xxxii—Al6—Al7^xxx	128.41 (13)	124.33 (13)	132.68 (14)
Na1^xxxii—Al6—O5^xiv	52.4 (3)	50.4 (3)	54.4 (3)
Na1^xxxii—Al6—O9^xv	51.1 (3)	49.7 (3)	52.7 (3)
Na1^xxxii—Al6—O10	137.4 (3)	133.6 (3)	141.2 (2)
Na1^xxxii—Al6—O15^xvi	112.9 (3)	109.1 (3)	116.8 (3)
Ca21^xxvi—Al6—Ca22^xxvi	14.35 (17)	14.35 (17)	14.35 (17)
Ca21^xxvi—Al6—Na2^xxvi	18.6 (2)	17.3 (2)	19.2 (2)
Ca21^xxvi—Al6—Al1^xiv	76.51 (12)	74.89 (12)	77.24 (12)
Ca21^xxvi—Al6—Al2^xvi	117.62 (13)	117.53 (13)	117.80 (13)
Ca21^xxvi—Al6—Al4^vii	120.08 (13)	117.76 (13)	121.31 (13)
Ca21^xxvi—Al6—Si6	0	0	0
Ca21^xxvi—Al6—Al7^xxx	68.25 (10)	67.37 (10)	68.66 (10)
Ca21^xxvi—Al6—O5^xiv	59.6 (3)	58.3 (3)	61.2 (3)
Ca21^xxvi—Al6—O9^xv	107.6 (3)	105.5 (3)	108.5 (3)
Ca21^xxvi—Al6—O10	140.5 (3)	139.7 (3)	142.3 (3)
Ca21^xxvi—Al6—O15^xvi	45.8 (3)	44.0 (3)	46.8 (3)
Ca22^xxvi—Al6—Na2^xxvi	3.5 (3)	2.9 (3)	4.4 (3)
Ca22^xxvi—Al6—Al1^xiv	63.19 (17)	62.53 (16)	64.52 (17)
Ca22^xxvi—Al6—Al2^xvi	108.66 (18)	108.21 (18)	108.86 (18)
Ca22^xxvi—Al6—Al4^vii	128.44 (18)	127.03 (18)	130.90 (19)
Ca22^xxvi—Al6—Si6	0	0	0
Ca22^xxvi—Al6—Al7^xxx	74.25 (15)	73.75 (15)	75.33 (15)
Ca22^xxvi—Al6—O5^xiv	50.4 (3)	49.3 (3)	51.2 (3)
Ca22^xxvi—Al6—O9^xv	115.1 (3)	114.1 (3)	117.4 (3)
Ca22^xxvi—Al6—O10	132.6 (4)	130.5 (4)	133.5 (4)
Ca22^xxvi—Al6—O15^xvi	51.3 (3)	50.3 (3)	53.4 (4)
Na2^xxvi—Al6—Al1^xiv	60.8 (2)	60.2 (2)	61.3 (2)
Na2^xxvi—Al6—Al2^xvi	105.7 (2)	105.0 (2)	106.5 (2)
Na2^xxvi—Al6—Al4^vii	134.3 (2)	130.2 (2)	138.4 (2)
Na2^xxvi—Al6—Si6	0	0	0
Na2^xxvi—Al6—Al7^xxx	76.57 (18)	75.06 (19)	78.0 (2)
Na2^xxvi—Al6—O5^xiv	48.1 (3)	47.2 (3)	49.0 (3)
Na2^xxvi—Al6—O9^xv	119.6 (3)	116.9 (3)	122.3 (4)
Na2^xxvi—Al6—O10	128.5 (4)	126.4 (4)	130.4 (4)
Na2^xxvi—Al6—O15^xvi	54.1 (4)	51.8 (4)	56.5 (4)
Al1^xiv—Al6—Al2^xvi	90.92 (12)	89.97 (12)	91.89 (13)
Al1^xiv—Al6—Al4^vii	127.91 (11)	126.25 (11)	129.65 (10)
Al1^xiv—Al6—Si6	0	0	0
Al1^xiv—Al6—Al7^xxx	131.89 (15)	129.72 (15)	134.04 (15)
Al1^xiv—Al6—O5^xiv	20.1 (3)	18.2 (3)	21.9 (3)
Al1^xiv—Al6—O9^xv	111.6 (3)	111.1 (3)	112.2 (3)
Al1^xiv—Al6—O10	97.0 (3)	95.4 (3)	98.5 (3)
Al1^xiv—Al6—O15^xvi	112.7 (4)	109.6 (4)	115.8 (4)
Al2^xvi—Al6—Al4^vii	117.74 (14)	114.61 (14)	120.90 (14)
Al2^xvi—Al6—Si6	0	0	0
Al2^xvi—Al6—Al7^xxx	79.67 (9)	79.14 (9)	80.20 (9)
Al2^xvi—Al6—O5^xiv	108.7 (3)	106.2 (3)	111.2 (3)
Al2^xvi—Al6—O9^xv	134.6 (3)	132.3 (3)	136.9 (3)
Al2^xvi—Al6—O10	23.7 (3)	22.2 (3)	25.1 (3)
Al2^xvi—Al6—O15^xvi	91.3 (3)	90.6 (3)	91.9 (3)
Al4^vii—Al6—Si6	0	0	0
Al4^vii—Al6—Al7^xxx	97.16 (13)	95.90 (13)	98.45 (13)
Al4^vii—Al6—O5^xiv	122.0 (3)	119.7 (3)	124.3 (3)
Al4^vii—Al6—O9^xv	19.6 (3)	18.5 (3)	20.6 (3)
Al4^vii—Al6—O10	96.7 (4)	94.6 (4)	98.8 (3)
Al4^vii—Al6—O15^xvi	109.2 (4)	107.4 (4)	111.0 (4)
Si6—Al6—Al7^xxx	0	0	0
Si6—Al6—O5^xiv	0	0	0
Si6—Al6—O9^xv	0	0	0
Si6—Al6—O10	0	0	0
Si6—Al6—O15^xvi	0	0	0
Al7^xxx—Al6—O5^xiv	124.5 (3)	123.1 (3)	125.9 (3)
Al7^xxx—Al6—O9^xv	108.0 (3)	107.6 (3)	108.6 (3)
Al7^xxx—Al6—O10	92.6 (2)	92.2 (2)	93.0 (2)
Al7^xxx—Al6—O15^xvi	22.9 (3)	22.0 (3)	23.7 (3)
O5^xiv—Al6—O9^xv	102.9 (4)	101.5 (4)	104.4 (4)
O5^xiv—Al6—O10	117.0 (5)	115.1 (5)	118.8 (4)
O5^xiv—Al6—O15^xvi	102.2 (5)	99.8 (4)	104.6 (5)
O9^xv—Al6—O10	111.7 (4)	110.8 (4)	112.6 (4)
O9^xv—Al6—O15^xvi	113.1 (4)	112.3 (4)	114.0 (4)
O10—Al6—O15^xvi	109.6 (4)	108.9 (4)	110.4 (4)
Ca1—Si7—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—Si7—Al7	0	0	0
Ca1—Si7—O4	37.1 (3)	31.3 (3)	43.1 (3)
Ca1—Si7—O7	69.3 (3)	62.3 (3)	76.0 (3)
Ca1—Si7—O14^xii	127.8 (3)	123.3 (3)	132.3 (3)
Ca1—Si7—O15^xi	118.3 (4)	116.7 (4)	120.0 (3)
Na1—Si7—Al7	0	0	0
Na1—Si7—O4	37.1 (3)	31.3 (3)	43.1 (3)
Na1—Si7—O7	69.3 (3)	62.3 (3)	76.0 (3)
Na1—Si7—O14^xii	127.8 (3)	123.3 (3)	132.3 (3)
Na1—Si7—O15^xi	118.3 (4)	116.7 (4)	120.0 (3)
Al7—Si7—O4	0	0	0
Al7—Si7—O7	0	0	0
Al7—Si7—O14^xii	0	0	0
Al7—Si7—O15^xi	0	0	0
O4—Si7—O7	106.0 (4)	104.6 (4)	107.4 (4)
O4—Si7—O14^xii	109.5 (5)	107.7 (5)	111.2 (5)
O4—Si7—O15^xi	108.2 (4)	107.8 (4)	108.6 (4)
O7—Si7—O14^xii	111.1 (4)	109.7 (4)	112.6 (4)
O7—Si7—O15^xi	113.0 (5)	112.9 (5)	113.2 (5)
O14^xii—Si7—O15^xi	108.9 (4)	106.9 (4)	110.8 (4)
Ca1—Al7—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—Al7—Ca21^xxxiii	83.30 (11)	82.24 (11)	83.92 (11)
Ca1—Al7—Ca22^xxv	86.69 (14)	80.91 (13)	90.30 (14)
Ca1—Al7—Ca22^xxxiii	88.34 (14)	88.06 (14)	89.01 (14)
Ca1—Al7—Na2^xxv	84.11 (18)	79.47 (18)	88.85 (18)
Ca1—Al7—Al1^xii	138.67 (13)	133.60 (13)	143.25 (13)
Ca1—Al7—Al3^xviii	63.56 (10)	57.14 (9)	70.29 (11)
Ca1—Al7—Al5	91.89 (11)	86.37 (11)	97.13 (11)
Ca1—Al7—Al6^xiii	140.63 (15)	138.84 (16)	142.22 (14)
Ca1—Al7—Si7	0	0	0
Ca1—Al7—O4	37.1 (3)	31.3 (3)	43.1 (3)
Ca1—Al7—O7	69.3 (3)	62.3 (3)	76.0 (3)
Ca1—Al7—O14^xii	127.8 (3)	123.3 (3)	132.3 (3)
Ca1—Al7—O15^xi	118.3 (4)	116.7 (4)	120.0 (3)
Na1—Al7—Ca21^xxxiii	83.30 (11)	82.24 (11)	83.92 (11)
Na1—Al7—Ca22^xxv	86.69 (14)	80.91 (13)	90.30 (14)
Na1—Al7—Ca22^xxxiii	88.34 (14)	88.06 (14)	89.01 (14)
Na1—Al7—Na2^xxv	84.11 (18)	79.47 (18)	88.85 (18)
Na1—Al7—Al1^xii	138.67 (13)	133.60 (13)	143.25 (13)
Na1—Al7—Al3^xviii	63.56 (10)	57.14 (9)	70.29 (11)
Na1—Al7—Al5	91.89 (11)	86.37 (11)	97.13 (11)
Na1—Al7—Al6^xiii	140.63 (15)	138.84 (16)	142.22 (14)
Na1—Al7—Si7	0	0	0
Na1—Al7—O4	37.1 (3)	31.3 (3)	43.1 (3)
Na1—Al7—O7	69.3 (3)	62.3 (3)	76.0 (3)
Na1—Al7—O14^xii	127.8 (3)	123.3 (3)	132.3 (3)
Na1—Al7—O15^xi	118.3 (4)	116.7 (4)	120.0 (3)
Ca21^xxxiii—Al7—Ca22^xxv	128.81 (14)	127.11 (14)	129.55 (14)
Ca21^xxxiii—Al7—Ca22^xxxiii	13.62 (13)	13.62 (13)	13.62 (13)
Ca21^xxxiii—Al7—Na2^xxv	129.41 (19)	127.17 (19)	130.40 (19)
Ca21^xxxiii—Al7—Al1^xii	126.97 (10)	126.08 (10)	127.39 (10)
Ca21^xxxiii—Al7—Al3^xviii	67.41 (10)	65.54 (10)	68.23 (10)
Ca21^xxxiii—Al7—Al5	125.47 (15)	125.05 (15)	126.41 (15)
Ca21^xxxiii—Al7—Al6^xiii	59.23 (9)	58.42 (9)	60.98 (9)
Ca21^xxxiii—Al7—Si7	0	0	0
Ca21^xxxiii—Al7—O4	73.5 (3)	71.0 (3)	74.8 (3)
Ca21^xxxiii—Al7—O7	111.0 (4)	110.3 (4)	112.1 (3)
Ca21^xxxiii—Al7—O14^xii	135.5 (3)	133.6 (3)	136.6 (3)
Ca21^xxxiii—Al7—O15^xi	36.8 (3)	35.8 (3)	39.0 (3)
Ca22^xxv—Al7—Ca22^xxxiii	139.58 (17)	139.06 (17)	140.17 (17)
Ca22^xxv—Al7—Na2^xxv	1.62 (17)	1.05 (18)	1.86 (17)
Ca22^xxv—Al7—Al1^xii	55.15 (13)	53.81 (13)	55.74 (13)
Ca22^xxv—Al7—Al3^xviii	62.85 (14)	62.48 (14)	63.03 (14)
Ca22^xxv—Al7—Al5	104.67 (14)	104.35 (14)	105.35 (14)
Ca22^xxv—Al7—Al6^xiii	126.35 (15)	125.25 (16)	126.91 (15)
Ca22^xxv—Al7—Si7	0	0	0
Ca22^xxv—Al7—O4	68.2 (3)	67.0 (4)	68.8 (3)
Ca22^xxv—Al7—O7	110.6 (3)	110.3 (3)	110.7 (3)
Ca22^xxv—Al7—O14^xii	43.3 (3)	42.1 (3)	45.9 (3)
Ca22^xxv—Al7—O15^xi	135.4 (4)	135.3 (4)	135.7 (4)
Ca22^xxxiii—Al7—Na2^xxv	139.7 (2)	138.7 (2)	141.9 (2)
Ca22^xxxiii—Al7—Al1^xii	126.44 (13)	125.91 (13)	126.89 (13)
Ca22^xxxiii—Al7—Al3^xviii	78.87 (14)	78.03 (14)	80.81 (14)
Ca22^xxxiii—Al7—Al5	114.78 (17)	113.72 (17)	115.25 (17)
Ca22^xxxiii—Al7—Al6^xiii	53.35 (13)	51.50 (13)	54.16 (13)
Ca22^xxxiii—Al7—Si7	0	0	0
Ca22^xxxiii—Al7—O4	84.0 (3)	82.7 (3)	86.8 (3)
Ca22^xxxiii—Al7—O7	104.6 (4)	103.5 (4)	105.2 (4)
Ca22^xxxiii—Al7—O14^xii	134.9 (3)	133.8 (3)	137.4 (3)
Ca22^xxxiii—Al7—O15^xi	30.5 (3)	28.5 (3)	31.5 (3)
Na2^xxv—Al7—Al1^xii	55.48 (16)	53.89 (16)	57.06 (16)
Na2^xxv—Al7—Al3^xviii	62.65 (17)	62.11 (16)	63.20 (16)
Na2^xxv—Al7—Al5	104.26 (17)	103.18 (16)	105.34 (15)
Na2^xxv—Al7—Al6^xiii	127.23 (18)	126.06 (19)	128.42 (19)
Na2^xxv—Al7—Si7	0	0	0
Na2^xxv—Al7—O4	66.7 (4)	65.5 (4)	67.9 (4)
Na2^xxv—Al7—O7	109.3 (3)	109.0 (3)	109.7 (3)
Na2^xxv—Al7—O14^xii	45.4 (3)	43.3 (3)	47.5 (3)
Na2^xxv—Al7—O15^xi	136.8 (4)	136.2 (4)	137.4 (4)
Al1^xii—Al7—Al3^xviii	98.86 (13)	96.47 (13)	101.25 (13)
Al1^xii—Al7—Al5	91.53 (12)	89.01 (12)	94.07 (12)
Al1^xii—Al7—Al6^xiii	78.21 (11)	76.88 (11)	79.52 (11)
Al1^xii—Al7—Si7	0	0	0
Al1^xii—Al7—O4	117.0 (4)	113.9 (4)	120.2 (4)
Al1^xii—Al7—O7	114.2 (3)	113.3 (3)	115.2 (3)
Al1^xii—Al7—O14^xii	11.1 (3)	8.3 (3)	13.8 (3)
Al1^xii—Al7—O15^xi	98.3 (3)	97.7 (3)	98.9 (4)
Al3^xviii—Al7—Al5	152.19 (11)	151.75 (11)	152.61 (11)
Al3^xviii—Al7—Al6^xiii	106.91 (10)	106.28 (10)	107.58 (10)
Al3^xviii—Al7—Si7	0	0	0
Al3^xviii—Al7—O4	26.7 (3)	25.9 (3)	27.5 (3)
Al3^xviii—Al7—O7	132.7 (3)	131.9 (3)	133.5 (3)
Al3^xviii—Al7—O14^xii	94.9 (3)	93.0 (3)	96.7 (3)
Al3^xviii—Al7—O15^xi	93.3 (3)	92.8 (3)	93.8 (3)
Al5—Al7—Al6^xiii	100.41 (11)	99.77 (11)	101.04 (11)
Al5—Al7—Si7	0	0	0
Al5—Al7—O4	126.9 (3)	126.5 (3)	127.3 (3)
Al5—Al7—O7	24.2 (3)	22.9 (3)	25.6 (3)
Al5—Al7—O14^xii	90.5 (3)	87.7 (3)	93.3 (3)
Al5—Al7—O15^xi	110.7 (3)	110.3 (3)	111.1 (3)
Al6^xiii—Al7—Si7	0	0	0
Al6^xiii—Al7—O4	127.5 (2)	125.9 (2)	129.0 (3)
Al6^xiii—Al7—O7	112.1 (3)	111.6 (3)	112.6 (3)
Al6^xiii—Al7—O14^xii	89.2 (3)	85.5 (3)	92.8 (3)
Al6^xiii—Al7—O15^xi	22.8 (3)	20.7 (3)	24.9 (3)
Si7—Al7—O4	0	0	0
Si7—Al7—O7	0	0	0
Si7—Al7—O14^xii	0	0	0
Si7—Al7—O15^xi	0	0	0
O4—Al7—O7	106.0 (4)	104.6 (4)	107.4 (4)
O4—Al7—O14^xii	109.5 (5)	107.7 (5)	111.2 (5)
O4—Al7—O15^xi	108.2 (4)	107.8 (4)	108.6 (4)
O7—Al7—O14^xii	111.1 (4)	109.7 (4)	112.6 (4)
O7—Al7—O15^xi	113.0 (5)	112.9 (5)	113.2 (5)
O14^xii—Al7—O15^xi	108.9 (4)	106.9 (4)	110.8 (4)
Ca1^xxxiv—Si8—Na1^xxxiv	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—Si8—Ca21^xxxv	72.92 (10)	70.76 (9)	74.90 (10)
Ca1^xxxiv—Si8—Al8	0	0	0
Ca1^xxxiv—Si8—O2	133.4 (3)	132.3 (3)	134.5 (3)
Ca1^xxxiv—Si8—O3	64.7 (3)	59.4 (3)	70.1 (3)
Ca1^xxxiv—Si8—O6	114.9 (3)	113.2 (3)	116.7 (3)
Ca1^xxxiv—Si8—O13	42.0 (3)	37.4 (3)	46.6 (3)
Na1^xxxiv—Si8—Ca21^xxxv	72.92 (10)	70.76 (9)	74.90 (10)
Na1^xxxiv—Si8—Al8	0	0	0
Na1^xxxiv—Si8—O2	133.4 (3)	132.3 (3)	134.5 (3)
Na1^xxxiv—Si8—O3	64.7 (3)	59.4 (3)	70.1 (3)
Na1^xxxiv—Si8—O6	114.9 (3)	113.2 (3)	116.7 (3)
Na1^xxxiv—Si8—O13	42.0 (3)	37.4 (3)	46.6 (3)
Ca21^xxxv—Si8—Al8	0	0	0
Ca21^xxxv—Si8—O2	125.6 (4)	121.9 (4)	127.1 (4)
Ca21^xxxv—Si8—O3	122.3 (3)	120.5 (3)	126.1 (3)
Ca21^xxxv—Si8—O6	56.2 (3)	55.3 (3)	57.8 (3)
Ca21^xxxv—Si8—O13	47.6 (3)	47.4 (3)	48.3 (3)
Al8—Si8—O2	0	0	0
Al8—Si8—O3	0	0	0
Al8—Si8—O6	0	0	0
Al8—Si8—O13	0	0	0
O2—Si8—O3	110.7 (5)	108.9 (5)	112.4 (5)
O2—Si8—O6	108.9 (4)	107.9 (4)	109.8 (4)
O2—Si8—O13	112.7 (5)	112.1 (5)	113.3 (5)
O3—Si8—O6	113.7 (5)	113.2 (5)	114.1 (4)
O3—Si8—O13	106.2 (5)	105.4 (5)	107.0 (5)
O6—Si8—O13	104.6 (4)	103.0 (4)	106.2 (5)
Ca1^xxxiv—Al8—Na1^xxxiv	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—Al8—Ca21^xxxv	72.92 (10)	70.76 (9)	74.90 (10)
Ca1^xxxiv—Al8—Ca22^xxxv	63.29 (12)	61.71 (11)	65.67 (12)
Ca1^xxxiv—Al8—Al2^xxiii	74.78 (10)	72.04 (10)	77.61 (10)
Ca1^xxxiv—Al8—Al3^ix	122.04 (11)	120.75 (11)	123.34 (12)
Ca1^xxxiv—Al8—Al4	149.10 (13)	148.20 (13)	150.01 (13)
Ca1^xxxiv—Al8—Al5^xxx	56.21 (10)	53.86 (10)	58.59 (10)
Ca1^xxxiv—Al8—Si8	0	0	0
Ca1^xxxiv—Al8—O2	133.4 (3)	132.3 (3)	134.5 (3)
Ca1^xxxiv—Al8—O3	64.7 (3)	59.4 (3)	70.1 (3)
Ca1^xxxiv—Al8—O6	114.9 (3)	113.2 (3)	116.7 (3)
Ca1^xxxiv—Al8—O13	42.0 (3)	37.4 (3)	46.6 (3)
Na1^xxxiv—Al8—Ca21^xxxv	72.92 (10)	70.76 (9)	74.90 (10)
Na1^xxxiv—Al8—Ca22^xxxv	63.29 (12)	61.71 (11)	65.67 (12)
Na1^xxxiv—Al8—Al2^xxiii	74.78 (10)	72.04 (10)	77.61 (10)
Na1^xxxiv—Al8—Al3^ix	122.04 (11)	120.75 (11)	123.34 (12)
Na1^xxxiv—Al8—Al4	149.10 (13)	148.20 (13)	150.01 (13)
Na1^xxxiv—Al8—Al5^xxx	56.21 (10)	53.86 (10)	58.59 (10)
Na1^xxxiv—Al8—Si8	0	0	0
Na1^xxxiv—Al8—O2	133.4 (3)	132.3 (3)	134.5 (3)
Na1^xxxiv—Al8—O3	64.7 (3)	59.4 (3)	70.1 (3)
Na1^xxxiv—Al8—O6	114.9 (3)	113.2 (3)	116.7 (3)
Na1^xxxiv—Al8—O13	42.0 (3)	37.4 (3)	46.6 (3)
Ca21^xxxv—Al8—Ca22^xxxv	9.12 (11)	9.12 (11)	9.12 (11)
Ca21^xxxv—Al8—Al2^xxiii	125.01 (13)	123.69 (12)	127.44 (13)
Ca21^xxxv—Al8—Al3^ix	71.12 (11)	70.54 (11)	72.17 (11)
Ca21^xxxv—Al8—Al4	106.00 (14)	105.99 (14)	106.01 (14)
Ca21^xxxv—Al8—Al5^xxx	59.29 (11)	58.56 (11)	60.77 (11)
Ca21^xxxv—Al8—Si8	0	0	0
Ca21^xxxv—Al8—O2	125.6 (4)	121.9 (4)	127.1 (4)
Ca21^xxxv—Al8—O3	122.3 (3)	120.5 (3)	126.1 (3)
Ca21^xxxv—Al8—O6	56.2 (3)	55.3 (3)	57.8 (3)
Ca21^xxxv—Al8—O13	47.6 (3)	47.4 (3)	48.3 (3)
Ca22^xxxv—Al8—Al2^xxiii	122.84 (16)	120.29 (15)	124.12 (16)
Ca22^xxxv—Al8—Al3^ix	77.22 (13)	76.01 (13)	77.86 (13)
Ca22^xxxv—Al8—Al4	114.62 (17)	114.34 (16)	114.75 (17)
Ca22^xxxv—Al8—Al5^xxx	57.46 (14)	56.01 (13)	58.29 (14)
Ca22^xxxv—Al8—Si8	0	0	0
Ca22^xxxv—Al8—O2	128.1 (4)	126.6 (4)	131.6 (4)
Ca22^xxxv—Al8—O3	120.4 (4)	116.7 (4)	122.1 (4)
Ca22^xxxv—Al8—O6	63.3 (3)	61.6 (3)	64.2 (3)
Ca22^xxxv—Al8—O13	42.3 (3)	42.1 (3)	42.5 (3)
Al2^xxiii—Al8—Al3^ix	92.99 (12)	92.15 (12)	93.88 (12)
Al2^xxiii—Al8—Al4	122.72 (14)	119.09 (14)	126.28 (15)
Al2^xxiii—Al8—Al5^xxx	126.31 (11)	125.41 (11)	127.26 (11)
Al2^xxiii—Al8—Si8	0	0	0
Al2^xxiii—Al8—O2	109.0 (4)	107.1 (4)	110.9 (4)
Al2^xxiii—Al8—O3	11.9 (3)	9.7 (3)	14.1 (3)
Al2^xxiii—Al8—O6	104.3 (4)	102.9 (4)	105.6 (4)
Al2^xxiii—Al8—O13	116.7 (3)	114.4 (3)	118.9 (3)
Al3^ix—Al8—Al4	84.68 (9)	84.14 (9)	85.25 (9)
Al3^ix—Al8—Al5^xxx	129.48 (14)	127.24 (14)	131.74 (14)
Al3^ix—Al8—Si8	0	0	0
Al3^ix—Al8—O2	104.3 (3)	103.8 (3)	104.8 (3)
Al3^ix—Al8—O3	103.6 (3)	102.9 (3)	104.3 (3)
Al3^ix—Al8—O6	15.0 (3)	14.2 (4)	15.7 (3)
Al3^ix—Al8—O13	119.0 (3)	118.2 (3)	120.0 (3)
Al4—Al8—Al5^xxx	95.73 (13)	94.67 (13)	96.84 (13)
Al4—Al8—Si8	0	0	0
Al4—Al8—O2	23.1 (3)	20.9 (3)	25.3 (3)
Al4—Al8—O3	128.1 (4)	123.0 (4)	133.1 (4)
Al4—Al8—O6	86.9 (3)	86.2 (3)	87.6 (3)
Al4—Al8—O13	113.9 (4)	110.4 (3)	117.5 (4)
Al5^xxx—Al8—Si8	0	0	0
Al5^xxx—Al8—O2	92.3 (4)	89.5 (4)	94.9 (4)
Al5^xxx—Al8—O3	114.5 (3)	112.9 (3)	116.2 (3)
Al5^xxx—Al8—O6	114.5 (4)	111.5 (4)	117.6 (4)
Al5^xxx—Al8—O13	20.5 (3)	18.0 (3)	23.0 (3)
Si8—Al8—O2	0	0	0
Si8—Al8—O3	0	0	0
Si8—Al8—O6	0	0	0
Si8—Al8—O13	0	0	0
O2—Al8—O3	110.7 (5)	108.9 (5)	112.4 (5)
O2—Al8—O6	108.9 (4)	107.9 (4)	109.8 (4)
O2—Al8—O13	112.7 (5)	112.1 (5)	113.3 (5)
O3—Al8—O6	113.7 (5)	113.2 (5)	114.1 (4)
O3—Al8—O13	106.2 (5)	105.4 (5)	107.0 (5)
O6—Al8—O13	104.6 (4)	103.0 (4)	106.2 (5)
Ca1^xxiii—O1—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—O1—Si2^xi	127.8 (4)	124.6 (4)	131.0 (4)
Ca1^xxiii—O1—Al2^xi	127.8 (4)	124.6 (4)	131.0 (4)
Ca1^xxiii—O1—Si5	99.9 (3)	97.3 (3)	102.6 (3)
Ca1^xxiii—O1—Al5	99.9 (3)	97.3 (3)	102.6 (3)
Na1^xxiii—O1—Si2^xi	127.8 (4)	124.6 (4)	131.0 (4)
Na1^xxiii—O1—Al2^xi	127.8 (4)	124.6 (4)	131.0 (4)
Na1^xxiii—O1—Si5	99.9 (3)	97.3 (3)	102.6 (3)
Na1^xxiii—O1—Al5	99.9 (3)	97.3 (3)	102.6 (3)
Si2^xi—O1—Al2^xi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xi—O1—Si5	132.3 (6)	130.7 (6)	133.9 (6)
Si2^xi—O1—Al5	132.3 (6)	130.7 (6)	133.9 (6)
Al2^xi—O1—Si5	132.3 (6)	130.7 (6)	133.9 (6)
Al2^xi—O1—Al5	132.3 (6)	130.7 (6)	133.9 (6)
Si5—O1—Al5	0.0 (5)	0.0 (5)	0.0 (5)
Na2^xxvii—O2—Si4	89.9 (4)	85.7 (3)	94.0 (4)
Na2^xxvii—O2—Al4	89.9 (4)	85.7 (3)	94.0 (4)
Na2^xxvii—O2—Si8	135.0 (5)	132.7 (5)	137.4 (5)
Na2^xxvii—O2—Al8	135.0 (5)	132.7 (5)	137.4 (5)
Si4—O2—Al4	0.0 (5)	0.0 (5)	0.0 (5)
Si4—O2—Si8	133.9 (5)	129.2 (5)	138.4 (5)
Si4—O2—Al8	133.9 (5)	129.2 (5)	138.4 (5)
Al4—O2—Si8	133.9 (5)	129.2 (5)	138.4 (5)
Al4—O2—Al8	133.9 (5)	129.2 (5)	138.4 (5)
Si8—O2—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xxiii—O3—Al2^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xxiii—O3—Si8	156.5 (5)	152.4 (5)	160.6 (5)
Si2^xxiii—O3—Al8	156.5 (5)	152.4 (5)	160.6 (5)
Al2^xxiii—O3—Si8	156.5 (5)	152.4 (5)	160.6 (5)
Al2^xxiii—O3—Al8	156.5 (5)	152.4 (5)	160.6 (5)
Si8—O3—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—O4—Na1	0.0 (5)	0.0 (5)	0.0 (5)
Ca1—O4—Si3^xviii	115.0 (4)	103.9 (3)	126.2 (4)
Ca1—O4—Al3^xviii	115.0 (4)	103.9 (3)	126.2 (4)
Ca1—O4—Si7	117.6 (4)	107.6 (4)	127.5 (4)
Ca1—O4—Al7	117.6 (4)	107.6 (4)	127.5 (4)
Na1—O4—Si3^xviii	115.0 (4)	103.9 (3)	126.2 (4)
Na1—O4—Al3^xviii	115.0 (4)	103.9 (3)	126.2 (4)
Na1—O4—Si7	117.6 (4)	107.6 (4)	127.5 (4)
Na1—O4—Al7	117.6 (4)	107.6 (4)	127.5 (4)
Si3^xviii—O4—Al3^xviii	0.0 (5)	0.0 (5)	0.0 (5)
Si3^xviii—O4—Si7	126.9 (5)	125.2 (5)	128.7 (5)
Si3^xviii—O4—Al7	126.9 (5)	125.2 (5)	128.7 (5)
Al3^xviii—O4—Si7	126.9 (5)	125.2 (5)	128.7 (5)
Al3^xviii—O4—Al7	126.9 (5)	125.2 (5)	128.7 (5)
Si7—O4—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—O5—Na1^xxiii	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxiii—O5—Ca22^xxiv	105.4 (3)	105.0 (3)	106.2 (3)
Ca1^xxiii—O5—Na2^xxiv	109.1 (4)	107.6 (4)	110.5 (4)
Ca1^xxiii—O5—Si1	107.7 (3)	102.5 (3)	112.8 (3)
Ca1^xxiii—O5—Al1	107.7 (3)	102.5 (3)	112.8 (3)
Ca1^xxiii—O5—Si6^xxv	95.8 (5)	94.5 (4)	97.4 (5)
Ca1^xxiii—O5—Al6^xxv	95.8 (5)	94.5 (4)	97.4 (5)
Na1^xxiii—O5—Ca22^xxiv	105.4 (3)	105.0 (3)	106.2 (3)
Na1^xxiii—O5—Na2^xxiv	109.1 (4)	107.6 (4)	110.5 (4)
Na1^xxiii—O5—Si1	107.7 (3)	102.5 (3)	112.8 (3)
Na1^xxiii—O5—Al1	107.7 (3)	102.5 (3)	112.8 (3)
Na1^xxiii—O5—Si6^xxv	95.8 (5)	94.5 (4)	97.4 (5)
Na1^xxiii—O5—Al6^xxv	95.8 (5)	94.5 (4)	97.4 (5)
Ca22^xxiv—O5—Na2^xxiv	5.4 (4)	4.6 (4)	6.5 (4)
Ca22^xxiv—O5—Si1	106.1 (5)	105.2 (5)	107.8 (6)
Ca22^xxiv—O5—Al1	106.1 (5)	105.2 (5)	107.8 (6)
Ca22^xxiv—O5—Si6^xxv	96.8 (4)	96.1 (4)	97.1 (4)
Ca22^xxiv—O5—Al6^xxv	96.8 (4)	96.1 (4)	97.1 (4)
Na2^xxiv—O5—Si1	102.2 (6)	99.9 (5)	104.5 (6)
Na2^xxiv—O5—Al1	102.2 (6)	99.9 (5)	104.5 (6)
Na2^xxiv—O5—Si6^xxv	100.2 (4)	99.3 (4)	101.0 (4)
Na2^xxiv—O5—Al6^xxv	100.2 (4)	99.3 (4)	101.0 (4)
Si1—O5—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O5—Si6^xxv	139.6 (5)	135.1 (5)	144.2 (5)
Si1—O5—Al6^xxv	139.6 (5)	135.1 (5)	144.2 (5)
Al1—O5—Si6^xxv	139.6 (5)	135.1 (5)	144.2 (5)
Al1—O5—Al6^xxv	139.6 (5)	135.1 (5)	144.2 (5)
Si6^xxv—O5—Al6^xxv	0.0 (5)	0.0 (5)	0.0 (5)
Ca21^xxxv—O6—Si3^ix	118.1 (4)	117.7 (4)	119.2 (4)
Ca21^xxxv—O6—Al3^ix	118.1 (4)	117.7 (4)	119.2 (4)
Ca21^xxxv—O6—Si8	91.9 (4)	90.3 (4)	92.6 (3)
Ca21^xxxv—O6—Al8	91.9 (4)	90.3 (4)	92.6 (3)
Si3^ix—O6—Al3^ix	0.0 (5)	0.0 (5)	0.0 (5)
Si3^ix—O6—Si8	149.7 (7)	147.8 (7)	151.7 (7)
Si3^ix—O6—Al8	149.7 (7)	147.8 (7)	151.7 (7)
Al3^ix—O6—Si8	149.7 (7)	147.8 (7)	151.7 (7)
Al3^ix—O6—Al8	149.7 (7)	147.8 (7)	151.7 (7)
Si8—O6—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Si5—O7—Al5	0.0 (5)	0.0 (5)	0.0 (5)
Si5—O7—Si7	131.2 (6)	128.0 (5)	134.5 (6)
Si5—O7—Al7	131.2 (6)	128.0 (5)	134.5 (6)
Al5—O7—Si7	131.2 (6)	128.0 (5)	134.5 (6)
Al5—O7—Al7	131.2 (6)	128.0 (5)	134.5 (6)
Si7—O7—Al7	0.0 (5)	0.0 (5)	0.0 (5)
Ca21^xxxvi—O8—Ca22^xxxvi	20.7 (2)	20.7 (2)	20.7 (2)
Ca21^xxxvi—O8—Na2^xxxvi	24.8 (3)	23.5 (3)	26.0 (3)
Ca21^xxxvi—O8—Si3^ix	128.4 (4)	127.3 (4)	131.3 (4)
Ca21^xxxvi—O8—Al3^ix	128.4 (4)	127.3 (4)	131.3 (4)
Ca21^xxxvi—O8—Si5^xxvi	95.1 (4)	92.9 (4)	96.1 (4)
Ca21^xxxvi—O8—Al5^xxvi	95.1 (4)	92.9 (4)	96.1 (4)
Ca22^xxxvi—O8—Na2^xxxvi	5.5 (4)	4.2 (4)	6.4 (4)
Ca22^xxxvi—O8—Si3^ix	122.8 (4)	120.1 (4)	124.3 (4)
Ca22^xxxvi—O8—Al3^ix	122.8 (4)	120.1 (4)	124.3 (4)
Ca22^xxxvi—O8—Si5^xxvi	103.3 (5)	102.1 (5)	105.5 (5)
Ca22^xxxvi—O8—Al5^xxvi	103.3 (5)	102.1 (5)	105.5 (5)
Na2^xxxvi—O8—Si3^ix	115.6 (5)	112.1 (5)	119.3 (5)
Na2^xxxvi—O8—Al3^ix	115.6 (5)	112.1 (5)	119.3 (5)
Na2^xxxvi—O8—Si5^xxvi	109.0 (5)	106.4 (5)	111.6 (5)
Na2^xxxvi—O8—Al5^xxvi	109.0 (5)	106.4 (5)	111.6 (5)
Si3^ix—O8—Al3^ix	0.0 (5)	0.0 (5)	0.0 (5)
Si3^ix—O8—Si5^xxvi	134.8 (4)	133.0 (4)	136.5 (4)
Si3^ix—O8—Al5^xxvi	134.8 (4)	133.0 (4)	136.5 (4)
Al3^ix—O8—Si5^xxvi	134.8 (4)	133.0 (4)	136.5 (4)
Al3^ix—O8—Al5^xxvi	134.8 (4)	133.0 (4)	136.5 (4)
Si5^xxvi—O8—Al5^xxvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xvi—O9—Na1^xvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xvi—O9—Si4^xi	121.8 (4)	119.8 (4)	123.8 (3)
Ca1^xvi—O9—Al4^xi	121.8 (4)	119.8 (4)	123.8 (3)
Ca1^xvi—O9—Si6^xxxiii	97.7 (4)	95.8 (4)	99.5 (4)
Ca1^xvi—O9—Al6^xxxiii	97.7 (4)	95.8 (4)	99.5 (4)
Na1^xvi—O9—Si4^xi	121.8 (4)	119.8 (4)	123.8 (3)
Na1^xvi—O9—Al4^xi	121.8 (4)	119.8 (4)	123.8 (3)
Na1^xvi—O9—Si6^xxxiii	97.7 (4)	95.8 (4)	99.5 (4)
Na1^xvi—O9—Al6^xxxiii	97.7 (4)	95.8 (4)	99.5 (4)
Si4^xi—O9—Al4^xi	0.0 (5)	0.0 (5)	0.0 (5)
Si4^xi—O9—Si6^xxxiii	140.3 (5)	139.0 (5)	141.7 (5)
Si4^xi—O9—Al6^xxxiii	140.3 (5)	139.0 (5)	141.7 (5)
Al4^xi—O9—Si6^xxxiii	140.3 (5)	139.0 (5)	141.7 (5)
Al4^xi—O9—Al6^xxxiii	140.3 (5)	139.0 (5)	141.7 (5)
Si6^xxxiii—O9—Al6^xxxiii	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xvi—O10—Al2^xvi	0.0 (5)	0.0 (5)	0.0 (5)
Si2^xvi—O10—Si6	130.6 (6)	127.6 (6)	133.5 (6)
Si2^xvi—O10—Al6	130.6 (6)	127.6 (6)	133.5 (6)
Al2^xvi—O10—Si6	130.6 (6)	127.6 (6)	133.5 (6)
Al2^xvi—O10—Al6	130.6 (6)	127.6 (6)	133.5 (6)
Si6—O10—Al6	0.0 (5)	0.0 (5)	0.0 (5)
Ca21^xxvii—O11—Ca22^xxvii	21.1 (2)	21.1 (2)	21.1 (2)
Ca21^xxvii—O11—Na2^xxvii	26.3 (3)	25.4 (3)	26.9 (3)
Ca21^xxvii—O11—Si2	104.3 (4)	103.4 (4)	106.1 (4)
Ca21^xxvii—O11—Al2	104.3 (4)	103.4 (4)	106.1 (4)
Ca21^xxvii—O11—Si4	127.1 (4)	122.6 (4)	129.1 (4)
Ca21^xxvii—O11—Al4	127.1 (4)	122.6 (4)	129.1 (4)
Ca22^xxvii—O11—Na2^xxvii	5.3 (4)	4.6 (4)	6.3 (4)
Ca22^xxvii—O11—Si2	127.7 (4)	126.2 (4)	128.5 (4)
Ca22^xxvii—O11—Al2	127.7 (4)	126.2 (4)	128.5 (4)
Ca22^xxvii—O11—Si4	103.7 (4)	102.1 (4)	107.5 (4)
Ca22^xxvii—O11—Al4	103.7 (4)	102.1 (4)	107.5 (4)
Na2^xxvii—O11—Si2	129.5 (5)	127.0 (4)	132.0 (5)
Na2^xxvii—O11—Al2	129.5 (5)	127.0 (4)	132.0 (5)
Na2^xxvii—O11—Si4	102.9 (4)	98.9 (4)	107.1 (4)
Na2^xxvii—O11—Al4	102.9 (4)	98.9 (4)	107.1 (4)
Si2—O11—Al2	0.0 (5)	0.0 (5)	0.0 (5)
Si2—O11—Si4	127.5 (4)	125.8 (4)	129.1 (4)
Si2—O11—Al4	127.5 (4)	125.8 (4)	129.1 (4)
Al2—O11—Si4	127.5 (4)	125.8 (4)	129.1 (4)
Al2—O11—Al4	127.5 (4)	125.8 (4)	129.1 (4)
Si4—O11—Al4	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O12—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O12—Si4^xi	151.2 (7)	149.6 (7)	152.8 (7)
Si1—O12—Al4^xi	151.2 (7)	149.6 (7)	152.8 (7)
Al1—O12—Si4^xi	151.2 (7)	149.6 (7)	152.8 (7)
Al1—O12—Al4^xi	151.2 (7)	149.6 (7)	152.8 (7)
Si4^xi—O12—Al4^xi	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—O13—Na1^xxxiv	0.0 (5)	0.0 (5)	0.0 (5)
Ca1^xxxiv—O13—Ca21^xxxv	106.0 (3)	105.0 (3)	108.1 (3)
Ca1^xxxiv—O13—Si5^xxx	92.5 (3)	89.9 (3)	95.2 (3)
Ca1^xxxiv—O13—Al5^xxx	92.5 (3)	89.9 (3)	95.2 (3)
Ca1^xxxiv—O13—Si8	113.6 (5)	105.6 (5)	121.6 (5)
Ca1^xxxiv—O13—Al8	113.6 (5)	105.6 (5)	121.6 (5)
Na1^xxxiv—O13—Ca21^xxxv	106.0 (3)	105.0 (3)	108.1 (3)
Na1^xxxiv—O13—Si5^xxx	92.5 (3)	89.9 (3)	95.2 (3)
Na1^xxxiv—O13—Al5^xxx	92.5 (3)	89.9 (3)	95.2 (3)
Na1^xxxiv—O13—Si8	113.6 (5)	105.6 (5)	121.6 (5)
Na1^xxxiv—O13—Al8	113.6 (5)	105.6 (5)	121.6 (5)
Ca21^xxxv—O13—Si5^xxx	98.8 (5)	97.4 (5)	100.8 (5)
Ca21^xxxv—O13—Al5^xxx	98.8 (5)	97.4 (5)	100.8 (5)
Ca21^xxxv—O13—Si8	101.6 (3)	100.2 (3)	102.1 (3)
Ca21^xxxv—O13—Al8	101.6 (3)	100.2 (3)	102.1 (3)
Si5^xxx—O13—Al5^xxx	0.0 (5)	0.0 (5)	0.0 (5)
Si5^xxx—O13—Si8	140.2 (5)	136.0 (5)	144.4 (5)
Si5^xxx—O13—Al8	140.2 (5)	136.0 (5)	144.4 (5)
Al5^xxx—O13—Si8	140.2 (5)	136.0 (5)	144.4 (5)
Al5^xxx—O13—Al8	140.2 (5)	136.0 (5)	144.4 (5)
Si8—O13—Al8	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O14—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O14—Si7^xxvi	157.8 (6)	151.9 (6)	163.6 (6)
Si1—O14—Al7^xxvi	157.8 (6)	151.9 (6)	163.6 (6)
Al1—O14—Si7^xxvi	157.8 (6)	151.9 (6)	163.6 (6)
Al1—O14—Al7^xxvi	157.8 (6)	151.9 (6)	163.6 (6)
Si7^xxvi—O14—Al7^xxvi	0.0 (5)	0.0 (5)	0.0 (5)
Ca21^xxxi—O15—Ca22^xxxi	20.1 (2)	20.1 (2)	20.1 (2)
Ca21^xxxi—O15—Na2^xxxi	24.4 (3)	23.4 (3)	24.8 (3)
Ca21^xxxi—O15—Si6ⁱⁱ	105.5 (4)	104.7 (4)	107.3 (4)
Ca21^xxxi—O15—Al6ⁱⁱ	105.5 (4)	104.7 (4)	107.3 (4)
Ca21^xxxi—O15—Si7^ix	119.3 (4)	116.2 (4)	120.9 (4)
Ca21^xxxi—O15—Al7^ix	119.3 (4)	116.2 (4)	120.9 (4)
Ca22^xxxi—O15—Na2^xxxi	3.9 (3)	2.9 (3)	4.8 (3)
Ca22^xxxi—O15—Si6ⁱⁱ	96.5 (4)	94.4 (4)	97.5 (4)
Ca22^xxxi—O15—Al6ⁱⁱ	96.5 (4)	94.4 (4)	97.5 (4)
Ca22^xxxi—O15—Si7^ix	129.1 (5)	127.4 (4)	132.4 (5)
Ca22^xxxi—O15—Al7^ix	129.1 (5)	127.4 (4)	132.4 (5)
Na2^xxxi—O15—Si6ⁱⁱ	94.3 (4)	91.0 (4)	97.6 (4)
Na2^xxxi—O15—Al6ⁱⁱ	94.3 (4)	91.0 (4)	97.6 (4)
Na2^xxxi—O15—Si7^ix	130.2 (5)	127.1 (4)	133.2 (5)
Na2^xxxi—O15—Al7^ix	130.2 (5)	127.1 (4)	133.2 (5)
Si6ⁱⁱ—O15—Al6ⁱⁱ	0.0 (5)	0.0 (5)	0.0 (5)
Si6ⁱⁱ—O15—Si7^ix	134.3 (6)	131.5 (6)	137.2 (6)
Si6ⁱⁱ—O15—Al7^ix	134.3 (6)	131.5 (6)	137.2 (6)
Al6ⁱⁱ—O15—Si7^ix	134.3 (6)	131.5 (6)	137.2 (6)
Al6ⁱⁱ—O15—Al7^ix	134.3 (6)	131.5 (6)	137.2 (6)
Si7^ix—O15—Al7^ix	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O16—Al1	0.0 (5)	0.0 (5)	0.0 (5)
Si1—O16—Si3	131.9 (4)	128.1 (5)	135.4 (4)
Si1—O16—Al3	131.9 (4)	128.1 (5)	135.4 (4)
Al1—O16—Si3	131.9 (4)	128.1 (5)	135.4 (4)
Al1—O16—Al3	131.9 (4)	128.1 (5)	135.4 (4)
Si3—O16—Al3	0.0 (5)	0.0 (5)	0.0 (5)

Symmetry codes: (i) x₁−1/2, x₂+1/2, x₃, x₄+1/2; (ii) x₁−1/2, x₂+1/2, x₃−1/2, x₄; (iii) x₁, x₂+1, x₃−1/2, x₄+1/2; (iv) x₁+1, x₂+1, x₃+1/2, x₄+1/2; (v) x₁+1, x₂+1, x₃+1, x₄; (vi) x₁+1/2, x₂+1/2, x₃+1/2, x₄; (vii) x₁+1, x₂, x₃+1/2, x₄+1/2; (viii) x₁+1/2, x₂+1/2, x₃+1, x₄+1/2; (ix) x₁−1, x₂, x₃, x₄; (x) x₁, x₂−1, x₃, x₄; (xi) x₁+1, x₂, x₃, x₄; (xii) x₁+1/2, x₂+1/2, x₃, x₄+1/2; (xiii) x₁+1/2, x₂+1/2, x₃−1/2, x₄; (xiv) x₁, x₂, x₃+1, x₄; (xv) x₁, x₂, x₃+1/2, x₄+1/2; (xvi) x₁+1/2, x₂−1/2, x₃+1/2, x₄; (xvii) x₁−1, x₂, x₃−1, x₄; (xviii) x₁, x₂+1, x₃, x₄; (xix) x₁−1/2, x₂+1/2, x₃−1, x₄+1/2; (xx) x₁+1, x₂, x₃+1, x₄; (xxi) x₁, x₂+1, x₃+1, x₄; (xxii) x₁, x₂+1, x₃+1/2, x₄+1/2; (xxiii) x₁+1/2, x₂−1/2, x₃, x₄+1/2; (xxiv) x₁−1/2, x₂−1/2, x₃−1, x₄+1/2; (xxv) x₁, x₂, x₃−1, x₄; (xxvi) x₁−1/2, x₂−1/2, x₃, x₄+1/2; (xxvii) x₁−1/2, x₂−1/2, x₃−1/2, x₄; (xxviii) x₁, x₂−1, x₃−1, x₄; (xxix) x₁, x₂−1, x₃−1/2, x₄+1/2; (xxx) x₁−1/2, x₂−1/2, x₃+1/2, x₄; (xxxi) x₁−1, x₂, x₃−1/2, x₄+1/2; (xxxii) x₁+1/2, x₂−1/2, x₃+1, x₄+1/2; (xxxiii) x₁, x₂, x₃−1/2, x₄+1/2; (xxxiv) x₁, x₂−1, x₃+1/2, x₄+1/2; (xxxv) x₁−1, x₂−1, x₃−1/2, x₄+1/2; (xxxvi) x₁−1, x₂−1, x₃−1, x₄.

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