Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806040554/cv2130sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806040554/cv2130Isup2.hkl |
CCDC reference: 627472
Data collection: CAD-4 Software (Enraf-Nonius, 1989); cell refinement: CAD-4 Software; data reduction: NRCVAX (Gabe et al., 1989); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL-PC (Sheldrick, 1990); software used to prepare material for publication: WinGX (Farrugia, 1999).
[Co(C5H8N2)4(NCS)2] | F(000) = 2344 |
Mr = 559.65 | Dx = 1.316 Mg m−3 |
Orthorhombic, Pbca | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ac 2ab | Cell parameters from 25 reflections |
a = 16.096 (3) Å | θ = 4–14° |
b = 17.769 (4) Å | µ = 0.79 mm−1 |
c = 19.759 (4) Å | T = 293 K |
V = 5651 (2) Å3 | Block, pink |
Z = 8 | 0.30 × 0.20 × 0.10 mm |
Enraf-Nonius CAD-4 diffractometer | 2610 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.020 |
Graphite monochromator | θmax = 26.0°, θmin = 2.0° |
ω scans | h = 0→19 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = 0→21 |
Tmin = 0.828, Tmax = 0.924 | l = 0→24 |
5632 measured reflections | 3 standard reflections every 100 reflections |
5531 independent reflections | intensity decay: none |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.078 | H-atom parameters constrained |
wR(F2) = 0.195 | w = 1/[σ2(Fo2) + (0.0702P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.01 | (Δ/σ)max < 0.001 |
5531 reflections | Δρmax = 0.62 e Å−3 |
321 parameters | Δρmin = −0.42 e Å−3 |
0 restraints | Extinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.0016 (2) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Co | 0.27705 (5) | 0.21299 (4) | 0.70427 (4) | 0.0383 (3) | |
S1 | 0.12621 (14) | 0.40480 (12) | 0.57623 (11) | 0.0757 (7) | |
S2 | 0.35929 (14) | −0.01063 (11) | 0.81766 (12) | 0.0772 (7) | |
N1 | 0.1990 (4) | 0.2989 (3) | 0.6608 (3) | 0.0541 (16) | |
N2 | 0.3527 (3) | 0.1257 (3) | 0.7475 (3) | 0.0477 (14) | |
N3 | 0.2073 (3) | 0.2207 (3) | 0.7966 (3) | 0.0432 (13) | |
N4 | 0.1278 (3) | 0.2638 (3) | 0.8784 (3) | 0.0501 (15) | |
N5 | 0.1928 (3) | 0.1293 (3) | 0.6706 (3) | 0.0428 (13) | |
N6 | 0.1382 (4) | 0.0236 (3) | 0.6306 (3) | 0.0523 (15) | |
N7 | 0.3455 (3) | 0.2003 (3) | 0.6119 (3) | 0.0413 (13) | |
N8 | 0.3742 (4) | 0.2054 (3) | 0.5029 (3) | 0.0538 (15) | |
N9 | 0.3601 (3) | 0.2992 (3) | 0.7380 (3) | 0.0397 (13) | |
N10 | 0.4081 (4) | 0.4061 (3) | 0.7775 (3) | 0.0523 (15) | |
C1 | 0.1679 (4) | 0.3423 (4) | 0.6257 (3) | 0.0455 (17) | |
C2 | 0.3565 (4) | 0.0683 (4) | 0.7751 (3) | 0.0430 (16) | |
C3 | 0.1629 (4) | 0.2768 (4) | 0.8187 (3) | 0.0456 (17) | |
H3A | 0.1563 | 0.3216 | 0.7950 | 0.055* | |
C4 | 0.1518 (5) | 0.1916 (4) | 0.8978 (4) | 0.059 (2) | |
H4A | 0.1375 | 0.1663 | 0.9373 | 0.070* | |
C5 | 0.2004 (4) | 0.1663 (4) | 0.8467 (3) | 0.0523 (19) | |
H5A | 0.2256 | 0.1193 | 0.8453 | 0.063* | |
C6 | 0.0783 (5) | 0.3155 (4) | 0.9194 (4) | 0.067 (2) | |
H6A | 0.0278 | 0.2902 | 0.9334 | 0.080* | |
H6B | 0.0626 | 0.3583 | 0.8918 | 0.080* | |
C7 | 0.1228 (7) | 0.3430 (5) | 0.9806 (5) | 0.118 (4) | |
H7A | 0.0885 | 0.3786 | 1.0041 | 0.178* | |
H7B | 0.1738 | 0.3668 | 0.9672 | 0.178* | |
H7C | 0.1348 | 0.3013 | 1.0099 | 0.178* | |
C8 | 0.2081 (4) | 0.0611 (4) | 0.6461 (3) | 0.0490 (18) | |
H8A | 0.2613 | 0.0415 | 0.6403 | 0.059* | |
C9 | 0.0746 (4) | 0.0685 (4) | 0.6460 (4) | 0.056 (2) | |
H9A | 0.0184 | 0.0578 | 0.6412 | 0.067* | |
C10 | 0.1085 (4) | 0.1333 (4) | 0.6703 (3) | 0.0510 (18) | |
H10A | 0.0780 | 0.1748 | 0.6847 | 0.061* | |
C11 | 0.1343 (6) | −0.0532 (4) | 0.6009 (5) | 0.080 (3) | |
H11A | 0.1853 | −0.0798 | 0.6117 | 0.096* | |
H11B | 0.0886 | −0.0805 | 0.6214 | 0.096* | |
C12 | 0.1234 (9) | −0.0524 (5) | 0.5288 (5) | 0.170 (7) | |
H12A | 0.1103 | −0.1022 | 0.5134 | 0.255* | |
H12B | 0.1737 | −0.0355 | 0.5076 | 0.255* | |
H12C | 0.0787 | −0.0189 | 0.5173 | 0.255* | |
C13 | 0.3268 (4) | 0.2307 (4) | 0.5529 (3) | 0.0506 (19) | |
H13A | 0.2848 | 0.2661 | 0.5469 | 0.061* | |
C14 | 0.4281 (5) | 0.1563 (4) | 0.5311 (4) | 0.061 (2) | |
H14A | 0.4700 | 0.1298 | 0.5090 | 0.074* | |
C15 | 0.4093 (5) | 0.1532 (4) | 0.5976 (4) | 0.063 (2) | |
H15A | 0.4362 | 0.1231 | 0.6291 | 0.075* | |
C16 | 0.3671 (6) | 0.2276 (5) | 0.4307 (4) | 0.081 (3) | |
H16A | 0.3683 | 0.1827 | 0.4028 | 0.097* | |
H16B | 0.3140 | 0.2521 | 0.4237 | 0.097* | |
C17 | 0.4336 (7) | 0.2784 (5) | 0.4088 (4) | 0.111 (4) | |
H17A | 0.4244 | 0.2929 | 0.3627 | 0.166* | |
H17B | 0.4861 | 0.2531 | 0.4125 | 0.166* | |
H17C | 0.4339 | 0.3223 | 0.4370 | 0.166* | |
C18 | 0.3402 (4) | 0.3679 (4) | 0.7597 (3) | 0.0515 (18) | |
H18A | 0.2864 | 0.3866 | 0.7621 | 0.062* | |
C19 | 0.4756 (5) | 0.3609 (4) | 0.7685 (4) | 0.061 (2) | |
H19A | 0.5308 | 0.3719 | 0.7782 | 0.073* | |
C20 | 0.4442 (4) | 0.2964 (4) | 0.7423 (3) | 0.0506 (18) | |
H20A | 0.4763 | 0.2555 | 0.7290 | 0.061* | |
C21 | 0.4093 (6) | 0.4836 (4) | 0.8068 (4) | 0.077 (3) | |
H21A | 0.4605 | 0.5084 | 0.7935 | 0.092* | |
H21B | 0.3635 | 0.5123 | 0.7880 | 0.092* | |
C22 | 0.4029 (6) | 0.4843 (4) | 0.8811 (4) | 0.096 (3) | |
H22A | 0.4063 | 0.5352 | 0.8972 | 0.144* | |
H22B | 0.4476 | 0.4554 | 0.9001 | 0.144* | |
H22C | 0.3508 | 0.4628 | 0.8945 | 0.144* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Co | 0.0474 (5) | 0.0302 (4) | 0.0373 (5) | 0.0014 (4) | 0.0037 (4) | 0.0015 (4) |
S1 | 0.0902 (16) | 0.0679 (14) | 0.0691 (14) | 0.0140 (13) | −0.0206 (13) | 0.0183 (11) |
S2 | 0.0860 (16) | 0.0388 (11) | 0.1067 (18) | −0.0030 (11) | −0.0113 (14) | 0.0265 (11) |
N1 | 0.067 (4) | 0.049 (4) | 0.046 (3) | 0.003 (3) | 0.000 (3) | 0.009 (3) |
N2 | 0.056 (4) | 0.041 (3) | 0.046 (3) | 0.002 (3) | −0.001 (3) | 0.009 (3) |
N3 | 0.053 (3) | 0.030 (3) | 0.046 (3) | 0.005 (3) | 0.012 (3) | −0.003 (3) |
N4 | 0.064 (4) | 0.039 (3) | 0.048 (3) | 0.001 (3) | 0.013 (3) | −0.003 (3) |
N5 | 0.042 (3) | 0.044 (3) | 0.043 (3) | −0.008 (3) | −0.003 (3) | −0.007 (3) |
N6 | 0.056 (4) | 0.040 (3) | 0.061 (4) | −0.010 (3) | −0.008 (3) | −0.006 (3) |
N7 | 0.044 (3) | 0.039 (3) | 0.042 (3) | 0.007 (3) | 0.004 (3) | −0.002 (3) |
N8 | 0.069 (4) | 0.057 (4) | 0.036 (3) | −0.002 (3) | 0.003 (3) | −0.005 (3) |
N9 | 0.044 (3) | 0.032 (3) | 0.043 (3) | 0.001 (3) | 0.002 (3) | 0.003 (3) |
N10 | 0.069 (4) | 0.038 (3) | 0.051 (4) | −0.010 (3) | −0.006 (3) | 0.001 (3) |
C1 | 0.060 (5) | 0.041 (4) | 0.035 (4) | −0.007 (4) | 0.000 (4) | −0.003 (3) |
C2 | 0.048 (4) | 0.033 (3) | 0.048 (4) | 0.001 (3) | −0.008 (3) | −0.002 (3) |
C3 | 0.055 (4) | 0.037 (4) | 0.046 (4) | −0.009 (3) | 0.011 (3) | 0.002 (3) |
C4 | 0.090 (6) | 0.031 (4) | 0.055 (5) | 0.002 (4) | 0.025 (4) | 0.010 (3) |
C5 | 0.067 (5) | 0.029 (4) | 0.061 (5) | 0.004 (3) | 0.019 (4) | 0.003 (3) |
C6 | 0.082 (6) | 0.050 (5) | 0.067 (5) | 0.016 (4) | 0.031 (5) | −0.004 (4) |
C7 | 0.167 (10) | 0.097 (8) | 0.092 (7) | 0.017 (7) | 0.028 (7) | −0.050 (6) |
C8 | 0.052 (5) | 0.047 (4) | 0.048 (4) | 0.004 (4) | −0.003 (4) | 0.000 (3) |
C9 | 0.040 (4) | 0.064 (5) | 0.065 (5) | −0.008 (4) | −0.005 (4) | 0.011 (4) |
C10 | 0.047 (4) | 0.048 (4) | 0.058 (5) | 0.001 (4) | 0.000 (4) | −0.002 (4) |
C11 | 0.099 (7) | 0.038 (4) | 0.104 (7) | −0.005 (5) | −0.027 (6) | −0.002 (5) |
C12 | 0.348 (19) | 0.058 (6) | 0.105 (8) | 0.025 (9) | −0.115 (11) | −0.033 (6) |
C13 | 0.053 (4) | 0.054 (5) | 0.044 (4) | 0.007 (4) | 0.005 (4) | 0.000 (4) |
C14 | 0.066 (5) | 0.071 (5) | 0.047 (5) | 0.015 (4) | 0.009 (4) | −0.007 (4) |
C15 | 0.068 (5) | 0.058 (5) | 0.062 (5) | 0.017 (4) | 0.006 (4) | 0.006 (4) |
C16 | 0.107 (7) | 0.099 (7) | 0.037 (4) | −0.009 (6) | −0.004 (5) | −0.004 (5) |
C17 | 0.170 (10) | 0.110 (8) | 0.052 (6) | −0.036 (8) | 0.025 (6) | 0.007 (6) |
C18 | 0.049 (4) | 0.043 (4) | 0.062 (5) | 0.000 (4) | 0.000 (4) | 0.011 (4) |
C19 | 0.058 (5) | 0.053 (5) | 0.072 (6) | −0.014 (4) | −0.013 (4) | −0.003 (4) |
C20 | 0.047 (4) | 0.049 (4) | 0.056 (4) | 0.007 (4) | 0.002 (4) | −0.001 (4) |
C21 | 0.109 (7) | 0.035 (4) | 0.085 (6) | −0.005 (5) | −0.011 (5) | −0.011 (4) |
C22 | 0.165 (10) | 0.047 (5) | 0.077 (6) | 0.025 (6) | −0.033 (7) | −0.018 (5) |
Co—N5 | 2.119 (5) | C6—H6A | 0.9700 |
Co—N9 | 2.140 (5) | C6—H6B | 0.9700 |
Co—N7 | 2.143 (5) | C7—H7A | 0.9600 |
Co—N3 | 2.147 (5) | C7—H7B | 0.9600 |
Co—N2 | 2.148 (5) | C7—H7C | 0.9600 |
Co—N1 | 2.156 (6) | C8—H8A | 0.9300 |
S1—C1 | 1.625 (7) | C9—C10 | 1.362 (9) |
S2—C2 | 1.636 (7) | C9—H9A | 0.9300 |
N1—C1 | 1.152 (7) | C10—H10A | 0.9300 |
N2—C2 | 1.159 (7) | C11—C12 | 1.435 (11) |
N3—C3 | 1.302 (7) | C11—H11A | 0.9700 |
N3—C5 | 1.387 (7) | C11—H11B | 0.9700 |
N4—C3 | 1.328 (8) | C12—H12A | 0.9600 |
N4—C4 | 1.393 (8) | C12—H12B | 0.9600 |
N4—C6 | 1.460 (8) | C12—H12C | 0.9600 |
N5—C8 | 1.329 (8) | C13—H13A | 0.9300 |
N5—C10 | 1.358 (8) | C14—C15 | 1.349 (9) |
N6—C9 | 1.333 (8) | C14—H14A | 0.9300 |
N6—C8 | 1.344 (8) | C15—H15A | 0.9300 |
N6—C11 | 1.486 (8) | C16—C17 | 1.465 (11) |
N7—C13 | 1.319 (8) | C16—H16A | 0.9700 |
N7—C15 | 1.355 (8) | C16—H16B | 0.9700 |
N8—C13 | 1.327 (8) | C17—H17A | 0.9600 |
N8—C14 | 1.351 (8) | C17—H17B | 0.9600 |
N8—C16 | 1.485 (8) | C17—H17C | 0.9600 |
N9—C18 | 1.332 (7) | C18—H18A | 0.9300 |
N9—C20 | 1.357 (7) | C19—C20 | 1.355 (9) |
N10—C18 | 1.334 (8) | C19—H19A | 0.9300 |
N10—C19 | 1.362 (8) | C20—H20A | 0.9300 |
N10—C21 | 1.494 (8) | C21—C22 | 1.472 (10) |
C3—H3A | 0.9300 | C21—H21A | 0.9700 |
C4—C5 | 1.354 (8) | C21—H21B | 0.9700 |
C4—H4A | 0.9300 | C22—H22A | 0.9600 |
C5—H5A | 0.9300 | C22—H22B | 0.9600 |
C6—C7 | 1.487 (11) | C22—H22C | 0.9600 |
N5—Co—N9 | 178.8 (2) | N5—C8—N6 | 112.3 (6) |
N5—Co—N7 | 89.33 (19) | N5—C8—H8A | 123.9 |
N9—Co—N7 | 91.10 (19) | N6—C8—H8A | 123.9 |
N5—Co—N3 | 88.66 (19) | N6—C9—C10 | 106.3 (6) |
N9—Co—N3 | 90.94 (19) | N6—C9—H9A | 126.9 |
N7—Co—N3 | 177.59 (19) | C10—C9—H9A | 126.9 |
N5—Co—N2 | 88.9 (2) | N5—C10—C9 | 111.0 (6) |
N9—Co—N2 | 92.23 (19) | N5—C10—H10A | 124.5 |
N7—Co—N2 | 88.4 (2) | C9—C10—H10A | 124.5 |
N3—Co—N2 | 90.3 (2) | C12—C11—N6 | 112.7 (7) |
N5—Co—N1 | 89.9 (2) | C12—C11—H11A | 109.0 |
N9—Co—N1 | 88.9 (2) | N6—C11—H11A | 109.0 |
N7—Co—N1 | 92.0 (2) | C12—C11—H11B | 109.0 |
N3—Co—N1 | 89.3 (2) | N6—C11—H11B | 109.0 |
N2—Co—N1 | 178.8 (2) | H11A—C11—H11B | 107.8 |
C1—N1—Co | 165.4 (6) | C11—C12—H12A | 109.5 |
C2—N2—Co | 148.5 (5) | C11—C12—H12B | 109.5 |
C3—N3—C5 | 104.5 (5) | H12A—C12—H12B | 109.5 |
C3—N3—Co | 128.4 (4) | C11—C12—H12C | 109.5 |
C5—N3—Co | 127.1 (4) | H12A—C12—H12C | 109.5 |
C3—N4—C4 | 106.6 (6) | H12B—C12—H12C | 109.5 |
C3—N4—C6 | 128.0 (6) | N7—C13—N8 | 112.8 (6) |
C4—N4—C6 | 125.3 (6) | N7—C13—H13A | 123.6 |
C8—N5—C10 | 103.4 (6) | N8—C13—H13A | 123.6 |
C8—N5—Co | 129.4 (5) | C15—C14—N8 | 106.4 (7) |
C10—N5—Co | 127.2 (5) | C15—C14—H14A | 126.8 |
C9—N6—C8 | 107.1 (6) | N8—C14—H14A | 126.8 |
C9—N6—C11 | 127.5 (6) | C14—C15—N7 | 110.5 (7) |
C8—N6—C11 | 125.4 (7) | C14—C15—H15A | 124.8 |
C13—N7—C15 | 103.9 (6) | N7—C15—H15A | 124.8 |
C13—N7—Co | 126.3 (4) | C17—C16—N8 | 113.0 (7) |
C15—N7—Co | 129.2 (5) | C17—C16—H16A | 109.0 |
C13—N8—C14 | 106.4 (6) | N8—C16—H16A | 109.0 |
C13—N8—C16 | 125.5 (7) | C17—C16—H16B | 109.0 |
C14—N8—C16 | 128.1 (6) | N8—C16—H16B | 109.0 |
C18—N9—C20 | 104.6 (6) | H16A—C16—H16B | 107.8 |
C18—N9—Co | 127.3 (5) | C16—C17—H17A | 109.5 |
C20—N9—Co | 128.1 (4) | C16—C17—H17B | 109.5 |
C18—N10—C19 | 108.5 (6) | H17A—C17—H17B | 109.5 |
C18—N10—C21 | 125.6 (7) | C16—C17—H17C | 109.5 |
C19—N10—C21 | 125.7 (6) | H17A—C17—H17C | 109.5 |
N1—C1—S1 | 178.5 (7) | H17B—C17—H17C | 109.5 |
N2—C2—S2 | 176.8 (6) | N9—C18—N10 | 110.8 (6) |
N3—C3—N4 | 113.5 (6) | N9—C18—H18A | 124.6 |
N3—C3—H3A | 123.3 | N10—C18—H18A | 124.6 |
N4—C3—H3A | 123.3 | C20—C19—N10 | 104.6 (6) |
C5—C4—N4 | 105.1 (6) | C20—C19—H19A | 127.7 |
C5—C4—H4A | 127.4 | N10—C19—H19A | 127.7 |
N4—C4—H4A | 127.4 | C19—C20—N9 | 111.4 (6) |
C4—C5—N3 | 110.3 (6) | C19—C20—H20A | 124.3 |
C4—C5—H5A | 124.9 | N9—C20—H20A | 124.3 |
N3—C5—H5A | 124.9 | C22—C21—N10 | 113.2 (6) |
N4—C6—C7 | 113.3 (7) | C22—C21—H21A | 108.9 |
N4—C6—H6A | 108.9 | N10—C21—H21A | 108.9 |
C7—C6—H6A | 108.9 | C22—C21—H21B | 108.9 |
N4—C6—H6B | 108.9 | N10—C21—H21B | 108.9 |
C7—C6—H6B | 108.9 | H21A—C21—H21B | 107.8 |
H6A—C6—H6B | 107.7 | C21—C22—H22A | 109.5 |
C6—C7—H7A | 109.5 | C21—C22—H22B | 109.5 |
C6—C7—H7B | 109.5 | H22A—C22—H22B | 109.5 |
H7A—C7—H7B | 109.5 | C21—C22—H22C | 109.5 |
C6—C7—H7C | 109.5 | H22A—C22—H22C | 109.5 |
H7A—C7—H7C | 109.5 | H22B—C22—H22C | 109.5 |
H7B—C7—H7C | 109.5 | ||
N5—Co—N1—C1 | −91 (2) | C4—N4—C3—N3 | 0.2 (8) |
N9—Co—N1—C1 | 90 (2) | C6—N4—C3—N3 | 176.1 (7) |
N7—Co—N1—C1 | −1 (2) | C3—N4—C4—C5 | −0.2 (8) |
N3—Co—N1—C1 | −179 (2) | C6—N4—C4—C5 | −176.3 (7) |
N5—Co—N2—C2 | −36.5 (10) | N4—C4—C5—N3 | 0.2 (8) |
N9—Co—N2—C2 | 143.1 (10) | C3—N3—C5—C4 | −0.1 (8) |
N7—Co—N2—C2 | −125.8 (10) | Co—N3—C5—C4 | 179.4 (5) |
N3—Co—N2—C2 | 52.2 (10) | C3—N4—C6—C7 | −107.4 (9) |
N5—Co—N3—C3 | −112.9 (6) | C4—N4—C6—C7 | 67.9 (10) |
N9—Co—N3—C3 | 66.0 (6) | C10—N5—C8—N6 | 0.3 (7) |
N2—Co—N3—C3 | 158.2 (6) | Co—N5—C8—N6 | 179.4 (4) |
N1—Co—N3—C3 | −22.9 (6) | C9—N6—C8—N5 | −0.6 (8) |
N5—Co—N3—C5 | 67.8 (5) | C11—N6—C8—N5 | 178.7 (6) |
N9—Co—N3—C5 | −113.4 (5) | C8—N6—C9—C10 | 0.5 (8) |
N2—Co—N3—C5 | −21.2 (5) | C11—N6—C9—C10 | −178.7 (7) |
N1—Co—N3—C5 | 157.7 (5) | C8—N5—C10—C9 | 0.0 (8) |
N7—Co—N5—C8 | 50.2 (6) | Co—N5—C10—C9 | −179.1 (4) |
N3—Co—N5—C8 | −128.5 (6) | N6—C9—C10—N5 | −0.4 (8) |
N2—Co—N5—C8 | −38.2 (6) | C9—N6—C11—C12 | 81.5 (11) |
N1—Co—N5—C8 | 142.2 (6) | C8—N6—C11—C12 | −97.7 (10) |
N7—Co—N5—C10 | −130.9 (6) | C15—N7—C13—N8 | 0.4 (8) |
N3—Co—N5—C10 | 50.4 (6) | Co—N7—C13—N8 | −171.9 (4) |
N2—Co—N5—C10 | 140.7 (6) | C14—N8—C13—N7 | −0.9 (8) |
N1—Co—N5—C10 | −38.9 (6) | C16—N8—C13—N7 | 178.6 (6) |
N5—Co—N7—C13 | 80.8 (6) | C13—N8—C14—C15 | 1.1 (8) |
N9—Co—N7—C13 | −98.1 (6) | C16—N8—C14—C15 | −178.4 (7) |
N2—Co—N7—C13 | 169.7 (6) | N8—C14—C15—N7 | −1.0 (9) |
N1—Co—N7—C13 | −9.1 (6) | C13—N7—C15—C14 | 0.4 (8) |
N5—Co—N7—C15 | −89.6 (6) | Co—N7—C15—C14 | 172.4 (5) |
N9—Co—N7—C15 | 91.6 (6) | C13—N8—C16—C17 | 105.9 (9) |
N2—Co—N7—C15 | −0.6 (6) | C14—N8—C16—C17 | −74.7 (10) |
N1—Co—N7—C15 | −179.5 (6) | C20—N9—C18—N10 | −0.7 (7) |
N7—Co—N9—C18 | 127.3 (5) | Co—N9—C18—N10 | 179.2 (4) |
N3—Co—N9—C18 | −54.0 (5) | C19—N10—C18—N9 | −1.2 (8) |
N2—Co—N9—C18 | −144.3 (5) | C21—N10—C18—N9 | −177.2 (6) |
N1—Co—N9—C18 | 35.3 (5) | C18—N10—C19—C20 | 2.4 (8) |
N7—Co—N9—C20 | −52.9 (5) | C21—N10—C19—C20 | 178.5 (6) |
N3—Co—N9—C20 | 125.8 (5) | N10—C19—C20—N9 | −2.9 (8) |
N2—Co—N9—C20 | 35.5 (6) | C18—N9—C20—C19 | 2.3 (8) |
N1—Co—N9—C20 | −144.9 (6) | Co—N9—C20—C19 | −177.6 (5) |
C5—N3—C3—N4 | 0.0 (7) | C18—N10—C21—C22 | 88.5 (9) |
Co—N3—C3—N4 | −179.5 (4) | C19—N10—C21—C22 | −86.9 (10) |