Di-μ-acetato-bis[dicarbonyl(pyrazole)ruthenium(I)] and Di-μ-acetato-bis[dicarbonyl(3,5-dimethylpyrazole)ruthenium(I)]

Panneerselvam, K.; Lu, T.-H.; Huang, C.-H.; Tung, S.-F.; Shiu, K.-B.

doi:10.1107/S0108270197012274

Di--acetato-bis[dicarbonyl(pyrazole)ruthenium(I)] and Di--acetato-bis[dicarbonyl(3,5-dimethylpyrazole)ruthenium(I)]

K. Panneerselvam, T.-H. Lu, C.-H. Huang, S.-F. Tung and K.-B. Shiu

The crystal structures of the title compounds, [Ru₂(C₂H₃O₂)₂(C₃H₄N₂)₂(CO)₄], (1) and [Ru₂(C₂H₃O₂)₂(C₅H₈N₂)₂(CO)₄], (2), have been determined. The octahedral coordination about the Ru^I ion is slightly distorted in (I) and more distorted in (2), with the two O atoms and two C atoms in the equatorial positions, and one N atom and another Ru ion in the axial positions. Compound (2) has mirror symmetry.

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Di--acetato-bis[dicarbonyl(pyrazole)ruthenium(I)] and Di--acetato-bis[dicarbonyl(3,5-dimethylpyrazole)ruthenium(I)]

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	Crystallographic Information File (CIF) Contains datablocks I, II, global
	Structure factor file (CIF format) Contains datablock I
	Structure factor file (CIF format) Contains datablock n842