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The title compound, (C16H36N)2[Pd2Br6], was prepared from palladium(II) bromide and tetrabutylammonium bromide. In the anion, the terminal and bridging Pd—Br bond lengths lie in the ranges 2.3982 (9)–2.4185 (8) and 2.4389 (7)–2.4513 (7) Å, respectively. The anion can be viewed as a dimeric cluster consiting of two edge-sharing PdBr4 square units, which make a dihedral angle of 7.84 (4)°.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807009919/cv2197sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807009919/cv2197Isup2.hkl
Contains datablock I

CCDC reference: 642952

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.041
  • wR factor = 0.101
  • Data-to-parameter ratio = 27.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT230_ALERT_2_B Hirshfeld Test Diff for C213 - C214 .. 7.03 su
Alert level C PLAT063_ALERT_3_C Crystal Probably too Large for Beam Size ....... 0.70 mm PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.56 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.21 Ratio PLAT233_ALERT_4_C Hirshfeld (M-X Solvent) Pd1 - Br1 .. 14.90 su PLAT233_ALERT_4_C Hirshfeld (M-X Solvent) Pd1 - Br4 .. 11.03 su PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C113 PLAT243_ALERT_4_C High 'Solvent' Ueq as Compared to Neighbors for Br3 PLAT243_ALERT_4_C High 'Solvent' Ueq as Compared to Neighbors for Br4 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for Pd1 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for Pd2 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 2 BR6 -PD2 -BR3 -PD1 5.20 0.40 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 5 BR2 -PD1 -BR3 -PD2 32.90 0.40 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 7 BR5 -PD2 -BR4 -PD1 7.90 0.40 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 10 BR1 -PD1 -BR4 -PD2 46.10 0.30 1.555 1.555 1.555 1.555 PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 1 C16 H36 N PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2 C16 H36 N
Alert level G PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature . 293 K
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 17 ALERT level C = Check and explain 2 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 12 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: RAPID-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2001); software used to prepare material for publication: SHELXTL.

Bis(tetrabutylammonium) di-µ-bromido-bis[dibromidopalladate(II)] top
Crystal data top
(C16H36N)2[Pd2Br6]F(000) = 2320
Mr = 1177.18Dx = 1.743 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 24353 reflections
a = 13.641 (3) Åθ = 6.1–54.9°
b = 14.869 (3) ŵ = 6.17 mm1
c = 22.476 (5) ÅT = 293 K
β = 100.19 (3)°Block, black
V = 4486.8 (16) Å30.70 × 0.20 × 0.20 mm
Z = 4
Data collection top
Bruker P4
diffractometer
10238 independent reflections
Radiation source: fine-focus sealed tube6345 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.052
ω scansθmax = 27.5°, θmin = 3.0°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1714
Tmin = 0.237, Tmax = 0.291k = 1919
41842 measured reflectionsl = 2929
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.041Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.101H-atom parameters constrained
S = 1.05 w = 1/[σ2(Fo2) + (0.04P)2 + 1.4726P]
where P = (Fo2 + 2Fc2)/3
10238 reflections(Δ/σ)max = 0.001
379 parametersΔρmax = 0.70 e Å3
0 restraintsΔρmin = 0.89 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pd10.65099 (2)0.71073 (3)0.403568 (14)0.05555 (11)
Pd20.87817 (2)0.66818 (2)0.348743 (13)0.04894 (10)
Br10.47786 (4)0.68965 (4)0.36273 (3)0.08497 (18)
Br20.61144 (4)0.78386 (5)0.49247 (2)0.08827 (19)
Br30.70051 (3)0.64346 (4)0.31381 (2)0.07708 (17)
Br40.82973 (3)0.72086 (4)0.442141 (19)0.07020 (15)
Br50.91453 (4)0.61658 (4)0.25307 (2)0.07664 (16)
Br61.05160 (3)0.69633 (4)0.38971 (2)0.07244 (15)
N11.2064 (2)0.4125 (2)0.35062 (14)0.0471 (8)
N21.2858 (2)0.9296 (2)0.38656 (14)0.0515 (8)
C1111.1229 (3)0.3707 (3)0.3783 (2)0.0593 (11)
H11D1.09590.32030.35330.071*
H11E1.15150.34700.41780.071*
C1121.0383 (3)0.4324 (3)0.3857 (2)0.0720 (13)
H11F1.00510.45290.34620.086*
H11G1.06430.48470.40910.086*
C1130.9642 (4)0.3845 (4)0.4173 (2)0.0806 (15)
H11H0.93780.33290.39330.097*
H11I0.99850.36250.45600.097*
C1140.8805 (5)0.4429 (5)0.4271 (4)0.131 (3)
H11A0.83540.40890.44660.196*
H11B0.84590.46460.38880.196*
H11C0.90590.49290.45210.196*
C1211.1682 (3)0.4497 (3)0.28813 (17)0.0512 (10)
H12D1.22340.47800.27340.061*
H12E1.11970.49620.29160.061*
C1221.1203 (3)0.3820 (3)0.2410 (2)0.0688 (13)
H12F1.06020.35820.25270.083*
H12G1.16580.33230.23930.083*
C1231.0944 (4)0.4258 (4)0.1787 (2)0.0773 (15)
H12H1.05130.38550.15190.093*
H12I1.05750.48070.18220.093*
C1241.1831 (5)0.4475 (4)0.1510 (2)0.0983 (19)
H12A1.16180.47510.11220.147*
H12B1.21900.39330.14610.147*
H12C1.22570.48830.17680.147*
C1311.2829 (3)0.3379 (3)0.34901 (19)0.0544 (11)
H13D1.30590.31730.39010.065*
H13E1.24970.28770.32640.065*
C1321.3721 (3)0.3627 (3)0.3220 (2)0.0611 (12)
H13F1.40250.41670.34130.073*
H13G1.35150.37520.27920.073*
C1331.4475 (3)0.2869 (3)0.3301 (2)0.0711 (14)
H13H1.41630.23300.31110.085*
H13I1.46760.27470.37290.085*
C1341.5392 (4)0.3084 (4)0.3031 (2)0.0892 (18)
H13A1.58440.25840.30940.134*
H13B1.57130.36090.32240.134*
H13C1.51990.31940.26060.134*
C1411.2523 (3)0.4917 (3)0.38825 (17)0.0516 (10)
H14D1.30290.51790.36830.062*
H14E1.20090.53680.38840.062*
C1421.2987 (3)0.4719 (3)0.45290 (18)0.0611 (12)
H14F1.35120.42770.45380.073*
H14G1.24880.44720.47410.073*
C1431.3415 (4)0.5572 (3)0.48404 (19)0.0688 (13)
H14H1.38940.58270.46160.083*
H14I1.28830.60070.48350.083*
C1441.3919 (4)0.5414 (4)0.5488 (2)0.0931 (18)
H14A1.41780.59730.56640.140*
H14B1.44540.49930.54950.140*
H14C1.34440.51770.57150.140*
C2111.3929 (3)0.9383 (3)0.3763 (2)0.0713 (13)
H21D1.43250.96280.41280.086*
H21E1.41790.87840.37080.086*
C2121.4099 (4)0.9943 (4)0.3249 (3)0.0903 (16)
H21F1.38461.05460.32860.108*
H21G1.37600.96860.28710.108*
C2131.5260 (4)0.9969 (5)0.3262 (3)0.108 (2)
H21H1.55901.02290.36410.130*
H21I1.55080.93610.32360.130*
C2141.5486 (5)1.0504 (5)0.2757 (4)0.135 (3)
H21A1.61931.05110.27690.202*
H21B1.52511.11080.27880.202*
H21C1.51621.02430.23830.202*
C2211.2172 (3)0.8959 (3)0.33036 (18)0.0573 (11)
H22D1.15090.88990.33990.069*
H22E1.21390.94190.29950.069*
C2221.2434 (3)0.8091 (3)0.30379 (19)0.0589 (11)
H22F1.24430.76140.33340.071*
H22G1.30960.81350.29380.071*
C2231.1695 (4)0.7859 (3)0.2476 (2)0.0725 (14)
H22H1.10290.78810.25700.087*
H22I1.17350.83120.21700.087*
C2241.1855 (4)0.6961 (4)0.2222 (2)0.0886 (17)
H22A1.13610.68580.18670.133*
H22B1.18010.65060.25170.133*
H22C1.25070.69380.21160.133*
C2311.2483 (3)1.0205 (3)0.4031 (2)0.0637 (12)
H23D1.29751.04630.43500.076*
H23E1.24371.05970.36810.076*
C2321.1489 (3)1.0209 (3)0.4236 (2)0.0712 (13)
H23F1.10020.99020.39380.085*
H23G1.15470.98820.46140.085*
C2331.1134 (4)1.1145 (4)0.4324 (3)0.0937 (17)
H23H1.16391.14550.46080.112*
H23I1.10621.14620.39410.112*
C2341.0167 (4)1.1192 (4)0.4549 (3)0.106 (2)
H23A0.99811.18100.45830.159*
H23B1.02401.09090.49380.159*
H23C0.96611.08880.42700.159*
C2411.2857 (3)0.8611 (3)0.43660 (18)0.0611 (12)
H24D1.31450.80560.42490.073*
H24E1.21710.84840.44000.073*
C2421.3419 (4)0.8886 (4)0.4988 (2)0.0800 (15)
H24F1.41010.90370.49600.096*
H24G1.31090.94160.51260.096*
C2431.3415 (4)0.8132 (4)0.5441 (2)0.0936 (18)
H24H1.36810.75950.52830.112*
H24I1.38600.82940.58120.112*
C2441.2454 (5)0.7920 (6)0.5587 (3)0.132 (3)
H24A1.25220.74310.58710.198*
H24B1.20070.77490.52260.198*
H24C1.21950.84370.57620.198*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pd10.04746 (19)0.0662 (2)0.05327 (19)0.01114 (16)0.00961 (14)0.00953 (16)
Pd20.04530 (17)0.0498 (2)0.05181 (18)0.00214 (14)0.00882 (13)0.00025 (15)
Br10.0505 (3)0.1038 (5)0.0987 (4)0.0160 (3)0.0080 (3)0.0112 (3)
Br20.0817 (4)0.1140 (5)0.0726 (3)0.0258 (3)0.0230 (3)0.0066 (3)
Br30.0485 (3)0.1191 (5)0.0615 (3)0.0007 (3)0.0037 (2)0.0194 (3)
Br40.0550 (3)0.1010 (4)0.0533 (3)0.0045 (3)0.0059 (2)0.0116 (3)
Br50.0809 (3)0.0830 (4)0.0707 (3)0.0005 (3)0.0262 (3)0.0181 (3)
Br60.0481 (3)0.0704 (4)0.0973 (4)0.0034 (2)0.0087 (2)0.0051 (3)
N10.0489 (18)0.0352 (19)0.0577 (19)0.0032 (15)0.0113 (15)0.0045 (15)
N20.0480 (19)0.044 (2)0.061 (2)0.0021 (16)0.0029 (16)0.0034 (17)
C1110.054 (2)0.044 (3)0.083 (3)0.005 (2)0.020 (2)0.006 (2)
C1120.056 (3)0.059 (3)0.109 (4)0.001 (2)0.037 (3)0.008 (3)
C1130.069 (3)0.079 (4)0.101 (4)0.001 (3)0.034 (3)0.016 (3)
C1140.101 (5)0.102 (6)0.213 (8)0.014 (4)0.093 (5)0.035 (5)
C1210.045 (2)0.044 (2)0.063 (2)0.0027 (19)0.0061 (19)0.004 (2)
C1220.066 (3)0.056 (3)0.078 (3)0.016 (2)0.006 (2)0.004 (2)
C1230.076 (3)0.069 (4)0.076 (3)0.002 (3)0.017 (3)0.009 (3)
C1240.118 (5)0.098 (5)0.075 (3)0.015 (4)0.007 (3)0.013 (3)
C1310.057 (3)0.040 (3)0.064 (2)0.010 (2)0.004 (2)0.005 (2)
C1320.054 (3)0.059 (3)0.069 (3)0.010 (2)0.007 (2)0.003 (2)
C1330.065 (3)0.071 (4)0.075 (3)0.024 (3)0.007 (2)0.007 (3)
C1340.068 (3)0.120 (5)0.081 (3)0.031 (3)0.019 (3)0.009 (3)
C1410.053 (2)0.039 (2)0.065 (3)0.0022 (19)0.015 (2)0.000 (2)
C1420.068 (3)0.053 (3)0.062 (3)0.003 (2)0.013 (2)0.001 (2)
C1430.071 (3)0.067 (3)0.069 (3)0.003 (3)0.013 (2)0.009 (2)
C1440.098 (4)0.096 (5)0.078 (3)0.007 (3)0.004 (3)0.025 (3)
C2110.054 (3)0.063 (3)0.094 (3)0.000 (2)0.006 (2)0.002 (3)
C2120.091 (4)0.076 (4)0.109 (4)0.003 (3)0.032 (3)0.009 (3)
C2130.096 (5)0.099 (5)0.142 (6)0.024 (4)0.052 (4)0.004 (4)
C2140.098 (5)0.091 (5)0.229 (8)0.003 (4)0.067 (5)0.007 (6)
C2210.050 (2)0.057 (3)0.061 (2)0.003 (2)0.001 (2)0.000 (2)
C2220.050 (2)0.056 (3)0.070 (3)0.002 (2)0.010 (2)0.007 (2)
C2230.075 (3)0.072 (4)0.064 (3)0.010 (3)0.004 (2)0.011 (3)
C2240.095 (4)0.078 (4)0.095 (4)0.013 (3)0.024 (3)0.025 (3)
C2310.066 (3)0.049 (3)0.073 (3)0.000 (2)0.004 (2)0.006 (2)
C2320.058 (3)0.058 (3)0.094 (3)0.009 (2)0.003 (2)0.009 (3)
C2330.102 (4)0.067 (4)0.116 (4)0.016 (3)0.032 (3)0.011 (3)
C2340.073 (4)0.092 (5)0.152 (6)0.015 (3)0.015 (4)0.040 (4)
C2410.061 (3)0.051 (3)0.067 (3)0.000 (2)0.000 (2)0.006 (2)
C2420.087 (4)0.074 (4)0.072 (3)0.002 (3)0.005 (3)0.004 (3)
C2430.097 (4)0.101 (5)0.080 (4)0.014 (4)0.007 (3)0.007 (3)
C2440.110 (6)0.194 (9)0.096 (5)0.002 (6)0.030 (4)0.022 (5)
Geometric parameters (Å, º) top
Pd1—Br12.3982 (9)C142—H14F0.9700
Pd1—Br22.4181 (8)C142—H14G0.9700
Pd1—Br42.4435 (8)C143—C1441.513 (6)
Pd1—Br32.4513 (7)C143—H14H0.9700
Pd2—Br52.4158 (7)C143—H14I0.9700
Pd2—Br62.4185 (8)C144—H14A0.9600
Pd2—Br42.4389 (7)C144—H14B0.9600
Pd2—Br32.4396 (8)C144—H14C0.9600
N1—C1211.514 (5)C211—C2121.476 (7)
N1—C1411.519 (5)C211—H21D0.9700
N1—C1111.523 (5)C211—H21E0.9700
N1—C1311.527 (5)C212—C2131.579 (7)
N2—C2311.515 (5)C212—H21F0.9700
N2—C2211.517 (5)C212—H21G0.9700
N2—C2411.518 (5)C213—C2141.464 (8)
N2—C2111.524 (5)C213—H21H0.9700
C111—C1121.506 (6)C213—H21I0.9700
C111—H11D0.9700C214—H21A0.9600
C111—H11E0.9700C214—H21B0.9600
C112—C1131.512 (6)C214—H21C0.9600
C112—H11F0.9700C221—C2221.493 (6)
C112—H11G0.9700C221—H22D0.9700
C113—C1141.482 (7)C221—H22E0.9700
C113—H11H0.9700C222—C2231.510 (6)
C113—H11I0.9700C222—H22F0.9700
C114—H11A0.9600C222—H22G0.9700
C114—H11B0.9600C223—C2241.484 (7)
C114—H11C0.9600C223—H22H0.9700
C121—C1221.521 (6)C223—H22I0.9700
C121—H12D0.9700C224—H22A0.9600
C121—H12E0.9700C224—H22B0.9600
C122—C1231.529 (6)C224—H22C0.9600
C122—H12F0.9700C231—C2321.507 (6)
C122—H12G0.9700C231—H23D0.9700
C123—C1241.490 (7)C231—H23E0.9700
C123—H12H0.9700C232—C2331.498 (7)
C123—H12I0.9700C232—H23F0.9700
C124—H12A0.9600C232—H23G0.9700
C124—H12B0.9600C233—C2341.495 (7)
C124—H12C0.9600C233—H23H0.9700
C131—C1321.500 (6)C233—H23I0.9700
C131—H13D0.9700C234—H23A0.9600
C131—H13E0.9700C234—H23B0.9600
C132—C1331.514 (6)C234—H23C0.9600
C132—H13F0.9700C241—C2421.527 (6)
C132—H13G0.9700C241—H24D0.9700
C133—C1341.518 (7)C241—H24E0.9700
C133—H13H0.9700C242—C2431.515 (7)
C133—H13I0.9700C242—H24F0.9700
C134—H13A0.9600C242—H24G0.9700
C134—H13B0.9600C243—C2441.440 (8)
C134—H13C0.9600C243—H24H0.9700
C141—C1421.508 (5)C243—H24I0.9700
C141—H14D0.9700C244—H24A0.9600
C141—H14E0.9700C244—H24B0.9600
C142—C1431.515 (6)C244—H24C0.9600
Br1—Pd1—Br291.52 (3)H14F—C142—H14G108.1
Br1—Pd1—Br4175.62 (3)C144—C143—C142112.7 (4)
Br2—Pd1—Br491.92 (3)C144—C143—H14H109.0
Br1—Pd1—Br391.59 (3)C142—C143—H14H109.0
Br2—Pd1—Br3176.18 (3)C144—C143—H14I109.0
Br4—Pd1—Br385.08 (3)C142—C143—H14I109.0
Br5—Pd2—Br693.03 (3)H14H—C143—H14I107.8
Br5—Pd2—Br4176.15 (2)C143—C144—H14A109.5
Br6—Pd2—Br490.71 (3)C143—C144—H14B109.5
Br5—Pd2—Br390.82 (3)H14A—C144—H14B109.5
Br6—Pd2—Br3176.15 (2)C143—C144—H14C109.5
Br4—Pd2—Br385.43 (3)H14A—C144—H14C109.5
Pd2—Br3—Pd194.38 (3)H14B—C144—H14C109.5
Pd2—Br4—Pd194.59 (3)C212—C211—N2117.0 (4)
C121—N1—C141105.9 (3)C212—C211—H21D108.0
C121—N1—C111111.6 (3)N2—C211—H21D108.0
C141—N1—C111110.6 (3)C212—C211—H21E108.0
C121—N1—C131111.6 (3)N2—C211—H21E108.0
C141—N1—C131111.1 (3)H21D—C211—H21E107.3
C111—N1—C131106.1 (3)C211—C212—C213107.1 (5)
C231—N2—C221108.2 (3)C211—C212—H21F110.3
C231—N2—C241111.9 (3)C213—C212—H21F110.3
C221—N2—C241108.3 (3)C211—C212—H21G110.3
C231—N2—C211109.6 (3)C213—C212—H21G110.3
C221—N2—C211111.6 (3)H21F—C212—H21G108.5
C241—N2—C211107.2 (3)C214—C213—C212110.3 (6)
C112—C111—N1116.0 (4)C214—C213—H21H109.6
C112—C111—H11D108.3C212—C213—H21H109.6
N1—C111—H11D108.3C214—C213—H21I109.6
C112—C111—H11E108.3C212—C213—H21I109.6
N1—C111—H11E108.3H21H—C213—H21I108.1
H11D—C111—H11E107.4C213—C214—H21A109.5
C111—C112—C113110.7 (4)C213—C214—H21B109.5
C111—C112—H11F109.5H21A—C214—H21B109.5
C113—C112—H11F109.5C213—C214—H21C109.5
C111—C112—H11G109.5H21A—C214—H21C109.5
C113—C112—H11G109.5H21B—C214—H21C109.5
H11F—C112—H11G108.1C222—C221—N2117.5 (3)
C114—C113—C112113.0 (5)C222—C221—H22D107.9
C114—C113—H11H109.0N2—C221—H22D107.9
C112—C113—H11H109.0C222—C221—H22E107.9
C114—C113—H11I109.0N2—C221—H22E107.9
C112—C113—H11I109.0H22D—C221—H22E107.2
H11H—C113—H11I107.8C221—C222—C223111.1 (4)
C113—C114—H11A109.5C221—C222—H22F109.4
C113—C114—H11B109.5C223—C222—H22F109.4
H11A—C114—H11B109.5C221—C222—H22G109.4
C113—C114—H11C109.5C223—C222—H22G109.4
H11A—C114—H11C109.5H22F—C222—H22G108.0
H11B—C114—H11C109.5C224—C223—C222113.9 (4)
N1—C121—C122116.0 (3)C224—C223—H22H108.8
N1—C121—H12D108.3C222—C223—H22H108.8
C122—C121—H12D108.3C224—C223—H22I108.8
N1—C121—H12E108.3C222—C223—H22I108.8
C122—C121—H12E108.3H22H—C223—H22I107.7
H12D—C121—H12E107.4C223—C224—H22A109.5
C121—C122—C123110.9 (4)C223—C224—H22B109.5
C121—C122—H12F109.5H22A—C224—H22B109.5
C123—C122—H12F109.5C223—C224—H22C109.5
C121—C122—H12G109.5H22A—C224—H22C109.5
C123—C122—H12G109.5H22B—C224—H22C109.5
H12F—C122—H12G108.0C232—C231—N2116.1 (4)
C124—C123—C122113.7 (4)C232—C231—H23D108.3
C124—C123—H12H108.8N2—C231—H23D108.3
C122—C123—H12H108.8C232—C231—H23E108.3
C124—C123—H12I108.8N2—C231—H23E108.3
C122—C123—H12I108.8H23D—C231—H23E107.4
H12H—C123—H12I107.7C233—C232—C231111.9 (4)
C123—C124—H12A109.5C233—C232—H23F109.2
C123—C124—H12B109.5C231—C232—H23F109.2
H12A—C124—H12B109.5C233—C232—H23G109.2
C123—C124—H12C109.5C231—C232—H23G109.2
H12A—C124—H12C109.5H23F—C232—H23G107.9
H12B—C124—H12C109.5C234—C233—C232114.4 (5)
C132—C131—N1116.0 (3)C234—C233—H23H108.7
C132—C131—H13D108.3C232—C233—H23H108.7
N1—C131—H13D108.3C234—C233—H23I108.7
C132—C131—H13E108.3C232—C233—H23I108.7
N1—C131—H13E108.3H23H—C233—H23I107.6
H13D—C131—H13E107.4C233—C234—H23A109.5
C131—C132—C133110.5 (4)C233—C234—H23B109.5
C131—C132—H13F109.5H23A—C234—H23B109.5
C133—C132—H13F109.5C233—C234—H23C109.5
C131—C132—H13G109.5H23A—C234—H23C109.5
C133—C132—H13G109.5H23B—C234—H23C109.5
H13F—C132—H13G108.1N2—C241—C242115.6 (4)
C132—C133—C134112.7 (4)N2—C241—H24D108.4
C132—C133—H13H109.1C242—C241—H24D108.4
C134—C133—H13H109.1N2—C241—H24E108.4
C132—C133—H13I109.1C242—C241—H24E108.4
C134—C133—H13I109.1H24D—C241—H24E107.4
H13H—C133—H13I107.8C243—C242—C241110.9 (4)
C133—C134—H13A109.5C243—C242—H24F109.5
C133—C134—H13B109.5C241—C242—H24F109.5
H13A—C134—H13B109.5C243—C242—H24G109.5
C133—C134—H13C109.5C241—C242—H24G109.5
H13A—C134—H13C109.5H24F—C242—H24G108.1
H13B—C134—H13C109.5C244—C243—C242115.3 (5)
C142—C141—N1116.6 (3)C244—C243—H24H108.5
C142—C141—H14D108.2C242—C243—H24H108.5
N1—C141—H14D108.2C244—C243—H24I108.5
C142—C141—H14E108.2C242—C243—H24I108.5
N1—C141—H14E108.2H24H—C243—H24I107.5
H14D—C141—H14E107.3C243—C244—H24A109.5
C141—C142—C143110.1 (4)C243—C244—H24B109.5
C141—C142—H14F109.6H24A—C244—H24B109.5
C143—C142—H14F109.6C243—C244—H24C109.5
C141—C142—H14G109.6H24A—C244—H24C109.5
C143—C142—H14G109.6H24B—C244—H24C109.5
Br5—Pd2—Br3—Pd1173.68 (2)C131—C132—C133—C134179.7 (4)
Br6—Pd2—Br3—Pd15.2 (4)C121—N1—C141—C142178.5 (3)
Br4—Pd2—Br3—Pd15.43 (2)C111—N1—C141—C14260.4 (4)
Br1—Pd1—Br3—Pd2177.43 (2)C131—N1—C141—C14257.2 (5)
Br2—Pd1—Br3—Pd232.9 (4)N1—C141—C142—C143179.6 (3)
Br4—Pd1—Br3—Pd25.42 (2)C141—C142—C143—C144178.4 (4)
Br5—Pd2—Br4—Pd17.9 (4)C231—N2—C211—C21264.8 (5)
Br6—Pd2—Br4—Pd1174.53 (2)C221—N2—C211—C21255.0 (6)
Br3—Pd2—Br4—Pd15.45 (2)C241—N2—C211—C212173.5 (4)
Br1—Pd1—Br4—Pd246.1 (3)N2—C211—C212—C213176.9 (4)
Br2—Pd1—Br4—Pd2172.21 (3)C211—C212—C213—C214179.1 (6)
Br3—Pd1—Br4—Pd25.42 (2)C231—N2—C221—C222176.7 (4)
C121—N1—C111—C11259.2 (5)C241—N2—C221—C22261.8 (5)
C141—N1—C111—C11258.4 (5)C211—N2—C221—C22256.0 (5)
C131—N1—C111—C112179.1 (4)N2—C221—C222—C223178.8 (4)
N1—C111—C112—C113176.3 (4)C221—C222—C223—C224174.4 (4)
C111—C112—C113—C114178.6 (5)C221—N2—C231—C23266.8 (5)
C141—N1—C121—C122178.7 (4)C241—N2—C231—C23252.5 (5)
C111—N1—C121—C12260.9 (5)C211—N2—C231—C232171.3 (4)
C131—N1—C121—C12257.6 (5)N2—C231—C232—C233173.8 (4)
N1—C121—C122—C123174.3 (4)C231—C232—C233—C234178.0 (5)
C121—C122—C123—C12471.1 (6)C231—N2—C241—C24254.3 (5)
C121—N1—C131—C13256.9 (4)C221—N2—C241—C242173.5 (4)
C141—N1—C131—C13261.0 (4)C211—N2—C241—C24265.9 (5)
C111—N1—C131—C132178.7 (4)N2—C241—C242—C243176.9 (4)
N1—C131—C132—C133173.1 (3)C241—C242—C243—C24466.9 (7)
 

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