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metal-organic compounds
The Sn atom in the title compound, [Sn(CH3)2(C15H9Cl2O2)2], has a highly distorted octahedral coordination that may be best described as skew-trapezoid planar for the carboxylates. The ligands are asymmetrically coordinated to the Sn atoms with Sn—O covalent bonds and dative bonds. The mean Sn—C distance for the methyl groups is 2.094 (6) Å, with a bent C—Sn—C angle of 145.77 (11)°.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804014710/lh6234sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804014710/lh6234Isup2.hkl |
CCDC reference: 245149
Key indicators
- Single-crystal X-ray study
- T = 173 K
- Mean (C-C) = 0.004 Å
- R factor = 0.032
- wR factor = 0.075
- Data-to-parameter ratio = 18.0
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Sn1 - O4 .. 5.10 su
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 1 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion
Computing details top
Data collection: COLLECT (Hooft, 1998); cell refinement: HKL DENZO (Otwinowski & Minor, 1997); data reduction: SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SAPI91 (Fan, 1991); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97 (Sheldrick, 1997).
Crystal data top
[Sn(CH3)2(C15H9Cl2O2)2] | Z = 2 |
Mr = 733.00 | F(000) = 732 |
Triclinic, P1 | Dx = 1.625 Mg m−3 |
Hall symbol: -P 1 | Melting point: 473-476 K K |
a = 8.4740 (11) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 10.2770 (12) Å | Cell parameters from 12446 reflections |
c = 19.472 (4) Å | θ = 3.1–27.3° |
α = 95.817 (6)° | µ = 1.25 mm−1 |
β = 99.748 (7)° | T = 173 K |
γ = 114.116 (8)° | Prism, colorless |
V = 1497.7 (4) Å3 | 0.14 × 0.12 × 0.10 mm |
Data collection top
Nonius KappaCCD diffractometer | 6683 independent reflections |
Radiation source: fine-focus sealed tube | 5570 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.032 |
ω and φ scans | θmax = 27.3°, θmin = 3.1° |
Absorption correction: multi-scan (SORTAV; Blessing, 1997) | h = −10→10 |
Tmin = 0.845, Tmax = 0.886 | k = −13→13 |
12446 measured reflections | l = −25→25 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.032 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.075 | H-atom parameters constrained |
S = 1.01 | w = 1/[σ2(Fo2) + (0.0343P)2 + 0.4509P] where P = (Fo2 + 2Fc2)/3 |
6683 reflections | (Δ/σ)max = 0.01 |
372 parameters | Δρmax = 0.43 e Å−3 |
0 restraints | Δρmin = −0.68 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Sn1 | 0.26139 (2) | 0.005495 (17) | 0.417574 (9) | 0.02159 (7) | |
Cl1 | −0.24802 (11) | −0.55145 (9) | −0.01231 (4) | 0.0531 (2) | |
Cl2 | −0.71382 (10) | 0.12751 (9) | 0.03621 (4) | 0.0447 (2) | |
Cl3 | 0.02708 (9) | 0.65950 (7) | 0.62064 (4) | 0.03262 (16) | |
Cl4 | 1.05421 (10) | 0.80855 (8) | 0.90539 (4) | 0.04376 (19) | |
O1 | 0.0518 (2) | 0.02613 (19) | 0.35061 (9) | 0.0303 (4) | |
O2 | 0.0772 (2) | −0.16400 (18) | 0.29998 (9) | 0.0281 (4) | |
O3 | 0.2828 (2) | 0.19300 (18) | 0.48343 (9) | 0.0262 (4) | |
O4 | 0.4908 (2) | 0.13198 (18) | 0.53037 (9) | 0.0281 (4) | |
C1 | 0.1230 (3) | −0.1579 (3) | 0.46970 (15) | 0.0305 (6) | |
H1A | 0.2003 | −0.1499 | 0.5150 | 0.046* | |
H1B | 0.0860 | −0.2531 | 0.4401 | 0.046* | |
H1C | 0.0178 | −0.1476 | 0.4784 | 0.046* | |
C2 | 0.4616 (4) | 0.0795 (3) | 0.36113 (15) | 0.0339 (6) | |
H2A | 0.5746 | 0.1453 | 0.3941 | 0.051* | |
H2B | 0.4300 | 0.1312 | 0.3256 | 0.051* | |
H2C | 0.4737 | −0.0036 | 0.3374 | 0.051* | |
C3 | 0.0026 (3) | −0.0817 (3) | 0.29848 (13) | 0.0243 (5) | |
C4 | −0.1431 (3) | −0.1031 (3) | 0.23630 (13) | 0.0245 (5) | |
C5 | −0.2237 (3) | −0.0140 (3) | 0.24145 (13) | 0.0251 (5) | |
H5 | −0.1886 | 0.0465 | 0.2868 | 0.030* | |
C6 | −0.1736 (3) | −0.2153 (3) | 0.17416 (13) | 0.0239 (5) | |
C7 | −0.0449 (4) | −0.1902 (3) | 0.13481 (14) | 0.0316 (6) | |
H7 | 0.0605 | −0.1016 | 0.1476 | 0.038* | |
C8 | −0.0681 (4) | −0.2928 (3) | 0.07707 (15) | 0.0352 (6) | |
H8 | 0.0197 | −0.2742 | 0.0501 | 0.042* | |
C9 | −0.2200 (4) | −0.4219 (3) | 0.05950 (14) | 0.0319 (6) | |
C10 | −0.3494 (4) | −0.4506 (3) | 0.09780 (15) | 0.0325 (6) | |
H10 | −0.4533 | −0.5402 | 0.0852 | 0.039* | |
C11 | −0.3258 (3) | −0.3467 (3) | 0.15506 (14) | 0.0272 (6) | |
H11 | −0.4147 | −0.3657 | 0.1815 | 0.033* | |
C12 | −0.3553 (3) | 0.0060 (3) | 0.18972 (14) | 0.0264 (6) | |
C13 | −0.4555 (3) | −0.0855 (3) | 0.12429 (14) | 0.0298 (6) | |
H13 | −0.4474 | −0.1740 | 0.1119 | 0.036* | |
C14 | −0.5661 (4) | −0.0489 (3) | 0.07751 (15) | 0.0323 (6) | |
H14 | −0.6332 | −0.1116 | 0.0333 | 0.039* | |
C15 | −0.5780 (3) | 0.0799 (3) | 0.09582 (14) | 0.0305 (6) | |
C16 | −0.4836 (4) | 0.1716 (3) | 0.16014 (15) | 0.0331 (6) | |
H16 | −0.4937 | 0.2593 | 0.1724 | 0.040* | |
C17 | −0.3743 (4) | 0.1337 (3) | 0.20629 (14) | 0.0302 (6) | |
H17 | −0.3098 | 0.1964 | 0.2508 | 0.036* | |
C18 | 0.4145 (3) | 0.2129 (3) | 0.53461 (13) | 0.0228 (5) | |
C19 | 0.4681 (3) | 0.3310 (2) | 0.59681 (13) | 0.0218 (5) | |
C20 | 0.6116 (3) | 0.3532 (3) | 0.64726 (13) | 0.0245 (5) | |
H20 | 0.6584 | 0.2846 | 0.6398 | 0.029* | |
C21 | 0.3564 (3) | 0.4112 (2) | 0.60124 (13) | 0.0202 (5) | |
C22 | 0.3138 (3) | 0.4765 (2) | 0.54587 (13) | 0.0222 (5) | |
H22 | 0.3540 | 0.4683 | 0.5037 | 0.027* | |
C23 | 0.2135 (3) | 0.5529 (2) | 0.55209 (13) | 0.0223 (5) | |
H23 | 0.1870 | 0.5989 | 0.5148 | 0.027* | |
C24 | 0.1520 (3) | 0.5620 (2) | 0.61307 (14) | 0.0231 (5) | |
C25 | 0.1876 (3) | 0.4945 (3) | 0.66803 (14) | 0.0263 (6) | |
H25 | 0.1433 | 0.4997 | 0.7094 | 0.032* | |
C26 | 0.2894 (3) | 0.4193 (3) | 0.66109 (13) | 0.0241 (5) | |
H26 | 0.3140 | 0.3721 | 0.6982 | 0.029* | |
C27 | 0.7075 (3) | 0.4645 (3) | 0.71148 (13) | 0.0250 (5) | |
C28 | 0.8130 (4) | 0.4355 (3) | 0.76525 (14) | 0.0321 (6) | |
H28 | 0.8128 | 0.3425 | 0.7607 | 0.038* | |
C29 | 0.9181 (4) | 0.5401 (3) | 0.82526 (15) | 0.0359 (7) | |
H29 | 0.9889 | 0.5189 | 0.8616 | 0.043* | |
C30 | 0.9188 (3) | 0.6749 (3) | 0.83167 (14) | 0.0310 (6) | |
C31 | 0.8164 (4) | 0.7075 (3) | 0.77893 (15) | 0.0317 (6) | |
H31 | 0.8187 | 0.8012 | 0.7837 | 0.038* | |
C32 | 0.7115 (3) | 0.6032 (3) | 0.71965 (14) | 0.0279 (6) | |
H32 | 0.6408 | 0.6254 | 0.6837 | 0.034* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Sn1 | 0.02230 (10) | 0.01842 (9) | 0.02110 (10) | 0.00858 (7) | 0.00058 (7) | −0.00027 (7) |
Cl1 | 0.0521 (5) | 0.0577 (5) | 0.0428 (5) | 0.0328 (4) | −0.0090 (4) | −0.0255 (4) |
Cl2 | 0.0458 (4) | 0.0523 (4) | 0.0395 (4) | 0.0335 (4) | −0.0083 (3) | 0.0011 (3) |
Cl3 | 0.0314 (4) | 0.0343 (3) | 0.0356 (4) | 0.0202 (3) | 0.0061 (3) | −0.0025 (3) |
Cl4 | 0.0360 (4) | 0.0483 (4) | 0.0279 (4) | 0.0082 (3) | −0.0025 (3) | −0.0134 (3) |
O1 | 0.0349 (10) | 0.0286 (9) | 0.0233 (10) | 0.0173 (9) | −0.0067 (8) | −0.0060 (8) |
O2 | 0.0296 (10) | 0.0250 (9) | 0.0269 (10) | 0.0137 (8) | −0.0016 (8) | −0.0007 (7) |
O3 | 0.0265 (9) | 0.0241 (9) | 0.0237 (9) | 0.0123 (8) | −0.0036 (8) | −0.0037 (7) |
O4 | 0.0281 (10) | 0.0256 (9) | 0.0290 (10) | 0.0145 (8) | −0.0001 (8) | −0.0038 (8) |
C1 | 0.0222 (13) | 0.0295 (14) | 0.0345 (16) | 0.0074 (12) | 0.0017 (12) | 0.0083 (12) |
C2 | 0.0310 (15) | 0.0336 (15) | 0.0305 (15) | 0.0072 (13) | 0.0085 (12) | 0.0054 (12) |
C3 | 0.0257 (13) | 0.0222 (12) | 0.0200 (13) | 0.0079 (11) | 0.0011 (11) | 0.0010 (10) |
C4 | 0.0264 (13) | 0.0234 (13) | 0.0194 (13) | 0.0090 (11) | 0.0007 (11) | 0.0021 (10) |
C5 | 0.0267 (13) | 0.0275 (13) | 0.0188 (13) | 0.0114 (11) | 0.0017 (11) | 0.0024 (10) |
C6 | 0.0268 (13) | 0.0239 (12) | 0.0187 (13) | 0.0122 (11) | −0.0015 (10) | 0.0006 (10) |
C7 | 0.0284 (14) | 0.0312 (14) | 0.0296 (15) | 0.0105 (12) | 0.0019 (12) | −0.0001 (12) |
C8 | 0.0358 (16) | 0.0426 (16) | 0.0286 (15) | 0.0205 (14) | 0.0060 (13) | 0.0009 (13) |
C9 | 0.0357 (16) | 0.0340 (15) | 0.0255 (14) | 0.0220 (13) | −0.0056 (12) | −0.0060 (12) |
C10 | 0.0353 (15) | 0.0226 (13) | 0.0322 (16) | 0.0124 (12) | −0.0072 (13) | 0.0003 (11) |
C11 | 0.0279 (14) | 0.0264 (13) | 0.0228 (13) | 0.0106 (12) | −0.0009 (11) | 0.0020 (11) |
C12 | 0.0260 (13) | 0.0285 (13) | 0.0233 (14) | 0.0121 (12) | 0.0031 (11) | 0.0023 (11) |
C13 | 0.0300 (14) | 0.0291 (14) | 0.0278 (15) | 0.0155 (12) | −0.0026 (12) | −0.0012 (11) |
C14 | 0.0312 (15) | 0.0337 (15) | 0.0272 (15) | 0.0156 (13) | −0.0046 (12) | −0.0028 (12) |
C15 | 0.0263 (14) | 0.0391 (15) | 0.0279 (15) | 0.0183 (13) | 0.0010 (12) | 0.0058 (12) |
C16 | 0.0367 (16) | 0.0345 (15) | 0.0327 (16) | 0.0224 (13) | 0.0049 (13) | 0.0007 (12) |
C17 | 0.0331 (15) | 0.0326 (14) | 0.0235 (14) | 0.0160 (13) | 0.0021 (12) | −0.0011 (11) |
C18 | 0.0218 (12) | 0.0192 (12) | 0.0226 (13) | 0.0056 (10) | 0.0030 (10) | 0.0017 (10) |
C19 | 0.0215 (12) | 0.0180 (11) | 0.0238 (13) | 0.0081 (10) | 0.0028 (10) | 0.0023 (10) |
C20 | 0.0265 (13) | 0.0215 (12) | 0.0258 (14) | 0.0127 (11) | 0.0026 (11) | 0.0015 (10) |
C21 | 0.0189 (12) | 0.0155 (11) | 0.0196 (12) | 0.0040 (10) | 0.0000 (10) | −0.0023 (9) |
C22 | 0.0215 (12) | 0.0214 (12) | 0.0196 (13) | 0.0060 (10) | 0.0053 (10) | 0.0006 (10) |
C23 | 0.0224 (13) | 0.0194 (12) | 0.0226 (13) | 0.0082 (11) | 0.0020 (10) | 0.0016 (10) |
C24 | 0.0178 (12) | 0.0194 (12) | 0.0288 (14) | 0.0071 (10) | 0.0048 (10) | −0.0037 (10) |
C25 | 0.0252 (13) | 0.0253 (13) | 0.0233 (14) | 0.0072 (11) | 0.0058 (11) | −0.0012 (11) |
C26 | 0.0242 (13) | 0.0230 (12) | 0.0206 (13) | 0.0080 (11) | 0.0006 (10) | 0.0022 (10) |
C27 | 0.0232 (13) | 0.0279 (13) | 0.0219 (13) | 0.0124 (11) | 0.0004 (11) | −0.0013 (10) |
C28 | 0.0369 (16) | 0.0316 (14) | 0.0290 (15) | 0.0195 (13) | 0.0011 (12) | 0.0022 (12) |
C29 | 0.0352 (16) | 0.0438 (16) | 0.0257 (15) | 0.0207 (14) | −0.0058 (12) | −0.0001 (13) |
C30 | 0.0237 (13) | 0.0367 (15) | 0.0239 (14) | 0.0092 (12) | 0.0014 (11) | −0.0069 (12) |
C31 | 0.0280 (14) | 0.0274 (14) | 0.0326 (16) | 0.0091 (12) | 0.0014 (12) | −0.0027 (12) |
C32 | 0.0253 (13) | 0.0267 (13) | 0.0283 (14) | 0.0115 (12) | −0.0013 (11) | 0.0016 (11) |
Geometric parameters (Å, º) top
Sn1—C1 | 2.089 (3) | C12—C17 | 1.399 (4) |
Sn1—C2 | 2.100 (3) | C12—C13 | 1.403 (4) |
Sn1—O1 | 2.116 (2) | C13—C14 | 1.385 (4) |
Sn1—O3 | 2.127 (2) | C13—H13 | 0.9500 |
Sn1—O4 | 2.491 (2) | C14—C15 | 1.384 (4) |
Sn1—O2 | 2.544 (2) | C14—H14 | 0.9500 |
Cl1—C9 | 1.743 (3) | C15—C16 | 1.379 (4) |
Cl2—C15 | 1.742 (3) | C16—C17 | 1.379 (4) |
Cl3—C24 | 1.743 (2) | C16—H16 | 0.9500 |
Cl4—C30 | 1.737 (3) | C17—H17 | 0.9500 |
O1—C3 | 1.297 (3) | C18—C19 | 1.487 (3) |
O2—C3 | 1.246 (3) | C19—C20 | 1.348 (3) |
O3—C18 | 1.294 (3) | C19—C21 | 1.495 (3) |
O4—C18 | 1.249 (3) | C20—C27 | 1.463 (3) |
C1—H1A | 0.9800 | C20—H20 | 0.9500 |
C1—H1B | 0.9800 | C21—C26 | 1.389 (4) |
C1—H1C | 0.9800 | C21—C22 | 1.398 (3) |
C2—H2A | 0.9800 | C22—C23 | 1.384 (3) |
C2—H2B | 0.9800 | C22—H22 | 0.9500 |
C2—H2C | 0.9800 | C23—C24 | 1.384 (4) |
C3—C4 | 1.502 (3) | C23—H23 | 0.9500 |
C4—C5 | 1.353 (3) | C24—C25 | 1.389 (4) |
C4—C6 | 1.493 (3) | C25—C26 | 1.386 (3) |
C5—C12 | 1.466 (3) | C25—H25 | 0.9500 |
C5—H5 | 0.9500 | C26—H26 | 0.9500 |
C6—C7 | 1.392 (4) | C27—C28 | 1.396 (4) |
C6—C11 | 1.393 (4) | C27—C32 | 1.404 (3) |
C7—C8 | 1.389 (4) | C28—C29 | 1.387 (4) |
C7—H7 | 0.9500 | C28—H28 | 0.9500 |
C8—C9 | 1.378 (4) | C29—C30 | 1.376 (4) |
C8—H8 | 0.9500 | C29—H29 | 0.9500 |
C9—C10 | 1.379 (4) | C30—C31 | 1.387 (4) |
C10—C11 | 1.390 (4) | C31—C32 | 1.377 (4) |
C10—H10 | 0.9500 | C31—H31 | 0.9500 |
C11—H11 | 0.9500 | C32—H32 | 0.9500 |
C1—Sn1—C2 | 145.77 (11) | C14—C13—C12 | 121.1 (2) |
C1—Sn1—O1 | 101.90 (9) | C14—C13—H13 | 119.5 |
C2—Sn1—O1 | 100.97 (10) | C12—C13—H13 | 119.5 |
C1—Sn1—O3 | 101.12 (9) | C15—C14—C13 | 119.4 (2) |
C2—Sn1—O3 | 106.20 (9) | C15—C14—H14 | 120.3 |
O1—Sn1—O3 | 84.27 (6) | C13—C14—H14 | 120.3 |
C1—Sn1—O4 | 89.28 (9) | C16—C15—C14 | 121.3 (2) |
C2—Sn1—O4 | 89.19 (9) | C16—C15—Cl2 | 119.4 (2) |
O1—Sn1—O4 | 140.23 (6) | C14—C15—Cl2 | 119.3 (2) |
O3—Sn1—O4 | 56.03 (6) | C15—C16—C17 | 118.8 (2) |
C1—Sn1—O2 | 88.61 (9) | C15—C16—H16 | 120.6 |
C2—Sn1—O2 | 83.70 (9) | C17—C16—H16 | 120.6 |
O1—Sn1—O2 | 55.55 (6) | C16—C17—C12 | 122.1 (3) |
O3—Sn1—O2 | 139.83 (6) | C16—C17—H17 | 118.9 |
O4—Sn1—O2 | 164.02 (5) | C12—C17—H17 | 118.9 |
C3—O1—Sn1 | 101.33 (14) | O4—C18—O3 | 119.1 (2) |
C3—O2—Sn1 | 82.90 (14) | O4—C18—C19 | 122.4 (2) |
C18—O3—Sn1 | 100.18 (14) | O3—C18—C19 | 118.5 (2) |
C18—O4—Sn1 | 84.58 (14) | C20—C19—C18 | 116.7 (2) |
Sn1—C1—H1A | 109.5 | C20—C19—C21 | 124.6 (2) |
Sn1—C1—H1B | 109.5 | C18—C19—C21 | 118.7 (2) |
H1A—C1—H1B | 109.5 | C19—C20—C27 | 131.1 (2) |
Sn1—C1—H1C | 109.5 | C19—C20—H20 | 114.4 |
H1A—C1—H1C | 109.5 | C27—C20—H20 | 114.4 |
H1B—C1—H1C | 109.5 | C26—C21—C22 | 118.7 (2) |
Sn1—C2—H2A | 109.5 | C26—C21—C19 | 119.6 (2) |
Sn1—C2—H2B | 109.5 | C22—C21—C19 | 121.7 (2) |
H2A—C2—H2B | 109.5 | C23—C22—C21 | 120.5 (2) |
Sn1—C2—H2C | 109.5 | C23—C22—H22 | 119.8 |
H2A—C2—H2C | 109.5 | C21—C22—H22 | 119.8 |
H2B—C2—H2C | 109.5 | C22—C23—C24 | 119.5 (2) |
O2—C3—O1 | 120.2 (2) | C22—C23—H23 | 120.2 |
O2—C3—C4 | 121.1 (2) | C24—C23—H23 | 120.2 |
O1—C3—C4 | 118.7 (2) | C23—C24—C25 | 121.2 (2) |
C5—C4—C6 | 127.8 (2) | C23—C24—Cl3 | 119.19 (19) |
C5—C4—C3 | 116.8 (2) | C25—C24—Cl3 | 119.6 (2) |
C6—C4—C3 | 115.3 (2) | C26—C25—C24 | 118.4 (2) |
C4—C5—C12 | 131.6 (2) | C26—C25—H25 | 120.8 |
C4—C5—H5 | 114.2 | C24—C25—H25 | 120.8 |
C12—C5—H5 | 114.2 | C25—C26—C21 | 121.6 (2) |
C7—C6—C11 | 118.5 (2) | C25—C26—H26 | 119.2 |
C7—C6—C4 | 119.5 (2) | C21—C26—H26 | 119.2 |
C11—C6—C4 | 122.0 (2) | C28—C27—C32 | 118.0 (2) |
C8—C7—C6 | 121.0 (3) | C28—C27—C20 | 118.0 (2) |
C8—C7—H7 | 119.5 | C32—C27—C20 | 123.7 (2) |
C6—C7—H7 | 119.5 | C29—C28—C27 | 121.1 (2) |
C9—C8—C7 | 119.1 (3) | C29—C28—H28 | 119.4 |
C9—C8—H8 | 120.5 | C27—C28—H28 | 119.4 |
C7—C8—H8 | 120.5 | C30—C29—C28 | 119.4 (2) |
C8—C9—C10 | 121.3 (3) | C30—C29—H29 | 120.3 |
C8—C9—Cl1 | 119.1 (2) | C28—C29—H29 | 120.3 |
C10—C9—Cl1 | 119.6 (2) | C29—C30—C31 | 120.9 (2) |
C9—C10—C11 | 119.2 (3) | C29—C30—Cl4 | 119.9 (2) |
C9—C10—H10 | 120.4 | C31—C30—Cl4 | 119.2 (2) |
C11—C10—H10 | 120.4 | C32—C31—C30 | 119.6 (2) |
C10—C11—C6 | 120.9 (3) | C32—C31—H31 | 120.2 |
C10—C11—H11 | 119.6 | C30—C31—H31 | 120.2 |
C6—C11—H11 | 119.6 | C31—C32—C27 | 121.0 (2) |
C17—C12—C13 | 117.4 (2) | C31—C32—H32 | 119.5 |
C17—C12—C5 | 115.9 (2) | C27—C32—H32 | 119.5 |
C13—C12—C5 | 126.6 (2) | ||
C1—Sn1—O1—C3 | −80.61 (17) | C17—C12—C13—C14 | 1.3 (4) |
C2—Sn1—O1—C3 | 73.75 (17) | C5—C12—C13—C14 | −175.0 (3) |
O3—Sn1—O1—C3 | 179.19 (16) | C12—C13—C14—C15 | −0.2 (4) |
O4—Sn1—O1—C3 | 175.91 (14) | C13—C14—C15—C16 | −0.8 (4) |
O2—Sn1—O1—C3 | −0.68 (14) | C13—C14—C15—Cl2 | 178.7 (2) |
C1—Sn1—O2—C3 | 106.17 (16) | C14—C15—C16—C17 | 0.7 (4) |
C2—Sn1—O2—C3 | −107.24 (17) | Cl2—C15—C16—C17 | −178.9 (2) |
O1—Sn1—O2—C3 | 0.70 (15) | C15—C16—C17—C12 | 0.5 (4) |
O3—Sn1—O2—C3 | 0.49 (19) | C13—C12—C17—C16 | −1.4 (4) |
O4—Sn1—O2—C3 | −171.3 (2) | C5—C12—C17—C16 | 175.2 (3) |
C1—Sn1—O3—C18 | 79.62 (16) | Sn1—O4—C18—O3 | −3.0 (2) |
C2—Sn1—O3—C18 | −79.55 (17) | Sn1—O4—C18—C19 | 176.4 (2) |
O1—Sn1—O3—C18 | −179.34 (15) | Sn1—O3—C18—O4 | 3.6 (3) |
O4—Sn1—O3—C18 | −1.88 (14) | Sn1—O3—C18—C19 | −175.89 (18) |
O2—Sn1—O3—C18 | −179.18 (13) | O4—C18—C19—C20 | 3.9 (4) |
C1—Sn1—O4—C18 | −102.03 (16) | O3—C18—C19—C20 | −176.7 (2) |
C2—Sn1—O4—C18 | 112.17 (16) | O4—C18—C19—C21 | −173.0 (2) |
O1—Sn1—O4—C18 | 5.87 (19) | O3—C18—C19—C21 | 6.4 (3) |
O3—Sn1—O4—C18 | 1.92 (14) | C18—C19—C20—C27 | 174.8 (3) |
O2—Sn1—O4—C18 | 175.6 (2) | C21—C19—C20—C27 | −8.5 (5) |
Sn1—O2—C3—O1 | −1.1 (2) | C20—C19—C21—C26 | −51.7 (3) |
Sn1—O2—C3—C4 | 177.9 (2) | C18—C19—C21—C26 | 125.0 (3) |
Sn1—O1—C3—O2 | 1.3 (3) | C20—C19—C21—C22 | 129.6 (3) |
Sn1—O1—C3—C4 | −177.67 (19) | C18—C19—C21—C22 | −53.7 (3) |
O2—C3—C4—C5 | 176.0 (2) | C26—C21—C22—C23 | 2.8 (4) |
O1—C3—C4—C5 | −5.1 (4) | C19—C21—C22—C23 | −178.5 (2) |
O2—C3—C4—C6 | −7.6 (4) | C21—C22—C23—C24 | −1.4 (4) |
O1—C3—C4—C6 | 171.3 (2) | C22—C23—C24—C25 | −0.7 (4) |
C6—C4—C5—C12 | −2.9 (5) | C22—C23—C24—Cl3 | 179.58 (19) |
C3—C4—C5—C12 | 173.0 (3) | C23—C24—C25—C26 | 1.1 (4) |
C5—C4—C6—C7 | 107.7 (3) | Cl3—C24—C25—C26 | −179.11 (18) |
C3—C4—C6—C7 | −68.3 (3) | C24—C25—C26—C21 | 0.4 (4) |
C5—C4—C6—C11 | −73.9 (4) | C22—C21—C26—C25 | −2.3 (4) |
C3—C4—C6—C11 | 110.2 (3) | C19—C21—C26—C25 | 178.9 (2) |
C11—C6—C7—C8 | 0.9 (4) | C19—C20—C27—C28 | 159.5 (3) |
C4—C6—C7—C8 | 179.4 (2) | C19—C20—C27—C32 | −26.1 (5) |
C6—C7—C8—C9 | −1.0 (4) | C32—C27—C28—C29 | 0.4 (4) |
C7—C8—C9—C10 | 0.4 (4) | C20—C27—C28—C29 | 175.1 (3) |
C7—C8—C9—Cl1 | −179.3 (2) | C27—C28—C29—C30 | −0.3 (5) |
C8—C9—C10—C11 | 0.3 (4) | C28—C29—C30—C31 | −0.2 (5) |
Cl1—C9—C10—C11 | 179.89 (19) | C28—C29—C30—Cl4 | −178.3 (2) |
C9—C10—C11—C6 | −0.3 (4) | C29—C30—C31—C32 | 0.6 (4) |
C7—C6—C11—C10 | −0.3 (4) | Cl4—C30—C31—C32 | 178.7 (2) |
C4—C6—C11—C10 | −178.7 (2) | C30—C31—C32—C27 | −0.5 (4) |
C4—C5—C12—C17 | −163.1 (3) | C28—C27—C32—C31 | 0.0 (4) |
C4—C5—C12—C13 | 13.2 (5) | C20—C27—C32—C31 | −174.4 (3) |
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