Poly­[[silver(I)-di-μ-1,5-bis­(phenyl­thio)­pentane] hexa­fluoro­phosphate]: a two-dimensional molecular-rectangle coordination ploymer

In the title Ag^I complex of 1,5-bis­(phenyl­thio)­pentane, {[Ag(C₁₇H₂₀S₂)₂]PF₆}_n, Ag^I centers coordinate to four S atoms and display a distorted tetrahedral geometry. Ligands link adjacent Ag^I atoms to form an infinite parquet-like framework. The PF₆⁻ ions are incorporated in the cavities of the network to complete and stabilize the structure.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.009 Å
• R factor = 0.034
• wR factor = 0.089
• Data-to-parameter ratio = 12.4

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



PLAT_320  Alert C Check Hybridisation of  C(1)   in main residue          ?

PLAT_320  Alert C Check Hybridisation of  C(5)   in main residue          ?

General Notes



FORMU_01  There is a discrepancy between the atom counts in the
          _chemical_formula_sum and _chemical_formula_moiety. This is
          usually due to the moiety formula being in the wrong format.
          Atom count from _chemical_formula_sum:   C34 H40 Ag1 F6 P1 S4
          Atom count from _chemical_formula_moiety:C34 H40 Ag1 F1 P6 S4

REFLT_03
         From the CIF: _diffrn_reflns_theta_max           25.03
         From the CIF: _reflns_number_total               5142
         Count of symmetry unique reflns         3255
         Completeness (_total/calc)            157.97%
         TEST3: Check Friedels for noncentro structure
         Estimate of Friedel pairs measured      1887
         Fraction of Friedel pairs measured     0.580
         Are heavy atom types Z>Si present          yes
          Please check that the estimate of the number of Friedel pairs is
          correct. If it is not, please give the correct count in the
          _publ_section_exptl_refinement section of the submitted CIF.


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 2 Alert Level C = Please check

---

Computing details

Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: XP (Bruker, 1998).

Poly[[silver(I)-di-µ-1,5-bis(phenylthio)pentane] hexafluorophosphate]

Crystal data

[Ag(C17H20S2)2]PF6	F(000) = 848
Mr = 829.74	Dx = 1.502 Mg m^−3
Monoclinic, Pc	Mo Kα radiation, λ = 0.71073 Å
a = 9.3876 (10) Å	Cell parameters from 7412 reflections
b = 10.2213 (11) Å	θ = 2.0–25.0°
c = 19.640 (2) Å	µ = 0.87 mm^−1
β = 103.161 (2)°	T = 293 K
V = 1835.0 (3) Å^3	Prism, colorless
Z = 2	0.30 × 0.20 × 0.20 mm

Data collection

Bruker SMART1000 diffractometer	4522 reflections with I > 2σ(I)
ω scans	Rint = 0.022
Absorption correction: multi-scan [SAINT (Bruker 1998) and SADABS (Sheldrick, 1997)]	θmax = 25.0°
Tmin = 0.779, Tmax = 0.845	h = −11→8
7412 measured reflections	k = −12→9
5142 independent reflections	l = −22→23

Refinement

Refinement on F^2	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.034	w = 1/[σ^2(Fo^2) + (0.0554P)^2 + 0.1885P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.089	(Δ/σ)max = 0.019
S = 1.02	Δρmax = 0.52 e Å^−3
5142 reflections	Δρmin = −0.35 e Å^−3
415 parameters

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Full-MATRIX

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ag1	0.82775 (2)	0.80911 (4)	0.101332 (17)	0.06501 (13)
S1	0.65042 (15)	0.83982 (12)	0.18588 (7)	0.0579 (3)
S2	1.01890 (15)	0.98886 (14)	0.09152 (8)	0.0675 (3)
S3	0.66147 (15)	0.81643 (12)	−0.02914 (7)	0.0579 (3)
S4	0.90410 (16)	0.56369 (12)	0.11148 (7)	0.0623 (3)
C1	0.8115 (6)	1.3294 (4)	0.1566 (3)	0.0620 (13)
H1A	0.9085	1.3122	0.1851	0.074*
H1B	0.8107	1.3015	0.1093	0.074*
C2	0.7024 (5)	1.2474 (5)	0.1839 (3)	0.0568 (12)
H2A	0.6039	1.2691	0.1587	0.068*
H2B	0.7103	1.2666	0.2330	0.068*
C3	0.7305 (5)	1.1024 (5)	0.1751 (3)	0.0587 (12)
H3A	0.7420	1.0875	0.1279	0.070*
H3B	0.8218	1.0786	0.2070	0.070*
C4	0.6110 (5)	1.0145 (5)	0.1884 (3)	0.0622 (13)
H4A	0.5218	1.0331	0.1538	0.075*
H4B	0.5932	1.0355	0.2340	0.075*
C5	1.1425 (7)	0.9614 (6)	0.0341 (3)	0.0732 (15)
H5A	1.0869	0.9679	−0.0139	0.088*
H5B	1.2146	1.0310	0.0416	0.088*
C6	0.2207 (9)	0.8343 (6)	0.0428 (4)	0.0859 (19)
H6A	0.1505	0.7637	0.0304	0.103*
H6B	0.2709	0.8232	0.0914	0.103*
C7	0.3346 (7)	0.8268 (6)	−0.0044 (3)	0.0800 (17)
H7A	0.2835	0.8335	−0.0531	0.096*
H7B	0.4013	0.9003	0.0062	0.096*
C8	0.4188 (7)	0.7043 (6)	0.0062 (3)	0.0781 (16)
H8A	0.3507	0.6316	−0.0014	0.094*
H8B	0.4729	0.7007	0.0545	0.094*
C9	0.5260 (7)	0.6862 (6)	−0.0408 (4)	0.0760 (16)
H9A	0.4724	0.6844	−0.0892	0.091*
H9B	0.5755	0.6029	−0.0303	0.091*
C10	0.7846 (5)	0.4737 (5)	0.1560 (3)	0.0609 (13)
H10A	0.7998	0.5048	0.2038	0.073*
H10B	0.6835	0.4909	0.1329	0.073*
C11	0.7558 (6)	0.8124 (4)	0.2727 (3)	0.0522 (11)
C12	0.6872 (7)	0.7749 (6)	0.3243 (3)	0.0745 (16)
H12A	0.5865	0.7617	0.3142	0.089*
C13	0.7713 (9)	0.7568 (8)	0.3927 (4)	0.0879 (19)
H13A	0.7247	0.7338	0.4280	0.105*
C14	0.9164 (8)	0.7716 (6)	0.4082 (3)	0.0797 (17)
H14A	0.9703	0.7572	0.4535	0.096*
C15	0.9855 (7)	0.8083 (5)	0.3566 (3)	0.0742 (15)
H15A	1.0864	0.8198	0.3672	0.089*
C16	0.9063 (6)	0.8281 (5)	0.2897 (3)	0.0632 (14)
H16A	0.9543	0.8525	0.2551	0.076*
C17	1.1472 (5)	1.0094 (4)	0.1724 (3)	0.0538 (11)
C22	1.1966 (7)	1.1346 (6)	0.1939 (4)	0.0796 (17)
H22A	1.1653	1.2067	0.1655	0.095*
C21	1.2938 (9)	1.1502 (8)	0.2586 (5)	0.096 (2)
H21A	1.3266	1.2336	0.2734	0.115*
C20	1.3409 (7)	1.0475 (8)	0.3000 (4)	0.0859 (18)
H20A	1.4048	1.0599	0.3432	0.103*
C19	1.2947 (6)	0.9249 (6)	0.2784 (3)	0.0694 (14)
H19A	1.3287	0.8535	0.3069	0.083*
C18	1.1999 (6)	0.9054 (5)	0.2161 (3)	0.0600 (12)
H18A	1.1697	0.8209	0.2025	0.072*
C23	1.0804 (5)	0.5416 (4)	0.1671 (3)	0.0525 (11)
C24	1.1081 (7)	0.5607 (5)	0.2386 (3)	0.0673 (14)
H24A	1.0319	0.5811	0.2598	0.081*
C25	1.2486 (9)	0.5493 (6)	0.2782 (4)	0.089 (2)
H25A	1.2657	0.5616	0.3263	0.106*
C26	1.3623 (9)	0.5210 (7)	0.2494 (6)	0.105 (3)
H26A	1.4569	0.5145	0.2769	0.126*
C27	1.3339 (8)	0.5017 (8)	0.1771 (6)	0.109 (3)
H27A	1.4110	0.4825	0.1563	0.131*
C28	1.1946 (7)	0.5103 (6)	0.1360 (3)	0.0743 (15)
H28A	1.1771	0.4955	0.0881	0.089*
C29	0.7866 (6)	0.7618 (5)	−0.0782 (2)	0.0542 (11)
C30	0.8508 (7)	0.8559 (5)	−0.1128 (3)	0.0655 (14)
H30A	0.8211	0.9427	−0.1128	0.079*
C31	0.9583 (8)	0.8215 (6)	−0.1473 (3)	0.0708 (16)
H31A	1.0007	0.8854	−0.1699	0.085*
C32	1.0026 (8)	0.6954 (6)	−0.1483 (4)	0.0799 (18)
H32A	1.0762	0.6730	−0.1708	0.096*
C33	0.9384 (9)	0.6019 (6)	−0.1160 (4)	0.094 (2)
H33A	0.9669	0.5151	−0.1179	0.113*
C34	0.8332 (8)	0.6325 (5)	−0.0808 (3)	0.0759 (16)
H34A	0.7923	0.5670	−0.0584	0.091*
P1	0.40746 (18)	0.28600 (16)	0.99063 (8)	0.0720 (4)
F1	0.4883 (6)	0.3998 (5)	1.0371 (3)	0.143 (2)
F2	0.2686 (5)	0.3755 (6)	0.9679 (3)	0.1375 (19)
F3	0.3617 (8)	0.2291 (6)	1.0564 (2)	0.147 (2)
F4	0.3258 (7)	0.1702 (5)	0.9455 (3)	0.1329 (19)
F5	0.5460 (7)	0.1968 (5)	1.0122 (3)	0.142 (2)
F6	0.4604 (7)	0.3358 (6)	0.9245 (3)	0.151 (2)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0744 (3)	0.0620 (2)	0.0589 (2)	0.0054 (2)	0.01552 (18)	0.0024 (2)
S1	0.0532 (7)	0.0571 (7)	0.0645 (8)	−0.0050 (5)	0.0158 (6)	−0.0020 (6)
S2	0.0499 (7)	0.0826 (9)	0.0721 (8)	0.0012 (6)	0.0185 (6)	0.0160 (7)
S3	0.0649 (8)	0.0582 (7)	0.0519 (7)	0.0121 (6)	0.0163 (6)	0.0036 (5)
S4	0.0703 (8)	0.0547 (7)	0.0600 (7)	0.0078 (6)	0.0107 (6)	0.0086 (6)
C1	0.059 (3)	0.056 (3)	0.071 (3)	0.007 (2)	0.015 (3)	0.003 (2)
C2	0.054 (3)	0.054 (3)	0.059 (3)	0.004 (2)	0.006 (2)	0.004 (2)
C3	0.051 (3)	0.057 (3)	0.069 (3)	0.008 (2)	0.014 (2)	0.002 (2)
C4	0.043 (3)	0.072 (3)	0.072 (3)	0.010 (2)	0.015 (2)	0.010 (3)
C5	0.068 (4)	0.088 (4)	0.066 (3)	−0.004 (3)	0.020 (3)	0.014 (3)
C6	0.101 (5)	0.096 (5)	0.062 (3)	0.006 (4)	0.022 (4)	−0.001 (3)
C7	0.085 (5)	0.080 (4)	0.078 (4)	−0.001 (3)	0.025 (4)	−0.002 (3)
C8	0.075 (4)	0.084 (4)	0.079 (4)	−0.006 (3)	0.025 (3)	−0.001 (3)
C9	0.066 (4)	0.087 (4)	0.080 (4)	−0.009 (3)	0.025 (3)	−0.004 (3)
C10	0.047 (3)	0.054 (3)	0.082 (4)	0.005 (2)	0.016 (3)	0.003 (2)
C11	0.054 (3)	0.045 (2)	0.062 (3)	0.0037 (19)	0.023 (2)	0.000 (2)
C12	0.063 (4)	0.083 (4)	0.084 (4)	−0.004 (3)	0.028 (3)	0.010 (3)
C13	0.103 (6)	0.104 (5)	0.066 (4)	0.005 (4)	0.039 (4)	0.021 (4)
C14	0.093 (5)	0.072 (4)	0.070 (4)	0.012 (3)	0.011 (4)	0.003 (3)
C15	0.063 (4)	0.081 (4)	0.077 (4)	0.010 (3)	0.012 (3)	0.000 (3)
C16	0.053 (3)	0.068 (3)	0.072 (4)	0.003 (2)	0.022 (3)	−0.002 (3)
C17	0.046 (3)	0.057 (3)	0.065 (3)	0.001 (2)	0.026 (2)	0.010 (2)
C22	0.068 (4)	0.063 (3)	0.117 (5)	0.010 (3)	0.040 (4)	0.008 (3)
C21	0.096 (6)	0.086 (5)	0.116 (6)	−0.021 (4)	0.047 (5)	−0.045 (5)
C20	0.075 (4)	0.115 (6)	0.074 (4)	−0.003 (4)	0.030 (3)	−0.016 (4)
C19	0.064 (3)	0.085 (4)	0.062 (3)	0.005 (3)	0.021 (3)	0.002 (3)
C18	0.060 (3)	0.062 (3)	0.063 (3)	−0.005 (2)	0.027 (3)	0.003 (2)
C23	0.057 (3)	0.039 (2)	0.064 (3)	0.0033 (19)	0.018 (2)	0.003 (2)
C24	0.081 (4)	0.051 (3)	0.067 (3)	−0.002 (2)	0.011 (3)	−0.002 (2)
C25	0.108 (6)	0.062 (3)	0.080 (4)	−0.014 (4)	−0.011 (4)	0.002 (3)
C26	0.063 (5)	0.084 (5)	0.152 (8)	−0.008 (3)	−0.005 (5)	0.024 (5)
C27	0.060 (5)	0.105 (5)	0.169 (9)	0.016 (4)	0.043 (5)	0.029 (6)
C28	0.076 (4)	0.074 (4)	0.080 (4)	0.010 (3)	0.032 (3)	0.012 (3)
C29	0.068 (3)	0.057 (3)	0.039 (2)	0.006 (2)	0.016 (2)	0.002 (2)
C30	0.079 (4)	0.057 (3)	0.060 (3)	−0.005 (3)	0.014 (3)	0.003 (3)
C31	0.083 (4)	0.075 (4)	0.062 (3)	−0.011 (3)	0.033 (3)	0.003 (3)
C32	0.091 (5)	0.087 (4)	0.076 (4)	0.004 (3)	0.049 (4)	−0.009 (3)
C33	0.139 (6)	0.062 (3)	0.099 (5)	0.025 (4)	0.062 (5)	−0.003 (3)
C34	0.104 (5)	0.053 (3)	0.083 (4)	0.008 (3)	0.047 (4)	0.008 (3)
P1	0.0735 (10)	0.0870 (10)	0.0523 (8)	−0.0103 (8)	0.0079 (7)	0.0002 (7)
F1	0.164 (5)	0.106 (3)	0.122 (3)	−0.052 (3)	−0.044 (3)	0.016 (3)
F2	0.093 (3)	0.172 (5)	0.133 (4)	0.041 (3)	−0.003 (3)	−0.037 (4)
F3	0.206 (6)	0.159 (4)	0.084 (3)	−0.084 (4)	0.053 (3)	−0.007 (3)
F4	0.157 (5)	0.128 (4)	0.093 (3)	−0.013 (3)	−0.013 (3)	−0.034 (3)
F5	0.141 (5)	0.162 (5)	0.107 (3)	0.049 (3)	−0.003 (3)	0.026 (3)
F6	0.135 (4)	0.230 (6)	0.097 (3)	0.043 (4)	0.045 (3)	0.075 (4)

Geometric parameters (Å, º)

Ag1—S4	2.6040 (13)	C13—C14	1.335 (10)
Ag1—S2	2.6059 (15)	C13—H13A	0.9300
Ag1—S1	2.6241 (14)	C14—C15	1.373 (9)
Ag1—S3	2.6809 (13)	C14—H14A	0.9300
S1—C11	1.788 (6)	C15—C16	1.370 (9)
S1—C4	1.827 (5)	C15—H15A	0.9300
S2—C17	1.774 (5)	C16—H16A	0.9300
S2—C5	1.814 (6)	C17—C18	1.385 (7)
S3—C29	1.770 (5)	C17—C22	1.394 (8)
S3—C9	1.819 (6)	C22—C21	1.396 (11)
S4—C23	1.778 (5)	C22—H22A	0.9300
S4—C10	1.821 (5)	C21—C20	1.339 (11)
C1—C10^i	1.497 (6)	C21—H21A	0.9300
C1—C2	1.513 (7)	C20—C19	1.363 (9)
C1—H1A	0.9700	C20—H20A	0.9300
C1—H1B	0.9700	C19—C18	1.353 (8)
C2—C3	1.522 (7)	C19—H19A	0.9300
C2—H2A	0.9700	C18—H18A	0.9300
C2—H2B	0.9700	C23—C24	1.381 (7)
C3—C4	1.506 (7)	C23—C28	1.387 (7)
C3—H3A	0.9700	C24—C25	1.376 (9)
C3—H3B	0.9700	C24—H24A	0.9300
C4—H4A	0.9700	C25—C26	1.348 (11)
C4—H4B	0.9700	C25—H25A	0.9300
C5—C6^ii	1.483 (8)	C26—C27	1.398 (11)
C5—H5A	0.9700	C26—H26A	0.9300
C5—H5B	0.9700	C27—C28	1.374 (10)
C6—C5^iii	1.483 (8)	C27—H27A	0.9300
C6—C7	1.567 (9)	C28—H28A	0.9300
C6—H6A	0.9700	C29—C30	1.392 (8)
C6—H6B	0.9700	C29—C34	1.397 (8)
C7—C8	1.470 (9)	C30—C31	1.382 (8)
C7—H7A	0.9700	C30—H30A	0.9300
C7—H7B	0.9700	C31—C32	1.356 (8)
C8—C9	1.523 (9)	C31—H31A	0.9300
C8—H8A	0.9700	C32—C33	1.360 (9)
C8—H8B	0.9700	C32—H32A	0.9300
C9—H9A	0.9700	C33—C34	1.365 (8)
C9—H9B	0.9700	C33—H33A	0.9300
C10—C1^iv	1.497 (6)	C34—H34A	0.9300
C10—H10A	0.9700	P1—F1	1.564 (5)
C10—H10B	0.9700	P1—F3	1.564 (5)
C11—C12	1.374 (8)	P1—F5	1.566 (5)
C11—C16	1.385 (8)	P1—F2	1.572 (5)
C12—C13	1.406 (9)	P1—F4	1.570 (5)
C12—H12A	0.9300	P1—F6	1.578 (5)
S4—Ag1—S2	120.18 (5)	C13—C12—H12A	120.5
S4—Ag1—S1	105.66 (4)	C14—C13—C12	121.6 (6)
S2—Ag1—S1	120.61 (5)	C14—C13—H13A	119.2
S4—Ag1—S3	100.97 (4)	C12—C13—H13A	119.2
S2—Ag1—S3	99.81 (5)	C13—C14—C15	119.4 (6)
S1—Ag1—S3	106.64 (4)	C13—C14—H14A	120.3
C11—S1—C4	101.5 (2)	C15—C14—H14A	120.3
C11—S1—Ag1	106.98 (16)	C16—C15—C14	120.3 (6)
C4—S1—Ag1	107.22 (17)	C16—C15—H15A	119.9
C17—S2—C5	100.1 (3)	C14—C15—H15A	119.9
C17—S2—Ag1	110.84 (15)	C15—C16—C11	121.0 (5)
C5—S2—Ag1	119.0 (2)	C15—C16—H16A	119.5
C29—S3—C9	103.4 (3)	C11—C16—H16A	119.5
C29—S3—Ag1	101.39 (17)	C18—C17—C22	118.0 (5)
C9—S3—Ag1	109.7 (2)	C18—C17—S2	122.6 (4)
C23—S4—C10	103.3 (2)	C22—C17—S2	119.4 (4)
C23—S4—Ag1	111.77 (15)	C21—C22—C17	118.9 (6)
C10—S4—Ag1	109.53 (16)	C21—C22—H22A	120.5
C10^i—C1—C2	115.0 (4)	C17—C22—H22A	120.5
C10^i—C1—H1A	108.5	C20—C21—C22	121.4 (7)
C2—C1—H1A	108.5	C20—C21—H21A	119.3
C10^i—C1—H1B	108.5	C22—C21—H21A	119.3
C2—C1—H1B	108.5	C21—C20—C19	119.7 (7)
H1A—C1—H1B	107.5	C21—C20—H20A	120.2
C1—C2—C3	110.5 (4)	C19—C20—H20A	120.2
C1—C2—H2A	109.6	C18—C19—C20	120.9 (6)
C3—C2—H2A	109.6	C18—C19—H19A	119.6
C1—C2—H2B	109.6	C20—C19—H19A	119.6
C3—C2—H2B	109.6	C19—C18—C17	121.1 (5)
H2A—C2—H2B	108.1	C19—C18—H18A	119.4
C4—C3—C2	113.9 (4)	C17—C18—H18A	119.4
C4—C3—H3A	108.8	C24—C23—C28	119.7 (5)
C2—C3—H3A	108.8	C24—C23—S4	122.7 (4)
C4—C3—H3B	108.8	C28—C23—S4	117.6 (4)
C2—C3—H3B	108.8	C23—C24—C25	119.8 (6)
H3A—C3—H3B	107.7	C23—C24—H24A	120.1
C3—C4—S1	114.5 (3)	C25—C24—H24A	120.1
C3—C4—H4A	108.6	C26—C25—C24	122.0 (7)
S1—C4—H4A	108.6	C26—C25—H25A	119.0
C3—C4—H4B	108.6	C24—C25—H25A	119.0
S1—C4—H4B	108.6	C25—C26—C27	118.0 (7)
H4A—C4—H4B	107.6	C25—C26—H26A	121.0
C6^ii—C5—S2	115.8 (4)	C27—C26—H26A	121.0
C6^ii—C5—H5A	108.3	C28—C27—C26	121.6 (7)
S2—C5—H5A	108.3	C28—C27—H27A	119.2
C6^ii—C5—H5B	108.3	C26—C27—H27A	119.2
S2—C5—H5B	108.3	C27—C28—C23	118.9 (6)
H5A—C5—H5B	107.4	C27—C28—H28A	120.6
C5^iii—C6—C7	111.2 (5)	C23—C28—H28A	120.6
C5^iii—C6—H6A	109.4	C30—C29—C34	117.5 (5)
C7—C6—H6A	109.4	C30—C29—S3	117.6 (4)
C5^iii—C6—H6B	109.4	C34—C29—S3	124.8 (4)
C7—C6—H6B	109.4	C31—C30—C29	120.6 (5)
H6A—C6—H6B	108.0	C31—C30—H30A	119.7
C8—C7—C6	112.0 (5)	C29—C30—H30A	119.7
C8—C7—H7A	109.2	C32—C31—C30	120.6 (5)
C6—C7—H7A	109.2	C32—C31—H31A	119.7
C8—C7—H7B	109.2	C30—C31—H31A	119.7
C6—C7—H7B	109.2	C31—C32—C33	119.4 (6)
H7A—C7—H7B	107.9	C31—C32—H32A	120.3
C7—C8—C9	115.2 (5)	C33—C32—H32A	120.3
C7—C8—H8A	108.5	C34—C33—C32	121.6 (5)
C9—C8—H8A	108.5	C34—C33—H33A	119.2
C7—C8—H8B	108.5	C32—C33—H33A	119.2
C9—C8—H8B	108.5	C33—C34—C29	120.3 (5)
H8A—C8—H8B	107.5	C33—C34—H34A	119.9
C8—C9—S3	112.0 (4)	C29—C34—H34A	119.9
C8—C9—H9A	109.2	F1—P1—F3	89.0 (3)
S3—C9—H9A	109.2	F1—P1—F5	90.7 (3)
C8—C9—H9B	109.2	F3—P1—F5	85.9 (4)
S3—C9—H9B	109.2	F1—P1—F2	89.6 (3)
H9A—C9—H9B	107.9	F3—P1—F2	94.8 (4)
C1^iv—C10—S4	112.3 (4)	F5—P1—F2	179.2 (3)
C1^iv—C10—H10A	109.1	F1—P1—F4	178.7 (3)
S4—C10—H10A	109.1	F3—P1—F4	89.8 (3)
C1^iv—C10—H10B	109.1	F5—P1—F4	89.0 (3)
S4—C10—H10B	109.1	F2—P1—F4	90.7 (3)
H10A—C10—H10B	107.9	F1—P1—F6	92.2 (3)
C12—C11—C16	118.6 (5)	F3—P1—F6	176.4 (4)
C12—C11—S1	119.8 (4)	F5—P1—F6	90.7 (3)
C16—C11—S1	121.6 (4)	F2—P1—F6	88.6 (3)
C11—C12—C13	119.1 (6)	F4—P1—F6	89.0 (4)
C11—C12—H12A	120.5

Symmetry codes: (i) x, y+1, z; (ii) x+1, y, z; (iii) x−1, y, z; (iv) x, y−1, z.