Bis(pyridine-2-thione)-2κS;3κS-tetra-μ-sulfido-1:2κ4S;1:3κ4S-bis(triphenylphosphine)-2κP;3κP-dicoppermolybdenum Bis(dichloromethane) Solvate

Wang, Q.; Wu, X.; Huang, Q.; Sheng, T.

doi:10.1107/S0108270196008608

Bis(pyridine-2-thione)-2κS;3κS-tetra-μ-sulfido-1:2κ⁴S;1:3κ⁴S-bis(triphenylphosphine)-2κP;3κP-dicoppermolybdenum Bis(dichloromethane) Solvate

The structure determination of [Cu₂MoS₄(C₅H₅NS)₂(C₁₈H₁₅P)₂].2CH₂Cl₂ is reported. The compound contains a linear [CuS₂MoS₂Cu] cluster core, with each Cu atom having a distorted tetrahedral coordination involving two S atoms at a tetradentate MoS₄²⁻ moiety, one S atom of a pyridine-2-thione ligand and one P atom of a triphenylphosphine ligand.

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Bis(pyridine-2-thione)-2κS;3κS-tetra-μ-sulfido-1:2κ⁴S;1:3κ⁴S-bis(triphenylphosphine)-2κP;3κP-dicoppermolybdenum Bis(dichloromethane) Solvate

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