Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229616006859/yp3115sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S2053229616006859/yp3115Isup2.hkl | |
Portable Document Format (PDF) file https://doi.org/10.1107/S2053229616006859/yp3115sup3.pdf |
CCDC reference: 1451243
Data collection: APEX2 (Bruker, 2012); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL2012 (Sheldrick, 2015); molecular graphics: SHELXTL (Sheldrick, 2008b); software used to prepare material for publication: SHELXTL (Sheldrick, 2008b).
[Rh(C15H22BN6)(C5H9N)(C3H9P)] | F(000) = 584 |
Mr = 559.31 | Dx = 1.377 Mg m−3 |
Monoclinic, P21 | Mo Kα radiation, λ = 0.71073 Å |
a = 8.4544 (8) Å | Cell parameters from 4074 reflections |
b = 15.0084 (14) Å | θ = 2.4–27.9° |
c = 10.6904 (10) Å | µ = 0.72 mm−1 |
β = 95.975 (2)° | T = 100 K |
V = 1349.1 (2) Å3 | Needle, yellow |
Z = 2 | 0.18 × 0.16 × 0.10 mm |
Bruker SMART APEXII CCD Platform diffractometer | 12861 independent reflections |
Radiation source: fine-focus sealed tube | 9022 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.088 |
ω scans | θmax = 36.3°, θmin = 1.9° |
Absorption correction: multi-scan (SADABS; Sheldrick, 2008a) | h = −14→14 |
Tmin = 0.697, Tmax = 0.747 | k = −24→24 |
36418 measured reflections | l = −17→17 |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: mixed |
R[F2 > 2σ(F2)] = 0.053 | H atoms treated by a mixture of independent and constrained refinement |
wR(F2) = 0.096 | w = 1/[σ2(Fo2) + (0.0278P)2] where P = (Fo2 + 2Fc2)/3 |
S = 0.99 | (Δ/σ)max = 0.001 |
12861 reflections | Δρmax = 1.25 e Å−3 |
313 parameters | Δρmin = −1.02 e Å−3 |
1 restraint | Absolute structure: Refined as an inversion twin. |
Primary atom site location: difference Fourier map | Absolute structure parameter: 0.05 (3) |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
Refinement. Refined as a 2-component racemic twin (95:05). The borohydride hydrogen atom was found from the difference Fourier map and refined freely. |
x | y | z | Uiso*/Ueq | ||
Rh1 | 0.54121 (3) | 0.29151 (2) | 0.19412 (3) | 0.01279 (6) | |
P1 | 0.62592 (10) | 0.29078 (15) | 0.39694 (8) | 0.01597 (18) | |
N1 | 0.3661 (4) | 0.3823 (3) | 0.2105 (3) | 0.0152 (7) | |
N2 | 0.2113 (4) | 0.3587 (3) | 0.1738 (3) | 0.0134 (7) | |
N3 | 0.4300 (4) | 0.2737 (2) | 0.0110 (3) | 0.0146 (9) | |
N4 | 0.2686 (4) | 0.2579 (2) | −0.0015 (3) | 0.0133 (7) | |
N5 | 0.1479 (4) | 0.2047 (3) | 0.3221 (3) | 0.0171 (7) | |
N6 | 0.2036 (4) | 0.1921 (3) | 0.2080 (3) | 0.0135 (7) | |
B1 | 0.1715 (5) | 0.2677 (3) | 0.1112 (4) | 0.0136 (9) | |
H1 | 0.045 (5) | 0.270 (3) | 0.077 (4) | 0.014 (12)* | |
C1 | 0.3653 (5) | 0.4672 (3) | 0.2464 (4) | 0.0179 (9) | |
C2 | 0.2099 (6) | 0.4993 (3) | 0.2365 (4) | 0.0179 (9) | |
H2 | 0.1760 | 0.5572 | 0.2579 | 0.021* | |
C3 | 0.1149 (5) | 0.4291 (3) | 0.1891 (4) | 0.0164 (8) | |
C4 | 0.4788 (5) | 0.2620 (3) | −0.1021 (4) | 0.0150 (8) | |
C5 | 0.3501 (5) | 0.2392 (3) | −0.1891 (4) | 0.0163 (8) | |
H5 | 0.3525 | 0.2271 | −0.2761 | 0.020* | |
C6 | 0.2198 (5) | 0.2378 (3) | −0.1228 (4) | 0.0153 (8) | |
C7 | 0.1777 (5) | 0.1299 (3) | 0.3865 (4) | 0.0170 (9) | |
C8 | 0.2532 (5) | 0.0677 (3) | 0.3156 (4) | 0.0188 (9) | |
H8 | 0.2868 | 0.0093 | 0.3402 | 0.023* | |
C9 | 0.2687 (5) | 0.1092 (3) | 0.2019 (4) | 0.0161 (8) | |
C10 | 0.5160 (6) | 0.5158 (3) | 0.2847 (5) | 0.0237 (10) | |
H10A | 0.6065 | 0.4757 | 0.2788 | 0.036* | |
H10B | 0.5161 | 0.5366 | 0.3716 | 0.036* | |
H10C | 0.5247 | 0.5670 | 0.2289 | 0.036* | |
C11 | −0.0614 (5) | 0.4267 (3) | 0.1542 (5) | 0.0226 (10) | |
H11A | −0.1055 | 0.3730 | 0.1894 | 0.034* | |
H11B | −0.0839 | 0.4260 | 0.0624 | 0.034* | |
H11C | −0.1100 | 0.4796 | 0.1880 | 0.034* | |
C12 | 0.6488 (5) | 0.2760 (3) | −0.1241 (4) | 0.0194 (12) | |
H12A | 0.7093 | 0.2959 | −0.0459 | 0.029* | |
H12B | 0.6551 | 0.3213 | −0.1894 | 0.029* | |
H12C | 0.6935 | 0.2199 | −0.1514 | 0.029* | |
C13 | 0.0498 (5) | 0.2184 (3) | −0.1673 (4) | 0.0216 (10) | |
H13A | 0.0111 | 0.1702 | −0.1169 | 0.032* | |
H13B | 0.0412 | 0.2005 | −0.2559 | 0.032* | |
H13C | −0.0143 | 0.2720 | −0.1584 | 0.032* | |
C14 | 0.1313 (6) | 0.1221 (4) | 0.5176 (4) | 0.0253 (11) | |
H14A | 0.0804 | 0.1776 | 0.5406 | 0.038* | |
H14B | 0.2263 | 0.1112 | 0.5762 | 0.038* | |
H14C | 0.0567 | 0.0725 | 0.5217 | 0.038* | |
C15 | 0.3348 (5) | 0.0712 (3) | 0.0891 (4) | 0.0184 (9) | |
H15A | 0.2545 | 0.0749 | 0.0162 | 0.028* | |
H15B | 0.3638 | 0.0087 | 0.1050 | 0.028* | |
H15C | 0.4293 | 0.1050 | 0.0720 | 0.028* | |
N7 | 0.7006 (4) | 0.2004 (3) | 0.1645 (3) | 0.0155 (7) | |
C16 | 0.7795 (5) | 0.1432 (3) | 0.1411 (4) | 0.0174 (9) | |
C17 | 0.8701 (5) | 0.0629 (3) | 0.1141 (4) | 0.0203 (9) | |
H17A | 0.9657 | 0.0581 | 0.1756 | 0.024* | |
H17B | 0.9056 | 0.0676 | 0.0290 | 0.024* | |
C18 | 0.7669 (6) | −0.0202 (3) | 0.1216 (5) | 0.0228 (10) | |
H18A | 0.6748 | −0.0162 | 0.0566 | 0.027* | |
H18B | 0.8297 | −0.0733 | 0.1028 | 0.027* | |
C19 | 0.7058 (6) | −0.0326 (3) | 0.2501 (4) | 0.0217 (10) | |
H19A | 0.6263 | −0.0812 | 0.2442 | 0.026* | |
H19B | 0.6514 | 0.0227 | 0.2723 | 0.026* | |
C20 | 0.8370 (6) | −0.0544 (4) | 0.3549 (5) | 0.0321 (13) | |
H20A | 0.7913 | −0.0582 | 0.4353 | 0.048* | |
H20B | 0.9180 | −0.0075 | 0.3596 | 0.048* | |
H20C | 0.8858 | −0.1116 | 0.3370 | 0.048* | |
C21 | 0.6523 (7) | 0.1787 (3) | 0.4612 (4) | 0.0265 (11) | |
H21B | 0.6829 | 0.1822 | 0.5521 | 0.040* | |
H21C | 0.7359 | 0.1480 | 0.4209 | 0.040* | |
H21D | 0.5524 | 0.1456 | 0.4453 | 0.040* | |
C22 | 0.8158 (6) | 0.3405 (4) | 0.4571 (5) | 0.0265 (11) | |
H22A | 0.8322 | 0.3331 | 0.5486 | 0.040* | |
H22D | 0.8149 | 0.4041 | 0.4363 | 0.040* | |
H22B | 0.9021 | 0.3110 | 0.4186 | 0.040* | |
C23 | 0.4891 (6) | 0.3367 (4) | 0.5005 (5) | 0.0264 (11) | |
H23D | 0.5265 | 0.3221 | 0.5879 | 0.040* | |
H23A | 0.3830 | 0.3113 | 0.4789 | 0.040* | |
H23B | 0.4842 | 0.4016 | 0.4905 | 0.040* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Rh1 | 0.01127 (11) | 0.01270 (12) | 0.01410 (11) | 0.0004 (2) | −0.00014 (8) | −0.0007 (2) |
P1 | 0.0157 (4) | 0.0171 (4) | 0.0146 (4) | −0.0007 (9) | −0.0008 (3) | −0.0004 (9) |
N1 | 0.0128 (16) | 0.0155 (19) | 0.0172 (17) | 0.0002 (14) | 0.0007 (13) | −0.0003 (14) |
N2 | 0.0102 (16) | 0.0153 (19) | 0.0152 (17) | 0.0005 (14) | 0.0032 (13) | −0.0014 (14) |
N3 | 0.0117 (14) | 0.016 (3) | 0.0159 (15) | 0.0010 (12) | 0.0004 (11) | −0.0009 (12) |
N4 | 0.0099 (15) | 0.0144 (16) | 0.0154 (16) | −0.0023 (12) | 0.0008 (12) | −0.0001 (12) |
N5 | 0.0174 (18) | 0.0188 (19) | 0.0152 (17) | −0.0001 (15) | 0.0023 (14) | 0.0000 (14) |
N6 | 0.0145 (17) | 0.0137 (19) | 0.0127 (17) | −0.0021 (15) | 0.0031 (13) | −0.0004 (14) |
B1 | 0.0112 (19) | 0.013 (2) | 0.017 (2) | −0.0015 (15) | 0.0028 (16) | −0.0012 (15) |
C1 | 0.021 (2) | 0.014 (2) | 0.018 (2) | −0.0005 (17) | 0.0000 (17) | −0.0005 (16) |
C2 | 0.020 (2) | 0.010 (2) | 0.024 (2) | 0.0044 (17) | 0.0045 (18) | 0.0004 (17) |
C3 | 0.015 (2) | 0.016 (2) | 0.018 (2) | 0.0033 (17) | 0.0034 (16) | 0.0023 (16) |
C4 | 0.0121 (18) | 0.0151 (19) | 0.0175 (19) | −0.0002 (14) | 0.0003 (15) | 0.0018 (14) |
C5 | 0.016 (2) | 0.018 (2) | 0.0146 (19) | −0.0006 (17) | 0.0012 (15) | −0.0008 (16) |
C6 | 0.018 (2) | 0.013 (2) | 0.0141 (18) | −0.0020 (16) | −0.0016 (15) | −0.0007 (15) |
C7 | 0.016 (2) | 0.019 (2) | 0.0153 (19) | −0.0017 (17) | 0.0000 (15) | 0.0024 (16) |
C8 | 0.017 (2) | 0.017 (2) | 0.022 (2) | −0.0006 (17) | −0.0013 (17) | 0.0047 (18) |
C9 | 0.013 (2) | 0.012 (2) | 0.022 (2) | −0.0027 (16) | −0.0017 (17) | −0.0010 (17) |
C10 | 0.022 (2) | 0.015 (2) | 0.033 (3) | −0.0024 (18) | −0.001 (2) | −0.0050 (19) |
C11 | 0.014 (2) | 0.022 (2) | 0.032 (3) | 0.0043 (18) | 0.0029 (18) | 0.002 (2) |
C12 | 0.0152 (17) | 0.023 (4) | 0.0200 (18) | −0.0018 (17) | 0.0027 (14) | 0.0004 (17) |
C13 | 0.017 (2) | 0.031 (3) | 0.016 (2) | −0.0037 (19) | −0.0017 (16) | −0.0051 (19) |
C14 | 0.029 (3) | 0.029 (3) | 0.017 (2) | −0.001 (2) | 0.0012 (19) | 0.0035 (19) |
C15 | 0.020 (2) | 0.012 (2) | 0.024 (2) | 0.0011 (17) | 0.0057 (17) | −0.0025 (17) |
N7 | 0.0137 (17) | 0.0175 (19) | 0.0150 (17) | 0.0001 (14) | 0.0004 (13) | 0.0028 (14) |
C16 | 0.016 (2) | 0.017 (2) | 0.019 (2) | −0.0025 (17) | 0.0005 (16) | 0.0009 (16) |
C17 | 0.017 (2) | 0.019 (2) | 0.025 (2) | 0.0032 (18) | 0.0050 (18) | −0.0032 (18) |
C18 | 0.027 (2) | 0.012 (2) | 0.029 (2) | 0.0010 (18) | 0.0007 (19) | −0.0048 (18) |
C19 | 0.020 (2) | 0.016 (2) | 0.029 (2) | −0.0069 (18) | 0.0005 (18) | 0.0001 (18) |
C20 | 0.027 (3) | 0.036 (3) | 0.032 (3) | −0.009 (2) | −0.002 (2) | 0.008 (2) |
C21 | 0.036 (3) | 0.021 (2) | 0.021 (2) | −0.001 (2) | −0.002 (2) | 0.0041 (19) |
C22 | 0.022 (2) | 0.033 (3) | 0.022 (2) | −0.005 (2) | −0.0056 (19) | −0.002 (2) |
C23 | 0.025 (2) | 0.032 (3) | 0.023 (2) | 0.005 (2) | 0.0068 (19) | 0.000 (2) |
Rh1—N1 | 2.033 (4) | C10—H10C | 0.9800 |
Rh1—N7 | 1.968 (4) | C11—H11A | 0.9800 |
Rh1—N3 | 2.098 (3) | C11—H11B | 0.9800 |
Rh1—P1 | 2.2116 (9) | C11—H11C | 0.9800 |
N7—C16 | 1.131 (6) | C12—H12A | 0.9800 |
P1—C23 | 1.818 (5) | C12—H12B | 0.9800 |
P1—C21 | 1.822 (5) | C12—H12C | 0.9800 |
P1—C22 | 1.825 (5) | C13—H13A | 0.9800 |
N1—C1 | 1.330 (6) | C13—H13B | 0.9800 |
N1—N2 | 1.373 (5) | C13—H13C | 0.9800 |
N2—C3 | 1.355 (6) | C14—H14A | 0.9800 |
N2—B1 | 1.543 (6) | C14—H14B | 0.9800 |
N3—C4 | 1.329 (5) | C14—H14C | 0.9800 |
N3—N4 | 1.377 (5) | C15—H15A | 0.9800 |
N4—C6 | 1.354 (5) | C15—H15B | 0.9800 |
N4—B1 | 1.534 (6) | C15—H15C | 0.9800 |
N5—C7 | 1.328 (6) | C16—C17 | 1.472 (7) |
N5—N6 | 1.365 (5) | C17—C18 | 1.530 (7) |
N6—C9 | 1.366 (6) | C17—H17A | 0.9900 |
N6—B1 | 1.540 (6) | C17—H17B | 0.9900 |
B1—H1 | 1.10 (4) | C18—C19 | 1.527 (7) |
C1—C2 | 1.392 (6) | C18—H18A | 0.9900 |
C1—C10 | 1.488 (6) | C18—H18B | 0.9900 |
C2—C3 | 1.388 (6) | C19—C20 | 1.528 (6) |
C2—H2 | 0.9500 | C19—H19A | 0.9900 |
C3—C11 | 1.499 (6) | C19—H19B | 0.9900 |
C4—C5 | 1.399 (6) | C20—H20A | 0.9800 |
C4—C12 | 1.495 (6) | C20—H20B | 0.9800 |
C5—C6 | 1.371 (6) | C20—H20C | 0.9800 |
C5—H5 | 0.9500 | C21—H21B | 0.9800 |
C6—C13 | 1.495 (6) | C21—H21C | 0.9800 |
C7—C8 | 1.397 (6) | C21—H21D | 0.9800 |
C7—C14 | 1.499 (6) | C22—H22A | 0.9800 |
C8—C9 | 1.384 (6) | C22—H22D | 0.9800 |
C8—H8 | 0.9500 | C22—H22B | 0.9800 |
C9—C15 | 1.494 (6) | C23—H23D | 0.9800 |
C10—H10A | 0.9800 | C23—H23A | 0.9800 |
C10—H10B | 0.9800 | C23—H23B | 0.9800 |
N7—Rh1—N1 | 175.08 (15) | H11A—C11—H11C | 109.5 |
N7—Rh1—N3 | 90.55 (14) | H11B—C11—H11C | 109.5 |
N1—Rh1—N3 | 84.61 (13) | C4—C12—H12A | 109.5 |
N7—Rh1—P1 | 89.83 (11) | C4—C12—H12B | 109.5 |
N1—Rh1—P1 | 94.77 (11) | H12A—C12—H12B | 109.5 |
N3—Rh1—P1 | 169.05 (10) | C4—C12—H12C | 109.5 |
C23—P1—C21 | 100.5 (2) | H12A—C12—H12C | 109.5 |
C23—P1—C22 | 102.8 (2) | H12B—C12—H12C | 109.5 |
C21—P1—C22 | 100.1 (2) | C6—C13—H13A | 109.5 |
C23—P1—Rh1 | 115.69 (17) | C6—C13—H13B | 109.5 |
C21—P1—Rh1 | 112.88 (18) | H13A—C13—H13B | 109.5 |
C22—P1—Rh1 | 121.76 (17) | C6—C13—H13C | 109.5 |
C1—N1—N2 | 107.2 (4) | H13A—C13—H13C | 109.5 |
C1—N1—Rh1 | 133.8 (3) | H13B—C13—H13C | 109.5 |
N2—N1—Rh1 | 118.9 (3) | C7—C14—H14A | 109.5 |
C3—N2—N1 | 109.4 (4) | C7—C14—H14B | 109.5 |
C3—N2—B1 | 129.5 (4) | H14A—C14—H14B | 109.5 |
N1—N2—B1 | 120.7 (4) | C7—C14—H14C | 109.5 |
C4—N3—N4 | 106.7 (3) | H14A—C14—H14C | 109.5 |
C4—N3—Rh1 | 135.5 (3) | H14B—C14—H14C | 109.5 |
N4—N3—Rh1 | 117.1 (2) | C9—C15—H15A | 109.5 |
C6—N4—N3 | 109.3 (3) | C9—C15—H15B | 109.5 |
C6—N4—B1 | 129.8 (3) | H15A—C15—H15B | 109.5 |
N3—N4—B1 | 120.9 (3) | C9—C15—H15C | 109.5 |
C7—N5—N6 | 106.4 (4) | H15A—C15—H15C | 109.5 |
N5—N6—C9 | 110.3 (4) | H15B—C15—H15C | 109.5 |
N5—N6—B1 | 116.4 (4) | C16—N7—Rh1 | 172.8 (4) |
C9—N6—B1 | 133.1 (4) | N7—C16—C17 | 174.4 (5) |
N4—B1—N6 | 112.7 (3) | C16—C17—C18 | 110.2 (4) |
N4—B1—N2 | 108.4 (3) | C16—C17—H17A | 109.6 |
N6—B1—N2 | 110.2 (3) | C18—C17—H17A | 109.6 |
N4—B1—H1 | 109 (2) | C16—C17—H17B | 109.6 |
N6—B1—H1 | 110 (2) | C18—C17—H17B | 109.6 |
N2—B1—H1 | 106 (2) | H17A—C17—H17B | 108.1 |
N1—C1—C2 | 110.0 (4) | C19—C18—C17 | 113.2 (4) |
N1—C1—C10 | 121.2 (4) | C19—C18—H18A | 108.9 |
C2—C1—C10 | 128.7 (4) | C17—C18—H18A | 108.9 |
C3—C2—C1 | 105.7 (4) | C19—C18—H18B | 108.9 |
C3—C2—H2 | 127.1 | C17—C18—H18B | 108.9 |
C1—C2—H2 | 127.1 | H18A—C18—H18B | 107.7 |
N2—C3—C2 | 107.6 (4) | C18—C19—C20 | 113.4 (4) |
N2—C3—C11 | 123.1 (4) | C18—C19—H19A | 108.9 |
C2—C3—C11 | 129.2 (4) | C20—C19—H19A | 108.9 |
N3—C4—C5 | 110.1 (4) | C18—C19—H19B | 108.9 |
N3—C4—C12 | 121.3 (4) | C20—C19—H19B | 108.9 |
C5—C4—C12 | 128.6 (4) | H19A—C19—H19B | 107.7 |
C6—C5—C4 | 105.7 (4) | C19—C20—H20A | 109.5 |
C6—C5—H5 | 127.1 | C19—C20—H20B | 109.5 |
C4—C5—H5 | 127.1 | H20A—C20—H20B | 109.5 |
N4—C6—C5 | 108.1 (4) | C19—C20—H20C | 109.5 |
N4—C6—C13 | 122.4 (4) | H20A—C20—H20C | 109.5 |
C5—C6—C13 | 129.5 (4) | H20B—C20—H20C | 109.5 |
N5—C7—C8 | 110.8 (4) | P1—C21—H21B | 109.5 |
N5—C7—C14 | 119.8 (4) | P1—C21—H21C | 109.5 |
C8—C7—C14 | 129.4 (4) | H21B—C21—H21C | 109.5 |
C9—C8—C7 | 105.5 (4) | P1—C21—H21D | 109.5 |
C9—C8—H8 | 127.3 | H21B—C21—H21D | 109.5 |
C7—C8—H8 | 127.3 | H21C—C21—H21D | 109.5 |
N6—C9—C8 | 107.0 (4) | P1—C22—H22A | 109.5 |
N6—C9—C15 | 125.0 (4) | P1—C22—H22D | 109.5 |
C8—C9—C15 | 127.9 (4) | H22A—C22—H22D | 109.5 |
C1—C10—H10A | 109.5 | P1—C22—H22B | 109.5 |
C1—C10—H10B | 109.5 | H22A—C22—H22B | 109.5 |
H10A—C10—H10B | 109.5 | H22D—C22—H22B | 109.5 |
C1—C10—H10C | 109.5 | P1—C23—H23D | 109.5 |
H10A—C10—H10C | 109.5 | P1—C23—H23A | 109.5 |
H10B—C10—H10C | 109.5 | H23D—C23—H23A | 109.5 |
C3—C11—H11A | 109.5 | P1—C23—H23B | 109.5 |
C3—C11—H11B | 109.5 | H23D—C23—H23B | 109.5 |
H11A—C11—H11B | 109.5 | H23A—C23—H23B | 109.5 |
C3—C11—H11C | 109.5 | ||
C1—N1—N2—C3 | −0.9 (5) | B1—N2—C3—C2 | −172.6 (4) |
Rh1—N1—N2—C3 | −178.3 (3) | N1—N2—C3—C11 | 178.2 (4) |
C1—N1—N2—B1 | 172.5 (4) | B1—N2—C3—C11 | 5.5 (7) |
Rh1—N1—N2—B1 | −4.9 (5) | C1—C2—C3—N2 | 0.9 (5) |
C4—N3—N4—C6 | −0.8 (4) | C1—C2—C3—C11 | −177.1 (5) |
Rh1—N3—N4—C6 | −172.9 (3) | N4—N3—C4—C5 | 0.4 (5) |
C4—N3—N4—B1 | −178.5 (3) | Rh1—N3—C4—C5 | 170.3 (3) |
Rh1—N3—N4—B1 | 9.5 (5) | N4—N3—C4—C12 | 178.5 (4) |
C7—N5—N6—C9 | −0.2 (5) | Rh1—N3—C4—C12 | −11.6 (6) |
C7—N5—N6—B1 | 175.6 (4) | N3—C4—C5—C6 | 0.1 (5) |
C6—N4—B1—N6 | 110.4 (5) | C12—C4—C5—C6 | −177.8 (4) |
N3—N4—B1—N6 | −72.5 (5) | N3—N4—C6—C5 | 0.9 (5) |
C6—N4—B1—N2 | −127.3 (4) | B1—N4—C6—C5 | 178.3 (4) |
N3—N4—B1—N2 | 49.8 (5) | N3—N4—C6—C13 | −179.0 (4) |
N5—N6—B1—N4 | 167.2 (3) | B1—N4—C6—C13 | −1.6 (7) |
C9—N6—B1—N4 | −18.3 (6) | C4—C5—C6—N4 | −0.6 (5) |
N5—N6—B1—N2 | 46.0 (5) | C4—C5—C6—C13 | 179.3 (5) |
C9—N6—B1—N2 | −139.5 (5) | N6—N5—C7—C8 | 0.0 (5) |
C3—N2—B1—N4 | 118.3 (5) | N6—N5—C7—C14 | 179.7 (4) |
N1—N2—B1—N4 | −53.6 (5) | N5—C7—C8—C9 | 0.1 (5) |
C3—N2—B1—N6 | −118.0 (5) | C14—C7—C8—C9 | −179.5 (4) |
N1—N2—B1—N6 | 70.1 (5) | N5—N6—C9—C8 | 0.2 (5) |
N2—N1—C1—C2 | 1.5 (5) | B1—N6—C9—C8 | −174.5 (4) |
Rh1—N1—C1—C2 | 178.3 (3) | N5—N6—C9—C15 | 177.2 (4) |
N2—N1—C1—C10 | −176.2 (4) | B1—N6—C9—C15 | 2.4 (8) |
Rh1—N1—C1—C10 | 0.6 (7) | C7—C8—C9—N6 | −0.2 (5) |
N1—C1—C2—C3 | −1.4 (5) | C7—C8—C9—C15 | −177.0 (4) |
C10—C1—C2—C3 | 176.0 (5) | C16—C17—C18—C19 | −59.0 (5) |
N1—N2—C3—C2 | 0.0 (5) | C17—C18—C19—C20 | −67.9 (5) |
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