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The title compound, [Ru(C18H12N5)Cl(C8H4N2)(C2H6OS)], consists of an RuII atom hexagonally coordinated by a tridendate isoindoline ligand, a Cl atom, the S atom of a dimethyl sulfoxide molecule and an N atom of a CN group of dicyano­benzene. In the crystal structure, a three-dimensional network is built up owing to the presence of weak C—H...O and C—H...Cl intermolecular hydrogen bonds.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804031812/cv6427sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804031812/cv6427Isup2.hkl
Contains datablock I

CCDC reference: 262242

Key indicators

  • Single-crystal X-ray study
  • T = 153 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.041
  • wR factor = 0.094
  • Data-to-parameter ratio = 20.3

checkCIF/PLATON results

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Alert level C PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.95 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.15 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.22 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for N6 - C19 .. 6.53 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Ru1 - Cl1 .. 9.13 su PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for S1 PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C19 - C20 ... 1.43 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C25 - C26 ... 1.44 Ang.
Alert level G ABSTM02_ALERT_3_G When printed, the submitted absorption T values will be replaced by the scaled T values. Since the ratio of scaled T's is identical to the ratio of reported T values, the scaling does not imply a change to the absorption corrections used in the study. Ratio of Tmax expected/reported 0.949 Tmax scaled 0.921 Tmin scaled 0.691
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: X-AREA (Stoe & Cie, 2004); cell refinement: X-AREA; data reduction: X-RED32 (Stoe & Cie, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: SHELXL97.

[1,3-Bis(2-pyridylimino)isoindolinato-κ3N,N',N'']chloro(1,2-dicyanobenzene- κN)(dimethyl sulfoxide-κS)ruthenium(II) top
Crystal data top
[Ru(C18H12N5)Cl(C8H4N2)(C2H6OS)]F(000) = 1296
Mr = 641.11Dx = 1.642 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 40303 reflections
a = 11.5299 (5) Åθ = 1.8–29.6°
b = 12.9081 (5) ŵ = 0.83 mm1
c = 17.4774 (9) ÅT = 153 K
β = 94.538 (4)°Block, dark_red
V = 2593.0 (2) Å30.35 × 0.24 × 0.10 mm
Z = 4
Data collection top
Stoe IPDS-II
diffractometer
7199 independent reflections
Radiation source: fine-focus sealed tube6291 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.043
ω scansθmax = 29.6°, θmin = 2.0°
Absorption correction: multi-scan
(MULrefABS in PLATON; Spek, 2003)
h = 1515
Tmin = 0.728, Tmax = 0.970k = 1717
37823 measured reflectionsl = 2424
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.041Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.094H-atom parameters constrained
S = 1.07 w = 1/[σ2(Fo2) + (0.0441P)2 + 3.0086P]
where P = (Fo2 + 2Fc2)/3
7199 reflections(Δ/σ)max = 0.001
354 parametersΔρmax = 0.57 e Å3
0 restraintsΔρmin = 0.98 e Å3
Special details top

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru10.46569 (1)0.33773 (1)0.27080 (1)0.0225 (1)
Cl10.33623 (5)0.35500 (5)0.15468 (4)0.0295 (2)
S10.58304 (6)0.32097 (5)0.37623 (4)0.0302 (2)
O10.56308 (19)0.23245 (18)0.42604 (13)0.0431 (7)
N10.48688 (18)0.17767 (15)0.25140 (13)0.0263 (5)
N20.63069 (18)0.19282 (16)0.15703 (12)0.0277 (6)
N30.59775 (17)0.36426 (15)0.20611 (12)0.0242 (5)
N40.62250 (19)0.54847 (16)0.22296 (14)0.0307 (6)
N50.45035 (17)0.49807 (15)0.28520 (12)0.0253 (5)
N60.32508 (18)0.30844 (16)0.33006 (12)0.0263 (5)
N70.1547 (3)0.4996 (2)0.47166 (18)0.0497 (9)
C10.4272 (2)0.1088 (2)0.29132 (17)0.0340 (8)
C20.4264 (2)0.0037 (2)0.28020 (18)0.0360 (8)
C30.4929 (3)0.03681 (19)0.22503 (18)0.0356 (8)
C40.5575 (3)0.0305 (2)0.18498 (16)0.0342 (8)
C50.5555 (2)0.13740 (18)0.19918 (15)0.0266 (6)
C60.6481 (2)0.29164 (19)0.16261 (14)0.0251 (6)
C70.7338 (2)0.34367 (19)0.11736 (15)0.0275 (6)
C80.8067 (2)0.3068 (2)0.06452 (16)0.0311 (7)
C90.8730 (2)0.3787 (2)0.02800 (18)0.0391 (8)
C100.8655 (3)0.4838 (2)0.0446 (2)0.0447 (9)
C110.7951 (2)0.5201 (2)0.09955 (19)0.0400 (9)
C120.7300 (2)0.4482 (2)0.13548 (15)0.0293 (7)
C130.6444 (2)0.45926 (18)0.19302 (15)0.0271 (6)
C140.5321 (2)0.56760 (19)0.26785 (15)0.0279 (6)
C150.5256 (3)0.6714 (2)0.29218 (18)0.0356 (8)
C160.4329 (3)0.7058 (2)0.32970 (18)0.0385 (8)
C170.3446 (3)0.6358 (2)0.34167 (18)0.0369 (8)
C180.3574 (2)0.5352 (2)0.31927 (17)0.0325 (7)
C190.2461 (2)0.28527 (19)0.36179 (15)0.0281 (6)
C200.1512 (2)0.2462 (2)0.40096 (14)0.0276 (6)
C210.1216 (2)0.1420 (2)0.39264 (15)0.0309 (7)
C220.0327 (2)0.1022 (2)0.43229 (17)0.0362 (8)
C230.0274 (2)0.1650 (2)0.47970 (17)0.0374 (8)
C240.0020 (2)0.2682 (2)0.48905 (15)0.0331 (7)
C250.0911 (2)0.3093 (2)0.45012 (15)0.0294 (7)
C260.1262 (2)0.4152 (2)0.46225 (17)0.0352 (8)
C270.7337 (3)0.3138 (3)0.3576 (2)0.0510 (10)
C280.5871 (5)0.4324 (3)0.4360 (2)0.0792 (16)
H10.382200.135300.330100.0410*
H20.381200.040300.309700.0430*
H30.493800.109100.215100.0430*
H40.604300.004300.147000.0410*
H80.811400.234900.053600.0370*
H90.923900.355800.008700.0470*
H100.909700.531800.017600.0540*
H110.791900.591700.111900.0480*
H150.586300.718200.282500.0430*
H160.429100.775400.347000.0460*
H170.276900.657300.364900.0440*
H180.296700.488000.328200.0390*
H210.162200.098600.359900.0370*
H220.012700.031100.427000.0430*
H230.089200.136900.506000.0450*
H240.038900.310800.522100.0400*
H27A0.746500.252500.326300.0770*
H27B0.781600.308900.406400.0770*
H27C0.755200.376200.330100.0770*
H28A0.617000.491500.408300.1190*
H28B0.638200.419200.482500.1190*
H28C0.508500.448000.450200.1190*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0219 (1)0.0182 (1)0.0281 (1)0.0007 (1)0.0056 (1)0.0001 (1)
Cl10.0281 (3)0.0284 (3)0.0321 (3)0.0026 (2)0.0034 (2)0.0008 (2)
S10.0312 (3)0.0272 (3)0.0319 (3)0.0035 (2)0.0014 (2)0.0007 (2)
O10.0417 (11)0.0474 (12)0.0409 (11)0.0020 (9)0.0071 (9)0.0153 (9)
N10.0269 (9)0.0178 (9)0.0347 (10)0.0017 (7)0.0051 (8)0.0010 (7)
N20.0293 (10)0.0234 (9)0.0310 (10)0.0021 (8)0.0066 (8)0.0006 (8)
N30.0237 (9)0.0210 (8)0.0288 (10)0.0011 (7)0.0082 (7)0.0020 (7)
N40.0293 (10)0.0237 (9)0.0400 (12)0.0037 (8)0.0085 (9)0.0047 (8)
N50.0265 (9)0.0187 (8)0.0311 (10)0.0037 (7)0.0042 (7)0.0017 (7)
N60.0264 (9)0.0223 (9)0.0311 (10)0.0002 (7)0.0086 (8)0.0008 (7)
N70.0534 (16)0.0373 (14)0.0590 (17)0.0007 (12)0.0092 (13)0.0076 (12)
C10.0341 (13)0.0237 (11)0.0456 (15)0.0016 (10)0.0125 (11)0.0037 (10)
C20.0348 (13)0.0226 (11)0.0514 (16)0.0005 (10)0.0089 (11)0.0045 (11)
C30.0418 (14)0.0185 (10)0.0464 (15)0.0001 (10)0.0038 (12)0.0017 (10)
C40.0433 (14)0.0222 (11)0.0378 (14)0.0015 (10)0.0085 (11)0.0029 (10)
C50.0261 (11)0.0219 (10)0.0318 (12)0.0001 (8)0.0028 (9)0.0006 (9)
C60.0216 (10)0.0270 (11)0.0266 (11)0.0022 (8)0.0017 (8)0.0009 (9)
C70.0209 (10)0.0297 (11)0.0322 (12)0.0008 (8)0.0041 (8)0.0012 (9)
C80.0269 (11)0.0318 (12)0.0351 (13)0.0007 (9)0.0058 (9)0.0038 (10)
C90.0324 (13)0.0420 (15)0.0449 (15)0.0055 (11)0.0154 (11)0.0053 (12)
C100.0384 (15)0.0395 (15)0.0595 (19)0.0136 (12)0.0246 (14)0.0040 (14)
C110.0347 (13)0.0308 (13)0.0566 (18)0.0098 (11)0.0177 (12)0.0055 (12)
C120.0229 (10)0.0297 (12)0.0360 (13)0.0033 (9)0.0063 (9)0.0031 (10)
C130.0234 (10)0.0237 (11)0.0346 (12)0.0034 (8)0.0048 (9)0.0011 (9)
C140.0279 (11)0.0233 (10)0.0329 (12)0.0007 (9)0.0043 (9)0.0014 (9)
C150.0418 (14)0.0213 (11)0.0445 (15)0.0040 (10)0.0083 (11)0.0042 (10)
C160.0467 (15)0.0224 (11)0.0474 (16)0.0041 (10)0.0103 (13)0.0047 (11)
C170.0379 (14)0.0265 (12)0.0475 (16)0.0091 (10)0.0119 (12)0.0005 (11)
C180.0311 (12)0.0245 (11)0.0429 (14)0.0040 (9)0.0084 (10)0.0012 (10)
C190.0295 (11)0.0241 (10)0.0308 (12)0.0025 (9)0.0027 (9)0.0009 (9)
C200.0252 (11)0.0290 (11)0.0289 (11)0.0012 (9)0.0042 (9)0.0020 (9)
C210.0327 (12)0.0295 (12)0.0309 (12)0.0005 (9)0.0054 (9)0.0013 (9)
C220.0383 (14)0.0338 (13)0.0370 (14)0.0072 (11)0.0055 (11)0.0036 (11)
C230.0308 (12)0.0453 (16)0.0369 (14)0.0057 (11)0.0076 (10)0.0060 (12)
C240.0261 (11)0.0441 (15)0.0297 (12)0.0049 (10)0.0060 (9)0.0009 (11)
C250.0263 (11)0.0321 (12)0.0300 (12)0.0035 (9)0.0038 (9)0.0011 (9)
C260.0325 (13)0.0355 (13)0.0382 (14)0.0043 (10)0.0071 (10)0.0033 (11)
C270.0269 (13)0.067 (2)0.058 (2)0.0042 (14)0.0027 (13)0.0221 (17)
C280.120 (4)0.055 (2)0.055 (2)0.035 (2)0.041 (2)0.0268 (19)
Geometric parameters (Å, º) top
Ru1—Cl12.4325 (7)C15—C161.371 (5)
Ru1—S12.2087 (7)C16—C171.389 (4)
Ru1—N12.111 (2)C17—C181.368 (4)
Ru1—N31.997 (2)C19—C201.428 (3)
Ru1—N52.094 (2)C20—C211.392 (4)
Ru1—N62.027 (2)C20—C251.406 (4)
S1—O11.466 (2)C21—C221.381 (4)
S1—C271.795 (4)C22—C231.384 (4)
S1—C281.776 (4)C23—C241.381 (4)
N1—C11.352 (3)C24—C251.382 (3)
N1—C51.358 (3)C25—C261.437 (4)
N2—C51.381 (3)C1—H10.9500
N2—C61.294 (3)C2—H20.9500
N3—C61.365 (3)C3—H30.9500
N3—C131.366 (3)C4—H40.9500
N4—C131.298 (3)C8—H80.9500
N4—C141.376 (3)C9—H90.9500
N5—C141.353 (3)C10—H100.9500
N5—C181.354 (3)C11—H110.9500
N6—C191.143 (3)C15—H150.9500
N7—C261.146 (4)C16—H160.9500
C1—C21.370 (4)C17—H170.9500
C2—C31.381 (4)C18—H180.9500
C3—C41.372 (4)C21—H210.9500
C4—C51.403 (3)C22—H220.9500
C6—C71.475 (3)C23—H230.9500
C7—C81.382 (4)C24—H240.9500
C7—C121.387 (4)C27—H27A0.9800
C8—C91.389 (4)C27—H27B0.9800
C9—C101.391 (4)C27—H27C0.9800
C10—C111.387 (4)C28—H28A0.9800
C11—C121.376 (4)C28—H28B0.9800
C12—C131.471 (3)C28—H28C0.9800
C14—C151.410 (4)
Cl1—Ru1—S1179.64 (3)C15—C16—C17118.0 (3)
Cl1—Ru1—N191.54 (6)C16—C17—C18118.5 (3)
Cl1—Ru1—N387.53 (6)N5—C18—C17124.7 (2)
Cl1—Ru1—N587.57 (6)N6—C19—C20174.5 (3)
Cl1—Ru1—N688.89 (6)C19—C20—C21118.8 (2)
S1—Ru1—N188.12 (6)C19—C20—C25121.5 (2)
S1—Ru1—N392.58 (6)C21—C20—C25119.7 (2)
S1—Ru1—N592.78 (6)C20—C21—C22119.5 (2)
S1—Ru1—N691.00 (6)C21—C22—C23120.6 (2)
N1—Ru1—N388.50 (8)C22—C23—C24120.4 (2)
N1—Ru1—N5176.91 (8)C23—C24—C25119.8 (2)
N1—Ru1—N690.40 (8)C20—C25—C24120.0 (2)
N3—Ru1—N588.51 (8)C20—C25—C26119.7 (2)
N3—Ru1—N6176.22 (8)C24—C25—C26120.3 (2)
N5—Ru1—N692.54 (8)N7—C26—C25179.6 (3)
Ru1—S1—O1117.21 (10)N1—C1—H1117.00
Ru1—S1—C27113.05 (12)C2—C1—H1117.00
Ru1—S1—C28113.41 (15)C1—C2—H2121.00
O1—S1—C27105.50 (15)C3—C2—H2121.00
O1—S1—C28106.27 (16)C2—C3—H3121.00
C27—S1—C2899.7 (2)C4—C3—H3121.00
Ru1—N1—C1119.39 (17)C3—C4—H4119.00
Ru1—N1—C5124.31 (16)C5—C4—H4119.00
C1—N1—C5116.3 (2)C7—C8—H8121.00
C5—N2—C6124.8 (2)C9—C8—H8121.00
Ru1—N3—C6125.07 (16)C8—C9—H9120.00
Ru1—N3—C13125.24 (16)C10—C9—H9120.00
C6—N3—C13109.4 (2)C9—C10—H10119.00
C13—N4—C14124.7 (2)C11—C10—H10119.00
Ru1—N5—C14124.17 (16)C10—C11—H11121.00
Ru1—N5—C18118.68 (16)C12—C11—H11121.00
C14—N5—C18117.0 (2)C14—C15—H15120.00
Ru1—N6—C19175.4 (2)C16—C15—H15119.00
N1—C1—C2125.2 (2)C15—C16—H16121.00
C1—C2—C3118.4 (2)C17—C16—H16121.00
C2—C3—C4118.1 (2)C16—C17—H17121.00
C3—C4—C5121.0 (3)C18—C17—H17121.00
N1—C5—N2125.7 (2)N5—C18—H18118.00
N1—C5—C4121.0 (2)C17—C18—H18118.00
N2—C5—C4113.3 (2)C20—C21—H21120.00
N2—C6—N3130.5 (2)C22—C21—H21120.00
N2—C6—C7121.0 (2)C21—C22—H22120.00
N3—C6—C7108.6 (2)C23—C22—H22120.00
C6—C7—C8132.1 (2)C22—C23—H23120.00
C6—C7—C12106.6 (2)C24—C23—H23120.00
C8—C7—C12121.3 (2)C23—C24—H24120.00
C7—C8—C9117.6 (2)C25—C24—H24120.00
C8—C9—C10120.7 (3)S1—C27—H27A109.00
C9—C10—C11121.5 (3)S1—C27—H27B109.00
C10—C11—C12117.3 (2)S1—C27—H27C109.00
C7—C12—C11121.6 (2)H27A—C27—H27B110.00
C7—C12—C13106.6 (2)H27A—C27—H27C110.00
C11—C12—C13131.8 (2)H27B—C27—H27C109.00
N3—C13—N4129.6 (2)S1—C28—H28A109.00
N3—C13—C12108.8 (2)S1—C28—H28B109.00
N4—C13—C12121.6 (2)S1—C28—H28C109.00
N4—C14—N5125.6 (2)H28A—C28—H28B109.00
N4—C14—C15113.8 (2)H28A—C28—H28C109.00
N5—C14—C15120.6 (2)H28B—C28—H28C109.00
C14—C15—C16120.9 (3)
N1—Ru1—S1—O145.14 (12)C6—N3—C13—C121.2 (3)
N1—Ru1—S1—C2777.91 (15)C13—N3—C6—C70.3 (3)
N1—Ru1—S1—C28169.60 (19)C14—N4—C13—N310.0 (4)
N3—Ru1—S1—O1133.55 (12)C14—N4—C13—C12169.7 (2)
N3—Ru1—S1—C2710.51 (15)C13—N4—C14—C15178.8 (3)
N3—Ru1—S1—C28101.99 (19)C13—N4—C14—N52.6 (4)
N5—Ru1—S1—O1137.82 (12)C18—N5—C14—C156.7 (4)
N5—Ru1—S1—C2799.14 (15)Ru1—N5—C18—C17170.6 (2)
N5—Ru1—S1—C2813.36 (19)C18—N5—C14—N4169.3 (3)
N6—Ru1—S1—O145.22 (12)Ru1—N5—C14—C15168.1 (2)
N6—Ru1—S1—C27168.27 (15)Ru1—N5—C14—N415.9 (4)
N6—Ru1—S1—C2879.23 (19)C14—N5—C18—C174.6 (4)
Cl1—Ru1—N1—C1101.52 (19)N1—C1—C2—C31.2 (4)
Cl1—Ru1—N1—C576.8 (2)C1—C2—C3—C40.9 (4)
S1—Ru1—N1—C178.36 (19)C2—C3—C4—C50.5 (5)
S1—Ru1—N1—C5103.4 (2)C3—C4—C5—N12.0 (4)
N3—Ru1—N1—C1171.0 (2)C3—C4—C5—N2176.4 (3)
N3—Ru1—N1—C510.7 (2)N2—C6—C7—C80.5 (4)
N6—Ru1—N1—C112.6 (2)N2—C6—C7—C12179.1 (2)
N6—Ru1—N1—C5165.7 (2)N3—C6—C7—C8179.3 (3)
Cl1—Ru1—N3—C681.77 (19)N3—C6—C7—C120.7 (3)
Cl1—Ru1—N3—C1391.9 (2)C8—C7—C12—C13179.9 (2)
S1—Ru1—N3—C697.88 (19)C6—C7—C12—C11176.2 (2)
S1—Ru1—N3—C1388.5 (2)C6—C7—C8—C9176.1 (3)
N1—Ru1—N3—C69.8 (2)C12—C7—C8—C92.3 (4)
N1—Ru1—N3—C13176.5 (2)C6—C7—C12—C131.4 (3)
N5—Ru1—N3—C6169.4 (2)C8—C7—C12—C112.6 (4)
N5—Ru1—N3—C134.2 (2)C7—C8—C9—C100.0 (4)
Cl1—Ru1—N5—C14101.8 (2)C8—C9—C10—C112.1 (5)
Cl1—Ru1—N5—C1883.45 (19)C9—C10—C11—C121.9 (5)
S1—Ru1—N5—C1478.4 (2)C10—C11—C12—C13177.3 (3)
S1—Ru1—N5—C1896.45 (19)C10—C11—C12—C70.4 (4)
N3—Ru1—N5—C1414.2 (2)C11—C12—C13—N44.2 (4)
N3—Ru1—N5—C18171.0 (2)C7—C12—C13—N31.7 (3)
N6—Ru1—N5—C14169.5 (2)C7—C12—C13—N4178.6 (2)
N6—Ru1—N5—C185.3 (2)C11—C12—C13—N3175.6 (3)
C5—N1—C1—C23.5 (4)N5—C14—C15—C164.1 (4)
C1—N1—C5—N2174.4 (2)N4—C14—C15—C16172.4 (3)
Ru1—N1—C5—N27.3 (4)C14—C15—C16—C171.2 (5)
Ru1—N1—C5—C4174.5 (2)C15—C16—C17—C183.5 (5)
Ru1—N1—C1—C2174.9 (2)C16—C17—C18—N50.6 (5)
C1—N1—C5—C43.8 (4)C19—C20—C25—C260.7 (4)
C6—N2—C5—C4176.8 (2)C19—C20—C25—C24178.0 (2)
C5—N2—C6—N32.7 (4)C19—C20—C21—C22177.7 (2)
C5—N2—C6—C7177.5 (2)C25—C20—C21—C220.6 (4)
C6—N2—C5—N11.5 (4)C21—C20—C25—C240.9 (4)
Ru1—N3—C6—C7174.17 (16)C21—C20—C25—C26176.3 (2)
C13—N3—C6—N2179.9 (3)C20—C21—C22—C230.4 (4)
Ru1—N3—C6—N25.6 (4)C21—C22—C23—C241.1 (4)
Ru1—N3—C13—N46.5 (4)C22—C23—C24—C250.8 (4)
Ru1—N3—C13—C12173.27 (16)C23—C24—C25—C200.2 (4)
C6—N3—C13—N4179.1 (3)C23—C24—C25—C26177.0 (2)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C9—H9···O1i0.952.343.264 (3)165
C11—H11···O1ii0.952.593.241 (4)126
C23—H23···Cl1iii0.952.803.557 (3)137
Symmetry codes: (i) x+1/2, y+1/2, z1/2; (ii) x+3/2, y+1/2, z+1/2; (iii) x1/2, y+1/2, z+1/2.
 

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