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The successful attempt to solve the crystal structure of Co(CO3)0.5(OH)·0.11H2O (denoted CCH), based on synchrotron powder diffraction data, leads to a drastic revision of the chemical formula to Co6(CO3)2(OH)8·H2O [hexacobalt(II) bis(carbonate) octahydroxide monohydrate] and to a hexagonal cell instead of the orthorhombic cell suggested previously [Porta et al. (1992). J. Chem. Soc. Faraday Trans. 88, 311–319]. This results in a new structure-type related to malachite involving infinite chains of [CoO6] octahedra sharing edges along a short c axis, delimiting tunnels having a three-branched star section. All reports discussing cobalt hydroxycarbonates (CCH) without any structural knowledge and especially its topotactic decomposition into Co3O4 have, as a result, to be reconsidered.
Supporting information
CCDC reference: 1885213
Program(s) used to solve structure: McMaille (Le Bail, 2004) and ESPOIR (Le Bail,
2001); program(s) used to refine structure: FULLPROF (Rodriguez-Carvajal, 1993); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: publCIF (Westrip, 2010).
Hexacobalt(II) bis(carbonate) octahydroxide monohydrate
top
Crystal data top
Co6(CO3)2(OH)8·H2O | Dx = 3.617 Mg m−3 |
Mr = 627.69 | Synchrotron radiation, λ = 0.807700 Å |
Hexagonal, P62m | µ = 12.06 mm−1 |
Hall symbol: P -6 -2 | T = 293 K |
a = 10.3236 (4) Å | Particle morphology: powder of nanoneedles |
c = 3.12244 (15) Å | light pink |
V = 288.20 (2) Å3 | cylinder, 0.5 × 0.5 mm |
Z = 1 | Specimen preparation: Prepared at 293 K |
F(000) = 304 | |
Data collection top
MAR345dif diffractometer | Data collection mode: transmission |
Radiation source: synchrotron | Scan method: step |
Specimen mounting: quartz capillary | 2θmin = 3.883°, 2θmax = 58.870°, 2θstep = 0.020° |
Refinement top
Rp = 3.714 | 50 parameters |
Rwp = 4.827 | 0 restraints |
Rexp = 2.465 | H-atom parameters not refined |
RBragg = 3.948 | (Δ/σ)max < 0.001 |
2805 data points | |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Co1 | 0.42427 (12) | 0.00000 | 0.00000 | 0.0180 (4)* | |
Co2 | 0.36174 (19) | 0.2336 (2) | 0.50000 | 0.0328 (7)* | 0.500 |
O1 | 0.5360 (4) | 0.2464 (4) | 0.00000 | 0.0278 (9)* | |
O2 | 0.1908 (5) | 0.1908 (5) | 0.00000 | 0.0278 (9)* | |
O3 | 0.5545 (6) | 0.00000 | 0.50000 | 0.0278 (9)* | |
O4 | 0.2852 (7) | 0.00000 | 0.50000 | 0.0278 (9)* | |
C1 | 0.66667 | 0.33333 | 0.00000 | 0.0278 (9)* | |
Geometric parameters (Å, º) top
Co1—O1 | 2.206 (4) | Co2—O1iii | 2.335 (4) |
Co1—O3 | 2.060 (4) | Co2—O2 | 2.229 (4) |
Co1—O4 | 2.121 (5) | Co2—O4 | 2.130 (2) |
Co1—O3i | 2.060 (4) | Co2—O2iii | 2.229 (4) |
Co1—O4i | 2.121 (5) | Co2—O3iv | 1.908 (6) |
Co1—O1ii | 2.206 (4) | O1—C1 | 1.189 (4) |
Co2—O1 | 2.335 (4) | | |
| | | |
O1—Co1—O3 | 92.01 (8) | Co2—O2—Co2i | 88.9 (2) |
O1—Co1—O4 | 87.92 (8) | Co2—O2—Co2v | 120.7 (2) |
O1—Co1—O3i | 92.01 (8) | Co2—O2—Co2vi | 61.87 (10) |
O1—Co1—O4i | 87.92 (8) | Co2i—O2—Co2v | 61.87 (10) |
O1—Co1—O1ii | 173.9 (2) | Co2i—O2—Co2vi | 120.7 (2) |
O3—Co1—O4 | 83.34 (19) | Co2v—O2—Co2vi | 88.94 (17) |
O3—Co1—O3i | 98.53 (19) | Co1—O3—Co1iii | 98.5 (3) |
O3—Co1—O4i | 178.1 (2) | Co1—O3—Co2vii | 121.46 (6) |
O1ii—Co1—O3 | 92.01 (11) | Co1—O3—Co2viii | 121.46 (6) |
O3i—Co1—O4 | 178.1 (2) | Co1iii—O3—Co2vii | 121.46 (6) |
O4—Co1—O4i | 94.8 (2) | Co1iii—O3—Co2viii | 121.46 (6) |
O1ii—Co1—O4 | 87.92 (12) | Co2vii—O3—Co2viii | 73.8 (3) |
O3i—Co1—O4i | 83.34 (19) | Co1—O4—Co2 | 97.59 (11) |
O1ii—Co1—O3i | 92.01 (11) | Co1—O4—Co1iii | 94.8 (3) |
O1ii—Co1—O4i | 87.92 (12) | Co1—O4—Co2ix | 97.60 (12) |
O2—Co2—O4 | 88.10 (19) | Co1iii—O4—Co2 | 97.59 (11) |
O2—Co2—O2iii | 88.94 (17) | Co2—O4—Co2ix | 157.5 (4) |
O2—Co2—O3iv | 95.0 (2) | Co1iii—O4—Co2ix | 97.60 (12) |
O2iii—Co2—O4 | 88.10 (19) | O1—C1—O1x | 120.0 (4) |
O3iv—Co2—O4 | 175.6 (3) | O1—C1—O1vii | 120.0 (3) |
O2iii—Co2—O3iv | 95.0 (2) | O1x—C1—O1vii | 120.0 (4) |
Co1—O1—C1 | 127.7 (3) | | |
| | | |
O3—Co1—O1—C1 | 49.31 (13) | O3—Co1—O4—Co2 | 98.33 (17) |
O4—Co1—O1—C1 | 132.56 (15) | O2—Co2—O4—Co1 | 87.6 (2) |
O1—Co1—O4—Co2 | 6.07 (19) | | |
Symmetry codes: (i) x, y, z−1; (ii) x−y, −y, −z; (iii) x, y, z+1; (iv) −x+y+1, −x+1, −z+1; (v) y, x, z−1; (vi) y, x, z; (vii) −y+1, x−y, z; (viii) −x+1, −x+y, z; (ix) x−y, −y, −z+1; (x) −x+y+1, −x+1, −z. |
Valence bond analysis according to the empirical expression from Brown and
Altermatt [Brown, I. D. and Altermatt, D. (1985). Acta Cryst.
B41,
244–247], using parameters for solids from Brese and O'Keeffe
[Brese, N. E. and O'Keeffe, M. (1991). Acta Cryst. B47,
192–197].
The valence deficit observed for atoms O2, O3 and O4 is expected to be
compensated by hydrogen bonding and the water molecule would be preferentially
located on the O2 site. top | O1 | O2 | O3 | O4 | Σ | Σ(expected) |
Co1 | 0.245 × 2 | | 0.363 × 2 | 0.308 × 2 | 1.83 | 2 |
| | | × 2 | × 2 | | |
Co2 | 0.173 × 2 | 0.230 × 2 | 0.547 | 0.301 | 1.65 | 2 |
| | × 2 | | | | |
C1 | 1.721 × 3 | | | | 5.16 | 4 |
Σ | 2.14 | 0.46 | 1.23 | 0.92 | | |
Σ(expected) | 2 | 2 | 2 | 2 | | |
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